JPH06325777A - Gas seal structural body for fuel cell - Google Patents
Gas seal structural body for fuel cellInfo
- Publication number
- JPH06325777A JPH06325777A JP5108347A JP10834793A JPH06325777A JP H06325777 A JPH06325777 A JP H06325777A JP 5108347 A JP5108347 A JP 5108347A JP 10834793 A JP10834793 A JP 10834793A JP H06325777 A JPH06325777 A JP H06325777A
- Authority
- JP
- Japan
- Prior art keywords
- cell
- fuel cell
- gasket
- sheet
- gaskets
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
Abstract
Description
【0001】[0001]
【産業上の利用分野】この発明は、固体高分子電解質膜
を用いる燃料電池のガスシール構造体に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a gas seal structure for a fuel cell using a solid polymer electrolyte membrane.
【0002】[0002]
【従来の技術】従来、固体高分子電解質膜を用いる燃料
電池では、セル端部に液状のシール剤を塗布・乾燥させ
た後にセパレータに挟み込んで締め付けることにより、
ガスのリークを防止していた。これを、図2(A),
(B)を参照して説明する。図2(A)は、固体高分子
電解質膜1を上下からガス拡散電極2,3で挟んだセル
4を示す。まず、このセル4の側面、上部周縁部、下部
周縁部にシール剤5を塗布し(図2(B)参照)、セル
4の端部からのガスリークを図った。2. Description of the Related Art Conventionally, in a fuel cell using a solid polymer electrolyte membrane, a liquid sealing agent is applied to the cell end portion, dried, and then sandwiched between separators and tightened.
It was preventing gas leaks. This is shown in FIG.
This will be described with reference to (B). FIG. 2 (A) shows a cell 4 in which a solid polymer electrolyte membrane 1 is sandwiched between gas diffusion electrodes 2 and 3 from above and below. First, the sealant 5 was applied to the side surface, the upper peripheral portion, and the lower peripheral portion of the cell 4 (see FIG. 2 (B)), and gas leakage from the end portion of the cell 4 was attempted.
【0003】[0003]
【発明が解決しようとする課題】しかしながら、図2
(B)のようにシール剤5を塗布した状態では図2
(C)に示す如く、シール剤5を塗布したセル4を上下
のセパレータ6,7で挟んで積層化する際、シール剤5
とセパレータ6,7の当たりが悪く、リークが生じる。However, as shown in FIG.
When the sealant 5 is applied as shown in FIG.
As shown in (C), when the cell 4 coated with the sealing agent 5 is sandwiched between the upper and lower separators 6 and 7 to be laminated, the sealing agent 5
And the separators 6 and 7 do not hit well, and a leak occurs.
【0004】そこで、リークを防止するためにはシール
剤5を均一にムラなく塗布し乾燥する必要があった。ま
た、セル4が柔軟性を持つ際はシール剤5とセル端部が
接することができず、例えばガス拡散電極3内を透過し
てきたガスの他方のガス拡散電極2側へのガスリークを
止めることができない(図2(D)参照)。Therefore, in order to prevent leakage, it is necessary to apply the sealant 5 uniformly and evenly. Further, when the cell 4 has flexibility, the sealant 5 and the cell end cannot come into contact with each other, and, for example, stop the gas leaked to the other gas diffusion electrode 2 side of the gas that has permeated through the gas diffusion electrode 3. Cannot be performed (see FIG. 2D).
【0005】この発明はこうした事情を考慮してなされ
たもので、セルをセパレータで挟み積層化する際のリー
クを防止するとともに、セルが柔軟性を持つ際にセルの
一方のガス拡散電極から他方のガス拡散電極へのガスリ
ークを防止しえる燃料電池のガスシール構造体を提供す
ることを目的とする。The present invention has been made in consideration of the above circumstances, and prevents leakage when the cells are sandwiched by the separators and laminated, and when the cells are flexible, the gas diffusion electrode from one of the cells to the other of the cells can be prevented. It is an object of the present invention to provide a gas seal structure for a fuel cell, which can prevent gas leakage to the gas diffusion electrode.
【0006】[0006]
【課題を解決するための手段】この発明は、固体高分子
電解質膜とこの固体高分子電解質膜の両面に配置された
ガス拡散電極からなる燃料電池発電体と、前記燃料電池
発電体の両主面側に夫々配置され、前記燃料電池発電体
の縁部よりはみ出す大きさをもつシート状ガスケット
と、前記シート状ガスケットの外側に夫々配置され、該
ガスケットを外側から燃料電池発電体の縁部及び端面部
に密着させる外側押え手段とを具備することを特徴とす
る燃料電池のガスシール構造体である。The present invention is directed to a fuel cell power generator comprising a solid polymer electrolyte membrane and gas diffusion electrodes arranged on both sides of the solid polymer electrolyte membrane, and to both the fuel cell power generator and the fuel cell power generator. Sheet-shaped gaskets respectively arranged on the surface side and having a size protruding from the edge of the fuel cell power generator, and respectively arranged outside the sheet-shaped gasket, and the gasket is arranged from the outside to the edge of the fuel cell power generator and A gas seal structure for a fuel cell, characterized in that the gas seal structure is provided with an outer pressing means that is brought into close contact with the end face portion.
【0007】この発明において、外側押え手段として
は、図1に示す如く互いに分離した外側押えとセパレー
タから構成されるもの、あるいは外側押えとセパレータ
とが一体になったものが挙げられる。In the present invention, the outer pressing means may be composed of an outer pressing member and a separator which are separated from each other as shown in FIG. 1, or a unit in which the outer pressing member and the separator are integrated.
【0008】[0008]
【作用】この発明において、シート状ガスケットでセル
を挟み外側押え手段で押えることによって、セルと外側
押え手段間によるリークを防止できる。また、シート状
ガスケットにせん断力を与えセル端面方向に曲げ、セル
端面に密着させることによって隙間が無くなり、セルの
ガス拡散電極内を透過してきたガスのリークを防止でき
る。In the present invention, by sandwiching the cell with the sheet-like gasket and pressing it with the outer pressing means, it is possible to prevent the leak between the cell and the outer pressing means. Further, a shearing force is applied to the sheet-like gasket to bend it toward the cell end face and bring it into close contact with the cell end face, thereby eliminating the gap and preventing gas leaking through the gas diffusion electrode of the cell from leaking.
【0009】[0009]
【実施例】以下、この発明の一実施例を図1(A)〜
(C)を参照して説明する。ここで、図1(A)はこの
実施例に係る燃料電池のガスシール構造体の展開図、図
1(B)は積層化したガスシール構造体の要部の断面
図、図1(C)は積層化したガスシール構造体における
力の発生状態を示す説明図である。図中の符番11は、矩
形状の燃料電池発電体(セル)である。このセル11は、
固体高分子電解質膜12と、この固体高分子電解質膜12の
上下面側に夫々配置されたガス拡散電極13a,13bから
構成されている。前記セル11の両主面側には、セル11の
縁部よりはみ出す大きさをもつ厚さ0.5mmのシート状
ガスケット14a,14bが配置されている。前記シート状
ガスケット14a,14bの外側には、前記セル11の外径よ
り大きい穴15をもつ外側押え16a,16bが夫々配置され
ている。これら外側押え16a,16bは、前記シート状ガ
スケット14a,14bをセル端部に押し付けるためのもの
であり、ある程度弾性をもたせたものを使用する。前記
外側押え16a,16bの外側には、セパレータ17a,17b
が配置されている。ここで、前記外側押え及びセパレー
タにより外側押え手段が構成されている。DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENT An embodiment of the present invention will be described below with reference to FIGS.
This will be described with reference to (C). Here, FIG. 1A is a development view of a gas seal structure of a fuel cell according to this embodiment, FIG. 1B is a cross-sectional view of a main part of a laminated gas seal structure, and FIG. FIG. 4 is an explanatory diagram showing a force generation state in a laminated gas seal structure. Reference numeral 11 in the figure is a rectangular fuel cell power generator (cell). This cell 11
The solid polymer electrolyte membrane 12 and the gas diffusion electrodes 13a and 13b arranged on the upper and lower surfaces of the solid polymer electrolyte membrane 12, respectively. Sheet-like gaskets 14a, 14b having a thickness of 0.5 mm and having a size protruding from the edge of the cell 11 are arranged on both main surface sides of the cell 11. Outside the sheet-like gaskets 14a, 14b, outside pressers 16a, 16b having holes 15 larger than the outer diameter of the cell 11 are arranged, respectively. The outer pressers 16a and 16b are used to press the sheet-like gaskets 14a and 14b against the cell ends, and are used to have elasticity to some extent. Separators 17a and 17b are provided outside the outer pressers 16a and 16b.
Are arranged. Here, the outer pressing means and the separator constitute outer pressing means.
【0010】この実施例では、外側押え16a,16bをセ
パレータ17a,17bで挟み圧縮することにより、図1
(C)中に示した矢印方向に力を発生させるようにし
た。前記シート状ガスケット14a,14bは、セル11の端
部及び外側押え16a,16bによってせん断応力を受け、
セル端面に密着する。In this embodiment, the outer pressers 16a and 16b are sandwiched between the separators 17a and 17b and compressed, so that
A force was generated in the direction of the arrow shown in (C). The sheet-like gaskets 14a, 14b are subjected to shear stress by the ends of the cells 11 and the outer pressers 16a, 16b,
It adheres to the cell end face.
【0011】なお、図示しないが、セパレータの外側に
はフランジなど(図示せず)を配置し、ボルト・ナット
にて締め付けた構造になっている。また、図1(A)は
単一のセルの場合を示すもので、一般的にはセパレータ
とセルとを交互に積層し、ボルト・ナットにて締め付け
たスタック構造になっている。Although not shown, a flange or the like (not shown) is arranged on the outside of the separator, and the separator is tightened with bolts and nuts. Further, FIG. 1A shows a case of a single cell, and generally has a stack structure in which separators and cells are alternately laminated and tightened with bolts and nuts.
【0012】上記実施例に係る燃料電池のガスシール構
造体は、図1に示す如く、固体高分子電解質膜12及び該
固体高分子電解質膜12の上下面側に配置されたガス拡散
電極13a,13bからなる矩形状のセル11と、前記セル11
の両主面側に配置された厚さ0.5mmのシート状ガスケ
ット14a,14bと、前記シート状ガスケット14a,14
bの外側に配置された、前記セル11の外径より大きい
穴15をもちかつある程度弾性をもつ外側押え16a,16b
と、前記外側押え16a,16bの外側に配置されたセパレ
ータ17a,17bとを具備し、外側押え16a,16bをもセ
パレータ17a,17bで挟み圧縮することにより、図1
(C)中に示した矢印方向に力を発生させるように構成
されている。従って、従来のセルのようにシール剤を塗
布する必要がないため、生産性が向上する。また、柔軟
なシート状ガスケット14a,14bを用いてセル11の縁部
と端面部を挟み、更にそのシート状ガスケット14a,14
bに外側押え16a,16bによりせん断をかけてシールす
る構成であるため、ガスのリークを確実に防止できる。As shown in FIG. 1, the gas seal structure for a fuel cell according to the above-mentioned embodiment comprises a solid polymer electrolyte membrane 12 and gas diffusion electrodes 13a arranged on the upper and lower surfaces of the solid polymer electrolyte membrane 12. A rectangular cell 11 composed of 13b and the cell 11
Sheet-like gaskets 14a, 14b having a thickness of 0.5 mm arranged on both main surface sides of the sheet-like gaskets, and the sheet-like gaskets 14a, 14
Outer retainers 16a, 16b, which are arranged on the outer side of b and have a hole 15 larger than the outer diameter of the cell 11 and have elasticity to some extent.
And separators 17a and 17b arranged outside the outer pressers 16a and 16b, and the outer pressers 16a and 16b are also sandwiched between the separators 17a and 17b and compressed, thereby
It is configured to generate a force in the arrow direction shown in (C). Therefore, unlike the conventional cell, it is not necessary to apply the sealant, and the productivity is improved. Further, the flexible sheet-like gaskets 14a and 14b are used to sandwich the edge portion and the end face portion of the cell 11, and further, the sheet-like gaskets 14a and 14b.
Since the b is sealed by the outer pressers 16a and 16b for sealing, gas leakage can be reliably prevented.
【0013】なお、上記実施例では、シート状ガスケッ
トとして厚さ0.5mmのものを使用したが、これに限ら
ず、ガスケットの柔軟性が大きい場合は更に厚いものを
選定すればよい。In the above embodiment, the sheet-like gasket having a thickness of 0.5 mm is used. However, the present invention is not limited to this, and if the gasket has a large flexibility, a thicker gasket may be selected.
【0014】[0014]
【発明の効果】以上詳述したようにこの発明によれば、
セルをセパレータで挟み積層化する際のリークを防止す
るとともに、セルが柔軟性を持つ際にセルの一方のガス
拡散電極から他方のガス拡散電極へのガスリークを防止
しえ、更に生産性を向上しえる燃料電池のガスシール構
造体を提供できる。As described above in detail, according to the present invention,
Prevents leaks when stacking cells by sandwiching them with separators and prevents gas leaks from one gas diffusion electrode of the cell to the other gas diffusion electrode when the cell is flexible, further improving productivity A gas seal structure for a fuel cell can be provided.
【図1】この発明の一実施例に係る燃料電池のガスシー
ル構造体の説明図であり、図1(A)はガスシール構造
体の展開図、図1(B)は積層化したガスシール構造体
の要部の断面図、図1(C)は積層化したガスシール構
造体における力の発生状態を示す説明図この発明の一実
施例の全体構成を示すブロック図。1 is an explanatory view of a gas seal structure of a fuel cell according to an embodiment of the present invention, FIG. 1 (A) is a development view of the gas seal structure, and FIG. 1 (B) is a laminated gas seal. Sectional drawing of the principal part of a structure, FIG.1 (C) is explanatory drawing which shows the generation | occurrence | production state of the force in the laminated gas seal structure. The block diagram which shows the whole structure of one Example of this invention.
【図2】従来のセルの説明図であり、図2(A)はセル
の斜視図、図2(B)は同セルにシール剤を付けた状態
の説明図、図2(C)は同セルをセパレータで挟み積層
化する際のリークの状況を示す説明図、図2(D)は同
セルが柔軟性を持つ場合のガスリークの状況を示す説明
図。FIG. 2 is an explanatory view of a conventional cell, FIG. 2 (A) is a perspective view of the cell, FIG. 2 (B) is an explanatory view of a state in which a sealing agent is attached to the cell, and FIG. 2 (C) is the same. Explanatory drawing showing the situation of leakage when sandwiching a cell with a separator, FIG. 2 (D) is an explanatory view showing the situation of gas leakage when the cell has flexibility.
11…セル、 12…固体高分子電
解質膜、13a,13b…ガス拡散電極、 14a,14
b…シート状ガスケット、16a,16b…外側押え、
17a,17b…セパレータ。11 ... Cell, 12 ... Solid polymer electrolyte membrane, 13a, 13b ... Gas diffusion electrode, 14a, 14
b ... Sheet gasket, 16a, 16b ... Outer retainer,
17a, 17b ... Separator.
Claims (1)
解質膜の両面に配置されたガス拡散電極からなる燃料電
池発電体と、前記燃料電池発電体の両主面側に夫々配置
され、前記燃料電池発電体の縁部よりはみ出す大きさを
もつシート状ガスケットと、前記シート状ガスケットの
外側に夫々配置され、該ガスケットを外側から燃料電池
発電体の縁部及び端面部に密着させる外側押え手段とを
具備することを特徴とする燃料電池のガスシール構造
体。1. A fuel cell power generator comprising a solid polymer electrolyte membrane and gas diffusion electrodes disposed on both sides of the solid polymer electrolyte membrane, and a fuel cell power generator disposed on both main surface sides of the fuel cell power generator, respectively. A sheet-like gasket having a size protruding from the edge of the fuel cell power generator, and outer pressing means arranged respectively on the outer side of the sheet-like gasket and closely contacting the gasket with the edge and the end face of the fuel cell power generator from the outside. A gas seal structure for a fuel cell, comprising:
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP5108347A JP3068365B2 (en) | 1993-05-10 | 1993-05-10 | Gas seal structure of fuel cell |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP5108347A JP3068365B2 (en) | 1993-05-10 | 1993-05-10 | Gas seal structure of fuel cell |
Publications (2)
Publication Number | Publication Date |
---|---|
JPH06325777A true JPH06325777A (en) | 1994-11-25 |
JP3068365B2 JP3068365B2 (en) | 2000-07-24 |
Family
ID=14482404
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP5108347A Expired - Lifetime JP3068365B2 (en) | 1993-05-10 | 1993-05-10 | Gas seal structure of fuel cell |
Country Status (1)
Country | Link |
---|---|
JP (1) | JP3068365B2 (en) |
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---|---|---|---|---|
WO2002061869A1 (en) * | 2001-01-31 | 2002-08-08 | Matsushita Electric Industrial Co., Ltd. | High polymer electrolyte fuel cell and electrolyte film-gasket assembly for the fuel cell |
KR20040004934A (en) * | 2002-07-06 | 2004-01-16 | 엘지전자 주식회사 | Membrane assembly for fuel cell |
US6699613B2 (en) | 2000-05-02 | 2004-03-02 | Honda Giken Kogyo Kabushiki Kaisha | Fuel cell having sealant for sealing a solid polymer electrolyte membrane |
JP2006179298A (en) * | 2004-12-22 | 2006-07-06 | Hitachi Ltd | Solid polymer electrolyte membrane-electrode joining body and polymer electrolyte fuel cell using it |
US7081314B2 (en) | 2000-05-02 | 2006-07-25 | Honda Giken Kogyo Kabushiki Kaisha | Fuel cell having sealant for sealing a solid polymer electrolyte membrane |
JP2006210234A (en) * | 2005-01-31 | 2006-08-10 | Uchiyama Mfg Corp | Constituent member of fuel cell |
JP2006236957A (en) * | 2005-01-31 | 2006-09-07 | Uchiyama Mfg Corp | Constituent member for fuel cell |
WO2006121041A1 (en) * | 2005-05-11 | 2006-11-16 | Matsushita Electric Industrial Co., Ltd. | Fuel cell |
FR2887686A1 (en) * | 2005-06-28 | 2006-12-29 | Peugeot Citroen Automobiles Sa | SEAL AND FUEL CELL COMPRISING SUCH A SEAL APPOSE TO BIPOLAR PLATES |
JP2007335353A (en) * | 2006-06-19 | 2007-12-27 | Toyota Motor Corp | Fuel cell |
WO2008001755A1 (en) * | 2006-06-26 | 2008-01-03 | Panasonic Corporation | Solid polymer electrolyte fuel cell |
WO2009069771A1 (en) * | 2007-11-28 | 2009-06-04 | Toyota Jidosha Kabushiki Kaisha | Unit cell of fuel battery |
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1993
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Cited By (23)
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US6699613B2 (en) | 2000-05-02 | 2004-03-02 | Honda Giken Kogyo Kabushiki Kaisha | Fuel cell having sealant for sealing a solid polymer electrolyte membrane |
US7081314B2 (en) | 2000-05-02 | 2006-07-25 | Honda Giken Kogyo Kabushiki Kaisha | Fuel cell having sealant for sealing a solid polymer electrolyte membrane |
US7651805B2 (en) | 2000-05-02 | 2010-01-26 | Honda Giken Kogyo Kabushiki Kaisha | Fuel cell having sealant for sealing a solid polymer electrolyte membrane |
WO2002061869A1 (en) * | 2001-01-31 | 2002-08-08 | Matsushita Electric Industrial Co., Ltd. | High polymer electrolyte fuel cell and electrolyte film-gasket assembly for the fuel cell |
US6840969B2 (en) | 2001-01-31 | 2005-01-11 | Matsushita Electric Industrial Co., Ltd. | High polymer electrolyte fuel cell and electrolyte film-gasket assembly for the fuel cell |
CN1305157C (en) * | 2001-01-31 | 2007-03-14 | 松下电器产业株式会社 | High polymer electrolyte fuel cell and electrolyte film-gasket assembly for fuel cell |
KR20040004934A (en) * | 2002-07-06 | 2004-01-16 | 엘지전자 주식회사 | Membrane assembly for fuel cell |
JP2006179298A (en) * | 2004-12-22 | 2006-07-06 | Hitachi Ltd | Solid polymer electrolyte membrane-electrode joining body and polymer electrolyte fuel cell using it |
JP2006210234A (en) * | 2005-01-31 | 2006-08-10 | Uchiyama Mfg Corp | Constituent member of fuel cell |
JP2006236957A (en) * | 2005-01-31 | 2006-09-07 | Uchiyama Mfg Corp | Constituent member for fuel cell |
US8404401B2 (en) | 2005-05-11 | 2013-03-26 | Panasonic Corporation | Fuel cell having improved contact between separators and gas diffusion layers |
WO2006121041A1 (en) * | 2005-05-11 | 2006-11-16 | Matsushita Electric Industrial Co., Ltd. | Fuel cell |
JP4995573B2 (en) * | 2005-05-11 | 2012-08-08 | パナソニック株式会社 | Fuel cell |
WO2007003742A2 (en) * | 2005-06-28 | 2007-01-11 | Peugeot Citroen Automobiles S.A. | Seal and fuel cell comprising same affixed on the bipolar plates |
US7713647B2 (en) | 2005-06-28 | 2010-05-11 | Peugeot Citroen Automobiles Sa | Seal and fuel cell comprising same affixed on the bipolar plates |
WO2007003742A3 (en) * | 2005-06-28 | 2007-03-08 | Peugeot Citroen Automobiles Sa | Seal and fuel cell comprising same affixed on the bipolar plates |
FR2887686A1 (en) * | 2005-06-28 | 2006-12-29 | Peugeot Citroen Automobiles Sa | SEAL AND FUEL CELL COMPRISING SUCH A SEAL APPOSE TO BIPOLAR PLATES |
JP2007335353A (en) * | 2006-06-19 | 2007-12-27 | Toyota Motor Corp | Fuel cell |
WO2008001755A1 (en) * | 2006-06-26 | 2008-01-03 | Panasonic Corporation | Solid polymer electrolyte fuel cell |
JPWO2008001755A1 (en) * | 2006-06-26 | 2009-11-26 | パナソニック株式会社 | Solid polymer electrolyte fuel cell |
US7833673B2 (en) | 2006-06-26 | 2010-11-16 | Panasonic Corporation | Solid polymer electrolytic fuel cell |
WO2009069771A1 (en) * | 2007-11-28 | 2009-06-04 | Toyota Jidosha Kabushiki Kaisha | Unit cell of fuel battery |
JP5024386B2 (en) * | 2007-11-28 | 2012-09-12 | トヨタ自動車株式会社 | Fuel cell single cell |
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