JPH0715111B2 - Glass cleaner composition - Google Patents
Glass cleaner compositionInfo
- Publication number
- JPH0715111B2 JPH0715111B2 JP61101709A JP10170986A JPH0715111B2 JP H0715111 B2 JPH0715111 B2 JP H0715111B2 JP 61101709 A JP61101709 A JP 61101709A JP 10170986 A JP10170986 A JP 10170986A JP H0715111 B2 JPH0715111 B2 JP H0715111B2
- Authority
- JP
- Japan
- Prior art keywords
- glass cleaner
- cleaner composition
- glass
- component
- alkyl ether
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Landscapes
- Detergent Compositions (AREA)
Description
【発明の詳細な説明】 〔産業上の利用分野〕 本発明はガラスクリーナー組成物に関するものであり、
更に詳しくは洗浄力が大きく、又拭き取りが容易で拭い
た後に残留物を残さないガラスクリーナー組成物に関す
るものである。DETAILED DESCRIPTION OF THE INVENTION [Field of Industrial Application] The present invention relates to a glass cleaner composition,
More specifically, the present invention relates to a glass cleaner composition having a high cleaning power, easy wiping and leaving no residue after wiping.
ガラスクリーナーは、ガラス面に付着している砂,ホコ
リ,その他の無機物からなる汚染物をガラス面より浮き
上がらせ、溶解あるいは分散させて、布や紙による拭き
取りを容易にするものであり、従来より種々のガラスク
リーナーが提案ないし市販されている。The glass cleaner floats the contaminants such as sand, dust, and other inorganic substances adhering to the glass surface from the glass surface, dissolves or disperses it, and makes it easier to wipe with a cloth or paper. Various glass cleaners have been proposed or marketed.
しかしながら、従来提案ないし市販されているガラスク
リーナーは、洗浄力、拭き取り性という基本性能におい
て未だ満足できるものではなかつた。すなわち、有機性
の頑固な汚れを落すことができず、また洗浄性を向上さ
せるために界面活性剤量を多くすると、しつこい泡がで
き、拭きとつても泡が拭き筋として残り仕上り感をそこ
なうという欠点があつた。However, the glass cleaners conventionally proposed or commercially available have not yet been satisfactory in basic performance such as cleaning power and wiping property. That is, it is impossible to remove organic stubborn stains, and if a large amount of surfactant is used to improve detergency, persistent bubbles are created, and even after wiping, the bubbles remain as wiping lines and impair the finish feeling. There was a drawback.
本発明者らは、これらのガラスクリーナーの持つ欠点を
改善せんと鋭意研究した結果、特定の水溶性溶剤を含有
するガラスクリーナーが洗浄力、拭き取り性が顕著に改
善されることを見出し、本発明を完成した。As a result of intensive studies to improve the drawbacks of these glass cleaners, the present inventors have found that a glass cleaner containing a specific water-soluble solvent has markedly improved detergency and wiping properties. Was completed.
すなわち、本発明な必須成分として、(A)ポリオキシ
エチレンアルキルエーテル、(B)陰イオン性界面活性
剤および(C)次式(I) (式中、Rは炭素数1〜3のアルキル基を示す) で表される水溶性溶剤を含有することを特徴とするガラ
スクリーナー組成物を提供するものである。本発明で用
いられる(A)成分のポリオキシエチレンアルキルエー
テルの中でも炭酸数8〜22の高級アルコールに酸化エチ
レン1〜150モルに付加したポリオキシエチレンアルキ
ルエーテルが好ましい。ポリオキシエチレンアルキルエ
ーテルの量は、特に限定されるものではなく、また種類
によつても異なるが、通常0.005〜5重量%、好ましく
は0.05〜1重量%である。That is, as the essential components of the present invention, (A) polyoxyethylene alkyl ether, (B) anionic surfactant and (C) the following formula (I) (In the formula, R represents an alkyl group having 1 to 3 carbon atoms). A glass cleaner composition comprising a water-soluble solvent represented by the following formula. Among the polyoxyethylene alkyl ethers of the component (A) used in the present invention, polyoxyethylene alkyl ethers obtained by adding 1 to 150 mol of ethylene oxide to a higher alcohol having a carbon number of 8 to 22 are preferable. The amount of polyoxyethylene alkyl ether is not particularly limited and varies depending on the kind, but is usually 0.005 to 5% by weight, preferably 0.05 to 1% by weight.
本発明に用いることのできる(B)成分の陰イオン界面
活性剤としては、アルキルベンゼンスルホン酸塩,アル
キル硫酸エステル塩,アルキルエトキシ硫酸エステル
塩,オレフインスルホン酸塩,脂肪酸塩,アルキルエト
キシカルボン酸塩,α−スルホ脂肪酸エステル塩,α−
スルホ脂肪酸塩,モノアルキルリン酸エステル塩などを
挙げることができる。これらの中でも炭素数8〜16のア
ルキルベンゼンスルホン酸塩が好ましい。陰イオン性界
面活性剤の量は、特に限定されるものではなく、また種
類によつても異なるが、通常0.005〜5重量%、好まし
くは0.05〜1重量%である。The component (B) anionic surfactant that can be used in the present invention includes alkylbenzene sulfonate, alkyl sulfate ester salt, alkyl ethoxy sulfate ester salt, olefin sulfonate salt, fatty acid salt, alkyl ethoxy carboxylate salt, α-sulfo fatty acid ester salt, α-
Examples thereof include sulfo fatty acid salt and monoalkyl phosphate ester salt. Of these, alkylbenzene sulfonates having 8 to 16 carbon atoms are preferable. The amount of the anionic surfactant is not particularly limited and varies depending on the kind, but is usually 0.005 to 5% by weight, preferably 0.05 to 1% by weight.
また、(C)成分の(I)式で表わされる1,3−ジアル
キル−2−イミダゾリジノンの配合量は、0.5〜20重量
%、好ましくは1〜10重量%である。The amount of 1,3-dialkyl-2-imidazolidinone represented by the formula (I) as the component (C) is 0.5 to 20% by weight, preferably 1 to 10% by weight.
本発明のガラスクリーナー組成物には、更に必要に応じ
て、尿素,ピロリン酸塩,トリポリリン酸塩,オルソリ
ン酸塩,硫酸塩,硝酸塩,塩化物,アルカノールアミ
ン,両性界面活性剤,香料,顔料,染料などを添加する
こともできる。The glass cleaner composition of the present invention further comprises urea, pyrophosphate, tripolyphosphate, orthophosphate, sulfate, nitrate, chloride, alkanolamine, amphoteric surfactant, perfume, pigment, if necessary. A dye or the like can be added.
本発明のガラスクリーナー組成物は、液体のまま使用す
ることもでき、またLPGなどを噴射剤として上記の組成
の液体に3〜10重量%混合しエアゾール製品としても使
用することも可能である。The glass cleaner composition of the present invention can be used as a liquid as it is, or can also be used as an aerosol product by mixing 3 to 10% by weight of the liquid having the above composition with LPG or the like as a propellant.
本発明の水溶性溶剤を用いたガラスクリーナー組成物
は、界面活性剤量を低滅させても洗浄力に優れているた
め、拭き取り性がよい。また、本発明の水溶性溶剤を用
いると、繊維に対するぬれが良くなるためか、洗浄液は
布への吸収性がよく、汚染物のガラス面への再付着も少
ない。これらの効果によつて本発明のガラスクリーナー
組成物を用いると、頑固な汚れで覆われたガラス面も汚
染物を完全に落とし、かつ拭き取り性が良いために、二
度拭きの必要がない。The glass cleaner composition using the water-soluble solvent of the present invention is excellent in detergency even if the amount of the surfactant is reduced, and thus has good wiping property. Further, the use of the water-soluble solvent of the present invention improves the wettability of the fiber, and the cleaning liquid has a good absorbability to the cloth, and the contaminants are hardly redeposited on the glass surface. Due to these effects, when the glass cleaner composition of the present invention is used, the glass surface covered with stubborn stains can completely remove contaminants and has good wiping property, so that it is not necessary to wipe it twice.
次に実施例を挙げて説明する。 Next, examples will be described.
実施例1 表−1に示す組成物について溶剤の違いによる拭き取り
性とモデル汚れに対する洗浄力を調べた。結果を表−1
に示す。Example 1 With respect to the compositions shown in Table-1, the wiping property due to the difference in solvent and the cleaning power against model stains were examined. The results are shown in Table-1
Shown in.
清浄なガラスにガラスクリーナーを塗布し、布で軽く拭
き取つたときの乾き易さを次の基準で評価した。A glass cleaner was applied to clean glass, and the ease of drying when wiped off with a cloth was evaluated according to the following criteria.
◎:優れている ○:良 △:普通 ×:悪い 〔モデル汚れの作成方法と洗浄率算出方法〕 タバコのヤニを人工的に付着させた人工汚染ガラスにガ
ラスクリーナーをスプレーしたときのタバコのヤニの洗
浄率を、ガラスクリーナーをスプレーし1秒後、ガラス
表面を水で洗い流した後、画像解析装置によりタバコの
ヤニの付着面積を測定し、下記の式によつて求めた。◎: Excellent ○: Good Δ: Normal ×: Poor [Model stain creation method and cleaning rate calculation method] Tobacco tar when a glass cleaner is sprayed onto artificially contaminated glass to which the tobacco tar is artificially adhered The cleaning rate of was measured by the following formula after spraying a glass cleaner for 1 second, washing the glass surface with water, measuring the adhesion area of the tar of the cigarette with an image analyzer.
実施例2 表−2に示す組成を含有する各種ガラスクリーナー液を
調整し、LPGをガラスクリーナー液に対して6重量%混
合してエアゾール製品とし性能を試験した。結果を表−
2に示す。 Example 2 Various glass cleaner liquids containing the compositions shown in Table 2 were prepared, and 6% by weight of LPG was mixed with the glass cleaner liquid to prepare an aerosol product, and its performance was tested. Table of results
2 shows.
市販品(A):ポリオキシエチレンアルキルフエノール
エーテル ポリオキシエチレンアルキル硫酸塩 アルカノールアミン イソプロピルアルコール エチレングリコールモノメリルエーテル これら成分を含有するガラスクリーナー(エアゾール
型) 市販品(B):ポリオキシエチレンアルキルエーテル モルホリン エタノール エチレングリコールモノエチルエーテル これら成分を含有するガラスクリーナー(エアゾール
型) 実施例3 表−3に示す組成のガラスクリーナー液について拭き取
り性とモデル汚れに対する洗浄力を調べた。結果を表−
3に示す。 Commercial product (A): polyoxyethylene alkylphenol ether polyoxyethylene alkyl sulfate, alkanolamine isopropyl alcohol, ethylene glycol monomeryl ether Glass cleaner (aerosol type) containing these components Commercial product (B): polyoxyethylene alkyl ether morpholine Ethanol Ethylene glycol monoethyl ether Glass cleaner containing these components (aerosol type) Example 3 With respect to the glass cleaner liquid having the composition shown in Table 3, the wiping property and the detergency against model stains were examined. Table of results
3 shows.
Claims (4)
アルキルエーテル、(B)陰イオン性界面活性剤および
(C)次式(I) (式中、Rは炭素数1〜3のアルキル基を示す) で表される水溶性溶剤を含有することを特徴とするガラ
スクリーナ組成物。1. An (A) polyoxyethylene alkyl ether, (B) an anionic surfactant and (C) the following formula (I) as essential components. (In formula, R shows a C1-C3 alkyl group.) The glass cleaner composition characterized by containing the water-soluble solvent represented by these.
キルベンゼンスルホン酸塩である請求項1記載のガラス
クリーナー組成物。2. The glass cleaner composition according to claim 1, wherein the anionic surfactant as the component (B) is an alkylbenzene sulfonate.
ルアルキルエーテルに酸化エチレンを1〜150モル付加
したポリオキシエチレンアルキルエーテルである請求項
1または2記載のガラスクリーナー組成物。3. The glass cleaner composition according to claim 1, wherein the component (A) is a polyoxyethylene alkyl ether obtained by adding 1 to 150 mol of ethylene oxide to a higher alcohol alkyl ether having 8 to 22 carbon atoms.
ゼンスルホン酸塩である請求項1〜3のいずれかの項記
載のガラスクリーナー組成物。4. The glass cleaner composition according to claim 1, wherein the component (B) is an alkylbenzene sulfonate having 8 to 16 carbon atoms.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP61101709A JPH0715111B2 (en) | 1986-05-01 | 1986-05-01 | Glass cleaner composition |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP61101709A JPH0715111B2 (en) | 1986-05-01 | 1986-05-01 | Glass cleaner composition |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS62257994A JPS62257994A (en) | 1987-11-10 |
JPH0715111B2 true JPH0715111B2 (en) | 1995-02-22 |
Family
ID=14307835
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP61101709A Expired - Lifetime JPH0715111B2 (en) | 1986-05-01 | 1986-05-01 | Glass cleaner composition |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH0715111B2 (en) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2219001B (en) * | 1988-05-27 | 1992-03-04 | Trico Folberth Ltd | Glass cleaning composition |
JP2521630B2 (en) * | 1992-12-10 | 1996-08-07 | 花王株式会社 | Cleaning composition for hard surfaces |
RO112762B1 (en) * | 1996-11-20 | 1997-12-30 | Sc Dmk Srl | Glass cleaning products |
JP4025953B2 (en) | 2001-01-05 | 2007-12-26 | 荒川化学工業株式会社 | Cleaning composition |
JP4864598B2 (en) * | 2006-08-11 | 2012-02-01 | 花王株式会社 | Cleaning composition for hard surface |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6191299A (en) * | 1984-10-12 | 1986-05-09 | 川研ファインケミカル株式会社 | Hard surface cleanser |
-
1986
- 1986-05-01 JP JP61101709A patent/JPH0715111B2/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
JPS62257994A (en) | 1987-11-10 |
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