JPH0639374A - Water softening apparatus having regenerating function - Google Patents
Water softening apparatus having regenerating functionInfo
- Publication number
- JPH0639374A JPH0639374A JP19936592A JP19936592A JPH0639374A JP H0639374 A JPH0639374 A JP H0639374A JP 19936592 A JP19936592 A JP 19936592A JP 19936592 A JP19936592 A JP 19936592A JP H0639374 A JPH0639374 A JP H0639374A
- Authority
- JP
- Japan
- Prior art keywords
- water
- tank
- exchange resin
- cation exchange
- diaphragm
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/42—Treatment of water, waste water, or sewage by ion-exchange
- C02F2001/425—Treatment of water, waste water, or sewage by ion-exchange using cation exchangers
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
- C02F1/461—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
- C02F1/46104—Devices therefor; Their operating or servicing
- C02F1/4618—Devices therefor; Their operating or servicing for producing "ionised" acidic or basic water
- C02F2001/46185—Devices therefor; Their operating or servicing for producing "ionised" acidic or basic water only anodic or acidic water, e.g. for oxidizing or sterilizing
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2201/00—Apparatus for treatment of water, waste water or sewage
- C02F2201/46—Apparatus for electrochemical processes
- C02F2201/461—Electrolysis apparatus
- C02F2201/46105—Details relating to the electrolytic devices
- C02F2201/46115—Electrolytic cell with membranes or diaphragms
Landscapes
- Treatment Of Water By Ion Exchange (AREA)
- Water Treatment By Electricity Or Magnetism (AREA)
Abstract
Description
【0001】[0001]
【産業上の利用分野】本発明は、軟水槽に陽イオン交換
樹脂を内蔵して、水の硬度を低下させる再生機能を有す
る軟水器に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a water softener having a regeneration function for reducing the hardness of water by incorporating a cation exchange resin in a soft water tank.
【0002】[0002]
【従来の技術】水の硬度を低下させるため、一般に強酸
性の陽イオン交換樹脂が用いられている。陽イオン交換
樹脂は、スチレンとジビニルベンゼンの共重合物の如く
水に不溶性の高分子に、イオン交換基としてスルホン
基、カルボキシル基、ホスホン基、アルソン基、フェノ
ール性水酸基などが結合した樹脂である。2. Description of the Related Art Generally, a strongly acidic cation exchange resin is used to reduce the hardness of water. The cation exchange resin is a resin in which a sulfone group, a carboxyl group, a phosphone group, an arsone group, a phenolic hydroxyl group or the like is bonded as an ion exchange group to a water-insoluble polymer such as a copolymer of styrene and divinylbenzene. .
【0003】上記のイオン交換基を有する陽イオン交換
樹脂の中で、スルホン基を有する陽イオン交換樹脂を一
例にして水の硬度低下作用について説明する。陽イオン
交換樹脂は、次の反応式に示す如く水の硬度成分である
カルシウムイオンとマグネシウムイオンを除去すること
ができる。Among the above cation exchange resins having an ion exchange group, a cation exchange resin having a sulfone group will be taken as an example to explain the action of decreasing the hardness of water. The cation exchange resin can remove calcium ion and magnesium ion which are hardness components of water as shown in the following reaction formula.
【0004】 2R−SO3 H +Ca2+ →(R−SO3 )2 Ca
+2H+ 2R−SO3 H +Mg2+ →(R−SO3 )2 Mg
+2H+ しかし、上の反応式に示す如く水の硬度成分であるカル
シウムイオンおよびマグネシウムイオンが、イオン交換
基の水素イオンと置換すると陽イオン交換樹脂は、水の
硬度を低下させる機能を失う。そこで、陽イオン交換の
活性を失った陽イオン交換樹脂のカルシウムイオンとマ
グネシウムイオンを水素イオンに置き換える、陽イオン
交換樹脂の再生が必要である。2R-SO 3 H + Ca 2+ → (R-SO 3 ) 2 Ca
+ 2H + 2R-SO 3 H + Mg 2+ → (R-SO 3) 2 Mg
+ 2H + However, as shown in the above reaction formula, when calcium ions and magnesium ions, which are hardness components of water, are replaced with hydrogen ions of ion exchange groups, the cation exchange resin loses the function of lowering the hardness of water. Therefore, it is necessary to regenerate the cation exchange resin by replacing the calcium ion and magnesium ion of the cation exchange resin having lost the cation exchange activity with hydrogen ion.
【0005】ところで、上記の陽イオン交換樹脂の再生
機構を有する軟水器としては、 硫酸、塩酸などの酸を陽イオン交換樹脂に流すもの、 硫酸、塩酸などの酸を流した状態で電気分解するも
の、 等が知られている。By the way, as the water softener having the above-mentioned cation-exchange resin regeneration mechanism, an acid such as sulfuric acid or hydrochloric acid is passed through the cation-exchange resin, or electrolysis is carried out in the state where an acid such as sulfuric acid or hydrochloric acid is passed. Things, etc. are known.
【0006】しかし、上記のような再生機構を有する軟
水器は、硫酸、塩酸などの酸の添加が必要となり、硫
酸、塩酸などの酸の使用に際して安全面および排水処理
面に問題があり、例えば家庭等における利用には実用的
でない。However, the water softener having the above-mentioned regeneration mechanism requires the addition of acids such as sulfuric acid and hydrochloric acid, and there are problems in safety and wastewater treatment when using acids such as sulfuric acid and hydrochloric acid. It is not practical for home use.
【0007】[0007]
【発明が解決しようとする課題】したがって、本発明の
課題は、硫酸、塩酸などの酸の添加が不要で、陽イオン
交換樹脂を容易に再生でき、簡単且つ安全に利用できる
実用性の高い再生機能を有する軟水器を提供する点にあ
る。SUMMARY OF THE INVENTION Therefore, the object of the present invention is to regenerate a cation exchange resin easily without adding acid such as sulfuric acid and hydrochloric acid, and to recycle the cation exchange resin with high practicality. The point is to provide a water softener having a function.
【0008】[0008]
【課題を解決するための手段】本発明の再生機能を有す
る軟水器は、(1)電気分解器1と軟水器2から構成さ
れた、水の硬度を低下させる軟水器であって、(2)上
記電気分解器1は電気分解槽16を備え、(3)上記電
気分解槽16内には陽極3と陰極4の間に隔膜5を備
え、(4)上記隔膜5を境にして陽極3側を酸性水槽6
とし、(5)上記隔膜5を境にして陰極4側をアルカリ
性水槽7とし、(6)上記軟水器2は軟水槽17とこの
軟水槽17に内蔵された陽イオン交換樹脂11とから構
成され、さらに、(7)上記酸性水槽6と軟水槽17が
連通されていることを特徴とする。A water softener having a regenerating function of the present invention is (1) a water softener which comprises an electrolyzer 1 and a water softener 2 and which lowers the hardness of water. ) The electrolyzer 1 is provided with an electrolysis tank 16, (3) a diaphragm 5 is provided between the anode 3 and the cathode 4 in the electrolysis tank 16, and (4) the anode 3 with the diaphragm 5 as a boundary. Side of acidic water tank 6
(5) The cathode 4 side is an alkaline water tank 7 with the diaphragm 5 as a boundary, and (6) the water softener 2 is composed of a water softener 17 and a cation exchange resin 11 contained in the water softener 17. Further, (7) the acidic water tank 6 and the soft water tank 17 are communicated with each other.
【0009】[0009]
【作用】本発明の再生機能を有する軟水器を構成する電
気分解器1において、水を電気分解した際に次の反応が
起こる。In the electrolyzer 1 constituting the water softener having the regeneration function of the present invention, the following reaction occurs when water is electrolyzed.
【0010】 陽極3では、 2OH- →2H+ +4e- +O2 ↑ 陰極4では、 2H+ +2e- → H2 ↑ 陽極3側では、水素イオンが発生するため酸性水が生成
される。陰極4側では、水素イオン濃度が減少するので
アルカリ性水が生成される。At the anode 3, 2OH − → 2H + + 4e − + O 2 ↑ At the cathode 4, 2H + + 2e − → H 2 ↑ At the anode 3 side, hydrogen ions are generated, so that acidic water is generated. On the cathode 4 side, the hydrogen ion concentration decreases, so alkaline water is generated.
【0011】陽極3と陰極4の間に隔膜5を備えるの
で、電気分解によって発生した、上記酸性水とアルカリ
性水が隔膜5で分離され、上記隔膜5を境にして陽極3
側の酸性水槽6に酸性水が生成し、また、上記隔膜5を
境にして陰極4側のアルカリ性水槽7にアルカリ性水が
生成する。Since the diaphragm 5 is provided between the anode 3 and the cathode 4, the acidic water and alkaline water generated by electrolysis are separated by the diaphragm 5, and the anode 5 is separated by the diaphragm 5 as a boundary.
Acidic water is generated in the acidic water tank 6 on the side, and alkaline water is generated in the alkaline water tank 7 on the side of the cathode 4 with the diaphragm 5 as a boundary.
【0012】軟水器2は軟水槽17に陽イオン交換樹脂
11が内蔵されており、酸性水槽6と軟水槽17が連通
されているので、電気分解によって発生した酸性水をイ
オン交換基の活性を失った陽イオン交換樹脂11を内蔵
する軟水槽17に通すと、軟水槽17に内蔵された陽イ
オン交換樹脂11が陽イオン交換の活性をとりもどし、
陽イオン交換樹脂11の再生をすることができる。下の
反応式は、スルホン基を有する陽イオン交換樹脂11を
一例として、示したものである。In the water softener 2, the cation exchange resin 11 is built in the soft water tank 17, and the acidic water tank 6 and the soft water tank 17 are connected to each other, so that the acidic water generated by electrolysis can be activated by the ion exchange group. When the lost cation exchange resin 11 is passed through the soft water tank 17 containing the cation exchange resin 11, the cation exchange resin 11 contained in the soft water tank 17 restores the cation exchange activity,
The cation exchange resin 11 can be regenerated. The reaction formula below shows the cation exchange resin 11 having a sulfone group as an example.
【0013】 (R−SO3 )2 Ca +2H+ →2R−SO3 H +
Ca2+ (R−SO3 )2 Mg +2H+ →2R−SO3 H +
Mg2+ (R-SO 3 ) 2 Ca + 2H + → 2R-SO 3 H +
Ca 2+ (R-SO 3 ) 2 Mg + 2H + → 2R-SO 3 H +
Mg 2+
【0014】[0014]
【実施例】以下、本発明を実施例に係る図面に基づいて
詳しく説明する。DESCRIPTION OF THE PREFERRED EMBODIMENTS The present invention will be described in detail below with reference to the drawings according to the embodiments.
【0015】図1は本発明の一実施例に係る再生機能を
有する軟水器の断面図である。本発明の再生機能を有す
る軟水器は、電気分解器1を備える。この電気分解器1
は電気分解槽16の内部に形成された陽極3と陰極4、
この陽極3と陰極4の間に設けられた隔膜5、隔膜5を
境にして陽極3側の酸性水槽6、および、隔膜5を境に
して陰極4側のアルカリ性水槽7とで構成する。ここ
で、電気分解槽16は円筒型でも角型でもよい。電気分
解槽16の下部側面には開閉自在な電磁弁12を備えた
配水管9が設けられている。また、電気分解槽16の上
部には給水管8を備えている。FIG. 1 is a sectional view of a water softener having a regeneration function according to an embodiment of the present invention. A water softener having a regeneration function of the present invention includes an electrolyzer 1. This electrolyzer 1
Is an anode 3 and a cathode 4 formed inside the electrolysis tank 16,
It comprises a diaphragm 5 provided between the anode 3 and the cathode 4, an acidic water tank 6 on the anode 3 side with the diaphragm 5 as a boundary, and an alkaline water tank 7 on the cathode 4 side with the diaphragm 5 as a boundary. Here, the electrolysis tank 16 may be cylindrical or rectangular. A water pipe 9 having a solenoid valve 12 that can be opened and closed is provided on the lower side surface of the electrolysis tank 16. Further, a water supply pipe 8 is provided above the electrolysis tank 16.
【0016】本発明の再生機能を有する軟水器は、さら
に電気分解槽16の下部底面に接続された供給管10を
介して軟水槽17を備えている。この軟水器2は軟水槽
17と軟水槽17に内蔵された陽イオン交換樹脂11か
らなる。この陽イオン交換樹脂11としては、例えば、
スルホン基を持つ強酸性型のイオン交換樹脂であれば、
酸性水である限り、水のpHの大小にかかわらず再生で
きるので好ましい。The water softener having a regeneration function of the present invention further includes a water softener 17 via a supply pipe 10 connected to the lower bottom surface of the electrolysis tank 16. The water softener 2 comprises a soft water tank 17 and a cation exchange resin 11 contained in the soft water tank 17. As the cation exchange resin 11, for example,
If it is a strong acid type ion exchange resin having a sulfone group,
Acidic water is preferable because it can be regenerated regardless of the pH of the water.
【0017】また、上記軟水槽17の下部底面には、三
方弁13を備えた出水管14と排水管15が設けられて
いる。上記出水管14と排水管15は三方弁13の所で
分かれている。A water outlet pipe 14 having a three-way valve 13 and a drain pipe 15 are provided on the bottom bottom surface of the soft water tank 17. The water pipe 14 and the drain pipe 15 are separated at the three-way valve 13.
【0018】硬水を軟水化するとき、硬度処理の必要な
水は、電気分解槽16の上部の給水管8、電気分解槽1
6の酸性水槽6、電気分解槽16の下部底面の軟水槽1
7に通じる供給管10を通って、軟水槽17の内部に入
る。軟水槽17の内部の陽イオン交換樹脂11と水とが
接触して、水中のカルシウムイオンとマグネシウムイオ
ンが除去され、水の硬度が低下され、三方弁13を通
り、三方弁13を備えた出水管14より、軟水として供
給される。なお、このとき水の電気分解を起こす必要は
ないので、電気分解槽16の内部の陽極3と陰極4には
電圧は印加せず、電磁弁12は閉じた状態にある。When softening hard water, the water that needs hardness treatment is supplied to the water supply pipe 8 above the electrolysis tank 16 and the electrolysis tank 1.
6, the acidic water tank 6 and the electrolysis tank 16 at the bottom bottom of the soft water tank 1
It enters into the inside of the soft water tank 17 through the supply pipe 10 leading to 7. The cation exchange resin 11 inside the soft water tank 17 comes into contact with water to remove calcium ions and magnesium ions in the water, the hardness of the water is lowered, the water passes through the three-way valve 13, and the three-way valve 13 is provided. It is supplied as soft water from the water pipe 14. At this time, since it is not necessary to electrolyze water, no voltage is applied to the anode 3 and the cathode 4 inside the electrolysis tank 16, and the solenoid valve 12 is in a closed state.
【0019】軟水槽17の内部の陽イオン交換の活性を
失った陽イオン交換樹脂11の再生するとき、陽極3と
陰極4に電圧を印加し、給水管8より電気分解槽16中
の水を電気分解し、酸性水とアルカリ性水を生成する。
軟水槽17の内部の陽イオン交換樹脂11の再生に必要
となる、生成した酸性水は、酸性水槽6を出て、電気分
解槽16の下部の供給管10を通り抜け、軟水槽17に
入り、陽イオン交換樹脂11の再生をする。再生終了後
の排水は、三方弁13の所で出水管14を通らず、排水
管15から捨てられる。再生に不要なアルカリ性水は、
開閉自在な電磁弁12を備えた配水管9から排出され
る。When the cation exchange resin 11 that has lost the cation exchange activity inside the soft water tank 17 is regenerated, a voltage is applied to the anode 3 and the cathode 4, and the water in the electrolysis tank 16 is removed from the water supply pipe 8. Electrolyzes to produce acidic water and alkaline water.
The generated acidic water required for regeneration of the cation exchange resin 11 inside the soft water tank 17 exits the acidic water tank 6, passes through the supply pipe 10 below the electrolysis tank 16, and enters the soft water tank 17. The cation exchange resin 11 is regenerated. The drainage after completion of regeneration does not pass through the water discharge pipe 14 at the three-way valve 13 and is discharged from the drainage pipe 15. Alkaline water that is unnecessary for regeneration,
It is discharged from a water pipe 9 equipped with a solenoid valve 12 that can be opened and closed.
【0020】[0020]
【発明の効果】本発明の再生機能を有する軟水器による
と、軟水器は軟水槽に陽イオン交換樹脂が内蔵され、酸
性水槽と軟水槽が連通されているので、電気分解によっ
て発生した酸性水を陽イオン交換の活性を失った陽イオ
ン交換樹脂を内蔵する軟水槽に通すと、陽イオン交換の
活性を取戻し、陽イオン交換樹脂を容易に再生をするこ
とができ、硫酸、塩酸などの酸の添加が不要で、簡単且
つ安全に利用でき、特に家庭用として、実用的である。According to the water softener having a regenerating function of the present invention, the water softener has a cation exchange resin built in the soft water tank, and the acidic water tank and the soft water tank are in communication with each other. When the cation exchange resin is passed through a soft water tank containing a cation exchange resin that has lost cation exchange activity, the cation exchange activity can be restored and the cation exchange resin can be easily regenerated. It is simple and safe to use, and is practical, especially for household use.
【図1】本発明の実施例に係る再生機能を有する軟水器
の断面図である。FIG. 1 is a sectional view of a water softener having a regeneration function according to an embodiment of the present invention.
1 電気分解器 2 軟水器 3 陽極 4 陰極 5 隔膜 6 酸性水槽 7 アルカリ性水槽 8 給水管 9 配水管 10 供給管 11 陽イオン交換樹脂 12 電磁弁 13 三方弁 14 出水管 15 排水管 16 電気分解槽 17 軟水槽 DESCRIPTION OF SYMBOLS 1 Electrolyzer 2 Water softener 3 Anode 4 Cathode 5 Diaphragm 6 Acidic water tank 7 Alkaline water tank 8 Water supply pipe 9 Water distribution pipe 10 Supply pipe 11 Cation exchange resin 12 Solenoid valve 13 Three-way valve 14 Water discharge pipe 15 Drainage pipe 16 Electrolysis tank 17 Soft water tank
─────────────────────────────────────────────────────
─────────────────────────────────────────────────── ───
【手続補正書】[Procedure amendment]
【提出日】平成4年9月2日[Submission date] September 2, 1992
【手続補正1】[Procedure Amendment 1]
【補正対象書類名】明細書[Document name to be amended] Statement
【補正対象項目名】請求項2[Name of item to be corrected] Claim 2
【補正方法】変更[Correction method] Change
【補正内容】[Correction content]
【手続補正2】[Procedure Amendment 2]
【補正対象書類名】明細書[Document name to be amended] Statement
【補正対象項目名】0001[Correction target item name] 0001
【補正方法】変更[Correction method] Change
【補正内容】[Correction content]
【0001】本発明は、軟水槽に陽イオン交換樹脂を内
蔵して、水の硬度を低下させる、再生機能を有する軟水
器に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a water softener having a regeneration function, which contains a cation exchange resin in a soft water tank to reduce the hardness of water.
【手続補正3】[Procedure 3]
【補正対象書類名】明細書[Document name to be amended] Statement
【補正対象項目名】0002[Name of item to be corrected] 0002
【補正方法】変更[Correction method] Change
【補正内容】[Correction content]
【0002】水の硬度を低下させるため、一般に陽イオ
ン交換樹脂が用いられている。陽イオン交換樹脂は、ス
チレンとジビニルベンゼンの共重合物の如く水に不溶性
の高分子に、イオン交換基としてスルホン基、カルボキ
シル基、ホスホン基、アルソン基、フェノール性水酸基
などが結合した樹脂である。In order to reduce the hardness of water, it is common to use
Resin is used. The cation exchange resin is a resin in which a sulfone group, a carboxyl group, a phosphone group, an arsone group, a phenolic hydroxyl group or the like is bonded as an ion exchange group to a water-insoluble polymer such as a copolymer of styrene and divinylbenzene. .
【手続補正4】[Procedure amendment 4]
【補正対象書類名】明細書[Document name to be amended] Statement
【補正対象項目名】0016[Correction target item name] 0016
【補正方法】変更[Correction method] Change
【補正内容】[Correction content]
【0016】本発明の再生機能を有する軟水器は、さら
に電気分解槽16の下部底面に接続された供給管10を
介して軟水器2を備えている。この軟水器2は軟水槽1
7と軟水槽17に内蔵された陽イオン交換樹脂11から
なる。この陽イオン交換樹脂11としては、例えば、ス
ルホン基を持つ強酸型のイオン交換樹脂であれば、酸性
水である限り、水のpHの大小にかかわらず再生できる
ので好ましい。The water softener having a regenerating function of the present invention further includes a water softener 2 via a supply pipe 10 connected to the lower bottom surface of the electrolysis tank 16. This water softener 2 is a soft water tank 1
7 and a cation exchange resin 11 contained in a soft water tank 17. As the cation exchange resin 11, for example, a strong acid type ion exchange resin having a sulfone group is preferable as long as it is acidic water, it can be regenerated regardless of the pH of the water.
Claims (2)
れた、水の硬度を低下させる軟水器であって、(2)上
記電気分解器1は電気分解槽16を備え、(3)上記電
気分解槽16内には陽極3と陰極4の間に隔膜5を備
え、(4)上記隔膜5を境にして陽極3側を酸性水槽6
とし、(5)上記隔膜5を境にして陰極4側をアルカリ
性水槽7とし、(6)上記軟水器2は軟水槽17とこの
軟水槽17に内蔵された陽イオン交換樹脂11とから構
成され、さらに、(7)上記酸性水槽6と軟水槽17が
連通されていることを特徴とする再生機能を有する軟水
器。(1) A water softener for reducing the hardness of water, which comprises an electrolyzer 1 and a water softener 2. (2) The electrolyzer 1 comprises an electrolyzer tank 16; 3) The electrolysis tank 16 is provided with a diaphragm 5 between the anode 3 and the cathode 4, and (4) with the diaphragm 5 as a boundary, the side of the anode 3 is an acidic water tank 6
(5) The cathode 4 side is an alkaline water tank 7 with the diaphragm 5 as a boundary, and (6) the water softener 2 is composed of a water softener 17 and a cation exchange resin 11 contained in the water softener 17. Further, (7) a water softener having a regeneration function, characterized in that the acidic water tank 6 and the soft water tank 17 are communicated with each other.
型のイオン交換樹脂であることを特徴とする請求項1記
載の再生機能を有する軟水器。2. A water softener having a regeneration function according to claim 1, wherein (1) the cation exchange resin 11 is a strongly acidic ion exchange resin.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP19936592A JPH0639374A (en) | 1992-07-27 | 1992-07-27 | Water softening apparatus having regenerating function |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP19936592A JPH0639374A (en) | 1992-07-27 | 1992-07-27 | Water softening apparatus having regenerating function |
Publications (1)
Publication Number | Publication Date |
---|---|
JPH0639374A true JPH0639374A (en) | 1994-02-15 |
Family
ID=16406548
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP19936592A Pending JPH0639374A (en) | 1992-07-27 | 1992-07-27 | Water softening apparatus having regenerating function |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH0639374A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR101277126B1 (en) * | 2010-05-10 | 2013-06-20 | 미우라고교 가부시키카이샤 | Method for operating ion exchange equipment and ion exchange equipment |
-
1992
- 1992-07-27 JP JP19936592A patent/JPH0639374A/en active Pending
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR101277126B1 (en) * | 2010-05-10 | 2013-06-20 | 미우라고교 가부시키카이샤 | Method for operating ion exchange equipment and ion exchange equipment |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US5965009A (en) | Method of producing acid water and electrolytic cell therefor | |
US4294697A (en) | Apparatus for treatment of sewage | |
US6773575B2 (en) | Electrolytic cell and process for the production of hydrogen peroxide solution and hypochlorous acid | |
US5439564A (en) | Method of processing organic quaternary ammonium hydroxide-containing waste liquid | |
KR960014414A (en) | Electrolyzed Water Manufacturing Equipment | |
WO2020228638A1 (en) | Method for efficiently regenerating resin by using electrolytic salt solution | |
WO2015165234A1 (en) | Method for decontamination treatment and utilization as resource of ion exchange resin desorption solution | |
US4483754A (en) | Electrolysis of sodium chloride with the use of ion exchange membranes | |
WO2003037802A1 (en) | A water purifier using electrolysis | |
CN107298490B (en) | Electrochemical reactor, method for removing chloride ions in wastewater through electric flocculation, precipitated product and application | |
WO1991013834A1 (en) | Method and apparatus for treatment of liquid photographic pr ocessing wastes | |
JPH0639374A (en) | Water softening apparatus having regenerating function | |
CN100413593C (en) | Process for regenerating of in-situ electricity of adsorption resin | |
JPH06142649A (en) | Treatment of organic quaternary ammonium hydroxide-containing waste liquid | |
JPH07256297A (en) | Purification treatment of livestock excretion | |
JPH0558601A (en) | Method for regenerating sulfuric acid salt | |
JP2001192875A (en) | Method and apparatus for preparing hydrogen peroxide | |
JP3122026B2 (en) | Electrolytic water generation method and apparatus | |
JP2003117554A (en) | Cleaning water producing apparatus | |
CN114920398B (en) | High-salt ammonia nitrogen wastewater treatment device and treatment method | |
SU1723047A1 (en) | Method of cleaning sewage from dissolved impurities | |
JP2001276631A (en) | Device for regenerating ion exchange resin | |
JPH09108677A (en) | Electrolytic water generator | |
JP2007105707A (en) | Method of removing phosphorus in water by crystallization, and device therefor | |
JPH0691260A (en) | Water softening device for steam generating apparatus |