JPH07195273A - Surface treatment method of metallic material - Google Patents
Surface treatment method of metallic materialInfo
- Publication number
- JPH07195273A JPH07195273A JP5352598A JP35259893A JPH07195273A JP H07195273 A JPH07195273 A JP H07195273A JP 5352598 A JP5352598 A JP 5352598A JP 35259893 A JP35259893 A JP 35259893A JP H07195273 A JPH07195273 A JP H07195273A
- Authority
- JP
- Japan
- Prior art keywords
- inorganic salt
- shot
- metallic material
- powder
- surface treatment
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B24—GRINDING; POLISHING
- B24C—ABRASIVE OR RELATED BLASTING WITH PARTICULATE MATERIAL
- B24C1/00—Methods for use of abrasive blasting for producing particular effects; Use of auxiliary equipment in connection with such methods
- B24C1/08—Methods for use of abrasive blasting for producing particular effects; Use of auxiliary equipment in connection with such methods for polishing surfaces, e.g. smoothing a surface by making use of liquid-borne abrasives
- B24C1/086—Descaling; Removing coating films
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B24—GRINDING; POLISHING
- B24C—ABRASIVE OR RELATED BLASTING WITH PARTICULATE MATERIAL
- B24C11/00—Selection of abrasive materials or additives for abrasive blasts
- B24C11/005—Selection of abrasive materials or additives for abrasive blasts of additives, e.g. anti-corrosive or disinfecting agents in solid, liquid or gaseous form
Abstract
Description
【０００１】[0001]
【産業上の利用分野】この発明は、金属材料の表面を研
磨し、かつ該表面に防食被膜を形成するための処理方法
に関するものである。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a treatment method for polishing a surface of a metal material and forming an anticorrosion coating on the surface.
【０００２】[0002]
【従来の技術】ボルト、ナット、その他の鍛造機械部品
の製造に供される線材に防食被膜を形成するための処理
方法として、ディッピング方式が知られている。このデ
ィッピング方式では、図３に示すように、処理用線材の
コイル１０をコの字形状のハッカー１１に掛け、このハ
ッカー１１をホイスト（図示されていない）で吊下げ、
オーバーレールに沿って移動させながら第１酸洗槽１２
ａ、第２酸洗槽１２ｂ、第３酸洗槽１２ｃ、第１水洗槽
１３ａ、第２水洗槽１３ｂ、第３水洗槽１３ｃ、化成被
膜用薬液槽１４、第４水洗槽１３ｄ、湯洗槽１５および
潤滑剤槽１６に順に浸漬し、その間に線材表面のスケー
ル等を除去し、この除去後の線材表面にリン酸塩等の化
成被膜およびステアリン酸系もしくは石灰石鹸系の潤滑
剤被膜を形成し、しかるのち乾燥機１７で乾燥し（ただ
し、潤滑剤が８０℃以上の高温の場合は乾燥が省略され
る）、アンコイラー１８でコイル１０を巻き戻し、線材
１０ａを第１引張りローラ１９ａで引出し、スキンパス
２０のダイスに通し、第２引張りローラ１９ｂで引出し
て線径を均一にしたのち巻芯２１に巻取り、再びコイル
１０Ａを形成していた。2. Description of the Related Art A dipping method is known as a processing method for forming an anticorrosion coating on a wire used for manufacturing bolts, nuts and other forged machine parts. In this dipping method, as shown in FIG. 3, a coil 10 of a wire for processing is hung on a hacker 11 having a U-shape, and the hacker 11 is hung by a hoist (not shown),
First pickling tank 12 while moving along the overrail
a, 2nd pickling tank 12b, 3rd pickling tank 12c, 1st water washing tank 13a, 2nd water washing tank 13b, 3rd water washing tank 13c, chemical solution tank 14 for chemical conversion coating, 4th water washing tank 13d, hot water washing tank 15 and the lubricant tank 16 in that order, during which scales and the like on the surface of the wire are removed, and a chemical conversion film such as phosphate and a stearic acid-based or lime soap-based lubricant film is formed on the surface of the wire after this removal. Then, it is dried in a dryer 17 (however, if the lubricant is at a high temperature of 80 ° C. or higher, drying is omitted), the coil 10 is rewound by the uncoiler 18, and the wire rod 10a is pulled out by the first pulling roller 19a. After passing through the die of the skin pass 20 and being drawn out by the second pulling roller 19b to make the wire diameter uniform, the wire was wound around the winding core 21 and the coil 10A was formed again.
【０００３】上記のディッピング方式は、湿式処理であ
るため、多量の工業用水および排水処理を必要として公
害を発生し易く、また湯洗や化成被膜液の加熱により有
害ガスが発生して大気公害となり、また合計１０個の浸
漬槽と乾燥機のための広いスペースを必要とし、乾燥に
よる時間ロスも生じて加工時間が長くなり、また酸洗槽
や水洗槽、リン酸塩槽での濃度コントロールが難しく、
化成被膜槽の化成液を線材の種類に応じてリン酸塩溶液
その他の薬液に交換しなければならない等、作業が面倒
であった。Since the above-mentioned dipping method is a wet treatment, it requires a large amount of industrial water and wastewater treatment and is liable to cause pollution, and harmful gas is generated due to washing with hot water and heating of the chemical conversion coating solution, resulting in atmospheric pollution. In addition, a total of 10 dipping tanks and a wide space for a dryer are required, and the time loss due to drying also increases the processing time, and the concentration control in the pickling tank, water washing tank and phosphate tank is possible. Difficult,
The work was troublesome because the chemical conversion solution in the chemical conversion coating tank had to be replaced with a phosphate solution or other chemicals depending on the type of wire.
【０００４】このディッピング方式の欠点を除くため、
ストランド方式が開発された。このストランド方式で
は、図４に示すように、第１巻芯２１ａ上のコイル１０
から線材１０ａを引出し、矯正機２２で巻き癖を除去し
たのち、ショットブラスト機２３で線材１０ａにショッ
トを打ちつけて線材表面のスケール等を除去し、しかる
のち湯洗槽１５、化成被膜用薬液槽１４、湯洗ブロー１
５ａ、潤滑剤槽１６および乾燥機１７に導き、その間に
化成被膜および潤滑剤被膜を形成し、乾燥し、以後はデ
ィッピング方式と同様にスキンパスを経て巻芯に巻取っ
ていた。In order to eliminate the drawbacks of this dipping method,
The strand method was developed. In this strand system, as shown in FIG. 4, the coil 10 on the first winding core 21a is
After removing the wire rod 10a from the wire rod and removing the curl by the straightening machine 22, the shot blasting machine 23 hits the wire rod 10a with a shot to remove the scale and the like on the wire rod surface. 14, hot water blow 1
5a, led to the lubricant tank 16 and the dryer 17, formed a chemical conversion film and a lubricant film therebetween, dried, and thereafter wound around a core through a skin pass as in the dipping system.
【０００５】しかしながら、このストランド方式は、デ
ィッピング方式の酸洗工程および水洗工程をショットブ
ラスト機で置換しているので、工業用水の使用量が減少
し、省スペースが可能になるが、湿式工程を全廃するも
のではなく、化成被膜の形成を湿式で行うので、排水処
理が依然として必要であり、ディッピング方式と同様に
大気汚染の問題も残り、更に硬いショットまたはグリッ
トを使用するので、ショット傷やグリット付着が発生す
るという問題があった。なお、以上は、線材等の長尺の
金属材料についてのものであるが、ビレット、スラブ
等、任意形態の金属材料においても同様の問題があっ
た。However, in this strand method, since the pickling step and the water washing step of the dipping method are replaced by a shot blasting machine, the amount of industrial water used is reduced and space can be saved. Since it does not completely abolish, but the conversion coating is formed by a wet process, wastewater treatment is still required, and the problem of air pollution remains similar to the dipping method, and since a harder shot or grit is used, shot scratches and grit There is a problem that adhesion occurs. Although the above is for a long metal material such as a wire rod, there is a similar problem in a metal material of any form such as a billet or a slab.
【０００６】[0006]
【発明が解決しようとする課題】この発明は、上記のス
トランド方式を更に改良し、化成被膜の形成をも乾式で
行って酸洗工程、水洗工程、湯洗工程を無くし、すなわ
ち水の使用工程を皆無にして排水処理を不要にし、かつ
有害ガスの発生による大気汚染を無くし、ショット傷、
グリット付着の恐れが無く、作業が容易で、大幅な省ス
ペースを可能にするものである。DISCLOSURE OF THE INVENTION The present invention is a further improvement of the above-mentioned strand method, in which the formation of the chemical conversion coating is also carried out by a dry method so as to eliminate the pickling step, the water washing step and the hot water washing step. Eliminates the need for wastewater treatment, eliminates air pollution due to the generation of harmful gases, shot scratches,
There is no risk of grit sticking, work is easy, and significant space saving is possible.
【０００７】[0007]
【課題を解決するための手段】すなわち、この発明は、
チャンバ内で金属材料にセラミックスからなるショット
とリン酸塩等の化成被膜形成用無機塩類からなる粉末と
の混合物を加圧空気で吹付けることを特徴とする金属材
料の表面処理方法である。That is, the present invention is
A surface treatment method for a metal material, characterized in that a mixture of a shot made of ceramics and a powder made of an inorganic salt for forming a chemical conversion film such as phosphate is blown onto the metal material in a chamber with pressurized air.
【０００８】上記の金属材料は、炭素鋼、クロム鋼、ニ
ッケルクロム鋼、クロムモリブデン鋼、ステンレス鋼、
銅、アルミニウム等の金属からなる線材、帯材等の長尺
材料およびスラブ、ビレットその他任意形態の成形品あ
る。そして、金属材料の表面を均一に処理するため、金
属材料をその形態に応じて適当な手段で動かすことがで
きる。例えば、線材や帯材等の長尺の金属材料を処理す
る際は、チャンバ内に多数のガイドを配置し、このガイ
ドで長尺金属材料を案内してループ、波形、蛇行等の任
意の曲線状に走行させ、この金属材料を囲む複数個のノ
ズルから上記混合物を吹付けることにより、長尺の金属
材料が狭いチャンバ内に滞留している間に目的の表面処
理を完結させることができる。他方、スラブやビレット
等の比較的短尺の成形品にあっては、ベルトコンベヤで
搬送したり、バケットローダ等で攪拌したりして上記成
形品を動かしながら、複数方向のノズルから上記吹付け
を行うことが好ましい。The above metal materials are carbon steel, chrome steel, nickel chrome steel, chrome molybdenum steel, stainless steel,
Wires made of metals such as copper and aluminum, long materials such as strips, slabs, billets and other shaped articles of any shape are available. Then, in order to uniformly treat the surface of the metal material, the metal material can be moved by an appropriate means depending on its form. For example, when processing long metal materials such as wire rods and strips, many guides are placed in the chamber, and the guides guide the long metal materials to form arbitrary curves such as loops, corrugations, and meanders. The target surface treatment can be completed while the long metal material stays in the narrow chamber by spraying the mixture from a plurality of nozzles that surround the metal material. On the other hand, for relatively short molded products such as slabs and billets, while moving the molded products by conveying them with a belt conveyor or stirring them with a bucket loader, spraying them from nozzles in multiple directions. It is preferable to carry out.
【０００９】ショットを構成するセラミックスは、機械
材料として使用される窒化けい素セラミックス、炭化け
い素セラミックス、アルミナセラミックス、ジルコニア
セラミックス等のセラミックスであり、特にジルコニア
セラミックスは、靱性に富み、割れ難い点で好ましい。
なお、その大きさは、直径０．２〜１．０mmの球形が好
ましい。The ceramics forming the shot are ceramics such as silicon nitride ceramics, silicon carbide ceramics, alumina ceramics and zirconia ceramics used as mechanical materials. Especially, zirconia ceramics are rich in toughness and hard to crack. preferable.
The size is preferably spherical with a diameter of 0.2 to 1.0 mm.
【００１０】化成被膜形成用無機塩類は、リン酸亜鉛、
リン酸鉄、その他リン酸系または亜鉛系、アルミ系、酸
化鉄系等の無機塩類である．この発明では、化成被膜形
成の目的に応じて上記無機塩類の少なくとも１種類が選
択され、この無機塩類の粉末が上記のセラミックス製シ
ョットと混合使用される。ショットとの混合比は、ショ
ット重量の２〜５％が好ましい。なお、これらの無機塩
類は、ショットの表面に被膜の形に付着して使用するこ
とができる。The inorganic salt for forming the chemical conversion film is zinc phosphate,
Inorganic salts such as iron phosphate and other phosphoric acid-based or zinc-based, aluminum-based, iron oxide-based. In the present invention, at least one of the above-mentioned inorganic salts is selected according to the purpose of forming the chemical conversion film, and the powder of this inorganic salt is mixed with the above-mentioned ceramic shot. The mixing ratio with shots is preferably 2 to 5% of the shot weight. In addition, these inorganic salts can be used by adhering to the surface of the shot in the form of a film.
【００１１】[0011]
【作用】金属材料にセラミックスのショットを無機塩類
粉末と共に吹付けることにより、金属材料の表面の酸化
膜が除去され、同時に無機塩類の被膜が長尺金属材料の
表面に形成される。そして、長尺金属材料にループ等の
任意の曲線を描かせながら走行させた場合は、長尺金属
材料を直線状に走行させる場合に比してチャンバの長さ
を短くして省スペースを可能にすることができる。The oxide film on the surface of the metal material is removed by spraying a shot of ceramics on the metal material together with the inorganic salt powder, and at the same time, a film of the inorganic salt is formed on the surface of the long metal material. And when running while drawing an arbitrary curve such as a loop on a long metal material, the chamber length can be shortened compared to when running a long metal material in a straight line to save space. Can be
【００１２】[0012]
【実施例】図１において、チャンバ３０の片側に線材１
０ａの導入口３０ａが、また反対側に導出口３０ｂがそ
れぞれ開口している。このチャンバ３０内には、導入口
３０ａに対向して第１送りローラ３１が、また導出口３
０ｂに対向して第２送りローラ３２がそれぞれ設けら
れ、かつ導入口３０ａ、導出口３０ｂを結ぶ直線の上下
に４個のガイドローラ３３ａ、３３ｂ、３３ｃ、３３ｄ
が配置され、導入口３０ａおよび第１送りローラ３１を
経て導入された線材１０ａを第１ガイドローラ３３ａ、
第２ガイドローラ３３ｂ、第３ガイドローラ３３ｃおよ
び第４ガイドローラ３３ｄで案内して２個のループＬ
ａ、Ｌｂを描かせ、しかるのち第２送りローラ３２およ
び導出口３０ｂを経て次工程に送り出すようになってい
る。EXAMPLE In FIG. 1, a wire 1 is provided on one side of a chamber 30.
An inlet port 30a of 0a is opened, and an outlet port 30b is opened on the opposite side. In the chamber 30, there is a first feed roller 31 facing the inlet 30a, and an outlet 3
The second feed roller 32 is provided so as to face 0b, and four guide rollers 33a, 33b, 33c, 33d are provided above and below a straight line connecting the inlet 30a and the outlet 30b.
And the wire rod 10a introduced through the introduction port 30a and the first feed roller 31 into the first guide roller 33a,
The two loops L are guided by the second guide roller 33b, the third guide roller 33c and the fourth guide roller 33d.
A and Lb are drawn, and then sent out to the next process through the second feed roller 32 and the outlet 30b.
【００１３】そして、上記チャンバ３０の内側に、多数
個のショット吹付け用ノズル３４が上記２個のループＬ
ａ、Ｌｂを囲むように図示の位置および紙面手前側、紙
背側等の適当箇所に配置される。一方、チャンバ３０の
外側にショットタンク、無機塩類タンク、ショットと無
機塩類の混合タンクおよびエアコンプレッサが配置さ
れ、これらのタンクおよびエアコンプレッサが上記のノ
ズル３４にパイプ３５を介して接続され、エアコンプレ
ッサの駆動により、ショットタンクからショットが、ま
た無機塩類タンクから無機塩類の粉末がそれぞれ排出さ
れ、これらが混合タンクで混合され、パイプ３５を経て
ノズル３４に送られるようになっている。Inside the chamber 30, a large number of shot spraying nozzles 34 are provided and the two loops L are arranged.
They are arranged at appropriate positions such as the illustrated position and the front side and the back side of the paper so as to surround a and Lb. On the other hand, a shot tank, an inorganic salt tank, a shot / inorganic salt mixing tank, and an air compressor are arranged outside the chamber 30, and these tanks and air compressors are connected to the nozzle 34 through a pipe 35. The shots are discharged from the shot tank and the inorganic salt powders are discharged from the inorganic salt tank by the driving of No. 1, and these are mixed in the mixing tank and sent to the nozzle 34 through the pipe 35.
【００１４】直径４mmの低炭素鋼からなる線材１０ａに
直径約１ｍの２個のループＬａ、Ｌｂを描かせながら、
２０ｍ／分の速度で走行させ、この線材１０ａに３個の
ノズル３４からショットと無機塩類粉末の混合物を吹付
けた。ショットには、ジルコニアセラミックスからなる
直径０．６mmのジルコニアビーズを使用した。また、無
機塩類粉末には、亜鉛系無機塩類、リン酸系無機塩類、
アルミ系無機塩類、酸化鉄系無機塩類、チタン系無機塩
類、無機系特殊添加剤、食添顔料の混合粉末を使用し
た。上記のショットおよび無機塩類粉末を６００／１の
重量比で混合し、圧力５kg／cm2 の圧縮空気で上記の線
材１０ａに吹付けた。While drawing the two loops La and Lb having a diameter of about 1 m on the wire 10a made of low carbon steel having a diameter of 4 mm,
The wire rod 10a was run at a speed of 20 m / min, and a mixture of shot and inorganic salt powder was sprayed from the three nozzles 34. For the shot, zirconia beads made of zirconia ceramics having a diameter of 0.6 mm were used. Further, the inorganic salt powder includes zinc-based inorganic salts, phosphoric acid-based inorganic salts,
A mixed powder of aluminum-based inorganic salts, iron oxide-based inorganic salts, titanium-based inorganic salts, inorganic-based special additives, and food additive pigments was used. The shot and the inorganic salt powder were mixed at a weight ratio of 600/1 and sprayed on the wire 10a with compressed air having a pressure of 5 kg / cm 2 .
【００１５】図２は、図４に示した従来のストランド方
式におけるショットブラスト機２３から湯洗ブロー１５
ａまでの一連の装置を図１の装置で置換した防食処理シ
ステムを例示する。すなわち、コイル（図示されていな
い）から線材１０ａを引出し、矯正機２２で線材１０ａ
の巻き癖を除去したのち、この線材１０ａをチャンバ３
０内でループ状に走行させ、ジルコニアセラミックスか
らなるショットと無機塩類粉末の混合物をノズル３４か
ら吹付けて線材表面のスケール等を除去すると共に線材
表面に無機塩類の被膜を形成し、しかるのち潤滑剤槽１
６においてステアリン酸系潤滑剤を付着させ、乾燥機１
７で乾燥し、スキンパス２０を経て巻芯２１（図３参
照）に巻取ってコイル１０Ａを形成する。FIG. 2 shows the conventional strand type shot blasting machine 23 shown in FIG.
1 illustrates an anticorrosion treatment system in which a series of devices up to a is replaced by the device of FIG. 1. That is, the wire rod 10a is pulled out from the coil (not shown), and the wire rod 10a is moved by the straightening machine 22.
After removing the curl of the wire, remove the wire 10a from the chamber 3
Run in a loop within 0, spray a mixture of shots of zirconia ceramics and inorganic salt powder from the nozzle 34 to remove scales and the like on the surface of the wire, form a film of inorganic salt on the surface of the wire, and then lubricate. Agent tank 1
In step 6, a stearic acid-based lubricant is attached, and the dryer 1
7 and then wound on the winding core 21 (see FIG. 3) through the skin pass 20 to form the coil 10A.
【００１６】得られた処理線材は、無機塩類被膜（被膜
重量１０〜１５ｇ／ｍ2 ）の上に厚さ１〜２０μの潤滑
剤被膜を均一に有し、従来のデッピング方式で得られた
線材に比して被膜厚、加工ミス、コスト、不良品発生率
等のいずれの点でも優れていた。しかも、水を全く使用
しないため、排水処理の必要が無く、スペースがデイッ
ピング方式およびストランド方式に比してそれぞれ５０
％および８０％減少した。また、ジルコニアセラミック
スからなるショットを使用したため、従来のストランド
方式で認められたショット傷が皆無であった。The resulting treated wire rod has a lubricant coating film having a thickness of 1 to 20 μ evenly on an inorganic salt coating film (coating weight of 10 to 15 g / m 2 ), and is obtained by a conventional depping method. In comparison with the above, the film thickness, processing error, cost, defective product generation rate, etc. were all excellent. Moreover, since no water is used, there is no need for wastewater treatment, and the space is 50% compared to the dipping method and the strand method.
% And 80%. Moreover, since shots made of zirconia ceramics were used, there were no shot scratches recognized by the conventional strand method.
【００１７】なお、実験によれば、細い線材を処理する
場合は、線材が細い程ショットが当たり難くなるため、
上記ノズルの個数が一定の場合は、処理時間を長く設定
する必要がある。すなわち、線材を走行させる場合は、
線材が細い程、走行速度を遅く設定する必要がある。図
５は、線材の周囲に３個のノズルを１２０度間隔で設置
して上記の混合物を吹付けた場合における線材の周長
（mm）と該線材の処理加工に要した所要時間（分）との
関係を示すグラフであり、曲線Ａは純鉄、炭素鋼、クロ
ム鋼等の一般鋼Ａを、また曲線Ｂはステンレススチー
ル、アルミニウム、チタン、銅等の非鉄金属をそれぞれ
示す。According to experiments, when processing a thin wire, the thinner the wire, the harder it is to hit the shot.
When the number of nozzles is constant, it is necessary to set a long processing time. That is, when running a wire rod,
The thinner the wire rod, the slower the traveling speed needs to be set. FIG. 5 shows the peripheral length (mm) of the wire rod and the time (minutes) required for processing the wire rod when the above mixture is sprayed by installing three nozzles around the wire rod at 120 degree intervals. Curve A shows general steel A such as pure iron, carbon steel and chrome steel, and curve B shows non-ferrous metal such as stainless steel, aluminum, titanium and copper.
【００１８】[0018]
【発明の効果】請求項１に記載された発明は、チャンバ
内で金属材料にセラミックスからなるショットとリン酸
塩等の化成被膜形成用無機塩類からなる粉末との混合物
を加圧空気で吹付けることを特徴とする金属材料の表面
処理方法であるから、金属材料の表面の酸化膜が除去さ
れ、同時に無機塩類の被膜が金属材料の表面に形成され
る。そして、従来のように水を全く使用しないので、排
水処理および乾燥装置の必要が無く、そのため従来のデ
イッピング方式やストランド方式に比して大幅な省スペ
ースが可能になり、かつ有害ガスの発生が無く、大気を
汚染することがない。また、セラミックスからなるショ
ットを使用するため、従来のストランド方式におけるシ
ョット傷が皆無になる。更に、ショットおよび粉末の混
合物を使用するので、混合物の吹付け後にチャンバ内に
堆積した上記混合物を回収して再使用することができ
る。According to the first aspect of the present invention, a mixture of a shot made of ceramics and a powder made of an inorganic salt for forming a chemical conversion coating such as phosphate is blown on a metallic material in a chamber with pressurized air. According to the method of treating the surface of a metal material, the oxide film on the surface of the metal material is removed, and at the same time, a film of an inorganic salt is formed on the surface of the metal material. And since it does not use water at all as in the past, there is no need for wastewater treatment and a drying device, so it is possible to save a large amount of space compared to the conventional dipping method and strand method, and the generation of harmful gas No pollution of the atmosphere. Further, since shots made of ceramics are used, shot scratches in the conventional strand method are eliminated. Further, since a mixture of shot and powder is used, the mixture deposited in the chamber after spraying the mixture can be collected and reused.
【００１９】請求項２に記載された発明は、上記の請求
項１に記載された発明において、長尺の金属材料をガイ
ドで案内して曲線状に走行させながら、上記の吹付けを
行う方法であるから、線材等の長尺の金属材料を処理す
る際にチャンバの長さを短くして一層の省スペースを可
能にする。According to a second aspect of the present invention, in the above-mentioned first aspect of the present invention, the above-mentioned spraying is performed while a long metal material is guided by a guide to run in a curved shape. Therefore, when processing a long metal material such as a wire rod, the length of the chamber is shortened to enable further space saving.
【図面の簡単な説明】[Brief description of drawings]
【図１】この発明の実施態様を例示する処理装置の縦断
面図である。FIG. 1 is a vertical cross-sectional view of a processing apparatus illustrating an embodiment of the present invention.
【図２】図１の装置を利用して線材の表面処理を行う工
程説明図である。FIG. 2 is a process explanatory diagram of performing surface treatment of a wire rod by using the apparatus of FIG.
【図３】従来のデイッピング方式の工程説明図である。FIG. 3 is a process explanatory diagram of a conventional dipping method.
【図４】従来のストランド方式の工程説明図である。FIG. 4 is a process explanatory diagram of a conventional strand system.
【図５】線材処理の際の線材の周長と所要時間との関係
を示すグラフである。FIG. 5 is a graph showing a relationship between a peripheral length of a wire rod and a required time when the wire rod is processed.
１０：１０Ａ：コイル、１０ａ：線材、１１：ハッカ
ー、１２ａ、１２ｂ、１２ｃ：酸洗槽、１３ａ、１３
ｂ、１３ｃ：１３ｄ：水洗槽、１４：化成被膜用薬液
槽、１５：湯洗槽、１５ａ：湯洗ブロー、１６：潤滑剤
槽、１７：乾燥機、１８：アンコイラー、１９ａ、１９
ｂ：引張りローラ、２０：スキンパス、２１、２１ａ：
巻芯、２２：矯正機、２３：ショットブラスト機、３
０：チャンバ、３０ａ：導入口、３０ｂ：導出口、３
１、３２：送りローラ、３３ａ、３３ｂ、３３ｃ、３３
ｄ：ガイドローラ、Ｌａ、Ｌｂ：線材のループ、３４：
ショット吹付け用ノズル、３５：パイプ。10: 10A: coil, 10a: wire rod, 11: hacker, 12a, 12b, 12c: pickling tank, 13a, 13
b, 13c: 13d: water washing tank, 14: chemical bath for chemical conversion coating, 15: hot water washing tank, 15a: hot water washing blow, 16: lubricant tank, 17: dryer, 18: uncoiler, 19a, 19
b: pulling roller, 20: skin pass, 21, 21a:
Winding core, 22: straightening machine, 23: shot blasting machine, 3
0: chamber, 30a: inlet, 30b: outlet, 3
1, 32: feed rollers, 33a, 33b, 33c, 33
d: guide roller, La, Lb: loop of wire rod, 34:
Shot spray nozzle, 35: pipe.
───────────────────────────────────────────────────── フロントページの続き (72)発明者 関 憲生 愛知県名古屋市中村区高道町１丁目７番地 ６号 (72)発明者 伊藤 進 愛知県名古屋市中川区宗円町１丁目41番地 ─────────────────────────────────────────────────── ─── Continuation of the front page (72) Inventor Kensei Seki, 1-7 Takamichi-cho, Nakamura-ku, Nagoya, Aichi Prefecture No. 6 (72) Inventor Susumu Ito 1-41, Soenmachi, Nakagawa-ku, Nagoya City, Aichi Prefecture
Claims (2)
らなるショットとリン酸塩等の化成被膜形成用無機塩類
からなる粉末との混合物を加圧空気で吹付けることを特
徴とする金属材料の表面処理方法。1. A surface treatment of a metallic material, characterized in that a mixture of a shot made of ceramics and a powder made of an inorganic salt for forming a chemical conversion coating such as phosphate is blown with pressurized air in the chamber. Method.
あり、この長尺の金属材料をガイドで案内して曲線状に
走行させながら吹付けを行う請求項１に記載された金属
材料の表面処理方法。2. The method according to claim 1, wherein the metal material is a long material such as a wire material or a band material, and the long metal material is guided by a guide and sprayed while traveling in a curved shape. Surface treatment method for metallic materials.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP5352598A JPH07195273A (en) | 1993-12-29 | 1993-12-29 | Surface treatment method of metallic material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP5352598A JPH07195273A (en) | 1993-12-29 | 1993-12-29 | Surface treatment method of metallic material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH07195273A true JPH07195273A (en) | 1995-08-01 |
Family
ID=18425144
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP5352598A Pending JPH07195273A (en) | 1993-12-29 | 1993-12-29 | Surface treatment method of metallic material |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH07195273A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2010502468A (en) * | 2006-09-11 | 2010-01-28 | エンバイオ リミテッド | Surface doping method |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5721268A (en) * | 1980-07-11 | 1982-02-03 | Nitto Electric Ind Co Ltd | Resin particles for use in sand blasting process |
-
1993
- 1993-12-29 JP JP5352598A patent/JPH07195273A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5721268A (en) * | 1980-07-11 | 1982-02-03 | Nitto Electric Ind Co Ltd | Resin particles for use in sand blasting process |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2010502468A (en) * | 2006-09-11 | 2010-01-28 | エンバイオ リミテッド | Surface doping method |
| JP2013136148A (en) * | 2006-09-11 | 2013-07-11 | Enbio Ltd | Method of doping surface |
| US8889212B2 (en) | 2006-09-11 | 2014-11-18 | Enbio Limited | Method of doping surfaces |
| US9034422B2 (en) | 2006-09-11 | 2015-05-19 | Enbio Limited | Method of doping surfaces |
| US20150190841A1 (en) * | 2006-09-11 | 2015-07-09 | Enbio Ltd. | Method of doping surfaces |
| JP2015171757A (en) * | 2006-09-11 | 2015-10-01 | エンバイオ リミテッドＥｎｂｉｏ Ｌｉｍｉｔｅｄ | Method of doping surface |
| US9242268B2 (en) | 2006-09-11 | 2016-01-26 | Enbio Limited | Method of doping surfaces |
| USRE45877E1 (en) | 2006-09-11 | 2016-02-02 | Enbio Limited | Method of doping surfaces |
| US9695505B2 (en) | 2006-09-11 | 2017-07-04 | Enbio Limited | Method of treating surfaces |
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