JPH0663374A - Solubilizing agent composition - Google Patents
Solubilizing agent compositionInfo
- Publication number
- JPH0663374A JPH0663374A JP4242570A JP24257092A JPH0663374A JP H0663374 A JPH0663374 A JP H0663374A JP 4242570 A JP4242570 A JP 4242570A JP 24257092 A JP24257092 A JP 24257092A JP H0663374 A JPH0663374 A JP H0663374A
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- JP
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- Prior art keywords
- surfactant
- solubilizing
- temperature range
- solubilizing agent
- agent composition
- Prior art date
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- Medicinal Preparation (AREA)
- Cosmetics (AREA)
- Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
Abstract
Description
【０００１】[0001]
【産業上の利用分野】本発明は、油性成分を水に溶解さ
せることのできる可溶化剤に関し、更に詳細には、芳香
剤や化粧品等に添加して香料や油脂類等の可溶化剤とし
て用いることができ、しかも、広い温度範囲にわたって
可溶化領域を有する可溶化剤組成物に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a solubilizing agent capable of dissolving an oily component in water, and more specifically, as a solubilizing agent for perfumes, oils and fats by adding it to fragrances and cosmetics. The present invention relates to a solubilizing agent composition which can be used and has a solubilizing region over a wide temperature range.
【０００２】[0002]
【従来の技術】従来より、芳香剤や化粧品等に香料や油
脂類の油性成分を配合するにあたっては、成分の分離を
防止するため、界面活性剤などを可溶化剤として添加す
ることが行われていた。2. Description of the Related Art Conventionally, when compounding an oily component such as a fragrance or an oil and fat into a fragrance or cosmetics, a surfactant or the like is added as a solubilizing agent in order to prevent separation of the components. Was there.
【０００３】この可溶化剤については、これまでにも多
くのものが提案されており、例えば、水素添加したヒマ
シ油とγ−ブチロラクトンとの反応生成物のエチレンオ
キシド付加物（特開昭５２−９８６８９号）、分枝アル
コールのエチレンオキシド付加物（特開昭５２−２５０
３８号）、分枝アルキル基あるいはアルケニル基をもつ
高級アルコールのアルキレンオキシド付加物（特開昭５
４−１３２４９１号）、フェノール類のエチレンオキシ
ドまたはプロピレンオキシド付加物（特開昭５７−７０
１９７号）、アルキルグリセリンエーテルリン酸エステ
ル（特開昭６０−６１０３０号）等が知られている。Many solubilizing agents have been proposed so far, for example, an ethylene oxide adduct of a reaction product of hydrogenated castor oil and γ-butyrolactone (Japanese Patent Laid-Open No. 52-98689). No.), an ethylene oxide adduct of a branched alcohol (JP-A-52-250).
No. 38), an alkylene oxide adduct of a higher alcohol having a branched alkyl group or an alkenyl group (Japanese Patent Laid-Open No. Sho 5).
4-132491), an ethylene oxide or propylene oxide adduct of phenols (JP-A-57-70).
197), alkyl glycerin ether phosphate (JP-A-60-61030) and the like are known.
【０００４】また、界面活性剤を組合せた可溶化剤とし
ては、例えば、イオン性界面活性剤と非イオン性界面活
性剤および電解質との混合物（特開昭５８−１３１１２
７号）、イオン性界面活性剤と非イオン性界面活性剤の
特定範囲での組合せ（特開昭５８−１２８３１１号）、
鎖状高分子カルボン酸とプロトン受容基をもつ非イオン
性高分子化合物の組合せ（特開昭５８−１０４６２６
号）、フッ素界面活性剤と他の界面活性剤の組合せ（特
開昭６３−２２２７６７号）、Ｃ1〜Ｃ6アルカノールの
プロピレンオキシドとエチレンオキシド重合体および非
イオン性乳化剤の組合せ（特開平１−５２４７０号）等
が知られている。As a solubilizing agent in which a surfactant is combined, for example, a mixture of an ionic surfactant, a nonionic surfactant and an electrolyte (Japanese Patent Laid-Open No. 58-13112).
No. 7), a combination of an ionic surfactant and a nonionic surfactant in a specific range (JP-A-58-128311),
A combination of a chain polymer carboxylic acid and a nonionic polymer compound having a proton accepting group (JP-A-58-104626).
No.), a combination of a fluorosurfactant and another surfactant (JP-A-63-222767), a combination of a propylene oxide of a C 1 -C 6 alkanol with an ethylene oxide polymer and a nonionic emulsifier (JP-A-1-221). No. 52470) and the like are known.
【０００５】ところで、一般に芳香剤や化粧品等は輸
送、保管および使用期間中に、たとえば−５℃から＋６
０℃程度までの広い温度条件におかれる可能性がある。
従って、これらに用いられる可溶化剤には、このよう
な広い温度範囲にわたって優れた可溶化性能を有するこ
とが求められる。 このような、広い温度範囲における
可溶化性能は、例えば、特開昭５８−１３１１２７号、
特開昭５８−１２８３１１号、特開昭６３−２２２７６
７号においても追求されている。By the way, in general, fragrances, cosmetics and the like are transported, stored and used during, for example, -5 ° C to +6.
There is a possibility of being exposed to wide temperature conditions up to about 0 ° C.
Therefore, the solubilizing agent used for these is required to have excellent solubilizing performance over such a wide temperature range. Such solubilization performance in a wide temperature range is described in, for example, JP-A-58-131127,
JP-A-58-128311, JP-A-63-22276
It is also pursued in No. 7.
【０００６】しかしながら、これまでに提案された可溶
化剤はいずれも、広い温度範囲にわたる可溶化性能が充
分でない、原料物質が高価であるなどの問題点を有して
おり、必ずしも満足すべきものではなかった。However, all of the solubilizers proposed so far have problems such as insufficient solubilization performance over a wide temperature range and high cost of raw material, and they are not always satisfactory. There wasn't.
【０００７】[0007]
【発明が解決しようとする課題】従って、広い温度範囲
にわたって優れた可溶化剤性能を有し、かつ安価な可溶
化剤の開発が切望されていた。Therefore, it has been earnestly desired to develop an inexpensive solubilizing agent having excellent solubilizing agent performance over a wide temperature range.
【０００８】[0008]
【課題を解決するための手段】本発明者らは上記実情に
鑑み、可溶化剤組成物について鋭意研究を行なった結
果、狭い温度範囲で良好な可溶化性能を持つ界面活性剤
と、広い温度範囲で優れた乳化性能を示す界面活性剤と
を組み合わせることにより、広い温度範囲での可溶化性
能を有する界面活性剤組成物が得られることを見出し
た。In view of the above circumstances, the inventors of the present invention have conducted earnest research on a solubilizing agent composition, and as a result, have found that a surfactant having a good solubilizing performance in a narrow temperature range and a wide temperature range. It has been found that a surfactant composition having solubilizing performance in a wide temperature range can be obtained by combining with a surfactant exhibiting excellent emulsification performance in the range.
【０００９】即ち、 広い温度範囲にわたって良好な
乳化性能を有する界面活性剤と、狭い温度範囲で良好
な可溶化性能を示す界面活性剤とを組合せることによっ
て、相乗的に可溶化性能が増強され、 の界面活性剤
で得られたのと同様の広い温度範囲にわたって、 の
界面活性剤で得られたと同様の良好な可溶化性能が得ら
れるという知見を得た。さらに、本発明可溶化剤に陰イ
オン界面活性剤を添加することにより、その可溶化性能
が一層高まることをも見出し、本発明を完成した。That is, by combining a surfactant having a good emulsifying performance over a wide temperature range and a surfactant having a good solubilizing performance over a narrow temperature range, the solubilizing performance is synergistically enhanced. It was found that the same good solubilization performance as that obtained with the surfactant can be obtained over a wide temperature range similar to that obtained with the surfactant. Furthermore, they have found that the solubilizing performance of the solubilizing agent of the present invention is further improved by adding an anionic surfactant, and the present invention has been completed.
【００１０】すなわち、本発明は、広い温度範囲にわた
って乳化性能を示す界面活性剤と、狭い温度範囲で可溶
化性能を示す界面活性剤とを組合せてなる可溶化剤組成
物を提供するものである。That is, the present invention provides a solubilizing agent composition comprising a combination of a surfactant exhibiting emulsifying performance over a wide temperature range and a surfactant exhibiting solubilizing performance over a narrow temperature range. .
【００１１】本明細書中において、広い温度範囲とは、
芳香剤や化粧品等が輸送、保管および使用期間中にさら
される可能性のある温度範囲をいい、一般的には−５℃
から＋６０℃程度の温度範囲を意味する。 一方、狭い
温度範囲とは、上記の温度範囲の中の一部分を意味し、
一般にその温度幅は１０℃から２０℃程度の範囲であ
る。In the present specification, a wide temperature range means
The temperature range to which fragrances, cosmetics, etc. may be exposed during transportation, storage and use, generally -5 ° C.
To + 60 ° C. is meant. On the other hand, the narrow temperature range means a part of the above temperature range,
Generally, the temperature range is in the range of 10 ° C to 20 ° C.
【００１２】また、界面活性剤が乳化性能を有すると
は、被乳化物の重量に対して、例えば０.５倍から３倍
程度の添加量で安定した乳化状態を保持し得る能力をい
い、界面活性剤が可溶化性能を有するとは、被可溶化物
の重量に対して、例えば０.５倍から３倍程度の添加量
で均一かつ完全な溶解状態を保持し得る能力をいう。The fact that the surfactant has an emulsifying property means the ability to maintain a stable emulsified state with an addition amount of, for example, about 0.5 to 3 times the weight of the substance to be emulsified, The fact that the surfactant has solubilizing ability means the ability to maintain a uniform and complete dissolved state with an addition amount of, for example, about 0.5 to 3 times the weight of the substance to be solubilized.
【００１３】本発明で用いられる広い温度範囲にわたっ
て乳化性能を有する界面活性剤（以下、「乳化性界面活
性剤」という）としては、例えば、エチレンオキシドと
プロピレンオキシドの共重合体およびアルキレンオキシ
ド付加不飽和カルボン酸（またはエステル）の共重合体
をあげることができる。The surfactant having emulsifying ability over a wide temperature range used in the present invention (hereinafter referred to as "emulsifying surfactant") is, for example, a copolymer of ethylene oxide and propylene oxide and alkylene oxide addition unsaturated. Examples thereof include copolymers of carboxylic acid (or ester).
【００１４】このうち、エチレンオキシドとプロピレン
オキシドの共重合体の好ましい例は、平均分子量が２,
５００〜５,０００の範囲で、エチレンオキシド単位の
含有率が３０％〜５０％程度のものである。具体的に
は、松本油脂製薬（株）製 アクチノールＰ−３０３５
等を例示することが出来る。Among these, preferred examples of the copolymer of ethylene oxide and propylene oxide have an average molecular weight of 2,
In the range of 500 to 5,000, the content of ethylene oxide units is about 30% to 50%. Specifically, Actinol P-3035 manufactured by Matsumoto Yushi-Seiyaku Co., Ltd.
Etc. can be illustrated.
【００１５】また、アルキレンオキシド付加不飽和カル
ボン酸（又はエステル）の共重合体の例としては、ポリ
エチレングリコールモノメタクリレートとブチルメタク
リレートの共重合体、メトキシポリエチレングリコール
アクリレートとドデシルアクリレートのの共重合体など
を挙げることができる。 これらの好ましい平均分子量
は、１０００〜５０万であり、また、共重合体中のアル
キレンオキシド付加不飽和カルボン酸（又はエステル）
の含有率は３〜５５重量％である。Examples of copolymers of alkylene oxide-added unsaturated carboxylic acid (or ester) include copolymers of polyethylene glycol monomethacrylate and butyl methacrylate, copolymers of methoxy polyethylene glycol acrylate and dodecyl acrylate, and the like. Can be mentioned. The preferred average molecular weight of these is 1,000 to 500,000, and the alkylene oxide addition unsaturated carboxylic acid (or ester) in the copolymer is
Is 3 to 55% by weight.
【００１６】アルキレンオキシド付加不飽和カルボン酸
（又はエステル）共重合体の具体的な例としては、日本
触媒化学工業（株）製高分子界面活性剤ＨＰＳ−Ｎ５９
２、ＨＰＳ−Ｎ５９５、ＨＰＳ−Ｎ５９８（特開平１−
２９７１３７号）等をあげることができる。Specific examples of alkylene oxide-added unsaturated carboxylic acid (or ester) copolymers include polymer surfactant HPS-N59 manufactured by Nippon Shokubai Kagaku Kogyo Co., Ltd.
2, HPS-N595, HPS-N598 (JP-A-1-
No. 297137) and the like.
【００１７】一方、比較的狭い温度範囲で良好な可溶化
性能を示す界面活性剤（以下、「可溶化性界面活性剤」
という）としては、例えば、ポリオキシエチレンアルキ
ルフェニルエーテル、ポリオキシエチレンアルキルエー
テルおよびポリオキシエチレンポリスチリルフェニルエ
ーテルを挙げることが出来る。On the other hand, a surfactant showing good solubilizing performance in a relatively narrow temperature range (hereinafter referred to as "solubilizing surfactant").
Can include, for example, polyoxyethylene alkyl phenyl ether, polyoxyethylene alkyl ether and polyoxyethylene polystyryl phenyl ether.
【００１８】このうち、ポリオキシエチレンアルキルフ
ェニルエーテルの好ましい例としては、アルキル基の炭
素数が６〜１２で、エチレンオキシド付加モル数が５〜
３０のものである。 また、ポリオキシエチレンアルキ
ルエーテルの好ましい例としては、アルキル基の炭素数
が８〜２０で、エチレンオキシド付加モル数が５〜３０
のものである。また、ポリオキシエチレンポリスチリル
フェニルエーテルの好ましい例としては、エチレンオキ
シド付加モル数が１３〜２５のものである。Of these, preferred examples of polyoxyethylene alkylphenyl ethers are alkyl groups having 6 to 12 carbon atoms and ethylene oxide addition mole numbers of 5 to 5.
30's. Moreover, as a preferable example of polyoxyethylene alkyl ether, carbon number of an alkyl group is 8-20, and ethylene oxide addition mole number is 5-30.
belongs to. Further, a preferable example of the polyoxyethylene polystyryl phenyl ether is one having an ethylene oxide addition mole number of 13 to 25.
【００１９】本発明の可溶化剤組成物は、上記乳化性界
面活性剤および可溶化性界面活性剤を通常１：９ないし
９：１の割合で混合することにより調製できる。 この
乳化性界面活性剤と可溶化性界面活性剤は、それぞれ単
独であるいは２種以上を組合せて用いることができる。The solubilizing agent composition of the present invention can be prepared by mixing the emulsifying surfactant and the solubilizing surfactant in a ratio of usually 1: 9 to 9: 1. The emulsifying surfactant and the solubilizing surfactant can be used alone or in combination of two or more kinds.
【００２０】本発明の可溶化剤は、必須成分である上記
の乳化性界面活性剤および可溶化性界面活性剤に加え、
更に必要に応じ他の成分、例えば、他の界面活性剤やエ
タノール等の溶媒を加えて調整することも可能である。
これらの任意成分の中で、特に好適に用いることがで
きるものは、アルキルベンゼンスルホン酸塩、アルキル
硫酸エステル塩、ジアルキルスルホコハク酸塩等の陰イ
オン界面活性剤である。
The solubilizing agent of the present invention comprises, in addition to the above-mentioned emulsifying surfactant and solubilizing surfactant, which are essential components,
Furthermore, if necessary, other components, for example, other surfactants and solvents such as ethanol can be added for adjustment.
Among these optional components, those which can be particularly preferably used are anionic surfactants such as alkylbenzene sulfonate, alkyl sulfate ester salt, and dialkylsulfosuccinate.
【００２１】本発明者らは、これらの陰イオン界面活性
剤を本発明の可溶化剤組成物に添加することにより、可
溶化性能が一層増強され、可溶化領域がさらに高温側に
広がるとの知見を得ている。 これらの陰イオン界面活
性剤を加える場合、本発明可溶化剤組成物（乳化性界面
活性剤および可溶化性界面活性剤の和）と陰イオン界面
活性剤の比率は通常９５：５ないし５０：５０である。The inventors of the present invention have found that by adding these anionic surfactants to the solubilizing agent composition of the present invention, the solubilizing performance is further enhanced and the solubilizing region is further expanded to the high temperature side. I have knowledge. When these anionic surfactants are added, the ratio of the solubilizer composition of the present invention (the sum of the emulsifying surfactant and the solubilizing surfactant) and the anionic surfactant is usually 95: 5 to 50: 50.
【００２２】以上の如くして得られた可溶化剤組成物
は、油性成分を水系成分中に溶解させて調製される各種
の組成物、例えば、芳香剤、化粧料、医薬、殺虫剤、防
虫剤等に広く使用されるが、特に、高温から低温までの
温度変化にさらされる組成物、例えば芳香剤や化粧料に
有利に使用することができる。The solubilizing agent composition obtained as described above is various compositions prepared by dissolving an oily component in an aqueous component, for example, a fragrance, a cosmetic, a medicine, an insecticide, an insect repellent. It is widely used as an agent and the like, and particularly, it can be advantageously used for a composition which is exposed to a temperature change from a high temperature to a low temperature, such as an aromatic and a cosmetic.
【００２３】例えば、本発明の可溶化剤組成物を上記目
的に使用する場合、その添加量は被可溶化物の重量に対
して、０.５〜３倍程度となるようにすることが好まし
い。For example, when the solubilizing agent composition of the present invention is used for the above purpose, the addition amount thereof is preferably about 0.5 to 3 times the weight of the substance to be solubilized. .
【００２４】[0024]
【実施例】次に、実施例および比較例を挙げ、本発明を
更に詳しく説明するが、本発明はこれら実施例になんら
制約されるものでない。EXAMPLES Next, the present invention will be described in more detail with reference to Examples and Comparative Examples, but the present invention is not limited to these Examples.
【００２５】実 施 例 １ 表１に示す組成の界面活性剤を混合し、可溶化剤組成物
を調製した。得られた可溶化剤組成物について、その可
溶化性能を次の様にして調べた。すなわち、１００ｍｌ
ビーカーにグリーン系香料２.０ｇおよび本発明可溶化
剤３.０ｇを入れ、室温においてマグネチックスタラー
で撹拌しながら水９５.０ｇを徐々に加えて香料・可溶
化剤混合液を調製した。Example 1 A surfactant having a composition shown in Table 1 was mixed to prepare a solubilizing agent composition. The solubilizing performance of the obtained solubilizing agent composition was examined as follows. That is, 100 ml
2.0 g of the green fragrance and 3.0 g of the solubilizer of the present invention were placed in a beaker, and 95.0 g of water was gradually added while stirring with a magnetic stirrer at room temperature to prepare a fragrance / solubilizer mixture.
【００２６】この混合液を５等分し、それぞれ−５℃、
５℃、２５℃、４０℃および６０℃に保持し、経時初期
（２４時間後）および１ヵ月後に混合液の状態を観察し
た。また比較として各種界面活性剤を単独で配合したも
のについても同様の条件で試験を行った（比較例１〜
３）。 この結果を表２に示す。This mixed solution was divided into 5 equal parts, each at -5 ° C,
The mixture was kept at 5 ° C, 25 ° C, 40 ° C and 60 ° C, and the state of the mixed solution was observed at the beginning of aging (after 24 hours) and after 1 month. Further, as a comparison, a test was conducted under the same conditions even for those in which various surfactants were blended alone (Comparative Examples 1 to 1).
3). The results are shown in Table 2.
【００２７】 * アクチノールＰ−３０３５（松本油脂製薬（株）
製） ** アルキレンオキシド付加不飽和カルボン酸またはエ
ステル共重合体（日本触媒化学工業（株）製）[0027] * Actinol P-3035 (Matsumoto Yushi-Seiyaku Co., Ltd.)
Manufactured) ** Alkylene oxide-added unsaturated carboxylic acid or ester copolymer (manufactured by Nippon Shokubai Chemical Co., Ltd.)
【００２８】 + 液の状態 ○ 透明（可溶化状態） △ 不透明均一（乳化状態） × 相分離（不均一）[0028] + Liquid state ○ Transparent (solubilized state) △ Opaque uniform (emulsified state) × Phase separation (non-uniform)
【００２９】[0029]
【発明の効果】本発明の可溶化剤組成物は、−５℃から
＋６０℃までの広い温度範囲で、良好な可溶化性能を示
すため、芳香剤や化粧品に使用した場合、香料や油脂類
等の分離がほとんどなくなり、製品の安定性を高めるこ
とができる。また、本発明の可溶化剤組成物では、原料
化合物を比較的安価な物質から種々組合せて用いること
が可能であり、経済的にも利用価値の高いものである。 以 上The solubilizer composition of the present invention exhibits good solubilizing performance in a wide temperature range from -5 ° C to + 60 ° C. Therefore, when it is used as a fragrance or a cosmetic product, fragrances and oils and fats are used. Almost no separation occurs, and the stability of the product can be improved. Further, in the solubilizing agent composition of the present invention, it is possible to use various raw material compounds in various combinations from relatively inexpensive substances, which is economically highly useful. that's all
───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.5 識別記号 庁内整理番号 ＦＩ 技術表示箇所 Ｂ０１Ｆ 17/42 ─────────────────────────────────────────────────── ─── Continuation of the front page (51) Int.Cl. 5 Identification code Internal reference number FI technical display location B01F 17/42
Claims (6)
界面活性剤と、狭い温度範囲で可溶化性能を示す界面活
性剤とを組合せてなる可溶化剤組成物。1. A solubilizing agent composition comprising a combination of a surfactant exhibiting emulsifying performance over a wide temperature range and a surfactant exhibiting solubilizing performance over a narrow temperature range.
界面活性剤が、−５℃から＋６０℃の範囲で良好な乳化
性能を示すものであり、狭い温度範囲で可溶化剤性能を
示す界面活性剤が上記温度範囲の中の１０℃〜２０℃の
温度幅で可溶化性能を示す界面活性剤である請求項第１
項記載の可溶化剤組成物。2. A surfactant having an emulsifying property over a wide temperature range, which exhibits a good emulsifying property in the range of -5 ° C. to + 60 ° C., and a solubilizing agent having a narrow temperature range. Is a surfactant exhibiting solubilizing performance in a temperature range of 10 ° C to 20 ° C within the above temperature range.
The solubilizing agent composition according to the item.
界面活性剤が、エチレンオキシドとプロピレンオキシド
の共重合体およびアルキレンオキシド付加不飽和カルボ
ン酸（又はエステル）の共重合体から選ばれる界面活性
剤の１種または２種以上である請求項第１項記載の可溶
化剤組成物。3. A surfactant having an emulsifying property over a wide temperature range, which is selected from a copolymer of ethylene oxide and propylene oxide and a copolymer of alkylene oxide-added unsaturated carboxylic acid (or ester). The solubilizer composition according to claim 1, wherein the solubilizer composition is one kind or two or more kinds.
性剤が、ポリオキシエチレンアルキルフェニルエーテ
ル、ポリオキシエチレンアルキルエーテルおよびポリオ
キシエチレンポリスチリルフェニルエーテルから選ばれ
る界面活性剤の１種または２種以上である請求項第１項
記載の可溶化剤組成物。4. The surfactant having a solubilizing ability in a narrow temperature range is one or two selected from polyoxyethylene alkyl phenyl ether, polyoxyethylene alkyl ether and polyoxyethylene polystyryl phenyl ether. The solubilizer composition according to claim 1, which comprises at least one species.
請求項第１項ないし第４項記載のいずれかの項記載の可
溶化剤組成物。5. The solubilizer composition according to any one of claims 1 to 4, further containing an anionic surfactant.
ンスルホン酸塩、アルキル硫酸エステル塩およびジアル
キルスルホコハク酸塩から選ばれる界面活性剤の１種又
は２種以上である請求項第５項記載の可溶化剤組成物。6. The solubilization according to claim 5, wherein the anionic surfactant is one or more surfactants selected from alkylbenzene sulfonates, alkyl sulfate ester salts and dialkylsulfosuccinates. Agent composition.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP24257092A JP3305369B2 (en) | 1992-08-20 | 1992-08-20 | Solubilizer composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP24257092A JP3305369B2 (en) | 1992-08-20 | 1992-08-20 | Solubilizer composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH0663374A true JPH0663374A (en) | 1994-03-08 |
| JP3305369B2 JP3305369B2 (en) | 2002-07-22 |
Family
ID=17091042
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP24257092A Expired - Lifetime JP3305369B2 (en) | 1992-08-20 | 1992-08-20 | Solubilizer composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP3305369B2 (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003231625A (en) * | 2002-02-04 | 2003-08-19 | Shiseido Co Ltd | Perfume composition |
| JP2007099982A (en) * | 2005-10-06 | 2007-04-19 | T Hasegawa Co Ltd | Solubilizer composition |
| JP2011120985A (en) * | 2009-12-09 | 2011-06-23 | Sanyo Chem Ind Ltd | Perfume solubilizer |
-
1992
- 1992-08-20 JP JP24257092A patent/JP3305369B2/en not_active Expired - Lifetime
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003231625A (en) * | 2002-02-04 | 2003-08-19 | Shiseido Co Ltd | Perfume composition |
| JP2007099982A (en) * | 2005-10-06 | 2007-04-19 | T Hasegawa Co Ltd | Solubilizer composition |
| JP2011120985A (en) * | 2009-12-09 | 2011-06-23 | Sanyo Chem Ind Ltd | Perfume solubilizer |
Also Published As
| Publication number | Publication date |
|---|---|
| JP3305369B2 (en) | 2002-07-22 |
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