JPH06330714A - Manufacture of heat resistance aluminum alloy made valve body - Google Patents

Manufacture of heat resistance aluminum alloy made valve body

Info

Publication number
JPH06330714A
JPH06330714A JP11985793A JP11985793A JPH06330714A JP H06330714 A JPH06330714 A JP H06330714A JP 11985793 A JP11985793 A JP 11985793A JP 11985793 A JP11985793 A JP 11985793A JP H06330714 A JPH06330714 A JP H06330714A
Authority
JP
Japan
Prior art keywords
valve body
aluminum alloy
heat
resistant aluminum
heat resistance
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP11985793A
Other languages
Japanese (ja)
Inventor
Kazuhisa Shibue
和久 渋江
Yoshimasa Okubo
喜正 大久保
Shinichi Tani
真一 谷
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sumitomo Light Metal Industries Ltd
Original Assignee
Sumitomo Light Metal Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sumitomo Light Metal Industries Ltd filed Critical Sumitomo Light Metal Industries Ltd
Priority to JP11985793A priority Critical patent/JPH06330714A/en
Publication of JPH06330714A publication Critical patent/JPH06330714A/en
Pending legal-status Critical Current

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Abstract

PURPOSE:To form a valve body without deteriorating strength of heat resistance aluminum alloy. CONSTITUTION:Rapid cooling coagulation powder of particle dispersion type heat resistance aluminum alloy having component of al-7, 7Fe-2, 5V-0, 5Mo-0 and 4Zr is manufactured, and it is push-formed so as to form a cylindrical push casting billet 15. The push casting billet 15 is arranged on the push plate 13 of a container 11 bottom part as shown in figure (a), and dies 17 on which a valve body mold 17a is formed are arranged. The dies 17 are pressed forcibly and pushed down by a punch 19 as shown in figure (b) so as to form a valve body (an intake valve) for an internal combustion engine having a shaft part 1a and an umbrella part 1b by a push casting method.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は、内燃機関の吸気弁に使
用される耐熱アルミニウム合金製弁体の製造方法に係わ
り、特に耐熱アルミニウム合金の強度を劣化させること
なく弁体を成形することのできる弁体の製造方法に関す
る。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for manufacturing a heat-resistant aluminum alloy valve body used for an intake valve of an internal combustion engine, and particularly to forming a valve body without deteriorating the strength of the heat-resistant aluminum alloy. The present invention relates to a method of manufacturing a valve body that can be used.

【0002】[0002]

【従来の技術】従来より、図3に示すように、内燃機関
に備えられる吸気弁P1及び排気弁P3は、各々軸部P
5及びかさ部P7を有し、周知のように燃焼ガスをシリ
ンダー室P9の中に規則正しく送り、そして排気させる
役目を果たすものである。
2. Description of the Related Art Conventionally, as shown in FIG. 3, an intake valve P1 and an exhaust valve P3 provided in an internal combustion engine each have a shaft portion P.
5 and a bulge portion P7, they serve to send the combustion gas regularly into the cylinder chamber P9 and exhaust it, as is well known.

【0003】現在のところ、この吸気弁P1及び排気弁
P3には、SUH3やSUH11などの鉄鋼材が主に用
いられており、その製造方法としては、鉄鋼材よりなる
小径棒の一端に、据込みによってかさ部を成形する工程
(up−set法)が主に用いられている。即ち、図4
(a)に示すように、小径棒P11の端部P13を加熱
しながら据込みパンチP15によって圧縮し、図4
(b)に示すように、その端部P13を押し広げてかさ
部P17を成形している。
At present, iron and steel materials such as SUH3 and SUH11 are mainly used for the intake valve P1 and the exhaust valve P3. A process (up-set method) of forming a bulky portion by embedding is mainly used. That is, FIG.
As shown in (a), the end P13 of the small diameter rod P11 is heated and compressed by the upsetting punch P15,
As shown in (b), the end portion P13 is pushed open to form the umbrella portion P17.

【0004】ところで、近頃では、内燃機関の出力、燃
費及び即応性の向上のために、吸・排気弁の小型化及び
軽量化が特に求められており、この内吸気弁について
は、その使用温度がおよそ300℃までと比較的低いの
で、耐熱アルミニウム合金による軽量化が検討されてい
る。この耐熱アルミニウム合金としては、例えば特公昭
63−10221号公報、特公昭63−10222号公
報あるいは特開平1−147037に開示されるよう
に、Fe,V,Mo,Zr,Ti,Crなどの金属を所
定量含んだ粒子分散型のアルミニウム合金を用いること
が試みられている。
By the way, recently, in order to improve the output, fuel efficiency and responsiveness of the internal combustion engine, it is particularly required to reduce the size and weight of the intake / exhaust valve. Is comparatively low up to about 300 ° C., so weight reduction using a heat-resistant aluminum alloy is being studied. Examples of the heat-resistant aluminum alloy include metals such as Fe, V, Mo, Zr, Ti, and Cr as disclosed in JP-B-63-10221, JP-B-63-10222, or JP-A-1-147037. It has been attempted to use a particle-dispersed aluminum alloy containing a predetermined amount of.

【0005】[0005]

【発明が解決しようとする課題】しかしながら、上述の
ような耐熱アルミニウム合金を用いて弁体を製造する場
合、上記従来の鉄鋼材に適用していたup−set法に
よって成形すると、高温加熱を必要とするので、かさ部
などに強度低下が生じてしまい、成形後の強度が弁体に
要求される強度より低くなってしまうという問題が生じ
る。
However, when a valve body is manufactured using the heat-resistant aluminum alloy as described above, high temperature heating is required if the valve body is molded by the up-set method applied to the conventional steel material. Therefore, there is a problem in that the strength is lowered in the bulky portion and the strength after molding becomes lower than the strength required for the valve body.

【0006】本発明は、前記課題を解決するためになさ
れ、耐熱アルミニウム合金の強度を劣化させることなく
弁体を成形することのできる耐熱アルミニウム合金製弁
体の製造方法を提供することを目的とする。
The present invention has been made to solve the above problems, and an object of the present invention is to provide a method for manufacturing a valve body made of a heat-resistant aluminum alloy, which can form the valve body without deteriorating the strength of the heat-resistant aluminum alloy. To do.

【0007】[0007]

【課題を解決するための手段】前記目的を達成するため
の請求項1の発明は、軸部及びかさ部を備え、内燃機関
の吸気弁に使用される耐熱アルミニウム合金製弁体の製
造方法であって、前記耐熱アルミニウム合金よりなり、
前記かさ部の外径と略等しい直径を有する棒材を製造し
た後、ダイスに形成された弁体型のかさ部側に前記棒材
を配置し、該棒材を加熱して押出鍛造することによっ
て、前記軸部及びかさ部を備える弁体を製造することを
特徴とする耐熱アルミニウム合金製弁体の製造方法を要
旨とする。
In order to achieve the above object, the invention of claim 1 is a method of manufacturing a valve body made of a heat-resistant aluminum alloy, which has a shaft portion and a bulk portion and is used for an intake valve of an internal combustion engine. It consists of the heat resistant aluminum alloy,
After manufacturing a bar material having a diameter substantially equal to the outer diameter of the bulge portion, the bar material is arranged on the bulge portion side of the valve body mold formed in a die, and the rod material is heated and extrusion-forged by A gist is a method for manufacturing a valve body made of a heat-resistant aluminum alloy, which is characterized in that a valve body having the shaft portion and the cap portion is manufactured.

【0008】ここで、前記耐熱アルミニウム合金として
は、特にその組成などに限定はないが、例えば特公昭6
3−10221号公報、特公昭63−10222号公報
あるいは特開平1−147037などに開示されるよう
に、Fe,V,Mo,Zr,Ti,Cr,Co,Ceな
どの中から選ばれた金属を所定量含んだ粒子分散型のア
ルミニウム合金を用いることができる。
The composition of the heat-resistant aluminum alloy is not particularly limited.
A metal selected from Fe, V, Mo, Zr, Ti, Cr, Co, Ce and the like, as disclosed in Japanese Patent Publication No. 3-10221, Japanese Patent Publication No. 63-10222, Japanese Patent Laid-Open No. 1-147037, and the like. A particle-dispersed aluminum alloy containing a predetermined amount of can be used.

【0009】前記棒材は、前記耐熱アルミニウム合金よ
り形成されるものである。より具体的には、例えば上述
の粒子分散型の耐熱アルミニウム合金の急冷凝固材をエ
アーアトマイズ法などによって製造し、これを押出など
の塑性加工によって棒状に成形して得ることができる。
また、この急冷凝固材を熱間等方圧プレス(HIP)や
冷間等方圧プレス(CIP)などの圧縮加工によって棒
状に成形して得ることもできる。更に、この急冷凝固材
を押出加工やプレス加工などによって一旦成形した後、
旋削などの他の加工を施すことによって前記棒材を得て
もよい。
The rod is made of the heat resistant aluminum alloy. More specifically, it can be obtained, for example, by manufacturing a rapidly solidified material of the above-mentioned particle dispersion type heat-resistant aluminum alloy by an air atomizing method or the like and molding it into a rod shape by plastic working such as extrusion.
It is also possible to obtain this rapidly solidified material by molding it into a rod shape by compression processing such as hot isostatic pressing (HIP) or cold isostatic pressing (CIP). Furthermore, after this rapidly solidified material is once molded by extrusion or pressing,
The bar may be obtained by performing other processing such as turning.

【0010】また、前記弁体型とは、ダイスの中に形成
された弁体の形状をした空間を指す。
The term "valve element type" refers to a space having the shape of a valve element formed in a die.

【0011】[0011]

【作用】前記請求項1の発明においては、まず、耐熱ア
ルミニウム合金よりなり、製造する弁体のかさ部の外径
と略等しい直径を有する棒材を製造する。そして、ダイ
スに形成された弁体型のかさ部側にこの棒材を配置し、
棒材を加熱して押出鍛造することにより、軸部及びかさ
部を備える弁体を製造する。
According to the first aspect of the present invention, first, a bar member made of a heat-resistant aluminum alloy and having a diameter substantially equal to the outer diameter of the bulk portion of the valve body to be manufactured is manufactured. Then, this bar is placed on the side of the valve body mold formed on the die,
The rod body is heated and extrusion-forged to manufacture a valve body having a shaft portion and a bulk portion.

【0012】このような押出鍛造によって弁体を製造す
れば、従来の据込みによる方法に比べて、弁体の成形の
際に(即ち押出鍛造の際に)耐熱アルミニウム合金を加
熱する温度を低く抑えることができ、従って合金の強度
を低下させることなく、弁体を製造することができる。
When the valve body is manufactured by such extrusion forging, the temperature for heating the heat-resistant aluminum alloy at the time of forming the valve body (that is, at the time of extrusion forging) is lowered as compared with the conventional upsetting method. The valve body can be manufactured without suppressing the strength of the alloy.

【0013】[0013]

【実施例】以下、本発明を具体化した実施例を、比較例
とともに説明する。 [実施例] (1)まず、粒子分散型の耐熱性高強度アルミ合金とし
て、Al−7.7Fe−2.5V−0.5Mo−0.4Zr
(Fe:7.7%,V:2.5%,Mo:0.5%,Z
r:0.4%を含み、残部はAlである)の成分を持つ
合金を溶製し、エアーアトマイズ法によって、平均粒径
60μmの急冷凝固粉末を製造した。
EXAMPLES Examples embodying the present invention will be described below together with comparative examples. [Examples] (1) First, as a particle-dispersed heat-resistant high-strength aluminum alloy, Al-7.7Fe-2.5V-0.5Mo-0.4Zr was used.
(Fe: 7.7%, V: 2.5%, Mo: 0.5%, Z
An alloy having a composition of r: 0.4% and the balance being Al) was melted, and a rapidly solidified powder having an average particle diameter of 60 μm was manufactured by an air atomizing method.

【0014】(2)この急冷凝固粉末を、直径95mm,
高さ300mmのアルミ容器に封入して、400℃にて真
空脱ガス処理の後、400℃にて容器とともに金型圧縮
して粉末を緻密化させた。そして、外部の容器を旋削し
て取り除き、内部の成形体(直径90mm、高さ150m
m)を得た。これを次の押出工程に用いる押出用ビレッ
トとした。
(2) The rapidly solidified powder was
After enclosing in an aluminum container having a height of 300 mm and performing vacuum degassing treatment at 400 ° C., the powder was densified by compressing the mold together with the container at 400 ° C. Then, the outer container is turned and removed, and the inner molded body (diameter 90 mm, height 150 m
m) got. This was used as an extrusion billet used in the next extrusion step.

【0015】(3)この押出用ビレットを400℃にて
間接押出して、直径30mm(押出比10)の押出棒を得
た。そして、これを長さ22mmに切断して、以下の押出
鍛造工程に用いる押出鍛造用ビレット(棒材)とした。 (4)この押出鍛造用ビレットを、380℃に加熱し、
以下に述べるように押出鍛造して、図1に示すような軸
部1a及びかさ部1bを有する弁体(吸気弁)1を作成
した。
(3) This extrusion billet was indirectly extruded at 400 ° C. to obtain an extrusion rod having a diameter of 30 mm (extrusion ratio 10). Then, this was cut into a length of 22 mm to obtain an extrusion forging billet (bar material) used in the following extrusion forging step. (4) This extrusion forging billet is heated to 380 ° C.,
Extrusion forging was performed as described below to prepare a valve body (intake valve) 1 having a shaft portion 1a and a bulge portion 1b as shown in FIG.

【0016】即ち、まず図2(a)に示すように、円筒
形のコンテナ11の下部の押板13の上に押出鍛造用ビ
レット15を配置し、その上に、弁体型17aが形成さ
れたダイス17を配置した。つまり、ダイス17の弁体
型17aのかさ部17b側に押出用ビレット15を配置
した。そして、図2(b)に示すように、パンチ19に
よってダイス17を強圧して押し下げ、軸部1aを押し
出すようにして弁体1を成形した。
That is, first, as shown in FIG. 2 (a), the extrusion forging billet 15 is arranged on the lower push plate 13 of the cylindrical container 11, and the valve body mold 17a is formed thereon. The die 17 was placed. That is, the extrusion billet 15 was arranged on the side of the bulb portion 17b of the valve body die 17a of the die 17. Then, as shown in FIG. 2 (b), the die 17 was strongly pressed and pushed down by the punch 19, and the shaft portion 1 a was pushed out to form the valve body 1.

【0017】次に、上述のようにして製造した弁体1の
強度を確認するために行った強度試験について説明す
る。まず、上述の工程(3)にて成形した押出棒につい
て、250℃にて引張試験を行った。その結果を下記表
1に示す。
Next, a strength test conducted to confirm the strength of the valve body 1 manufactured as described above will be described. First, a tensile test was performed at 250 ° C. on the extruded rod formed in the above step (3). The results are shown in Table 1 below.

【0018】次に、押出鍛造によって得られた弁体1に
ついて、軸部1aより引張試験片を作成し、上述の押出
棒の場合と同様に250℃にて引張試験を行うととも
に、軸部1及びかさ部3のロックウェル硬さを測定し
た。その結果を下記表1に示す。
Next, with respect to the valve body 1 obtained by extrusion forging, a tensile test piece is prepared from the shaft portion 1a, and a tensile test is carried out at 250 ° C. as in the case of the above-mentioned extruded rod, and the shaft portion 1 And the Rockwell hardness of the umbrella portion 3 was measured. The results are shown in Table 1 below.

【0019】[0019]

【表1】 [Table 1]

【0020】表1から明らかなように、実施例の製造方
法によって成形された弁体1は、耐力(0.2%の永久
伸びを生じる応力)、引張強さ、伸びのすべてにおいて
鍛造前の押出棒と同等な結果が得られており、押出鍛造
によって弁体に成形した後でも、十分な高温強度を保持
していることが判る。また、ロックウェル硬さについて
も、軸部及びかさ部の間に硬さの差が存在せず、非常に
好ましかった。
As is clear from Table 1, the valve body 1 molded by the manufacturing method of the example has the same yield strength (stress that causes permanent elongation of 0.2%), tensile strength and elongation before forging. The result is equivalent to that of the extruded rod, and it can be seen that the extruded rod retains sufficient high temperature strength even after being formed into a valve body by extrusion forging. Also, regarding Rockwell hardness, there was no difference in hardness between the shaft portion and the bulk portion, which was very preferable.

【0021】以上のように、本実施例の弁体の製造方法
によれば、耐熱アルミニウム合金の強度を劣化させるこ
となく、軸部及びかさ部を有する弁体に成形できるとい
う顕著な効果がある。 [比較例]次に、現行材(鉄鋼材)に用いられている据
込み(up−set法)によって、耐熱アルミニウム合
金製弁体を製造した比較例について説明する。
As described above, according to the method of manufacturing the valve body of this embodiment, there is a remarkable effect that the valve body having the shaft portion and the bulk portion can be formed without deteriorating the strength of the heat-resistant aluminum alloy. . [Comparative Example] Next, a comparative example in which a heat-resistant aluminum alloy valve body is manufactured by upsetting (up-set method) used for a current material (steel material) will be described.

【0022】まず、上述の実施例の工程(3)で得られ
た直径30mmの丸棒を削り出しによって直径8mmに加工
し、据込みによって、この棒材の一端にかさ部を成形す
ることを試みた。即ち、丸棒を成形金形内に配置し、電
極を介して丸棒の一端部に通電して、これによるジュー
ル熱で材料の一端を加熱した後、この一端部に荷重を加
えて据込むことにより、かさ部の成形を試みた。尚、加
熱温度は、350℃〜460℃まで変化させて行った。
First, the round bar having a diameter of 30 mm obtained in the step (3) of the above-mentioned embodiment is machined into a diameter of 8 mm by carving, and a cap portion is formed at one end of this bar material by upsetting. I tried. That is, a round bar is placed in a molding die, one end of the round bar is energized via an electrode, and one end of the material is heated by Joule heat by this, and then a load is applied to the one end to set it up. By doing so, an attempt was made to form the bulky portion. The heating temperature was changed from 350 ° C to 460 ° C.

【0023】その結果、材料の加熱温度が350℃〜4
50℃の場合、据込み中にかさ部の張り出し部に割れが
生じ、成形が不可能であった。一方、材料の加熱温度が
460℃の場合、かさ部に割れを生じることなく据込み
が可能であった。
As a result, the heating temperature of the material is 350 ° C.-4.
In the case of 50 ° C, cracking occurred in the overhanging portion of the bulky portion during upsetting, and molding was impossible. On the other hand, when the heating temperature of the material was 460 ° C., upsetting was possible without causing cracks in the bulk.

【0024】そして、この高温での据込みによって得ら
れた弁体(弁体2とする)の軸部より引張試験片を作成
して、実施例と同様に250℃における引張試験を行う
とともに、軸部及びかさ部のロックウェル硬さを測定し
た。その結果を同じく上記表1に示す。
Then, a tensile test piece was prepared from the shaft portion of the valve body (referred to as the valve body 2) obtained by the upsetting at this high temperature, and a tensile test at 250 ° C. was conducted in the same manner as in the example. The Rockwell hardness of the shaft and the bulk was measured. The results are also shown in Table 1 above.

【0025】表1から明らかなように、比較例の弁体2
の引張強さは、実施例の丸棒材と比較してほぼ同等であ
った。しかしながら、弁体2は、かさ部のロックウェル
硬さ(85)が軸部の値(91)に比べて低く、かさ部
が通電加熱による熱影響を受けて劣化していることが判
った。
As is clear from Table 1, the valve body 2 of the comparative example
The tensile strength of was almost the same as that of the round bar material of the example. However, in the valve body 2, it was found that the Rockwell hardness (85) of the bulge portion was lower than the value (91) of the shaft portion, and the bulge portion was deteriorated by the heat effect due to the electric heating.

【0026】以上の比較例の結果より、粒子分散形の耐
熱アルミニウム合金において据込みによりかさ部を成形
するのは容易でないことが判った。以上実施例について
説明したが、本発明は上記実施例に限定されるものでは
なく、種々の態様で実施し得る。
From the results of the above comparative examples, it was found that it is not easy to form the bulky part by upsetting in the particle-dispersed heat-resistant aluminum alloy. Although the embodiments have been described above, the present invention is not limited to the above embodiments and can be implemented in various modes.

【0027】[0027]

【発明の効果】以上のように、本発明の製造方法におい
ては、耐熱アルミニウム合金よりなり、製造すべき弁体
のかさ部の外径と略等しい直径を有する棒材を製造した
後、ダイスに形成された弁体型のかさ部側に棒材を配置
し、この棒材を加熱して押出鍛造することによって弁体
を製造する。よって、耐熱アルミニウム合金の強度を劣
化させることなく弁体を成形でき、成形後も弁体に要求
される強度等の耐熱性を保持することができるという顕
著な効果がある。
As described above, according to the manufacturing method of the present invention, a bar made of a heat-resistant aluminum alloy and having a diameter substantially equal to the outer diameter of the bulk part of the valve body to be manufactured is manufactured and then formed into a die. A valve element is manufactured by arranging a rod member on the side of the formed valve body mold on the bulge portion and heating the rod member for extrusion forging. Therefore, there is a remarkable effect that the valve body can be molded without deteriorating the strength of the heat-resistant aluminum alloy and the heat resistance such as the strength required for the valve body can be maintained even after the molding.

【図面の簡単な説明】[Brief description of drawings]

【図1】実施例の弁体を示す正面図である。FIG. 1 is a front view showing a valve body of an embodiment.

【図2】実施例の弁体の製造方法を示す説明図である。FIG. 2 is an explanatory view showing a method for manufacturing the valve body of the embodiment.

【図3】従来技術を示す説明図である。FIG. 3 is an explanatory diagram showing a conventional technique.

【図4】従来技術を示す説明図である。FIG. 4 is an explanatory diagram showing a conventional technique.

【符号の説明】[Explanation of symbols]

1…弁体 1a…軸部 1b…かさ部 15…押出用ビレット(棒材) 17…ダイス 17a…弁体型 DESCRIPTION OF SYMBOLS 1 ... Valve body 1a ... Shaft part 1b ... Bulk part 15 ... Extrusion billet (bar material) 17 ... Die 17a ... Valve body type

Claims (1)

【特許請求の範囲】[Claims] 【請求項1】 軸部及びかさ部を備え、内燃機関の吸気
弁に使用される耐熱アルミニウム合金製弁体の製造方法
であって、 前記耐熱アルミニウム合金よりなり、前記かさ部の外径
と略等しい直径を有する棒材を製造した後、 ダイスに形成された弁体型のかさ部側に前記棒材を配置
し、該棒材を加熱して押出鍛造することによって、前記
軸部及びかさ部を備える弁体を製造することを特徴とす
る耐熱アルミニウム合金製弁体の製造方法。
1. A method for manufacturing a valve body made of a heat-resistant aluminum alloy, comprising a shaft portion and a bulk portion, which is used for an intake valve of an internal combustion engine, comprising the heat-resistant aluminum alloy, and having an outer diameter substantially equal to that of the bulk portion. After manufacturing the rod having the same diameter, the rod is arranged on the side of the valve body mold formed in the die, and the rod and the bar are heated and extrusion-forged to form the shaft and the bulb. A method of manufacturing a valve body made of a heat-resistant aluminum alloy, which comprises manufacturing a valve body having the same.
JP11985793A 1993-05-21 1993-05-21 Manufacture of heat resistance aluminum alloy made valve body Pending JPH06330714A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP11985793A JPH06330714A (en) 1993-05-21 1993-05-21 Manufacture of heat resistance aluminum alloy made valve body

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP11985793A JPH06330714A (en) 1993-05-21 1993-05-21 Manufacture of heat resistance aluminum alloy made valve body

Publications (1)

Publication Number Publication Date
JPH06330714A true JPH06330714A (en) 1994-11-29

Family

ID=14771997

Family Applications (1)

Application Number Title Priority Date Filing Date
JP11985793A Pending JPH06330714A (en) 1993-05-21 1993-05-21 Manufacture of heat resistance aluminum alloy made valve body

Country Status (1)

Country Link
JP (1) JPH06330714A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100559623B1 (en) * 1999-11-26 2006-03-10 현대자동차주식회사 Intake valve for vehicle

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100559623B1 (en) * 1999-11-26 2006-03-10 현대자동차주식회사 Intake valve for vehicle

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