JPH0643612A - Silver halide color photographic sensitive material - Google Patents

Abstract

PURPOSE:To obtain the photosensitive material capable of forming a color image superior in color reproduction performance and lightfastnes by incroporating a specified compound. CONSTITUTION:This photosensitive material contains in the same one layer, pyrazoloazole type dye stuff coupler and the compounds of formulae I and II in which A is a simmple bond, or-O-,-S(O)Q-, or the like; Q is 0, 1, or 2; each of R21 and R22 is H, an aliphatic or heterocyclic group, acyl, sulfonyl, or the like; each of R23 and R24 is an aliphatic group; each of R25 and R26 is, a substituent m and n are integer 1 to 3; When m and n are more than 2, R25 and R26 may be same or different, each of (R21 and R23), (R22 and R24) (R23 and R25), and (R24 and R26) may combine with each to form a 5-8-membered ring; R4 is an aliphatic, aromatic, or heterocyclic group or the like; and each of R5-R9 is, independently, H, an aliphatic or aromatic group, or the like.

Description

Detailed Description of the Invention

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a silver halide color photographic light-sensitive material, and more particularly to a halogenated dye in which a dye image formed from a pyrazoloazole coupler is prevented from fading or discoloring to light or heat. The present invention relates to a silver color photographic light-sensitive material.

[0002]

2. Description of the Related Art Using exposed silver halide as an oxidant, an oxidized aromatic primary amine type color developing agent and a coupler react to give indophenol, indoaniline, indamine, azomethine, phenoxazine, phenazine and It is well known that similar dyes are formed and color images are formed. Among these, in order to form a magenta image, 5-pyrazolone, cyanoacetophenone, indazolone, pyrazolobenzimidazole,
A pyrazolotriazole coupler is used.

Conventionally, most of the 5-pyrazolones have been widely put to practical use as magenta color image-forming couplers and studied. However, it has been known that a dye formed from a 5-pyrazolone-based coupler has a side absorption at around 430 nm, which causes a color stain. As the magenta image forming skeleton having less absorption in the yellow region, a pyrazolobenzimidazole skeleton described in British Patent 1,047,612, an indazolone skeleton described in US Pat. No. 3,770,447,
Further, a pyrazolo [5,1-c] -1,2,4-triazole skeleton described in US Pat. No. 3,725,067 has been proposed. Further, as a magenta coupler with little yellow unnecessary absorption and good color development, imidazo [1,2-b] pyrazoles, pyrazolo [1,5-b] [1,2,4] triazoles, pyrazolo [1,5-d] ] Tetrazoles, pyrazolo [1,5-d] benzimidazoles, pyrazoloazole-based magenta couplers of pyrazolopyrazoles, and the like have also been developed. Recently, a coupler that develops cyan with the same nucleus has also been developed.

[0004]

However, the azomethine dye formed from such a pyrazoloazole-based coupler has a relatively low fastness to light, and a color image stabilizer which has been generally used conventionally (for example, It has been found that alkyl-substituted hydroquinones) cannot sufficiently prevent this photobleaching. In order to solve this problem, improvement by adding various compounds has been attempted. For example, JP-A-59-
125732, 60-262159, 61-2
82245, 624244045, 62-24
No. 4046, No. 62-273531, No. 61-158.
No. 330, No. 63-95439, No. 63-95448
No. 63-95450 and JP-A No. 63-2845.
In this method, the alkoxybenzene derivative described in No. 48 or the like is added. The compounds described therein certainly show an excellent effect of improving light fastness in a region where the dye concentration generated by color development of the coupler is high (hereinafter referred to as a high concentration region).

However, in a region where the dye concentration generated by coupler color development is low (hereinafter referred to as a low concentration region), the dye formed from the pyrazoloazole-based coupler has particularly low light fastness, and particularly in the reflection-based light-sensitive material. However, this is further emphasized, which is not preferable in terms of the balance of fading with other colors, and even with the above-mentioned alkoxybenzene derivative, the effect of improving light fastness in a low concentration range is weak, and this improvement technique has been earnestly desired.

On the other hand, a bisphenol compound alone or a combination of a bisphenol compound and a specific alkoxybenzene compound suppresses yellow stain generated from a 5-pyrazolone magenta coupler or improves the light fastness of the color image. The method is Japanese Examined Japanese Patent Publication Sho 60-317
3, 60-3174, and JP-A-52-72225.
No. 54-70830, No. 61-158333, and JP-A No. 62-24250.

The methods described in these patent publications have a strong effect on the suppression of yellow stain and the fastness of the color image with respect to the 5-pyrazolone type magenta coupler, but the pyrazoloazole type magenta. The effect was not sufficient with the coupler.

Further, a method of improving the fastness of a color image by using a bisphenol compound alone or a bisphenol compound and a specific alkoxybenzene compound in combination with a pyrazoloazole coupler is disclosed in Japanese Patent Application Laid-Open No. HEI-1.
-134359, 2-139544, and Japanese Patent Application No. 2-
No. 28944, European Patent No. 391341 and European Patent No. 218,266 are proposed.

In the methods described in these patent publications, the hue and photographic characteristics are adversely affected, and the fastness of the color image is not always sufficient.

In this sense, a technique for improving the robustness of the color image, particularly a technique for suppressing photobleaching in the low density region has been desired.

Therefore, a first object of the present invention is to use a pyrazoloazole-based coupler excellent in color forming property and to provide a silver halide color photographic light-sensitive material which gives a color image excellent in color reproducibility and light fastness. To provide.

A second object of the present invention is to provide a silver halide color photographic light-sensitive material in which light fastness in a low density region of a color image is improved and the fading balance of three colors is improved.

A third object of the present invention is to contain an anti-fading agent which does not adversely affect photographic characteristics, does not adversely affect hue, is excellent in preventing fading of a color image, and does not color unexposed areas. An object is to provide a silver halide color photographic light-sensitive material.

[0014]

As a result of various investigations by the present inventors, at least one pyrazoloazole type dye-forming coupler, at least one compound represented by the following general formula (A), and the following general formula: It has been found that the object of the present invention can be achieved by incorporating at least one of the compounds represented by (B) in the same layer of a silver halide color photographic light-sensitive material.

[0015]

[Chemical 5] [In the formula, A is a simple bond, -O-, -S (O) _Q- ,
_{-N (R 27) -, -} (C (R 28) (R 29)) T - represents a or linking group L.

[0016]

[Chemical 6]

R ₂₁ and R ₂₂ are each a hydrogen atom, an aliphatic group, an aromatic group, a heterocyclic group, an acyl group, a sulfonyl group, -P (R ₃₂ ) (R ₃₃ ), -P (O) (R ₃₃ ) (R ₃₄ ) or a silyl group. R ₂₃ and R ₂₄ each represent an aliphatic group, and R ₂₅ and R ₂₆ each represent a substituent. m and n represent an integer of 1 to 3. When m and n are 2 or more, a plurality of R ₂₅ and R ₂₆ may be the same or different. R ₂₁ and R ₃₀ , R ₂₂ and R ₃₀ , R ₂₁ and R ₂₃ , R
₂₂ and R ₂₄ , R ₂₃ and R _25, and R ₂₄ and R ₂₆ may be bonded to each other to form a 5- to 8-membered ring. B is -O-,-
S (O) _Q - or _{-C (R 28) (R 29} ) - represents, Q
Represents 0, 1 or 2. R ₂₇ is a hydrogen atom, an aliphatic group,
It represents an acyl group, a sulfonyl group, an aliphatic oxycarbonyl group or an aromatic oxycarbonyl group. R ₂₈ and R
₂₉ represents a hydrogen atom aliphatic group or an aromatic group, respectively, and T represents 1 or 2. R ₃₀ has the same meaning as R ₂₁ , R ₃₁ represents a substituent, V represents an integer of 0 to 3, and when V is plural, plural R ₃₁ may be the same or different. . R ₃₂ , R ₃₃ and R ₃₃ each represent an aliphatic group, an aromatic group, an aliphatic oxy group or an aromatic oxy group. However, at least one of R ₂₁ , R ₂₂ and R ₃₀ is a hydrogen atom, and at least one is not a hydrogen atom. )

[0018]

[Chemical 7]

(In the formula, R ₄ represents an aliphatic group, an aromatic group, a heterocyclic group or a silyl group. R ₅ , R ₆ , R ₇ and R ₈
R ₉ and R ₉ may be the same or different and each is a hydrogen atom, an aliphatic group, an aromatic group, an amino group having a substituent, an aliphatic thio group, an aromatic thio group, a halogen atom, or -C.
Represents OOR ₄ 'or -OR ₄ '. Here, R ₄ 'is synonymous with R ₄ . R ₄ and R ₅ , R ₅ and R ₆ or R ₆
And R ₇ may combine with each other to form a 5-membered 6-membered ring or a spiro ring. )

The aliphatic mentioned in the present invention may be linear, branched or cyclic and may be saturated or unsaturated, for example, alkyl, alkenyl, alkynyl, cycloalkyl,
Alternatively, it represents cycloalkenyl, which may further have a substituent. Aromatic represents aryl,
It may further have a substituent. The heterocyclic ring has a hetero atom in the ring, includes an aromatic ring, and may have a substituent. In the aliphatic described in the present invention, an alkyl in terms of the effect of the present invention,
Cycloalkyl is preferable, aromatic is preferably phenyl, and those further having a substituent are also preferable.

The substituent described in the present invention may be a substitutable group, and examples thereof include an aliphatic group, an aromatic group, a heterocyclic group, an acyl group, an acyloxy group, an acylamino group, an aliphatic oxy group and an aromatic group. Group oxy group, heterocyclic oxy group, aliphatic oxycarbonyl group, aromatic oxycarbonyl group, heterocyclic oxycarbonyl group, aliphatic carbamoyl group, aromatic carbamoyl group, aliphatic sulfonyl group, aromatic sulfonyl group, aliphatic sulfamoyl group Group, aromatic sulfamoyl group, aliphatic sulfonamide group, aromatic sulfonamide group, aliphatic amino group, aromatic amino group, aliphatic sulfinyl group, aromatic sulfinyl group, aliphatic thio group, aromatic thio group, mercapto Group, hydroxy group, cyano group, nitro group, hydroxyamino group, halogen atom and the like.

The pyrazoloazole type dye-forming coupler is represented by the formula [M].

[0023]

[Chemical 8]

Here, R ₁ represents a hydrogen atom or a substituent. Z represents a group of non-metal atoms necessary for forming a 5-membered azole ring containing 2 to 4 nitrogen atoms, and the azole ring may have a substituent (including a condensed ring). X represents a hydrogen atom or a group capable of splitting off upon a coupling reaction with an oxidized product of a developing agent.

The present coupler will be described in detail below. Among the coupler skeletons represented by the formula [M], preferred skeletons are 1H-imidazo [1,2-b] pyrazole, 1H-pyrazolo [1,5-b] [1,2,4] triazole, 1H.
-Pyrazolo [5,1-c] [1,2,4] triazole, 1H-pyrazolo [1,5-d] tetrazole and 1H-pyrazolo [1,5-a] benzimidazole, each of formula [M- I], [M-II], [M-III
], [M-IV] and [MV].

[0026]

[Chemical 9]

Substituents R ₁₁ , R ₁₂ , R in these formulas
₁₃ , R ₁₄ , n and X will be described in detail.

R ₁₁ is a hydrogen atom, halogen atom, alkyl group, aryl group, heterocyclic group, cyano group, hydroxy group, nitro group, carboxy group, sulfo group, amino group, alkoxy group, aryloxy group, acylamino group, Alkylamino group, anilino group, ureido group, sulfamoylamino group, alkylthio group, arylthio group, alkoxycarbonylamino group, sulfonamide group, carbamoyl group, sulfamoyl group, sulfonyl group, alkoxycarbonyl group, heterocyclic oxy group, azo A group, an acyloxy group, a carbamoyloxy group, a silyloxy group, an aryloxycarbonylamino group, an imide group, a heterocyclic thio group, a sulfinyl group, a phosphonyl group, an aryloxycarbonyl group, an acyl group, or an azolyl group, R ₁₁
May form a dimer or higher multimer with a divalent group.

More specifically, R ₁₁ is each a hydrogen atom, a halogen atom (eg, chlorine atom, bromine atom), an alkyl group (eg, a straight chain or branched chain alkyl group having 1 to 32 carbon atoms, an aralkyl group, an alkenyl). Group, alkynyl group,
A cycloalkyl group or a cycloalkenyl group, more specifically,
For example, methyl, ethyl, propyl, isopropyl, t-
Butyl, tridecyl, 2-methanesulfonylethyl, 3
-(3-Pentadecylphenoxy) propyl, 3- {4
-{2- [4- (4-hydroxyphenylsulfonyl)
Phenoxy] dodecanamide} phenyl} propyl, 2
-Ethoxytridecyl, trifluoromethyl, cyclopentyl, 3- (2,4-di-t-amylphenoxy) propyl), aryl groups (e.g. phenyl, 4-t-butylphenyl, 2,4-di-t-). Amylphenyl, 2,
4,6-Trimethylphenyl, 3-tridecanamide-
2,4,6-trimethylphenyl, 4-tetradecanamidophenyl, tetrafluorophenyl), heterocyclic group (for example, 2-furyl, 2-thienyl, 2-pyrimidinyl, 2-benzothiazolyl), cyano group, hydroxy group, nitro Group, carboxy group, sulfo group, amino group, alkoxy group (for example, methoxy, ethoxy, 2-methoxyethoxy, 2-dodecylethoxy, 2-methanesulfonylethoxy), aryloxy group (for example, phenoxy, 2-methylphenoxy, 4-t-butylphenoxy, 3-nitrophenoxy, 3-t-butyloxycarbamoylphenoxy, 3-methoxycarbamoyl), an acylamino group (for example, acetamide, benzamide,
Tetradecanamide, 2- (2,4-di-t-amylphenoxy) butanamide, 4- (3-t-butyl-4-)
Hydroxyphenoxy) butanamide, 2- {4- (4
-Hydroxyphenylsulfonyl) phenoxy} decanamide), an alkylamino group (eg, methylamino,
Butylamino, dodecylamino, diethylamino, methylbutylamino), anilino group (eg, phenylamino, 2-chloroanilino, 2-chloro-5-tetradecaneaminoanilino, 2-chloro-5-dodecyloxycarbonylanilino, N- Acetylanilino, 2-chloro-5- {2- (3-t-butyl-4-hydroxyphenoxy) dodecanamide} anilino), a ureido group (eg, phenylureido, methylureido, N, N-dibutylureido), A sulfamoylamino group (for example,
N, N-dipropylsulfamoylamino, N-methyl-N-decylsulfamoylamino), alkylthio group (for example, methylthio, octylthio, tetradecylthio, 2-phenoxyethylthio, 3-phenoxypropylthio, 3- (4-t-butylphenoxy) propylthio), an arylthio group (for example, phenylthio, 2-butoxy-5-t-octylphenylthio, 3-pentadecylphenylthio, 2-carboxyphenylthio, 4-
Tetradecanamide phenylthio), alkoxycarbonylamino group (eg, methoxycarbonylamino, tetradecyloxycarbonylamino), sulfonamide group (eg, methanesulfonamide, hexadecanesulfonamide, benzenesulfonamide, p-toluenesulfonamide, octadecanesulfone) Amide, 2-methoxy-5-t-butylbenzenesulfonamide), carbamoyl group (eg, N-ethylcarbamoyl, N, N
-Dibutylcarbamoyl, N- (2-dodecyloxyethyl) carbamoyl, N-methyl-N-dodecylcarbamoyl, N- {3- (2,4-di-t-amylphenoxy) propyl} carbamoyl), sulfamoyl group (for example, , N-ethylsulfamoyl, N, N-dipropylsulfamoyl, N- (2-dodecyloxyethyl) sulfamoyl, N-ethyl-N-dodecylsulfamoyl, N, N-diethylsulfamoyl), sulfonyl Group (for example, methanesulfonyl, octanesulfonyl, benzenesulfonyl, toluenesulfonyl), alkoxycarbonyl group (for example, methoxycarbonyl, butyloxycarbonyl, dodecyloxycarbonyl, octadecyloxycarbonyl), heterocyclic oxy group (for example,
1-phenyltetrazole-5-oxy, 2-tetrahydropyranyloxy), azo group (for example, phenylazo, 4-methoxyphenylazo, 4-pivaloylaminophenylazo, 2-hydroxy-4-propanoylphenylazo) An acyloxy group (eg acetoxy),
Carbamoyloxy group (for example, N-methylcarbamoyloxy, N-phenylcarbamoyloxy), silyloxy group (for example, trimethylsilyloxy, dibutylmethylsilyloxy), aryloxycarbonylamino group (for example, phenoxycarbonylamino), imide group (for example, , N-succinimide, N-phthalimide,
3-octadecenylsuccinimide), a heterocyclic thio group (for example, 2-benzothiazolylthio, 2,4-di-phenoxy-1,3,5-triazole-6-thio, 2-
Pyridylthio), a sulfinyl group (for example, dodecanesulfinyl, 3-pentadecylphenylsulfinyl,
3-phenoxypropylsulfinyl), phosphonyl group (for example, phenoxyphosphonyl, octyloxyphosphonyl, phenylphosphonyl), aryloxycarbonyl group (for example, phenoxycarbonyl), acyl group (for example, acetyl, 3-phenylpropanoyl, Benzoyl, 4-dodecyloxybenzoyl), and an azolyl group (eg, imidazolyl, pyrazolyl, 3-chloro-pyrazol-1-yl, triazolyl). Among these substituents, the group capable of further having a substituent may further have an organic substituent or a halogen atom linked by a carbon atom, an oxygen atom, a nitrogen atom or a sulfur atom.

Of these substituents, preferred R ₁₁ is alkyl group, aryl group, alkoxy group, aryloxy group, alkylthio group, ureido group, urethane group,
An acylamino group can be mentioned.

R ₁₂ is a group similar to the substituents exemplified for R ₁₁ , and is preferably a hydrogen atom, an alkyl group, an aryl group, a heterocyclic group, an alkoxycarbonyl group, a carbamoyl group, a sulfamoyl group, a sulfinyl group, an acyl group. Or a cyano group.

R ₁₃ is a group having the same meaning as the substituent exemplified for R ₁₁ , and is preferably a hydrogen atom, an alkyl group, an aryl group, a heterocyclic group, an alkoxy group, an aryloxy group, an alkylthio group, an arylthio group or an alkoxy group. It is a carbonyl group, a carbamoyl group or an acyl group, more preferably an alkyl group, an aryl group, a heterocyclic group, an alkylthio group or an arylthio group.

R ₁₄ is a group having the same meaning as the substituent exemplified for R ₁₁ , and preferably a hydrogen atom, an alkyl group,
Aryl group, heterocyclic group, alkoxy group, aryloxy group, alkoxycarbonyl group, carbamoyl group, sulfamoyl group, sulfonyl group, acyl group, acylamino group, alkoxycarbonylamino group, sulfonamide group, sulfamoylamino group, or cyano It is a base.

N represents an integer of 1 to 4, preferably 1 to 3.

X represents a hydrogen atom or a group capable of splitting off upon reaction with an oxidized product of an aromatic primary amine color developing agent. The splitting-off group is specifically described as a halogen atom, an alkoxy group, an aryloxy group or an acyloxy group. Group, alkyl or aryl sulfonyloxy group, acylamino group, alkyl or aryl sulfonamide group, alkoxycarbonyloxy group, aryloxycarbonyloxy group, alkyl, aryl or heterocyclic thio group, carbamoylamino group, 5-membered or 6-membered group There are a nitrogen heterocyclic group, an imide group, an arylazo group and the like, and these groups may be further substituted with a group which is allowed as a substituent for R ₁₁ .

More specifically, halogen atom (eg, fluorine atom, chlorine atom, bromine atom), alkoxy group (eg, ethoxy, dodecyloxy, methoxyethylcarbamoylmethoxy, carboxypropyloxy, methylsulfonylethoxy, ethoxycarbonylmethoxy), aryl An oxy group (for example, 4-methylphenoxy, 4-
Chlorophenoxy, 4-methoxyphenoxy, 4-carboxyphenoxy, 3-ethoxycarboxyphenoxy, 4-methoxycarbonylphenoxy, 3-acetylaminophenoxy, 2-carboxyphenoxy), acyloxy group (for example, acetoxy, tetradecanoyloxy, benzoyl) Oxy), an alkyl or aryl sulfonyloxy group (eg, methanesulfonyloxy, toluenesulfonyloxy), an acylamino group (eg, dichloroacetylamino, heptafluorobutyrylamino), an alkyl or aryl sulfonamide group (eg, methanesulfonamino) , Trifluoromethanesulfonamino, p-toluenesulfonylamino),
Alkoxycarbonyloxy groups (eg ethoxycarbonyloxy, benzyloxycarbonyloxy), aryloxycarbonyloxy groups (eg phenoxycarbonyloxy), alkyl, aryl or heterocyclic thio groups (eg dodecylthio, 1-carboxydodecylthio, phenylthio , 2-butoxy-5-t-octylphenylthio, 2-benzyloxycarbonylaminophenylthio, tetrazolylthio), carbamoylamino group (for example, N-methylcarbamoylamino, N
-Phenylcarbamoylamino), a 5- or 6-membered nitrogen-containing heterocyclic group (for example, 1-imidazolyl, 1-pyrazolyl, 1,2,4-triazol-1-yl, tetrazolyl, 3,5-dimethyl-1- Pyrazolyl, 4-cyano-1-pyrazolyl, 4-methoxycarbonyl-1-
Pyrazolyl, 4-acetylamino-1-pyrazolyl,
1,2-dihydro-2-oxo-1-pyridyl), an imide group (eg, succinimide, hydantoinyl), an arylazo group (eg, phenylazo, 4-methoxyphenylazo). In addition to these, X may take the form of a bis-type coupler obtained by condensing a 4-equivalent coupler with an aldehyde or a ketone as a leaving group bonded via a carbon atom. Further, X may contain a photographically useful group such as a development inhibitor or a development accelerator. Preferred X is a halogen atom, an alkoxy group, an aryloxy group, an alkyl or arylthio group, a 5-membered or 6-membered nitrogen-containing heterocyclic group bonded to the coupling active position with a nitrogen atom, particularly preferably a halogen atom or a substituent. An aryloxy group, a substituted arylthio group, or a substituted 1-pyrazolyl group

In terms of the effect of the present invention, the formulas [M-1] to [M-
Of the coupler skeletons represented by V], [M-II] and [M-III] are particularly preferable, and [M-II]
Is most preferred.

From the viewpoint of the effect of the present invention, R ₁₁ is particularly preferably an alkyl group, an alkoxy group or an aryloxy group, and particularly preferably a branched chain alkyl group, an alkoxy group or an aryloxy group.

From the viewpoint of the effect of the present invention, R ₁₂ and R ₁₃ are more preferably an alkyl group, an aryl group or a heterocyclic group, and particularly preferably a branched chain alkyl or aryl group.

Examples of compounds of the magenta coupler represented by the formula [M] are shown below, but the invention is not limited thereto.

[0041]

[Chemical 10]

[0042]

[Chemical 11]

[0043]

[Chemical 12]

[0044]

[Chemical 13]

[0045]

[Chemical 14]

[0046]

[Chemical 15]

[0047]

[Chemical 16]

[0048]

[Chemical 17]

[0049]

[Chemical 18]

[0050]

[Chemical 19]

[0051]

[Chemical 20]

[0052]

[Chemical 21]

[0053]

[Chemical formula 22]

[0054]

[Chemical formula 23]

[0055]

[Chemical formula 24]

[0056]

[Chemical 25]

[0057]

[Chemical formula 26]

[0058]

[Chemical 27]

[0059]

[Chemical 28]

[0060]

[Chemical 29]

[0061]

[Chemical 30]

[0062]

[Chemical 31]

[0063]

[Chemical 32]

[0064]

[Chemical 33]

[0065]

[Chemical 34]

[0066]

[Chemical 35]

[0067]

[Chemical 36]

[0068]

[Chemical 37]

[0069]

[Chemical 38]

References which describe a method for synthesizing the coupler represented by the formula [M] are listed below.

The compound of formula [M-I] is described in US Pat.
Compounds of formula [M-II], such as 630, are described in US Pat.
No. 654, No. 4,705,863, JP-A No. 61-65245, No. 62-
Nos. 209457 and 62-249155, the compound of the formula [M-III] is Japanese Patent Publication No. 47-27411, U.S. Pat. No. 3,725,067 and the like, and the compound of the formula [M-IV] is JP-A-60-33552. It can be synthesized by the method described in.

The pyrazoloazole type dye-forming coupler of the present invention contains 1 × per mol of silver halide present in the same layer.
10 ⁻³ mol to 1 mol, preferably 5 × 10 ⁻² mol to 5 ×
It is added to the emulsion layer in a ratio of 10 ^-1 mol. Further, two or more kinds of couplers of the present invention can be added to the same layer and can be added to other layers. The coupler of the present invention can also be added to the same layer together with other types of couplers.

Next, the general formula (A) will be described in more detail. A is a mere bond, -O-, -S (O) _Q- ,
_{-N (R 27) -, -} C (R 28) (R 29)) T - or represents a linking group L. B is -O-, -S (O) _Q- or -C
Represents (R ₂₈ ) (R ₂₉ )-. Here, R ₂₇ is a hydrogen atom, an aliphatic group (eg, methyl, ethyl, butyl, isopropyl, dodecyl, benzyl), an acyl group (eg, acetyl, pivaloyl, myristoyl, benzoyl), a sulfonyl group (eg, methanesulfonyl, octanesulfonyl, benzene). Sulfonyl), an aliphatic oxycarbonyl group (eg methoxycarbonyl, hexadecyloxycarbonyl) or an aromatic oxycarbonyl group (eg phenoxycarbonyl, 4-t-butylphenoxycarbonyl). R ₂₈ and R ₂₉ each represent a hydrogen atom, an aliphatic group (eg, methyl, ethyl, butyl, isopropyl, octyl, benzyl) or an aromatic group (eg, phenyl, 2-hydroxyphenyl, 4-t-butylphenyl). , T represents 1 or 2. R ₃₀ has the same meaning as R ₂₁ described later, R ₃₁ represents a substituent, and a preferable substituent in this case is an aliphatic group, an acylamino group, an aliphatic oxy group, Aromatic oxy group, aliphatic thio group,
An aromatic thio group, a hydroxy group and a halogen atom are preferred, and an aliphatic group is most preferred. Q represents 0, 1 or 2, and T represents 1 or 2. V represents an integer of 1 to 3. In terms of the effect of the present invention, A is a single bond, -O-,
-CH (R ₂₈₎ - or preferably represents a linking group L-1, -CH (R ₂₈₎ - if it is or linking group L-1 is most preferred. In terms of the effect of the present invention, B is -O-,
It is preferably —S— or —CH (R ₂₈ ) —,
Most preferred is -CH (R ₂₈ )-.

[0074]

[Chemical Formula 39]

R ₂₁ and R ₂₂ are each a hydrogen atom, an aliphatic group (eg, methyl, ethyl, isopropyl, benzyl, octyl, dodecyl, methoxyethyl, allyl),
Aromatic groups (eg phenyl, 4-methoxyphenyl),
Heterocyclic groups (eg 2-tetrahydropyranyl, 2-tetrahydrothienyl), acyl groups (eg acetyl, pivaloyl, myristoyl, benzoyl, 3,5-di-t-).
Butyl-4-hydroxybenzoyl), sulfonyl group (for example, methanesulfonyl, octanesulfonyl, benzenesulfonyl), -P (R ₃₂ ) (R ₃₃ ), -P.
It represents (O) (R ₃₂ ) (R ₃₃ ), and a silyl group (eg, trimethylsilyl, dimethyl-t-butylsilyl, triphenylsilyl). Here, R ₃₂ and R ₃₃ are an aliphatic group (eg, methyl, ethyl, octyl), an aromatic group (eg, phenyl, 4-t-butylphenyl), an aliphatic oxy group (eg, methoxy, t-butoxy, octyl). Oxy) or an aromatic oxy group (eg, phenoxy, 4-
Methoxyphenoxy).

At least one of R ₂₁ , R ₂₂ and R ₃₀ described above is a hydrogen atom, and at least one of them is not a hydrogen atom. In terms of an aliphatic group, an acyl group, a sulfonyl group, and -P (O) (R ₃₂ ) (R ₃₃ ) (R ₃₂ or R ₃₃ is an aromatic group and the other is an aliphatic oxy group or aromatic group). (Oxy group) is preferable, and an aliphatic group, an acyl group and a sulfonyl group are particularly preferable.

R ₂₃ and R ₂₄ are each an aliphatic group (eg, methyl, ethyl, isopropyl, t-butyl, t-).
Amyl, isobutyl, sec-butyl, cyclohexyl,
1-methylcyclohexyl, benzyl, lauryloxyethyl, allyl). R ₂₃ and R ₂₄ are an alkyl group having 1 to 40 carbon atoms or 5 to 40 carbon atoms from the viewpoint of the effect of the present invention.
Is preferred, and an alkyl group having 1 to 20 carbon atoms or a cycloalkyl group having 5 to 20 carbon atoms is most preferred.

R ₂₅ and R ₂₆ each represent a substituent, and the substituents are the same as those mentioned above in the description of the substituents. Preferred substituents in this case are an aliphatic group, an acylamino group and an aliphatic oxy group. , An aromatic oxy group, an aliphatic thio group,
An aromatic thio group, a hydroxy group and a halogen atom are preferred, and an aliphatic group is most preferred.

In the general formula (A), the following general formula (AI) is preferable from the viewpoint of the effect of the present invention, and when m and n are 1, R ₂₅ and R ₂₆ are para to the oxygen atom. It is more preferable when the position is substituted.

[0080]

[Chemical 40]

Specific examples of the compound represented by formula (A) of the present invention are shown below, but the invention is not necessarily limited thereto.

[0082]

[Chemical 41]

[0083]

[Chemical 42]

[0084]

[Chemical 43]

[0085]

[Chemical 44]

[0086]

[Chemical formula 45]

[0087]

[Chemical formula 46]

[0088]

[Chemical 47]

[0089]

[Chemical 48]

[0090]

[Chemical 49]

[0091]

[Chemical 50]

[0092]

[Chemical 51]

[0093]

[Chemical 52]

[0094]

[Chemical 53]

[0095]

[Chemical 54]

The compound represented by the general formula (A) of the present invention can be synthesized by the method described in JP-A No. 62-262047 and JP-A No. 1-137254, and a method according to the method.

The compound represented by the general formula (A) of the present invention varies depending on the compound species and the pyrazoloazole type dye-forming coupler, but is 5 × 10 ^{−3 to} 3 mol, preferably 1 × 10 3. It is used by adding it in the same layer as the coupler in a ratio of ^-2 mol to 1 mol.

Next, the general formula (B) will be described in detail. In the formula,
R ₄ is an alkyl group (eg methyl, n-butyl, n-octyl, n-hexadecyl, ethoxyethyl, 3-phenoxypropyl, benzyl), an alkenyl group (eg vinyl, allyl), an aryl group (eg phenyl, naphthyl), Heterocyclic groups (eg pyridyl, tetrahydropyranyl) or silyl groups (eg trimethylsilyl, t-
Butyldimethylsilyl). R ₅ , R ₆ , R ₇ ,
R ₈ and R ₉ may be the same or different and each is a hydrogen atom, an alkyl group (for example, methyl, n-butyl, n-octyl, sec-dodecyl, t-butyl, t-).
Amyl, t-hexyl, t-octyl, t-octadecyl, α, α-dimethylbenzyl, 1,1-dimethyl-4
-Hexyloxycarbonylbutyl), alkenyl groups (eg vinyl, allyl), aryl groups (eg phenyl, naphthyl, p-methoxyphenyl, 2,4-t-).
Butylphenyl), a substituted amino group (eg acetylamino, propylonylamino, benzamino,
N-methylamino, N, N-dimethylamino, N, N-
Dihexylamino, N-cyclohexylamino, N-
(T-butyl) amino, and a nitrogen-containing heterocyclic group in which a substituent is closed, for example, piperidino, 1-piperazinyl),
Alkylthio groups (eg methylthio, n-butylthio,
sec-butylthio, t-butylthio, dodecylthio),
Arylthio group (eg phenylthio, naphthylthio), halogen atom (eg chlorine, bromine), —COO
R _'4 (e.g. octyloxycarbonyl, 2,4-di -t- butyl phenoxycarbonyl), or -O-
It represents the R _'4. Here, R ′ ₄ has the same meaning as R ₄ . R
₄ and R ₅ may combine with each other to form a 5-membered ring, a 6-membered ring or a spiro ring. R ₅ and R ₆ or R ₆ and R ₇ may combine with each other to form a 5-membered ring, a 6-membered ring or a spiro ring. Examples of these rings include a chroman ring, a coumaran ring, a spirochroman ring, and a spiroindane ring.

From the viewpoint of the effect of the present invention, at least one of the substituents represented by R _{5 to} R ₉ of the compound represented by the general formula (B) has at least one of the benzene ring and a hetero atom (particularly preferably an oxygen atom, Substituents bound by a nitrogen atom) are preferred.
Among the compounds represented by the general formula (B), those represented by the following general formulas [BI] to [B-VIII] are more preferable from the viewpoint of the effect of the present invention.

[0100]

[Chemical 55]

[0101]

[Chemical 56]

[0102]

[Chemical 57]

In the general formulas [BI] to [B-VIII],
R ₄ , R ₄ ′, R ₅ , R ₆ , R ₇ , R ₈ and R ₉ represent the same groups as in the general formula [B]. R _{51 to} R _{61, which} may be the same or different, each represents a hydrogen atom, an alkyl group (eg, methyl, ethyl, isopropyl, dodecyl) or an aryl group (eg, phenyl, p-methoxyphenyl). R ₅₄ and R ₅₅ , R ₅₅ and R ₅₆ may combine with each other to form a 5- to 7-membered hydrocarbon ring. R ₆₂ and R
₆₃ may be the same or different and each is a hydrogen atom, an alkyl group (eg, methyl, ethyl, dodecyl), an aryl group (eg, phenyl, 4-chloro-phenyl), an acyl group (eg, acetyl, benzoyl, dodecanoyl), oxycarbonyl. Represents a group (eg, methoxycarbonyl, 4-dodecyloxyphenoxycarbonyl), a sulfonyl group (eg, methanesulfonyl, octanesulfonyl, benzenesulfonyl, etc.). However, R ₆₂ and R ₆₃
Are not hydrogen atoms at the same time. Also R ₆₂ and R
₆₃ may combine with each other to form a 5- to 7-membered ring (for example, a morpholine ring or a piperidine ring).

Of the compounds represented by the general formulas [BI] to [B-VIII], it is preferable that R ₄ and R ′ ₄ are an alkyl group or an aryl group, and most preferably an alkyl group. In addition, general formulas [BI] to [B-
Of the compounds represented by VIII], it is preferable that R _{5 to} R ₉ are hydrogen atoms, alkyl groups or aryl groups. Among the compounds represented by the general formulas [BI] to [B-VIII], more preferable compounds from the viewpoint of the effect of the present invention are the general formulas [BV] to [B-VI] and the general formula [B
-VII], most preferably the compound of general formula [B-VII]. The specific examples of the compounds represented by formula (B) are shown below, but the invention is not limited thereto.

[0105]

[Chemical 58]

[0106]

[Chemical 59]

[0107]

[Chemical 60]

[0108]

[Chemical formula 61]

[0109]

[Chemical formula 62]

[0110]

[Chemical formula 63]

[0111]

[Chemical 64]

[0112]

[Chemical 65]

[0113]

[Chemical formula 66]

[0114]

[Chemical formula 67]

[0115]

[Chemical 68]

[0116]

[Chemical 69]

These compounds are disclosed in JP-B-45-14034.
No. 56, No. 56-24257, No. 59-52421, JP-A No. 55-89835, No. 56-159644, No. 62-244045, No. 62-244046, No. 6
2-2735351, 63-220142, 63
-95439, 63-95448, 63-95.
It can be synthesized by the method described in No. 450, European Patent No. 0,239,972 or the like or a method analogous thereto. The amount of these compounds added is from 2 to 400 mol%, preferably 5 to 5 mol% based on the pyrazoloazole type dye-forming coupler.
~ 200 mol%.

The compound and / or color coupler of the present invention can be introduced into the light-sensitive material by various known dispersion methods.
It can be usually added by an oil-in-water dispersion method known as an oil protect method. After being dissolved in a solvent, it is emulsified and dispersed in a gelatin aqueous solution containing a surfactant. Alternatively, water or a gelatin aqueous solution may be added to the solution of the compound of the present invention and / or the color coupler containing a surfactant to form an oil-in-water dispersion with phase inversion. Further, the alkali-soluble compound and / or color coupler of the present invention can be dispersed by a so-called Fisher dispersion method. The low boiling point organic solvent may be removed from the compound and / or color coupler dispersion of the present invention by a method such as distillation, washing with noodles or ultrafiltration, and then mixed with a photographic emulsion. The dispersion medium of the compound and color coupler of the present invention has a dielectric constant (25 ° C.) of 2
It is preferable to use a high boiling point organic solvent having a refractive index (25 ° C.) of 1.5 to 1.7 and / or a water-insoluble polymer compound. The compound of the present invention is preferably used by being coemulsified with a color coupler.

Examples of the high boiling point solvent used in the oil-in-water dispersion method are described in US Pat. No. 2,322,027. In addition, a specific example of the latex for the steps, effects, and impregnation of the latex dispersion method as one of the polymer dispersion methods is as follows.
US Patent No. 4,199,363, West German Patent Application No. (O
LS) 2,541,274 and 2,541,230
No. PCT International Publication No. WO88 / 00 for a dispersion method using an organic solvent-soluble polymer.
No. 723.

As the high boiling point organic solvent which can be used in the above oil-in-water dispersion method, phthalic acid esters (for example, dibutyl phthalate, dioctyl phthalate, dicyclohexyl phthalate, di-2-ethylhexyl phthalate, decyl phthalate, bis ( 2,4-di-t-
Amylphenyl) isophthalate, bis (1,1-diethylpropyl) phthalate), esters of phosphoric acid or phosphonic acid (for example, diphenyl phosphate, triphenyl phosphate, tricresyl phosphate, 2-
Ethylhexyl diphenyl phosphate, dioctyl butyl phosphate, tricyclohexyl phosphate,
Tri-2-ethylhexyl phosphate, tridodecyl phosphate, di-2-ethylhexyl phenylphosphonate), benzoic acid esters (for example, 2-ethylhexyl benzoate, 2,4-dichlorobenzoate,
Dodecyl benzoate, 2-ethylhexyl-p-hydroxybenzoate), amides (eg, N, N-diethyldodecane amide, N, N-diethyllauryl amide), alcohols or phenols (isostearyl alcohol, 2,4-di). -Tert-amylphenol, etc., aliphatic esters (for example, dibutoxyethyl succinate, di-2-ethylhexyl succinate, 2-hexyldecyl tetradecanoate, tributol citrate, diethyl azelate, isostearyl lactate, trioctyl). Citrate), aniline derivative (N, N-dibutyl-
2-butoxy-5-tert-octylaniline, etc., chlorinated paraffins (paraffins having a chlorine content of 10% to 80%), trimesic acid esters (eg, tributyl trimesate), dodecylbenzene, diisopropylnaphthalene and the like. To be As an auxiliary solvent, an organic solvent having a boiling point of 30 ° C. or higher and about 160 ° C. or higher (eg, ethyl acetate, butyl acetate, ethyl propionate, methyl ethyl ketone, cyclohexanone, 2-ethoxyethyl acetate, dimethylformamide) may be used in combination.

The color light-sensitive material of the present invention may contain a hydroquinone derivative, an aminophenol derivative, a gallic acid derivative, an ascorbic acid derivative or the like as a color fog inhibitor.

Various anti-fading agents can be used in combination with the light-sensitive material of the present invention. Hindered phenols centering on hydroquinones, 6-hydroxychromans, 5-hydroxycoumarans, spirochromans, p-alkoxyphenols and bisphenols as organic anti-fading agents for cyan, magenta and / or yellow images , Gallic acid derivatives, methylenedioxybenzenes,
Representative examples include aminophenols, hindered amines, and ether or ester derivatives obtained by silylating or alkylating the phenolic hydroxyl groups of these compounds. Further, a metal complex represented by (bissalicylaldoximato) nickel complex and (bis-N, N-dialkyldithiocarbamato) nickel complex can also be used.

Specific examples of the organic anti-fading agent include US Pat. Nos. 2,360,290 and 2,418,613,
2,700,453, 2,701,197, 2,728,659, 2,732,300, 2,735,765, 3,982,944, 4 , 430,425, British Patent No. 1,363,921
No. 2,710,801 and 2,816, US Pat.
No. 028, etc .; hydroquinones; US Pat. No. 3,
Nos. 432,300, 3,573,050, 3,5
74,627, 3,698,909, 3,76
4,337, 6-hydroxychromans, 5-hydroxychromans, spirochromans described in JP-A-52-152225; U.S. Pat. No. 4,360,589.
Spiroindenes described in US Pat. No. 2,735,735.
765, British Patent 2,066,975, JP-A-5
9-10539, p-alkoxyphenols described in JP-B-57-19765, etc .; US Pat. No. 3,70.
0,455, 4,228,235, JP-A-52-1
No. 72224, Japanese Patent Publication No. 52-6623 and the like; gallic acid derivatives described in US Pat. No. 3,457,079; US Pat. No. 4,332,88.
Methylenedioxybenzenes described in No. 6; Japanese Patent Publication No. 56
Aminophenols described in JP-A-21144; U.S. Pat. Nos. 3,336,135, 4,268,593, British Patents 1,326,889, 1,354,313.
No. 1,410,846, Japanese Patent Publication No. 51-1420
JP-A-58-114036 and 59-53846.
Nos. 59-78344 and the like; hindered amines described in U.S. Pat. Nos. 4,050,938 and 4,241.
155, British Patent No. 2,027,731 (A) and the like, and the metal complexes and the like. These compounds are usually used in an amount of 5 to 10 with respect to the corresponding color coupler.
The object can be achieved by co-emulsifying 0% by weight of the coupler and adding it to the photosensitive layer.

In order to prevent the cyan dye image from being deteriorated by heat and especially by light, it is more effective to introduce an ultraviolet absorber into the cyan coloring layer and the layers on both sides adjacent to the cyan coloring layer.

As the ultraviolet absorber, a benzotriazole compound substituted with an aryl group (for example, those described in US Pat. No. 3,533,794) and a 4-thiazolidone compound (for example, US Pat. No. 3,314,794) are used. No. 3,352,681), benzophenone compounds (for example, those described in JP-A-46-2784), cinnamic acid ester compounds (for example, US Pat.
705,805 and 3,707,395), butadiene compounds (US Pat. No. 4,045,22).
9) or a benzoxazole compound (for example, US Pat. Nos. 3,406,070 and 4,27).
Those described in No. 1,307) can be used. An ultraviolet absorbing coupler (for example, an α-naphthol-based cyan dye forming coupler), an ultraviolet absorbing polymer, or the like may be used. These UV absorbers may be mordanted in a specific layer. Among them, the benzotriazole compound substituted with the above aryl group is preferable.

To apply the present invention to multilayer silver halide color photographic light-sensitive materials, a blue-sensitive silver halide emulsion layer containing a yellow coupler and a green-sensitive silver halide emulsion layer containing a magenta coupler are provided on a support. Although at least one red-sensitive silver halide emulsion layer containing a cyan coupler and a cyan coupler can be applied in this order, the order may be different. Also, an infrared-sensitive silver halide emulsion layer can be used in place of at least one of the above-mentioned photosensitive emulsion layers. Color reproduction of the subtractive method is performed by incorporating a silver halide emulsion having sensitivity in each wavelength range and a color coupler forming a dye having a complementary color relationship with the light to be exposed in these light-sensitive emulsion layers. be able to. However, the photosensitive emulsion layer and the coloring hue of the color coupler may not have the above correspondence.

The compound of the present invention can be applied to, for example, color paper, color reversal paper, direct positive color photographic material, color negative film, color positive film, color reversal film and the like. Among them, a color photosensitive material having a reflective support (for example, color paper, color reversal paper) or a color photosensitive material for forming a positive image (for example,
It is preferably applied to a direct positive color light-sensitive material, a color positive film, a color reversal film).

The silver halide emulsion and other materials (additives and the like) and photographic constituent layers (layer arrangement and the like) applied in the present invention, and the processing method and processing addition applied for processing the light-sensitive material. Examples of the agent include the following patent publications, particularly European Patent EP 0,355,660A2 (Japanese Patent Application No.
Those described in No. 107011) are preferably used.

[0129]

[Table 1]

[0130]

[Table 2]

[0131]

[Table 3]

[0132]

[Table 4]

[0133]

[Table 5]

Further, as a cyan coupler, JP-A-2-
In addition to the diphenylimidazole-based cyan coupler described in 33144, European Patent EP 0,333,185A2
3-Hydroxypyridine cyan couplers (especially couplers (42) listed as specific examples, which have been converted into 2-equivalent by attaching a base-eliminating group to couplers (6) and (9)) Is particularly preferable) and JP-A-64
It is also preferable to use the cyclic active methylene cyan couplers described in No. 32260 (among which coupler examples 3, 8, and 34 listed as specific examples are particularly preferable).

As the silver halide used in the present invention, silver chloride, silver bromide, silver chlorobromide, silver iodochlorobromide, silver iodobromide and the like can be used, but especially for the purpose of rapid processing. It is preferable to use a silver chlorobromide or silver chloride emulsion having a silver chloride content substantially free of silver iodide of 90 mol% or more, further 95% or more, and particularly 98% or more.

Further, in the light-sensitive material according to the present invention, a hydrophilic colloid layer is added to the photosensitive colloid layer for the purpose of improving the sharpness of an image, etc., in EP No. 0,337,490A2, No. 27-No.
Dyes which can be decolorized by processing (among others, oxonol dyes) described on page 76 are added so that the optical reflection density at 680 nm of the light-sensitive material becomes 0.70 or more,
It is preferable that the water-resistant resin layer of the support contains 12% by weight or more (more preferably 14% by weight or more) of titanium oxide surface-treated with a divalent to tetravalent alcohol (eg, trimethylolethane).

Further, in the light-sensitive material according to the present invention, it is preferable to use a color image storability improving compound as described in European Patent EP 0,277,589A2 together with a coupler. In particular, it is preferably used in combination with a pyrazoloazole coupler.

That is, the compound (F) and // which chemically bond with the aromatic amine developing agent remaining after the color developing treatment to form a chemically inactive and substantially colorless compound.
Alternatively, the compound (G) which chemically bonds with an oxidized product of an aromatic amine color developing agent remaining after the color developing treatment to form a chemically inactive and substantially colorless compound is used simultaneously or alone. However, it is preferable to prevent the occurrence of stains and other side effects due to the formation of a coloring dye due to the reaction of the residual color developing agent in the film or the oxidant thereof with the coupler during storage after processing.

Further, in order to prevent various molds and bacteria which propagate in the hydrophilic colloid layer and deteriorate the image, the light-sensitive material according to the present invention has an anti-mold property as described in JP-A-63-271247. It is preferable to add an agent.

As the support used in the light-sensitive material of the present invention, a white polyester support for display or a layer containing a white pigment is provided on the support having a silver halide emulsion layer. A support may be used. Further, in order to improve the sharpness, it is preferable to apply an antihalation layer on the silver halide emulsion layer coated side or the back side of the support. In particular, the transmission density of the support is 0.3 so that the display can be viewed with both reflected light and transmitted light.
It is preferably set in the range of 5 to 0.8.

The light-sensitive material according to the present invention may be exposed to visible light or infrared light. The exposure method may be low-illuminance exposure or high-illuminance short-time exposure, and in the latter case, a laser scanning exposure method in which the exposure time per pixel is shorter than 10 ⁻⁴ seconds is preferable. Further, upon exposure, it is preferable to use the band stop filter described in US Pat. No. 4,880,726. As a result, light color mixture is removed, and color reproducibility is significantly improved.

The light-sensitive material according to the present invention can be processed by a conventional method described in Research Disclosure No. 17643, pages 28 to 29, and No. 18716, 615, left column to right column. it can. For example,
A color development processing step, a desilvering processing step, and a water washing processing step are performed. In the desilvering process, instead of the bleaching process using a bleaching agent and the fixing process using a fixing solution, a bleach-fixing processing process using a bleach-fixing solution can be performed, or a bleaching process step, a fixing process step, The bleach-fixing steps may be combined in any order. The stabilizing step may be performed instead of the washing step, or the stabilizing step may be performed after the washing step. It is also possible to perform a monobath processing step using a one-bath development bleach-fix processing solution in which color development, bleaching and fixing are carried out in one bath. In combination with these processing steps, a pre-hardening step, a neutralizing step thereof, a stop-fixing step, a post-hardening step, an adjusting step, an intensifying step and the like may be performed. An intermediate water washing step may be optionally provided between the above steps. In these processings, a so-called activator processing step may be performed instead of the color development processing step.

[0143]

The present invention is described in detail below with reference to examples, but the present invention is not limited to these. Example 1 5.8 g of the coupler (M-4) of the present invention was weighed, 5.8 g of a high boiling organic solvent dibutyl phthalate was added, and 24 ml of ethyl acetate was further added to dissolve the solution, and this solution was added to sodium dodecylbenzenesulfonate. 10 wt% including 1.5 g
It was emulsified and dispersed in 200 g of an aqueous gelatin solution.

The total amount of this emulsified dispersion was added to a high silver chloride emulsion 24.
7 g (silver 70.0 g / kg emulsion, silver bromide content 0.5 mol%) and coated on a triacetate film base having an undercoat layer so that the coated silver amount was 1.73 g / m ^2. Sample 101 was prepared by providing a gelatin layer as a protective layer on the coating layer so that the dry film thickness was 1.0 μm. As a gelatin hardener, 1-oxy-3,
5-Dichloro-s-triazine sodium salt was used.

When the above emulsified dispersion was prepared in the same manner as in Sample 101, as shown in Table A, the coupler and the color image stabilizer 1 (the compound represented by the general formula (A), 20 mol based on the coupler) were used. %)), A color image stabilizer 2 (a compound represented by the general formula (B), and 100 mol% based on the coupler) are combined to emulsify, and the mixture is applied in the same manner as in Sample 101, and Samples 102 to 147. made.

Each of the samples thus obtained was subjected to wedge exposure and then developed in the following processing steps. [Processing step] [Temperature] [Time] Color development 35 ° C. 45 seconds Bleach fixing 30-35 ° C. 45 seconds Rinse 30-35 ° C. 20 seconds Rinse 30-35 ° C. 20 seconds Rinse 30-35 ° C. 20 seconds Dry 70 ~ 80 ° C 60 seconds

The composition of each processing liquid is as follows. [Color developer] Water 800 ml Ethylenediamine-N, N, N, N-tetramethylenephosphonic acid 1.5 g Potassium bromide 0.015 g Triethanolamine 8.0 g Sodium chloride 1.4 g Potassium carbonate 25 g N-Ethyl-N- (Β-Methanesulfonamidoethyl) -3-methyl-4-aminoaniline sulfate 5.0 g N, N-bis (carboxymethyl) hydrazine 5.5 g Optical brightener (WHITEX 4B, manufactured by Sumitomo Chemical Co., Ltd.) 1. 0g Add water and 1000ml pH (25 ℃) 10.05

[Bleach-fixing solution] Water 400 ml Ammonium thiosulfate (700 g / liter) 100 ml Sodium sulfite 17 g Ethylenediaminetetraacetic acid iron (III) ammonium 55 g Ethylenediaminetetraacetic acid disodium 5 g Ammonium bromide 40 g Water is added to 1000 ml pH (25 ° C.) 6.0 [Rinse solution] Ion-exchanged water (calcium and magnesium are 3ppm or less each)

101 to form a dye image in this way
Each sample of 147 was equipped with a UV absorption filter manufactured by Fuji Photo Film Co., Ltd., which cuts light of 400 nm or less, and was set to 8 with a xenon tester (illuminance 200,000 lux).
Exposed for a day. The yellow density (stain) of the unexposed portion of each sample was measured, and the density residual ratio at the initial density of 1.0 and 0.5 was determined. The measurement was carried out with a Fuji Denki densitometer. Further, the entire surface of the coated sample was separately exposed, and the above-mentioned development processing was performed. The spectral absorption spectrum of each of the obtained samples was measured, and the absorbance at 650 nm part / absorbance at λmax part x 1
00 was obtained and the cloudiness of the hue was evaluated. The results obtained are shown in Table A.

[0150]

[Table 6]

[0151]

[Table 7]

[0152]

[Chemical 70]

[0153]

[Chemical 71]

[0154]

[Chemical 72]

[0155]

[Chemical formula 73]

From these results, the samples using the comparative compounds have been improved in the light fastness of the color image, but the generation of stains and the bad influence on the hue are great. On the other hand, the sample of the present invention has an improved light fastness of the color image, and the occurrence of stain and the adverse effect on the hue are very small. Moreover, in the sample of the present invention, the generation of stain is suppressed as compared with the case where only the compound represented by the general formula (A) of the present invention is used in combination with the coupler. These results were remarkably excellent by the technique known so far, which was unexpectedly unexpected.

Example 2 The surface of a paper support laminated on both sides with polyethylene was subjected to a corona discharge treatment, and then a gelatin subbing layer containing sodium dodecylbenzenesulfonate was provided, and various photographic constituent layers were further coated to prepare a A multilayer color photographic paper having the layer structure shown was produced. The coating liquid was prepared as follows.

Preparation of coating solution for fifth layer Cyan coupler (ExC) 32.0 g, color image stabilizer (C
od-2) 3.0 g, color image stabilizer (Cpd-4) 2.0
g, color image stabilizer (Cpd-6) 18.0 g, color image stabilizer (Cpd-7) 40.0 g and color image stabilizer (Cpd-).
8) 5.0 g, ethyl acetate 50.0 cc and solvent (S
14.0 g of olv-6) was added and dissolved, and this solution was added to 500 cc of a 20% gelatin aqueous solution containing 8 cc of sodium dodecylbenzenesulfonate, and then emulsified and dispersed by an ultrasonic homogenizer to prepare an emulsified dispersion. on the other hand,
Silver chlorobromide emulsion (cubic, 1: 4 of large size emulsion of average grain size 0.58 μm and small size emulsion of 0.45 μm)
Mixture (Ag molar ratio). Coefficients of variation of grain size distribution are 0.09 and 0.11, respectively, and each size emulsion is AgBr
0.6 mol% was locally contained in a part of the particle surface) was prepared. The red-sensitive sensitizing dye E shown below was added to this emulsion in an amount of 0.9 × 10 ^-4 per mol of silver for a large-sized emulsion.
Mol, and 1.1 × 10 ⁻⁴ mol was added to the small size emulsion. The chemical ripening of this emulsion was performed by adding a sulfur sensitizer and a gold sensitizer. The above emulsified dispersion and this red-sensitive silver chlorobromide emulsion were mixed and dissolved to prepare a coating solution for the fifth layer having the composition shown below.

The coating solutions for the first to fourth layers, the sixth layer and the seventh layer were prepared in the same manner as the coating solution for the fifth layer. 1-Oxy-3,5-dichloro-s-triazine sodium salt was used as a gelatin hardening agent for each layer. In addition, the total amount of Cpd-10 and Cpd-11 in each layer is 2
It was added to a 5.0 mg / m ² and 50.0 mg / m ^2.
The following spectral sensitizing dyes were used for the silver chlorobromide emulsion of each photosensitive emulsion layer.

[Blue Sensitive Emulsion Layer] Sensitizing Dye A

[0161]

[Chemical 74]

And sensitizing dye B

[0163]

[Chemical 75]

(2.0 × 10 ^-4 mol for large size emulsion and 2.5 × 10 ^-4 mol for small size emulsion per mol of silver halide) [Green-sensitive emulsion Layer] Sensitizing dye C

[0165]

[Chemical 76]

(Per mol of silver halide, 4.0 × 10 ^-4 mol for large size emulsion, 5.6 × 10 ^-4 mol for small size emulsion) and sensitizing dye D

[0167]

[Chemical 77]

(7.0 × 10 ⁻⁵ mol for large size emulsion and 1.0 × 10 ⁻⁵ mol for small size emulsion per mol of silver halide) [Red-sensitive emulsion layer] Sensitizing dye E

[0169]

[Chemical 78]

(0.9 × 10 ^-4 mol for large size emulsion and 1.1 × 10 ^-4 mol for small size emulsion per mol of silver halide) Further, the following compounds were halogenated. 2.6 × 10 ⁻³ mol was added per mol of silver halide.

[0171]

[Chemical 79]

Further, 1- (5-methylureidophenyl) -5-mercaptotetrazole was added to the blue-sensitive emulsion layer, the green-sensitive emulsion layer and the red-sensitive emulsion layer at 8.5 × 10 ⁻ per mol of silver halide. ⁵ mol, 7.7 × 10 ^-4
Mol, 2.5 × 10 ⁻⁴ mol. Further, 4-hydroxy-6-methyl-1,3,3a, 7-tetrazaindene was added to the blue-sensitive emulsion layer and the green-sensitive emulsion layer in an amount of 1 × 10 ⁻⁴ mol and 2 mol, respectively, per mol of silver halide. × 10 ^-4
Mol added. Further, the following dyes (the amount in parentheses represents the coating amount) were added to the emulsion layer in order to prevent irradiation.

[0173]

[Chemical 80]

(Layer Structure) The composition of each layer is shown below. The numbers represent the coating amount (g / m ² ). The silver halide emulsion represents the coating amount in terms of silver.

Support Polyethylene laminated paper [Polyethylene on the first layer side contains a white pigment (TiO ₂ ) and a bluish dye (ultraviolet)]

First Layer (Blue Sensitive Emulsion Layer) Silver chlorobromide emulsion (cubic, 3: 7 mixture of large size emulsion having average grain size of 0.88 μ and small size emulsion of 0.70 μ (silver molar ratio) The coefficient of variation of the grain size distribution is 0.08 and 0.10, respectively, and each size emulsion contains 0.3 mol% of silver bromide localized on a part of the grain surface.) 0.30 Gelatin 1.86 Yellow coupler (ExY) 0.82 Color image stabilizer (Cpd-1) 0.19 Solvent (Solv-3) 0.18 Solvent (Solv-7) 0.18 Color image stabilizer (Cpd-7) 0.06

Second layer (color mixing prevention layer) Gelatin 0.99 Color mixing inhibitor (Cpd-5) 0.08 Solvent (Solv-1) 0.16 Solvent (Solv-4) 0.08

Third Layer (Green-Sensitive Emulsion Layer) Silver chlorobromide emulsion (cubic, 1: 3 mixture of large size emulsion having average grain size 0.55μ and small size emulsion 0.39μ (Ag molar ratio) The coefficient of variation of the grain size distribution was 0.10 and 0.08, respectively, and 0.8 mol% of AgBr was locally contained in a part of the grain in each size emulsion.) 0.12 Gelatin 1.24 Magenta Coupler (ExM) 0.23 Color image stabilizer (Cpd-2) 0.03 Color image stabilizer (Cpd-3) 0.16 Color image stabilizer (Cpd-4) 0.02 Color image stabilizer (Cpd-) 9) 0.02 solvent (Solv-2) 0.40

Fourth Layer (UV Absorbing Layer) Gelatin 1.58 UV Absorbing Agent (UV-1) 0.47 Color Mixing Inhibitor (Cpd-5) 0.05 Solvent (Solv-5) 0.24

Fifth Layer (Red-Sensitive Emulsion Layer) Silver chlorobromide emulsion (cubic, 1: 4 mixture of large size emulsion with average grain size 0.58μ and small size emulsion 0.45μ (Ag molar ratio) The coefficient of variation of the grain size distribution was 0.09 and 0.11, and 0.6 mol% of AgBr was locally contained in a part of the grain surface in each size emulsion.) 0.23 Gelatin 1.34 Cyan coupler (ExC) 0.32 Color image stabilizer (Cpd-2) 0.03 Color image stabilizer (Cpd-4) 0.02 Color image stabilizer (Cpd-6) 0.18 Color image stabilizer (Cpd-7) ) 0.40 color image stabilizer (Cpd-8) 0.05 solvent (Solv-6) 0.14

Sixth Layer (UV Absorbing Layer) Gelatin 0.53 UV Absorbing Agent (UV-1) 0.16 Color Mixing Inhibitor (Cpd-5) 0.02 Solvent (Solv-5) 0.08

Seventh layer (protective layer) Gelatin 1.33 Acrylic modified copolymer of polyvinyl alcohol (17% conversion) 0.17 Liquid paraffin 0.03

[0183]

[Chemical 81]

[0184]

[Chemical formula 82]

[0185]

[Chemical 83]

[0186]

[Chemical 84]

[0187]

[Chemical 85]

[0188]

[Chemical 86]

[0189]

[Chemical 87]

[0190]

[Chemical 88]

[0191]

[Chemical 89]

The sample thus obtained was designated as 1A, and the magenta coupler and color image stabilizer (Cpd-
9) instead of the compound of the general formula (A) of the present invention,
Another sample was prepared in the same manner as Sample 1A except that the compound of the general formula (B) of the present invention was used instead of the color image stabilizer (Cpd-3), and the compounds were combined and emulsified as shown in Table B. 2A-11A were created. The addition amount was replaced by an equimolar amount. The comparative compound is the same as in Example 1. These were processed as follows.

First, a sensitometer (FWH type, manufactured by Fuji Photo Film Co., Ltd., color temperature of light source: 3200 ° K) manufactured by Fuji Photo Film Co., Ltd. was used for each sample, and gradation exposure of a three-color separation filter for sensitometry was performed. The exposure at this time is 250 with an exposure time of 0.1 seconds.
The exposure amount of CMS was adjusted. The exposed sample was subjected to continuous processing (running test) using a paper processor using a liquid having the following processing step and processing composition until the tank was replenished to twice the capacity of the color developing tank.

Treatment process Temperature Time Replenisher ^* Tank capacity (ml) (liter) Color development 35 ° C 45 seconds 161 17 Bleach fixing 30-35 ° C 45 seconds 215 17 rinse 30-35 ° C 20 seconds -10 rinse 30- 35 ° C. 20 sec −10 Rinse 30 to 35 ° C. 20 sec 350 10 Dry 70 to 80 ° C. 60 sec * Replenishment amount per 1 m ² of light-sensitive material Rinsing from to tank 3 countercurrent system. The composition of each treatment liquid is as follows.

[Color developer] Tank solution Replenisher Water 800ml 800ml Ethylenediamine-N, N, N, N-tetramethylenephosphonic acid 1.5g 2.0g Potassium bromide 0.015g-Triethanolamine 8.0g 12.0g Sodium chloride 1.4g -Potassium carbonate 25 g 25 g N-ethyl-N- (β-methanesulfonamidoethyl) -3-methyl-4-aminoaniline sulfate 5.0 g 7.0 g N, N-bis (carboxymethyl) hydrazine 4.0 g 5.0 g N, N-di (sulfoethyl) hydroxylamine ・ 1Na 4.0g 5.0g Optical brightener (WHITEX 4B, Sumitomo Chemical Co., Ltd.) 1.0g 2.0g Add water 1000ml 1000ml pH (25 ℃) 10.05 10.45

[Bleach-fixing solution] (tank solution and replenisher are the same) Water 400 ml Ammonium thiosulfate (70%) 100 ml Sodium sulfite 17 g Ethylenediaminetetraacetic acid iron (III) ammonium 55 g Ethylenediaminetetraacetic acid disodium 5 g Ammonium bromide Add 40 g water and add 1000 ml pH (25 ℃) 6.0

[Rinse solution] (tank solution and replenisher are the same) Ion exchange water (calcium and magnesium are 3 ppm each)
Less than)

Each sample thus formed with a dye image was tested for fading. The anti-fading effect was evaluated by using a xenon tester (illuminance: 200,000 lux) for 10 days at an initial density of 1.0 and 0.5 and remaining magenta density.
The results obtained are shown in Table B.

[0199]

[Table 8]

From the results shown in Table B, it is understood that the sample of the present invention to which the compound of the present invention is added exhibits the same excellent effect as in Example 1 even in the light-sensitive material having a multilayer structure. Further, the sample of the present invention also obtained good results with respect to the stain hue.

Example 3 Example 1, Sample 101 described in Japanese Patent Application Laid-Open No. 2-854.
In the ninth layer, the coupler C-4 in the ninth layer was changed to the coupler M-14, M-27 or M-41 of the present invention (the addition amount was replaced by an equal amount at the reaction site of the coupler with the developing agent),
The compound A-1, A-5, A-8 or A-34 of the general formula (A) of the present invention is added to the seventh layer, the eighth layer and the ninth layer (the addition amount is the amount added to the coupler of each layer). 5 mol%), and further the compounds B-3 and B of the general formula (B) of the present invention.
-12, B-18, B-27 or B-31 was added (addition amount was 50 mol% with respect to the coupler of each layer) except that the mixture was co-emulsified, JP-A-2-854, Example 1, sample. Samples were prepared as in 101. When these samples were subjected to the same fading test as in Example 2 of the present invention, the samples of the present invention showed an excellent anti-fading effect.
It has been found that the present invention has an excellent anti-fading effect even in this light-sensitive material.

Example 4 In the sixth and seventh layers of the color photographic light-sensitive material of Example 2 described in JP-A-1-158431, the couplers ExM-1 and M2 were replaced with the couplers M-14 and M of the present invention. -3
5 or M-48 (addition amount is equimolar replacement), the compound of the general formula (A) of the present invention A-1, A-5,
A-8 or A-33 was added (addition amount was 25 mol% with respect to the coupler of each layer), and an anti-fading agent Cpd was added.
-9 is the compound of the general formula (B) of the present invention B-3, B-1
2, B-27, B-31 or B-42, except that the emulsion was changed to coemulsified, JP-A-1-158431, Example 2
A sample was prepared in the same manner as in. When these samples were subjected to the same fading test as in Example 2 of the present invention, the samples of the present invention showed an excellent anti-fading effect. It has been found that the present invention has an excellent anti-fading effect even in this light-sensitive material.

[0203]

According to the present invention, the color reproducibility of the dye image formed by color development processing is good, and the light fastness of the magenta dye image in the high density region and particularly in the low density region is remarkably improved.
It is possible to obtain a silver halide color photographic light-sensitive material in which the stain in the unexposed area is small and the fading balance is well balanced.

─────────────────────────────────────────────────── ───

[Procedure amendment]

[Submission date] May 12, 1992

[Procedure Amendment 1]

[Document name to be amended] Statement

[Name of item to be corrected] Claim 1

[Correction method] Change

[Correction content]

[Chemical 1] (In the formula, A is a mere bond, -O-, -S (O) _Q- ,
_{-N (R 27) -, -} (C (R 28) (R 29)) T -
Alternatively, it represents a linking group L.

[Chemical 2] R ₂₁ and R ₂₂ are each a hydrogen atom, an aliphatic group,
Aromatic group, heterocyclic group, acyl group, sulfonyl group, -P
(R ₃₂ ) (R ₃₃ ), -P (O) (R ₃₃ ).
(R ₃₄ ) or a silyl group. R ₂₃ and R
₂₄ represents an aliphatic group, and R ₂₅ and R ₂₆
Each represents a substituent. m and n represent an integer of 1 to 3. When m and n are 2 or more, a plurality of R ₂₅ , R
₂₆ may be the same or different. R ₂₁ and R
₃₀ , R ₂₂ and R ₃₀ , R ₂₁ and R ₂₃ , R ₂₂ and R
₂₄ , R ₂₃ and R _25, and R ₂₄ and R ₂₆ may be bonded to each other to form a 5- to 8-membered ring. B is -O-,
-S (O) _Q- or -C (R < ₂₈ >) (R < ₂₉ >) represents one, and Q represents 0, 1 or 2. R ₂₇ is a hydrogen atom,
It represents an aliphatic group, an acyl group, a sulfonyl group, an aliphatic oxycarbonyl group or an aromatic oxycarbonyl group. R
₂₈ and R ₂₉ each represent a hydrogen atom, an aliphatic group or an aromatic group, and T represents 1 or 2. R ₃₀ has the same meaning as R ₂₁ , R ₃₁ represents a substituent, and V is 0.
Represents an integer of 3 and when V is plural, plural R ₃₁ may be the same or different. R ₃₂ , R ₃₃ and R ₃₄ each represent an aliphatic group, an aromatic group, an aliphatic oxy group or an aromatic oxy group. However, R ₂₁ , R
_At least one of ₂₂ and R ₃₀ is a hydrogen atom,
And at least one is not a hydrogen atom. )

[Chemical 3] (In the formula, R ₄ represents an aliphatic group, an aromatic group, a heterocyclic group or a silyl group. R ₅ , R ₆ , R ₇ , R ₈ and R ₉ may be the same or different and each is a hydrogen atom. , An aliphatic group, an aromatic group, an amino group having a substituent, an aliphatic thio group, an aromatic thio group, a halogen atom, —COOR ₄ ′ or —OR ₄ ′, wherein R ₄ ′ is R ₄ synonymous.-OR ₄ 'and its adjacent position _{R 4} and _{R 5, R} 5 _{R 6}
Alternatively, R _{6 and} R ₇ may combine with each other to form a 5-membered ring, a 6-membered ring or a spiro ring. )

[Procedure Amendment 2]

[Document name to be amended] Statement

[Correction target item name] 0017

[Correction method] Change

[Correction content]

R ₂₁ and R ₂₂ are each a hydrogen atom, an aliphatic group, an aromatic group, a heterocyclic group, an acyl group, a sulfonyl group, -P (R ₃₂ ) (R ₃₃ ), -P (O) (R
₃₃ ) (R ₃₄ ) or a silyl group. R ₂₃ and R ₂₄ each represent an aliphatic group, and R ₂₅ and R _24
26 each represents a substituent. m and n represent an integer of 1 to 3. When m and n are 2 or more, a plurality of R ₂₅ and R ₂₆ may be the same or different. R
₂₁ and R ₃₀ , R ₂₂ and R ₃₀ , R ₂₁ and R ₂₃ , R
₂₂ and R ₂₄ , R ₂₃ and R _25, and R ₂₄ and R ₂₆ may be bonded to each other to form a 5- to 8-membered ring. The B -O -, - S (O ) Q - or -C _{(R 28)}
(R ₂₉ )-, and Q represents 0, 1 or 2. R
₂₇ is a hydrogen atom, an aliphatic group, an acyl group, a sulfonyl group,
It represents an aliphatic oxycarbonyl group or an aromatic oxycarbonyl group. R ₂₈ and R ₂₉ each represent a hydrogen atom, an aliphatic group or an aromatic group, and T is 1 or 2
Represents R ₃₀ has the same meaning as R ₂₁ , R ₃₁ represents a substituent, V represents an integer of 0 to 3, and when V is plural, plural R ₃₁ may be the same or different. . R ₃₂ , R ₃₃ and R ₃₃ are each an aliphatic group,
It represents an aromatic group, an aliphatic oxy group or an aromatic oxy group. Provided that at least one of R ₂₁ , R ₂₂ and R ₃₀ is
One is a hydrogen atom and at least one is not a hydrogen atom. )

[Procedure 3]

[Document name to be amended] Statement

[Correction target item name] 0019

[Correction method] Change

[Correction content]

(In the formula, R ₄ represents an aliphatic group, an aromatic group, a heterocyclic group or a silyl group. R ₅ , R ₆ , R ₇ and R ₈
R ₉ and R ₉ may be the same or different and each is a hydrogen atom, an aliphatic group, an aromatic group, an amino group having a substituent, an aliphatic thio group, an aromatic thio group, a halogen atom, or -C.
Represents the OOR ₄ 'or -OR _4'. Here, R ₄ 'is synonymous with R ₄ . -OR ₄ 'and its adjacent positions R ₄ and R ₅ , R ₅ and R ₆ or R ₆ and R ₇ are bonded to each other to form 5
A member ring, a 6-membered ring or a spiro ring may be formed. )

[Procedure amendment 4]

[Document name to be amended] Statement

[Name of item to be corrected] 0037

[Correction method] Change

[Correction content]

In terms of the effect of the present invention, the formulas [MI] to [M-
Of the coupler skeletons represented by V], [M-II] and [M-HIII] are particularly preferable, and [M-II]
-II] is most preferable.

[Procedure Amendment 5]

[Document name to be amended] Statement

[Correction target item name] 0048

[Correction method] Change

[Correction content]

[0048]

[Chemical 17]

[Procedure correction 6]

[Document name to be amended] Statement

[Correction target item name] 0075

[Correction method] Change

[Correction content]

R ₂₁ and R ₂₂ are each a hydrogen atom,
Aliphatic groups (eg methyl, ethyl, isopropyl, benzyl, octyl, dodecyl, methoxyethyl, allyl), aromatic groups (eg phenyl, 4-methoxyphenyl), heterocyclic groups (eg 2-tetrahydropyranyl, 2
-Tetrahydrothienyl), acyl groups (e.g. acetyl, pivaloyl, myristoyl, benzoyl, 3,5-
Di-t-butyl-4-hydroxybenzoyl), a sulfonyl group (for example, methanesulfonyl, octanesulfonyl, benzenesulfonyl), -P (R ₃₂ ).
(R ₃₃ ), —P (O) (R ₃₃ ) (R ₃₄ ) and a silyl group (eg, trimethylsilyl, dimethyl-t-butylsilyl, triphenylsilyl). Where R
₃₂ , R ₃₃ and R ₃₄ are aliphatic groups (eg methyl, ethyl, octyl) aromatic groups (eg phenyl,
4-t-butylphenyl), an aliphatic oxy group (for example,
Methoxy, t-butoxy, octyloxy) or an aromatic oxy group (eg phenoxy, 4-methoxyphenoxy).

[Procedure Amendment 7]

[Document name to be amended] Statement

[Correction target item name] 0076

[Correction method] Change

[Correction content]

At least one of R ₂₁ , R ₂₂ and R ₃₀ described above is a hydrogen atom, and at least one of them is not a hydrogen atom, and the effect of the present invention as a substituent when it is not a hydrogen atom In terms of an aliphatic group, an acyl group, a sulfonyl group, and -P (O) (R ₃₃ ) (R ₃₄ ).
(One of R _{33 and} R ₃₄ is an aromatic group and the other is an aliphatic oxy group or an aromatic oxy group) is preferable, and an aliphatic group, an acyl group and a sulfonyl group are particularly preferable.

[Procedure Amendment 8]

[Document name to be amended] Statement

[Correction target item name] 0098

[Correction method] Change

[Correction content]

Next, the general formula (B) will be described in detail. In the formula,
R ₄ is an aliphatic group (eg methyl, n-butyl, n-octyl, n-hexadecyl, ethoxyethyl, 3-phenoxypropyl, benzyl, vinyl, allyl), an aromatic group (eg phenyl, naphthyl), a heterocyclic group (Eg pyridyl, tetrahydropyranyl) or a silyl group (eg trimethylsilyl, t-butyldimethylsilyl). R < ₅ >, R < ₆ >, R <_7> , R < ₈ > and R < ₉ > may be the same or different from each other, and each is a hydrogen atom or an aliphatic group (e.g., methyl, n-butyl, n-octyl, sec-dodecyl, t-butyl). , T-amyl, t-hexyl, t-octyl, t-octadecyl, α, α-dimethylbenzyl, 1,1-dimethyl-4-hexyloxycarbonylbutyl, vinyl, allyl), aromatic groups (eg phenyl, naphthyl). , P-methoxyphenyl, 2,4-t-butylphenyl), an amino group having a substituent (for example, acetylamino, propylonylamino, benzamino, N
-Methylamino, N, N-dimethylamino, N, N-dihexylamino, N-cyclohexylamino, N- (t
-Butyl) amino, and a nitrogen-containing heterocyclic group in which a substituent is closed, for example, piperidino, 1-piperazinyl), an aliphatic thio group (for example, methylthio, n-butylthio, sec-
Butylthio, t-butylthio, dodecylthio), aromatic thio group (eg phenylthio, naphthylthio), halogen atom (eg chlorine, bromine), —COOR ′ ₄ (eg octyloxycarbonyl, 2,4-di-t-butylphenoxycarbonyl). ) Or -OR ' ₄ .
Here, R ′ ₄ has the same meaning as R ₄ . R ₄ and R ₅ may combine with each other to form a 5-membered ring, a 6-membered ring or a spiro ring. —OR ₄ ′ and its adjacent positions R ₅ and R ₆ or R ₆ and R ₇ may be bonded to each other to form a 5-membered ring, a 6-membered ring or a spiro ring. Examples of these rings include a chroman ring, a coumaran ring, a spirochroman ring, and a spiroindane ring.

[Procedure Amendment 9]

[Document name to be amended] Statement

[Correction target item name] 0108

[Correction method] Change

[Correction content]

[0108]

[Chemical formula 61]

[Procedure Amendment 10]

[Document name to be amended] Statement

[Correction target item name] 0120

[Correction method] Change

[Correction content]

As the high boiling point organic solvent which can be used in the above oil-in-water dispersion method, phthalic acid esters (for example, dibutyl phthalate, dioctyl phthalate, dicyclohexyl phthalate, di-2-ethylhexyl phthalate, decyl phthalate, bis ( 2,4-di-t-
Amylphenyl) isophthalate, bis (1,1-diethylpropyl) phthalate), esters of phosphoric acid or phosphonic acid (for example, diphenyl phosphate, triphenyl phosphate, tricresyl phosphate, 2-
Ethylhexyl diphenyl phosphate, dioctyl butyl phosphate, tricyclohexyl phosphate,
Tri-2-ethylhexyl phosphate, tridodecyl phosphate, di-2-ethylhexyl phenylphosphonate), benzoic acid esters (for example, 2-ethylhexyl benzoate, 2,4-dichlorobenzoate,
Dodecyl benzoate, 2-ethylhexyl-p-hydroxybenzoate), amides (eg, N, N-diethyldodecane amide, N, N-diethyllauryl amide), alcohols or phenols (isostearyl alcohol, 2,4-di). -Tert-amylphenol, etc., aliphatic esters (eg, dibutoxyethyl succinate, di-2-ethylhexyl succinate, 2-hexyldecyl tetradecanoate, tributol citrate, diethyl azelate, isostearyl lactate, trioctyl). Citrate), aniline derivatives (N, N-dibutyl-2-butoxy-5-tert-octylaniline, etc.), chlorinated paraffins (chlorine content 10% to 80%)
Paraffins), trimesic acid esters (eg, tributyl trimesate), dodecylbenzene, diisopropylnaphthalene, and the like. As an auxiliary solvent, an organic solvent having a boiling point of 30 ° C. or higher and about 160 ° C. or lower (eg, ethyl acetate, butyl acetate, ethyl propionate, methyl ethyl ketone, cyclohexanone, 2-ethoxyethyl acetate, dimethylformamide) may be used in combination.

[Procedure Amendment 11]

[Document name to be amended] Statement

[Name of item to be corrected] 0122

[Correction method] Change

[Correction content]

Various anti-fading agents can be used in combination with the light-sensitive material of the present invention. Hindered phenols centering on hydroquinones, 6-hydroxychromans, 5-hydroxycoumarans, spirochromans, p-alkoxyphenols and bisphenols as organic anti-fading agents for cyan, magenta and / or yellow images , Gallic acid derivatives, methylenedioxybenzenes,
Typical examples include aminophenols, hindered amines, and ether or acylated ester derivatives in which the phenolic hydroxyl groups of these compounds are silylated or alkylated. Further, a metal complex represented by (bissalicylaldoximato) nickel complex and (bis-N, N-dialkyldithiocarbamato) nickel complex can also be used.

[Procedure Amendment 12]

[Document name to be amended] Statement

[Correction target item name] 0147

[Correction method] Change

[Correction content]

The composition of each processing liquid is as follows. [Color developer] Water 800 ml Ethylenediamine-N, N, N ', N'-tetramethylenephosphonic acid 1.5 g Potassium bromide 0.015 g Triethanolamine 8.0 g Sodium chloride 1.4 g Potassium carbonate 25 g N-ethyl -N- (β-methanesulfonamidoethyl) -3-methyl-4-aminoaniline sulfate 5.0 g N, N-bis (carboxymethyl) hydrazine 5.5 g Optical brightener (WHITEX4B, manufactured by Sumitomo Chemical Co., Ltd.) 1. 0 g Water was added to 1000 ml pH (25 ° C) 10.05

[Procedure Amendment 13]

[Document name to be amended] Statement

[Correction target item name] 0173

[Correction method] Change

[Correction content]

[0173]

[Chemical 80]

[Procedure Amendment 14]

[Document name to be amended] Statement

[Name of item to be corrected] 0186

[Correction method] Change

[Correction content]

[0186]

[Chemical 84]

[Procedure Amendment 15]

[Document name to be amended] Statement

[Name of item to be corrected] 0195

[Correction method] Change

[Correction content]

[0195]

Claims (2)

[Claims] 1. A same layer containing at least one pyrazoloazole type dye-forming coupler, at least one compound represented by the following general formula (A), and at least one compound represented by the following general formula (B). A silver halide color photographic light-sensitive material characterized by being contained therein. [Chemical 1] (In the formula, A is a mere bond, -O-, -S (O) _Q- ,
_{-N (R 27) -, -} (C (R 28) (R 29)) T - or represents a linking group L. [Chemical 2] R ₂₁ and R ₂₂ are each a hydrogen atom, an aliphatic group, an aromatic group, a heterocyclic group, an acyl group, a sulfonyl group, or -P.
(R ₃₂ ) (R ₃₃ ), —P (O) (R ₃₃ ) (R ₃₄ ), or a silyl group. R ₂₃ and R ₂₄ each represent an aliphatic group, and R ₂₅ and R ₂₆ each represent a substituent. m and n represent an integer of 1 to 3. When m and n are 2 or more, a plurality of R ₂₅ and R ₂₆ may be the same or different. R ₂₁ and R ₃₀ , R ₂₂ and R ₃₀ , R ₂₁ and R ₂₃ , R ₂₂ and R ₂₄ , R ₂₃ and R _25, and R ₂₄ and R ₂₆ are bonded to each other, and
A ~ 8-membered ring may be formed. B is -O-, -S
(O) _Q - or _{-C (R 28) (R 29} ) - represents, Q represents 0, 1 or 2. R ₂₇ represents a hydrogen atom, an aliphatic group, an acyl group, a sulfonyl group, an aliphatic oxycarbonyl group or an aromatic oxycarbonyl group. R ₂₈ and R ₂₉
Each represents a hydrogen atom aliphatic group or an aromatic group,
T represents 1 or 2. R ₃₀ has the same meaning as R ₂₁ ,
₃₁ represents a substituent, V represents an integer of 0 to 3, and when V is plural, plural R ₃₁ may be the same or different. R ₃₂ , R ₃₃ and R ₃₄ each represent an aliphatic group, an aromatic group, an aliphatic oxy group or an aromatic oxy group.
However, at least one of R ₂₁ , R ₂₂ and R ₃₀ is a hydrogen atom, and at least one is not a hydrogen atom. ) [Chemical 3] (In the formula, R ₄ represents an aliphatic group, an aromatic group, a heterocyclic group or a silyl group. R ₅ , R ₆ , R ₇ , R ₈ and R ₉ may be the same or different and each is a hydrogen atom. , An aliphatic group, an aromatic group, an amino group having a substituent, an aliphatic thio group, an aromatic thio group, a halogen atom, —COOR ₄ ′ or —OR ₄ ′, wherein R ₄ ′ is R ₄ and R ₄ and R ₅ , R ₅ and R _6, or R ₆ and R ₇ may combine with each other to form a 5-membered 6-membered ring or a spiro ring.) 2. The silver halide color photographic light-sensitive material according to claim 1, wherein the compound represented by the general formula (A) is a compound represented by the following general formula (AI). [Chemical 4] (In the formula, A, R ₂₁ , R ₂₂ , R ₂₃ , R ₂₄ , R ₂₅ , R ₂₆ ,
m and n have the same meanings as in general formula (A). )