JPH0696802B2 - PVC gloves - Google Patents
PVC glovesInfo
- Publication number
- JPH0696802B2 JPH0696802B2 JP23613092A JP23613092A JPH0696802B2 JP H0696802 B2 JPH0696802 B2 JP H0696802B2 JP 23613092 A JP23613092 A JP 23613092A JP 23613092 A JP23613092 A JP 23613092A JP H0696802 B2 JPH0696802 B2 JP H0696802B2
- Authority
- JP
- Japan
- Prior art keywords
- vinyl chloride
- microcapsules
- glove
- layer
- pile
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Landscapes
- Gloves (AREA)
Description
【０００１】[0001]
【産業上の利用分野】本発明は、保温性の向上と非粘着
性及滑性の付与を同時に行った塩化ビニル製手袋に関す
るものである。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a vinyl chloride glove that simultaneously improves heat retention and imparts non-adhesiveness and lubricity.
【０００２】[0002]
【従来の技術】従来、塩化ビニル製手袋の保温性を付与
するには手袋本体の内面にパイルによる植毛を行ってい
る。2. Description of the Related Art Conventionally, in order to impart heat-retaining properties to vinyl chloride gloves, flocking with a pile is performed on the inner surface of the glove body.
【０００３】[0003]
【発明が解決しようとする問題点】しかしながら、上記
パイルにより植毛した手袋は、使用時、手からの発汗に
より汗がパイルにしみ込んで保温効果を減じることや、
長時間の使用でパイルが接着剤層から剥れたり，製造工
程中におけるパイルの飛散による作業環境の低下など多
くの問題があった。However, in the glove in which the hair is transplanted by the pile, sweat permeates the pile due to perspiration from the hand and the heat retaining effect is reduced, and
There were many problems such as peeling of the pile from the adhesive layer after long-term use and deterioration of the working environment due to scattering of the pile during the manufacturing process.
【０００４】また、食品加工業では食品を直接手で触れ
ることは衛生上問題があるため、各種手袋を使用してい
るが、パイル層のある手袋は、内部のパイルが剥れた場
合食品に混入してしまう危険性があるため嫌われてい
る。そのため、使用上不便でも肉厚の薄い保温効果のな
い手袋を使用せざるを得ない現状であった。Further, in the food processing industry, since it is a sanitary problem to directly touch the food with a hand, various gloves are used. However, a glove with a pile layer is used as a food when the inner pile is peeled off. It is disliked because of the risk of mixing. Therefore, even though it is inconvenient to use, it has been unavoidable to use gloves that are thin and have no heat insulating effect.
【０００５】また、単なる発泡層を作るという観点から
すれば、化学発泡剤による発泡層を形成する事が出来る
が、表面がパイルの様にスウェード調にする事が不可能
であった。From the viewpoint of simply forming a foam layer, a foam layer made of a chemical foaming agent can be formed, but it is impossible to make the surface of the surface like a pile.
【０００６】[0006]
【問題点を解決するための手段】本発明は、このような
事情に鑑みてなされたものであり、その手段は、塩化ビ
ニル製手袋本体の内面に、予じめ調整してあるマイクロ
カプセルを含有している塩化ビニルペーストゾルを塗布
し、マイクロカプセルによる独立気泡の緻密なセルに形
成した皮膜層とし、更にその内面に滑性及非粘着性のウ
レタン又はアクリルなどの合成樹脂製の表面皮膜を設け
ることにより、保温性が優れ、かつ、手の出し入れの容
易な手袋を供することが出来た。SUMMARY OF THE INVENTION The present invention has been made in view of the above-mentioned circumstances, and the means is to provide a pre-adjusted microcapsule on the inner surface of a vinyl chloride glove body. A vinyl chloride paste sol is applied to form a film layer formed in a close-packed cell with closed cells by microcapsules, and the inner surface of the film is made of synthetic resin such as urethane or acrylic that is slippery and non-adhesive. By providing the glove, it was possible to provide a glove that has excellent heat retention and is easy to put in and take out.
【０００７】[0007]
【実施例】本発明の実施例を図面に基づいて説明する
と、まず、手袋本体１は此種の技術分野において周知な
形態のものであり、一般的に行なわれている塩化ビニル
ペーストに製造型を浸漬後加熱を行って半ゲル化する。
この半ゲル化状態でマイクロカプセルを０．１〜２０Ｐ
ＨＲを配合した塩化ビニルペーストに浸漬して前記本体
１の表面に薄膜を塗布し充分厚みのある皮膜層２が得
る。この皮膜層２の粘度は３００〜２０００ＣＰＳ、膜
厚としては、０．０１〜０．３ｍｍ程度あれば充分であ
る。DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS An embodiment of the present invention will be described with reference to the drawings. First, the glove body 1 has a form well known in the technical field of this type, and is generally made of vinyl chloride paste. After soaking, heating is performed to semi-gelate.
In this semi-gelled state, microcapsules of 0.1-20
By dipping in a vinyl chloride paste containing HR and applying a thin film on the surface of the main body 1, a coating layer 2 having a sufficient thickness is obtained. It is sufficient that the film layer 2 has a viscosity of 300 to 2000 CPS and a film thickness of 0.01 to 0.3 mm.
【０００８】また、皮膜層２のベースポリマーを塩化ビ
ニルとしたのは、手袋本体１との接着性が良いためであ
る。この塩化ビニルペーストの薄膜は後述する中空粒子
からなるマイクロカプセルを含有しており、該カプセル
の気泡による独立気泡を持った発泡層のような状態とな
る。その際熱膨張性のカプセルを用いた場合には加熱温
度１４０℃以上にすると、マイクロカプセルが熱膨張
し、直径３０〜１００μｍ以下の均一な独立気泡による
発泡層が発現するのである。この時、薄膜は１．５〜１
０倍の膜厚となる。しかる後、このような発泡状態の皮
膜層２の内面に滑性及非粘着性に優れた合成樹脂エマル
ジョンを塗布し、表面皮膜３となる薄膜を形成する。The base polymer of the coating layer 2 is vinyl chloride because it has good adhesiveness to the glove body 1. This thin film of vinyl chloride paste contains microcapsules composed of hollow particles, which will be described later, and is in a state like a foam layer having closed cells due to the bubbles of the capsules. In this case, when a heat-expandable capsule is used, if the heating temperature is 140 ° C. or higher, the microcapsule thermally expands, and a foamed layer with uniform closed cells having a diameter of 30 to 100 μm or less is developed. At this time, the thin film is 1.5-1
The film thickness is 0 times. Then, a synthetic resin emulsion having excellent lubricity and non-adhesiveness is applied to the inner surface of the foamed coating layer 2 to form a thin film which becomes the surface coating 3.
【０００９】塩化ビニル皮膜層２におけるマイクロカプ
セルは無機質又は有機質の殻から構成された中空球体で
粒径が２００μ以下の中空粒子状のものであり、殻の組
成が無機質の物は耐熱安定性が高く、有機質の物は弾性
に富んでおり、さらに有機質のマイクロカプセルには熱
膨張性のものがあり常温では有機質の単なる粒子である
が、１４０℃以上の熱をかけると粒子が内部ガスにより
膨張し、中空を形成するものとなる。したがってこの熱
膨張性のマイクロカプセルが好ましいものである。The microcapsules in the vinyl chloride coating layer 2 are hollow spheres composed of an inorganic or organic shell and have a particle size of 200 μm or less. The shell having an inorganic composition has heat resistance stability. High and organic substances are highly elastic, and some organic microcapsules have thermal expansion properties, so they are mere organic particles at room temperature, but when heated to 140 ° C or higher, the particles expand due to internal gas. To form a hollow. Therefore, the thermally expandable microcapsules are preferable.
【００１０】表面皮膜３は手袋の内面層で非粘着性と滑
性を付与するものであり、例えばウレタン又はアクリル
樹脂２〜１０部を含有する粘度１０〜２００ｃｐｓ程度
の合成樹脂エマルジョンよりなる表面処理剤を前記マイ
クロカプセルを含有する皮膜層２の表面に付着せしめて
薄膜を形成したものである。The surface coating 3 is an inner surface layer of the glove that imparts non-adhesiveness and lubricity, and is made of, for example, a synthetic resin emulsion containing 2 to 10 parts of urethane or acrylic resin and having a viscosity of about 10 to 200 cps. The agent is attached to the surface of the coating layer 2 containing the microcapsules to form a thin film.
【００１１】次に具体的な実施の態様について詳述す
る。 （１）手袋型に塩化ビニールペーストを塗布し、手袋本
体を成形する。この方法は、一般的な浸漬成形で行う。
使用する塩化ビニールペーストの配合は以下のものであ
る。Next, specific embodiments will be described in detail. (1) Apply vinyl chloride paste to the glove mold to mold the glove body. This method is performed by general dip molding.
The composition of the vinyl chloride paste used is as follows.
【００１２】 塩化ビニルペーストレジン（重合度＝１６５０） １００ＰＨＲ 可塑剤（フタル酸エステル，ポリエステル) １００ＰＨＲ 安定剤（Ｃａ−Ｂａ−Ｚｕ） ４ＰＨＲ ゲル化剤（Ｃａ／Ｓｉ） ４ＰＨＲ 顔 料 １ＰＨＲ 浸漬成形後１７０℃、４分間のセミキュアーを行った
後、常温迄冷却する。 （２）次にマイクロカプセルの入った塩化ビニルペース
トに浸漬し成形する。Vinyl chloride paste resin (degree of polymerization = 1650) 100PHR Plasticizer (phthalate ester, polyester) 100PHR Stabilizer (Ca-Ba-Zu) 4PHR Gelling agent (Ca / Si) 4PHR Facial agent 1PHR After dipping molding 170 After semi-curing at 4 ° C for 4 minutes, cool to room temperature. (2) Next, it is dipped in a vinyl chloride paste containing microcapsules to be molded.
【００１３】その配合は以下の通りである。前記（１）
で塗布された型を下記塩化ビニルペーストに浸漬する。
このとき膜厚は０．１ｍｍ程度になる様に塩化ビニルペ
ーストの粘度（１０００ＣＰＳ）を調整しておく。The composition is as follows. (1)
The mold applied in step 1 is dipped in the vinyl chloride paste below.
At this time, the viscosity (1000 CPS) of the vinyl chloride paste is adjusted so that the film thickness is about 0.1 mm.
【００１４】 塩化ビニルペーストレジン（重合度＝１６５０） １００ＰＨＲ 可塑剤（フタル酸エステル，ポリエステル） １００ＰＨＲ 安定剤（Ｃａ−Ｂａ−Ｚｕ） ４ＰＨＲ ゲル化剤（Ｃａ／Ｓｉ） ４ＰＨＲ 顔 料 １ＰＨＲ 熱膨脹性マイクロカプセル ３ＰＨＲ （マツモトマイクロスフェア Ｆ−８５） ミネラルスピリット 適 量 浸漬成形後１７０℃、４分間のセミキュアーを行う。そ
の後、型を冷却する。 （３）次に表面を非粘着及び滑性を付与するために表面
処理剤に浸漬を行う。Vinyl chloride paste resin (polymerization degree = 1650) 100PHR Plasticizer (phthalate ester, polyester) 100PHR Stabilizer (Ca-Ba-Zu) 4PHR Gelling agent (Ca / Si) 4PHR Facial agent 1PHR Heat-expandable microcapsule 3PHR (Matsumoto Microsphere F-85) Mineral Spirit Proper amount After semi-curing at 170 ° C, semi-cure is performed for 4 minutes. Then, the mold is cooled. (3) Next, the surface is dipped in a surface treatment agent in order to impart non-adhesion and lubricity.
【００１５】この表面処理剤の配合例としては下記のも
のがある。The following are examples of formulations of this surface treatment agent.
【００１６】 ポリエステル系ポリウレタン ４ ＰＨＲ アニオン系界面活性剤 ０．５ＰＨＲ ポリエーテル系消泡剤 ０．５ＰＨＲ 水 ９５ ＰＨＲ 前記（２）で塗布された型を上記表面処理剤に浸漬後１
４０℃、２分間乾燥した後２００℃、１０分間のキュア
ーを行う。この時塩化ビニルペースト中のマイクロカプ
セルは膨張し独立気泡層を形成する。 （４）然る後、型温を７０℃まで冷却して反転離型し塩
化ビニル製手袋を得る。Polyester polyurethane 4 PHR Anionic surfactant 0.5 PHR Polyether antifoaming agent 0.5 PHR Water 95 PHR After dipping the mold coated in the above (2) in the surface treatment agent, 1
After drying at 40 ° C. for 2 minutes, curing is performed at 200 ° C. for 10 minutes. At this time, the microcapsules in the vinyl chloride paste expand and form a closed cell layer. (4) After that, the mold temperature is cooled to 70 ° C., and the mold is reversed and released to obtain vinyl chloride gloves.
【００１７】尚、本実施例では熱膨張性の有機質マイク
ロカプセル用いたが無機質の例えば中空セラミックスか
らなるカプセルを用いることも可能である。In this embodiment, the thermally expandable organic microcapsules are used, but it is also possible to use inorganic capsules made of, for example, hollow ceramics.
【００１８】[0018]
【効果】本発明は手袋本体の内面にマイクロカプセルに
よる気泡を有する塩化ビニル皮膜層を形成し、更にその
内面に滑性及び非粘着性の合成樹脂製表面皮膜を設けた
から一般のパイル植毛手袋では、汗により次第に保温効
果がなくなってくるのに比べて、マイクロカプセルによ
る気泡が断熱材として作用し保温性が向上すると共にこ
れが長期間にわたって維持される。また、表面処理剤が
非粘着及滑性を付与し、手への脱着も容易である。[Effect] According to the present invention, since a vinyl chloride film layer having bubbles due to microcapsules is formed on the inner surface of the glove body, and a smooth and non-adhesive synthetic resin surface film is further provided on the inner surface of the glove body As compared with the fact that the heat insulating effect gradually disappears due to sweat, the air bubbles by the microcapsules act as a heat insulating material to improve the heat insulating property and this is maintained for a long period of time. Further, the surface treatment agent imparts non-adhesion and lubricity, and can be easily attached to and detached from the hand.
【００１９】 一般パイル植毛品 本発明品 １００％力（kgf ／cm） １．６ １．６ 伸び （％） ４２５ ４１３ 引張り荷重（kgf ／cm） ４．８ ４．９ 指又引裂力（Kgf ） １６．１ １６．３ 耐洗剤性 伸び残留率（％） １００ １００ 引張り残留率（％） ９６ ９５ 耐油性 伸び残留率（％） ８８ ８８ 引張り残留率（％） １４９ １４２ 耐酸性 伸び残留率（％） ９４ ９６ 引張り残留率（％） ９６ ９８ 一般パイル植毛品 本発明品 耐アルカリ性 伸び残留率（％） ８８ ８９ 引張り残留率（％） ８５ ８６ 熱伝導率* （Ｋｃａｌ／℃・ＨＲ） ０．３０ ０．１７ （保温性＝汗の付着状態） ＊熱伝導率は手袋内面を水で完全に湿潤した状態（汗で
湿潤した状態の再現）で測定を行った。General pile flocked product 100% force (kgf / cm) 1.6 1.6 Elongation (%) 425 413 Tensile load (kgf / cm) 4.8 4.9 Finger or tear force (Kgf) 16.1 16.3 Detergent resistance Deterioration residual rate (%) 100 100 Tensile residual rate (%) 96 95 Oil resistance Extended residual rate (%) 88 88 Tensile residual rate (%) 149 142 Acid resistant residual elongation rate (%) ) 94 96 Tensile residual rate (%) 96 98 General pile transplanted product The present invention product Alkali resistance Extension residual rate (%) 88 89 Tensile residual rate (%) 85 86 Thermal conductivity * (Kcal / ° C / HR) 0.30 0.17 (Heat retention = state of adhesion of sweat) * The thermal conductivity was measured in a state where the inner surface of the glove was completely wet with water (reproduction of a state wet with sweat).
【図１】 本発明塩化ビニル製手袋の正面図で一部切欠
する。FIG. 1 is a partially cutaway front view of a vinyl chloride glove of the present invention.
【図２】 拡大断面図。FIG. 2 is an enlarged sectional view.
１は手袋本体 ２はマイクロカプセルを含有する塩化ビニル皮膜層 ３は合成樹脂製表面皮膜 1 is a glove body 2 is a vinyl chloride film layer containing microcapsules 3 is a synthetic resin surface film
Claims (1)
カプセルによる気泡を有する塩化ビニル皮膜層を形成
し、更にその内面に滑性及非粘着性に優れた合成樹脂製
表面皮膜を設けた塩化ビニル製手袋。1. A vinyl chloride film having a vinyl chloride film layer having air bubbles formed by microcapsules formed on the inner surface of a vinyl chloride glove body, and further having a synthetic resin surface film excellent in lubricity and non-adhesiveness formed on the inner surface thereof. Made gloves.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP23613092A JPH0696802B2 (en) | 1992-09-03 | 1992-09-03 | PVC gloves |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP23613092A JPH0696802B2 (en) | 1992-09-03 | 1992-09-03 | PVC gloves |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH0681203A JPH0681203A (en) | 1994-03-22 |
| JPH0696802B2 true JPH0696802B2 (en) | 1994-11-30 |
Family
ID=16996208
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP23613092A Expired - Lifetime JPH0696802B2 (en) | 1992-09-03 | 1992-09-03 | PVC gloves |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0696802B2 (en) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AUPQ142199A0 (en) * | 1999-07-05 | 1999-07-29 | Bland, Richard | Heat retaining material and articles made therefrom |
| JP6088121B2 (en) * | 2010-09-21 | 2017-03-01 | オカモト株式会社 | PVC gloves |
| CN108477714B (en) * | 2018-04-18 | 2020-05-19 | 山东星宇手套有限公司 | Preparation method of chloroprene chemical-resistant gloves |
| CN108433220B (en) * | 2018-04-28 | 2020-07-03 | 山东星宇手套有限公司 | Preparation method of butyronitrile particle anti-slip gloves |
| CN108813764B (en) * | 2018-06-14 | 2020-05-19 | 山东星宇手套有限公司 | Preparation method of finger-strengthening gloves |
-
1992
- 1992-09-03 JP JP23613092A patent/JPH0696802B2/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0681203A (en) | 1994-03-22 |
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