JPH06297192A - Manufacture of sheet for cladding by welding - Google Patents

Manufacture of sheet for cladding by welding

Info

Publication number
JPH06297192A
JPH06297192A JP9152693A JP9152693A JPH06297192A JP H06297192 A JPH06297192 A JP H06297192A JP 9152693 A JP9152693 A JP 9152693A JP 9152693 A JP9152693 A JP 9152693A JP H06297192 A JPH06297192 A JP H06297192A
Authority
JP
Japan
Prior art keywords
welding
sheet
water glass
sheet material
water
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP9152693A
Other languages
Japanese (ja)
Inventor
Shinichi Yamamoto
伸一 山元
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
NIKKO KASEI KK
NIKKO YOUZAI KOGYO KK
Original Assignee
NIKKO KASEI KK
NIKKO YOUZAI KOGYO KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by NIKKO KASEI KK, NIKKO YOUZAI KOGYO KK filed Critical NIKKO KASEI KK
Priority to JP9152693A priority Critical patent/JPH06297192A/en
Publication of JPH06297192A publication Critical patent/JPH06297192A/en
Pending legal-status Critical Current

Links

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  • Arc Welding In General (AREA)
  • Butt Welding And Welding Of Specific Article (AREA)

Abstract

PURPOSE:To manufacture a metallic material, which is used superposed on a base material at the time of cladding by welding, with less penetration into the base material, and in such a manner that the scattering of dust and the generation of odor at the time of welding are eliminated so that the material is used without impairing the working environment, and that suitable slag is formed to perform welding with a satisfactory bead appearance even by a carbon dioxide gas arc welding. CONSTITUTION:A powdery mixture P consisting of metallic powder for cladding by welding, water glass and polysaccharide is scattered on the surface of a web-shaped sheet material 1, a web shaped protective sheet material 8 made of glass paper is superposed thereon, then passed through an electric heating furnace 13 to convert the water glass into a hydrated water glass, thereby both sheet materials 1, 8 and powdery mixture P are adhered and integrated to manufacture the sheet for clad welding.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】この発明は鋼材への肉盛溶接に用
いられる肉盛溶接用シートの製造方法に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for manufacturing a sheet for overlay welding used for overlay welding on a steel material.

【0002】[0002]

【従来の技術】従来、溶接にはアーク溶接、サブマージ
アーク溶接など多くの方法があるが、ワイヤを用いて肉
盛溶接を行なうと、溶接時に溶接金属と母材の表面部分
とが溶融混合され、溶着する金属が所期した成分と異な
ったものになるので、溶着金属に所要の強度を発揮させ
るためには多層状に肉盛する必要がある。
2. Description of the Related Art Conventionally, there are many methods such as arc welding and submerged arc welding for welding. However, when overlay welding is performed using a wire, the weld metal and the surface portion of the base metal are melt-mixed during welding. Since the metal to be deposited is different from the intended component, it is necessary to build up in multiple layers in order to make the deposited metal exhibit the required strength.

【0003】肉盛溶接を行なう際には、別途、粉末状の
充隙用金属材料を用いることが知られているが、このも
のは溶接時のアークの衝撃で被溶接母材の表面から飛散
するので、作業上好ましいものではない。このため、金
属粉末の上にフラックスを散布して、サブマージアーク
溶接、バンドアーク溶接を行なうようにしていた。
It is known that a powdery metallic material for filling gap is separately used for overlay welding, but this material is scattered from the surface of the base metal to be welded by the impact of arc during welding. Therefore, it is not preferable in terms of work. Therefore, submerged arc welding and band arc welding are performed by dispersing flux on the metal powder.

【0004】[0004]

【発明が解決しようとする課題】しかし、前記した肉盛
溶接では、何度も重ね合わせて同じ箇所を溶接すること
となるので、熱量を多く必要とし、溶接部分の歪みも大
きくなる。
However, in the above-mentioned build-up welding, the same portion is welded by overlapping many times, so that a large amount of heat is required and the distortion of the welded portion becomes large.

【0005】比較的広い面積を肉盛溶接するには、前記
したように金属粉末の上からフラックスを散布する方法
が採られるが、作業能率が悪く、粉塵が発生すると共
に、酸化物の強い臭気が発生して作業環境が損なわれる
という問題点がある。また、フラックスを用いると、炭
酸ガスアーク溶接を行なった場合に、スラグが全く生成
しないので、ビート外観を良好に形成できないという問
題点もある。
To build up a relatively large area by overlay welding, as described above, a method in which flux is sprinkled over the metal powder is used, but the work efficiency is poor, dust is generated, and the strong odor of oxides is generated. Occurs and the working environment is impaired, which is a problem. Further, when the flux is used, there is a problem in that when carbon dioxide arc welding is performed, slag is not generated at all, so that the beat appearance cannot be formed well.

【0006】上記金属粉末に代えて板状またはブロック
状の充隙剤を用いれば粉塵は発生しないが、溶接時にこ
のような金属材料を用いると、多量の熱を要し母材にも
多くの熱量が吸収されることとなるため、金属材料と母
材とが多量に溶融混合されることとなり、所期した金属
組成で肉盛溶接層を形成できない。
If a plate-like or block-like filler is used in place of the above metal powder, no dust will be generated. However, if such a metal material is used during welding, a large amount of heat is required and a lot of base metal is used. Since the amount of heat is absorbed, the metal material and the base material are melt-mixed in a large amount, and the overlay welding layer cannot be formed with the intended metal composition.

【0007】そこで、この発明は、上記した問題点を解
決し、肉盛溶接を行なうときに予め母材に重ねて用いる
金属材料を、母材への溶け込みが少なく、溶接時に粉塵
の飛散や悪臭の発生がなく作業環境を損なうこともなく
使用でき、さらには適当なスラグが形成されて炭酸ガス
アーク溶接によってもビート外観を良好にして溶接でき
るように製造することを課題としている。
In view of the above, the present invention solves the above-mentioned problems, and a metal material used in advance for overlaying a base material when overlay welding is performed is less likely to be melted into the base material, and scattering of dust or a bad odor is caused during welding. It is an object of the present invention to manufacture such that it can be used without causing the occurrence of heat generation and does not impair the working environment, and that an appropriate slag is formed so that the beet appearance can be improved and the welding can be performed by carbon dioxide gas arc welding.

【0008】[0008]

【課題を解決するための手段】上記の課題を解決するた
め、この発明においては、ウェブ状のシート材表面に溶
接用金属粉末と水ガラスとを散布し、この上にウェブ状
の保護シート材を重ね合わせ、次いで前記水ガラスを和
水水ガラス化して両シート材および前記金属粉末を接着
一体化して肉盛溶接用シートを製造したのである。
In order to solve the above-mentioned problems, in the present invention, a metal powder for welding and water glass are sprinkled on the surface of a web-shaped sheet material, and a web-shaped protective sheet material is spread thereon. Then, the above-mentioned water glass was made into a water-water water glass, and both sheet materials and the above-mentioned metal powder were adhered and integrated to produce a sheet for overlay welding.

【0009】また、ウェブ状のシート材表面に溶接用金
属粉末と水ガラスと多糖類とを散布し、この上にウェブ
状でスラグ形成成分を含有する保護シート材を重ね合わ
せ、次いで前記水ガラスを和水水ガラス化して両シート
材および前記金属粉末を接着一体化して肉盛溶接用シー
トを製造することもできる。
Further, the metal powder for welding, water glass and polysaccharides are sprinkled on the surface of the web-shaped sheet material, and a web-shaped protective sheet material containing a slag-forming component is superposed thereon, and then the above-mentioned water glass. It is also possible to manufacture a sheet for build-up welding by making both of the sheet materials and the metal powder into an integral body by vitrifying the above with water and water.

【0010】以下に、その詳細を述べる。The details will be described below.

【0011】この発明に用いるウェブ状のシート材また
は保護シート材は、溶接金属粉末を付着して保持できる
材料であれば、特に限定されるものでなく、有機繊維、
無機繊維、合成樹脂シートなどを使用できる。このうち
無機繊維としては、ガラス繊維、カーボン繊維、金属繊
維、ロックウールなどが挙げられる。有機繊維として
は、綿、麻その他の天然繊維またはポリアミド、ポリエ
ステルなどが例示できるが、動物性蛋白質や塩化物など
は加熱時に悪臭を発生するので好ましくない。これら繊
維の形態としては、不織布、編織布のいずれであっても
よい。
The web-like sheet material or protective sheet material used in the present invention is not particularly limited as long as it is a material capable of adhering and holding weld metal powder, and organic fiber,
Inorganic fibers, synthetic resin sheets, etc. can be used. Among these, examples of the inorganic fiber include glass fiber, carbon fiber, metal fiber, rock wool and the like. Examples of the organic fibers include cotton, hemp and other natural fibers, polyamides, polyesters, etc., but animal proteins, chlorides, etc. are not preferred because they produce a bad odor when heated. The form of these fibers may be either non-woven fabric or knitted fabric.

【0012】この発明に用いる溶接用金属粉末の成分
は、溶接する母材に適当な強度で溶着されるように適宜
調製されるものであるから、特に限定されるものでな
く、その材料としては、鉄、非鉄金属、種々の合金のほ
か、クロムカーバイド、タングステンカーバイドなどの
炭化物、グラファイトなどを用い、これらを粉末化した
ものであってよい。これら金属粉末の粒径も特に限定さ
れるものではないが、たとえば平均粒径にて200〜5
00μmのものを用いて良好な結果を得ている。
The components of the metal powder for welding used in the present invention are appropriately prepared so as to be welded to the base material to be welded with an appropriate strength, and are not particularly limited. In addition to iron, non-ferrous metals, various alloys, carbides such as chromium carbide and tungsten carbide, graphite, and the like, these may be powdered. The particle size of these metal powders is also not particularly limited, but is, for example, 200 to 5 in average particle size.
Good results have been obtained using a film having a diameter of 00 μm.

【0013】この発明に用いる水ガラスは、アルカリ−
ケイ酸系ガラスとして周知のものを用いればよく、Si
2 23〜37、Na2 O 6〜18、Fe2 3
0.03〜0.05のものが一般的に用いられる。この
ものは、水、アルコール類に溶解するが、加熱、乾燥な
どにより水分量を10〜30%に調製すれば、和水水ガ
ラス化して、可撓性のある固体となる。
The water glass used in the present invention is alkali-based.
A well-known silicate glass may be used.
O 2 23-37, Na 2 O 6-18, Fe 2 O 3 <
Those of 0.03 to 0.05 are generally used. This substance dissolves in water and alcohols, but if the water content is adjusted to 10 to 30% by heating, drying, etc., it becomes viscous water water and becomes a flexible solid.

【0014】この発明における多糖類としては、デンプ
ン、セルロース、グリコーゲン、アルギン酸、ブドウ糖
などが挙げられる。これらは、溶接時に酸化した場合に
金属酸化物の刺激臭を緩和するので、マスキング剤とし
て、および結合助剤として有用である。
Examples of the polysaccharide in the present invention include starch, cellulose, glycogen, alginic acid, glucose and the like. These are useful as a masking agent and as a bonding aid because they alleviate the pungent odor of metal oxides when oxidized during welding.

【0015】このような多糖類は、金属粉末100重量
部に対して、1〜5重量部の割合で配合する。なぜな
ら、多糖類が1重量部未満の少量では結合助剤として所
期の効果が得られない。また、5重量部を越える多量で
は、溶接熱によって分解した場合にポーラス部が大きく
なり、溶接時に収縮して母材との接着性が低下するから
である。
Such a polysaccharide is blended in an amount of 1 to 5 parts by weight with respect to 100 parts by weight of the metal powder. Because, if the amount of the polysaccharide is less than 1 part by weight, the desired effect as a binding aid cannot be obtained. On the other hand, when the amount is more than 5 parts by weight, the porous portion becomes large when decomposed by welding heat and shrinks during welding to reduce the adhesiveness to the base material.

【0016】前記した保護シート材に含有させるスラグ
形成成分としては、CaO、Al23 、SiOなどが
挙げられる。スラグ形成材は、保護シート材料に分散、
溶解または物理的に保持させて含有させることができる
ほか、ガラス繊維からなる不織布または編織布であれば
保護シートそのものであってもよい。
Examples of the slag forming component contained in the above-mentioned protective sheet material include CaO, Al 2 O 3 and SiO. The slag forming material is dispersed in the protective sheet material,
The protective sheet itself may be contained by being dissolved or physically retained, and may be a protective sheet itself as long as it is a non-woven fabric or a woven fabric made of glass fibers.

【0017】このような素材からなる肉盛溶接用シート
は、その厚さは8mm以下として適当である。8mmを
越える厚さでは、溶接時にシートで奪われる熱量が多く
なり、母材への熱量が不足して溶着不良を起こす。ま
た、アーク溶接の場合のように溶接電流を多くして入熱
量を高めても、溶接部分の歪みが大きくなるので好まし
くないからである。
The thickness of the overlay welding sheet made of such a material is suitably 8 mm or less. If the thickness exceeds 8 mm, the amount of heat taken up by the sheet during welding increases, and the amount of heat to the base material becomes insufficient, resulting in poor welding. Further, even if the welding current is increased to increase the heat input as in the case of arc welding, the distortion of the welded portion becomes large, which is not preferable.

【0018】[0018]

【作用】この発明の肉盛溶接用シートの製造方法では、
水ガラスをバインダーとしてシート材の表面に所要の肉
厚となるように充分な量の溶接用金属粉末を付着させ、
この上に保護シート材を前記水ガラスでもって接着一体
化するので、広幅で充分に厚肉であると共に、溶接時に
金属粉末が飛散しない肉盛溶接シートを製造できる。前
記金属粉末は、熱の伝達効率が良く溶接時に速やかに溶
融するので、金属シート材料と母材との溶融混合を最小
限に止めることができる。
According to the method for manufacturing the overlay welding sheet of the present invention,
Using water glass as a binder, deposit a sufficient amount of welding metal powder on the surface of the sheet material so that the required thickness is obtained,
Since the protective sheet material is bonded and integrated with the water glass on the above, it is possible to manufacture a build-up welded sheet which is wide and has a sufficiently thick wall and which does not scatter metal powder during welding. Since the metal powder has a high heat transfer efficiency and is rapidly melted during welding, it is possible to minimize the melting and mixing of the metal sheet material and the base material.

【0019】また、前記水ガラスと共に多糖類を併用し
て製造すれば、溶接時に多糖類が金属酸化物臭をマスキ
ングする。前記保護シート材にスラグ形成材を添加して
製造すると、炭酸ガスアーク溶接を行なった場合でも適
当にスラグが生成されてビート外観が向上するものが製
造できる。
If the water glass is used in combination with a polysaccharide, the polysaccharide masks the odor of metal oxide during welding. When a slag forming material is added to the protective sheet material, a slag is appropriately generated even when carbon dioxide gas arc welding is performed, and a beet appearance is improved.

【0020】[0020]

【実施例】実施例の製造方法を以下、図面に基づいて説
明する。
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS A manufacturing method of an embodiment will be described below with reference to the drawings.

【0021】図1に示すように実施例では、ガラス繊維
製織り布からなるウェブ状のシート材1をロール体2か
ら繰り出し、2〜5m/分の一定速度で上下端面開口の
枠型容器3の下端面に沿わせて進行させた。そして、こ
の枠型容器3の上方にはホッパー4を配置して、さらに
その上方には攪拌機付きの混合供給装置5を配置した。
混合容器供給装置5には、C5重量%、Cr25重量
%、残部Feから組成された金属粉末100重量部に対
してデンプンを1〜5重量部の割合で配合した混合粉末
Pを収容し、これを連続的にホッパー4に供給した。
As shown in FIG. 1, in the embodiment, a web-shaped sheet material 1 made of glass fiber woven cloth is fed from a roll body 2 and a frame-shaped container 3 having upper and lower end faces opened at a constant speed of 2 to 5 m / min. It was advanced along the lower end surface of. Then, a hopper 4 was arranged above the frame-shaped container 3, and a mixing / supplying device 5 with a stirrer was further arranged above it.
The mixing container supply device 5 contains a mixed powder P in which 1 to 5 parts by weight of starch is mixed with 100 parts by weight of a metal powder composed of C 5% by weight, Cr 25% by weight, and the balance Fe. Was continuously supplied to the hopper 4.

【0022】上記した枠型容器3のシート材1の進行方
向下流側の側面下部には、混合粉末Pをシート材1表面
に均等な厚みで供給するためのギャップ6を形成してい
る。このギャップ6は、枠型容器3の下流側の側面を上
下方向にスライド可能としたもので、ギャップ6の間隔
を調節して所要の厚みで混合粉末Pを供給することがで
きるようになっている。
A gap 6 for supplying the mixed powder P to the surface of the sheet material 1 with a uniform thickness is formed in the lower portion of the side surface of the frame-shaped container 3 on the downstream side in the traveling direction of the sheet material 1. The gap 6 is configured so that the downstream side surface of the frame-shaped container 3 can be slid in the vertical direction, and the gap 6 can be adjusted to supply the mixed powder P with a required thickness. There is.

【0023】次工程では、シート材1の上方から、噴霧
器7で水/水ガラス=100/10〜20(重量比)の
水ガラス水溶液Lを200g/m2 の割合で散布した。
In the next step, the water glass aqueous solution L of water / water glass = 100/10 to 20 (weight ratio) was sprayed from above the sheet material 1 with the sprayer 7 at a rate of 200 g / m 2 .

【0024】次いで、ガラスペーパーからなる保護シー
ト材8をロール体9から繰り出してシート材1と同じ速
度で進行させ、混合粉末P上に添着させ、複数のロール
10、11、12で厚さが8mm以下となるように挟圧
した。
Next, the protective sheet material 8 made of glass paper is fed out from the roll body 9 and is advanced at the same speed as the sheet material 1 to be attached onto the mixed powder P, and the plurality of rolls 10, 11 and 12 are used to adjust the thickness. The pressure was applied so that it would be 8 mm or less.

【0025】そして、これを80〜120℃に設定され
た電気加熱炉13に5分間加熱されるように通過させ、
切断機14で所望の大きさに切断して肉盛溶接用シート
Aを得た。
Then, this was passed through an electric heating furnace 13 set at 80 to 120 ° C. so as to be heated for 5 minutes,
A sheet A for overlay welding was obtained by cutting into a desired size with a cutting machine 14.

【0026】得られた肉盛溶接用シートAは、添加した
水ガラスが和水水ガラス化してバインダーおよび接着剤
として作用しており、可撓性を有して曲面の溶接用材料
としても優れており、また肉盛溶接に用いて粉塵および
悪臭の発生がなく、ビート外観もよく、肉盛溶接作業を
効率良く行なえるものであった。
In the obtained overlay welding sheet A, the added water glass is converted to Japanese water and water glass to act as a binder and an adhesive, and is flexible and excellent as a curved welding material. In addition, there was no generation of dust and odor when used in the overlay welding, the beet appearance was good, and the overlay welding work could be performed efficiently.

【0027】[0027]

【効果】この発明は、以上説明したように、水ガラスを
バインダーとしてシート材の表面に肉盛溶接用金属粉末
を付着させ、この上に保護シート材を和水水ガラスでも
って接着一体化して製造したので、比較的厚肉で幅の広
い肉盛溶接に適用できるシートを連続して効率よく製造
できる。そして、製造される肉盛溶接用シートは、溶接
金属が粉状の溶接金属を含有して、溶接時に母材へ溶け
込みむ割合が少なく、粉塵の飛散もない。溶接金属粉末
と共に多糖類を添加して製造すると、悪臭の発生がな
く、溶接作業環境を損なうことがないものが得られる。
また、スラグ形成剤を含有する保護シートを接着したも
のも製造できるので、ビート外観を良好にして炭酸ガス
アーク溶接によっても良好な外観で溶接できるものが得
られるという利点もある。
As described above, according to the present invention, metal powder for overlay welding is adhered to the surface of a sheet material using water glass as a binder, and a protective sheet material is bonded and integrated with this using water water glass. Since it is manufactured, it is possible to continuously and efficiently manufacture a sheet applicable to overlay welding having a relatively thick wall and a wide width. In the manufactured overlay welding sheet, the weld metal contains powdery weld metal, and the proportion of the weld metal that melts into the base metal during welding is small and dust is not scattered. When the polysaccharide is added together with the weld metal powder to produce the product, it is possible to obtain a product that does not generate a bad odor and does not impair the welding work environment.
Further, since a product to which a protective sheet containing a slag forming agent is adhered can be manufactured, there is an advantage that a product having a good beet appearance and a good appearance can be obtained by carbon dioxide arc welding.

【図面の簡単な説明】[Brief description of drawings]

【図1】実施例を模式化して示す製造工程図FIG. 1 is a manufacturing process diagram schematically showing an example.

【符号の説明】[Explanation of symbols]

1 シート材 2 ロール体 3 枠型容器 4 ホッパー 5 混合供給装置 7 噴霧機 8 保護シート材 13 電気加熱炉 P 混合粉末 L 水ガラス水溶液 A 肉盛溶接用シート DESCRIPTION OF SYMBOLS 1 sheet material 2 roll body 3 frame type container 4 hopper 5 mixing supply device 7 sprayer 8 protective sheet material 13 electric heating furnace P mixed powder L water glass aqueous solution A sheet for overlay welding

Claims (2)

【特許請求の範囲】[Claims] 【請求項1】 ウェブ状のシート材表面に溶接用金属粉
末と水ガラスとを散布し、この上にウェブ状の保護シー
ト材を重ね合わせ、次いで前記水ガラスを和水水ガラス
化して両シート材および前記金属粉末を接着一体化する
ことからなる肉盛溶接用シートの製造方法。
1. A web-shaped sheet material is sprayed with a metal powder for welding and water glass, a web-shaped protective sheet material is superposed thereon, and then the water glass is made into a water-water-water glass. A method for manufacturing a sheet for overlay welding, which comprises integrally bonding a material and the metal powder together.
【請求項2】 ウェブ状のシート材表面に溶接用金属粉
末と水ガラスと多糖類とを散布し、この上にウェブ状で
スラグ形成成分を含有する保護シート材を重ね合わせ、
次いで前記水ガラスを和水水ガラス化して両シート材お
よび前記金属粉末を接着一体化することからなる肉盛溶
接用シートの製造方法。
2. A metal sheet for welding, water glass, and a polysaccharide are sprinkled on the surface of a web-shaped sheet material, and a web-shaped protective sheet material containing a slag-forming component is superposed thereon.
Next, a method for producing a build-up welding sheet, which comprises making the above-mentioned water glass into a water-water water glass and integrally adhering both sheet materials and the above metal powder.
JP9152693A 1993-04-19 1993-04-19 Manufacture of sheet for cladding by welding Pending JPH06297192A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP9152693A JPH06297192A (en) 1993-04-19 1993-04-19 Manufacture of sheet for cladding by welding

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP9152693A JPH06297192A (en) 1993-04-19 1993-04-19 Manufacture of sheet for cladding by welding

Publications (1)

Publication Number Publication Date
JPH06297192A true JPH06297192A (en) 1994-10-25

Family

ID=14028879

Family Applications (1)

Application Number Title Priority Date Filing Date
JP9152693A Pending JPH06297192A (en) 1993-04-19 1993-04-19 Manufacture of sheet for cladding by welding

Country Status (1)

Country Link
JP (1) JPH06297192A (en)

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