JPH06306799A - Antifalsification paper - Google Patents

Abstract

PURPOSE:To obtain antifalsification paper capable of providing only a copy having color tone entirely different from that of an original even when copying is carried with a copier. CONSTITUTION:The antifalsification paper is obtained by unevenly distributing fragments 2 having performance bondable to base paper 1 and brightness in the surface of the base paper in a step for forming the sheet of paper. For example, the paper is produced by forming a metal vapor deposition layer on one or both surfaces of a film having 60-80 deg.C dissolving temperature in hot water, further forming a coating layer composed of a resin or the resin and a colorant thereon, blending the resultant fragments and forming the sheet of paper.

Description

Detailed Description of the Invention

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to anti-counterfeit paper. More specifically, the present invention relates to an anti-counterfeit paper which can obtain only a copy having a color tone completely different from that of an original even when copying by a copying machine.

[0002]

2. Description of the Related Art Recently, the accuracy of copying machines has been remarkably improved, and in particular, the spread of electrophotographic color copying machines facilitates the forgery of various securities. To prevent this, various anti-counterfeiting measures have been considered. One of them is that the present copying machines cannot reproduce a glittering material such as metallic color or interference color. There is something.

For example, as proposed in Japanese Utility Model Laid-Open No. 58-168754, a copy is prepared by providing a bright plate such as aluminum foil having a remarkable metal color tone on the upper surface of a base paper and providing a letter pattern on the surface of the bright plate. There is a proposal for non-copyable paper by machine.
When this is copied, the character pattern applied to the paper surface becomes unreadable because the foil surface is blackened when the light is emitted from the copying machine. Although this paper has the advantage that copying itself is impossible (the copy cannot be read), it has the drawback that the metallic color is overemphasized because it occupies a large area on the bright printing paper, which makes it uncomfortable. Further, there are other problems such that the manufacturing process of the paper becomes complicated, the cost is inevitably increased, and it is difficult to collect the papermaking fibers from the waste paper.

The present inventors have conducted investigations with the objective of solving these problems. The inventors of the present invention changed their minds and paid attention to the fact that even if the image is copied by a color copying machine, it can be judged whether or not it is genuine if it is copied in a hue different from the original.

The inventors of the present invention first divided a silver-colored aluminum vapor-deposited polyester film having excellent glitter into pieces,
We considered making it into paper. Since the paper produced in this manner cannot reproduce a metallic luster feeling by a color copier, it was found that the portion where the strips were mixed was simply copied in black, and the paper had anti-counterfeiting ability. However, it has been found that in the paper manufactured in this manner, the strip does not firmly adhere to the paper, and the strip comes off during printing, which causes a serious problem. Further, this paper has another problem that it is difficult to remove the polyester film constituting the strip, and it is extremely difficult to recover the papermaking fibers from the waste paper or the waste paper.

[0006]

SUMMARY OF THE INVENTION An object of the present invention is to solve the above problems. That is, it is an object to obtain an anti-counterfeit paper which has excellent adhesion between the strip and the sheet even if the strip having the glittering property is ubiquitous on the sheet and does not cause any printing trouble. Another issue is to obtain a paper that does not feel uncomfortable to the eye and to provide the ability to easily collect papermaking fibers from spoiled paper and waste paper.

[0007]

Means for Solving the Problems The inventors of the present invention first prepared fine strips having a glittering property based on various base materials, and advanced them into paper for further study. As a result, the above problems can be solved by using a specific strip, and the present invention has been completed. The present invention will be described with reference to FIG. FIG. 1 is a partially enlarged sectional view of an example of the anti-counterfeit paper of the present invention. The gist of the present invention resides in an anti-counterfeit paper in which glittering strips 2 are ubiquitous on the surface of a base paper 1, and the strips 2 have a capability of adhering to the base paper in a papermaking process. The anti-counterfeit paper is characterized in that

In order to enable the strip 2 to adhere to the base paper in the papermaking process, it has been found that it is preferable to use a film having a hot water melting temperature of 60 to 80 ° C. as one of the components of the strip. . By doing so, the film swells due to the heat when the wet paper is dried in the drying step at the time of paper making, and the film firmly adheres to the paper.

Further, the hot water-soluble film to be used is such that the film is not dissolved or excessively swelled by water at the time of forming the web (wet part), and the wet paper drying zone (multi-cylinder cylinder dryer) during the papermaking process. It has also been found that the above film has this property, and it is necessary that the film does not cause a practically problematic deformation with a Yankee type dryer) and that it has excellent adhesion to the base paper after drying.

Another advantage of using this film is that it is easy to dispose of waste paper or waste paper that is always generated in the printing process of the paper when manufacturing the paper. This is because the film forming the strip can be easily dissolved by heating the water with a beater, pulper or the like and treating the broke or waste paper.

There are various water-soluble films, for example, starch-based, methylcellulose-based, carboxylated methylcellulose-based, hydroxyethylcellulose-based, polyvinyl alcohol (hereinafter referred to as PVA) -based, polyvinylpyrrolidone-based, vinylethyl ether-maleic anhydride copolymerization. Examples of the film include a polyacrylic acid-based film, a polyacrylic acid-based film, and a polyethylene oxide-based film. The film used in the present invention needs to be dissolved in hot water at 60 to 80 ° C., and the above water-soluble polymers contained in this range, functional groups introduced therein, and water-proofing agents are added. Those having a higher melting temperature can be used in combination.

In the present invention, it is preferable to use PVA because it is relatively inexpensive, easily available, and has an adequate physical strength. The solubility of PVA in water is largely governed by the degree of polymerization and the degree of saponification, especially the degree of saponification. For example, water having a saponification degree of 88% or less is completely dissolved even in water at 20 ° C., but about 50% at a saponification degree of 97%.
It can be dissolved in hot water of ℃ at about 80 ℃ for complete saponification. When a film that melts at less than 60 ° C is cut into pieces and cut into paper, the pieces melt or excessively swell in the drying zone of the paper machine, and cannot maintain a predetermined shape. If it dissolves, the slurry should be 8
Since it is extremely difficult and dangerous to set the temperature to 0 ° C. or higher, the melting temperature needs to be in the above range.
The thickness of the hot water-soluble film is usually 5 to 100 μm, preferably 10 to 25 μm.

Next, an example of producing a strip will be described. Example 1 A metal vapor deposition layer of aluminum, tin, zinc, chromium, cobalt, nickel, copper, gold, silver or the like is formed on one side or both sides of a hot water-soluble film as described above by a vacuum vapor deposition method, a sputtering method, an ion plating method. It is formed by a known method such as. The vapor deposition thickness is usually in the range of 200 to 1500 angstroms. In the present invention, it is preferable to use aluminum as the metal because it is inexpensive, does not easily corrode, has an excellent metallic luster, and dissolves easily in an alkali.

Then, a coating layer comprising a resin or a resin and a colorant is formed on the vapor deposition surface. It is desirable to use an organic solvent-based resin because it prevents deformation of the hot water-soluble film and does not impair the coatability. Considering the recovery efficiency of damaged paper, a resin soluble in a hot alkaline aqueous solution is used. Is particularly preferable. As the resin soluble in the hot alkaline aqueous solution, vinyl acetate resin, polyester resin, acrylic resin, polycarbonate resin, polyacetal resin, ionomer resin, nitrocellulose resin, acetylcellulose resin, maleic acid resin , Phenol resin, melamine resin, urea resin, casein resin, shellac resin, etc., or a resin modified by introducing a functional group such as a hydroxyl group or a carboxyl group so as to make them alkali-soluble. Alternatively, a mixture may be used. In the present invention, 60 to 80 are selected from these resins.
It is preferable to select and use one that does not dissolve in hot water in the temperature range of ° C, but dissolves only in hot alkaline water. Alkali concentration is usually 0.01 when recovering pulp from broke
Since it is in the range of 0.5 wt%, it is preferable to use a resin that dissolves in this range.

As the colorant, an organic pigment, an inorganic pigment, a dye or the like can be used. When a colored coating is applied on the vapor-deposited layer, it is preferable to use a dye in order not to reduce the metallic luster.
When no colorant is used, a vapor-deposited metal color, for example aluminum, gives a silver color, and a yellow color gives a gold color. Further, auxiliary agents such as a viscosity adjusting agent and a curing agent may be appropriately used in combination as long as the object of the present invention is not impaired. In some cases, an anchor coating layer and a back surface coating layer are provided, but it is preferable that the resin used for this also be dissolved in a hot alkaline aqueous solution at 60 to 80 ° C., and a colorant and other additives can be used in combination. The coating material thus prepared is applied to the vapor-deposited surface or the film surface, and the coating amount is usually 1
It is set to 10 μm, preferably 2 to 5 μm. The sheet produced in this manner is cut into pieces by the method described later.

Example 2 Use of Transfer Foil As a transfer foil having a glitter, a transfer foil having an interference color and a transfer foil having a metallic color are known. For example, a transfer foil having an interference color is composed of a resin layer (having a release layer and a surface protective layer, for example, a coating layer mainly composed of nitrocellulose), a very thin aluminum vapor deposition layer (light (Semi-transmissive layer), a very thin resin coating layer (interference layer), an aluminum vapor deposition layer (light reflection layer), and a heat-sensitive adhesive layer. As another example, instead of the above-mentioned resin interference layer, an interference layer formed by depositing an inorganic oxide such as SiO ₂ is formed. As another example, a transfer foil using a hologram interference color is known. this is,
A resin layer (which also serves as a release layer and a surface protective layer, for example, a coating layer containing nitrocellulose as a main component) is formed on a polyester base film, a hologram pattern is heat-embossed on the surface, and then an aluminum vapor deposition layer (light Reflective layer), a heat-sensitive adhesive layer formed thereon, and the like.
Using these transfer foils, a heat-sensitive adhesive and a substrate surface, for example, a hot water-soluble film surface, are passed through a heat roll to bond the both, and then cooled, and the polyester base film is peeled off and then cut into pieces. Further, a hot water-soluble film may be further attached to the transfer surface by using, for example, a polyurethane adhesive or the like to be made into pieces. With this structure, the hot water-soluble film surface is located on the outer side of both surfaces, so that there is an advantage that the adhesion to the paper becomes stronger.

Further, the metal transfer foil is, for example, coated on a polyester base film sequentially with a resin layer (having a release layer and a surface protective layer, for example, nitrocellulose as a main component, and a colorant if necessary). Layer), an aluminum vapor deposition layer, and a heat-sensitive adhesive layer. Use this transfer foil,
The heat-sensitive adhesive and the surface of the base material, for example, the surface of a hot water-soluble film, are combined, passed between hot rolls and bonded to each other, and then cooled, and the polyester base film is peeled off and then cut into pieces. Further, a hot water-soluble film may be further attached to the transfer surface by using, for example, a polyurethane adhesive or the like to be made into pieces. With this structure, the hot water-soluble film surface is located on the outer side of both surfaces, so that there is an advantage that the adhesion to the paper becomes stronger.

Example 3 A method in which paper coated with a coating solution prepared by mixing a metal powder or a pearl pigment with a hot water-soluble binder is cut into pieces. 80 to 300 parts by weight of a hot water-soluble binder such as polyvinyl alcohol is usually added to 100 parts by weight of a pearl pigment such as mica or bismuth oxychloride coated with metal powder such as aluminum or brass or titanium oxide to form a paint. It is prepared, and is usually applied to a base paper having a basis weight of 30 to 100 g / m ² and then made into pieces. If you use a strip of pearl pigment that emits an iris color as a pearl pigment, you can see the presence of this strip when you see it, but you can get the effect that a color copying machine cannot reproduce the iris color. . There are various iris colors,
Two or more types of strips that emit different iris colors can be used in combination.

Example 4 A method in which a coating liquid prepared by mixing a metal powder or a pearl pigment with a binder is coated on paper, and a hot water-soluble binder such as PVA is further coated on the surface of the paper to obtain pieces. The strip of this construction has the advantage of better adhesion to the base paper than the strip of Example 3.

Example 5 A method in which hot water-soluble films are attached to both surfaces of a film having a glitter property to form fine pieces. Examples of the film having glittering property include those obtained by vapor-depositing a metal on a polyester film, those obtained by forming a resin layer on a polyester film and embossing a hologram pattern on the surface of the film, and vapor-depositing a metal, by directly embossing a hologram pattern on a vinyl chloride film. Metal vapor deposited, polyester film with very thin metal vapor deposited (semi-transmissive layer of light) and then interference layer,
Any of those having a metal vapor deposition layer (light reflection layer) formed, metal powder coated with an adhesive on a base sheet, and pearl pigment coated with an adhesive on a base sheet can be used. A hot water-soluble film is attached to both surfaces of these glittering films by using a polyurethane-based dry laminating adhesive or the like to make them into pieces.

Example 6 A method of kneading a metal powder or a pearl pigment into a hot water-soluble resin to form a film into pieces. When a leaf-shaped metal powder or a pearl pigment is kneaded, the film is more uniaxially or biaxially stretched to improve the glitter.

In the present invention, the shape of the strip may be any shape such as a circle, an ellipse, a square, a rectangle or a star. As the method, any method such as a method of punching out using a tooth profile having the above-mentioned shape, or a method of slitting with a micro slitter and cutting it into fine pieces can be adopted. The size for fragmentation is usually about 0.2 to 10 mm.

The paper of the present invention comprises bleached softwood kraft pulp (NBKP), bleached hardwood kraft pulp (LBKP),
Softwood bleached sulfite pulp (NBSP), thermomechanical pulp (TMP) and other papermaking pulp are the main constituents of which dry paper strength enhancer, wet strength enhancer, sizing agent, fixing agent, retention improver, drainage improver Freeness of 550
~ 250 ml C.I. S. F. The paper is made using a known paper machine such as a Fourdrinier paper machine or a cylinder paper machine. In the present invention, it is also possible to apply starch, polyvinyl alcohol, various surface sizes, and the like on the paper surface during the papermaking process with a size press device or the like. If necessary, machine calendering treatment or super calendering treatment may be performed to improve the surface smoothness.

When the base paper is made into paper, the strips are inserted so that they are ubiquitous near the surface of the base paper, and this method can employ the following method. 1) Sprinkle the strips on the web on a Fourdrinier or cylinder machine. 2) At the position immediately before or immediately after slicing on the Fourdrinier paper machine, the stock material and water containing strips are blown out from several places in the width direction by nozzles. 3) Sprinkle strips onto the wet paper just before the press roll. 4) Mixing the strips into the coating liquid of the size press machine and coating. By doing so, the strips are ubiquitous near the surface of the base paper. That is, the strips are exposed on the surface of the base paper, and some of the strips dig up near the surface and become ubiquitous near the surface.

The paper web thus formed is dried by being heated in a drying zone of a paper machine such as a cylinder dryer or a Yankee dryer. At the initial stage of drying, since the web contains a large amount of water, hot water also comes into contact with the strips, and the hot water-soluble film or the like swells or dissolves only a small portion thereof and firmly adheres to the paper. In order to impart surface smoothness to the paper, machine calendering treatment or super calendering treatment can be appropriately performed. The anti-counterfeit paper of the present invention is manufactured as described above.

As the strips, several kinds of strips having the same hue or different hues may be used in combination, and strips having the same hue but different tones may be incorporated.

Further, the anti-counterfeit paper of the present invention can be used together with other anti-counterfeit means. For example, see-through, mixed paper with dyed fibers, thread-making, and the like. As a result, the forgery prevention effect can be further enhanced.

[0028]

Example 1 Manufacturing structure of strip 1 500 μm of aluminum metal was vacuum-deposited on a PVA film having a thickness of 25 μm and a hot water dissolution temperature of 80 ° C., and a yellow dye (trade name: Oreosol First Yellow, Sumitomo Chemical The coating composition obtained by adding 15 parts by weight to 100 parts by weight of the alkali-soluble nitrocellulose-based resin was coated (dry thickness). Then, a punching machine was used to produce circular strips having a diameter of 1 mm.

Structure 2 A film having a thickness of 12 μm and a hot water melting temperature of 80 ° C. and a transfer foil (rainbow transfer foil) having an interference color are passed between hot rolls to be bonded, and after cooling, they are used as a base of the transfer foil. A polyester film was removed. Then, a punching machine was used to produce circular strips having a diameter of 1 mm.

Composition 3 : Coated paper having a basis weight of 70 g / m ² has a particle size of 40 μm on both sides.
7 g / m on one side using an air knife coater, using a paint consisting of 100 parts by weight of a pearl pigment of mica powder having a titanium oxide coverage of 28% and 200 parts by weight of polyvinyl alcohol.
^Two coats each. Then 1mm using a punching machine
A rectangular strip of x 1.5 mm was produced.

Structure 4 A coated paper having a basis weight of 70 g / m ² has a particle size of 40 μm on both sides.
Using a paint consisting of 100 parts by weight of a pearl pigment of mica powder having a titanium oxide coverage of 28% and 220 parts by weight of an acrylic emulsion, using an air knife coater, one side is 7 g / m
^Two coats each. Then, a polyvinyl alcohol film having a thickness of 12 μm and a hot water dissolution temperature of 80 ° C. was attached to both surfaces using a polyurethane adhesive. A 1 mm x 1.5 mm rectangular strip was then produced using a punching machine.

Example 1 350 ml of 20 parts by weight of NBKP and 80 parts by weight of LBKP
C. S. F. Beaten to 10 parts by weight of clay, 0.3 parts by weight of paper strengthening agent (trade name "Polystron 191", manufactured by Arakawa Chemical Industry Co., Ltd.), sizing agent (trade name "Size Pine E", Arakawa A chemical was prepared by adding 1.0 part by weight of Chemical Industry Co., Ltd. and an appropriate amount of a sulfuric acid band. Using a Fourdrinier paper machine, a grammage of 110 g / m ² paper was sprinkled immediately after slicing with the strip of the above constitution 1 at the time of papermaking. After that, it was manufactured according to a conventional method (drying was performed with a multi-cylinder cylinder dryer). The obtained anti-counterfeit paper contained an average of 1400 strips per 1 m ² and were ubiquitous on the surface. When copying this paper with a color copier (trade name "Canon Pixel"), the metallic color of the strip (in this case, gold or silver) is not reproduced, and both can be visually judged (manuscript and copy).
The difference was clearly recognized. Even when the offset printing was performed, the falling of the strip was not recognized. 5 parts by weight of the paper thus made, 95 parts by weight of water (that is, pulp concentration 5%), and 0.1 parts by weight of caustic soda were charged into a high-concentration pulper, and rotated while blowing in live steam to raise the temperature to 60 ° C. As a result, the base film, vapor deposition layer, and resin coating layer forming the strip were completely dissolved. The residual dye was finely divided and completely dispersed in the pulp, and even when the recovered pulp was used for papermaking, this effect was not observed at all.

Example 2 Paper was made with the stock formulation of Example 1, and immediately before slicing, the strips of composition 2 were dispersed in water and blown out into the paper by a nozzle (papermaking width 1300 mm, every 10 cm a blowing nozzle. installed). After that, it was manufactured according to a conventional method (drying was performed with a multi-cylinder cylinder dryer). Even when the offset printing was performed, the falling of the strip was not recognized. When this paper was copied with a color copier (trade name "Canon Pixel"), the glittering interference colors of the strips (in this case, red, orange,
Yellow, green, blue, indigo, and purple) were not reproduced, and the difference between the two (manuscript and copy) was clearly recognized by visual judgment. The paper was treated in the same manner as in Example 1, but the papermaking pulp could be easily recovered.

Example 3 Paper was made with the stock formulation of Example 1 and sprinkled with strips of Configuration 3 just before the press rolls on the paper machine. After that, it was manufactured according to a conventional method (drying was performed with a multi-cylinder cylinder dryer).
Unlike the strips of Examples 1 and 2, it was not immediately understood that the obtained sheets were mixed, and by tilting the sheets at an appropriate angle, the irradiation light incident on the strips reflected and entered the eyes. The existence was confirmed for the first time. The paper had very little discomfort due to the inclusion of strips. Even when the offset printing was performed, the falling of the strip was not recognized. When copying this paper with a color copier (trade name "Canon Pixel"), the color of the strip (in this case, pearlescent color) is not reproduced, and the difference between the two (manuscript and copy) is clear by visual judgment. Was recognized by. The paper was treated in the same manner as in Example 1, but the papermaking pulp could be easily recovered.

Example 4 When making a paper with the stock formulation of Example 1 and applying a surface strength improver (PVA) with a size press machine on a paper machine, the strips of composition 4 were mixed in the coating liquid. Coated After that, it was manufactured according to a conventional method (drying was performed with a multi-cylinder cylinder dryer).
It was not immediately understood that the obtained paper was mixed, unlike the strips of Examples 1 and 2, and when the paper was tilted at an appropriate angle, the irradiation light incident on the strip was reflected and entered the eyes for the first time. Its existence was confirmed. The paper had very little discomfort due to the inclusion of strips. Even when the offset printing was performed, the falling of the strip was not recognized. When copying this paper with a color copier (trade name "Canon Pixel"), the color of the strip (in this case, pearlescent color) is not reproduced, and the difference between the two (manuscript and copy) is clear by visual judgment. Was recognized by. The paper was treated in the same manner as in Example 1, but the papermaking pulp could be easily recovered.

[0036]

As described above, the anti-counterfeit paper of the present invention is manufactured, and has the following remarkable effects. 1) Even if an attempt is made to make a copy with a color copying machine, the color of the glittering strips mixed in the paper cannot be reproduced, and therefore it is possible to immediately determine whether the copy is a forged one. In particular, strips using a pearl pigment have an advantage that they do not give a feeling of strangeness due to being mixed. 2) Since the strip is firmly adhered to the paper, there is no problem that the strip comes off during printing. 3) It is possible to manufacture strips that allow easy recovery of papermaking fibers from broke and waste paper. 4) Taking advantage of such characteristics, the anti-counterfeit paper of the present invention is suitably used for check paper, stock paper, bond paper, paper money, gift paper, passport paper, various ticket papers, boarding tickets, and the like.

[Brief description of drawings]

FIG. 1 is a partially enlarged cross-sectional view of a forgery prevention sheet of the present invention.

[Explanation of symbols]

 1 Base paper 2 Strips with glitter

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[Procedure amendment]

[Submission date] September 24, 1993

[Procedure Amendment 2]

[Document name to be amended] Statement

[Name of item to be amended] Claims

[Correction method] Change

[Correction content]

[Claims]

─────────────────────────────────────────────────── ─── Continuation of the front page (51) Int.Cl. ⁵ Identification code Office reference number FI technical display location G03G 21/00

Claims (11)

[Claims] 1. An anti-counterfeit paper in which glittering strips 2 are ubiquitous on the surface of a base paper 1, characterized in that the strips 2 have a capability of adhering to the base paper in a papermaking process. Anti-counterfeit paper. 2. The anti-counterfeit paper according to claim 1, wherein one of the components of the strip is a film having a hot water dissolution temperature of 60 to 80 ° C. 3. A strip having a hot water dissolution temperature of 60 to 80 ° C. and a metal vapor deposition layer formed on one side or both sides thereof, and a coating layer comprising a resin or a resin and a colorant formed thereon. The anti-counterfeit paper according to claim 1, which is made of: 4. The anti-counterfeit paper according to claim 3, wherein the resin is soluble in alkaline hot water at 60 to 80 ° C. 5. The strip has a metal vapor deposition layer formed on one side of a film having a hot water dissolution temperature of 60 to 80 ° C., and a coating layer comprising a resin and a colorant is formed on the metal vapor deposition layer, if necessary. The anti-counterfeit paper according to claim 1, wherein the anti-counterfeit paper is formed by laminating a film having a hot water dissolution temperature of 60 to 80 ° C on its surface. 6. The forgery prevention according to claim 1, wherein the strip is formed by transferring a transfer foil having an iris color or metallic luster onto a film having a hot water dissolution temperature of 60 to 80 ° C. Paper. 7. A strip having a hot water dissolution temperature of 60 to 80 ° C., onto which a transfer foil having an iris color or a metallic luster is transferred, and having a hot water dissolution temperature of 60 to 80 ° C. formed on the surface thereof. The anti-counterfeit paper according to claim 1 or 2, which is formed by pasting. 8. The strip is formed by coating a paper with a coating liquid prepared by mixing a metal powder or a pearl pigment with a binder, and then bonding hot water-soluble films to both surfaces of the paper. The anti-counterfeit paper described in 1. 9. The anti-counterfeit paper according to claim 1, wherein the strip comprises a film having a hot water dissolution temperature of 60 to 80 ° C. in which metal powder is kneaded. 10. The anti-counterfeit paper according to claim 1, wherein the strip comprises a film having a hot water dissolution temperature of 60 to 80 ° C. in which a pearl pigment is kneaded. 11. The anti-counterfeit paper according to claim 8, wherein the pearl pigment is a pearl pigment which emits an iris color.