JPH0631370B2 - Lubricity-imparting coating agent - Google Patents
Lubricity-imparting coating agentInfo
- Publication number
- JPH0631370B2 JPH0631370B2 JP60119675A JP11967585A JPH0631370B2 JP H0631370 B2 JPH0631370 B2 JP H0631370B2 JP 60119675 A JP60119675 A JP 60119675A JP 11967585 A JP11967585 A JP 11967585A JP H0631370 B2 JPH0631370 B2 JP H0631370B2
- Authority
- JP
- Japan
- Prior art keywords
- group
- lubricity
- coating agent
- fine particles
- resin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
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- Lubricants (AREA)
Description
【発明の詳細な説明】 （産業上の利用分野） 本発明は、金属、ゴム、プラスチツク、ガラス、皮革、
紙など基材に塗布し、基材に潤滑性を付与するための被
覆剤に関するものである。DETAILED DESCRIPTION OF THE INVENTION (Industrial field of application) The present invention relates to metal, rubber, plastic, glass, leather,
The present invention relates to a coating agent applied to a base material such as paper to impart lubricity to the base material.
（従来の技術） 各種基材から製造される製品、特にシートやフイルム
は、一般に流れ作業により製造されることが多く、製造
行程中のトラブルの原因として潤滑性の欠如が指摘され
ている。また、製品の保存や使用時におけるブロツキン
グ擦り疵の発生も潤滑性の欠如によるところが大きい。
したがつて、基材に潤滑性を付与するための試みとし
て、基材に各種球形微粒子を配合したり、基材の上に油
や潤滑性塗料などの被膜を形成することが広く行われて
いる。(Prior Art) Products manufactured from various base materials, particularly sheets and films, are often manufactured by flow work in general, and it is pointed out that lack of lubricity is a cause of trouble during the manufacturing process. In addition, the occurrence of blocking scratches during product storage and use is largely due to lack of lubricity.
Therefore, as an attempt to impart lubricity to the base material, it has been widely practiced to mix various spherical fine particles into the base material or to form a film such as oil or lubricating paint on the base material. There is.
従来、被膜に潤滑性を付与するための添加剤として二硫
化モリブデン、グラフアイト等の無機質系滑剤やパラフ
イン、金属石けん、ポリエチレン粒子、ポリテトラフル
オロエチレン粒子等の有機質系滑剤が配合されている。
しかし、無機質系滑剤の場合には着色や分散性等に問題
があり、前記有機質系滑剤の場合には耐溶剤性や被膜形
成樹脂との密着性等に問題があり、いずれの場合にも欠
点のあるものであつた。Conventionally, inorganic lubricants such as molybdenum disulfide and graphite, and organic lubricants such as paraffin, metallic soap, polyethylene particles and polytetrafluoroethylene particles have been blended as additives for imparting lubricity to the coating.
However, in the case of an inorganic lubricant, there is a problem in coloring and dispersibility, and in the case of the above organic lubricant, there is a problem in solvent resistance and adhesion to a film-forming resin, and in any case there are drawbacks. It was something with.
また、本発明者は、特開昭５７−125247号においてベン
ゾグアナミン・ホルムアルデヒド樹脂またはベンゾグア
ナミン・メラミン・ホルムアルデヒド樹脂の硬化球形微
粒子を配合するポリエステルフイルムの滑り性改良方法
を開示しているが、これはポリエステル基材に配合して
基材そのものに潤滑性を付与するものであり、より簡便
な方法でしかも他の基材にも応用できる潤滑性付与方法
が望まれるところであつた。The inventor of the present invention discloses in JP-A-57-125247 a method for improving the slipperiness of a polyester film which contains hardened spherical fine particles of a benzoguanamine / formaldehyde resin or a benzoguanamine / melamine / formaldehyde resin. Since it is added to the base material to impart lubricity to the base material itself, there is a need for a lubricity imparting method that is simpler and can be applied to other base materials.
一方、特開昭５９−204670号にはスチレンおよび／また
はメタクリル酸メチルを主体とする架橋球状微小重合体
を配合せしめてなる塗料組成物が開示されているが、金
属など比較的高温で処理される基材の場合耐熱性に問題
があり、また耐溶剤性も充分とは言い難いものであつ
た。したがつて、基材の処理条件や被覆剤中の溶剤など
の影響を無視しては、優れた潤滑性の得られないもので
あつた。On the other hand, Japanese Patent Application Laid-Open No. 59-204670 discloses a coating composition containing a crosslinked spherical micropolymer mainly containing styrene and / or methyl methacrylate, which is treated at a relatively high temperature such as metal. In the case of the base material, there was a problem in heat resistance and it was difficult to say that the solvent resistance was sufficient. Therefore, if the effects of the processing conditions of the base material and the solvent in the coating material are ignored, excellent lubricity cannot be obtained.
（発明が解決しようとする問題点） 本発明は、このような従来技術の欠点を改良するもので
あり、耐熱性、耐溶剤性ともにより優れた潤滑性付与被
覆剤を提供するものである。(Problems to be Solved by the Invention) The present invention solves the above-mentioned drawbacks of the prior art, and provides a lubricity-imparting coating agent having more excellent heat resistance and solvent resistance.
（問題点を解決するための手段および作用） 即ち、本発明は一般式 （但し式中、R1は水素原子、アルキル基、アリール基、
ヒドロキシル基、メルカプト基、複素環基または-NR4R5
（R4とR5とはそれぞれ独立に水素原子、低級アルキル
基、アリール基または低級アルケニル基である。）を示
し、R2とR3とはそれぞれ独立に水素原子、低級アルキル
基、アリール基または低級アルケニル基を示す。）で表
わされるアミノトリアジン化合物(A)を主成分とするア
ミノ基含有化合物とアルデヒドとの縮合反応によつて得
られるアミノ樹脂からなる平均粒子径が0.1〜５０μの
硬化球形微粒子を、被覆剤固形分中0.1〜５０重量％の
範囲の割合で含んでなる潤滑性付与被覆剤に関するもの
である。(Means and Actions for Solving Problems) That is, the present invention provides a general formula (In the formula, R 1 represents a hydrogen atom, an alkyl group, an aryl group,
Hydroxyl group, mercapto group, heterocyclic group or -NR 4 R 5
(R 4 and R 5 are each independently a hydrogen atom, a lower alkyl group, an aryl group or a lower alkenyl group.), And R 2 and R 3 are each independently a hydrogen atom, a lower alkyl group, an aryl group. Alternatively, it represents a lower alkenyl group. ) The cured spherical fine particles having an average particle size of 0.1 to 50 μm and made of an amino resin obtained by a condensation reaction of an amino group-containing compound having an aminotriazine compound (A) as a main component with an aldehyde are coated with a solid coating agent. The present invention relates to a lubricity-imparting coating agent which is contained in a proportion of 0.1 to 50% by weight per minute.
アミノトリアジン化合物(A)は前記一般式で表わされる
化合物であり、例えばメラミン、置換メラミン、ベンゾ
グアナミン、置換ベンゾグアナミン、アセトグアナミ
ン、置換アセトグアナミン等を挙げることができる。中
でもメラミン、ベンゾグアナミンが工業的に安価に入手
しやすいので特に有用である。The aminotriazine compound (A) is a compound represented by the above general formula, and examples thereof include melamine, substituted melamine, benzoguanamine, substituted benzoguanamine, acetoguanamine, and substituted acetoguanamine. Among them, melamine and benzoguanamine are particularly useful because they are industrially easily available at low cost.
本発明に用いられる硬化球形微粒子は、アミノトリアジ
ン化合物(A)を主成分とするアミノ基含有化合物とアル
デヒドとの縮合反応によつて得られるアミノ樹脂からな
るものであり、公知の製造方法により得ることができ
る。このような製造方法としては、例えば特公昭５６−
42614号、特開昭５２−16594号および特開昭５２−5149
3号に開示の方法を挙げることができ、これらに開示さ
れている方法に基づけば、耐熱性および耐溶剤性に優
れ、粒子径がほぼ均一であり、且つ任意の粒子径の硬化
球形微粒子が得られる。The hardened spherical fine particles used in the present invention are composed of an amino resin obtained by a condensation reaction of an amino group-containing compound containing an aminotriazine compound (A) as a main component and an aldehyde, and obtained by a known production method. be able to. As such a manufacturing method, for example, Japanese Patent Publication No. 56-
42614, JP-A-52-16594 and JP-A-52-5149.
The method disclosed in No. 3 can be mentioned, based on the methods disclosed therein, excellent heat resistance and solvent resistance, the particle size is almost uniform, and cured spherical fine particles of any particle size can get.
アミノ樹脂を得るに際して用いられるアミノ基含有化合
物は、前記アミノトリアジン化合物(A)を主成分とする
ものであるが、アミノトリアジン化合物(A)と共縮合し
得るアミノ基含有化合物例えば尿素、アニリン、パラト
ルエンスルホンアミドなどを併用しても良い。また、ア
ルデヒドとしては例えばホルムアルデヒド、パラホルム
アルデヒド、アセトアルデヒドなどを挙げることができ
る。更に、アルデヒドと縮合し得るフエノールをアミノ
基含有化合物と併用することも自由である。縮合反応
は、硫酸などの無機酸やパラトルエンスルホン酸などの
有機酸の酸触媒を使用する公知の方法によつて行うこと
ができる。The amino group-containing compound used in obtaining the amino resin is a compound whose main component is the aminotriazine compound (A), but an amino group-containing compound that can be co-condensed with the aminotriazine compound (A), such as urea or aniline, You may use paratoluene sulfonamide etc. together. Examples of the aldehyde include formaldehyde, paraformaldehyde, acetaldehyde and the like. Furthermore, it is also possible to use a phenol capable of condensing with an aldehyde together with an amino group-containing compound. The condensation reaction can be carried out by a known method using an acid catalyst of an inorganic acid such as sulfuric acid or an organic acid such as paratoluenesulfonic acid.
本発明に用いられる硬化球形微粒子の平均粒子径は0.1
〜５０μの範囲である。平均粒子径が0.1μより小さい
と潤滑性付与効果が不充分であり、また５０μを超える
と該微粒子の分散性等に問題が生じ易くなる。The average particle size of the cured spherical fine particles used in the present invention is 0.1
It is in the range of up to 50μ. If the average particle size is less than 0.1 μm, the effect of imparting lubricity is insufficient, and if it exceeds 50 μm, problems tend to occur in the dispersibility of the fine particles.
本発明の潤滑性付与被覆剤は、前記の硬化球形微粒子を
被覆剤中に配合してなるものであり、該硬化球形微粒子
の配合量は被覆剤固形分中0.1〜５０重量％の範囲の割
合となる量である。該微粒子の配合量が0.1重量％より
も少なければ潤滑性付与硬化が不充分であり、また５０
重量％を超える多量では被膜の可とう性が低下し被覆の
ひび、割れ等の問題を引き起こし易く、いずれも好まし
くない。The lubricity-imparting coating material of the present invention is prepared by blending the above-mentioned cured spherical fine particles in the coating material, and the blending amount of the cured spherical particulates is in the range of 0.1 to 50% by weight in the solid content of the coating material. Is the amount. If the content of the fine particles is less than 0.1% by weight, the lubricity-imparting and curing will be insufficient.
When the amount is more than 10% by weight, the flexibility of the coating is lowered and the coating tends to be cracked or cracked, which is not preferable.
本発明の潤滑性付与被覆剤は、前記の硬化球形微粒子を
特定量含んでなるものであるが、該硬化球形微粒子以外
の主な構成成分としては、皮膜形成性樹脂および水もし
くは有機溶媒からなる希釈剤がある。一般には、皮膜形
成性樹脂水溶液もしくは有機溶剤溶液または皮膜形成性
樹脂エマルシヨンに該硬化球形微粒子を混合し、充分に
分散させることにより、本発明の潤滑性付与被覆剤を調
製することができる。皮膜形成性樹脂としては、アクリ
ル系、アルキド系、ウレタン系、ビニル系、エポキシ
系、オレフイン系、ケイ素系などの種々の樹脂を使用す
ることができるが、特にアクリル系、アルキド系あるい
はウレタン系樹脂が好ましい。The lubricity-imparting coating agent of the present invention contains the above-mentioned cured spherical fine particles in a specific amount, and the main constituents other than the cured spherical fine particles are a film-forming resin and water or an organic solvent. There is a diluent. Generally, the lubricity-imparting coating agent of the present invention can be prepared by mixing the cured spherical fine particles with an aqueous solution of a film-forming resin or an organic solvent solution or emulsion of a film-forming resin and sufficiently dispersing them. As the film-forming resin, various resins such as acryl-based, alkyd-based, urethane-based, vinyl-based, epoxy-based, olefin-based, and silicon-based resins can be used, but particularly acrylic-based, alkyd-based or urethane-based resins. Is preferred.
また、本発明の潤滑性付与被覆剤は、目的および用途に
応じて、顔料、レベリング剤、消泡剤、防腐剤等各種の
添加剤を混合して使用することができる。Further, the coating agent for imparting lubricity of the present invention can be used by mixing various additives such as pigments, leveling agents, defoaming agents and antiseptics depending on the purpose and application.
（発明の効果） 本発明の潤滑性付与被覆剤は、金属、ゴム、プラスチツ
ク、ガラス、皮革、紙などの基材に塗布することによ
り、それら基材の摩擦係数を下げ、摺動抵抗の少ない潤
滑性のある表面を形成し、基材の加工性、耐擦傷性を向
上するものであり、基材に対する密着性にも優れ、作業
性や経済性にも優れたものである。(Effect of the invention) The coating agent for imparting lubricity of the present invention reduces the friction coefficient of the base material by applying it to the base material such as metal, rubber, plastic, glass, leather, and paper, and has a small sliding resistance. It forms a lubricious surface and improves the workability and scratch resistance of the base material. It also has excellent adhesion to the base material and excellent workability and economy.
以下、実施例により本発明を更に具体的に説明するが、
これらにより本発明は何ら限定を受けるものではない。Hereinafter, the present invention will be described in more detail with reference to Examples.
The present invention is not limited to these.
なお、例中の部および％は特にことわりのない限りそれ
ぞれ重量部および重量％を示すものとする。In the examples, parts and% represent parts by weight and% by weight, respectively, unless otherwise specified.
実施例１〜３ 平均粒子径２μのベンゾグアナミン・ホルムアルデヒド
樹脂製硬化球形微粒子（商品名エポスター Ｍ、日本触
媒化学工業（株）製）を、アクリル系樹脂エマルシヨン
（商品名アクリセツト 210Ｅ、日本触媒化学工業
（株）製、固形分４９％）アルキド系樹脂（商品名アロ
プラツツ 1085、日本触媒化学工業（株）製、固形分５
０％）およびウレタン系樹脂（商品名アロタン 171、
日本触媒化学工業（株）製、固形分４２％）のそれぞれ
に対し、それぞれの樹脂固形分１００部あたり第１表に
示す量添加し、約２mmガラスビーズ入り容器中に密ぺい
してペイントシエーカーで５分間混合、分散して潤滑性
付与被覆剤を得た。それぞれの潤滑性付与被覆剤を電気
亜鉛メツキ鋼板に乾燥膜厚が約３μになるように塗布乾
燥した。得られた被覆剤処理鋼板のそれぞれについて被
膜同志間の静摩擦係数を測定し、その結果を第１表に示
す。Examples 1 to 3 Benzoguanamine formaldehyde having an average particle diameter of 2 μ
Resin-cured spherical fine particles (brand name: Eposter M, Japanese touch
Made by Mecha Chemical Industry Co., Ltd., acrylic resin emulsion
(Product name Acryset 210E, Nippon Shokubai Chemical Industry
Co., Ltd., solid content 49%) Alkyd resin (trade name Aro
Platz 1085, manufactured by Nippon Shokubai Chemical Co., Ltd., solid content 5
0%) and urethane resin (trade name Arotane) 171,
Made by Nippon Shokubai Chemical Co., Ltd., solid content 42%)
In contrast, in Table 1 per 100 parts of each resin solid content
Add the indicated amount and seal in a container containing about 2 mm glass beads.
Then mix with paint shaker for 5 minutes, disperse and lubricity
An applied coating was obtained. Each lubricity-imparting coating is electrically
Apply it to a zinc plated steel sheet so that the dry film thickness is approximately 3μ and dry.
Dried For each of the obtained coated steel sheets,
The static coefficient of friction between the membranes was measured and the results are shown in Table 1.
You
比較例１〜３ 実施例１〜３における硬化球形微粒子を使用しない以外
は、実施例１〜３と全く同様にしてアクリル系樹脂、ア
ルキド系樹脂またはウレタン系樹脂のみからなる被覆剤
で処理された鋼板を作成し、それらのそれぞれについて
被膜同志間の静摩擦係数を測定した。その結果を第１表
に示すが、本発明の硬化球形微粒子の配合された潤滑性
付与被覆剤で処理されたものに比較して、潤滑性が劣つ
ていた。Comparative Examples 1 to 3 Treated with a coating agent consisting of an acrylic resin, an alkyd resin or a urethane resin alone in exactly the same manner as in Examples 1 to 3 except that the cured spherical fine particles in Examples 1 to 3 were not used. Steel plates were prepared and the coefficient of static friction between the coating films was measured for each of them. The results are shown in Table 1, and the lubricity was inferior as compared with those treated with the lubricity-imparting coating agent containing the cured spherical fine particles of the invention.
実施例４〜６ 攪拌機、還流冷却器、温度計を備えた四つ口フラスコに
ベンゾグアナミン１２０部、メラミン３０部、ホルマリ
ン（ホルムアルデヒド分３７％）１６２部および１０％
炭酸ナトリウム水溶液0.65部を仕込み、攪拌しながら９
５℃に昇温し、４時間反応させて樹脂液を得た。Examples 4 to 6 In a four-necked flask equipped with a stirrer, a reflux condenser, and a thermometer, 120 parts of benzoguanamine, 30 parts of melamine, 162 parts and 10% of formalin (formaldehyde content 37%).
Charge 0.65 parts of sodium carbonate aqueous solution and stir 9
The temperature was raised to 5 ° C and the reaction was carried out for 4 hours to obtain a resin liquid.
別にポリビニルアルコール（商品名クラレポバール１１
７、（株）クラレ製）8.5部を水６００部に溶解させて
おき、この水溶液を８５℃に昇温し、ホモミキサーを用
い3000rpmで攪拌した。攪拌下にあるポリビニルアルコ
ール水溶液に上記樹脂液を投入し白色の乳化物を得た。
この乳化物を４０℃に冷却し、ドデシルベンゼンスルホ
ン酸３部を加え、錨型攪拌機でゆるやかに攪拌しながら
５０℃で1.5時間保ち、ついで６０℃で、７０℃および
９０℃の温度にそれぞれ２時間ずつ保つて硬化させ、ベ
ンゾグアナミン・メラミン・ホルムアルデヒド樹脂製硬
化球形微粒子の懸濁液を得た。Separately, polyvinyl alcohol (trade name Kuraray Poval 11
8.5 parts of No. 7, manufactured by Kuraray Co., Ltd. were dissolved in 600 parts of water, the temperature of this aqueous solution was raised to 85 ° C., and the mixture was stirred at 3000 rpm using a homomixer. The above resin solution was added to a polyvinyl alcohol aqueous solution under stirring to obtain a white emulsion.
This emulsion was cooled to 40 ° C, 3 parts of dodecylbenzenesulfonic acid was added, and the mixture was kept at 50 ° C for 1.5 hours while gently stirring with an anchor type stirrer, then at 60 ° C, 70 ° C and 90 ° C respectively. The mixture was maintained for each hour for curing to obtain a suspension of cured spherical fine particles made of a benzoguanamine / melamine / formaldehyde resin.
懸濁液から硬化球形微粒子を別水洗し、８０℃で２時
間ついで１４０℃で３時間乾燥後、粉砕して、平均粒子
径８μのベンゾグアナミン・メラミン・ホルムアルデヒ
ド樹脂製硬化球形微粒子（以下、硬化球形微粒子（Ｉ）
という。）を得た。得られた硬化球形微粒子（Ｉ）を実
施例１〜３で用いたのと同じアクリル系樹脂、アルキド
系樹脂およびウレタン系樹脂のそれぞれに対しそれぞれ
の樹脂固形分１００部あたり第１表に示す量添加し、混
合分散して潤滑性付与被覆剤を得た。得られたそれぞれ
の潤滑性付与被覆剤を用いて、実施例１〜３と同様にし
て、乾燥膜厚約２０μになるように塗布された被覆剤処
理鋼板を作成し、それらの被膜同志間の静摩擦係数を測
定した。その結果を第１表に示す。Hardened spherical fine particles are separately washed with water from the suspension, dried at 80 ° C. for 2 hours and then at 140 ° C. for 3 hours, and then pulverized to obtain a cured spherical fine particle made of benzoguanamine / melamine / formaldehyde resin having an average particle diameter of 8 μ (hereinafter, cured spherical Fine particles (I)
Say. ) Got. The amount of the obtained cured spherical fine particles (I) shown in Table 1 per 100 parts of each resin solid content for each of the same acrylic resin, alkyd resin and urethane resin as used in Examples 1 to 3. The mixture was added, mixed and dispersed to obtain a lubricity imparting coating material. Using each of the obtained lubricity-imparting coating agents, a coating agent-treated steel sheet was applied in the same manner as in Examples 1 to 3 so as to have a dry film thickness of about 20 μm, and the coating layers were coated with each other. The static friction coefficient was measured. The results are shown in Table 1.
実施例７ 実施例３におけるエポスター Ｍとウレタン系樹脂（商
品名アロタン 171、日本触媒化学工業（株）製）との
混合、分散を行うに際し、ペイントシエーカー運動時間
を５分間から３０分間に延長した他は、実施例３と全く
同様にして潤滑性付与被覆剤を得た。得られた潤滑性付
与被覆剤を用いて、実施例３と同様にして静摩擦係数を
測定した結果、実施例３における静摩擦係数と同じ0.22
であり、ウレタン系樹脂中の溶剤（キシレンおよびセロ
ソルブアセテート）の影響を全く受けないことがわかつ
た。 Example 7 Eposter in Example 3 M and urethane resin (quote
Product name Arotan 171, with Nippon Shokubai Chemical Industry Co., Ltd.
Paint shaker movement time when mixing and dispersing
Was extended from 5 minutes to 30 minutes.
A lubricity-imparting coating material was obtained in the same manner. With the obtained lubricity
Using a coating agent, the coefficient of static friction was determined in the same manner as in Example 3.
As a result of measurement, 0.22, which is the same as the coefficient of static friction in Example 3.
And the solvent in the urethane resin (xylene and cellulosic
I was not affected by (solve acetate) at all.
It was
───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.5 識別記号 庁内整理番号 ＦＩ 技術表示箇所 Ｃ１０Ｎ 20:00 Ａ 8217−4Ｈ 20:06 Ｚ 8217−4Ｈ 30:06 ─────────────────────────────────────────────────── ─── Continuation of the front page (51) Int.Cl. 5 Identification number Office reference number FI technical display location C10N 20:00 A 8217-4H 20:06 Z 8217-4H 30:06
Claims (2)
ヒドロキシル基、メルカプト基、複素環基または-NR4R5
（R4とR5とはそれぞれ独立に水素原子、低級アルキル
基、アリール基または低級アルケニル基である。）を示
し、R2とR3とはそれぞれ独立に水素原子、低級アルキル
基、アリール基または低級アルケニル基を示す。）で表
わされるアミノトリアジン化合物(A)を主成分とするア
ミノ基含有化合物とアルデヒドとの縮合反応によつて得
られるアミノ樹脂からなる平均粒子径が0.1〜５０μの
硬化球形微粒子を、被覆剤固形分中0.1〜５０重量％の
範囲の割合で含んでなる潤滑性付与被覆剤。1. A general formula (In the formula, R 1 represents a hydrogen atom, an alkyl group, an aryl group,
Hydroxyl group, mercapto group, heterocyclic group or -NR 4 R 5
(R 4 and R 5 are each independently a hydrogen atom, a lower alkyl group, an aryl group or a lower alkenyl group.), And R 2 and R 3 are each independently a hydrogen atom, a lower alkyl group, an aryl group. Alternatively, it represents a lower alkenyl group. ) The cured spherical fine particles having an average particle diameter of 0.1 to 50 μm and made of an amino resin obtained by a condensation reaction of an amino group-containing compound having an aminotriazine compound (A) as a main component with an aldehyde are coated with a solid coating agent. A lubricity-imparting coating material comprising a proportion of 0.1 to 50% by weight per minute.
よび／またはベンゾグアナミンである特許請求の範囲第
１項記載の潤滑性付与被覆剤。2. The lubricity imparting coating agent according to claim 1, wherein the aminotriazine compound (A) is melamine and / or benzoguanamine.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP60119675A JPH0631370B2 (en) | 1985-06-04 | 1985-06-04 | Lubricity-imparting coating agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP60119675A JPH0631370B2 (en) | 1985-06-04 | 1985-06-04 | Lubricity-imparting coating agent |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS61278594A JPS61278594A (en) | 1986-12-09 |
| JPH0631370B2 true JPH0631370B2 (en) | 1994-04-27 |
Family
ID=14767266
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP60119675A Expired - Fee Related JPH0631370B2 (en) | 1985-06-04 | 1985-06-04 | Lubricity-imparting coating agent |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0631370B2 (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112996887B (en) * | 2019-01-11 | 2022-11-18 | Nok克鲁勃株式会社 | Composition for sliding member and sliding member |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5216594A (en) * | 1975-07-30 | 1977-02-07 | Nippon Shokubai Kagaku Kogyo Co Ltd | Process for preparing finely powdered colored resin with improved disp ersibility |
| JPS5642614A (en) * | 1979-09-13 | 1981-04-20 | Fukubi Kagaku Kogyo Kk | Method of molding expanded graphite |
| JPS5765795A (en) * | 1980-10-08 | 1982-04-21 | Nippon Steel Corp | Lubricated metallic plate having excellent ddep drawability |
| JPS582393A (en) * | 1981-06-29 | 1983-01-07 | Seiko Epson Corp | Precise sliding part |
-
1985
- 1985-06-04 JP JP60119675A patent/JPH0631370B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| JPS61278594A (en) | 1986-12-09 |
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