JPH07122764B2 - Development device - Google Patents

Development device

Info

Publication number
JPH07122764B2
JPH07122764B2 JP62277347A JP27734787A JPH07122764B2 JP H07122764 B2 JPH07122764 B2 JP H07122764B2 JP 62277347 A JP62277347 A JP 62277347A JP 27734787 A JP27734787 A JP 27734787A JP H07122764 B2 JPH07122764 B2 JP H07122764B2
Authority
JP
Japan
Prior art keywords
magnetic
developer
magnetic particles
free end
particles
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP62277347A
Other languages
Japanese (ja)
Other versions
JPH01120581A (en
Inventor
貴裕 久保
初雄 田嶋
博司 田鹿
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Canon Inc
Original Assignee
Canon Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Canon Inc filed Critical Canon Inc
Priority to JP62277347A priority Critical patent/JPH07122764B2/en
Priority to US07/266,810 priority patent/US4876574A/en
Publication of JPH01120581A publication Critical patent/JPH01120581A/en
Publication of JPH07122764B2 publication Critical patent/JPH07122764B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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  • Dry Development In Electrophotography (AREA)

Description

【発明の詳細な説明】 (産業上の利用分野) 本発明は、非磁性現像剤により静電潜像を現像する現像
装置に関する。
TECHNICAL FIELD The present invention relates to a developing device for developing an electrostatic latent image with a non-magnetic developer.

(従来の技術及び問題点) 従来、乾式一成分現像装置としては各種装置が提案され
また実用化されている。しかし、いずれの現像方式にお
いても乾式一成分現像剤の薄層を形成することは、極め
て難しい。しかるに現像画像の鮮明度、解像力、などの
向上が求められている現在、乾式一成分現像剤の薄層形
成方法及びその装置に関する開発は必須となっており、
またこれに応えていくつかの方策が提案されている。
(Prior Art and Problems) Various devices have been proposed and put into practical use as dry one-component developing devices. However, it is extremely difficult to form a thin layer of a dry one-component developer by any of the developing methods. However, at present, it is essential to develop a method for forming a thin layer of a dry type one-component developer and an apparatus therefor, which is required to improve the sharpness of the developed image, the resolution, and the like.
In response, some measures have been proposed.

一方、非磁性現像剤と磁性粒子とを用いる二成分現像剤
の薄層形成のためには、例えば、現像剤担持体に対向し
て磁性粒子拘束部材を設け、該現像剤担持体表面の移動
方向に関し、磁性粒子拘束部材の上流に磁界発生手段の
磁気力により磁性粒子の磁気ブラシを形成し、該磁気ブ
ラシを磁性粒子拘束部材で拘束することによって磁性粒
子を現像剤容器内に留めて、非磁性現像剤のみの薄層を
現像剤担持体に形成する装置が既に提案されている。こ
れにより非磁性現像剤のみによる現像が可能となり、カ
ラー化も可能となった。しかし、このように現像剤容器
内にのみ磁性粒子とトナー粒子とを混在させている現像
装置では、画質向上のために細かい磁性粒子を用いると
磁性粒子が漏れるという問題が生じている。さらに、高
画質の要求に応じ、上記現像剤容器内で撹拌によって十
分かつ均一にトナーにトリボを与えねばならないという
要求もある。
On the other hand, in order to form a thin layer of a two-component developer using a non-magnetic developer and magnetic particles, for example, a magnetic particle restraining member is provided facing the developer carrier, and the surface of the developer carrier is moved. Regarding the direction, a magnetic brush of magnetic particles is formed by the magnetic force of the magnetic field generating means upstream of the magnetic particle restraining member, and the magnetic particles are retained in the developer container by restraining the magnetic brush with the magnetic particle restraining member. An apparatus for forming a thin layer containing only a non-magnetic developer on a developer carrier has already been proposed. This made it possible to develop only with a non-magnetic developer, and it became possible to colorize. However, in the developing device in which the magnetic particles and the toner particles are mixed only in the developer container as described above, there is a problem that the magnetic particles leak if fine magnetic particles are used for improving the image quality. Further, in response to the demand for high image quality, there is also a demand that tribo is imparted to the toner sufficiently and uniformly by stirring in the developer container.

(問題点を解決するための手段) 本発明は上述の種の二成分現像剤を用いた従来の現像装
置の問題点を解決し、簡易な構成により良好な磁性粒子
の拘束性と安定性を保証し、非磁性現像剤の薄層を現像
剤担持体表面に長期にわたって安定的に形成し、良好な
画像の得られる現像装置の提供を目的とする。
(Means for Solving the Problems) The present invention solves the problems of the conventional developing device using the above-described two-component developer, and provides good magnetic particle restraint and stability with a simple structure. It is an object of the present invention to provide a developing device which guarantees a stable formation of a thin layer of a non-magnetic developer on the surface of a developer bearing member for a long period of time and obtains a good image.

本発明は、上記目的のために 非磁性現像剤と磁性粒子とを収容した現像剤容器の開口
に設けられ、該現像剤容器の内部と外部とを無端運動可
能な現像剤担持体と、 上記現像剤担持体内部に設けられた磁界発生手段と、 現像剤担持体に当接されており、磁性粒子の通過は阻止
し、非磁性現像剤は通過させて現像剤担持体表面に非磁
性現像剤層を形成する磁性粒子拘束手段と、 を備えた現像装置において、 上記磁性粒子拘束手段は、自由端と現像剤担持体との間
に上記磁性粒子の平均粒径よりも小なる間隙が形成され
るようにして、自由端近傍の腹の面が現像剤担持体に当
接された非磁性弾性板であって、この当接部から固定端
部までの腹の面と現像担持体表面との間隔が現像剤担持
体移動方向に増大して行くように配設された非磁性弾性
板と、この弾性板の少なくとも自由端部の、上記腹の面
とは反対側の面に設けられ、上記磁界発生手段の、現像
剤担持体移動方向に関し、弾性板自由端よりも上流側に
位置する磁極との間に磁性粒子を拘束する磁界を形成す
る磁性部材とを有する、 ことにより構成される。
For this purpose, the present invention provides a developer carrier which is provided in an opening of a developer container containing a non-magnetic developer and magnetic particles and is capable of endless movement inside and outside the developer container, The magnetic field generating means provided inside the developer carrying member is in contact with the developer carrying member to prevent the passage of magnetic particles and allow the non-magnetic developer to pass therethrough so that the surface of the developer carrying member is non-magnetically developed. In a developing device including magnetic particle restraining means for forming a developer layer, the magnetic particle restraining means forms a gap between the free end and the developer carrier, the gap being smaller than the average particle diameter of the magnetic particles. In this way, the antinode surface near the free end is the non-magnetic elastic plate abutting on the developer carrier, and the antinode surface from the abutting part to the fixed end and the surface of the developer carrier. Non-magnetic elastic plate arranged so that the interval between the two increases in the moving direction of the developer carrier. Provided on the surface of at least the free end of the elastic plate opposite to the antinode surface, and is located upstream of the elastic plate free end of the magnetic field generating means in the moving direction of the developer carrier. And a magnetic member that forms a magnetic field that restrains magnetic particles between the magnetic pole and the magnetic pole.

(実施例) 以下、添付図面にもとづいて本発明の実施例を説明す
る。第1図に示される一実施例としての現像装置におい
て、21は二成分現像剤を収容する現像剤容器、22は現像
剤担持体としての現像スリーブである。該現像スリーブ
22は、例えばアルミニウム等の非磁性スリーブであり、
図において現像剤容器21の左側壁の下部に容器長手方向
(紙面に直角方向)に形成された横長開口に、右略半周
面を現像剤容器21内へ突入させ、左略半周面を容器外に
露出させて回転自在な支承させて横設してあり、矢示の
反時計方向bに回転駆動される。現像剤担持体22は上記
円筒体(スリーブ)に限らず、回転駆動される無端ベル
ト形態にしてもよい。また導電性ゴムローラを用いても
よい。上記現像スリーブ22の容器外への露出面は、矢示
a方向に回転駆動されている感光体等の潜像保持部材3
の面に僅小な隙間を保って対面ないしは接触している。
Embodiment An embodiment of the present invention will be described below with reference to the accompanying drawings. In the developing device as one embodiment shown in FIG. 1, reference numeral 21 is a developer container for containing a two-component developer, and 22 is a developing sleeve as a developer carrying member. The developing sleeve
22 is a non-magnetic sleeve such as aluminum,
In the figure, a right approximately half-circumferential surface is projected into the developer container 21 in a laterally long opening formed in the lower part of the left side wall of the developer container 21 in the longitudinal direction of the container (a direction perpendicular to the paper surface), and a left approximately half peripheral surface is outside the container. It is exposed to and is rotatably supported and laid laterally, and is rotationally driven in the counterclockwise direction b indicated by the arrow. The developer carrying member 22 is not limited to the above cylindrical body (sleeve), and may be in the form of an endless belt that is rotationally driven. Alternatively, a conductive rubber roller may be used. The exposed surface of the developing sleeve 22 to the outside of the container is a latent image holding member 3 such as a photoconductor that is rotationally driven in the direction of arrow a.
Is in contact with or facing each other with a small gap.

上記現像スリーブ22内は、図示の位置・姿勢に位置決め
保持した磁界発生手段としての永久磁石(マグネット)
23が固定位置に挿入配置されている。この磁石23は図示
のごとくN極23a、S極23bの二磁極を有しているが、こ
れは永久磁石に代えて電磁石としてもよい。
The inside of the developing sleeve 22 is a permanent magnet (magnet) as a magnetic field generating means that is positioned and held in the position and orientation shown in the figure.
23 is inserted in the fixed position. The magnet 23 has two magnetic poles, an N pole 23a and an S pole 23b, as shown in the figure, but it may be an electromagnet instead of a permanent magnet.

上記現像スリーブ22の上部の面には、磁性粒子拘束部材
としての非磁性の弾性部材たる弾性ブレード50が上記現
像スリーブ22の長手方向に沿って接触するように設けら
れている。該弾性ブレード50は一端で固定され、他端た
る自由端近傍にて図における長手方向で距離lにて接触
している(以下この接触を「ニップ」という)。そして
自由端では現像スリーブ22との間に間隙を形成し、さら
に少なくとも上記自由端に近い部分の上面に磁性部材51
が取付けられている。例えば、上記弾性ブレード50は、
好ましい形態として、厚さ0.5〜3.0mm、硬度30゜〜90゜
(JIS−A)のウレタンゴム板で、これを20〜200g/cmの
当接圧(紙面に直角方向の単位距離当り圧力で示す線
圧)で接触されている。また、磁性部材51としては厚さ
0.5〜2mmの鉄板が使用されている。さらに、上記ニップ
幅lに関しては、第2図に示されるごとく、磁石23の磁
極23aと磁性部材51との間の磁界にもとづく磁気的吸引
作用が磁性粒子の拘束適正に有効に働くように、5mm以
下好ましくは3mm以下に設定することが望ましい。この
lが5mmよりも大きいと上記磁界が磁性粒子を弾性ブレ
ードの自由端で通過させやすくする方向に働くため、弾
性ブレード50による機械的拘束作用の負担が増すことと
なる。したがって、弾性ブレード50の設定条件が狭くな
ってしまう。
An elastic blade 50, which is a non-magnetic elastic member as a magnetic particle restraining member, is provided on the upper surface of the developing sleeve 22 so as to come into contact with the developing sleeve 22 in the longitudinal direction. The elastic blade 50 is fixed at one end and is in contact with the free end, which is the other end, at a distance 1 in the longitudinal direction in the figure (hereinafter, this contact is referred to as a "nip"). A gap is formed between the free end and the developing sleeve 22, and a magnetic member 51 is formed on the upper surface of at least the portion near the free end.
Is installed. For example, the elastic blade 50,
A preferred form is a urethane rubber plate having a thickness of 0.5 to 3.0 mm and a hardness of 30 ° to 90 ° (JIS-A), and a contact pressure of 20 to 200 g / cm (at a pressure per unit distance in the direction perpendicular to the paper surface). They are in contact with each other at the indicated line pressure. The thickness of the magnetic member 51 is
0.5-2 mm steel plate is used. Further, with respect to the nip width l, as shown in FIG. 2, the magnetic attraction action based on the magnetic field between the magnetic pole 23a of the magnet 23 and the magnetic member 51 works properly and effectively so as to restrain the magnetic particles. It is desirable to set it to 5 mm or less, preferably 3 mm or less. If this l is larger than 5 mm, the magnetic field acts in a direction that facilitates the passage of magnetic particles at the free end of the elastic blade, which increases the burden of mechanical restraint by the elastic blade 50. Therefore, the setting condition of the elastic blade 50 becomes narrow.

また、弾性ブレードの自由端における現像スリーブとの
間隙dは、磁性粒子の平均粒径rとの関係でr>dであ
ることが好ましい。すなわち、非磁性弾性ブレード50の
スリーブとの当接条件は、該弾性ブレード50との当接面
が自由端部でいわゆる腹当りさせることにより上記関係
を得られる。
The gap d between the free end of the elastic blade and the developing sleeve is preferably r> d in relation to the average particle size r of the magnetic particles. That is, the contact condition of the non-magnetic elastic blade 50 with the sleeve can be obtained by causing the contact surface of the non-magnetic elastic blade 50 with the elastic blade 50 to have a so-called abdomen contact at the free end.

以上のように、磁性部材をもつ弾性ブレード51がスリー
ブ22に接触あるいは圧接されると、磁性粒子の漏出をほ
ぼ完全に防ぐことができる。この理由は磁性部材51と磁
極23aとの磁界による拘束力だけでなく非磁性弾性ブレ
ード50による機械的拘束力が作用するためである。しか
し、この場合は弾性ブレードを通過してスリーブ22上に
塗布されるべき現像剤塗布層が弾性ブレードによってか
き落とされないようにブレードの接触圧力、先端形状を
設定する必要がある。接触圧力及び間隙dは一般的に非
磁性の弾性ブレード50によってのみ設定されるが、本発
明によれば磁性部材51と磁極23aとの間で発生する磁力
により、非磁性弾性ブレード50は現像スリーブ22の表面
にて均一に長手方向に引き寄せられるので、非磁性弾性
ブレード50に関する機械的設定条件が緩められることと
なる。
As described above, when the elastic blade 51 having a magnetic member is brought into contact with or pressed against the sleeve 22, it is possible to prevent leakage of magnetic particles almost completely. This is because not only the binding force of the magnetic field between the magnetic member 51 and the magnetic pole 23a but also the mechanical binding force of the non-magnetic elastic blade 50 acts. However, in this case, it is necessary to set the blade contact pressure and tip shape so that the developer coating layer to be coated on the sleeve 22 after passing through the elastic blade is not scraped off by the elastic blade. The contact pressure and the gap d are generally set only by the non-magnetic elastic blade 50, but according to the present invention, the magnetic force generated between the magnetic member 51 and the magnetic pole 23a causes the non-magnetic elastic blade 50 to develop. Since the surface of 22 is uniformly attracted in the longitudinal direction, the mechanical setting conditions for the non-magnetic elastic blade 50 are relaxed.

次に、現像剤容器21内には、磁性粒子27と非磁性現像剤
28からなる二成分現像剤が収容されている。磁性粒子27
は平均粒径が30〜200μm、好ましくは40〜70μmであ
る。
Next, in the developer container 21, the magnetic particles 27 and the non-magnetic developer are
A two-component developer consisting of 28 is contained. Magnetic particles 27
Has an average particle size of 30 to 200 μm, preferably 40 to 70 μm.

磁性粒子は細かい粒径のもの程、画像性が良く、特に地
カブリ及びスリーブゴーストに対して良好である。これ
は粒径が細かくなる程その比表面積は増加し、被接触物
との接触度合も増加するので、現像スリーブ22と磁性粒
子との間で行なわれる現像剤へのトリボ付与も十分行な
われるためである。逆に磁性粒子を粗めにすると、地カ
ブリ及びスリーブゴーストが発生する。
The finer the particle size of the magnetic particles, the better the imageability, and especially the good against the background fog and the sleeve ghost. This is because the smaller the particle size is, the more the specific surface area is increased and the degree of contact with the contacted object is also increased. Therefore, tribo is sufficiently applied to the developer between the developing sleeve 22 and the magnetic particles. Is. On the contrary, if the magnetic particles are made coarse, background fog and sleeve ghost will occur.

しかしながら、粒径を細かくすると、磁界による磁気的
拘束力が小さくなり、磁性粒子が現像容器外へ漏れやす
くなる。したがって、磁性粒子の粒度分布は磁性粒子が
容器外に漏れ出さない範囲で極力細かくすることが良
く、精度の良い分級が必要となる。
However, if the particle size is made small, the magnetic restraining force due to the magnetic field becomes small, and the magnetic particles easily leak out of the developing container. Therefore, the particle size distribution of the magnetic particles should be as fine as possible within the range where the magnetic particles do not leak out of the container, and accurate classification is required.

例えば、公知の方法で、表面にシリコン系樹脂を塗布し
たフェライト系の磁性粒子をつくりJIS−Z8801で規定さ
れる標準ふるいを用いて分級をし、JIS−H2601に準拠し
た粒度分布試験法によって粒度分布を測定により、上記
磁性粒子を145〜400メッシュの間で5段階に分級してこ
れらを適宜混合したものについて、画像形成の良否を比
較した結果、次のことが確認された。
For example, by a known method, a ferrite-based magnetic particle coated with a silicon-based resin is formed on the surface and classified using a standard sieve defined by JIS-Z8801, and a particle size distribution test method according to JIS-H2601 is used. The distribution was measured, and the magnetic particles were classified into 5 stages between 145 and 400 mesh and appropriately mixed, and the quality of image formation was compared. As a result, the following was confirmed.

磁性粒子の漏れに対処するためには400メッシュ以
下の粒度成分を10重量%以下にすることが好ましい。
In order to deal with leakage of magnetic particles, it is preferable that the particle size component of 400 mesh or less is 10% by weight or less.

画像のスリーブゴーストについては145メッシュ以
上の粒度成分を極力分級除去し、250〜350メッシュの平
均粒径のピークをもつようにすることが好ましい。
For the sleeve ghost of the image, it is preferable to remove the particle size component of 145 mesh or more as much as possible so as to have a peak of the average particle size of 250 to 350 mesh.

地カブリに関しては、145〜250メッシュという比較
的粒度の大きい磁性粒子が約50%含めている場合でもほ
とんど発生がなかった。これは弾性ブレードによって現
像スリーブ上の非磁性現像剤を摺擦するために、磁性粒
子による摺擦だけでは地カブリを発生するような不十分
なトリボ付与状態でも、地カブリを発生しにくいことに
よる。
The ground fog did not occur even when about 50% of magnetic particles having a relatively large size of 145 to 250 mesh were included. This is because the non-magnetic developer on the developing sleeve is rubbed by the elastic blade, so that the ground fog is less likely to occur even in the insufficient tribo-applied state where the ground fog is generated only by the rubbing with the magnetic particles. .

各磁性粒子は磁性材料のみから成るものでも、磁性材料
と非磁性材料との結合体でもよいし、二種以上の磁性粒
子の混合物でも良い。かかる、磁性粒子と上記非磁性現
像剤を混合したとき、磁石23と弾性ブレード50に取付け
られた磁性部材51との間に形成される磁界によって、現
像剤容器内では、上記スリーブ22に対する第1層として
の磁性粒子層の外側に多量に貯溜して第2層として存在
するようになる。そして、磁石23の磁極23a位置に対応
するスリーブ表面付近の磁性粒子層部分に磁極23aの強
い磁界により磁性粒子の磁気ブラシ27aが形成される。
Each magnetic particle may be composed of only a magnetic material, a combination of a magnetic material and a non-magnetic material, or a mixture of two or more kinds of magnetic particles. When the magnetic particles and the non-magnetic developer are mixed, the magnetic field formed between the magnet 23 and the magnetic member 51 attached to the elastic blade 50 causes the first magnetic field relative to the sleeve 22 in the developer container. A large amount of it is stored outside the magnetic particle layer as a layer and exists as a second layer. Then, a magnetic brush 27a of magnetic particles is formed in the magnetic particle layer portion near the surface of the sleeve corresponding to the position of the magnetic pole 23a of the magnet 23 by the strong magnetic field of the magnetic pole 23a.

また磁性粒子拘束部材たる非磁性弾性ブレード50の先端
部近傍部の磁性粒子層部分は、現像スリーブ22が矢示b
方向に回転駆動されても、重力、磁気力及び磁性部材51
の存在に基づく拘束力と、現像スリーブ22の移動方向へ
の搬送力との釣合いによって現像スリーブ22表面の点25
位置で拘束され、多少は動き得るが殆ど不動の静止層27
bを形成する。
Further, the developing sleeve 22 is shown by the arrow b in the magnetic particle layer portion near the tip of the non-magnetic elastic blade 50 which is a magnetic particle restraining member.
Direction, the gravitational force, magnetic force, and magnetic member 51
Of the developing sleeve 22 and the carrying force in the moving direction of the developing sleeve 22 are balanced by the restraining force due to the presence of
A stationary layer that is constrained in position and can move slightly, but is almost immobile 27
form b.

また現像スリーブ22を矢示b方向に回転させたとき、磁
極23aの配置位置と磁性粒子27の流動性及び磁気特性を
適宜選ぶことによって、上記磁気ブラシ27aは磁極23aの
付近で矢印c方向に循環し、循環層27cを形成する(第
1図参照)。該循環層27cにおいて、現像スリーブ22に
比較的近い磁性粒子は現像スリーブ22の回転によって磁
極23a近傍から現像スリーブの回転下流側へ盛り上が
る。すなわち上部へ押し上げる力を受ける。その押し上
げられた磁性粒子は、重力によって落下し、再び磁極23
a近傍へ戻る。つまり該循環層27cでは重力と磁極による
磁気力と摩擦力及び磁性粒子の流動性(粘性)によって
矢印cのごとく磁性粒子の磁気ブラシ27aの循環が行な
われ、磁気ブラシはこの循環の際に磁性粒子層の上にあ
る現像剤層から非磁性現像剤28を逐次取込んで現像剤容
器21内の下部に戻り、以下現像スリーブ22の回転駆動に
伴ないこの循環を繰返す。このとき磁性部材51の影響に
より、該磁性部材51が存在しない場合に比べると磁極23
aの磁界が弾性ブレード50の先端へ集中しやすくなるの
で、該先端位置で磁性粒子の保持力が高まり非磁性現像
剤28へのトリボ付与能力が増すとともに、磁性部材をも
つ弾性ブレード50の先端から非磁性現像剤28が直接取込
まれることがなくなり、カブリやスリーブゴーストのな
い良好な画像を得られる。また、磁界の影響により弾性
ブレードの先端にて磁気拘束力によって現像スリーブ22
の長手方向に均一に保持されるため現像スリーブ22の表
面上に非磁性現像剤28をムラなくコーティングすること
ができる。
Further, when the developing sleeve 22 is rotated in the direction of arrow b, the magnetic brush 27a is moved in the direction of arrow c near the magnetic pole 23a by appropriately selecting the arrangement position of the magnetic pole 23a and the fluidity and magnetic characteristics of the magnetic particles 27. It circulates to form a circulation layer 27c (see FIG. 1). In the circulation layer 27c, the magnetic particles relatively close to the developing sleeve 22 swell from the vicinity of the magnetic pole 23a to the downstream side of the developing sleeve by the rotation of the developing sleeve 22. That is, it receives the force of pushing it up. The magnetic particles pushed up fall by gravity, and the magnetic pole 23
a Return to the vicinity. That is, in the circulation layer 27c, the magnetic brush 27a of magnetic particles is circulated as indicated by an arrow c due to the magnetic force and frictional force due to gravity and magnetic poles and the fluidity (viscosity) of the magnetic particles. The non-magnetic developer 28 is successively taken from the developer layer above the particle layer and returned to the lower part inside the developer container 21, and this circulation is repeated as the developing sleeve 22 is rotationally driven. At this time, due to the influence of the magnetic member 51, compared with the case where the magnetic member 51 does not exist, the magnetic pole 23
Since the magnetic field of a tends to concentrate on the tip of the elastic blade 50, the holding force of the magnetic particles is increased at the tip position and the tribo imparting ability to the non-magnetic developer 28 is increased, and the tip of the elastic blade 50 having a magnetic member is provided. Therefore, the non-magnetic developer 28 is not directly taken in, and a good image without fog or sleeve ghost can be obtained. In addition, due to the influence of the magnetic field, the developing sleeve 22 is magnetically constrained at the tip of the elastic blade.
Since it is uniformly held in the longitudinal direction, the surface of the developing sleeve 22 can be coated with the nonmagnetic developer 28 evenly.

さらにまた、磁性部材51の端部を、非磁性弾性ブレード
50の自由端よりも、スリーブの回転方向に対して上流側
に突出させることにより、この循環をよくすることも可
能である。また、このように、磁性部材を配置すること
により、やはり弾性ブレードの先端25に非磁性現像剤28
が上方から直接取り込まれることがなくなり、カブリや
スリーブゴーストのない良好な画像を提供できる。ま
た、実験により上記磁性部材の突出長さl1は、1cm以下
好ましくは8mm以下でなければ、かえって上記循環が悪
くなり、磁性粒子の点25付近でのパッキングが強くなり
すぎて、非磁性ブレード50の機械的拘束力を増さなくて
はならず、この非磁性弾性ブレード50の設定条件を厳し
くするものであり好ましくない。
Furthermore, the end of the magnetic member 51 is connected to the non-magnetic elastic blade.
It is also possible to improve this circulation by projecting the sleeve 50 upstream of the free end in the rotational direction of the sleeve. Further, by disposing the magnetic member in this manner, the non-magnetic developer 28 is also attached to the tip 25 of the elastic blade.
Is not directly taken in from above, and a good image without fog or sleeve ghost can be provided. Further, according to the experiment, the protruding length l 1 of the magnetic member is not more than 1 cm, preferably not more than 8 mm, rather, the circulation becomes worse, the packing of the magnetic particles near the point 25 becomes too strong, and the non-magnetic blade. The mechanical restraining force of 50 must be increased, and the setting conditions of the non-magnetic elastic blade 50 become strict, which is not preferable.

現像スリーブ22面の磁性粒子層内に逐次に取込まれ混入
した非磁性現像剤は、磁性粒子の流動で磁性粒子との摩
擦、現像スリーブ面との摩擦等で帯電する。この場合、
好ましくは磁性粒子表面に酸化膜または非磁性現像剤と
静電的に同準位にある樹脂などの絶縁処理を施し、磁性
粒子からのトリボ付与を少なくし、必要な帯電を現像ス
リーブ22から受けるようにすれば、磁性粒子の劣化の影
響を防ぐことができるとともに、現像スリーブ22への現
像剤塗布が安定する。この帯電現像剤は非磁性であるた
め、磁極23aの磁界によっては拘束されず、現像スリー
ブ面が現像スリーブ22を配設した容器開口下縁の磁性部
材31の所から非磁性弾性ブレード50の自由端部まで回転
移動する間に、鏡映力によって現像スリーブ表面に各部
均一に薄くコーティングされる。
The non-magnetic developer that is sequentially taken into and mixed in the magnetic particle layer on the surface of the developing sleeve 22 is charged by friction with the magnetic particles due to the flow of the magnetic particles, friction with the developing sleeve surface, and the like. in this case,
Preferably, the surface of the magnetic particles is subjected to an insulation treatment such as an oxide film or a resin that is electrostatically in the same level as the non-magnetic developer to reduce tribo application from the magnetic particles and receive necessary charging from the developing sleeve 22. By doing so, it is possible to prevent the influence of the deterioration of the magnetic particles and stabilize the application of the developer to the developing sleeve 22. Since this charged developer is non-magnetic, it is not restricted by the magnetic field of the magnetic pole 23a, and the developing sleeve surface is free from the non-magnetic elastic blade 50 from the magnetic member 31 at the lower edge of the container opening where the developing sleeve 22 is arranged. While rotating and moving to the end, the surface of the developing sleeve is uniformly and thinly coated by the mirror force.

そして非磁性弾性ブレード50の自由端部近傍の磁性粒子
静止層27bの磁性粒子は、現像スリーブ22が回転してい
ても前述したように重力と磁気力及び磁性ブレード51の
存在による効果に基づく拘束力と、現像スリーブ22の移
動方向への搬送力との釣り合いによって拘束されて、非
磁性弾性ブレード50の自由端部と現像スリーブ22との隙
間部dを通過せず、現像スリーブ22面に形成された上記
非磁性現像剤のコーティング薄層のみが、現像スリーブ
22の回転に伴ない弾性ブレードと現像スリーブとの間d
を通過して潜像担持体3側に回動搬送され、該潜像担持
体の現像部32に接近対面し(第1図参照)、ここで現像
がなされる。
The magnetic particles in the magnetic particle stationary layer 27b near the free end of the non-magnetic elastic blade 50 are constrained by the effect of gravity and the magnetic force and the presence of the magnetic blade 51 as described above even when the developing sleeve 22 is rotating. Is constrained by the balance between the force and the conveying force in the moving direction of the developing sleeve 22, and does not pass through the gap d between the free end of the non-magnetic elastic blade 50 and the developing sleeve 22, and is formed on the surface of the developing sleeve 22. Only the coating thin layer of the above-mentioned non-magnetic developer is applied to the developing sleeve.
Between the elastic blade and the developing sleeve with the rotation of 22 d
After passing through, the toner is rotatably conveyed to the latent image carrier 3 side, approaches the developing unit 32 of the latent image carrier (see FIG. 1), and development is performed here.

かくして現像装置では、非磁性現像剤についてこれを現
像剤担持部材面に対し各部十分な帯電量を有しており、
均一な薄層とし長期にわたって安定にコーティング形成
させることができる。したがって、この薄い現像剤層に
より潜像担持面の潜像を鮮明にかつ解像性よく現像処理
することが可能となる。
Thus, in the developing device, each portion of the non-magnetic developer has a sufficient charge amount with respect to the surface of the developer carrying member,
It is possible to form a uniform thin layer and form a stable coating over a long period of time. Therefore, this thin developer layer makes it possible to develop the latent image on the latent image bearing surface clearly and with good resolution.

また非磁性現像剤は色彩の鮮やかなものを得ることがで
きるから、色再現性に優れた高品位のカラーコピー(単
色、多色、天然色)を得ることができる。
Further, since a non-magnetic developer having a vivid color can be obtained, it is possible to obtain a high-quality color copy (single color, multi-color, natural color) having excellent color reproducibility.

次に、第1図の現像装置についての具体例を説明する。
第1図において、現像剤担持体22として直径20mmのアル
ミスリーブの表面を、アランダム砥粒により不定型サン
ドブラスト処理したものを用い、磁石23としてN極、S
極の2極着磁され、N極は約750ガウスで第2図のごと
く、スリーブの中心Oを通る鉛直線mとのなす角αが95
゜となる位置に配置した。なお、上記磁石を1000ガウス
にすると第1図のc方向での循環は約2倍となった。
Next, a specific example of the developing device shown in FIG. 1 will be described.
In FIG. 1, as the developer carrying member 22, an aluminum sleeve having a diameter of 20 mm, the surface of which has been irregularly sandblasted with alundum abrasive grains, is used.
Two poles are magnetized, and the N pole is about 750 gauss and the angle α with the vertical line m passing through the center O of the sleeve is 95 as shown in FIG.
It was placed at a position where It should be noted that when the above magnet was set to 1000 gauss, the circulation in the direction c in FIG. 1 doubled.

非磁性弾性ブレード50は、2mm厚、硬度65゜のウレタン
ゴムを使用した。また、磁性部材51としては1mm厚の鉄
板に化学ニッケルメッキをしたものであり、鉄板の材質
として工業的に常用されるSPC鋼板、ケイ素鋼板、パー
マロイ等が望ましい。また、これら磁性体を接線方向の
磁界を強めるように着磁しても良い。この磁性部材51
は、非磁性弾性ブレード50の自由端から2mmの距離に第
1図のごとく設定されている。第1図の装置では、θ=
30゜とした(第2図参照)。
The non-magnetic elastic blade 50 is made of urethane rubber having a thickness of 2 mm and a hardness of 65 °. Further, the magnetic member 51 is a 1 mm thick iron plate plated with chemical nickel, and an SPC steel plate, a silicon steel plate, a permalloy or the like which is industrially commonly used as a material of the iron plate is preferable. Further, these magnetic bodies may be magnetized so as to strengthen the magnetic field in the tangential direction. This magnetic member 51
Is set at a distance of 2 mm from the free end of the non-magnetic elastic blade 50 as shown in FIG. In the device of FIG. 1, θ =
It was set at 30 ° (see Fig. 2).

また、磁性粒子としては、63〜44μm(250/350メッシ
ュ)で、表面にアクリルと弗素との混合樹脂を塗布した
フェライト粒子(最大磁化65emu/g)を用い、非磁性現
像剤として、スチレン/ブタジェン共重合体系樹脂100
部に銅フタロシアニン系顔料5部から成る平均粒径12μ
mのトナー粉体にコロイダルシリカ0.6%を外添したブ
ルートナーを用いたところ、スリーブ上にコーティング
厚約30〜50μm、ブローオフ法で測定したスリーブ上の
トナーのトリボ電荷量が+15μCoul/gの良好なコーティ
ングが得られた。
As magnetic particles, ferrite particles (maximum magnetization 65 emu / g) of 63 to 44 μm (250/350 mesh) coated with a mixed resin of acrylic and fluorine on the surface were used. Butadiene Copolymer Resin 100
Average particle diameter of 12μ consisting of 5 parts of copper phthalocyanine pigment
m toner powder with 0.6% colloidal silica added externally, the coating thickness on the sleeve was about 30-50 μm, and the tribo charge on the sleeve measured by the blow-off method was +15 μCoul / g. A good coating was obtained.

この実施例の現像装置を第1図においてバイアス電源34
として周波数1600Hz、ピーク対ピーク値1300Vの交流電
圧に−300Vの直流電圧を重畳させた複写機に用い、現像
スリーブ22とOPC感光体3の間隔を300μmに設定して現
像を行なったところ、良好なブルー色の画像を得た。
The developing device of this embodiment is shown in FIG.
As a result, it was used in a copying machine in which a DC voltage of -300V was superimposed on an AC voltage of frequency 1600Hz and a peak-to-peak value of 1300V, and development was performed by setting the distance between the developing sleeve 22 and the OPC photoconductor 3 to 300µm. I got a nice blue image.

本発明は、磁性部材に磁界発生手段を用いても有効的に
発揮できる。
The present invention can be effectively exhibited even when a magnetic field generating means is used for the magnetic member.

第3図は、その一実施例を示したものである。第3図に
おいて、52は磁界発生手段たる磁性部材であり、本実施
例では二極の永久磁石を用いている。第3図のごとく、
磁極23aのN極とは異極である磁極52aのS極側を、非磁
性弾性ブレード50の自由端側に配置することにより、磁
極23aと磁極52aとの間での磁界を、より強めることがで
き、これにより、点25付近での磁性粒子28の保持力及び
拘束力が増大される。したがって、非磁性現像剤27への
トリボ付与能力が高まり、非磁性弾性ブレード50の機械
的設定条件も緩和されることになる。
FIG. 3 shows an example thereof. In FIG. 3, reference numeral 52 is a magnetic member as a magnetic field generating means, and in this embodiment, a bipolar permanent magnet is used. As shown in Figure 3,
By arranging the S pole side of the magnetic pole 52a, which is different from the N pole of the magnetic pole 23a, on the free end side of the non-magnetic elastic blade 50, the magnetic field between the magnetic pole 23a and the magnetic pole 52a is further strengthened. Therefore, the holding force and the binding force of the magnetic particles 28 near the point 25 are increased. Therefore, the ability to apply tribo to the non-magnetic developer 27 is enhanced, and the mechanical setting conditions of the non-magnetic elastic blade 50 are alleviated.

また、弾性部材に金属薄板を用いてもよい。Alternatively, a thin metal plate may be used as the elastic member.

さらに、金属弾性部材を用いる場合は、金属弾性部材と
スリーブとの間の摺擦による摩耗が激しくなるので、金
属弾性部材のスリーブと圧接する面に軟弾性部材を用い
るのが好ましい。
Further, when a metal elastic member is used, it is preferable to use a soft elastic member on the surface of the metal elastic member that comes into pressure contact with the sleeve, because the abrasion due to the sliding friction between the metal elastic member and the sleeve becomes severe.

なお、前述の実施例では非磁性現像剤を用いたが、磁性
粒子に比べ著しく弱い磁性であり、トリボ帯電可能であ
れば磁性現像剤も用いることができる。
Although a non-magnetic developer was used in the above-mentioned examples, a magnetic developer can be used as long as the magnetic property is extremely weak as compared with the magnetic particles and tribo charging is possible.

また、現像剤容器が現像容器と一体化された使いすてタ
イプの現像器を例として現像剤の供給例を述べたが、こ
の点についても現像剤容器とは別体であって、交換可能
な補給用カートリッジにも本発明は適用することができ
る。また、現像方法としては、交互バイアス電界を利用
した非接触現像法が好ましいが、それ以外の公知の現像
方法を用いてもよい。
Also, an example of supplying the developer was described using a single-use type developing device in which the developer container is integrated with the developer container, but this point is also a separate body from the developer container and can be replaced. The present invention can be applied to various replenishment cartridges. Further, as the developing method, a non-contact developing method utilizing an alternating bias electric field is preferable, but other known developing methods may be used.

現像バイアスは周期的変位電界にかかわらず直流電界で
もよい。非磁性弾性ブレードは現像剤に対して所定の帯
電極性を与えるように現像剤と摩擦帯電列の離れた材質
を選択することが好ましい。また、非磁性弾性ブレード
の現像スリーブと対向する面を荒して表面に凹凸を設け
ることによってトナーへのトリボ付与をさらに向上させ
てもよい。さらに、現像スリーブ22内に配置した磁石23
は、実施例に示した、2極配置には限定されない。本発
明に係る磁性粒子の拘束に大きな影響を与えない範囲で
現像スリーブの回転方向に関して、磁極23bよりも上流
側に磁極を複数設置してもよい。これにより、弾性ブレ
ード部分から微小量で磁性粒子が漏れても、該磁性粒子
を現像容器内に回収できる。
The developing bias may be a DC electric field regardless of the periodic displacement electric field. For the non-magnetic elastic blade, it is preferable to select a material having a frictional charge line away from the developer so as to give a predetermined charge polarity to the developer. Further, the surface of the non-magnetic elastic blade facing the developing sleeve may be roughened to provide irregularities on the surface to further improve tribo imparting to the toner. Further, a magnet 23 arranged in the developing sleeve 22
Is not limited to the two-pole arrangement shown in the embodiment. A plurality of magnetic poles may be provided on the upstream side of the magnetic pole 23b in the rotation direction of the developing sleeve within a range that does not significantly affect the restraint of the magnetic particles according to the present invention. Thus, even if a small amount of magnetic particles leak from the elastic blade portion, the magnetic particles can be collected in the developing container.

(発明の効果) 以上説明したように、本発明によれば簡単な構成の磁性
弾性ブレードを使用することにより磁性粒子を使用する
現像装置において、磁性粒子の拘束性と安定かつ均一な
循環性を得ることができ、さらに、少なくとも弾性ブレ
ード自由端部と磁性部材を設けたことにより、この磁性
部材と現像スリーブ内磁極との間で発生する磁界の影響
により、磁性粒子に対する拘束力が増し磁性粒子弾性ブ
レード当接部付近に均一多量に保持できることとなり、
現像剤へのトリボ付与能力が高まり、その結果、少量の
磁性粒子を使用して、均一な層厚と均一で十分な帯電量
を有する現像剤薄層が長期にわたって安定して得られる
という効果をもたらす。その際、上記磁性部材は、磁界
発生手段の、現像剤担持体移動方向に関し、弾性板の自
由端より上流側の磁極との間に磁性粒子を拘束する磁界
を形成するので、磁性粒子が前述のごとく弾性板自由端
と現像剤担持体間の隙間に詰まってしまうことを防止し
長期間にわたって非磁性現像剤の均一は薄層の形成を可
能にする。特に、微粒子(10μm以下の粒径)の非磁性
トナーにおいても同様の効果を得ることができる。ま
た、上記現像剤薄層を現像作用に供したとき、安定した
現像画像を長期にわたって得ることが可能となる。特に
振動等が加わっても、漏れずに現像容器内に磁性粒子を
拘束することができるようになる。
(Effects of the Invention) As described above, according to the present invention, in a developing device using magnetic particles by using a magnetic elastic blade having a simple structure, the magnetic particles can be restrained and stably and uniformly circulated. Further, by providing at least the elastic blade free end and the magnetic member, the binding force to the magnetic particles is increased due to the influence of the magnetic field generated between the magnetic member and the magnetic pole in the developing sleeve. A large amount can be held near the elastic blade contact part,
The effect of imparting tribo to the developer is enhanced, and as a result, a small amount of magnetic particles is used, and a thin developer layer having a uniform layer thickness and a sufficient charge amount can be stably obtained over a long period of time. Bring At that time, since the magnetic member forms a magnetic field for restraining the magnetic particles between the magnetic field generating means and the magnetic pole on the upstream side of the free end of the elastic plate in the moving direction of the developer carrier, the magnetic particles are As described above, the gap between the free end of the elastic plate and the developer carrying member is prevented from being clogged, and the nonmagnetic developer can be uniformly formed over a long period of time to form a thin layer. In particular, the same effect can be obtained with a non-magnetic toner of fine particles (particle diameter of 10 μm or less). Further, when the thin developer layer is subjected to the developing action, it becomes possible to obtain a stable developed image for a long period of time. In particular, even if vibration or the like is applied, the magnetic particles can be restrained in the developing container without leaking.

さらに、上記非磁性弾性部材によって現像スリーブ上の
非磁性現像剤は十分摺擦され均一なかつ安定したトリボ
付与が行なわれるので、6〜20mmの外径寸法の現像スリ
ーブを用いても良好な画像を得ることができる。
Furthermore, since the non-magnetic developer on the developing sleeve is sufficiently rubbed by the non-magnetic elastic member to impart a uniform and stable tribo, a good image can be obtained even if a developing sleeve having an outer diameter of 6 to 20 mm is used. Obtainable.

かかる効果のもとに、非磁性現像剤を用いて鮮明なカラ
ー画像を形成することが可能となる。
Based on such an effect, it becomes possible to form a clear color image using a non-magnetic developer.

また、弾性体で現像スリーブ上のトナーを摺擦するた
め、弾性体によるトナーへのトリボ付与が行なわれ、そ
の分だけ磁性粒子によるトナーへのトリボ付与作用を軽
減できる。このため現像器内に投入する磁性粒子を少量
に減らすことができ、実施例の5分の1まで減らしても
ほぼ良好な画像が得られる。
Further, since the toner on the developing sleeve is rubbed by the elastic body, the tribo is imparted to the toner by the elastic body, and the tribo imparting effect to the toner by the magnetic particles can be reduced accordingly. Therefore, the amount of magnetic particles charged into the developing device can be reduced to a small amount, and a substantially good image can be obtained even if it is reduced to 1/5 of that in the embodiment.

【図面の簡単な説明】[Brief description of drawings]

第1図は本発明の現像装置の断面図、第2図は第1図装
置の現像スリーブと磁性弾性ブレード部分の拡大断面
図、第3図は本発明の現像装置の他の実施例の弾性ブレ
ードに磁性部材として磁石を用いた場合の断面図であ
る。 21……現像剤容器 22……現像剤保持部材(現像スリーブ) 23……磁界発生手段(磁石) 50……現像剤拘束部材(弾性ブレード) 51……磁性部材
1 is a sectional view of a developing device of the present invention, FIG. 2 is an enlarged sectional view of a developing sleeve and a magnetic elastic blade portion of the device of FIG. 1, and FIG. 3 is an elasticity of another embodiment of the developing device of the present invention. It is sectional drawing at the time of using a magnet as a magnetic member for a blade. 21 …… Developer container 22 …… Developer holding member (developing sleeve) 23 …… Magnetic field generating means (magnet) 50 …… Developer restraining member (elastic blade) 51 …… Magnetic member

───────────────────────────────────────────────────── フロントページの続き (56)参考文献 特開 昭62−96979(JP,A) 特開 昭61−175664(JP,A) 特開 昭62−234175(JP,A) 特開 昭57−78064(JP,A) 特開 昭61−86772(JP,A) 特開 昭62−59049(JP,A) ─────────────────────────────────────────────────── ─── Continuation of front page (56) Reference JP 62-96979 (JP, A) JP 61-175664 (JP, A) JP 62-234175 (JP, A) JP 57- 78064 (JP, A) JP 61-86772 (JP, A) JP 62-59049 (JP, A)

Claims (1)

【特許請求の範囲】[Claims] 【請求項1】非磁性現像剤と磁性粒子とを収容した現像
剤容器の開口に設けられ、該現像剤容器の内部と外部と
を無端運動可能な現像剤担持体と、 上記現像剤担持体内部に設けられた磁界発生手段と、 現像剤担持体に当接されており、磁性粒子の通過は阻止
し、非磁性現像剤は通過させて現像剤担持体表面に非磁
性現像剤層を形成する磁性粒子拘束手段と、 を備えた現像装置において、 上記磁性粒子拘束手段は、自由端と現像剤担持体との間
に上記磁性粒子の平均粒径よりも小なる間隙が形成され
るようにして、自由端近傍の腹の面が現像剤担持体に当
接さた非磁性弾性板であって、この当接部から固定端部
までの腹の面と現像担持体表面との間隙が現像剤担持体
移動方向に増大して行くように配設された非磁性弾性板
と、この弾性板の少なくとも自由端部の、上記腹の面と
の面とは反対側の面に設けられ、上記磁界発生手段の、
現像剤担持体移動方向に関し、弾性板自由端よりも上流
側に位置する磁極との間に磁性粒子を拘束する磁界を形
成する磁性部材とを有することを特徴とする現像装置。
1. A developer carrier provided in an opening of a developer container containing a non-magnetic developer and magnetic particles and capable of endless movement between the inside and the outside of the developer container, and the developer carrier. The magnetic field generating means provided inside is in contact with the developer carrying member, which blocks the passage of magnetic particles and allows the nonmagnetic developer to pass therethrough to form a nonmagnetic developer layer on the surface of the developer carrying member. In the developing device, the magnetic particle restraining means is configured such that a gap smaller than the average particle diameter of the magnetic particles is formed between the free end and the developer carrier. The non-magnetic elastic plate whose abdominal surface near the free end is in contact with the developer carrier, and the gap between the abdominal surface from this abutting part to the fixed end and the surface of the developer carrier is A non-magnetic elastic plate arranged so as to increase in the moving direction of the agent carrier, and a small number of these elastic plates. At least the free end portion, which is provided on the surface opposite to the surface with the antinode surface, of the magnetic field generating means,
A developing device comprising: a magnetic member that forms a magnetic field that restrains magnetic particles between a magnetic pole located upstream of the free end of the elastic plate in the moving direction of the developer carrier.
JP62277347A 1987-11-04 1987-11-04 Development device Expired - Fee Related JPH07122764B2 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
JP62277347A JPH07122764B2 (en) 1987-11-04 1987-11-04 Development device
US07/266,810 US4876574A (en) 1987-11-04 1988-11-03 Developing apparatus

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP62277347A JPH07122764B2 (en) 1987-11-04 1987-11-04 Development device

Publications (2)

Publication Number Publication Date
JPH01120581A JPH01120581A (en) 1989-05-12
JPH07122764B2 true JPH07122764B2 (en) 1995-12-25

Family

ID=17582260

Family Applications (1)

Application Number Title Priority Date Filing Date
JP62277347A Expired - Fee Related JPH07122764B2 (en) 1987-11-04 1987-11-04 Development device

Country Status (1)

Country Link
JP (1) JPH07122764B2 (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1999010933A1 (en) 1997-08-21 1999-03-04 Kaneka Corporation Thin film photoelectric transducer
EP2749608A1 (en) 2012-12-27 2014-07-02 Guardian Industries Corp. Anti-reflection coatings with self-cleaning properties, substrates including such coatings, and related methods
EP2752386A1 (en) 2012-12-13 2014-07-09 Guardian Industries Corp. Method of making coated article including anti-reflection coating with porosity differences in two layers, and products containing the same

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4845659B2 (en) * 2006-09-22 2011-12-28 三星電子株式会社 Development device

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5778064A (en) * 1980-11-01 1982-05-15 Ricoh Co Ltd Developing apparatus
JPS6186772A (en) * 1984-10-04 1986-05-02 Canon Inc Device for forming thin layer of developing agent
JPS61175664A (en) * 1985-01-30 1986-08-07 Canon Inc Forming device for thin film of developer
JPH0619638B2 (en) * 1985-10-24 1994-03-16 キヤノン株式会社 Thin developer layer forming device
JPS62234175A (en) * 1986-04-04 1987-10-14 Konika Corp Developing device

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1999010933A1 (en) 1997-08-21 1999-03-04 Kaneka Corporation Thin film photoelectric transducer
EP2752386A1 (en) 2012-12-13 2014-07-09 Guardian Industries Corp. Method of making coated article including anti-reflection coating with porosity differences in two layers, and products containing the same
EP2749608A1 (en) 2012-12-27 2014-07-02 Guardian Industries Corp. Anti-reflection coatings with self-cleaning properties, substrates including such coatings, and related methods

Also Published As

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