JPH06315534A - Oxygen concentrating device - Google Patents
Oxygen concentrating deviceInfo
- Publication number
- JPH06315534A JPH06315534A JP10816393A JP10816393A JPH06315534A JP H06315534 A JPH06315534 A JP H06315534A JP 10816393 A JP10816393 A JP 10816393A JP 10816393 A JP10816393 A JP 10816393A JP H06315534 A JPH06315534 A JP H06315534A
- Authority
- JP
- Japan
- Prior art keywords
- adsorbent
- oxygen
- bed
- surge tank
- adsorption
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- Oxygen, Ozone, And Oxides In General (AREA)
Abstract
Description
【0001】[0001]
【産業上の利用分野】本発明は、大気から酸素濃縮気体
を分離して使用するための酸素濃縮装置に関するもので
ある。さらに詳細には、圧力変動吸着型酸素濃縮装置に
関するものであって、より安定した濃度で酸素濃縮気体
を使用者に供給できるようにした改善された酸素濃縮装
置を提供するものである。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an oxygen concentrator for separating and using an oxygen enriched gas from the atmosphere. More specifically, the present invention relates to a pressure fluctuation adsorption type oxygen concentrator, and to provide an improved oxygen concentrator capable of supplying an oxygen-concentrated gas to a user at a more stable concentration.
【0002】[0002]
【従来の技術】近年ぜんそく、肺気腫症、慢性気管支炎
等の呼吸器系器官の疾患に苦しむ患者が増加する傾向に
あると言われているが、その治療法で最も効果的なもの
の1つに酸素吸入法がある。2. Description of the Related Art Recently, it is said that the number of patients suffering from diseases of respiratory organs such as asthma, emphysema, chronic bronchitis and the like tends to increase. There is an oxygen inhalation method.
【0003】かかる酸素吸入法とは、酸素ガスあるいは
酸素富化空気を患者に吸入させるものであって、その酸
素ガスや酸素富化空気の供給源として酸素ガスボンベが
従来より用いられていたが近年空気中から酸素濃縮気体
を分離する酸素濃縮装置が開発されてからは、使用時の
便利さや保守管理の容易さから次第に普及するようにな
ってきている。The oxygen inhalation method is to inhale oxygen gas or oxygen-enriched air into a patient, and an oxygen gas cylinder has been conventionally used as a supply source of the oxygen gas or oxygen-enriched air. Since the development of an oxygen concentrator that separates oxygen-enriched gas from the air, it has become increasingly popular due to its convenience in use and ease of maintenance.
【0004】酸素濃縮装置としては主に、酸素選択透過
性膜を用いた膜型酸素濃縮装置と、窒素又は酸素を選択
的に吸着し得る吸着剤を用いた吸着型酸素濃縮装置の2
種類があるが、本発明は吸着型酸素濃縮装置について改
善を加えようとするものである。The oxygen concentrator mainly comprises a membrane type oxygen concentrator using a selective oxygen permeable membrane and an adsorption type oxygen concentrator using an adsorbent capable of selectively adsorbing nitrogen or oxygen.
Although there are types, the present invention seeks to improve the adsorption type oxygen concentrator.
【0005】これまでの吸着型酸素濃縮装置の主なもの
としては、コンプレッサーを用いた圧力変動吸着型酸素
濃縮装置がある。かかる装置は通常、窒素を選択的に吸
着し得る吸着剤を充填した吸着床にコンプレッサーで加
圧された圧縮空気を導入して加圧状態で窒素を吸着させ
ることによって酸素濃縮気体を得る吸着工程と、吸着床
の内圧を減少させて脱着を行なう脱着工程を交互に行な
わせることによって酸素濃縮気体を得るものである。こ
の場合に、吸着床からの酸素濃縮気体を一時的に貯留し
ておくためのサージタンクが使用され、サージタンク内
に貯留された酸素濃縮気体を吸着床に逆流させて、吸着
床の再加圧や吸着床の脱着のためのリンス用に用いられ
ることが多い。The main adsorption type oxygen concentrators so far used are pressure fluctuation adsorption type oxygen concentrators using a compressor. Such an apparatus is usually an adsorption step in which compressed air compressed by a compressor is introduced into an adsorption bed filled with an adsorbent capable of selectively adsorbing nitrogen to adsorb nitrogen under pressure to obtain an oxygen-enriched gas. Then, the oxygen-concentrated gas is obtained by alternately performing the desorption step of desorbing by reducing the internal pressure of the adsorption bed. In this case, a surge tank is used to temporarily store the oxygen-enriched gas from the adsorption bed, and the oxygen-enriched gas stored in the surge tank is caused to flow back to the adsorption bed to re-add the adsorption bed. Often used for pressure and rinse for desorption of the adsorbent bed.
【0006】[0006]
【発明が解決しようとする課題】上記した吸着床におい
ては吸着床内の吸着剤粒子が吸脱着工程を繰返すことで
わずかに相互の位置をかえ、長時間の間に床内を対流す
る現象がみられる。このことは吸着床を安定的に使用
し、性能を維持するためには好ましくない。また複数の
種類の吸着剤を積層充填する吸着床では特にさけなけれ
ばならない現象の一つである。In the above-mentioned adsorption bed, the phenomenon in which the adsorbent particles in the adsorption bed slightly change their positions due to repeated adsorption / desorption steps and convection in the bed for a long time occurs. Seen. This is not preferable in order to use the adsorption bed stably and maintain the performance. In addition, this is one of the phenomena that must be avoided especially in an adsorption bed in which a plurality of types of adsorbents are packed in layers.
【0007】[0007]
【課題を解決するための手段】本発明者は、かかるこれ
までの酸素濃縮装置における問題点を解決することを目
的として鋭意研究した結果、吸着床の吸着剤を充填する
方法でバネ押えの多孔板と吸着剤の粒子が通過しない微
細な開孔をもつ部材を組合せることが非常に有効である
ことを見い出し、本発明に到達したものである。As a result of intensive research aimed at solving the problems in the conventional oxygen concentrators, the present inventor has found that the method of filling the adsorbent in the adsorbent bed is used for the spring-loaded porous method. The present inventors have found that it is very effective to combine a plate and a member having fine apertures through which particles of an adsorbent do not pass, and arrived at the present invention.
【0008】即ち本発明は、酸素よりも窒素を選択的に
吸着し得る吸着剤を充填した吸着床と、該吸着床へ圧縮
空気を供給するためのコンプレッサー手段と、該吸着床
からの酸素濃縮気体を受け取り貯留するためのサージタ
ンク手段と、酸素濃縮気体を使用に供するための酸素濃
縮気体供給手段を具備した圧力変動吸着(PSA)型酸
素濃縮器において、該吸着床が、吸着剤充填部の上端部
及び下端部に空気の流れを整流させるための多孔板を具
備し、且つ吸着剤充填部の中間部に吸着剤粒子の混合を
防止するため吸着剤粒子保持部材を具備し、さらに上端
部及び下端部の多孔板の一方に該多孔板を吸着剤側に押
しつけられた状態に保持するためのバネ手段を具備した
ことを特徴とする酸素濃縮装置を提供するものである。That is, the present invention is directed to an adsorbent bed filled with an adsorbent capable of selectively adsorbing nitrogen over oxygen, a compressor means for supplying compressed air to the adsorbent bed, and an oxygen concentration from the adsorbent bed. In a pressure swing adsorption (PSA) type oxygen concentrator equipped with a surge tank means for receiving and storing gas and an oxygen enriched gas supply means for using the oxygen enriched gas for use, the adsorbent bed has an adsorbent filling section. A perforated plate for rectifying the flow of air at the upper and lower ends of the adsorbent, and an adsorbent particle holding member for preventing admixture of adsorbent particles in the middle part of the adsorbent filling part, and the upper end The present invention provides an oxygen concentrator, characterized in that one of the lower part and the lower end of the perforated plate is provided with a spring means for holding the perforated plate in a state of being pressed against the adsorbent side.
【0009】かかる本発明の装置には、該吸着床が1基
であり、該コンプレッサー手段が吸着床へ圧縮空気を供
給する際にはコンプレッサーとして機能し、吸着床の脱
着工程時には真空ポンプとして機能するようにしたもの
である酸素濃縮装置が含まれる。In the apparatus of the present invention, the adsorption bed is one, and the compressor means functions as a compressor when supplying compressed air to the adsorption bed, and functions as a vacuum pump during the desorption process of the adsorption bed. An oxygen concentrator that is adapted to do so is included.
【0010】さらに本発明の装置には、該吸着剤粒子保
持部材が、吸着床内の空気の流れに対して実質上垂直に
位置し、実質上吸着床内の空気の流動抵抗とならないも
のであって、吸着剤の充填部を2〜4領域に分割するよ
うにしたものである酸素濃縮装置が含まれる。Further, in the apparatus of the present invention, the adsorbent particle holding member is positioned substantially perpendicular to the air flow in the adsorption bed, and does not substantially cause flow resistance of the air in the adsorption bed. Therefore, an oxygen concentrating device in which the adsorbent filling portion is divided into 2 to 4 regions is included.
【0011】さらに本発明の装置には、該サージタンク
手段の内部空間の一部に少なくとも酸素を吸着し得る吸
着剤が充填されており、該吸着床からの酸素濃縮気体が
該サージタンク手段に流入するための流入導管手段が該
サージタンク手段における吸着剤非充填領域において開
口しており、該サージタンク手段から酸素濃縮気体が流
出するための流出導管手段が該サージタンク手段の吸着
剤充填領域において開口しており、該流出導管手段が逆
流防止弁手段を介して製品タンク手段に連結されてお
り、該製品タンク手段に該酸素濃縮気体供給手段が連結
されている酸素濃縮装置が含まれる。Further, in the device of the present invention, at least a part of the internal space of the surge tank means is filled with an adsorbent capable of adsorbing oxygen, and the oxygen enriched gas from the adsorption bed is supplied to the surge tank means. Inflow conduit means for inflow is open in the adsorbent unfilled area of the surge tank means, and outflow conduit means for outflow of oxygen enriched gas from the surge tank means is adsorbent filled area of the surge tank means. An oxygen concentrator is included which is open at, the outlet conduit means is connected to the product tank means via a check valve means, and the oxygen tank gas supply means is connected to the product tank means.
【0012】さらに本発明の装置には、該サージタンク
手段に貯留された酸素濃縮気体が吸着床に逆流する工程
が圧力変動吸着工程に含まれるものである酸素濃縮装
置。Further, in the apparatus of the present invention, the pressure fluctuation adsorption step includes a step in which the oxygen enriched gas stored in the surge tank means flows back into the adsorption bed.
【0013】さらに本発明の装置には、該吸着剤充填領
域が該サージタンク手段の下方に位置しており、該吸着
剤充填領域における該流出導管手段の開口部が該吸着剤
充填領域内での気体の流れが該開口部に対して対称とな
るように下部層の中央部に位置している酸素濃縮装置が
含まれる。Further, in the apparatus of the present invention, the adsorbent filling area is located below the surge tank means, and the opening of the outflow conduit means in the adsorbent filling area is within the adsorbent filling area. An oxygen concentrator located in the center of the lower layer such that the gas flow is symmetrical with respect to the opening.
【0014】以下に本発明の酸素濃縮装置について、図
面に必要に応じて用いながら、さらに詳細に説明する。
一般に圧力変動型吸着(PSA)装置では、吸着床に充
填された吸着剤が工程の圧力変動に伴ってその位置を変
えることがある。特開平4―279173号公報や特願
平4―30693号明細書に記載される如き一塔式のP
SA装置で、圧縮ポンプとして機能させて脱着を確実に
するタイプの場合にもこの現象がみられる。The oxygen concentrator of the present invention will be described in more detail below with reference to the drawings as needed.
Generally, in a pressure fluctuation type adsorption (PSA) apparatus, the position of the adsorbent packed in the adsorption bed may change according to the pressure fluctuation of the process. One-tower type P as described in JP-A-4-279173 and Japanese Patent Application No. 4-30693
This phenomenon is also observed in the SA device of the type that functions as a compression pump to ensure desorption.
【0015】この現象は、従来使用されている図1のタ
イプでは特に顕著で、経時によって充填密度が高くな
り、上部に空間部ができるほどである。この場合、吸着
剤は塔内をあたかも水が温度差(密度差)で対流する現
象に近い挙動で対流する。これらは微妙な吸着帯形成を
要求される医療用のPSA方式の酸素濃縮装置において
は致命的であるともいえる。これらを改善するため上部
をバネ押えタイプとしたものもある。(図2上部の
み)。しかしこれでも流動完全に防止することはできな
い。これは図1の下部の流入方式では流れが均一でなく
吸着、脱着時の吸着剤の粒子の流動がさけられない。し
たがって吸着床内では実質的に軸方向の流れ成分のみを
作り出す構造が好ましい(図3参照)。This phenomenon is particularly remarkable in the conventionally used type shown in FIG. 1, and the packing density becomes high with the passage of time, and a space is formed at the upper part. In this case, the adsorbent convects inside the tower as if the water were convection due to a temperature difference (density difference). It can be said that these are fatal in the medical PSA type oxygen concentrator which requires a delicate adsorption zone formation. In order to improve these, there is also a type in which the upper part is spring-loaded. (Only the upper part of FIG. 2). However, even this cannot completely prevent the flow. This is because the flow is not uniform in the inflow method in the lower part of FIG. 1, and the flow of the particles of the adsorbent during adsorption and desorption cannot be avoided. Therefore, a structure that produces substantially only the axial flow component in the adsorption bed is preferable (see FIG. 3).
【0016】本発明の吸着床では、圧縮空気が流入する
部分では部分的に急激な温度変化が起こる。つまり脱着
時には十分に脱着が行われ、吸熱反応のために熱をうば
われ温度が著しく低下する。室温より10℃以上を低下
することもある。また吸着時には流入空気により急激な
窒素吸着がおこるため発熱反応のため昇温がはげしくお
こる。In the adsorbent bed of the present invention, a rapid temperature change partially occurs in the portion into which the compressed air flows. In other words, during desorption, the desorption is sufficiently carried out and heat is dissipated due to the endothermic reaction, resulting in a significant decrease in temperature. The temperature may drop 10 ° C or more from room temperature. In addition, during the adsorption, the inflowing air causes a rapid adsorption of nitrogen, so the temperature rises violently due to the exothermic reaction.
【0017】従来の吸着床を示す図1の場合、流入部周
辺において複雑な温度分布や温度変化を生じる。これは
酸素濃度を上昇させるために吸着剤が効果的に使用され
てないことを表わしている。即ち、気体と固体の接触が
効果的に行なわれない。In the case of FIG. 1 showing a conventional adsorption bed, a complicated temperature distribution and temperature change occur around the inflow section. This indicates that the adsorbent has not been effectively used to increase the oxygen concentration. That is, the contact between the gas and the solid is not effectively performed.
【0018】図2の様に改善することで大巾な酸素濃度
upがはかれた。これらは装置の小型化、吸着床の小型
化をはかっていく場合に特に必要で、吸着剤の生産性を
向上させていくには必要技術である。By improving as shown in FIG. 2, a wide oxygen concentration up was obtained. These are especially necessary when downsizing the apparatus and downsizing the adsorption bed, and are necessary techniques for improving the productivity of the adsorbent.
【0019】長時間の連続運転の場合でみると、さらに
床内の吸着剤流動を防止するために、本発明の酸素濃縮
装置における吸着床の1例である図3の不織布、金網等
の吸着剤流動防止手段としての吸着剤粒子保持部材12
が効果的である。In the case of continuous operation for a long time, in order to further prevent the flow of the adsorbent in the bed, the adsorption of the nonwoven fabric, wire mesh, etc. shown in FIG. 3 which is an example of the adsorption bed in the oxygen concentrator of the present invention. Adsorbent particle holding member 12 as agent flow prevention means
Is effective.
【0020】例えば図3において最下段部分には空気を
供給するため空気中の水分(湿度)に対して比較的強い
吸着剤を充填しその上部には窒素、酸素の分離性能のよ
う吸着剤を充填する場合などにその間に具備されたたと
えば不織布等が有効である。For example, in FIG. 3, the lowermost part is filled with an adsorbent which is relatively strong against moisture (humidity) in the air to supply air, and the upper part is filled with an adsorbent such as nitrogen and oxygen separation performance. For filling, for example, a nonwoven fabric or the like provided between them is effective.
【0021】この不織布の目的はあくまで吸着剤粒子の
移動を防止することであり粒子が通過しない開孔を持っ
ていればそれでよい。特別に吸着床壁(たとえばアルミ
筒)に固定する必要がなく吸着剤充填の際、中間に敷く
だけでよい。The purpose of this non-woven fabric is merely to prevent the movement of the adsorbent particles, and it is sufficient as long as it has openings through which the particles do not pass. There is no need to specially fix it to the adsorption bed wall (for example, an aluminum cylinder), and it is sufficient to lay it in the middle when filling the adsorbent.
【0022】したがって他に見られるようにたとえば工
業用の大型塔径の大きい吸着塔では塔中心部の流れが早
いため滞留時間を均一にするためにいわゆる再分配をも
たせるために中間部仕切板塔で流れのパターンを規制す
る構造物を設ける例もある。いわゆる流れ方向(軸方
向)に対して直角方向の流れを生じさせるものであり根
本的に本発明の吸着剤粒子保持部材とは異なる。Therefore, as seen elsewhere, for example, in an industrial large-scale adsorption tower with a large diameter, the flow in the central portion of the tower is fast, so that the so-called redistribution is made in order to make the retention time uniform and the intermediate partition tower. There is also an example in which a structure that regulates the flow pattern is provided. It causes a flow in a direction perpendicular to the so-called flow direction (axial direction) and is fundamentally different from the adsorbent particle holding member of the present invention.
【0023】[0023]
【発明の効果】本発明の酸素濃縮装置は、吸着床内での
個々の吸着剤粒子の位置が固定されやすく、長期間の連
続運転の際にも安定して吸着剤の性能が維持できる優れ
た効果を奏する。INDUSTRIAL APPLICABILITY The oxygen concentrator of the present invention is excellent in that the position of each adsorbent particle in the adsorption bed is easily fixed, and the performance of the adsorbent can be stably maintained even during long-term continuous operation. Produce the effect.
【図1】従来の吸着床の模式的例示。FIG. 1 is a schematic illustration of a conventional adsorption bed.
【図2】従来の吸着床の模式的例示。FIG. 2 is a schematic illustration of a conventional adsorption bed.
【図3】本発明の酸素濃縮装置における吸着床の模式的
例示。FIG. 3 is a schematic illustration of an adsorption bed in the oxygen concentrator of the present invention.
1 吸着床 2 圧縮空気入口 3 酸素濃縮空気出口 4 蓋 5 吸着剤押えバネ 6 シールパッキン 7,9 多孔板 8,10 不織布 11 吸着剤 12 吸着剤粒子保持部材 13 吸着剤充填口 14 空かん部 1 Adsorbent Bed 2 Compressed Air Inlet 3 Oxygen Concentrated Air Outlet 4 Lid 5 Adsorbent Holding Spring 6 Seal Packing 7,9 Perforated Plate 8,10 Nonwoven Fabric 11 Adsorbent 12 Adsorbent Particle Holding Member 13 Adsorbent Filling Port 14 Empty Space
Claims (6)
着剤を充填した吸着床と、該吸着床へ圧縮空気を供給す
るためのコンプレッサー手段と、該吸着床からの酸素濃
縮気体を受け取り貯留するためのサージタンク手段と、
酸素濃縮気体を使用に供するための酸素濃縮気体供給手
段を具備した圧力変動吸着型酸素濃縮器において、該吸
着床が、吸着剤充填部の上端部及び下端部に空気の流れ
を整流させるための多孔板を具備し、且つ吸着剤充填部
の中間部に吸着剤粒子の混合を防止するため吸着剤粒子
保持部材を具備し、さらに上端部及び下端部の多孔板の
一方に該多孔板を吸着剤側に押しつけられた状態に保持
するためのバネ手段を具備したことを特徴とする酸素濃
縮装置。1. An adsorption bed filled with an adsorbent capable of selectively adsorbing nitrogen over oxygen, a compressor means for supplying compressed air to the adsorption bed, and an oxygen-enriched gas from the adsorption bed. Surge tank means for storing,
In a pressure fluctuation adsorption type oxygen concentrator equipped with an oxygen-concentrated gas supply means for providing an oxygen-concentrated gas for use, the adsorption bed is for rectifying the flow of air to the upper end and the lower end of the adsorbent filling section. A perforated plate is provided, and an adsorbent particle holding member is provided in the middle part of the adsorbent-filled portion to prevent adsorbent particles from mixing, and the perforated plate is adsorbed on one of the upper and lower end perforated plates. An oxygen concentrator, comprising spring means for holding the agent in a pressed state.
ー手段が吸着床へ圧縮空気を供給する際にはコンプレッ
サーとして機能し、吸着床の脱着工程時には真空ポンプ
として機能するようにしたものである請求項1の酸素濃
縮装置。2. A single adsorbent bed, wherein the compressor means functions as a compressor when supplying compressed air to the adsorbent bed, and as a vacuum pump during the desorption process of the adsorbent bed. An oxygen concentrator according to claim 1.
気の流れに対して実質上垂直に位置し、実質上吸着床内
の空気の流動抵抗とならないものであって、吸着剤の充
填部を2〜4領域に分割するようにしたものである請求
項1又は2の酸素濃縮装置。3. The adsorbent particle holding member is positioned substantially perpendicular to the flow of air in the adsorbent bed and does not substantially cause flow resistance of the air in the adsorbent bed, The oxygen concentrator according to claim 1 or 2, wherein the filling portion is divided into 2 to 4 regions.
少なくとも酸素を吸着し得る吸着剤が充填されており、
該吸着床からの酸素濃縮気体が該サージタンク手段に流
入するための流入導管手段が該サージタンク手段におけ
る吸着剤非充填領域において開口しており、該サージタ
ンク手段から酸素濃縮気体が流出するための流出導管手
段が該サージタンク手段の吸着剤充填領域において開口
しており、該流出導管手段が逆流防止弁手段を介して製
品タンク手段に連結されており、該製品タンク手段に該
酸素濃縮気体供給手段が連結されている請求項1〜3の
いずれかの酸素濃縮装置。4. A part of the internal space of the surge tank means is filled with an adsorbent capable of adsorbing at least oxygen,
Inflow conduit means for the oxygen enriched gas from the adsorbent bed to enter the surge tank means is open in the adsorbent unfilled region of the surge tank means, and the oxygen enriched gas flows out of the surge tank means. Outflow conduit means open in the adsorbent fill region of the surge tank means, the outflow conduit means being connected to the product tank means via a check valve means, the product tank means containing the oxygen enriched gas. The oxygen concentrator according to any one of claims 1 to 3, wherein a supply means is connected.
縮気体が吸着床に逆流する工程が圧力変動吸着工程に含
まれるものである請求項1の酸素濃縮装置。5. The oxygen concentrator according to claim 1, wherein the step of reversely flowing the oxygen-enriched gas stored in the surge tank means to the adsorption bed is included in the pressure fluctuation adsorption step.
の下方に位置しており、該吸着剤充填領域における該流
出導管手段の開口部が該吸着剤充填領域内での気体の流
れが該開口部に対して対称となるように下部層の中央部
に位置している請求項1の酸素濃縮装置。6. The adsorbent filling area is located below the surge tank means, and the opening of the outflow conduit means in the adsorbent filling area is such that the flow of gas within the adsorbent filling area is The oxygen concentrator according to claim 1, wherein the oxygen concentrator is located in the center of the lower layer so as to be symmetrical with respect to the opening.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP10816393A JP2915245B2 (en) | 1993-05-10 | 1993-05-10 | Oxygen concentrator |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP10816393A JP2915245B2 (en) | 1993-05-10 | 1993-05-10 | Oxygen concentrator |
Publications (2)
Publication Number | Publication Date |
---|---|
JPH06315534A true JPH06315534A (en) | 1994-11-15 |
JP2915245B2 JP2915245B2 (en) | 1999-07-05 |
Family
ID=14477573
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP10816393A Expired - Lifetime JP2915245B2 (en) | 1993-05-10 | 1993-05-10 | Oxygen concentrator |
Country Status (1)
Country | Link |
---|---|
JP (1) | JP2915245B2 (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AU756159B2 (en) * | 1998-05-30 | 2003-01-02 | Samsung Electronics Co., Ltd. | Device and method for generating and distributing coded symbols in CDMA communication system |
JP2007111298A (en) * | 2005-10-21 | 2007-05-10 | Ngk Spark Plug Co Ltd | Oxygen concentrating apparatus |
-
1993
- 1993-05-10 JP JP10816393A patent/JP2915245B2/en not_active Expired - Lifetime
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AU756159B2 (en) * | 1998-05-30 | 2003-01-02 | Samsung Electronics Co., Ltd. | Device and method for generating and distributing coded symbols in CDMA communication system |
JP2007111298A (en) * | 2005-10-21 | 2007-05-10 | Ngk Spark Plug Co Ltd | Oxygen concentrating apparatus |
Also Published As
Publication number | Publication date |
---|---|
JP2915245B2 (en) | 1999-07-05 |
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