JPH0669547B2 - Method for manufacturing a decorative material having a synchronous embossing - Google Patents
Method for manufacturing a decorative material having a synchronous embossingInfo
- Publication number
- JPH0669547B2 JPH0669547B2 JP60132175A JP13217585A JPH0669547B2 JP H0669547 B2 JPH0669547 B2 JP H0669547B2 JP 60132175 A JP60132175 A JP 60132175A JP 13217585 A JP13217585 A JP 13217585A JP H0669547 B2 JPH0669547 B2 JP H0669547B2
- Authority
- JP
- Japan
- Prior art keywords
- pattern
- curing
- type
- wax
- ink
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/267—Marking of plastic artifacts, e.g. with laser
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C35/00—Heating, cooling or curing, e.g. crosslinking or vulcanising; Apparatus therefor
- B29C35/02—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould
- B29C35/08—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould by wave energy or particle radiation
- B29C35/0805—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould by wave energy or particle radiation using electromagnetic radiation
- B29C2035/0827—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould by wave energy or particle radiation using electromagnetic radiation using UV radiation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2995/00—Properties of moulding materials, reinforcements, fillers, preformed parts or moulds
- B29K2995/0037—Other properties
- B29K2995/0072—Roughness, e.g. anti-slip
- B29K2995/0074—Roughness, e.g. anti-slip patterned, grained
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2007/00—Flat articles, e.g. films or sheets
- B29L2007/002—Panels; Plates; Sheets
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2031/00—Other particular articles
- B29L2031/722—Decorative or ornamental articles
Landscapes
- Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Shaping Of Tube Ends By Bending Or Straightening (AREA)
Description
発明の目的 Purpose of the invention
本発明は、絵柄に同調したエンボスを有し、耐熱性、耐
摩耗性にすぐれた化粧材の製造方法に関する。TECHNICAL FIELD The present invention relates to a method for producing a decorative material having embossing that matches a pattern and having excellent heat resistance and abrasion resistance.
化粧材に、その絵柄に同調したエンボスを形成する方法
として、硬化抑制剤を添加したインキで絵柄を印刷し、
その上に硬化性の樹脂を塗布して、たとえば紫外線で硬
化させることによって同調エンボスを得る方法が行なわ
れている。この方法で十分な凹凸を形成するためには硬
化樹脂膜を厚くする必要があり、そうすると生産性が低
く、コストが高くなる。しかも、凹部表面が未硬化なた
めその部分の物性が悪いという弱点がある。 撥液剤を含んだインキで絵柄を印刷し、その上にのせる
表面樹脂層をはじいた状態で硬化させる同調エンボス法
もあるが、はじき効果が不安定であることと、凹凸部の
シャープさにかけることが難点である。As a method of forming embossing that matches the pattern on a decorative material, a pattern is printed with an ink containing a curing inhibitor,
A method of obtaining a tuning emboss by applying a curable resin on it and curing it with, for example, ultraviolet rays is performed. In order to form sufficient unevenness by this method, it is necessary to thicken the cured resin film, which results in low productivity and high cost. Moreover, since the surface of the concave portion is uncured, there is a weak point that the physical property of the portion is bad. There is also a synchronous embossing method in which a pattern is printed with an ink containing a liquid repellent, and the surface resin layer placed on top of it is cured, but there is an unstable repelling effect and sharpness of uneven parts. It is a difficulty to call.
本発明の目的は、絵柄と同調させたエンボスを有する、
意匠性が高い化粧材を、低コストで製造する方法を提供
することにある。 発明の構成The object of the invention is to have the embossing in line with the design,
An object of the present invention is to provide a method for manufacturing a decorative material having high designability at low cost. Structure of the invention
本発明の同調エンボスを有する化粧材の製造方法は、基
材上に撥液剤および金属キレート化剤からえらんだ硬化
抑制剤を添加したインキを用いて任意の絵柄を印刷し、
その上に、硬化抑制剤により硬化反応が抑制される紫外
線硬化型樹脂を含む表面樹脂層を設け、紫外線硬化する
ことにより絵柄部分を凹部とすることを特徴とする。 基材としては、アスベスト、ガラスウール、紙、合板、
布、ポリ塩化ビニル、金属板およびセメント板などがあ
り、用途に応じて適宜に選べばよい。 撥液剤には、シリコーン、ポリエチレンワックス、パラ
フィンワックス、アマイドワックス、ろうワックス、フ
ッ化ビニル化合物などから選んだものを使用する。 硬化抑制剤として使用する金属キレート化剤は、インキ
中に１〜20％、好ましくは１〜10％混入する。金属キレ
ート化剤としてはシュウ酸、コハク酸、マロン酸、シト
ラコン酸、クエン酸、酒石酸、イソクエン酸、ピルピル
酸、グリコール酸、チオグリコール酸、ジグリコール酸
などの脂肪族カルボン酸、サリチル酸、マンデル酸、安
息香酸、サリチルアルデヒド、クロモトローブ酸などの
芳香族カルボン酸あるいはアルデヒドのほか、γ−オキ
シキノリン、アセチルアセトン、ジメチルグリオキシ
ム、1,10−フェナントロリンおよびその誘導体、ベンゾ
イルアセトン、2,2′−ビピリジル−ジメチルジチオカ
ルバミン酸、ハイドロキノン、メチルハイドロキノン、
ｔ−ブチルハイドロキノン、Ｎ−ニトロソジフェニルア
ミン、２−メルカプトベンゾイミダゾール、ｐ−フェニ
レンジアミン、ｐ−ヒドロキシジアミン、テトロヒドロ
キノリン、ｐ−キノン、フェノチアジン、2,6−ジ−ｔ
−ブチル−ｐ−クレゾール−ｔ−ブチルカテコールなど
を用いる。 これら２種以上を混合使用することも可能である。さら
に、Ｎ−ニトロソフェニルヒドロキシルアミンアルミニ
ウム塩を使用すると、印刷インキとしても安定性があり
有用である。 ビヒクルには、フェノール系、尿素系、メラミン系、エ
ポキシ系、ポリエステル系およびポリウレタン系などの
熱硬化性樹脂から選んだものを使用する。 硬化抑制剤および撥液剤を添加したインキを用いる絵柄
の印刷は、一般に行なわれている直刷りや転写法のいず
れによってもよい。 表面樹脂層の形成成分としては、紫外線硬化タイプのポ
リエステル（メタ）アクリレート、ポリウレタン（メ
タ）アクリレート、ポリウレタン（メタ）アクリレー
ト、エポキシ（メタ）アクリレート、不飽和ポリエステ
ル樹脂およびジアリルフタレート樹脂などの樹脂から選
んだものを使用する。The method for producing a decorative material having a synchronous emboss of the present invention is to print an arbitrary pattern on a substrate using an ink to which a curing inhibitor selected from a liquid repellent and a metal chelating agent is added.
It is characterized in that a surface resin layer containing an ultraviolet curable resin whose curing reaction is suppressed by a curing inhibitor is provided thereon and the pattern portion is made into a recess by ultraviolet curing. As the base material, asbestos, glass wool, paper, plywood,
There are cloth, polyvinyl chloride, metal plate, cement plate and the like, which may be appropriately selected according to the application. As the liquid repellent, one selected from silicone, polyethylene wax, paraffin wax, amide wax, wax, vinyl fluoride compound and the like is used. The metal chelating agent used as a curing inhibitor is mixed in the ink in an amount of 1 to 20%, preferably 1 to 10%. Examples of metal chelating agents include carboxylic acids such as oxalic acid, succinic acid, malonic acid, citraconic acid, citric acid, tartaric acid, isocitric acid, pyrupillic acid, glycolic acid, thioglycolic acid, and diglycolic acid, salicylic acid, and mandelic acid. Aromatic carboxylic acids or aldehydes such as benzoic acid, salicylaldehyde and chromotropic acid, γ-oxyquinoline, acetylacetone, dimethylglyoxime, 1,10-phenanthroline and its derivatives, benzoylacetone, 2,2'-bipyridyl -Dimethyldithiocarbamic acid, hydroquinone, methylhydroquinone,
t-butylhydroquinone, N-nitrosodiphenylamine, 2-mercaptobenzimidazole, p-phenylenediamine, p-hydroxydiamine, tetrohydroquinoline, p-quinone, phenothiazine, 2,6-di-t.
-Butyl-p-cresol-t-butylcatechol and the like are used. It is also possible to use a mixture of two or more of these. Furthermore, the use of N-nitrosophenylhydroxylamine aluminum salt is stable and useful as a printing ink. The vehicle is selected from thermosetting resins such as phenolic, urea, melamine, epoxy, polyester and polyurethane resins. The printing of the pattern using the ink to which the curing inhibitor and the liquid repellent are added may be performed by either a direct printing method or a transfer method which is generally used. The surface resin layer forming component is selected from resins such as UV-curable polyester (meth) acrylate, polyurethane (meth) acrylate, polyurethane (meth) acrylate, epoxy (meth) acrylate, unsaturated polyester resin and diallyl phthalate resin. Use the one.
絵柄を印刷したインキには硬化抑制剤が含まれているの
で、この硬化抑制剤により硬化が抑制される紫外線硬化
型樹脂を添加した表面樹脂層の硬化は絵柄の部分におい
て抑制される。すると、その部分の紫外線硬化型樹脂を
含む表面樹脂層が硬化が盛んに起る部分に向って移動す
る。硬化抑制剤が存在しない部分で硬化が盛んに起るこ
とによる、いわば未硬化樹脂をひっぱる働きと、撥液剤
による押し出す方向の働きがあいまって、凹凸がはっき
りあらわれる。従って、絵柄部分は硬化後凹部となり、
それ以外の絵柄の印刷されていない部分は凸部となる。
このようにして、印刷した絵柄に同調したエンボスが形
成される。 その状況を模式的な断面図で示す。基材１上に硬化抑制
剤および撥液剤を添加したインキを用いて任意の絵柄の
印刷２をし、一般インキを用いて一般の印刷３をし、そ
の上に硬化抑制剤により硬化反応が抑制される紫外線硬
化型樹脂を含む表面樹脂層４を設けたところは、第１図
のとおりである。第２図は、撥液作用の下に紫外線を照
射して、硬化させているところを示す。 紫外線硬化の後、絵柄の印刷２部分が凹部となったとこ
ろは、第３図に示すとおりで、2Aは硬化後の絵柄の印刷
層を、4Aは硬化後の表面樹脂層をそれぞれ示す。 なお、絵柄が木目の導管部であって、基材がポリ塩化ビ
ニルのような熱可塑性樹脂のシートであり、導管部がシ
ートの巻き出し方向に平行に印刷されるときは、得られ
る化粧材において、絵柄の印刷2Aおよびその下部のシー
トが上方に凸部となった湾曲を生じることがある。この
現象は、シートを巻き出し方向に引っ張るために、相対
的に硬化の度合いの低い部分が変形することが原因とな
って起る。この現象を防ぐためには、シートの幅が収縮
しない程度にシートの両耳をくわえておくとよく、この
ようにすると、逆に絵柄の印刷2Aの部分およびその下部
のシートは下方に凸部となつた湾曲を生じ、凹部感が増
す。Since the ink on which the pattern is printed contains the curing inhibitor, the curing of the surface resin layer to which the ultraviolet curable resin whose curing is suppressed by the curing inhibitor is added is suppressed in the portion of the pattern. Then, the surface resin layer containing the ultraviolet curable resin in that portion moves toward the portion where curing is actively occurring. Unevenness appears clearly because the function of pulling the uncured resin, so to speak, due to the brisk curing occurring in the part where the curing inhibitor does not exist, and the function of pushing out by the liquid repellent. Therefore, the pattern part becomes a recess after curing,
The other non-printed portions of the pattern are convex portions.
In this way, the embossing that matches the printed design is formed. The situation is shown in a schematic sectional view. An arbitrary picture is printed 2 using an ink to which a curing inhibitor and a liquid repellent are added, a general printing 3 is performed using a general ink, and the curing reaction is suppressed by the curing inhibitor. The surface resin layer 4 containing the ultraviolet-curable resin is provided as shown in FIG. FIG. 2 shows a state where ultraviolet rays are irradiated and cured under the action of a liquid repellent. After UV curing, the area where the two printed portions of the pattern became concave was as shown in FIG. 3, 2A indicates the cured printed layer of the pattern, and 4A indicates the cured surface resin layer. When the design is a wood grain conduit portion, the base material is a sheet of thermoplastic resin such as polyvinyl chloride, and the conduit portion is printed parallel to the unwinding direction of the sheet, the resulting decorative material is obtained. In the above, in some cases, the pattern print 2A and the sheet below the print 2A may be curved with an upward convex portion. This phenomenon occurs because a portion having a relatively low degree of curing is deformed because the sheet is pulled in the unwinding direction. In order to prevent this phenomenon, it is good to hold both ears of the sheet to the extent that the width of the sheet does not shrink, and in this way, the pattern printing 2A part and the sheet below it will have convex parts downward. A dull curve is generated, and the feeling of recess is increased.
下記の配合の硬化抑制剤および撥液剤を添加したインキ
を調製した。「部」はいずれも重量部である。 下記の配合の一般インキを調製した。 塩化ビニル−酢酸ビニル共重合体 10部 メタクリル酸エステル樹脂 ５部 顔料 15部 溶剤 70部 合計100部 下記の配合の紫外線硬化型塗料を調製した。 ウレタンアクリレート 68部 ポリビニルピロリドン 10部 TMPTA 7.5部 増感剤 ２部 ポリエチワックス １部 マイクロシリカ ７部 酢酸ブチル 5.5部 合計100部 厚さ0.15mmの着色ポリ塩化ビニルシートに、上記の硬化
抑制剤および撥液剤を添加したインキで、導管溝部のグ
ラビア印刷をし、さらに一般インキで、導管溝部以外の
グラビア印刷をした。その上に、上記の紫外線硬化型塗
料をロールコーターで全面に10μの厚さに塗布し、紫外
線を照射（３本×80W/cm高圧水銀灯、20m/分）した。 その結果、硬化抑制剤および撥液剤を添加したインキの
パターンに同調したエンボスが形成され、立体感のある
意匠性の高いシートが得られた。 また、上記の実施例において、硬化剤および撥液剤を添
加したインキ100部に対し、さらにイソシアネート「コ
ロネートHL」（日本ポリウレタン製）10部を添加したも
のを使用したところ、導管溝部の表面の耐溶剤性が向上
したシートが得られた。 発明の効果 本発明の方法によれば、表面樹脂層が10μ以下でも、絵
柄に同調したエンボスを有する意匠性の高い化粧材が、
低コストで製造できる。An ink containing a curing inhibitor and a liquid repellent having the following composition was prepared. All "parts" are parts by weight. A general ink having the following formulation was prepared. Vinyl chloride-vinyl acetate copolymer 10 parts Methacrylic acid ester resin 5 parts Pigment 15 parts Solvent 70 parts Total 100 parts An ultraviolet curable coating composition having the following composition was prepared. Urethane acrylate 68 parts Polyvinylpyrrolidone 10 parts TMPTA 7.5 parts Sensitizer 2 parts Polyethylene wax 1 part Microsilica 7 parts Butyl acetate 5.5 parts Total 100 parts To the colored polyvinyl chloride sheet with a thickness of 0.15 mm, the above curing inhibitors and repellent agents are used. Gravure printing was performed on the conduit groove portion with the ink containing the liquid agent, and then gravure printing other than the conduit groove portion was performed using general ink. Then, the above-mentioned UV-curable coating material was applied on the entire surface by a roll coater to a thickness of 10 μm and irradiated with ultraviolet rays (3 × 80 W / cm high pressure mercury lamp, 20 m / min). As a result, embossing was formed in synchronization with the pattern of the ink to which the curing inhibitor and the liquid repellent were added, and a sheet having a three-dimensional appearance and high designability was obtained. In addition, when 100 parts of the ink added with the curing agent and the liquid repellent was further added with 10 parts of isocyanate “Coronate HL” (manufactured by Nippon Polyurethane) in the above-mentioned examples, the surface resistance of the conduit groove part was improved. A sheet having an improved solvent property was obtained. Advantageous Effects of Invention According to the method of the present invention, even if the surface resin layer is 10 μm or less, a decorative material having a high design property having an emboss in synchronization with the pattern,
It can be manufactured at low cost.
第１図は、基材上に絵柄を印刷し、その上に表面樹脂層
を設けたところを示す、模式的な断面図である。 第２図は、紫外線を照射して硬化させているところを示
す、同様な断面図である。 第３図は、紫外線硬化の結果、絵柄の印刷部分が凹部と
なったところを示す、同様な断面図である。 １……基材 ２……絵柄の印刷、2A……同（硬化後） ３……一般の印刷 ４……表面樹脂層、4A……同（硬化後）FIG. 1 is a schematic cross-sectional view showing a pattern printed on a substrate and a surface resin layer provided on the pattern. FIG. 2 is a similar cross-sectional view showing a state where ultraviolet rays are applied to cure. FIG. 3 is a similar cross-sectional view showing that the printed portion of the pattern becomes a recess as a result of ultraviolet curing. 1 ... Substrate 2 ... Design printing, 2A ... Same (after curing) 3 ... General printing 4 ... Surface resin layer, 4A ... Same (after curing)
Claims (3)
製造する方法であって、基材上に撥液剤および金属キレ
ート化剤からえらんだ硬化抑制剤を添加したインキを用
いて任意の絵柄を印刷し、その上に、硬化抑制剤により
硬化反応が抑制される紫外線硬化型樹脂を含む表面樹脂
層を設け、紫外線硬化することにより絵柄部分を凹部と
することを特徴とする方法。1. A method for producing a decorative material having an emboss that is synchronized with a pattern, wherein an arbitrary pattern is formed by using an ink containing a liquid repellent agent and a curing inhibitor selected from a metal chelating agent on a substrate. A method of printing, providing a surface resin layer containing an ultraviolet curable resin, the curing reaction of which is suppressed by a curing inhibitor, on the surface of the resin, and subjecting the pattern portion to a recess by ultraviolet curing.
ワックス、パラフィンワックス、アマイドワックス、ろ
うワックスおよびフッ化ビニル化合物から選んだものを
用い、ビヒクルとして、フェノール系、尿素系、メラミ
ン系、エポキシ系、ポリエステル系およびポリウレタン
系の熱硬化性樹脂から選んだものを用いたインキで絵柄
を印刷して実施する特許請求の範囲第１項に記載の製造
方法。2. A liquid repellent agent selected from silicone, polyethylene wax, paraffin wax, amide wax, wax wax and vinyl fluoride compound is used, and a vehicle is phenol type, urea type, melamine type, epoxy type, polyester. The manufacturing method according to claim 1, wherein a pattern is printed with an ink using an ink selected from a thermosetting resin of a polyurethane type and a polyurethane type.
タイプのポリエステル（メタ）アクリレート、ポリウレ
タン（メタ）アクリレート、エポキシ（メタ）アクリレ
ート、不飽和ポリエステル樹脂およびジアリルフタレー
トなどの樹脂から選んだものを使用して実施する特許請
求の範囲第１項に記載の製造方法。3. A surface resin layer-forming component selected from resins such as UV-curable polyester (meth) acrylate, polyurethane (meth) acrylate, epoxy (meth) acrylate, unsaturated polyester resin and diallyl phthalate. The manufacturing method according to claim 1, which is implemented by using the method.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP60132175A JPH0669547B2 (en) | 1985-06-18 | 1985-06-18 | Method for manufacturing a decorative material having a synchronous embossing |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP60132175A JPH0669547B2 (en) | 1985-06-18 | 1985-06-18 | Method for manufacturing a decorative material having a synchronous embossing |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS61291075A JPS61291075A (en) | 1986-12-20 |
| JPH0669547B2 true JPH0669547B2 (en) | 1994-09-07 |
Family
ID=15075127
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP60132175A Expired - Lifetime JPH0669547B2 (en) | 1985-06-18 | 1985-06-18 | Method for manufacturing a decorative material having a synchronous embossing |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0669547B2 (en) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SE516696C2 (en) | 1999-12-23 | 2002-02-12 | Perstorp Flooring Ab | Process for producing surface elements comprising an upper decorative layer as well as surface elements produced according to the method |
| SE525681C2 (en) | 2001-12-07 | 2005-04-05 | Pergo Ab | Structured panels with matched surface |
| SE526728C2 (en) | 2003-12-11 | 2005-11-01 | Pergo Europ Ab | A method of making panels with a decorative surface |
| JP2009172943A (en) * | 2008-01-28 | 2009-08-06 | Toppan Printing Co Ltd | Printed matter and its manufacturing method |
| JP5195769B2 (en) * | 2010-01-12 | 2013-05-15 | 大日本印刷株式会社 | Processing method of mat processed printed matter having unevenness |
| JP2014087959A (en) * | 2012-10-30 | 2014-05-15 | Achilles Corp | Vinyl chloride-based resin sheet |
| EP4159472A1 (en) * | 2018-10-31 | 2023-04-05 | Jesús Francisco Barberan Latorre | Method for producing a three-dimensional structure on a surface of a flat substrate, resulting substrate, and device for producing the substrate according to the method |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5896552A (en) * | 1981-12-03 | 1983-06-08 | 大日精化工業株式会社 | Manufacture of decorative board |
-
1985
- 1985-06-18 JP JP60132175A patent/JPH0669547B2/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| JPS61291075A (en) | 1986-12-20 |
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