JPH06312903A - Insect harm preventing sheet - Google Patents
Insect harm preventing sheetInfo
- Publication number
- JPH06312903A JPH06312903A JP5123199A JP12319993A JPH06312903A JP H06312903 A JPH06312903 A JP H06312903A JP 5123199 A JP5123199 A JP 5123199A JP 12319993 A JP12319993 A JP 12319993A JP H06312903 A JPH06312903 A JP H06312903A
- Authority
- JP
- Japan
- Prior art keywords
- insect
- oil
- adhesive
- insect repellent
- insecticide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
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- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Description
【０００１】[0001]
【産業上の利用分野】本発明は、虫害を防止するために
殺虫剤、防虫剤、昆虫忌避剤等を基材シートの中間層に
含浸させた虫害防止シートに関するものである。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an insect damage prevention sheet in which an intermediate layer of a base sheet is impregnated with an insecticide, insect repellent, insect repellent or the like for preventing insect damage.
【０００２】[0002]
【従来の技術】室内外における害虫、ダニ等を防止する
ための防虫剤は一般に固形タイプや液状タイプが用いら
れているが、取扱上の不便さを解消するため、虫害防止
シートが利用されるようになっている。2. Description of the Related Art Insect repellents for preventing harmful insects, mites, etc. indoors and outdoors are generally of solid type or liquid type, but insect repellent sheets are used to eliminate inconvenience in handling. It is like this.
【０００３】従来、虫害防止シートとしては、例えば実
開昭６２−６４７０１に示されるような、防虫剤を含浸
せしめた不織布と合成樹脂シートを組み合わせた虫害防
止シート、特開昭５６−７３００９、特開昭６１−１５
１２５８、特開昭６１−１３７８０３等に示されるよう
な防虫剤又はサイクロデキストリン等に担持させた防虫
剤をシート中に練り込んだ形態の虫害防止シート、或は
特開昭５８−２１３７０３、特開昭６２−１０９５７４
等に示されているような２枚の包装材料間の接着層に含
有せしめた虫害防止シート等が知られている。As a conventional insect damage prevention sheet, for example, as disclosed in Japanese Utility Model Laid-Open No. 62-64701, an insect damage prevention sheet in which a nonwoven fabric impregnated with an insecticide and a synthetic resin sheet are combined, is disclosed in Japanese Patent Laid-Open No. 56-73009. Kaisho 61-15
1258, an insect repellent sheet as disclosed in JP-A-61-137803, or an insect repellent supported on cyclodextrin, which is kneaded into a sheet, or JP-A-58-213703, JP-A-58-213703. 62-109574
There is known an insect damage prevention sheet or the like which is contained in an adhesive layer between two packaging materials as shown in US Pat.
【０００４】[0004]
【発明が解決しようとする課題】しかし、従来の虫害防
止シートは持続性の面が不十分で問題を残していた。即
ち、防虫剤を含浸せしめた紙、不織布等の場合、初期防
虫効果に優れるが、効果が持続しないという問題点があ
った。防虫剤を樹脂に練り込んでフィルム化した場合
は、加工中の熱により防虫剤の大部分が揮散してしまう
ため、必然的に添加量を多くする必要があり、また、添
加量の割には持続性がないと言う問題があった。However, the conventional insect damage-preventing sheet has a problem in that the sustainability is insufficient. That is, in the case of paper, non-woven fabric and the like impregnated with an insect repellent, the initial insect repellent effect is excellent, but there is a problem that the effect does not last. When the insect repellent is kneaded into the resin to form a film, most of the insect repellent is volatilized by the heat during processing, so it is necessary to increase the amount added inevitably. Had the problem of being unsustainable.
【０００５】２枚の包装材料を防虫剤を含有させた接着
剤によりラミネートした虫害防止シートは、接着剤に混
入できる防虫剤量をあまり増加できないため持続性の面
で問題があった。本発明は、上記のような問題点を解決
すべくなされたものであり、その目的とするところは、
持続性の優れた虫害防止シートを提供することにある。The insect damage prevention sheet obtained by laminating two packaging materials with an adhesive containing an insect repellent has a problem in terms of sustainability because the amount of the insect repellent that can be mixed in the adhesive cannot be increased so much. The present invention has been made to solve the above problems, and the purpose thereof is to:
It is to provide an insect damage prevention sheet with excellent sustainability.
【０００６】[0006]
【課題を解決するための手段】上記の目的を達成するた
め、本発明の虫害防止シートは、殺虫剤及び／又は防虫
剤を吸収したアクリル系高吸油性樹脂を含有する粘着剤
を介して、気体状態の殺虫剤または防虫剤を透過する包
装材料と任意の包装材料とを貼合した構成とした。In order to achieve the above object, the insect-damage-preventing sheet of the present invention comprises a pesticide and / or an insect-repellent-absorbing acrylic-based highly oil-absorbing resin-containing pressure-sensitive adhesive. A packaging material which is permeable to the insecticide or insect repellent in a gaseous state and an arbitrary packaging material are bonded together.
【０００７】更に、透油性を有する包装材料を、アクリ
ル系高吸油性樹脂を含有する粘着剤を介して接着するこ
とにより得られた吸油性シートに、透油性を有する包装
材料面より殺虫剤及び／又は防虫剤を高吸油性樹脂に吸
収せしめた構成とすることにより、殺虫剤又は防虫剤に
対する加熱工程を排除し、持続性の向上を図った。Further, an oil-absorbent sheet obtained by adhering an oil-permeable packaging material through a pressure-sensitive adhesive containing an acrylic highly oil-absorbent resin is used as a pesticide and an insecticide from the surface of the oil-permeable packaging material. By adopting a constitution in which the insect repellent is absorbed in the highly oil-absorbent resin, the heating step for the insecticide or insect repellent is eliminated and the sustainability is improved.
【０００８】また、粘着剤がエマルジョン型粘着剤及び
／又は水溶性型粘着剤であり、防虫成分がピレスロイド
系防虫成分、天然又は合成イソチオシアン酸アリルであ
る構成とした。The pressure-sensitive adhesive is an emulsion-type pressure-sensitive adhesive and / or a water-soluble pressure-sensitive adhesive, and the insect repellent component is a pyrethroid insect repellent component or natural or synthetic allyl isothiocyanate.
【０００９】本発明において、上記虫害防止シートは図
１に示すように、気体状態の殺虫剤又は防虫剤を透過す
る包装材料１と、殺虫剤及び／又は防虫剤を吸収させた
高吸油性樹脂を含有した粘着剤２と、任意の包装材料３
より構成される。In the present invention, the insect damage prevention sheet is, as shown in FIG. 1, a packaging material 1 permeable to a gas-state insecticide or insect repellent, and a highly oil-absorbent resin in which the insecticide and / or insect repellent is absorbed. Adhesive containing 2 and optional packaging material 3
It is composed of
【００１０】上記虫害防止シートは、あらかじめ殺虫剤
及び／又は防虫剤を吸収させた高吸油性樹脂をエマルジ
ョン型粘着剤及び／又は水溶性型粘着剤中に分散せしめ
た粘着剤により、気体状態の殺虫剤又は防虫剤を透過す
る包装材料１と、任意の包装材料３を貼合することによ
り得ることができる。The insect-damage-preventing sheet is in a gaseous state by a pressure-sensitive adhesive obtained by dispersing a highly oil-absorbent resin in which an insecticide and / or a repellent has been absorbed in an emulsion-type pressure-sensitive adhesive and / or a water-soluble pressure-sensitive adhesive. It can be obtained by pasting the packaging material 1 which is permeable to an insecticide or insect repellent and the optional packaging material 3.
【００１１】或いは、先ず高吸油性樹脂をエマルジョン
型粘着剤及び／又は水溶性型粘着剤中に分散せしめた粘
着剤により、透油性を有する包装材料面より殺虫剤及び
／又は防虫剤を高吸油性樹脂に吸収せしめることにより
得ることができる。Alternatively, first, an insecticide and / or insect repellent is highly oil-absorbed from the surface of a packaging material having oil permeability by using an adhesive obtained by dispersing a highly oil-absorbent resin in an emulsion-type adhesive and / or a water-soluble adhesive. It can be obtained by allowing the resin to absorb.
【００１２】この場合には、殺虫剤及び／又は防虫剤に
対する加熱工程が排除されるため、さらに持続性の高い
虫害防止シートを得ることが可能である。ここで、殺虫
剤及び／又は防虫剤は、それ単独又は油性溶媒に混合さ
れた形態で、透油性を有する包装材料面上に塗布或いは
スプレーされ、透油性を有する包装材料を透過し、高吸
油性樹脂に移行して吸収される。In this case, since the heating step for the insecticide and / or insect repellent is eliminated, it is possible to obtain a more durable insect damage prevention sheet. Here, the insecticide and / or insect repellent, alone or in a form mixed with an oily solvent, is applied or sprayed on the surface of the packaging material having oil permeability, penetrates the packaging material having oil permeability, and has high oil absorption. It is transferred to the resin and absorbed.
【００１３】上記構成により、多量の殺虫剤及び／又は
防虫剤を虫害防止シート内に封入せしめることが可能と
なる。また、油性溶媒の沸点又は揮発性等を選定するこ
とにより、虫害防止シートの持続性をコントロールする
ことも可能となる。当然、得られた虫害防止シートを更
に防虫成分の透油性を有するフィルムで被覆し、徐放性
をコントロールすることや、高吸油性含有粘着剤層をサ
ンドイッチする包装材料の防虫成分のバリヤー性を選択
することにより、片面からのみ防虫成分が揮散されるよ
うな構成とすることも可能である。With the above structure, a large amount of insecticide and / or insect repellent can be enclosed in the insect damage prevention sheet. Also, by selecting the boiling point or volatility of the oily solvent, it becomes possible to control the durability of the insect damage prevention sheet. Naturally, the insect damage prevention sheet thus obtained is further covered with a film having an oil permeable property of the insect repellent component to control the sustained release property, and the barrier property of the repellent component of the packaging material sandwiching the highly oil-absorbing pressure-sensitive adhesive layer is controlled. It is also possible to adopt a configuration in which the insect repellent component is volatilized from only one surface by selecting it.
【００１４】本発明においては、防虫剤を吸収する樹脂
として自己膨潤型で高い吸油倍率を有する高吸油性樹脂
が使用されている。この高吸油性樹脂はアクリル系のモ
ノマーを主原料とし、親油基を樹脂内に有し、吸油倍率
は重量に対して最大２５倍の吸油性を有するもので、そ
れ自体は既に知られているものである。In the present invention, a self-swelling resin having a high oil absorption capacity and having a high oil absorption is used as the resin for absorbing the insect repellent. This highly oil-absorbent resin has an acrylic monomer as a main raw material, has a lipophilic group in the resin, and has an oil absorption capacity of up to 25 times its weight, and it is already known as such. There is something.
【００１５】この高吸油性樹脂に吸収される物質は種類
も多く脂肪族炭化水素系、芳香族炭化水素系、アルコー
ル系、エーテル系、エステル系、ケトン系、油脂系、長
鎖脂肪酸系、長鎖アミン系鉱物油、動物油、植物油、塩
素系溶剤、各種有機溶剤、各種香料等の吸収が可能であ
る。前記高吸油性樹脂は、好ましくは微細な粒状の形態
で粘着剤中に分散させて使用する。There are many kinds of substances which are absorbed by the highly oil-absorbent resin, and they are aliphatic hydrocarbon type, aromatic hydrocarbon type, alcohol type, ether type, ester type, ketone type, fat and oil type, long chain fatty acid type, and long type fatty acid type. It is possible to absorb chain amine mineral oils, animal oils, vegetable oils, chlorine solvents, various organic solvents, various flavors and the like. The highly oil-absorbent resin is preferably used in the form of fine particles dispersed in an adhesive.
【００１６】そして、粘着剤としては、エマルジョン型
粘着剤及び／又は水溶性型粘着剤を用いることが可能で
ある。エマルジョン型粘着剤としては、例えば、アクリ
ルエマルジョン系、天然ゴムラテックス系、スチレン−
ブタジエンラテックス系の粘着剤を用いることができ
る。As the pressure-sensitive adhesive, an emulsion-type pressure-sensitive adhesive and / or a water-soluble pressure-sensitive adhesive can be used. Examples of emulsion type adhesives include acrylic emulsion type, natural rubber latex type, styrene-
A butadiene latex-based adhesive can be used.
【００１７】また、水溶性粘着剤としては、例えばポリ
ビニルアルコール、ポリビニルピロリドン、ポリアクリ
ルアミド、アクリル酸共重合体、ポリビニルメチルエー
テル、ポリエチレンオキシド、ポリプロピレンオキシ
ド、ポリサッカライド、ポリペプチド等を粘着成分とす
る粘着剤を用いることが可能である。ここで粘着剤とし
て溶剤型粘着剤を用いることは、高吸油性樹脂による溶
剤の吸収が発生するため好ましくない。As the water-soluble pressure-sensitive adhesive, for example, polyvinyl alcohol, polyvinylpyrrolidone, polyacrylamide, acrylic acid copolymer, polyvinyl methyl ether, polyethylene oxide, polypropylene oxide, polysaccharides, polypeptides, etc. are used as adhesive components. Agents can be used. Here, it is not preferable to use a solvent-type pressure-sensitive adhesive as the pressure-sensitive adhesive because the highly oil-absorbent resin causes absorption of the solvent.
【００１８】気体状態の殺虫剤又は防虫剤を透過する包
装材料としては、紙、不織布、有孔加工を施した各種プ
ラスチックフィルム、ポリオレフィンフィルム、塩化ビ
ニルフィルム、或いはそれらの貼合体を使用することが
できる。また、透油性を有する材料としては、紙、不織
布、有孔加工を施した各種プラスチックフィルム、或い
はそれらの貼合体を使用することができる。As the packaging material which is permeable to the insecticide or insect repellent in the gaseous state, paper, non-woven fabric, various plastic films having a perforated finish, polyolefin film, vinyl chloride film, or a laminate thereof is used. it can. In addition, as the material having oil permeability, paper, non-woven fabric, various plastic films having perforations, or a bonded body thereof can be used.
【００１９】粘着剤への高吸油性樹脂の含有量として
は、粘着剤の種類にもよるが、５〜９０重量％が望まし
い。含有量が５％未満となると、防虫成分の保持量が不
足するため、虫害防止シートとした際の持続性が低下す
るため、好ましくない。また、９０重量％を越えると、
基材シートの接着力が低下する。高吸油性樹脂を含有し
た粘着剤の基材シートへの塗布量としては、固形物換算
量で２０〜５００ｇ／ｍ２が望ましい。塗布量が２０ｇ
／ｍ２未満となると防虫成分の保持量が不足し、また塗
布量が５００ｇ／ｍ２を越えても防虫効果が増大せずコ
スト高となる。The content of the highly oil-absorbent resin in the adhesive depends on the kind of the adhesive, but is preferably 5 to 90% by weight. When the content is less than 5%, the amount of the insect repellent component retained is insufficient, and the durability of the insect damage prevention sheet is reduced, which is not preferable. If it exceeds 90% by weight,
The adhesive strength of the base sheet is reduced. The amount of the pressure-sensitive adhesive containing the highly oil-absorbent resin applied to the base sheet is preferably 20 to 500 g / m 2 in terms of solid matter. 20g coating amount
If it is less than / m 2, the amount of the insect repellent component retained becomes insufficient, and even if the coating amount exceeds 500 g / m 2 , the insect repellent effect does not increase and the cost increases.
【００２０】また、防虫成分としては、合成ピレスロイ
ド系、天然又は合成ピレトリン、低毒性有機燐酸殺虫
剤、昆虫忌避剤、天然又は合成イソチオシアン酸アリ
ル、植物精油成分等を始めとして広範囲のものが使用で
きる。上記の中、合成ピレスロイド系の防虫剤として
は、アレスリン、フェノトリン、ペルメトリン、エムペ
ントリン、フタルスリン、フラメトリン、レスメトリ
ン、エキスリン、プロパルトリン、フェンバレラート、
パーメトリン等の１種または２種以上を使用することが
できる。As the insect repellent, a wide variety of insect repellents such as synthetic pyrethroids, natural or synthetic pyrethrins, low-toxic organophosphate insecticides, insect repellents, natural or synthetic allyl isothiocyanate, and plant essential oils can be used. . Among the above, as a synthetic pyrethroid insect repellent, arethrin, phenothrin, permethrin, empentrin, phthalthrin, flamethrin, resmethrin, exulin, propalthrin, fenvalerate,
One kind or two or more kinds such as permethrin can be used.
【００２１】[0021]
【作用】上記のように構成された虫害防止シートにおい
ては、シート内部に大量の防虫成分を封入することがで
き、封入された防虫成分は高吸油性樹脂内より徐々に放
出されるため、高い持続性を付与することができる。In the insect damage prevention sheet constructed as described above, a large amount of insect repellent component can be encapsulated inside the sheet, and the encapsulated insect repellent component is gradually released from the highly oil-absorbent resin, which is high. Persistence can be added.
【００２２】[0022]
【実施例】以下に、実施例に基づいて本発明を詳細に説
明する。アクリル系高吸油性樹脂として、オレオソープ
ＳＬ（（株）日本触媒製）を用いた。これは粒径約３０
０μｍの高吸油性樹脂６０重量部を水に分散させたもの
である。上記オレオソープ５０重量部を下記組成の粘着
剤５０重量部と混合し、高吸油性樹脂含有粘着剤を作製
した。EXAMPLES The present invention will be described in detail below based on examples. As the acrylic oil-absorbent resin, Oleosorb SL (manufactured by Nippon Shokubai Co., Ltd.) was used. This has a particle size of about 30
60 parts by weight of a 0 μm highly oil-absorbent resin is dispersed in water. 50 parts by weight of the oleosope was mixed with 50 parts by weight of an adhesive having the following composition to prepare a highly oil-absorbent resin-containing adhesive.
【００２３】粘着剤組成 アクリル酸 ：１８部 アクリル酸メチル ：２部 水 ：８０部 過硫酸アンモニウム ：０．５部 ポリプロピレングリコール ：２８部 塩化アルミ水溶液（３３％）：３部Adhesive composition Acrylic acid: 18 parts Methyl acrylate: 2 parts Water: 80 parts Ammonium persulfate: 0.5 parts Polypropylene glycol: 28 parts Aluminum chloride aqueous solution (33%): 3 parts
【００２４】上記高吸油性樹脂含有粘着剤をポリエチレ
ンコート紙（紙：２２ｇ／ｍ２、ポリエチレンコート
層：７μｍ）のポリエチレン面に常法によりコートした
後、乾燥し、目付４０ｇ／ｍ２のプロピレン製不織布
（三井石油化学（株）製シンテックスＰＫ１０５）を積
層して吸油性シートを作製した。この吸油性シートの高
吸油性樹脂塗布量は固形物として１００ｇ／ｍ２であっ
た。The above-mentioned highly oil-absorbent resin-containing pressure-sensitive adhesive was coated on the polyethylene surface of polyethylene-coated paper (paper: 22 g / m 2 , polyethylene coat layer: 7 μm) by a conventional method and then dried to give a propylene having a basis weight of 40 g / m 2 . Nonwoven fabric (Syntex PK105, manufactured by Mitsui Petrochemical Co., Ltd.) was laminated to produce an oil-absorbent sheet. The coating amount of the highly oil-absorbent resin of this oil-absorbent sheet was 100 g / m 2 as a solid matter.
【００２５】エムペントリン５重量部とペルメトリン５
重量部をコーン油９０重量部に溶解し、前記吸油性シー
トの不織布面に連続的にスプレーし、固形物換算で１０
０ｇ／ｍ２の割合で吸収させ、１０×１０ｃｍに切断
し、虫害防止シートを作製した。（殺虫剤含量：１０ｇ
／ｍ２）5 parts by weight of empentrin and 5 of permethrin
90 parts by weight of corn oil are dissolved in 90 parts by weight of corn oil, and the nonwoven fabric surface of the oil-absorbent sheet is continuously sprayed to obtain 10 parts by weight of solid matter.
It was absorbed at a rate of 0 g / m 2 and cut into 10 × 10 cm to prepare an insect damage prevention sheet. (Insecticide content: 10g
/ M 2 )
【００２６】（比較例）エムペントリン５重量部とペル
メトリン５重量部を混合し、目付７０ｇ／ｍ２のクラフ
ト紙に吸収させ、１０×１０ｃｍに切断し、虫害防止シ
ートを作製した。（殺虫剤含量：１０ｇ／ｍ２）Comparative Example 5 parts by weight of empentrin and 5 parts by weight of permethrin were mixed, absorbed in kraft paper having a basis weight of 70 g / m 2 and cut into 10 × 10 cm to prepare an insect damage prevention sheet. (Insecticide content: 10 g / m 2 )
【００２７】（実験）上記実施例と比較例で作製した虫
害防止シートを２２℃で１年間保存し、一定期間経過後
に虫害防止能の評価を測定した。測定結果を表１に示
す。虫害防止能の評価については、ノシメコクガの幼虫
５０匹を、内寸で縦２２０×横２６０×高さ２００ｍｍ
の段ボールに入れて、上部、底部をガムテープで密封
し、２２℃で２４時間保存し、生存している幼虫の数に
よって虫害防止能を評価した。(Experiment) The insect damage prevention sheets prepared in the above-mentioned Examples and Comparative Examples were stored at 22 ° C. for 1 year, and the evaluation of insect damage prevention ability was measured after a certain period of time. The measurement results are shown in Table 1. For the evaluation of insect damage prevention ability, 50 larvae of Nobume stag beetle were measured in the inner dimensions of length 220 x width 260 x height 200 mm.
The product was placed in a corrugated cardboard, and the top and bottom were sealed with gum tape and stored at 22 ° C. for 24 hours, and the insect damage prevention ability was evaluated by the number of surviving larvae.
【００２８】[0028]
【表１】 [Table 1]
【００２９】[0029]
【発明の効果】本発明により、取扱が簡便な虫害防止シ
ートを供給することができ、更に高い防虫効果を長期間
に渡って保持することができる。INDUSTRIAL APPLICABILITY According to the present invention, it is possible to supply an insect damage prevention sheet which is easy to handle, and it is possible to maintain a high insect prevention effect for a long period of time.
【図１】本発明による虫害防止シートの模式断面図であ
る。FIG. 1 is a schematic sectional view of an insect damage prevention sheet according to the present invention.
１ 気体状態の殺虫剤または防虫剤を透過する包装材料 ２ 殺虫剤および／または防虫剤を吸収した高吸油性樹
脂 ３ 殺虫剤および／または防虫剤を吸収した高吸油性樹
脂を含有する粘着剤 ４ 任意の包装材料1 Packaging materials that are permeable to insecticides or insect repellents in a gaseous state 2 Highly oil-absorbent resin that has absorbed insecticide and / or insect repellent 3 Adhesive that contains highly oil-absorbent resin that has absorbed insecticide and / or insect repellent 4 Any packaging material
Claims (3)
リル系高吸油性樹脂を含有する粘着剤を介して、気体状
態の殺虫剤または防虫剤を透過する包装材料と任意の包
装材料とを貼合したことを特徴とする虫害防止シート。1. A packaging material which is permeable to a pesticide or insect repellent in a gas state and an arbitrary packaging material through an adhesive containing an acrylic highly oil-absorbent resin which has absorbed the insecticide and / or insect repellent. An insect damage prevention sheet characterized by being stuck together.
剤を介して、透油性材料からなるシートと任意の基材を
貼り合わせ、透油性材料面から防虫剤を高吸油性樹脂に
吸収せしめたことを特徴とする請求項１に記載の虫害防
止シート。2. A sheet made of an oil-permeable material and an arbitrary base material are bonded together via an adhesive containing an acrylic oil-absorbing resin so that the insect-repellent agent is absorbed from the oil-permeable material side. The insect damage prevention sheet according to claim 1, wherein the insect damage prevention sheet is used.
は水溶性型粘着剤であり、防虫成分がピレスロイド系防
虫成分、天然又は合成イソチオシアン酸アリルであるこ
とを特徴とする請求項１に記載の虫害防止シート。3. The adhesive according to claim 1, wherein the adhesive is an emulsion adhesive and / or a water-soluble adhesive, and the insect repellent is a pyrethroid insect repellent, natural or synthetic allyl isothiocyanate. Insect prevention sheet.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP5123199A JPH06312903A (en) | 1993-04-28 | 1993-04-28 | Insect harm preventing sheet |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP5123199A JPH06312903A (en) | 1993-04-28 | 1993-04-28 | Insect harm preventing sheet |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH06312903A true JPH06312903A (en) | 1994-11-08 |
Family
ID=14854651
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP5123199A Withdrawn JPH06312903A (en) | 1993-04-28 | 1993-04-28 | Insect harm preventing sheet |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH06312903A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4334776A1 (en) * | 1992-10-12 | 1994-04-14 | Nsk Ltd | Strengthened sliding seal for linear guide arrangement - has seal with reinforcement having aperture corresponding to mounting end plate, forming gap above guide rail |
| WO2021206021A1 (en) * | 2020-04-06 | 2021-10-14 | ニチバン株式会社 | Agrochemical-containing pressure-sensitive adhesive tape |
-
1993
- 1993-04-28 JP JP5123199A patent/JPH06312903A/en not_active Withdrawn
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4334776A1 (en) * | 1992-10-12 | 1994-04-14 | Nsk Ltd | Strengthened sliding seal for linear guide arrangement - has seal with reinforcement having aperture corresponding to mounting end plate, forming gap above guide rail |
| DE4334776C5 (en) * | 1992-10-12 | 2006-12-14 | Nsk Ltd. | Linear guide device with sliding seal |
| WO2021206021A1 (en) * | 2020-04-06 | 2021-10-14 | ニチバン株式会社 | Agrochemical-containing pressure-sensitive adhesive tape |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A300 | Withdrawal of application because of no request for examination |
Free format text: JAPANESE INTERMEDIATE CODE: A300 Effective date: 20000704 |