JPH0711199Y2 - Patterned coated paper - Google Patents
Patterned coated paperInfo
- Publication number
- JPH0711199Y2 JPH0711199Y2 JP1986080087U JP8008786U JPH0711199Y2 JP H0711199 Y2 JPH0711199 Y2 JP H0711199Y2 JP 1986080087 U JP1986080087 U JP 1986080087U JP 8008786 U JP8008786 U JP 8008786U JP H0711199 Y2 JPH0711199 Y2 JP H0711199Y2
- Authority
- JP
- Japan
- Prior art keywords
- oil
- pattern
- coated paper
- coating layer
- pigment
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Description
【考案の詳細な説明】 （産業上の利用分野） 本考案は、印刷、包装等に使用される鮮明な滲みのない
模様、文字等を付した美粧な模様入り塗被紙に関するも
のである。DETAILED DESCRIPTION OF THE INVENTION (Industrial field of application) The present invention relates to a coated paper with a beautiful pattern, which is used for printing, packaging, etc., with a clear pattern without blurring, characters and the like.
（従来の技術） 従来より、模様や文字を紙、板紙に付与することは、抄
紙工程において繊維の密度を変えること、いわゆる透か
し模様等を形成させたり、透明化する薬品を印刷機等で
塗布してパルプ繊維層内に浸透せしめ、模様や文字を形
成させたり、更には印刷インキを用いて模様や文字を
紙、板紙の表面に印刷する等の方法によりおこなわれて
きた。更に近時、印刷用紙、包装用紙として用いられて
いる塗被紙（塗被板紙を含む）において、塗被層に着色
顔料等を加えて着色し、光沢を付した美粧な塗被紙が供
給されるようになり、その上、塗被層に模様や文字等を
付すことが要求されるようになってきたが、塗被紙の塗
被層内に凹凸等機械的に模様、文字等を付するか、周知
技術である印刷インキによる印刷によって模様や文字を
付することしか行なわれていないのが現状である。(Prior art) Conventionally, applying patterns and characters to paper and paperboard involves changing the density of fibers in the papermaking process, forming a so-called watermark pattern, and applying chemicals that make transparent with a printing machine or the like. Then, it is permeated into the pulp fiber layer to form a pattern or a letter, and further, the pattern or the letter is printed on the surface of paper or paper board by using a printing ink. More recently, coated papers (including coated paperboards) used as printing papers and wrapping papers have been colored by adding coloring pigments to the coating layer to provide a glossy and beautiful coated paper. In addition, it has become necessary to add patterns and letters to the coating layer.However, mechanical patterns, letters, etc., such as irregularities, are formed in the coating layer of coated paper. At present, it is only performed to add a pattern or a character by printing or printing with a known printing ink.
（考案が解決しようとする問題点） 本考案は、塗被紙において、塗被層に模様や文字を必要
に応じて付与し、光沢を損なわせず、かつ凹凸を付する
ことなく、鮮明で滲み無く、模様や文字を付した美粧な
模様入り塗被紙を提供することを目的とするものであ
る。(Problems to be solved by the invention) The present invention provides a coated paper with a pattern or a character as needed, so that the gloss is not impaired and the surface is clear without unevenness. It is an object of the present invention to provide a coated paper having a beautiful pattern with a pattern and characters without bleeding.
（問題を解決するための手段） 本考案は、かかる要望に答えるべくなさせたものであ
る。本考案に使用される塗被紙は、紙、板紙等の基材の
表面に顔料を主成分とした塗被層を設けたもので、該塗
被層はカオリナイト、セリサイト、パイロフイライト等
のクレー、二酸化チタン、炭酸カルシウム、硫酸バリウ
ム等の無機質の顔料より選択された少なくとも１種の顔
料が約70〜80重量％含有されており、その無機質の顔料
により光を屈折、反射させ、白色、不透明の塗被層を形
成するもので、必要あれば着色顔料や染料を塗料に配合
し着色塗被層を形成せしめてなるものである。尚。ポリ
エチレン等よりなる有機質の顔料を配合せるもさしつか
えない、又、該顔料の接着剤としてカゼイン、澱粉、熱
可塑性樹脂、合成ゴム系ラテツクス等より選択された１
種以上の接着剤が使用される。この塗被紙の塗被層、即
ち、接着剤内に浸透する物質を模様状又は文字状に塗被
層面に塗被し浸透せしめ、塗被層内に保有させ、顔料の
持つ光の屈折率、反射率を変化させ、或いは接着剤等の
光の透過率を変化させ模様を発現させるこにより解決し
たものである。この塗被層内に浸透して顔料の光の屈折
率、反射率を変化させ、或いは接着剤等の光の透過率を
変化させる共に、浸透後分散して滲むことなく鮮明な模
様を形成し、かつ光沢を損なわない物質を種々検討せる
結果、特に油脂類が良好な結果を得、その他界面活性
剤、水溶性もしくは溶剤可溶性の樹脂が使用出来ること
が判り、本考案を完成にするに至ったものである。油脂
類の内、植物油としては、大豆油、菜種油、胡麻油、ひ
まし油等より選択された１種または数種の混合油、酸化
物、塩類、金属石鹸等を加えて変性した大豆油等のボイ
ル油、及びあまに油、大豆油、きり油等を加熱処理して
増粘させた油ワニスが良好な結果が得られた。鉱物油と
しては沸点の高い石油系の潤滑油等も使用出来る。又、
界面活性剤としては、ポリオキシエチレンノニルフエニ
ールエーテル、ポリオキシエチレンラウリルエーテル硫
酸塩、ソルビタンラウレート、ジエチレングリコール等
が良好であり、樹脂としては水、油、溶剤の何れかに可
溶のロジン、エステルガム、フエノール、アルキド、メ
ラミン、ビニル、ポリアミド等が良好であり、その他、
硝化綿、ポリビニルアルコール、澱粉、環化ゴム等の溶
剤も使用出来る。(Means for Solving the Problem) The present invention has been made to meet such a demand. The coated paper used in the present invention comprises a substrate, such as paper or paperboard, on the surface of which a coating layer containing a pigment as a main component is provided, and the coating layer is kaolinite, sericite or pyrophyllite. About 70 to 80% by weight of at least one pigment selected from clay, titanium dioxide, calcium carbonate, barium sulfate, and other inorganic pigments is contained, and the inorganic pigment refracts and reflects light, A white and opaque coating layer is formed, and if necessary, a coloring pigment or dye is mixed in the coating material to form a colored coating layer. still. An organic pigment such as polyethylene may be blended, and the adhesive for the pigment may be selected from casein, starch, thermoplastic resin, synthetic rubber-based latex, etc. 1
More than one adhesive is used. The coated layer of this coated paper, that is, the substance penetrating into the adhesive is applied to the surface of the coated layer in a pattern or in a letter form so that the substance permeates and is retained in the coated layer. The problem is solved by changing the reflectance or changing the light transmittance of an adhesive or the like to develop a pattern. It penetrates into this coating layer to change the light refractive index and reflectance of the pigment, or changes the light transmittance of the adhesive, etc., and after dispersion penetrates to form a clear pattern without bleeding. As a result of various studies on substances that do not impair the gloss, particularly good results were obtained for fats and oils, and it was found that other surfactants, water-soluble or solvent-soluble resins could be used, and the present invention was completed. It is a thing. Among the oils and fats, as vegetable oil, one or several kinds of mixed oil selected from soybean oil, rapeseed oil, sesame oil, castor oil, etc., boiled oil such as soybean oil modified by adding oxides, salts, metal soaps, etc. , And the oil varnish obtained by thickening linseed oil, soybean oil, cutting oil, etc. by heat treatment gave good results. As the mineral oil, a petroleum-based lubricating oil having a high boiling point can be used. or,
As the surfactant, polyoxyethylene nonylphenyl ether, polyoxyethylene lauryl ether sulfate, sorbitan laurate, diethylene glycol and the like are preferable, and as the resin, water, oil, a rosin soluble in any solvent, Ester gum, phenol, alkyd, melamine, vinyl, polyamide, etc. are good, and others,
Solvents such as nitrified cotton, polyvinyl alcohol, starch and cyclized rubber can also be used.
（作用） 紙、板紙等の基材の表面に、無機質等の顔料を主成分と
した塗料により、白色又は着色塗被層を塗被紙におい
て、塗被層内に模様状に保有せしめた浸透する物質は、
塗被層内の顔料および接着剤等の光の屈折率、反射率、
透過率等を変化せしめ、模様を出現せしめる作用を有す
る。(Function) Permeation of a white or colored coating layer coated on the surface of a substrate such as paper or paperboard with a coating material containing a pigment such as an inorganic substance in a pattern in the coating layer. The substance
Refractive index of light such as pigment and adhesive in the coating layer, reflectance,
It has the effect of changing the transmittance and the like to make a pattern appear.
（実施例） 本考案の実施例を以下に示すが、図面に示す如く、紙、
板紙等の基材（１）の表面に設けた塗被層（２）に油脂
類等塗被層に浸透する物質を保有せしめ模様部（３）を
形成せしめたものである。(Embodiment) An embodiment of the present invention will be described below.
A coating layer (2) provided on the surface of a substrate (1) such as paperboard is provided with a pattern portion (3) for holding a substance such as oils and fats that permeates the coating layer.
実施例１ 製紙用木材パルプを原料として抄造した坪量約100g/m2
の紙を基材とし、下記組成を有する塗料を基材の表面に
固形分として約25g/m2なるように塗被し、塗被層面を鏡
面仕上げをしたキャストドラムに密着させながら乾燥せ
しめて得た強光沢着色塗被紙を用い、植物油としてあま
に油、大豆油、しなきり油、菜種油、胡麻油、綿実油、
オリーブ油、ひまし油、ボイル油として大豆油、油ワニ
スとしてあまに油、鉱物油として石油系の潤滑油の一種
であるマシン油１号、流動パラフイン１号、スピンドル
油等を第２図に示す如く塗被層表面に模様を形成するよ
うに塗被、浸透させ、保有せしめた結果、表１に示す如
く、滲み無く、表面光沢も損なわない浸透性の物質とし
て、大豆油、菜種油、胡麻油、ひまし油、ボイル油の大
豆油、油ワニスのあまに油、鉱物油のマシン油１号等が
良好な結果を示した。Example 1 Paper-making wood pulp was used as a raw material for papermaking. The basis weight was about 100 g / m 2.
As a base material, a coating material having the following composition is coated on the surface of the base material so that the solid content is about 25 g / m 2 , and the coated layer surface is dried while being in close contact with a cast drum having a mirror finish. Using the obtained strong gloss colored coated paper, linseed oil, soybean oil, sesame oil, rapeseed oil, sesame oil, cottonseed oil as vegetable oil,
Olive oil, castor oil, soybean oil as boil oil, linseed oil as oil varnish, machine oil No. 1 which is a kind of petroleum-based lubricating oil as mineral oil, fluid paraffin No. 1, spindle oil, etc. are applied as shown in FIG. As shown in Table 1, as a penetrative substance that does not bleed and does not impair the surface gloss, soybean oil, rapeseed oil, sesame oil, castor oil, Boiled oil soybean oil, oil varnish linseed oil, and mineral oil machine oil No. 1 showed good results.
尚、何れの製品も、普通インキにより印刷を行なうも、
浸透、保有せしめた物質を有する模様部にも支障なく印
刷することが出来た。In addition, all products are printed with ordinary ink,
It was possible to print on the pattern part containing the permeated and retained substance without any trouble.
塗料組成 顔料 クレー 90％ 二酸化チタン 10％ 接着剤外 SBR 13％ カゼイン ７％ ステアリン酸アンモニウム １％ アンモニア １％ トリブチルサルフエート 0.5％ グリーン顔料 ２％ ブルー顔料 0.5％ 注１ 何れも重量百分率にて示す。Coating composition Pigment Clay 90% Titanium dioxide 10% Non-adhesive SBR 13% Casein 7% Ammonium stearate 1% Ammonia 1% Tributyl sulphate 0.5% Green pigment 2% Blue pigment 0.5% Note 1 All are shown as percentage by weight.
注２ 接着剤外は、顔料に対する重量百分率で示す。 Note 2: Outside the adhesive, it is shown as a percentage by weight with respect to the pigment.
注３ SBRは、スチレンブタンジエンラバーラテツク
スの略号である。Note 3 SBR is an abbreviation for styrene butane diene rubber latex.
以下、表２、表４においても同様である。 The same applies to Tables 2 and 4 below.
実施例２ 製紙用木材パルプを主原料として抄造した坪量250g/m2
の板紙を基材として下記組成の塗料を約20g/m2塗被して
実施例１と同様にして得た光沢のある塗被層を赤色に着
色した塗被板紙を用い、界面活性剤としてポリオキシエ
チレンノニルフエニールエーテル、ソルビタンラウレー
ト、ジエチレングリコール、ポリオキシエチレンラウリ
ルエーテル硫酸塩、アルフアオレフインスルホン酸ナト
リウム等を水に溶解し、実施例１同様、模様状に塗布，
塗被層に浸透、保有せしめた結果は表２に示すとおり、
ポリオキシエチレンノニルフエノールエーテル、ソルビ
タンラウレート、ジエチレングリコール、ポリオキシエ
チレンラウリルエーテル硫酸塩、アルフアオレフインス
ルホン酸ナトリウムが良好な結果が得られた。Example basis weight of 250 g / m 2 was papermaking 2 papermaking wood pulp as the main raw material
Paperboard coating having the following composition to about 20 g / m 2 coated with with coated paperboard colored coating layer red glossy obtained in the same manner as in Example 1 as a base material, as a surfactant Polyoxyethylene nonylphenyl ether, sorbitan laurate, diethylene glycol, polyoxyethylene lauryl ether sulphate, sodium alfaolephine sulfonate, etc. were dissolved in water and coated in a pattern as in Example 1.
The results of permeating and retaining the coated layer are as shown in Table 2.
Good results were obtained with polyoxyethylene nonylphenol ether, sorbitan laurate, diethylene glycol, polyoxyethylene lauryl ether sulphate and sodium alfaolephine sulfonate.
塗料組成 顔料 クレー 90％ 炭酸カルシウム 10％ 接着剤外 ポリアクリル酸ナトリウム 0.2％ カゼイン ６％ アンモニア 1.2％ MBR 14％ レツド顔料 ３％ ステアリン酸アンモニウム １％ 注１ 何れも重量百分率で示す。Coating composition Pigment Clay 90% Calcium carbonate 10% Non-adhesive Sodium polyacrylate 0.2% Casein 6% Ammonia 1.2% MBR 14% Red pigment 3% Ammonium stearate 1% Note 1 All are shown as weight percentage.
注２ 接着剤外は顔料に対する重量百分率で示す。 Note 2: Outside the adhesive, the percentage by weight relative to the pigment is shown.
注３ MBRは、メチルメタアクリレートブタジエンラ
バーラテツクスの略号である。Note 3 MBR is an abbreviation for methyl methacrylate butadiene rubber latex.
実施例３ 実施例１に用いたと同じ強光沢着色塗被紙を用い、メチ
ロールメラミン、ロジン変性フエノール、エポキシ系ポ
リアミドの樹脂類の外、硝化綿、エステル化澱粉、コー
ンスターチ等をそれぞれ表３に示す配合により浸透液と
して調整し、実施例１と動揺に保有せしめた結果を表４
にまとめた。 Example 3 Using the same strongly glossy colored coated paper as used in Example 1, Table 3 shows methylol melamine, rosin-modified phenol, epoxy polyamide resins, nitrified cotton, esterified starch, corn starch, etc., respectively. Table 4 shows the results obtained by adjusting the composition as a penetrating liquid and keeping it in Example 1 and shaking.
Summarized in.
結果は表４に示すとおり、澱粉類は模様の発現が薄く光
沢もやや損なう傾向が有ったが、その他メチロールメラ
ミン、ロジン変性フエノール、エポキシ系ポリアミド、
硝化綿等を用いた浸透液は良好であった。 The results are shown in Table 4, and the starches tended to have a weak pattern and a slight loss of gloss, but in addition to these, methylol melamine, rosin-modified phenol, epoxy-based polyamide,
The penetrant using nitrification cotton was good.
（結果） 以上述べた如く、本考案の模様入り塗被紙は、従来、印
刷等でしか模様を形成させることがなかった光沢のある
塗被紙において、塗被層内に浸透する油脂等の物質を模
様状、文字状に保有せしめることにより滲みのない模様
を形成せしめ、特に着色塗被層を有する美粧な塗被紙等
に濃色の滲みのない鮮明な模様、文字を形成させ、より
美粧な模様入り塗被紙を提供出来るのである。(Results) As described above, the patterned coated paper of the present invention is a glossy coated paper which has conventionally been formed only by printing or the like. By holding the substance in a pattern or character, a pattern without bleeding can be formed, and in particular, on a beautifully coated paper having a colored coating layer, a clear pattern without dark bleeding, characters can be formed. It is possible to provide a coated paper with a beautiful pattern.
図面は本考案の実施例をしめすもので、第１図は模様入
り塗被紙の模様部の部分断面図、第２図は模様入り塗被
紙の斜視図を示す。 １……基材、２……塗被層、３……模様部。The drawings show an embodiment of the present invention. FIG. 1 is a partial sectional view of a pattern portion of a patterned coated paper, and FIG. 2 is a perspective view of the patterned coated paper. 1 ... Substrate, 2 ... Coating layer, 3 ... Pattern.
───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.6 識別記号 庁内整理番号 ＦＩ 技術表示箇所 7199−3Ｂ Ｄ２１Ｈ 1/36 ─────────────────────────────────────────────────── ─── Continuation of the front page (51) Int.Cl. 6 Identification code Office reference number FI technical display location 7199-3B D21H 1/36
Claims (1)
ナイト、セリサイト、パイロフイライト等のクレー、二
酸化チタン、炭酸カルシウム、硫酸バリウム等の無機質
の顔料より選ばれた少なくとも１種の顔料を約70〜80重
量％含有した塗被層（２）を設けた塗被紙において、塗
被層内に浸透する油脂等の物質を鮮明な模様状または文
字状に保有してなる模様部（３）を有する模様入り塗被
紙。1. At least one selected from clays such as kaolinite, sericite and pyrophyllite, and inorganic pigments such as titanium dioxide, calcium carbonate and barium sulfate on the surface of a substrate (1) such as paper and paperboard. In a coated paper provided with a coating layer (2) containing about 70 to 80% by weight of one pigment, a substance such as oil or fat that penetrates into the coating layer is retained in a clear pattern or letter. Coated paper having a pattern portion (3) that is
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1986080087U JPH0711199Y2 (en) | 1986-05-27 | 1986-05-27 | Patterned coated paper |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1986080087U JPH0711199Y2 (en) | 1986-05-27 | 1986-05-27 | Patterned coated paper |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS62191429U JPS62191429U (en) | 1987-12-05 |
| JPH0711199Y2 true JPH0711199Y2 (en) | 1995-03-15 |
Family
ID=30930568
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP1986080087U Expired - Lifetime JPH0711199Y2 (en) | 1986-05-27 | 1986-05-27 | Patterned coated paper |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0711199Y2 (en) |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS55156050A (en) * | 1979-05-23 | 1980-12-04 | Noda Plywood Mfg Co Ltd | Dressing material and its preparation |
| JPS5617263A (en) * | 1979-07-24 | 1981-02-19 | Noda Plywood Mfg Co Ltd | Dressing materiaal and its manufacture |
| JPS58162342A (en) * | 1982-03-20 | 1983-09-27 | 永大産業株式会社 | Manufacture of decorative material |
| JPS58199185A (en) * | 1982-05-17 | 1983-11-19 | Mishima Seishi Kk | Water image sheet and preparation thereof |
-
1986
- 1986-05-27 JP JP1986080087U patent/JPH0711199Y2/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| JPS62191429U (en) | 1987-12-05 |
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