JPH0633746A - Electric heating catalytic device - Google Patents

Electric heating catalytic device

Info

Publication number
JPH0633746A
JPH0633746A JP18931392A JP18931392A JPH0633746A JP H0633746 A JPH0633746 A JP H0633746A JP 18931392 A JP18931392 A JP 18931392A JP 18931392 A JP18931392 A JP 18931392A JP H0633746 A JPH0633746 A JP H0633746A
Authority
JP
Japan
Prior art keywords
catalyst
foil
electric heating
electrically heated
exhaust passage
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP18931392A
Other languages
Japanese (ja)
Inventor
Toyoaki Fukui
豊明 福井
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Motors Corp
Original Assignee
Mitsubishi Motors Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Motors Corp filed Critical Mitsubishi Motors Corp
Priority to JP18931392A priority Critical patent/JPH0633746A/en
Publication of JPH0633746A publication Critical patent/JPH0633746A/en
Pending legal-status Critical Current

Links

Abstract

PURPOSE:To favorably purify a harmful substance in exhaust gas to be changed to a harmless substance by efficiently activating an electric heating catalyst. CONSTITUTION:An electric heating catalytic device 20 has spiral foil 24 provided in an exhaust passage of an engine to generate heat by a supplied current and a catalyst 25 mounted on the foil 24 to be activated. Here by forming a plate thickness of the foil 24 in the central part thinner than in the external side part and by increasing a resistance value per unit length of the supplied current in the foil 24 larger as it advances to a central part of the catalyst 25, so as to increase a heating value supplied to the catalyst 25, exhaust gas from the exhaust passage is purified.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は、エンジンの排気通路に
設けられ、電気加熱触媒を活性化させる電気加熱触媒装
置に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an electrically heated catalyst device provided in an exhaust passage of an engine to activate an electrically heated catalyst.

【0002】[0002]

【従来の技術】従来、エンジン始動直後に排出される有
害物質を低減する目的で、上記始動直後に触媒を急速に
加熱する電気加熱触媒装置が研究されている。このよう
な電気加熱触媒装置10は、例えば図5に示すように、
エンジン11の燃焼室12とマフラー14との間に介在
する排気通路13の中間に装備されており、発熱体であ
る担体15に、オン状態のスイッチ16を介してバッテ
リ電源17から電圧を印加し、上記担体15を急速に加
熱し、担体15に装着された電気加熱触媒を活性化させ
て、燃焼室11から排出される排気ガス中のCO(一酸
化炭素)やHC(炭化水素)等の有害物質を除去してい
た。
2. Description of the Related Art Conventionally, an electrically heated catalyst device has been studied which rapidly heats a catalyst immediately after the engine is started in order to reduce harmful substances emitted immediately after the engine is started. Such an electrically heated catalyst device 10 is, for example, as shown in FIG.
It is provided in the middle of the exhaust passage 13 interposed between the combustion chamber 12 of the engine 11 and the muffler 14, and a voltage is applied from a battery power source 17 to a carrier 15 which is a heating element via a switch 16 in an ON state. The carrier 15 is rapidly heated to activate the electrically heated catalyst mounted on the carrier 15 to remove CO (carbon monoxide), HC (hydrocarbons), etc. in the exhaust gas discharged from the combustion chamber 11. Had removed harmful substances.

【0003】[0003]

【発明が解決しようとする課題】ところが、上記電気加
熱触媒装置は、基本的には均一の抵抗体であり、電流に
よって均一に加熱されるが、外周部では、発生した熱が
大気へ奪われてしまい、触媒に供給するための熱量が有
効に活用されないという問題点があった。本発明は、上
記問題点に鑑みなされたもので、電気加熱触媒を効率よ
く活性化することができる電気加熱触媒装置を提供する
ことを目的とする。
However, the above-mentioned electrically heated catalyst device is basically a uniform resistor and is uniformly heated by an electric current, but the heat generated in the outer peripheral portion is taken to the atmosphere. As a result, the amount of heat supplied to the catalyst is not effectively used. The present invention has been made in view of the above problems, and an object of the present invention is to provide an electrically heated catalyst device that can efficiently activate an electrically heated catalyst.

【0004】[0004]

【課題を解決するための手段】上記目的を達成するた
め、本発明では、エンジンの排気通路に設けられるとと
もに、供給される電流によって発熱する発熱体と、該発
熱体に装着され、かつ、加熱によって活性化される電気
加熱触媒とを有し、当該電気加熱触媒によって前記排気
通路からの排気を浄化する電気加熱触媒装置において、
前記発熱体における供給電流の単位長さ当たりの抵抗値
を前記電気加熱触媒の中央部ほど大きくして、前記電気
加熱触媒に供給する熱量を高くする電気加熱触媒装置が
提供される。
In order to achieve the above object, according to the present invention, there is provided a heating element which is provided in an exhaust passage of an engine and which generates heat by a supplied current, and a heating element which is mounted on the heating element and which is heated. An electrically heated catalyst that is activated by, and an electrically heated catalyst device that purifies exhaust gas from the exhaust passage by the electrically heated catalyst,
There is provided an electrically heated catalyst device in which the resistance value of the supply current in the heating element per unit length is increased toward the central portion of the electrically heated catalyst to increase the amount of heat supplied to the electrically heated catalyst.

【0005】[0005]

【作用】例えば、発熱体に渦巻きフォイルを用いたハネ
カム型の電気加熱触媒装置においては、上記フォイルの
板厚を外側部より中央部で薄くし、発熱体における電気
加熱触媒の中央部の抵抗値を大きくすることによって、
発熱体の発熱を中央部で大きくし、その熱量を電気加熱
触媒に供給する。
For example, in a honeycomb type electric heating catalyst device using a spiral foil as a heating element, the thickness of the foil is made thinner in the central portion than in the outer portion, and the resistance value of the central portion of the electric heating catalyst in the heating element is reduced. By increasing
The heat generated by the heating element is increased at the central portion, and the amount of heat is supplied to the electrically heated catalyst.

【0006】従って、外周への熱損失を防止でき、電気
加熱触媒は良好に加熱されて排気ガスの浄化を良好に行
うことができる。
Therefore, heat loss to the outer circumference can be prevented, and the electrically heated catalyst can be favorably heated, and the exhaust gas can be favorably purified.

【0007】[0007]

【実施例】本発明の実施例を図1乃至図4の図面に基づ
き説明する。なお、以下に示す実施例では、発熱体に渦
巻きフォイルを用いたハネカム型の電気加熱触媒装置に
ついて説明する。図1は、本発明に係る電気加熱触媒装
置の一実施例を示す上面図である。図において、電気加
熱触媒装置20は、コーディライトや耐熱合金からなる
基体21と、図示しないバッテリ電源に接続され、装置
の中央部に設けられた中心電極22及び外側に設けられ
た外側電極23と、上記中心電極22に所定間隔で取り
付けられて基体21内に配設され、上記電極22,23
から供給される電流によって発熱する渦巻きフォイル2
4と、上記渦巻きフォイル24に装着される触媒25
と、上記基体21に内設される断熱材26とから構成さ
れている。
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS An embodiment of the present invention will be described with reference to the drawings of FIGS. In the following examples, a honeycomb type electrically heated catalyst device using a spiral foil as a heating element will be described. FIG. 1 is a top view showing an embodiment of the electrically heated catalyst device according to the present invention. In the figure, an electrically heated catalyst device 20 includes a substrate 21 made of cordierite or a heat-resistant alloy, a central electrode 22 provided in the central portion of the device and an outer electrode 23 provided outside, connected to a battery power source (not shown). , The electrodes 22 and 23 are attached to the center electrode 22 at predetermined intervals and disposed in the base 21.
Spiral foil 2 which is heated by the electric current supplied from the
4 and a catalyst 25 mounted on the spiral foil 24
And a heat insulating material 26 provided inside the base 21.

【0008】図2は、図1に示した渦巻きフォイルの一
実施例を示す斜視図である。図において、渦巻きフォイ
ル24は、板厚tが外側部より中心電極22側の中央部
で薄く構成されている。上記フォイル24は、一種の抵
抗体であり、中央部に近づくに従って、その板厚が薄く
なれば、上記フォイル24における電流経路の単位長さ
当たりの抵抗値は、上記中央部ほど大きくなる。これに
伴い、フォイル24は、バッテリ電源から供給される電
流に対して発熱し、渦が中央部に近づくほどその発熱が
大きくなる。すなわち、電気加熱触媒装置20を、図5
に示すバッテリ電源17に接続させた場合の等価回路を
図3に示すと、電気加熱触媒装置20は直列接続の抵抗
1 〜Rn と等価になり、上記抵抗R1 〜Rn がスイッ
チ16を介して、電圧Eのバッテリ電源17に接続され
て現すことができる。なお、nは、任意の整数である。
FIG. 2 is a perspective view showing an embodiment of the spiral foil shown in FIG. In the figure, the spiral foil 24 has a plate thickness t that is thinner in the central portion on the side of the center electrode 22 than in the outer portion. The foil 24 is a kind of resistor, and the resistance value per unit length of the current path in the foil 24 becomes larger toward the central portion as the plate thickness becomes thinner toward the central portion. Along with this, the foil 24 generates heat with respect to the current supplied from the battery power source, and the heat generation increases as the vortex approaches the central portion. That is, the electrically heated catalyst device 20 is shown in FIG.
3 shows an equivalent circuit when connected to the battery power source 17 shown in FIG. 3, the electric heating catalyst device 20 becomes equivalent to the series-connected resistors R 1 to R n, and the resistors R 1 to R n are connected to the switch 16. Connected to the battery power source 17 of voltage E via Note that n is an arbitrary integer.

【0009】ここで、電気加熱触媒装置20に供給され
る電流Iを求めると、
Here, when the electric current I supplied to the electrically heated catalyst device 20 is obtained,

【0010】[0010]

【数1】 [Equation 1]

【0011】ここで、Ri :局所抵抗 となり、上記式(1) を代入して総発電量Wを求めると、Here, R i is the local resistance, and when the above equation (1) is substituted to obtain the total power generation amount W,

【0012】[0012]

【数2】 [Equation 2]

【0013】となり、局所的な発熱量Wi は、Therefore, the local heat generation amount W i is

【0014】[0014]

【数3】 [Equation 3]

【0015】となる。よって、上記式から局所的な発熱
量は、局所抵抗に比例することが判る。このことから判
るように、本実施例に示したフォイル24の板厚が薄く
なるほど、局所抵抗値は、大きくなって、電流供給時の
発熱量を高くすることができる。触媒25は、例えば白
金族金属に遷移アルミナ、促進剤や安定化剤からなるウ
ォッシュコートと呼ばれる薄い層を設けて構成される。
[0015] Therefore, it can be seen from the above equation that the local heat generation amount is proportional to the local resistance. As can be seen from this, the smaller the plate thickness of the foil 24 shown in this embodiment, the larger the local resistance value, and the higher the amount of heat generation during current supply. The catalyst 25 is formed by providing a thin layer called a washcoat made of transition alumina, a promoter and a stabilizer on a platinum group metal, for example.

【0016】従って、本実施例では、フォイル24の板
厚を中央部に近づくほど薄くするので、装置の中央部付
近のフォイル24の抵抗値が大きくなって、電流供給時
の熱量が高くなり、外周への熱損失を防止することがで
き、これにより電気加熱触媒25を効率よく加熱して活
性化することができて、図示しないエンジンの燃焼室か
ら排気通路に排出され、図1中、矢印方向に流れる排気
ガス中の有害物質を、無害物質に良好に浄化することが
可能になる。
Therefore, in this embodiment, since the thickness of the foil 24 is made thinner toward the central portion, the resistance value of the foil 24 near the central portion of the apparatus is increased and the heat quantity at the time of current supply is increased. It is possible to prevent heat loss to the outer periphery, which allows the electrically heated catalyst 25 to be efficiently heated and activated, and is discharged from the combustion chamber of the engine (not shown) to the exhaust passage. It becomes possible to satisfactorily purify harmful substances in the exhaust gas flowing in the direction into harmless substances.

【0017】図4は、図1に示した渦巻きフォイルの他
の実施例を示す斜視図である。図において、フォイル2
4は、板幅Lが外側部より中心電極22側の中央部で小
さく構成されている。これにより、上記フォイル24
は、図2の場合と同様、中央部に近づくに従って、上記
フォイル24における電流経路の単位長さ当たりの抵抗
値が大きくなるので、その発熱が大きくなる。
FIG. 4 is a perspective view showing another embodiment of the spiral foil shown in FIG. In the figure, foil 2
In No. 4, the plate width L is smaller in the central portion on the side of the central electrode 22 than in the outer portion. This allows the foil 24
As in the case of FIG. 2, the resistance value per unit length of the current path in the foil 24 increases as it approaches the central portion, so that heat generation increases.

【0018】従って、本実施例では、フォイル24の板
幅を中央部に近づくほど小さくするので、上記実施例と
同様、電流供給時の装置中央部付近の熱量が高くなり、
外周への熱損失を防止することができ、これにより電気
加熱触媒を効率よく加熱して活性化することができて、
図示しないエンジンの燃焼室から排気通路に排出された
排気ガス中の有害物質を、無害物質に良好に浄化するこ
とが可能になる。
Therefore, in this embodiment, since the plate width of the foil 24 is made smaller toward the central portion, the amount of heat in the vicinity of the central portion of the device at the time of current supply is increased, as in the above embodiment.
It is possible to prevent heat loss to the outer circumference, which enables efficient heating and activation of the electrically heated catalyst,
It is possible to satisfactorily purify harmful substances in the exhaust gas discharged from the combustion chamber of the engine (not shown) into the exhaust passage into harmless substances.

【0019】[0019]

【発明の効果】以上、説明したように、本発明では、エ
ンジンの排気通路に設けられるとともに、供給される電
流によって発熱する発熱体と、該発熱体に装着され、か
つ、加熱によって活性化する電気加熱触媒とを有し、当
該電気加熱触媒によって前記排気通路からの排気を浄化
する電気加熱触媒装置において、前記発熱体における供
給電流の単位長さ当たりの抵抗値を前記電気加熱触媒の
中央部ほど大きくして、前記電気加熱触媒に供給する熱
量を高くするので、電気加熱触媒を効率よく活性化する
ことができる。
As described above, according to the present invention, a heating element which is provided in the exhaust passage of the engine and which generates heat by the supplied electric current, and which is attached to the heating element and is activated by heating. In an electric heating catalyst device having an electric heating catalyst for purifying exhaust gas from the exhaust passage by the electric heating catalyst, a resistance value per unit length of a supply current in the heating element is set to a central portion of the electric heating catalyst. Since the amount of heat supplied to the electrically heated catalyst is increased by increasing the amount, the electrically heated catalyst can be efficiently activated.

【図面の簡単な説明】[Brief description of drawings]

【図1】本発明に係る電気加熱触媒装置の一実施例を示
す上面図である。
FIG. 1 is a top view showing an embodiment of an electrically heated catalyst device according to the present invention.

【図2】図1に示した渦巻きフォイルの一実施例を示す
斜視図である。
FIG. 2 is a perspective view showing an embodiment of the spiral foil shown in FIG.

【図3】図1に示した電気加熱触媒装置の等価回路を示
す図である。
3 is a diagram showing an equivalent circuit of the electrically heated catalyst device shown in FIG.

【図4】図1に示した渦巻きフォイルの他の実施例を示
す斜視図である。
FIG. 4 is a perspective view showing another embodiment of the spiral foil shown in FIG.

【図5】電気加熱触媒装置の取り付け状態を説明するた
めの図である。
FIG. 5 is a diagram for explaining a mounting state of the electrically heated catalyst device.

【符号の説明】[Explanation of symbols]

10,20 電気加熱触媒装置 11 エンジン 12 燃焼室 13 排気通路 15 担体 17 バッテリ電源 21 基体 22,23 電極 24 フォイル 25 触媒 26 断熱材 10, 20 Electric heating catalyst device 11 Engine 12 Combustion chamber 13 Exhaust passage 15 Carrier 17 Battery power source 21 Base 22,23 Electrode 24 Foil 25 Catalyst 26 Insulation material

Claims (1)

【特許請求の範囲】[Claims] 【請求項1】 エンジンの排気通路に設けられるととも
に、供給される電流によって発熱する発熱体と、該発熱
体に装着され、かつ、加熱によって活性化する電気加熱
触媒とを有し、当該電気加熱触媒によって前記排気通路
からの排気を浄化する電気加熱触媒装置において、前記
発熱体における供給電流の単位長さ当たりの抵抗値を前
記電気加熱触媒の中央部ほど大きくして、前記電気加熱
触媒に供給する熱量を高くすることを特徴とする電気加
熱触媒装置。
1. An electric heating apparatus, comprising: a heating element which is provided in an exhaust passage of an engine and which generates heat by an electric current supplied; and an electric heating catalyst which is mounted on the heating element and activated by heating. In an electric heating catalyst device for purifying exhaust gas from the exhaust passage by a catalyst, a resistance value per unit length of a supply current in the heating element is increased toward a central portion of the electric heating catalyst and is supplied to the electric heating catalyst. An electrically heated catalyst device characterized by increasing the amount of heat generated.
JP18931392A 1992-07-16 1992-07-16 Electric heating catalytic device Pending JPH0633746A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP18931392A JPH0633746A (en) 1992-07-16 1992-07-16 Electric heating catalytic device

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP18931392A JPH0633746A (en) 1992-07-16 1992-07-16 Electric heating catalytic device

Publications (1)

Publication Number Publication Date
JPH0633746A true JPH0633746A (en) 1994-02-08

Family

ID=16239267

Family Applications (1)

Application Number Title Priority Date Filing Date
JP18931392A Pending JPH0633746A (en) 1992-07-16 1992-07-16 Electric heating catalytic device

Country Status (1)

Country Link
JP (1) JPH0633746A (en)

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