JPH07174704A - Humidity indicator - Google Patents
Humidity indicatorInfo
- Publication number
- JPH07174704A JPH07174704A JP32274893A JP32274893A JPH07174704A JP H07174704 A JPH07174704 A JP H07174704A JP 32274893 A JP32274893 A JP 32274893A JP 32274893 A JP32274893 A JP 32274893A JP H07174704 A JPH07174704 A JP H07174704A
- Authority
- JP
- Japan
- Prior art keywords
- deliquescent
- developer
- indicator
- humidity
- color
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Investigating Or Analyzing Non-Biological Materials By The Use Of Chemical Means (AREA)
- Investigating Or Analysing Materials By The Use Of Chemical Reactions (AREA)
Abstract
Description
【０００１】[0001]
【産業上の利用分野】本発明は、新規な湿度インジケー
タに関する。詳しくは、湿度の上昇を変色によって指示
し、且つ該指示にメモリー性をがあり、しかも、いずれ
の方向からでも変色による指示を確認することが可能な
湿度インジケーターである。FIELD OF THE INVENTION The present invention relates to a novel humidity indicator. Specifically, it is a humidity indicator that indicates an increase in humidity by discoloration, has a memory property for the instruction, and can confirm the discoloration instruction from any direction.
【０００２】尚、本発明において、変色とは無色から発
色する現象をも含むものである。In the present invention, the term "discoloration" also includes the phenomenon of developing color from colorless.
【０００３】[0003]
【従来の技術】吸湿能力の高い塩化カルシウム等の潮解
性物質を使用した除湿剤は、タンス、下駄箱、押入等の
家庭用除湿剤として種々のタイプのものが提案されてい
る。2. Description of the Related Art Various types of dehumidifying agents using a deliquescent substance such as calcium chloride having a high hygroscopic ability have been proposed as household dehumidifying agents such as chests of drawers, shoe racks and push-fits.
【０００４】例えば、透湿性且つ非透水性のシートより
なる蓋を有する容器中に、潮解性物質の粒状体を単に詰
めた形態のもの、一部が透湿性のシートよりなる袋体中
に、パーライト等の吸液性粉粒体に潮解性物質を含浸、
乾燥させた粉粒体を充填した形態のもの等が挙げられ
る。For example, in a container having a lid made of a moisture-permeable and water-impermeable sheet, in which granules of the deliquescent substance are simply packed, and in a bag partly made of a moisture-permeable sheet, Impregnating liquid-absorbing powder such as perlite with deliquescent substance,
Examples thereof include a form filled with dried powder and granules.
【０００５】そのうち、潮解性物質の粒状体を容器に単
に詰めた形態の除湿剤にあっては、潮解性物質の吸湿状
態を液状化の度合によって吸湿限界を検知することが可
能である。Among the dehumidifying agents in which the deliquescent substance particles are simply packed in a container, the moisture absorption limit of the deliquescent substance can be detected by the degree of liquefaction.
【０００６】しかしながら、潮解性物質を吸液性粉粒体
に含浸、乾燥して製造されたタイプの除湿剤において
は、目視によりその吸湿限界を検知することは困難であ
る。However, it is difficult to visually detect the moisture absorption limit in a dehumidifying agent of the type manufactured by impregnating a deliquescent substance into a liquid absorbing powder and drying it.
【０００７】そのため、上記タイプの除湿剤において
は、その吸湿限界を検知するためのインジケーターが必
要となる。Therefore, the above-mentioned type of dehumidifying agent requires an indicator for detecting its moisture absorption limit.
【０００８】従来、かかるインジケーターとして、
（ａ）シリカゲルに塩化コバルトを含浸して乾燥させた
もの（ｂ）潮解性物質を含浸、乾燥して担持した吸湿性
シートと色素を担持したシート或いはｐＨ指示薬を担持
したシートとを積層したもの（ｃ）（ｂ）の色素を担持
したシート上に更に吸液性の不透明シートを積層したも
の等が提案されている。Conventionally, as such an indicator,
(A) Silica gel impregnated with cobalt chloride and dried (b) Laminated hygroscopic sheet impregnated with a deliquescent substance and dried, and a sheet carrying a dye or a sheet carrying a pH indicator It is proposed that a liquid-absorbent opaque sheet is further laminated on the dye-carrying sheet of (c) and (b).
【０００９】しかしながら、（ａ）の湿度インジケータ
ーを前記した潮解性物質を吸液性粉粒体に含浸、乾燥し
て製造されたタイプの除湿剤中に混在させた場合、潮解
性物質の吸湿限界に近づいた時点で一時的に顕色性を示
すが、該潮解性物質の潮解液に残存する吸湿性により、
シリカゲルが脱水されて再び元の色に戻ってしまうとい
う現象が生ずる。However, when the moisture indicator (a) is mixed in a dehumidifying agent of the type produced by impregnating the deliquescent substance in the liquid absorbing powder and drying it, the moisture absorption limit of the deliquescent substance is limited. Shows a color developing property temporarily when approaching, but due to the hygroscopicity of the deliquescent substance remaining in the deliquescent liquid,
A phenomenon occurs in which the silica gel is dehydrated and returns to the original color again.
【００１０】そのため、潮解性物質による吸湿能力は既
に低下しているにもかかわらず、湿度インジケーターの
表示が出ないという問題点を有する。Therefore, there is a problem that the humidity indicator does not appear even though the hygroscopic ability of the deliquescent substance has already decreased.
【００１１】また、（ｂ）及び（ｃ）の湿度インジケー
ターは、湿度の上昇により、潮解性物質が吸湿した結果
生成する潮解液による色素の溶出或いはｐＨ指示薬の変
色を起こすものである。上記湿度インジケーターは、一
担変色した色は変化せず、表示のメモリー性を有する
が、シート状である上、表示に方向性があるという問題
点を有する。Further, the humidity indicators (b) and (c) cause the elution of the dye or the discoloration of the pH indicator by the deliquescent liquid produced as a result of the deliquescent substance absorbing moisture due to the increase in humidity. The above-mentioned humidity indicator does not change the color that has been changed for a while and has a display memory property, but it has a problem that it is in the form of a sheet and the display has directionality.
【００１２】即ち、かかる表示は積層されたシートの色
素或いはｐＨ指示薬が担持された一方の面側からしか確
認することができない。そのため、かかる湿度インジケ
ーターにあっては、容器の内壁に貼付して使用せざるを
得ず、そのセッティングに製造上の労力を有する。That is, such an indication can be confirmed only from one surface side of the laminated sheets on which the dye or the pH indicator is carried. Therefore, such a humidity indicator has to be attached to the inner wall of the container for use, and the setting has a labor in manufacturing.
【００１３】[0013]
【発明が解決しようとする課題】従って、本発明の目的
は、湿度検知による表示にメモリー性を有すると共に、
表示に方向性がなく、いずれの方向からでも表示を確認
することが可能な湿度インジケーターを提供することに
ある。SUMMARY OF THE INVENTION Therefore, an object of the present invention is to have a memory function for display by humidity detection, and
It is to provide a humidity indicator which has no directionality and which can be confirmed from any direction.
【００１４】また、本発明の他の目的は、粒状、板状、
棒状等の任意な形状に成形することができ、前記した潮
解性物質を吸液性粉粒体に含浸、乾燥して製造されたタ
イプの除湿剤中に単に分散させるだけで、該除湿剤の除
湿状態を示すインジケーターとして使用することがで
き、セッティングが容易な湿度インジケーターを提供す
ることにある。Another object of the present invention is to provide a granular, plate-shaped,
It can be molded into any shape such as a rod shape, and the deliquescent substance is simply dispersed in a dehumidifying agent of the type produced by impregnating the liquid-absorbent powder and drying it. The purpose of the present invention is to provide a humidity indicator that can be used as an indicator of the dehumidification state and is easy to set.
【００１５】[0015]
【課題を解決するための手段】本発明者らは、上記目的
に対し、潮解性物質と該潮解性物質の潮解液の接触によ
り顕色性を示す顕色剤とを乾燥した粉体の状態で混合し
て乾式成形することにより、顕色剤が顕色化する前の状
態で、該顕色剤と潮解性物質とをほぼ均一に分散した、
任意の形状の成形体を得ることができること、そして、
これにより、得られる成形体の全ての表面で湿度インジ
ケーターの表示を確認することができる（方向性がな
い）ため、前記除湿剤中に散在させて全体の吸湿状態を
検知することも可能となること、更に、応答性及び表示
のメモリー性も極めて良好であることを見い出し、本発
明を完成するに至った。For the above-mentioned purpose, the present inventors have developed a powdery state in which a deliquescent substance and a developer exhibiting a color developability by contact of the deliquescent liquid of the deliquescent substance are dried. In the state before the color developer is developed, the color developer and the deliquescent substance are almost uniformly dispersed by mixing and dry molding.
Being able to obtain a molded body of any shape, and
As a result, the display of the humidity indicator can be confirmed on all surfaces of the obtained molded body (there is no directionality), and it is possible to detect the entire moisture absorption state by being scattered in the dehumidifying agent. Furthermore, they have found that the responsiveness and the display memory property are also very good, and have completed the present invention.
【００１６】即ち、本発明は、粉状潮解性物質と該潮解
性物質の潮解液と接触することにより顕色化する粉状顕
色剤との乾式成形体よりなる湿度インジケーターであ
る。That is, the present invention is a humidity indicator comprising a dry molded product of a powdery deliquescent substance and a powdery color developer which develops color upon contact with the deliquescent liquid of the deliquescent substance.
【００１７】本発明において、潮解性物質は、潮解性を
示す公知の塩類が特に制限なく使用される。例えば、塩
化カルシウム、塩化マグネシウム、塩化リチウム等の塩
類が一般に挙げられる。In the present invention, as the deliquescent substance, known salts exhibiting deliquescent properties are used without particular limitation. For example, salts such as calcium chloride, magnesium chloride and lithium chloride are generally mentioned.
【００１８】上記潮解性物質は、顕色剤と乾式状態で混
合し、成形するため、粉体の形態で使用される。例え
ば、該潮解性物質自身を粉体の形態で使用しても良い
し、吸水性を有する粉体に予め含浸させて乾燥した粉体
の形態で使用しても良い。上記態様の内、特に、潮解性
物質自身を粉体の形態で使用する態様が、応答性の良い
湿度インジケーターを得ることができ好ましい。The deliquescent substance is used in the form of powder because it is mixed with the developer in a dry state and molded. For example, the deliquescent substance itself may be used in the form of powder, or may be used in the form of powder obtained by previously impregnating water-absorbing powder with water and drying. Among the above-mentioned modes, particularly the mode in which the deliquescent substance itself is used in the form of powder is preferable because a humidity indicator having good responsiveness can be obtained.
【００１９】また、粉状潮解性物質の粒子径は、一般に
５〜１０００μｍ程度、好ましくは１０〜１５０μｍの
大きさとすることが粉状顕色剤との良好な混合を行うこ
とができると共に、表示も鮮やかであるため好ましい。The particle size of the powder deliquescent substance is generally in the range of about 5 to 1000 μm, preferably 10 to 150 μm, so that good mixing with the powder developer can be carried out and display Is also preferable because it is vivid.
【００２０】また、本発明の他の成分である顕色剤は、
潮解性物質の潮解液との接触により顕色化するものが特
に制限なく使用される。具体的な顕色剤を例示すれば、
トリフェニルメタン系、ピラゾロン系、アゾ系、キサン
テン系等の水溶性の色素が挙げられる。そのうち、特に
溶解性が高い食用青色１号、食用黄色４号、食用赤色１
０２号等が好適に使用される。また、他の顕色剤とし
て、前記潮解性物質より生成する潮解液により変色する
フェノールレッド、ニュートラルレッド、クレゾールレ
ッド等のｐＨ指示薬、等が挙げられる。The developer which is another component of the present invention is
Any material that develops color when contacted with a deliquescent liquid of a deliquescent substance is used without particular limitation. As an example of a specific developer,
Examples thereof include water-soluble dyes such as triphenylmethane type, pyrazolone type, azo type and xanthene type. Among them, food blue 1, food yellow 4, food red 1 with high solubility
No. 02 and the like are preferably used. Examples of other developers include pH indicators such as phenol red, neutral red, and cresol red that change color by the deliquescent liquid generated from the deliquescent substance.
【００２１】これらの顕色剤は、上記潮解性物質と同様
に、粉状となるように配合される。These color-developing agents are blended in the form of powder, like the deliquescent material.
【００２２】代表的な形態を例示すれば、水溶性の色素
が固体の場合、それ自身を粉状で使用する態様、一担水
に溶解したものを粉状の担体に含浸し、乾燥させること
により担持させた形態で使用する態様等が挙げられる。As a representative example, when the water-soluble dye is a solid, it is used in a powder form, and one dissolved in water is impregnated into a powder carrier and dried. And the like, which is used in the form of being supported by.
【００２３】そのうち、色素自身を粉状で使用する態様
が、応答性、表示の顕色性の面で好適である。また、水
溶性の色素が液体の状態である場合は、粉状の担体に担
持させ、必要に応じて乾燥させた形態が一般に採用され
る。Among them, the mode in which the dye itself is used in powder form is preferable in terms of responsiveness and display color development. When the water-soluble dye is in a liquid state, a form in which it is supported on a powdery carrier and dried if necessary is generally adopted.
【００２４】上記粉粒状の担体は、公知の担体が特に制
限なく使用される。例えば、ホワイトカーボン、ケイ酸
カルシウム、パーライト等が挙げられる。これらの担体
は、場合によっては、後述する成形助剤を兼ねることが
できる。As the powdery or granular carrier, a known carrier is used without particular limitation. Examples thereof include white carbon, calcium silicate, perlite and the like. In some cases, these carriers can also serve as a molding aid described later.
【００２５】また、ｐＨ指示薬を使用する場合は、上記
水溶性の色素と同様に、固体の場合にはそれ自身を粉粒
体の形態で使用する態様、水、アルコール等に一担溶解
したものを前記粉粒状の担体に含浸し、乾燥させること
により担持させた形態で使用する態様等が挙げられる。When a pH indicator is used, as in the case of the water-soluble dye, when it is a solid, it is used in the form of powder or granules, and is dissolved in water, alcohol, etc. And the like, which is used by being impregnated into the powdery or granular carrier and dried to be carried.
【００２６】尚、ｐＨ指示薬の場合、高分散するほど均
一な変色が得られるため、前記担体に担持させた形態で
使用する態様が、応答性、表示の顕色性の面で好適であ
る。また、ｐＨ指示薬が液体の場合には、担体に担持さ
せて成形体中に分散させる形態が一般に採用される。In the case of a pH indicator, the more highly dispersed it is, the more uniform discoloration is obtained. Therefore, the mode of using it in the form of being supported on the carrier is preferable in terms of responsiveness and display color development. Further, when the pH indicator is a liquid, a form in which it is supported on a carrier and dispersed in a molded body is generally adopted.
【００２７】本発明において、粉状潮解性物質と粉状顕
色剤との使用割合は、粉状潮解性物質からの潮解液との
接触の前後で、顕色剤による成形体の顕色性を発揮する
範囲で適宜設定すればよい。In the present invention, the use ratio of the powder deliquescent substance and the powder color developer is such that the color developing property of the molded article by the color developer is before and after contact with the deliquescent liquid from the powder deliquescent substance. It may be set as appropriate within the range that exerts.
【００２８】また、顕色剤は、かかる範囲で且つ、成形
体の全重量に対して、０．０１〜１重量％となるように
設定することが好ましい。Further, the color developer is preferably set in such a range so as to be 0.01 to 1% by weight based on the total weight of the molded product.
【００２９】本発明において、粉状潮解性物質と粉状顕
色剤との混合物の乾式成形は、公知の手段が特に制限な
く採用される。例えば、成形助剤と共に乾式で混合を行
い、加圧成形する方法、その際加熱を併用する方法等が
一般的である。また、上記成形時の雰囲気は、相対湿度
６０％以下に設定することが、製造時の変色を効果的に
防止できるため好ましい。In the present invention, known methods can be used without particular limitation for dry molding of the mixture of the powder deliquescent substance and the powder color developer. For example, a method of performing dry mixing with a molding aid and performing pressure molding, and a method of using heating at the same time are generally used. The atmosphere during molding is preferably set to a relative humidity of 60% or less because discoloration during manufacturing can be effectively prevented.
【００３０】上記成形助剤としては、珪酸カルシウム等
の無機粉体、結晶性セルロース、ポリピービニルアルコ
ール、ビニロン、ナイロン等の繊維等の公知の成形助剤
が特に制限なく使用される。As the above-mentioned molding aid, known molding aids such as inorganic powder such as calcium silicate, crystalline cellulose, fibers such as poly (vinyl alcohol), vinylon and nylon are used without particular limitation.
【００３１】上記成形助剤は、使用環境下での粒子の衝
突等によって崩壊しない程度の圧縮強度を与える量で使
用すれば良い。かかる使用量としては、成形体を構成す
る各成分の比重によって多少異なるが、成形体の全重量
の５〜２５重量％の割合で使用することが望ましい。The above-mentioned molding aid may be used in such an amount as to give a compressive strength that does not cause collapse due to collision of particles in a use environment. The amount to be used is somewhat different depending on the specific gravity of each component constituting the molded product, but it is preferably used in a proportion of 5 to 25% by weight of the total weight of the molded product.
【００３２】本発明において、湿度インジケーターが吸
湿した結果、これを構成する成形体の強度の低下を防止
する目的で、成形体中に水硬性物質、高吸水性樹脂等の
添加剤の少なくとも一種を併用することは好ましい態様
である。即ち、水硬性物質は、潮解液の作用により成形
体中で硬化し、圧壊強度を高める如く作用し、高吸水性
樹脂は、過剰に生成する潮解液を吸収し、成形体の吸湿
後の強度低下を防止する如く作用する。In the present invention, at least one additive such as a hydraulic substance or a super absorbent resin is contained in the molded body for the purpose of preventing the strength of the molded body constituting the humidity indicator from being lowered as a result of moisture absorption. The combined use is a preferred embodiment. That is, the hydraulic substance is hardened in the molded body by the action of the deliquescent liquid and acts to increase the crushing strength, and the superabsorbent resin absorbs the excessively generated deliquescent liquid and the strength of the molded body after absorbing moisture. It acts to prevent a drop.
【００３３】かかる効果は、特に本発明の湿度インジケ
ーターを前記吸湿剤中に分散させて使用する場合、該吸
湿在中で湿度インジケーターが崩壊するのを防止する場
合に顕著である。Such an effect is particularly remarkable when the humidity indicator of the present invention is used by being dispersed in the hygroscopic agent, and when the humidity indicator is prevented from collapsing in the presence of moisture.
【００３４】上記水硬性物質としては、ポルトランドセ
メント、石膏、アルミナセメント、天然セメント、水硬
性石灰、ケイ酸カルシウム、アルミン酸カルシウム等の
公知のものが特に制限なく使用される。As the hydraulic substance, known substances such as Portland cement, gypsum, alumina cement, natural cement, hydraulic lime, calcium silicate and calcium aluminate can be used without particular limitation.
【００３５】また、高吸水性樹脂としては、ヒドロキシ
エチルセルロース、でんぷん系高分子吸水剤等の公知の
ものが特に制限なく使用される。As the highly water-absorbent resin, known ones such as hydroxyethyl cellulose and starch-based polymer water-absorbing agent can be used without particular limitation.
【００３６】これらの添加剤の使用量は、得られる乾式
成形体の強度を著しく低下せず、且つ顕色剤の機能を阻
害しない範囲で使用することができる。一般には、潮解
性物質１００重量部に対して０〜１０００重量部が好適
である。The amount of these additives used can be used within a range that does not significantly reduce the strength of the resulting dry molded product and does not hinder the function of the color developer. Generally, 0 to 1000 parts by weight is suitable for 100 parts by weight of the deliquescent material.
【００３７】本発明の湿度インジケーターは、粒状、棒
状、板状、フレーク等の種々の形状に成形して使用する
ことが可能である。The humidity indicator of the present invention can be molded into various shapes such as granular, rod-like, plate-like, and flakes for use.
【００３８】[0038]
【作用】本発明にかかる湿度インジケーターの内、顕色
剤として水溶性の色素を使用した場合、湿度インジケー
ターの接触する雰囲気の湿度が上昇すると、潮解性物質
の吸湿が始まり、これにより生じる潮解液が粉状で分散
する水溶性色素を溶解してその周辺に浸出するため、イ
ンジケーター全体が変色し、湿度の上昇を知ることがで
きる。In the humidity indicator according to the present invention, when a water-soluble dye is used as a color developer, when the humidity of the atmosphere in contact with the humidity indicator rises, the deliquescent substance starts to absorb moisture, resulting in deliquescent liquid. Dissolves the water-soluble dye dispersed in powder form and leaches out into the surrounding area, so that the entire indicator is discolored and the increase in humidity can be known.
【００３９】また、顕色剤としてｐＨ指示薬を使用した
場合、上記のように生じた潮解液がｐＨ指示薬を変色せ
しめ、かかる変色によって湿度の上昇を知ることができ
る。When a pH indicator is used as a color developer, the deliquescent liquid generated as described above causes the pH indicator to change color, and the increase in humidity can be known by the color change.
【００４０】[0040]
【効果】以上の説明より理解されるように、潮解性物質
と顕色剤とを粉状で混合して乾式成形することにより、
顕色剤が顕色化する前の状態で、該顕色剤と潮解性物質
とをほぼ均一に分散した、任意の形状の成形体を得るこ
とができる。[Effect] As can be understood from the above explanation, by mixing the deliquescent substance and the color developer in powder form and performing dry molding,
It is possible to obtain a molded product having an arbitrary shape in which the developer and the deliquescent substance are almost uniformly dispersed in a state before the developer is developed.
【００４１】これにより、本発明の湿度インジケーター
は、全ての表面で、方向性なく表示を確認することがで
きる。As a result, the humidity indicator of the present invention can confirm the display on all surfaces without directivity.
【００４２】従って、潮解性物質を吸液性粉粒体に含
浸、乾燥して製造されたタイプの前記除湿剤中に散在さ
せて全体の吸湿状態を検知することも可能である。Therefore, it is also possible to detect the entire moisture absorption state by dispersing the deliquescent substance in the liquid absorbent granular material and dispersing it in the dehumidifying agent of the type produced by drying.
【００４３】また、応答性も良好であると共に、一度変
色した後は、元に戻らず、表示のメモリー性も極めて良
好であるという特徴をも併せ有する。Further, it has a characteristic that the responsiveness is good and that once the color is changed, it does not return to the original state and the display has a very good memory property.
【００４４】[0044]
【実施例】以下、実施例により本発明を詳細に説明する
が本発明はこれらの実施例に限定されるものではない。The present invention will be described in detail below with reference to examples, but the present invention is not limited to these examples.
【００４５】尚、成形体の成形は、湿度５０％ＲＨに保
たれた室内において行った。The molding of the molded body was carried out in a room kept at a humidity of 50% RH.
【００４６】実施例１ 粉状無水塩化カルシウム１０重量部に対し、成形助剤と
してケイ酸カルシウム４重量部を混合した粉に、更に、
表１に示す種類の水溶性色素を表１に示す割合で乾式混
合したもの乾式プレス成形し、直径５ｍｍの錠剤型成形
品を得た。Example 1 10 parts by weight of powdery anhydrous calcium chloride was mixed with 4 parts by weight of calcium silicate as a molding aid, and further,
Water-soluble dyes of the types shown in Table 1 were dry-mixed in the proportions shown in Table 1 and subjected to dry press molding to obtain a tablet-shaped molded product having a diameter of 5 mm.
【００４７】これらの成形品を２５℃、８０％ＲＨ雰囲
気中に２日間放置して湿度インジケーターの変色状態を
観察した結果を表１に併せて示す。Table 1 also shows the results of observing the discolored state of the humidity indicator by allowing these molded products to stand in an atmosphere of 25 ° C. and 80% RH for 2 days.
【００４８】[0048]
【表１】 [Table 1]
【００４９】実施例２ 表２に示す本発明の湿度インジケーターの組成に、更に
表２に示す配合で各水硬性セメントを乾式混合し、これ
を乾式プレス成形して、直径５ｍｍの錠剤型成形品を得
た。Example 2 The composition of the humidity indicator of the present invention shown in Table 2 was further dry mixed with each hydraulic cement in the composition shown in Table 2, and this was dry press-molded to give a tablet-shaped molded product having a diameter of 5 mm. Got
【００５０】[0050]
【表２】 [Table 2]
【００５１】これらの成形品を、充分水に濡らした紙上
に静置した場合の色調の変化を観察した結果を表３に示
す。Table 3 shows the results of observing the change in color tone when these molded products were allowed to stand on paper which had been sufficiently wetted with water.
【００５２】[0052]
【表３】 [Table 3]
【００５３】水硬性物質とケイ酸カルシウムを並用する
ことにより、崩壊及び割れを改善できる。Disintegration and cracking can be improved by using a hydraulic substance and calcium silicate together.
【００５４】また、上記湿度インジケーターのメモリー
性をチェックするため、無水塩化カルシウム１重量部に
対し、ケイ酸カルシウム２重量部を混合し、湿式転動造
粒後乾燥して得られた吸湿剤（以下吸湿剤とする）２０
ｇ中に、青シリカゲル２ｇと共に該湿度インジケーター
を１粒混合し、これを片側が不透湿性の透明シートと片
側が透湿度４７００ｇ／ｍ2・２４ｈｒ以上の不透明シ
ートとよりなる包材に密閉し、２５℃、８０％ＲＨ雰囲
気中に５日間放置後、湿度１７〜２２℃、湿度３２〜４
２％ＲＨの室内に放置して湿度インジケーターの吸湿量
と変色の様子を観察した。結果を表４に示す。In order to check the memory property of the above humidity indicator, a hygroscopic agent obtained by mixing 2 parts by weight of calcium silicate with 1 part by weight of anhydrous calcium chloride, wet rolling granulation and drying ( Hereinafter referred to as a hygroscopic agent) 20
1 g of this humidity indicator was mixed with 2 g of blue silica gel in g, and this was sealed in a packaging material consisting of a moisture-impermeable transparent sheet on one side and an opaque sheet having a moisture permeability of 4700 g / m 2 · 24 hr or more on one side. After being left in an atmosphere of 25 ° C and 80% RH for 5 days, the humidity is 17 to 22 ° C and the humidity is 32 to 4
The humidity indicator of the humidity indicator and the state of discoloration were observed by leaving it in a room of 2% RH. The results are shown in Table 4.
【００５５】尚、表４には、参考のためシリカゲルの結
果も併せて示す。Table 4 also shows the results of silica gel for reference.
【００５６】[0056]
【表４】 [Table 4]
【００５７】実施例３ 吸湿後のヒビ、割れ防止を目的とし、高吸水性樹脂とし
てポリビニルアルコールを用い、表５に示す配合で各種
粉状体を乾式混合し、乾式プレス成形して、直径４ｍｍ
の錠剤型成形品を得た。Example 3 For the purpose of preventing cracks and cracks after moisture absorption, polyvinyl alcohol was used as a highly water-absorbent resin, and various powders were dry-mixed in the composition shown in Table 5 and dry-press molded to have a diameter of 4 mm.
A tablet-shaped molded product of
【００５８】[0058]
【表５】 [Table 5]
【００５９】これらの成形品を前記吸湿剤２０ｇに２０
粒の割合で混合し、これを片側が不透湿透明シート、片
側が透湿度４７００ｇ／ｍ2・２４ｈｒ以上の不透明シ
ートよりなる包材に充填した。20 g of these molded products were added to 20 g of the moisture absorbent.
The mixture was mixed in the proportion of particles, and this was filled into a packaging material composed of an impermeable transparent sheet on one side and an opaque sheet having a moisture permeability of 4700 g / m 2 · 24 hr or more on one side.
【００６０】これを室内に放置した場合、と２０ｇの水
でぬらした靴の中に入れて３回吸湿した場合における色
調、状態の変化を観察した。結果を表６（室内放置）及
び表７（靴中）にそれぞれ示す。Changes in color tone and state were observed when this was left indoors and when it was put into a shoe wet with 20 g of water and absorbed three times. The results are shown in Table 6 (leaved indoors) and Table 7 (in shoes), respectively.
【００６１】ポリビニルアルコールを加えることによ
り、吸湿後のヒビ、割れはなくなり、崩壊性も向上する
が、実施例３の配合では、成形時に離型性が低下する傾
向がみられた。By adding polyvinyl alcohol, cracks and cracks after absorption of moisture are eliminated and disintegration is improved, but with the formulation of Example 3, there was a tendency that the releasability was lowered during molding.
【００６２】また、得られた湿度インジケーターは、表
示のメモリー性が極めて良好であった。Further, the obtained humidity indicator had a very good display memory property.
【００６３】[0063]
【表６】 [Table 6]
【００６４】[0064]
【表７】 [Table 7]
【００６５】実施例４ 表８に示す配合で各種粉状体を乾式混合し、乾式プレス
成形して、直径４．５ｍｍの錠剤型成形品を得た。Example 4 Various powders having the composition shown in Table 8 were dry-mixed and dry-press molded to obtain a tablet-shaped molded product having a diameter of 4.5 mm.
【００６６】[0066]
【表８】 [Table 8]
【００６７】得られた錠剤型成形品２０粒を吸湿剤２０
ｇに混合し、片側が不透湿透明シート、片側が透湿度４
７００ｇ／ｍ2・２４ｈｒ以上の不透明シートよりなる
包材に充填し、これを室内放置した際の色調及び崩壊性
を観察した。20 tablets of the obtained tablet-shaped molded product were mixed with a moisture absorbent 20
Mixed with g, one side is a moisture-impermeable transparent sheet, one side is a moisture-permeable 4
The packaging material made of an opaque sheet of 700 g / m 2 · 24 hr or more was filled, and the color tone and the disintegration property were observed when the packaging material was left indoors.
【００６８】結果を表９に示す。The results are shown in Table 9.
【００６９】また、比較例として、青シリカゲル２ｇを
吸湿剤２０ｇに混合したサンプルの色調も表９に併せて
示す。As a comparative example, Table 9 also shows the color tone of a sample obtained by mixing 2 g of blue silica gel with 20 g of a moisture absorbent.
【００７０】水硬性物質及び高吸水性樹脂の両方を配合
することにより、吸湿後の崩壊、ヒビ、割れがなく、変
色のメモリー性が良好で、かつ成形の作業性も良好な湿
度インジケーターが得られた。By blending both a hydraulic substance and a super absorbent polymer, a humidity indicator free from disintegration, cracks and cracks after absorption of moisture, having good discoloration memory property and good molding workability can be obtained. Was given.
【００７１】[0071]
【表９】 [Table 9]
Claims (1)
接触することにより顕色化する粉状顕色剤との混合物の
乾式成形体よりなる湿度インジケーター。1. A humidity indicator comprising a dry molded product of a mixture of a powdery deliquescent substance and a powdery color developer that develops color by contact with a deliquescent liquid of the deliquescent substance.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP32274893A JP2878095B2 (en) | 1993-12-21 | 1993-12-21 | Humidity indicator |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP32274893A JP2878095B2 (en) | 1993-12-21 | 1993-12-21 | Humidity indicator |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH07174704A true JPH07174704A (en) | 1995-07-14 |
| JP2878095B2 JP2878095B2 (en) | 1999-04-05 |
Family
ID=18147204
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP32274893A Expired - Fee Related JP2878095B2 (en) | 1993-12-21 | 1993-12-21 | Humidity indicator |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2878095B2 (en) |
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| EP1705484A1 (en) * | 2005-03-23 | 2006-09-27 | GP&E America, LLC | Composition for non-toxic, non-hazardous, and environmentally friendly humidity-indicating agent and its application |
| KR100676777B1 (en) * | 2004-12-29 | 2007-02-02 | (주)지피엔이 | The Producing Method of Cobalt-free Humidity Indicating Agent and Its Application |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20040047035A (en) * | 2002-11-28 | 2004-06-05 | (주)지피엔이 | The Wide-range Humidity Indicating Cards |
| JP2005222756A (en) * | 2004-02-04 | 2005-08-18 | Matsushita Electric Ind Co Ltd | Fuel case for fuel cell and fuel cell pack |
| KR100676777B1 (en) * | 2004-12-29 | 2007-02-02 | (주)지피엔이 | The Producing Method of Cobalt-free Humidity Indicating Agent and Its Application |
| EP1705484A1 (en) * | 2005-03-23 | 2006-09-27 | GP&E America, LLC | Composition for non-toxic, non-hazardous, and environmentally friendly humidity-indicating agent and its application |
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| JP2007198828A (en) * | 2006-01-25 | 2007-08-09 | Toppan Printing Co Ltd | Moisture indicator and package |
| WO2007125953A1 (en) | 2006-04-26 | 2007-11-08 | Kyodo Printing Co., Ltd. | Coating for humidity indicator, method for production of the coating, humidity indicator using the coating |
| US8962521B2 (en) | 2006-04-26 | 2015-02-24 | Kyodo Printing Co., Ltd. | Coating for humidity indicator, method for production of the coating, and humidity indicator using the coating |
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| JP2011185695A (en) * | 2010-03-08 | 2011-09-22 | Kyodo Printing Co Ltd | Humidity indicator, method for manufacturing the same, and coating for humidity indicator used in the manufacturing method |
| JP2011185745A (en) * | 2010-03-09 | 2011-09-22 | Kyodo Printing Co Ltd | Humidity indicator, method for manufacturing the same, and coating for humidity indicator used in the manufacturing method |
| JP2016080543A (en) * | 2014-10-17 | 2016-05-16 | 株式会社サクラクレパス | Powder composition for moisture indicator |
| CN107286752A (en) * | 2017-07-04 | 2017-10-24 | 厦门麓山新材料科技有限公司 | A kind of vapor sensitive color shifting ink and wet sensitive antifalsification label |
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|---|---|
| JP2878095B2 (en) | 1999-04-05 |
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