JPH0653992B2 - Flameproofing agent for synthetic fiber materials - Google Patents
Flameproofing agent for synthetic fiber materialsInfo
- Publication number
- JPH0653992B2 JPH0653992B2 JP60215780A JP21578085A JPH0653992B2 JP H0653992 B2 JPH0653992 B2 JP H0653992B2 JP 60215780 A JP60215780 A JP 60215780A JP 21578085 A JP21578085 A JP 21578085A JP H0653992 B2 JPH0653992 B2 JP H0653992B2
- Authority
- JP
- Japan
- Prior art keywords
- phosphate
- flameproofing agent
- synthetic fiber
- agent
- fiber materials
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Landscapes
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Description
【発明の詳細な説明】 産業上の利用分野 本発明は、合成繊維材料、特にポリエステル繊維又はポ
リアミド繊維材料用防炎加工剤に関する。TECHNICAL FIELD The present invention relates to a flameproofing agent for synthetic fiber materials, in particular polyester fiber or polyamide fiber materials.
従来技術 合成繊維材料用防炎加工剤の一つとして、多臭素化有機
化合物が知られている。これらの化合物は、常温で固体
であり、かつ水不溶性であることから、従来は水系分散
体として使用されてきた。BACKGROUND ART A polybrominated organic compound is known as one of the flameproofing agents for synthetic fiber materials. Since these compounds are solid at room temperature and insoluble in water, they have been conventionally used as an aqueous dispersion.
水系分散体の製造方法としては、例えば特公昭５３−８
８４０号、特開昭５７−１３７３７７号などの公報に記
載されている通り、分散剤又は保護コロイドを含む水中
において粉砕機により、機械的に微粉化し、分散化を計
っているのが現状である。As a method for producing an aqueous dispersion, for example, JP-B-53-8
As described in JP-A No. 840 and Japanese Patent Application Laid-Open No. 57-137377, the current situation is to mechanically pulverize and disperse the particles in a water containing a dispersant or a protective colloid with a pulverizer. .
しかし、この方法では固体状のものを単に機械力によっ
て、物理的に微粉化しているにすぎず、得られる粒子の
径には自ずから限界があり、通常１μ以下の平均粒径を
有するものを得ることは極めて困難であった。However, in this method, a solid substance is merely finely pulverized by mechanical force, and the diameter of the obtained particles is naturally limited, and a substance having an average particle diameter of 1 μm or less is usually obtained. It was extremely difficult.
織物加工の場合、加工剤の粒径は極めて重要な因子であ
る。粒径が小さければ小さい程、加工剤として望まし
い。特に加工剤の効果の耐久性が要望される場合、粒径
が大きくなることは、繊維内部への加工剤の拡散が著し
く低下するため、致命的欠陥となる。In the case of textile processing, the particle size of the processing agent is a very important factor. The smaller the particle size, the more desirable as a processing agent. In particular, when durability of the effect of the processing agent is desired, the increase in the particle size is a fatal defect because the diffusion of the processing agent into the fiber is significantly reduced.
発明の目的 本発明は、多臭素化有機化合物、特にその化学構造から
繊維の後処理には適用し難いとされる1,2,5,6,9,10−ヘ
キサブロモシクロドデカンを使用して、合成繊維材料
に、安定して耐久性ある防炎加工をなしうる防炎加工剤
を提供することを目的とする。OBJECT OF THE INVENTION The present invention uses polybrominated organic compounds, especially 1,2,5,6,9,10-hexabromocyclododecane, which is difficult to apply to post-treatment of fibers due to its chemical structure. An object of the present invention is to provide a flameproofing agent capable of stably and durablely flameproofing a synthetic fiber material.
発明の構成 本発明の加工剤は、 イ）1,2,5,6,9,10−ヘキサブロモシクロドデカン ロ）トリス（1,3−ジクロロプロピル）ホスフェート、
トリス（β−クロロエチル）ホスフェート、トリフェニ
ールホスフェート、トリクレジルホスフェート、トリキ
シレニルホスフェート、ジメチルメチルホスフォネート
及びジエチルＮ，Ｎ−ビス（２−ヒドロキシエチル）ア
ミノメチルホスフォネートから選ばれる燐含有化合物 ハ）下記の構造式Ｉ及びIIで表される化合物の少なくと
も一種 （但し、ｌは１〜３の整数、ｎは１０〜３０の整数、Ｘ
はＮａ又はＮＨ4 を示す）、の３成分を含有するもので
ある。Composition of the Invention The processing agent of the present invention comprises: a) 1,2,5,6,9,10-hexabromocyclododecanero) tris (1,3-dichloropropyl) phosphate,
Phosphorus-containing material selected from tris (β-chloroethyl) phosphate, triphenylphosphate, tricresylphosphate, trixylenylphosphate, dimethylmethylphosphonate and diethyl N, N-bis (2-hydroxyethyl) aminomethylphosphonate Compound c) At least one compound represented by the following structural formulas I and II (However, l is an integer of 1 to 3, n is an integer of 10 to 30, X is
Indicates Na or NH 4 ), and three components.
イ）の1,2,5,6,9,10−ヘキサブロモシクロドデカンは、
液状処理剤として使用しにくいものであるが、ロ）の燐
含有化合物は、常温又は加温により、イ）の1,2,5,6,9,
10−ヘキサブロモシクロドデカンを単分子状に溶解し得
ると共に、臭素と燐の相乗効果により、合成繊維に優れ
た防炎性能を付与可能とするものである。B) 1,2,5,6,9,10-hexabromocyclododecane is
Although it is difficult to use as a liquid treatment agent, the phosphorus-containing compound in (b) can be added to 1,2,5,6,9,
It is possible to dissolve 10-hexabromocyclododecane in a monomolecular form, and it is possible to impart excellent flameproof performance to synthetic fibers due to the synergistic effect of bromine and phosphorus.
更に、ハ）の化合物としては、例えばトリスチレン化フ
ェノール・エチレンオキサイド付加物、トリスチレン化
フェノール・エチレンオキサイド付加物の硫酸化物等が
挙げられる。これらの化合物はロ）の燐系化合物への
イ）の多臭素化有機化合物の溶解性を助けるとともに、
イ）及びロ）の２種の化合物の繊維上への均一付与性を
高め、併せて、これら２種の化合物が熱処理により繊維
内部に均一に拡散するのを助ける働きをする。Examples of the compound (c) include tristyrenated phenol / ethylene oxide adducts, tristyrenated phenol / ethylene oxide adducts, and the like. These compounds assist the solubility of the b) polybrominated organic compound of b) in the phosphorus compound of b),
The function of uniformly imparting the two compounds of (a) and (2) onto the fiber is enhanced, and at the same time, it serves to help the two compounds uniformly diffuse into the inside of the fiber by heat treatment.
そのため、従来の多臭素化有機化合物分散体によるもの
に比べ、加工剤の効果の耐久性に優れること、加工布の
風合が極めて柔軟であること、粉ふき減少（加工布の表
面が白粉が付着したように白くなる現象）がないことな
どの大きな特長が得られる。Therefore, compared with the conventional polybrominated organic compound dispersion, the effect of the processing agent is superior in durability, the texture of the processed cloth is extremely flexible, and the dust reduction (the surface of the processed cloth has a white powder). It is possible to obtain major features such as no phenomenon that it becomes white as if it was attached.
化合物イ）、ロ）及びハ）の配合比率は特に限定されな
いが、重量割合で１０〜３０％：５０〜８０％：１０〜
２５％であるのが望ましい。The compounding ratio of the compounds a), b) and c) is not particularly limited, but is 10 to 30% by weight: 50 to 80%: 10 by weight.
It is preferably 25%.
本発明の防炎加工剤は、そのままパークレン、トリクレ
ン等の一般的な溶剤で希釈して、通常のパディング、予
備乾燥、熱処理により繊維に加工することが可能であ
る。また、本発明の防炎加工剤は、ホモミキサー等で撹
拌しながら水を徐々に添加していくことにより、簡単に
乳化可能なため、他の一般的な加工剤と同様に水系でパ
ッド−ドライ−キュア方式による加工も可能となる。液
流染色機、ビーム染色機、チーズ染色機、パッケージ染
色機等を用いた、所謂、浸漬加工方式による加工も可能
である。The flameproofing agent of the present invention can be directly diluted with a general solvent such as Perklen or trichlene and then processed into fibers by ordinary padding, preliminary drying and heat treatment. Further, since the flameproofing agent of the present invention can be easily emulsified by gradually adding water while stirring with a homomixer or the like, it can be padded in an aqueous system like other general finishing agents. Processing by the dry-cure method is also possible. Processing by a so-called dipping processing method using a jet dyeing machine, a beam dyeing machine, a cheese dyeing machine, a package dyeing machine or the like is also possible.
いずれにしても、本発明の防炎加工剤は、常温で固体の
多臭素化化合物を、燐系溶剤により単分子状に溶解して
含有しているため、水系乳化体とした場合も、従来の機
械的粉砕機による水系分散体に比べ、その粒径は通常約
0.3 μ以下と極めて小さくなり、均一な安定した加工を
可能とする。In any case, since the flameproofing agent of the present invention contains a polybrominated compound that is solid at room temperature and is dissolved in a monomolecular form with a phosphorus-based solvent, even when it is used as an aqueous emulsion, Compared with the water-based dispersion by mechanical crusher, the particle size is usually about
It is extremely small, 0.3 μ or less, enabling uniform and stable machining.
次に、実施例により、本発明を更に詳しく説明する。な
お、実施例における加工布の難燃性試験は下記の方法に
よった。Next, the present invention will be described in more detail by way of examples. The flame retardancy test of the work cloth in the examples was carried out by the following method.
１）難燃性試験：ＪＩＳ−１０９１Ｄ法 （数値が大きい程、難燃性に優れる。） ２）洗濯法： ＪＩＳ Ｌ−１０４２法 ３）ドライクリーニング法： ＪＩＳ Ｌ−１０１８法 実施例１． 加熱及び撹拌装置付のガラス製容器に1,2,5,6,9,10−ヘ
キサブロモシクロドデカン１５ｇ、トリス（β−クロロ
エチル）ホスフェート５５ｇ、トリスチレン化フェノー
ル・エチレンオキサイド１０モル付加体１０ｇを採取し
撹拌しながら、徐々に加熱し、１２０℃で１５分間保
ち、透明な液状物を得た。次いで、９０℃まで冷却し、
テトラクロルエチレン６０ｇを添加後、常温まで冷却し
た。1) Flame retardancy test: JIS-1091D method (The larger the value, the better the flame retardancy.) 2) Washing method: JIS L-1042 method 3) Dry cleaning method: JIS L-1018 method Example 1. In a glass container equipped with a heating and stirring device, 15 g of 1,2,5,6,9,10-hexabromocyclododecane, 55 g of tris (β-chloroethyl) phosphate, and 10 g of a 10 mol adduct of tristyrenated phenol / ethylene oxide were added. While collecting and stirring, the mixture was gradually heated and kept at 120 ° C. for 15 minutes to obtain a transparent liquid material. Then cool to 90 ° C,
After adding 60 g of tetrachloroethylene, it was cooled to room temperature.
得られた防炎加工剤（防炎剤有効成分５０％）をテトラ
クロルエチレンで更に３倍に希釈したものを処理液と
し、これに目付１８０g/m2のポリエステル織物をパッド
し、マングルで絞液（絞り率６０％）後、１３０℃で５
分乾燥し、次いで１７０℃で２分熱処理した。The obtained flameproofing agent (flameproofing agent active ingredient 50%) was further diluted 3-fold with tetrachloroethylene to obtain a treatment solution, which was padded with a polyester fabric having a basis weight of 180 g / m 2 and squeezed with a mangle. After liquid (squeeze ratio 60%), 5 at 130 ° C
It was dried for a minute and then heat-treated at 170 ° C. for 2 minutes.
比較例１． トリス（β−クロロエチル）ホスフェートの代わりに同
量のテトラクロルエチレンを用いた以外は実施例１と全
く同様にしてポリエステル織物を加工した。Comparative Example 1. A polyester woven fabric was processed in exactly the same manner as in Example 1 except that the same amount of tetrachloroethylene was used instead of tris (β-chloroethyl) phosphate.
比較例２． トリスチレン化フェノール・エチレンオキサイド１０モ
ル付加体の代わりに同量のテトラクロルエチレンを用い
た以外は実施例１と全く同様にしてポリエステル織物を
加工した。Comparative example 2. A polyester woven fabric was processed in the same manner as in Example 1 except that the same amount of tetrachloroethylene was used instead of the tristyrenated phenol / ethylene oxide 10 mol adduct.
実施例１及び比較例１、２で得られた加工布の難燃性試
験の結果を第１表に示す。Table 1 shows the results of the flame retardancy test of the work cloths obtained in Example 1 and Comparative Examples 1 and 2.
本発明による実施例１の加工布は、加工上がり、洗濯及
びドライクリーニング後いずれも非常に優れた難燃性を
示し、また風合も良好であった。これに対して、本発明
のロ）の化合物を用いずに加工した比較例１の加工布は
全般に難燃性に欠け、また本発明のハ）の化合物を用い
ずに加工した比較例２の加工布は難燃性にバラツキがあ
り、防炎剤の均一な付着が得られていないことを窺わせ
る。また、洗濯、ドライクリーニング耐久性も本発明法
に比べて劣る。 The processed cloth of Example 1 according to the present invention showed very excellent flame retardancy after processing, after washing and dry cleaning, and had a good feeling. On the other hand, the work cloth of Comparative Example 1 processed without using the compound of (b) of the present invention lacks incombustibility as a whole, and Comparative Example 2 processed without using the compound of (c) of the present invention. The processed cloth has uneven flame retardance, which suggests that the flameproofing agent is not uniformly attached. Also, the durability of washing and dry cleaning is inferior to that of the method of the present invention.
実施例２． 加熱及び撹拌装置付のガラス製容器に1,2,5,6,9,10−ヘ
キサブロモシクロドデカン１０ｇ、トリクレジールホス
フェート５０ｇ、トリスチレン化フェノール・エチレン
オキサイド２０モル付加体５ｇ、トリスチレン化フェノ
ール・エチレンオキサイド２０モル付加体の硫酸化物ア
ンモニュウム塩７ｇを採取し撹拌しながら、徐々に加熱
し、１２０℃で１５分間保ち、透明な液体物を得た。次
いで、これを９０℃まで冷却し、撹拌を続けながら、水
３０ｇを徐々に注入し、その後さらに１５分間撹拌した
後、徐々に常温まで冷却して粒径0.2〜0.3μの乳白色の
エマルジョンを得た（防炎剤有効成分５９％）。Example 2. In a glass container equipped with a heating and stirring device, 1,2,5,6,9,10-hexabromocyclododecane 10 g, tricresyl phosphate 50 g, tristyrenated phenol / ethylene oxide 20 mol adduct 5 g, tristyrenated 7 g of a sulfated ammonium salt of a phenol / ethylene oxide 20 mol adduct was taken, gradually heated with stirring, and kept at 120 ° C. for 15 minutes to obtain a transparent liquid substance. Next, this was cooled to 90 ° C., 30 g of water was gradually poured in while continuing stirring, and after further stirring for 15 minutes, gradually cooled to room temperature to obtain a milky white emulsion with a particle size of 0.2 to 0.3 μ. (Flameproofing agent active ingredient 59%).
このエマルジョンを用いて、ポリエステル試布を下記の
如く浸漬法で処理した。Using this emulsion, polyester sample cloth was treated by the dipping method as described below.
１）試布：ポリエステル１００％織物（目付２００g/cm
2） ２）処理機：轟産業(株)製ＨＩ−ＤＩ染色試験機 ３）処理条件： 実施例２のエマルジョン １７％o.w.f. 温度 １３０℃ 時間 ３０分 処理後、冷水で３分簡単に洗浄し、乾燥（１１０℃×３
分）後、難燃試験をした。結果を第２表に示す。なお、
本実施例で得た加工布の表面は、未加工布と同等の外観
を有するものであり、ルーペで観察しても、粉ふきは見
られなかった。1) Prototype: 100% polyester fabric (200g / cm basis weight)
2 ) 2) Processing machine: HI-DI dyeing test machine manufactured by Todoroki Sangyo Co., Ltd. 3) Processing conditions: Emulsion of Example 2 17% owf temperature 130 ° C time 30 minutes After processing, it is briefly washed with cold water for 3 minutes and dried. (110 ° C x 3
After that, a flame retardant test was performed. The results are shown in Table 2. In addition,
The surface of the processed cloth obtained in this example had an appearance similar to that of the unprocessed cloth, and no dusting was observed even when observed with a magnifying glass.
本発明に従った実施例２の加工布は難燃性に優れ、その
効果は洗濯、ドライクリーニング後も持続している。 The processed cloth of Example 2 according to the present invention has excellent flame retardancy, and its effect is maintained even after washing and dry cleaning.
比較例３ 1,2,5,6,9,10−ヘキサブロモシクロドデカンに水を加
え、サンドグラインダーで微粉化し、保護コロイド剤と
してカルボキシメチルセルロースを有効分の0.2％加え
て、1,2,5,6,9,10−ヘキサブロモシクロドデカンの分散
液（粒子径約１μｍ）を得た。Comparative Example 3 1,2,5,6,9,10-Hexabromocyclododecane was added with water, pulverized with a sand grinder, and 0.2% of active ingredient of carboxymethyl cellulose was added as a protective colloid to give 1,2,5. A dispersion liquid of 6,6,9,10-hexabromocyclododecane (particle diameter: about 1 μm) was obtained.
この分散液を、有効分が実施例２のエマルジョンと同様
となる量で使用し、実施例２と同様の方法でポリエステ
ル試布を処理した。処理後、布表面の汚れが著しかった
ので、明成化学工業社製の非イオン系界面活性剤（メイ
セリンＨ−１００）２cc／を用いて８０℃×１０分間
ソーピング処理した後、水洗し、乾燥（１１０℃×３分
間）した。A polyester cloth was treated in the same manner as in Example 2, except that this dispersion was used in an amount such that the effective content was similar to that of the emulsion of Example 2. After the treatment, the surface of the cloth was markedly soiled. Therefore, the soap was treated with 2 cc / nonionic surfactant (Meiserin H-100) manufactured by Meisei Chemical Industry Co., Ltd. at 80 ° C. for 10 minutes, washed with water, and dried ( 110 ° C. × 3 minutes).
この製品は、実施例２の製品とほぼ同等の難燃性を示し
たが、ソーピング後も、布表面の粉ふきは除去できず、
非常に外観が悪く、商品価値のないものとなった。更
に、処理装置の汚れも著しく、全く実用性のないもので
あった。This product showed almost the same flame retardancy as the product of Example 2, but the dust on the cloth surface could not be removed even after soaping,
It looked very bad and had no commercial value. Further, the processing device was significantly soiled, which was completely impractical.
発明の効果 本発明の防炎加工剤は、イ）多臭素化有機化合物をロ）
燐系化合物及びハ）前記構造式Ｉ及び／又はIIで示され
るの化合物と併用することによって、溶液状として提供
できるため、非常に取り扱い易く、溶液系及び水分散系
いずれの形で使用しても、容易に合成繊維材料への均一
な加工ができる。EFFECTS OF THE INVENTION The flameproofing agent of the present invention comprises a) a polybrominated organic compound b)
Phosphorus-based compound and c) It can be provided as a solution by using in combination with the compound represented by the structural formula I and / or II, and therefore it is very easy to handle, and it can be used in the form of either solution or water dispersion. Also, it is possible to easily process the synthetic fiber material uniformly.
また、本発明の防炎加工剤による加工では、イ）、ロ）
及びハ）三種の化合物の相乗効果によって、多臭素化有
機化合物単独では得られない優れた防炎性能が得られ、
加工布の風合も優れる。Further, in the processing with the flameproofing agent of the present invention, a), b)
And c) due to the synergistic effect of the three kinds of compounds, excellent flameproof performance that cannot be obtained by the polybrominated organic compound alone is obtained,
The texture of the processed cloth is also excellent.
───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.5 識別記号 庁内整理番号 ＦＩ 技術表示箇所 // Ｄ０６Ｍ 101:06 Ｄ０６Ｍ 13/18 (56)参考文献 特開 昭52−71571（ＪＰ，Ａ) 特開 昭58−67779（ＪＰ，Ａ) 特公 昭48−1476（ＪＰ，Ｂ１)─────────────────────────────────────────────────── ─── Continuation of the front page (51) Int.Cl. 5 Identification number Office reference number FI technical display location // D06M 101: 06 D06M 13/18 (56) References JP-A-52-71571 (JP, A) ) JP-A-58-67779 (JP, A) JP-B-48-1476 (JP, B1)
Claims (2)
デカン ロ）トリス（1,3-ジクロロプロピル）ホスフェート、ト
リス（β−クロロエチル）ホスフェート、トリフェニー
ルホスフェート、トリクレジルホスフェート、トリキシ
レニルホスフェート、ジメチルメチルホスフォネート及
びジエチルＮ，Ｎ−ビス（２−ヒドロキシエチル）アミ
ノメチルホスフォネートから選ばれる燐含有化合物 ハ）下記の構造式Ｉ及びIIで表される化合物の少なくと
も一種 （但し、ｌは１〜３の整数、ｎは１０〜３０の整数、Ｘ
はＮａ又はＮＨ４を示す）、の３成分を含有することを
特徴とする合成繊維材料用防炎加工剤。1. A) 1,2,5,6,9,10-hexabromocyclododecanero) tris (1,3-dichloropropyl) phosphate, tris (β-chloroethyl) phosphate, triphenyl phosphate, tricule. Phosphorus-containing compound selected from dil phosphate, trixylenyl phosphate, dimethylmethylphosphonate and diethyl N, N-bis (2-hydroxyethyl) aminomethylphosphonate c) Represented by the structural formulas I and II below. At least one of the compounds (However, l is an integer of 1 to 3, n is an integer of 10 to 30, X is
Represents Na or NH 4 ), and a flameproofing agent for synthetic fiber materials.
率で１０〜３０％：５０〜８０％：１０〜２５％の割合
で含有する特許請求の範囲第１項記載の防炎加工剤。2. The flameproof according to claim 1, which contains the compounds (a), (b) and (c) in a weight ratio of 10 to 30%: 50 to 80%: 10 to 25%. Processing agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP60215780A JPH0653992B2 (en) | 1985-09-27 | 1985-09-27 | Flameproofing agent for synthetic fiber materials |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP60215780A JPH0653992B2 (en) | 1985-09-27 | 1985-09-27 | Flameproofing agent for synthetic fiber materials |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6278261A JPS6278261A (en) | 1987-04-10 |
| JPH0653992B2 true JPH0653992B2 (en) | 1994-07-20 |
Family
ID=16678104
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP60215780A Expired - Fee Related JPH0653992B2 (en) | 1985-09-27 | 1985-09-27 | Flameproofing agent for synthetic fiber materials |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0653992B2 (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH03113072A (en) * | 1989-05-22 | 1991-05-14 | Dai Ichi Kogyo Seiyaku Co Ltd | Flame-proofing agent for synthetic fiber material |
| JP4527797B2 (en) * | 2007-09-26 | 2010-08-18 | 第一工業製薬株式会社 | Flame-retardant finishing agent for polyester fiber and its processing method |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5910375B2 (en) * | 1975-12-11 | 1984-03-08 | 東レ株式会社 | Flame-retardant thermofusible polyester synthetic fiber and its manufacturing method |
| JPS5867779A (en) * | 1981-10-19 | 1983-04-22 | Teijin Ltd | Ultraviolet absorbing agent composition capable of being dispersed into water |
-
1985
- 1985-09-27 JP JP60215780A patent/JPH0653992B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| JPS6278261A (en) | 1987-04-10 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US7736696B2 (en) | Methods, systems, and compositions for fire retarding substrates | |
| JP4348407B2 (en) | Flame retardant processing chemical, flame retardant fiber and method for producing the same | |
| US3644204A (en) | Agent for the post-treatment of washed laundry | |
| SK40393A3 (en) | Rinse conditioner | |
| JP2009174109A (en) | Flame retarding processing agent for polyester fiber and method of producing flame-retardant polyester fiber | |
| US4348306A (en) | Flame retardants | |
| JP2007182652A (en) | Flame retarding processing agent for polyester fiber and processing method | |
| JP4787532B2 (en) | Flame-retardant finishing agent for polyester fiber and method for producing flame-retardant polyester fiber using the same | |
| US4120798A (en) | Flame retardants for synethetic materials | |
| JP3490340B2 (en) | Flame retardant processing method of polyester fiber | |
| JPH0653992B2 (en) | Flameproofing agent for synthetic fiber materials | |
| JPWO2008047897A1 (en) | Non-halogen flameproofing agent and method for flameproofing fiber using the same | |
| JP5227547B2 (en) | Flame-retardant finishing agent and flame-retardant processing method of polyester fiber | |
| JP5898282B2 (en) | Aqueous dispersion for flameproofing, flameproofing method and flameproofed fiber | |
| KR20110046227A (en) | Flame retardant composition for synthetic fiber fabric and post-process flame retardant treatment method using same | |
| JP3605340B2 (en) | Flameproofing agent for synthetic fiber structure and flameproofing method | |
| JP4168128B2 (en) | Flameproofing agent for polylactic acid fiber and method of flameproofing polylactic acid fiber structure | |
| JPH0770924A (en) | Flameproofing agent for polyester textile product and flameproofing method | |
| JP2007131968A (en) | Flame-retardant finishing agent for polyester fiber and method for processing the same | |
| JPWO2008081809A1 (en) | POLYPHOSPHATE-CONTAINING AQUEOUS DISPERSION, FLAME-PROOFING AGENT USING SAME, AND FIBER-PROOFING | |
| DE2830158A1 (en) | STABILIZED Aqueous SUSPENSIONS OF ORGANIC COMPOUNDS CONTAINING BROMINE WITH A CONTENT OF WATER-INSOLUBLE INORGANIC THICKENERS AND THEIR USE AS A FLAME RETARDANT FOR FIBER MATERIALS | |
| JP2670964B2 (en) | Fiber treatment agent | |
| US3112265A (en) | Preparation of dispersions containing hydrous aluminum oxide | |
| JP2006104616A (en) | Flame retardant for polyester-based fiber | |
| US4211814A (en) | Method for the fireproofing of synthetic fiber material |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| LAPS | Cancellation because of no payment of annual fees |