JPH07101821A - Antibacterial cosmetic - Google Patents
Antibacterial cosmeticInfo
- Publication number
- JPH07101821A JPH07101821A JP26947393A JP26947393A JPH07101821A JP H07101821 A JPH07101821 A JP H07101821A JP 26947393 A JP26947393 A JP 26947393A JP 26947393 A JP26947393 A JP 26947393A JP H07101821 A JPH07101821 A JP H07101821A
- Authority
- JP
- Japan
- Prior art keywords
- antibacterial
- oxide
- cosmetic
- silver
- metal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
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- Cosmetics (AREA)
Abstract
Description
【０００１】[0001]
【産業上の利用分野】本発明は、抗菌性組成物を配合し
た抗菌性化粧料、詳しくは雑菌が繁殖せず、保存性にす
ぐれ、皮膚刺激のない安全で使用し易い抗菌性化粧料に
関するものである。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an antibacterial cosmetic composition containing an antibacterial composition, and more particularly to an antibacterial cosmetic composition which is free from the proliferation of germs, excellent in storability, safe against skin irritation and easy to use. It is a thing.
【０００２】[0002]
【従来の技術】化粧料は水分や栄養分に富んでおり、微
生物が繁殖し易い、更に使用者が使用の度に少量づつ取
出すため、大気中の微生物で汚染され、又使用者の指か
らそれらが混入される可能性も大きい。これらの汚染に
対し、化粧料には防腐剤が配合されている。防腐剤とし
てカチオン活性剤、フエノール類、ソルビタン酸類、サ
ルチル酸、デヒドロ酢酸、安息香酸及びそれらの塩など
の有機系防腐剤が使用され、特にパラオキシ安息香酸エ
ステル類が汎用されている。然しながら、これらの有機
系防腐剤は、耐性菌を生じたり、規定量の添加では充分
に微生物の繁殖を防止することができなかったりし、又
多量に添加したり、強い効力の物質を使用したりすると
皮膚に対し悪影響を顕わす。2. Description of the Related Art Cosmetics are rich in water and nutrients, and microorganisms are easily propagated. Further, since the user takes out a small amount each time they are used, they are contaminated with microorganisms in the atmosphere, and they are also removed from the user's finger. It is highly possible that the Antiseptic agents have been added to cosmetics to counter these contaminations. As preservatives, cationic preservatives, organic preservatives such as phenols, sorbitan acids, salicylic acid, dehydroacetic acid, benzoic acid and salts thereof are used, and paraoxybenzoic acid esters are widely used. However, these organic preservatives produce resistant bacteria, or cannot sufficiently prevent the growth of microorganisms by adding a prescribed amount, or add a large amount, or use a substance having a strong effect. If it does, it will have an adverse effect on the skin.
【０００３】これら有機系防腐剤の欠点を補うため、最
近無機系抗菌剤の化粧料への配合が考えられている。例
えば、特開昭６０−１７８８１０号公報は、頭髪化粧料
に抗菌性ゼオライトの使用を提案している。然しなが
ら、抗菌性ゼオライトは皮膚刺激が強く、実用しにくい
という問題がある。この点を改良し、特開平１−３０５
０１３号公報は、アミノ珪酸酸系抗菌剤の化粧料用防腐
剤を提案しているが、その製造が複雑であるという欠点
がある。又特開平４−３６２２０号公報は、無機オキソ
酸塩を抗菌性金属イオンでイオン交換してえられた塩を
配合した抗菌性化粧料を、特開平５−１５５７３３号公
報はＭ1 a Ａb Ｍ2 c （PO4)4 ・nH2Oで示される抗菌性
燐酸塩を化粧料に配合することを提案している。これら
無機抗菌剤は抗菌力が強く、微量で広範囲の微生物に効
果を有するが、その製造に手間がかかったり、長時間の
間には抗菌性金属イオンが遊離し、化粧料の変色を生じ
たり、皮膚に思わぬ障害を及ぼしたりする可能性があ
る。このように有機系及び無機系抗菌剤の化粧料への配
合は、現状では万全とは云えない。In order to make up for the drawbacks of these organic antiseptics, the incorporation of inorganic antibacterial agents into cosmetics has recently been considered. For example, JP-A-60-178810 proposes the use of antibacterial zeolite in hair cosmetics. However, there is a problem that antibacterial zeolite has strong skin irritation and is difficult to put into practical use. This point has been improved, and JP-A-1-305
Japanese Patent No. 013 proposes an aminosilicic acid antibacterial agent as a preservative for cosmetics, but it has a drawback that its production is complicated. Matatoku No. 4-36220 Patent Publication No., the inorganic oxo acid salt antibacterial metal ions blended salt was E by ion-exchange antimicrobial cosmetic, JP-A-5-155733 is M 1 a A b It has been proposed to incorporate an antibacterial phosphate represented by M 2 c (PO 4 ) 4 · nH 2 O into cosmetics. These inorganic antibacterial agents have a strong antibacterial activity and are effective in a wide range of microorganisms even in a trace amount, but it takes time to manufacture them, and antibacterial metal ions are released during a long time, causing discoloration of cosmetics. , May cause unexpected damage to the skin. Thus, at present, it cannot be said that the addition of organic and inorganic antibacterial agents to cosmetics is perfect.
【０００４】一方化粧料には従来から皮膚に悪影響を及
ぼさない各種の無機物質が顔料として使用されているこ
とも周知である。例えば白粉、口紅、その他の化粧料で
は種々の顔料が使用されている。タルク、カオリン、炭
酸カルシウム、酸化亜鉛、酸化チタン、酸化鉄、群青、
クロム緑、マイカ、雲母チタン、珪酸などである。これ
らはいずれも皮膚刺激がなく安全に化粧料に配合使用さ
れる。On the other hand, it is well known that cosmetics have conventionally used various inorganic substances as pigments which do not adversely affect the skin. For example, various pigments are used in white powder, lipstick, and other cosmetics. Talc, kaolin, calcium carbonate, zinc oxide, titanium oxide, iron oxide, ultramarine,
Examples include chrome green, mica, titanium mica, and silicic acid. All of these have no skin irritation and can be safely compounded and used in cosmetics.
【０００５】[0005]
【発明が解決しようとする課題】本発明は、抗菌効果が
高く、長時間経過しても化粧料が変質せず、皮膚に悪影
響を及ぼさず安全性の高い抗菌性化粧料を提供すること
を課題としている。DISCLOSURE OF THE INVENTION The present invention provides a highly safe antibacterial cosmetic composition which has a high antibacterial effect, does not deteriorate the cosmetic composition even after a long period of time, does not adversely affect the skin. It is an issue.
【０００６】[0006]
【課題を解決するための手段】上記課題を解決するた
め、種々検討した結果、従来から化粧料に配合使用され
ている顔料及びその類似物（以下これらをセラミックと
記す）に銀、銅及び亜鉛から選ばれた抗菌性金属の塩を
吸着担持させたのち、それを抗菌性金属の融点以上で焼
成することによって得られる抗菌性組成物は、抗菌性金
属塩やイオンが、抗菌性金属となるため、抗菌性金属イ
オンがセラミックから遊離することがなく加えて皮膚刺
激がないので、それらを配合してえられる化粧料は、時
間の経過で化粧料が変質することもなく、安全に長時間
保存できることを認めた。特に抗菌性金属として銀を使
用すると、９６０℃以上の温度で焼成することにより銀
イオンは銀として存在するようになり、抗菌力を保持し
たまゝ銀イオン特有の変色を生じない抗菌性組成物がえ
られ、これを配合した化粧料は特に好ましいと云える。[Means for Solving the Problems] In order to solve the above problems, as a result of various investigations, as a result, pigments and their analogues (hereinafter referred to as ceramics) which have been conventionally used in cosmetics are blended with silver, copper and zinc. The antibacterial composition obtained by adsorbing and supporting the salt of the antibacterial metal selected from the above and baking it at the melting point or higher of the antibacterial metal, the antibacterial metal salt or ion becomes the antibacterial metal. Therefore, since the antibacterial metal ions are not released from the ceramic and there is no skin irritation, the cosmetics obtained by blending them can be safely and long-term without the quality of the cosmetics changing. Approved that it can be saved. In particular, when silver is used as the antibacterial metal, the silver ion comes to exist as silver when baked at a temperature of 960 ° C. or higher, and the antibacterial composition does not cause discoloration peculiar to the silver ion while maintaining the antibacterial activity. Therefore, it can be said that a cosmetic containing the same is particularly preferable.
【０００７】本発明に使用するセラミックは、リン酸３
カルシウム、ハイドロキシアパタイト、炭酸カルシウ
ム、などのカルシウム含有化合物、酸化亜鉛、酸化ジル
コニウム、酸化チタン、酸化マグネシウム、酸化アルミ
ニウム、酸化ケイ素、タルク及びゼオライトより選ばれ
た少なくとも１つのセラミックであり、抗菌性金属塩
は、銀、銅及び亜鉛から選ばれた少なくとも１つの金属
の水溶性塩である。The ceramic used in the present invention is phosphoric acid 3
At least one ceramic selected from calcium-containing compounds such as calcium, hydroxyapatite, and calcium carbonate, zinc oxide, zirconium oxide, titanium oxide, magnesium oxide, aluminum oxide, silicon oxide, talc, and zeolite, and an antibacterial metal salt. Is a water-soluble salt of at least one metal selected from silver, copper and zinc.
【０００８】抗菌性金属塩の水溶液を常法に従いセラミ
ックと処理して金属塩をセラミックに吸着担持させる。
金属塩の吸着量は、使用する金属塩水溶液の濃度、セラ
ミックの種類及び処理温度により適宜選択されるが、一
般的にセラミックに対し重量で５０％程度までは容易に
吸着担持される。An aqueous solution of an antibacterial metal salt is treated with a ceramic according to a conventional method to adsorb and support the metal salt on the ceramic.
The amount of the metal salt adsorbed is appropriately selected depending on the concentration of the metal salt aqueous solution used, the type of ceramic and the treatment temperature, but in general, up to about 50% by weight of the metal salt is easily adsorbed and supported.
【０００９】このようにしてえられた抗菌性金属塩吸着
担持セラミックは焼成される。焼成処理は重要な工程で
あり、その焼成温度は使用した抗菌性金属塩及びセラミ
ックの種類により適宜選択する必要がある。特に抗菌性
金属塩として銀塩を使用した場合、焼成により担持され
た銀塩は、銀に転換される。一般に焼成により焼結がす
すみ、固体粒子の結合が進行し、全表面積、気孔率など
が減少することが認められている。従って抗菌性金属塩
担持セラミックを焼成し、えられた焼成物を微粉砕する
と、その微粉は未焼成のものと同等に強い抗菌力を示す
にかかわらず、担持された抗菌性金属と、セラミックの
結合力が強化され、担持された金属がセラミックより遊
離することがない。焼成温度は使用した金属塩及びセラ
ミックの種類により選択するが、一般に焼成温度の上昇
に伴い抗菌性金属のセラミックからの遊離量が減少する
ので、出来るだけ高温であることが望まれ、少なくとも
８００℃以上、好ましくは９６０℃以上、更に好ましく
は１１００℃以上であることが望まれる。又抗菌性金属
塩又は金属の吸着担持量が多すぎると、焼成温度によっ
ては焼成してもセラミックとの結合が弱く、セラミック
からそれらが遊離する場合を生じる。このため抗菌性金
属塩又は金属のセラミックに対する担持量を３０％以下
に制御し、焼成後それらのセラミックからの遊離を抑制
することが望まれる。The antibacterial metal salt adsorption supporting ceramic thus obtained is fired. The calcination process is an important step, and the calcination temperature must be appropriately selected depending on the types of the antibacterial metal salt and ceramic used. Especially when a silver salt is used as the antibacterial metal salt, the silver salt carried by firing is converted to silver. It is generally accepted that sintering promotes sintering, promotes bonding of solid particles, and reduces the total surface area, porosity, and the like. Therefore, when the antibacterial metal salt-supported ceramic is fired and the fired product obtained is finely pulverized, the finely divided powder shows a strong antibacterial activity equivalent to that of the unfired one, but the supported antibacterial metal and ceramic The cohesive strength is enhanced and the supported metal is not liberated from the ceramic. The firing temperature is selected depending on the type of metal salt and ceramic used, but generally, the release amount of the antibacterial metal from the ceramic decreases as the firing temperature rises, so it is desirable that the temperature be as high as possible, and at least 800 ° C. It is desired that the temperature is at least 960 ° C., preferably at least 960 ° C., more preferably at least 1100 ° C. Further, if the amount of the antibacterial metal salt or metal adsorbed and supported is too large, the binding with the ceramic is weak even if firing is performed depending on the firing temperature, and there is a case where they are released from the ceramic. Therefore, it is desired to control the amount of the antibacterial metal salt or metal supported on the ceramic to 30% or less so as to suppress the liberation from the ceramic after firing.
【００１０】焼成してえられた抗菌性セラミックをミル
で微粒砕してえた抗菌性組成物は、抗菌性金属イオン又
は金属がセラミックから遊離することがないので、化粧
料に添加使用しても抗菌性金属イオン又は金属がセラミ
ックから遊離し、化粧料中に溶出することがなく加えて
皮膚刺激も生じない。従ってえられた抗菌性組成物は、
化粧料用防腐剤、顔料として、従来から使用されている
化粧料成分に配合し化粧料として使用することができ
る。それらが配合される化粧料として、例えば、基礎化
粧料〔石ケン類、化粧水、クリーム、乳液、その他〕、
メイクアップ化粧料〔白粉、口紅、頬紅、ファンデーシ
ョンなど〕、毛髪用及び整髪用化粧料〔シャンプー、リ
ンス、ヘアリンス、その他〕などがある。抗菌性組成物
の化粧料への配合について、配合順序、使用する装置、
混合条件などに特に制限はなく、油性成分、水性成分に
抗菌性組成物を室温又は加温下で、常法により充分混合
すれば容易に抗菌性組成物を配合した化粧料をえること
ができる。使用する抗菌性組成物は、化粧料中に均一に
分散し、保存時においても沈降、凝集を生じないよう、
出来るだけ微粉に粉砕することが好ましく、粒子が小さ
ければ小さい程化粧料の均質性を向上するので、１０μ
m 以下であることが好まれるが、反射率、屈折率などを
考慮すると３〜１０μm 程度であることが望まれる。又
その配合量は、目的とする化粧料の種類及び抗菌性組成
物の抗菌性金属の含量により適宜選択される。微量の配
合で充分に抗菌性を示すので、一般に0.０５〜３０重量
％程度の配合で充分である。以下に実施例を示して具体
的に本発明を説明するが、本発明は実施例に限定される
ものではない。The antibacterial composition obtained by finely crushing the antibacterial ceramic obtained by firing with a mill does not release the antibacterial metal ions or metal from the ceramic, and therefore, even if it is used in cosmetics. The antibacterial metal ion or metal is released from the ceramic, does not elute in the cosmetic, and does not cause skin irritation. Therefore, the obtained antibacterial composition is
As a preservative for cosmetics and as a pigment, it can be used as a cosmetic by blending it with a conventionally used cosmetic ingredient. As cosmetics in which they are blended, for example, basic cosmetics [soaps, lotions, creams, emulsions, etc.],
There are makeup cosmetics [white powder, lipstick, blusher, foundation, etc.], cosmetics for hair and hair styling [shampoo, rinse, hair rinse, etc.]. Regarding the blending of the antibacterial composition with cosmetics, the blending order, the equipment used,
There is no particular limitation on mixing conditions, etc., and if the antibacterial composition is mixed with the oily component and the aqueous component at room temperature or under heating, it is possible to easily obtain a cosmetic product containing the antibacterial composition by thoroughly mixing the antibacterial composition. . The antibacterial composition used is uniformly dispersed in the cosmetic, so that it does not cause sedimentation or aggregation even during storage,
It is preferable to pulverize it into as fine a powder as possible. The smaller the particles, the better the homogeneity of the cosmetic.
Although it is preferably m or less, it is preferably about 3 to 10 μm in consideration of reflectance and refractive index. Further, the blending amount is appropriately selected depending on the kind of the intended cosmetic and the content of the antibacterial metal of the antibacterial composition. Since a small amount of the compound exhibits sufficient antibacterial properties, a compounding amount of about 0.05 to 30% by weight is generally sufficient. The present invention will be specifically described below with reference to examples, but the present invention is not limited to the examples.
【００１１】[0011]
【実施例１】１０リットルの蒸留水にハイドロキシアパ
タイト1.０kg、硝酸銀３２ｇを加え攪拌した。生成物を
蒸留水で良く洗い、乾燥し、一部を粉砕して、銀塩3.２
％を含有した抗菌性ハイドロキシアパタイトをえた（１
−１）。残りを１２００℃で焼成し、粉砕して銀２％を
含有した抗菌性ハイドロキシアパタイト組成物をえた
（１−２）。Example 1 1.0 kg of hydroxyapatite and 32 g of silver nitrate were added to 10 liters of distilled water and stirred. The product was washed well with distilled water, dried, and partly ground to give a silver salt 3.2.
% Antibacterial hydroxyapatite was obtained (1
-1). The rest was baked at 1200 ° C. and pulverized to obtain an antibacterial hydroxyapatite composition containing 2% of silver (1-2).
【００１２】[0012]
【実施例２】１０リットルの蒸留水にリン酸３カルシウ
ム1.０kg、酸化珪素２０ｇ、硝酸銀１２ｇを加えて攪拌
した。生成物を蒸留水で良く洗い、乾燥し、一部を粉砕
して銀塩1.０％を含有した抗菌性酸化ケイ素含有リン酸
３カルシウムをえた（２−１）。残りを９６０℃で焼成
し、粉砕して銀0.５％を含有した抗菌性酸化ケイ素含有
リン酸３カルシウム組成物をえた（２−２）。Example 2 To 10 liters of distilled water, 1.0 kg of tricalcium phosphate, 20 g of silicon oxide and 12 g of silver nitrate were added and stirred. The product was thoroughly washed with distilled water, dried, and a part thereof was crushed to obtain antibacterial silicon oxide-containing tricalcium phosphate containing 1.0% of silver salt (2-1). The rest was baked at 960 ° C. and pulverized to obtain an antibacterial silicon oxide-containing tricalcium phosphate composition containing 0.5% of silver (2-2).
【００１３】[0013]
【実施例３】１０リットルの蒸留水に酸化チタン1.０k
g、硝酸銀0.０１ｇを加えて攪拌した。生成物を蒸留水
で良く洗い、乾燥し、一部を粉砕して銀塩0.００１％を
含有した抗菌性酸化チタンをえた（３−１）。残りを１
０００℃で焼成し、粉砕して銀0.０００６％を含有した
抗菌性酸化チタン組成物をえた（３−２）。Example 3 Titanium oxide 1.0k in 10 liters of distilled water
g and 0.01 g of silver nitrate were added and stirred. The product was thoroughly washed with distilled water, dried, and a part thereof was pulverized to obtain antibacterial titanium oxide containing silver salt 0.001% (3-1). The rest 1
The composition was fired at 000 ° C and pulverized to obtain an antibacterial titanium oxide composition containing 0.0006% of silver (3-2).
【００１４】[0014]
【実施例４】硝酸銀1.６mgを蒸留水５００mlに溶解した
溶液に、アルミナ微粉末1.０kgを入れ、よく攪拌し、生
成物を水洗、乾燥し、一部を粉砕して銀塩0.０００１６
％を含有した抗菌性アルミナをえた（４−１）。残りを
１１００℃で焼成し、粉砕して銀0.０００１％を含有し
た抗菌性アルミナ組成物をえた（４−２）。Example 4 1.0 kg of alumina fine powder was added to a solution of 1.6 mg of silver nitrate in 500 ml of distilled water, stirred well, the product was washed with water, dried, and a part thereof was crushed to give a silver salt of 0.5 mg. 00016
% Antibacterial alumina was obtained (4-1). The rest was baked at 1100 ° C. and pulverized to obtain an antibacterial alumina composition containing 0.0001% of silver (4-2).
【００１５】[0015]
【実施例５】硝酸銀0.２ｇを水５０mlに溶解した溶液に
酸化マグネシウム粉末１００ｇを入れ、よく攪拌し、生
成物を水洗、乾燥し、その一部を粉砕して銀塩0.１６％
を含有した抗菌性酸化マグネシウムをえた（５−１）。
残りを１３００℃で焼成し、粉砕して銀0.１％を含有し
た抗菌性酸化マグネシウム組成物をえた（５−２）。Example 5 100 g of magnesium oxide powder was added to a solution prepared by dissolving 0.2 g of silver nitrate in 50 ml of water, stirred well, the product was washed with water, dried, and a part thereof was pulverized to obtain a silver salt of 0.16%.
Antibacterial magnesium oxide containing was obtained (5-1).
The rest was baked at 1300 ° C. and pulverized to obtain an antibacterial magnesium oxide composition containing 0.1% of silver (5-2).
【００１６】[0016]
【実施例６】硫酸銅1.５ｇを蒸留水５０mlに溶解した溶
液に酸化ジルコニウム微粉末１０ｇを入れてよく攪拌
し、生成物を水洗、乾燥し、一部を粉砕して銅塩１３％
を含有した抗菌性ジルコニウムをえた（６−１）。残り
を１１００℃で焼成し、粉砕して銅５％を含有した抗菌
性酸化ジルコニウム組成物をえた（６−２）。Example 6 10 g of fine zirconium oxide powder was added to a solution prepared by dissolving 1.5 g of copper sulfate in 50 ml of distilled water, stirred well, the product was washed with water, dried, and partly ground to give a copper salt of 13%.
An antibacterial zirconium containing was obtained (6-1). The rest was baked at 1100 ° C. and pulverized to obtain an antibacterial zirconium oxide composition containing 5% of copper (6-2).
【００１７】[0017]
【実施例７】硝酸亜鉛５ｇを蒸留水５０mlに溶解した溶
液中にタルク粉末１０ｇを入れ、攪拌し、生成物を水
洗、乾燥し、一部を粉砕して亜鉛塩３０％を含有した抗
菌性タルクをえた（７−１）。残りを１０００℃で焼成
し、粉砕して亜鉛１０％を含有した抗菌性タルク組成物
をえた（７−２）。Example 7 10 g of talc powder was added to a solution of 5 g of zinc nitrate dissolved in 50 ml of distilled water, the mixture was stirred, the product was washed with water, dried and partly ground to give an antibacterial property containing 30% of zinc salt. I got talc (7-1). The rest was baked at 1000 ° C. and pulverized to obtain an antibacterial talc composition containing 10% zinc (7-2).
【００１８】[0018]
【実施例８】１０リットルの蒸留水にゼオライト1.０k
g、硝酸銀５０ｇ、硝酸亜鉛５０ｇを加えて攪拌した。
生成物を蒸留水で良く洗い、乾燥し、一部を粉砕して銀
塩５％、亜鉛塩５％を含有した抗菌性ゼオライトをえた
（８−１）。残りを１０００℃で焼成し、粉砕して銀３
％、亜鉛1.５％を含有した抗菌性ゼオライト組成物をえ
た（８−２）。Example 8 Zeolite 1.0k in 10 liters of distilled water
g, 50 g of silver nitrate and 50 g of zinc nitrate were added and stirred.
The product was thoroughly washed with distilled water, dried, and a part thereof was pulverized to obtain an antibacterial zeolite containing 5% of silver salt and 5% of zinc salt (8-1). The rest is baked at 1000 ℃, crushed and silver 3
%, And an antibacterial zeolite composition containing 1.5% zinc was obtained (8-2).
【００１９】[0019]
【実施例９】 金属イオン溶出試験 実施例１〜８でえられたそれぞれの試料１ｇを蒸留水１
００mlに加え、３０分激しく攪拌した後、原子吸光分光
光度計を用いて溶液中の金属イオンを測定し、表１の結
果をえた。焼成した抗菌性組成物は、未焼成物に比し、
金属イオンの溶出のないことを示している。Example 9 Metal Ion Elution Test 1 g of each sample obtained in Examples 1 to 8 was distilled water 1
After adding vigorously to 00 ml and stirring vigorously for 30 minutes, metal ions in the solution were measured using an atomic absorption spectrophotometer, and the results shown in Table 1 were obtained. The fired antibacterial composition, compared to unfired,
It shows that there is no elution of metal ions.
【００２０】[0020]
【表１】 [Table 1]
【００２１】実施例１〜８でえられた抗菌性組成物を使
用し、以下に示す化粧料を作成した。（数値はいずれも
重量％である）。Using the antibacterial compositions obtained in Examples 1 to 8, the following cosmetics were prepared. (All values are% by weight).
【実施例１０】 油状軟膏ファンデーション 抗菌性組成物（実施例１−２でえられた抗菌性ハイドロキシアパタイト組成物 ） ３０．０ 粉末ハイドロキシアパタイト １０．０ パルミチン酸イソプロピル １５．０ ラノリンアルコール ５．０ 酢酸ラノリン ８．０ マイクロクリスタリンワックス ７．０ 流動パラフィン ２５．０ 香料及び酸化防止剤 適量Example 10 Oily ointment foundation Antibacterial composition (antibacterial hydroxyapatite composition obtained in Example 1-2) 30.0 Powdered hydroxyapatite 10.0 Isopropyl palmitate 15.0 Lanolin alcohol 5.0 Acetic acid Lanolin 8.0 Microcrystalline wax 7.0 Liquid paraffin 25.0 Perfume and antioxidants Appropriate amount
【００２２】[0022]
【実施例１１】 乳液状ファンデーション 抗菌性組成物（例２−２でえられた抗菌性酸化ケイ素含有リン酸３カルシウム 組成物） １２．０ ステアリン酸 ２．４ モノステアリン酸プロピレングリコール ２．０ セトステアリルアルコール ０．２ 液状ラノリン ２．０ 流動パラフィン ３．０ ミリスチン酸イソプロピル ８．５ カルボキシメチルセルローズナトリウム ０．２ プロピレングリコール ４．０ トリエタノールアミン １．１ 精製水 ６６．６ 香料 適量Example 11 Emulsion foundation Antibacterial composition (antibacterial silicon oxide-containing tricalcium phosphate composition obtained in Example 2-2) 12.0 Stearic acid 2.4 Propylene glycol monostearate 2.0 Set Stearyl alcohol 0.2 Liquid lanolin 2.0 Liquid paraffin 3.0 Isopropyl myristate 8.5 Carboxymethylcellulose sodium 0.2 Propylene glycol 4.0 Triethanolamine 1.1 Purified water 66.6 Perfume Suitable amount
【００２３】[0023]
【実施例１２】 スティック型口紅 抗菌性組成物（例３−２でえられた抗菌性酸化チタン組成物） ３．０ 赤色２０２号 ０．５ 赤色２０４号 ２．５ 赤色２２７号Ａ１レーキ ２．５ 橙色２０１号 ０．２ ヒマシ油 ４５．３ ヘキサデシルアルコール ２５．０ ミツロウ １０．０ キヤンデリラロウ ８．０ カルナバロウ ３．０ 香料、酸化防止剤 適量Example 12 Stick Type Lipstick Antibacterial Composition (Antibacterial Titanium Oxide Composition Obtained in Example 3-2) 3.0 Red No. 202 0.5 Red No. 204 2.5 Red No. 227 A1 Lake 2. 5 Orange No. 201 0.2 Castor oil 45.3 Hexadecyl alcohol 25.0 Beeswax 10.0 Candelilla wax 8.0 Carnauba wax 3.0 Fragrance, antioxidant Suitable amount
【００２４】[0024]
【実施例１３】 粉おしろい 抗菌性組成物（例３−２でえられた抗菌性酸化チタン組成物） ４５．０ タルク ５５．０ 着色顔料及び香料 適量Example 13 Powder powder antibacterial composition (antibacterial titanium oxide composition obtained in Example 3-2) 45.0 Talc 55.0 Coloring pigment and perfume
【００２５】[0025]
【実施例１４】 固型マスカラ 抗菌性組成物（例４−２でえられた抗菌性アルミナ組成物） １８．０ ステアリン酸トリエタノールアミン ２６．０ パラフィン ２６．０ ミツロウ １７．０ ラノリン １０．０ カルナバロウ ３．０Example 14 Solid Mascara Antibacterial Composition (Antibacterial Alumina Composition Obtained in Example 4-2) 18.0 Triethanolamine Stearate 26.0 Paraffin 26.0 Beeswax 17.0 Lanolin 10.0 Carnavalou 3.0
【００２６】[0026]
【実施例１５】 スティック型アイシャドー 抗菌性組成物（例５−２でえられた抗菌性酸化ジルコニウム組成物）８．０ 着色顔料 ８．０ セレシン ２５．０ 硬化綿実油 １６．０ ヒマシ油 ３３．０ 流動パラフィン ６．０ キヤンデリラロウ ４．０ 酸化防止剤 適量Example 15 Stick type eye shadow Antibacterial composition (antibacterial zirconium oxide composition obtained in Example 5-2) 8.0 Coloring pigment 8.0 Ceresin 25.0 Hardened cottonseed oil 16.0 Castor oil 33. 0 Liquid paraffin 6.0 Candelilla wax 4.0 Antioxidant Suitable amount
【００２７】[0027]
【実施例１６】 化粧料の抗菌試験 実施例１０〜１５でえられた化粧料、夫々１重量％添加
したリン酸緩衝液に、大腸菌、緑膿菌、カンジダ菌及び
黒麹黴を添加し、２４時間後の生菌を測定し表２の結果
をえた。夫々の化粧料が強い抗菌力を有することを示し
ている。Example 16 Antibacterial Test of Cosmetics To the cosmetics obtained in Examples 10 to 15 and phosphate buffer solutions containing 1% by weight of each, Escherichia coli, Pseudomonas aeruginosa, Candida and Koji mold are added, The viable bacteria after 24 hours were measured and the results shown in Table 2 were obtained. It shows that each cosmetic has strong antibacterial activity.
【００２７】[0027]
【表２】 [Table 2]
【００２８】[0028]
【発明の効果】本発明による抗菌性組成物を配合した化
粧料は、強い抗菌性を示し、微生物の発育を抑制すると
ともに、抗菌性の金属イオン又は金属が化粧料中に遊離
溶出することがなく安全に長時間保存できる。EFFECTS OF THE INVENTION The cosmetics containing the antibacterial composition according to the present invention exhibit strong antibacterial properties and suppress the growth of microorganisms, and antibacterial metal ions or metals may be released and eluted into the cosmetics. It can be safely stored for a long time.
Claims (7)
抗菌性組成物を配合してなる抗菌性化粧料。1. An antibacterial cosmetic comprising an antibacterial composition in which an antibacterial metal is supported on ceramics.
た抗菌性金属の塩を担持させた後、抗菌性金属の融点以
上の温度で焼成して得られた抗菌性組成物を配合するこ
とを特徴とする請求項１の抗菌性化粧料。2. An antibacterial composition obtained by supporting a salt of an antibacterial metal selected from silver, copper and zinc on ceramics and then firing at a temperature higher than the melting point of the antibacterial metal. An antibacterial cosmetic composition according to claim 1.
５〜３０％配合した請求項１又は２の抗菌性化粧料。3. The antibacterial composition is 0.0 by weight based on the cosmetic.
The antibacterial cosmetic composition according to claim 1 or 2, which is blended in an amount of 5 to 30%.
し重量で0.０００１〜１５％である抗菌性組成物を配合
した請求項１乃至３の抗菌性化粧料。4. The antibacterial cosmetic composition according to claim 1, which comprises an antibacterial composition in which the amount of the antibacterial metal supported is 0.0001 to 15% by weight of the ceramic.
鉛、酸化ジルコニウム、酸化チタン、酸化マグネシウ
ム、酸化アルミニウム、酸化ケイ素、タルク及びゼオラ
イトより選ばれた少なくとも１つである請求項１乃至４
のいずれか１項の抗菌性化粧料。5. The ceramic is at least one selected from a calcium compound, zinc oxide, zirconium oxide, titanium oxide, magnesium oxide, aluminum oxide, silicon oxide, talc, and zeolite.
The antibacterial cosmetic composition according to any one of 1.
ム、ハイドロキシアパタイト及び炭酸カルシウムから選
ばれた少なくとも１つである請求項５の抗菌性化粧料。6. The antibacterial cosmetic composition according to claim 5, wherein the calcium compound is at least one selected from tricalcium phosphate, hydroxyapatite and calcium carbonate.
０℃以上である請求項１乃至６のいずれか１項の抗菌性
化粧料。7. The antibacterial metal is silver and the firing temperature is 96.
The antibacterial cosmetic composition according to any one of claims 1 to 6, which has a temperature of 0 ° C or higher.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP26947393A JPH07101821A (en) | 1993-10-04 | 1993-10-04 | Antibacterial cosmetic |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP26947393A JPH07101821A (en) | 1993-10-04 | 1993-10-04 | Antibacterial cosmetic |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH07101821A true JPH07101821A (en) | 1995-04-18 |
Family
ID=17472935
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP26947393A Pending JPH07101821A (en) | 1993-10-04 | 1993-10-04 | Antibacterial cosmetic |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH07101821A (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH1045562A (en) * | 1996-08-08 | 1998-02-17 | Noevir Co Ltd | Antimicrobial and low-irritant cosmetic |
| EP0776191A4 (en) * | 1995-06-13 | 1999-01-20 | Zahra Mansouri | Methods of delivering materials into the skin, and compositions used therein |
| US6579516B1 (en) | 1995-06-13 | 2003-06-17 | Zahra Mansouri | Methods of delivering materials into the skin, and compositions used therein |
| JPWO2002030365A1 (en) * | 2000-10-06 | 2004-02-19 | 株式会社サンギ | Antibacterial resin |
| JP2006117611A (en) * | 2004-10-25 | 2006-05-11 | Kotoko Sato | Cosmetic agent for making corpse and use thereof |
| JP2010523344A (en) * | 2007-04-04 | 2010-07-15 | パーレン コンヴァーティング アクチェンゲゼルシャフト | Antibacterial material |
| KR102107041B1 (en) * | 2019-02-27 | 2020-05-06 | 박현 | Functional Cosmetic Composition For Reducing Hair Loss Problem |
| JP2022081317A (en) * | 2020-11-19 | 2022-05-31 | 株式会社三鷹ホールディングス | Antibacterial cosmetics |
-
1993
- 1993-10-04 JP JP26947393A patent/JPH07101821A/en active Pending
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0776191A4 (en) * | 1995-06-13 | 1999-01-20 | Zahra Mansouri | Methods of delivering materials into the skin, and compositions used therein |
| US6579516B1 (en) | 1995-06-13 | 2003-06-17 | Zahra Mansouri | Methods of delivering materials into the skin, and compositions used therein |
| US7655250B2 (en) | 1995-06-13 | 2010-02-02 | Laboratory Skin Care, Inc. | Topical formulations comprising ceramic hydroxyapatite particles |
| US7771753B2 (en) | 1995-06-13 | 2010-08-10 | Laboratory Skin Care, Inc. | Topical formulations comprising ceramic hydroxyapatite particles |
| JPH1045562A (en) * | 1996-08-08 | 1998-02-17 | Noevir Co Ltd | Antimicrobial and low-irritant cosmetic |
| JPWO2002030365A1 (en) * | 2000-10-06 | 2004-02-19 | 株式会社サンギ | Antibacterial resin |
| JP2006117611A (en) * | 2004-10-25 | 2006-05-11 | Kotoko Sato | Cosmetic agent for making corpse and use thereof |
| JP2010523344A (en) * | 2007-04-04 | 2010-07-15 | パーレン コンヴァーティング アクチェンゲゼルシャフト | Antibacterial material |
| KR102107041B1 (en) * | 2019-02-27 | 2020-05-06 | 박현 | Functional Cosmetic Composition For Reducing Hair Loss Problem |
| JP2022081317A (en) * | 2020-11-19 | 2022-05-31 | 株式会社三鷹ホールディングス | Antibacterial cosmetics |
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