JPH06289549A - Method for forming color proof by silver halide color photographic sensitive material - Google Patents

Abstract

PURPOSE:To provide the method for forming the color proof by using the silver halide color photographic sensitive material less probable to change hues even when dot gain is adjusted by changing an exposure amount. CONSTITUTION:The silver halide color photographic sensitive material has on a reflective support a blue-, green-, and red-sensitive silver halide emulsion layers and forms a yellow dot image by blue light, and it is characterized by that when (SB)B, (SGB, and (SR)B signify sensitivity of each of the blue-, green-, and red-sensitive emulsion layers to the blue light, the following sensitivity ratio is obtained: (Sc)B/(SB)B<=0.1, (SR)B/(SB)B<=0.1, and in the yellow image, an average main gradation in the range of from minimum density (Dmin)+0.5 to Dmin +1.1 is 1.7-2.8.

Description

Detailed Description of the Invention

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a color image forming method using a silver halide color light-sensitive material, and in particular, a proof color image (color proof) is obtained from a transmission type black and white halftone original which is color-separated from a color original. The present invention relates to a color proof making method using a silver halide color light-sensitive material suitable for making.

[0002]

2. Description of the Related Art Conventionally, in the process of color plate making and printing,
To improve the drawbacks of the overlay method and surprint method used as a method for obtaining a color proof from a plurality of black and white halftone images obtained by color separation and halftone conversion,
A method of using a silver halide color light-sensitive material is disclosed in JP-A-62-62.
-280747 to 280750 and 62-280849. Further, JP-A 1-298092 discloses that a color proof excellent in color reproducibility can be obtained by using a specific yellow coupler.

[0003]

However, recently, the market quality has increased, and the fields of use are wide-ranging. In a printed matter, the dot gain is one of the important characteristics that influence the image quality, and the dot gain differs depending on the type of printing. In a color proof using a silver halide color light-sensitive material, the dot gain can be adjusted by the exposure amount. That is, the exposure amount can be increased to increase the dot area on the proof screen, and the dot gain can be increased. However, when the exposure amount is increased, even the hue of dots is changed and the color reproducibility is deteriorated. In particular, there is a demand for the practical application of a color proof light-sensitive material in which the hue of a yellow image is largely deteriorated and the hue is less likely to change due to a change in exposure amount.

Therefore, an object of the present invention is to change the exposure amount when a color proof is prepared from halftone image information obtained by color separation and halftone image conversion using a silver halide color light-sensitive material. It is an object of the present invention to provide a method for producing a color proof using a silver halide color light-sensitive material (hereinafter, also referred to as “color light-sensitive material”) in which hue does not easily change even if the dot gain is adjusted.

[0005]

The above object of the present invention can be achieved by the following constitutions.

(1) On a reflective support, a blue-sensitive silver halide emulsion layer containing a yellow coupler, a green-sensitive silver halide emulsion layer containing a magenta coupler, and a red-sensitive halogenated halide containing a cyan coupler. In a silver halide color light-sensitive material having a silver emulsion layer and forming a yellow dot image by blue light, the sensitivity of the blue light-sensitive silver halide emulsion layer to blue light is (S _B ) _B , and the green light-sensitivity is The sensitivity of the silver halide emulsion layer to blue light is (S _G ) _B , and the sensitivity of the red-sensitive silver halide emulsion layer to blue light is (S _R ) _B
And the sensitivity ratio is as follows, (S _G ) _B / (S _B ) _B ≤0.1 (S _R ) _B / (S _B ) _B ≤0.1 and the main gradation of the yellow image (of the yellow image Minimum concentration
(Dmin) +0.5 ~ average density between minimum density + 1.1) is 1.7 ~
A method for producing a color proof using a silver halide color light-sensitive material, characterized in that it is 2.8.

(2) The method for producing a color proof according to (1), wherein the wavelength of the blue light is 350 to 500 nm.

(3) A silver halide color light-sensitive material characterized in that the main gradation is 2.0 to 2.6 (1)
How to make a color proof as described.

(4) In the color proof making method, the shoulder gradation of the yellow image (the minimum density (D
min) +1.4 to minimum density + 1.7) is 1.6 or more. The method for producing a color proof according to (1) using a silver halide color light-sensitive material.

(5) Main gradation of 1.7 to 1 shown in (1) above
2.8 is determined by processing in the following processing steps.

(Processing step) Processing step Processing temperature Time Color development 35.0 ± 0.3 ℃ 45 seconds Bleach fixing 35.0 ± 0.5 ℃ 45 seconds Water wash 30-34 ℃ 90 seconds Dry 60-80 ℃ 60 seconds (Color developer) Pure water 800 ml Triethanolamine 10g N, N-diethylhydroxylamine 5g Potassium bromide 0.02g Potassium chloride 2g Potassium sulfite 0.3g 1-Hydroxyethylidene-1,1-diphosphonic acid 1.0g Ethylenediaminetetraacetic acid 1.0g Catechol-3,5-diphosphonic acid Disodium 1.0g 4-Amino-N-ethyl-N- (β-hydroxyethyl) aniline sulfate 4.5g Optical brightener (4,4'-diaminostilbene sulfonic acid derivative) 1.0g Potassium carbonate 27g Add water Adjust the total volume to 1 liter and adjust the pH to 10.10.

(Bleach-fixing solution) Ethylenediaminetetraacetic acid ammonium ferric dihydrate 60 g Ethylenediaminetetraacetic acid 3 g Ammonium thiosulfate (70% aqueous solution) 100 ml Ammonium sulfite (40% aqueous solution) 27.5 ml Water is added to make 1 liter, Adjust to pH = 5.7 with potassium carbonate or glacial acetic acid.

(Washing liquid) 5-chloro-2-methyl-4-isothiazolin-3-one 1.0 g ethylene glycol 1.0 g 1-hydroxyethylidene-1,1-diphosphonic acid 2.0 g ethylenediaminetetraacetic acid 1.0 g ammonium hydroxide ( 20% aqueous solution) 3.0 g Optical brightener (4,4'-diaminostilbene sulfonic acid derivative) 1.5 g Water is added to bring the total volume to 1 liter, and pH is adjusted to 7.0 with sulfuric acid or potassium hydroxide.

(6) The blue-sensitive silver halide emulsion layer, the green-sensitive silver halide emulsion layer and the red-sensitive silver halide emulsion layer each have a silver chloride content of at least 80%.
The method for producing a color proof according to (1), wherein the silver halide color light-sensitive material is used.

(7) A silver halide color light-sensitive material containing a yellow coupler represented by the following general formula [YI] in the blue light-sensitive silver halide emulsion layer (1). How to make a color proof.

[0016]

[Chemical 4]

In the formula, R ₁ represents an alkyl group, a cycloalkyl group or an aryl group, R ₂ represents an alkyl group, a cycloalkyl group, an acyl group or an aryl group, and R ₃ represents a group capable of substituting on the benzene ring. Represent n represents 0 or 1. X
₁ represents a hydrogen atom or a group capable of splitting off upon coupling with an oxidized product of a developing agent, and Y ₁ represents an organic group.

(8) The silver halide color light-sensitive material described in (1), wherein at least one layer of the silver halide color light-sensitive material contains a high boiling point solvent represented by the following general formula [H]. How to make a color proof.

[0019]

[Chemical 5]

In the formula, R ₁₁ , R ₁₂ and R ₁₃ each represent an alkyl group, a cycloalkyl group or an aryl group, and p,
q and r each represent 0 or 1.

(9) The above (1), (3), (4),
A method for producing a color proof, which comprises treating the silver halide color light-sensitive material described in (6), (7) or (8) with a color developing solution containing the following general formula [D].

[0022]

[Chemical 6]

In the formula, R ₂₁ represents a hydrogen atom or an alkyl group, R ₂₂ represents an alkyl group, and R ₂₃ represents an alkylene group.

The present invention will be described in more detail below.

In the present invention, the main gradation means a characteristic curve when a sample subjected to wedge exposure and subjected to the treatment of the above (5) is measured, and the vertical axis shows the density and the horizontal axis shows the logarithm of the exposure amount. Dm
It is defined as the photographic gradation obtained when the point (a) intersecting with in + 0.5 and the point (b) intersecting with Dmin + 1.1 are connected, and the shoulder gradation is the same as the point where the characteristic curve intersects Dmin + 1.4 ( It is defined as the slope obtained when the c) and the point (d) that intersects Dmin + 1.7 are connected.
That is, main gradation = 0.6 / (ba) shoulder gradation = 0.3 / (dc) In the present invention, the main gradation of the yellow image is 1.7 to 2.8, but it is more preferable to be in the range of 2.0 to 2.6. . The shoulder gradation is preferably 1.6 or more, more preferably 1.8 or more.

The sensitivities of the blue-sensitive layer, green-sensitive layer and red-sensitive layer of the color light-sensitive material of the present invention to blue light are expressed as follows.

(S _G ) _B / (S _B ) _B ≤0.1 (S _R ) _B / (S _B ) _B ≤0.1 (S _B ) _B : Blue light sensitivity of the blue photosensitive layer (S _G ) _B : Green Blue light sensitivity (S _R ) _{B of the} photosensitive layer: Blue light sensitivity of the red photosensitive layer Blue light sensitivity: The reciprocal of the exposure amount that gives a density of Dmin + 0.5 when wedge exposure is performed with blue light (350 to 500 nm).

In the silver halide color light-sensitive material, the inventor of the present invention has a blue light-sensitive layer having a main gradation of 1.7 to 2.8, and has blue light-sensitive layers, green light-sensitive layers and red light-sensitive layers for blue light. The present invention has been completed by finding that if the sensitivity satisfies the above condition, the dot gain adjustment suitability of the photosensitive material is dramatically improved. The dot gain here is expressed by the following formula.

Dot gain = (halftone dot% of printed matter) − (halftone dot% of original) Halftone dot% (ADA) of printed matter is expressed by the following equation (Murray-Davis equation).

ADA = (1-10- ^Dt ) / (1-10- ^Ds ) In the formula, Dt = (optical density of halftone dot image part)-(optical density of white background part) Ds = (optical density of solid image part) )-(Optical density of white background portion) The halftone dot% of the printed matter in the above formula can be read as the halftone dot% of the proof image in the description of the present invention.

The following are typical methods for making a difference in sensitivity.

1: Raise the sensitivity of the blue-sensitive emulsion 2: Reduce the intrinsic sensitivity of the green-sensitive and red-sensitive emulsions to blue light 3: Providing a filter layer in the middle For example, the amount of dye is increased, the amount of sensitizer added is increased, and the particle size is increased. As a specific method of 2, there is a method of using a high silver chloride emulsion for the green photosensitive layer and the red photosensitive layer. As a specific method of 3, the blue photosensitive layer is farther from the support than the other photosensitive layers,
A yellow filter layer using yellow colloidal silver or the like is provided between the blue photosensitive layer and the multilayer.

In the method 1, if the sensitivity difference is extremely increased, the white background is deteriorated and the developability is deteriorated. In the method of 3, the sensitivity as a sensitive material is lowered. From these facts, the method of using a high silver chloride emulsion having a silver chloride content of 2 of 80 mol% or more is preferable. It is not necessary to use a high silver chloride emulsion for the blue-sensitive layer, but it is preferable to use a high silver chloride emulsion because rapid processing can be performed.

The methods 1 to 3 may be used alone or in combination of two or more.

As the silver halide used in the light-sensitive material of the present invention, any silver halide such as silver iodochloride, silver chlorobromide and silver chloride which are commonly used in silver halide emulsions can be used. The content of is preferably 80% or more.

The composition of the silver halide grain of the present invention may be uniform from the inside to the outside of the grain, or the composition inside and outside the grain may be different.

The grain size of the silver halide grains of the present invention is not particularly limited, but considering other photographic properties such as rapid processing property and sensitivity, it is preferably 0.2 to 1.6 μm, more preferably 0.25 to 1.2 μm. Is the range.

The grain size distribution of the silver halide grains of the present invention may be polydisperse or monodisperse.

In the grain size distribution of silver halide grains, the coefficient of variation is preferably 0.22 or less, more preferably 0.15.
The following are monodisperse silver halide grains. The coefficient of variation is represented by (standard deviation of particle size distribution) / (average particle size).

The silver halide grains used in the emulsion of the present invention may be those obtained by any of the acidic method, the neutral method and the ammonia method. The particles may be grown at one time,
The seed particles may be grown and then grown.

The method of reacting the soluble silver salt and the soluble halogen salt may be any of a forward mixing method, a back mixing method, a simultaneous mixing method, and a combination thereof, but those obtained by the simultaneous mixing method are preferable. .

The silver halide grains according to the present invention may have any shape. One preferred example is
It is a cube with the {100} plane as the crystal surface.

Further, grains such as octahedron, 14-faced dodecahedron and grains having twin planes may be used. As the silver halide grains, grains having a single shape may be used, or grains having various shapes may be mixed.

The silver halide grains used in the emulsion of the present invention are cadmium salt, zinc salt, lead salt, thallium salt, iridium salt (including complex salt) and rhodium during the grain forming process and / or the growing process. A metal ion is added using a salt (including a complex salt) or an iron salt (including a complex salt) and included in the inside of the particle and / or on the surface of the particle. Alternatively, it is preferable to impart a reduction sensitizing nucleus to the surface of the grain.

In the silver halide emulsion, unnecessary soluble salts may be removed after the growth of silver halide grains is completed,
Alternatively, it may remain contained. The removal of the salts can be carried out according to the method described in Research Disclosure 17643.

The silver halide grain may be a grain in which a latent image is mainly formed on the surface or may be a grain mainly formed inside the grain. Grains in which the latent image is mainly formed on the surface are preferable.

The silver halide emulsion is chemically sensitized (for example, sulfur sensitized, gold sensitized, noble metal sensitized, selenium sensitized,
Reduction sensitization) and spectral sensitization (for example, spectral sensitization with cyanine dye, merocyanine dye, hemicyanine dye, styryl dye, hemioxonol dye).
Further, an antifoggant or stabilizer known in the art (for example, azaindenes, mercapto heterocyclic compounds) can be added.

The blue light may have a continuous energy distribution or a bright line as long as it is in the range of 350 to 500 nm.

The light source used for the exposure of the present invention includes natural light, tungsten electric lamp, fluorescent lamp, mercury lamp, halogen electric lamp, laser and the like. In particular, a fluorescent lamp is preferable because the heat generation is small and the exposure apparatus can be downsized in scanning exposure.

The coupler used in the silver halide light-sensitive material according to the present invention forms a coupling product having a spectral absorption maximum wavelength in a wavelength region longer than 340 nm by a coupling reaction with an oxidant of a color developing agent. Although any compound to be obtained can be used, as a typical example, a yellow coupler having a spectral absorption maximum in a wavelength range of 350 to 500 nm, a magenta coupler having a spectral absorption maximum wavelength in a wavelength range of 500 to 600 nm, and a wavelength range of 600 The one known as a cyan coupler having a spectral absorption maximum wavelength at ˜750 nm is typical.

The yellow coupler represented by the general formula [Y-I] used in the present invention will be described.

In the general formula [Y-I], examples of the alkyl group represented by R ₁ include methyl, ethyl, isopropyl, t-butyl, dodecyl and the like. The alkyl group represented by R ₁ also includes those having a substituent, and examples of the substituent include a halogen atom, an aryl group, an alkoxy group, an aryloxy group, an alkylsulfonyl group, an acylamino group and a hydroxyl group. Can be mentioned.

Examples of the cycloalkyl group represented by R ₁ include cyclopropyl, cyclopentyl, cyclohexyl and the like, as well as organic hydrocarbon residues (for example, adamantyl) in which two or more cycloalkyls are condensed. The cycloalkyl group represented by R ₁ includes those having a substituent, and examples of the substituent include those exemplified as the above-mentioned substituents of the alkyl group.

Examples of the aryl group represented by R ₁ include phenyl and the like, and the aryl group includes those having a substituent. Examples of the substituent include those exemplified as the above-mentioned substituents of the alkyl group and the alkyl group.

R ₁ is preferably a branched alkyl group.

Examples of the alkyl group, cycloalkyl group and aryl group represented by R ₂ include the same groups as R ₁ and include those each having a substituent. Examples of the substituent include those exemplified for R ₁ . Examples of the acyl group include acetyl, propionyl, butyryl, hexanoyl, benzoyl and the like, and the acyl group includes those having a substituent.

R ₂ is preferably an alkyl group or an aryl group, more preferably an alkyl group, and particularly preferably a lower alkyl group having 5 or less carbon atoms.

Examples of the group capable of substituting the benzene ring represented by R ₃ include a halogen atom (eg chlorine), an alkyl group (eg ethyl, isopropyl, t-butyl etc.), an alkoxy group (eg methoxy), an aryloxy group. (Eg phenoxy), acyloxy group (eg acetyloxy, benzoyloxy etc.), acylamino group (eg acetamide, benzoylamino etc.), carbamoyl group (eg N-methylcarbamoyl, N-phenylcarbamoyl etc.), alkylsulfonamide group (eg Ethyl sulfonamide), aryl sulfonamide group (eg phenyl sulfonamide), sulfamoyl group (eg N-propylsulfamoyl, N-phenylsulfamoyl etc.)
And imide groups (eg, succinimide, glutarimide, etc.) and the like.

The organic group represented by Y ₁ is preferably a group represented by the following general formula [Y-II].

[0060] Formula [Y-II] - (J) p-R ₄ formula, R ₄ represents an organic group containing one linking group having a carbonyl or sulfonyl unit. p represents 0 or 1.

Examples of the group having a carbonyl unit include ester group, amide group, carbamoyl group, ureido group and urethane group. Examples of the group having a sulfonyl unit include sulfonyl group, sulfonylamino group, sulfamoyl group and aminosulfonyl group. An amino group etc. are mentioned.

J represents --N (R ₅ ) CO-- or --CON (R ₅ )-,
R ₅ represents a hydrogen atom, an alkyl group, an aryl group or a heterocyclic group.

Examples of the alkyl group represented by R ₅ include groups such as methyl, ethyl, isopropyl, t-butyl and dodecyl. Examples of the aryl group represented by R ₅ include a phenyl group and a naphthyl group. Examples of the heterocyclic group represented by R ₅ include a pyridyl group.

Each of the groups represented by R ₅ includes those having a substituent. The substituent is not particularly limited, but a typical one is a halogen atom (chlorine, etc.),
Alkyl group (ethyl, t-butyl etc.), aryl group (phenyl, p-methoxyphenyl, naphthyl etc.), alkoxy group (ethoxy, benzyloxy etc.), aryloxy group (phenoxy etc.), alkylthio group (ethylthio etc.),
Arylthio groups (phenylthio, etc.), alkylsulfonyl groups (β-hydroxyethylsulfonyl, etc.), arylsulfonyl groups (phenylsulfonyl, etc.), acylamino groups (acetamido, benzoylamino, etc.), carbamoyl groups (N-methylcarbamoyl, N-phenylcarbamoyl) Etc.), acyl groups (acetyl, benzoyl, etc.), sulfonamide groups (methylsulfonamide, benzenesulfonamide, etc.), sulfamoyl groups (N-methylsulfamoyl, N-phenylsulfamoyl, etc.), hydroxyl groups,
Examples thereof include a cyano group.

In the general formula [Y-I], the group represented by X ₁ which is released during the coupling reaction with the oxidation product of the developing agent is, for example, the following general formula [Y-III] or general formula [Y- IV], and particularly preferred is the group represented by the general formula [Y-IV].

[0066] In the general formula [Y-III] -OR ₆ formula, R ₆ represents an aryl group or a heterocyclic group include those having a substituent.

[0067]

[Chemical 7]

In the formula, Z ₁ is 5 or 6 in cooperation with the nitrogen atom.
It represents a group of non-metal atoms necessary for forming a member ring. For example, substituted or unsubstituted methylene and methine, = C = O, -N ( _RA )
- (R _A has the same meaning as the _{R 5), - N =,} -O-, -
S−, −SO ₂ − and the like can be mentioned.

The yellow coupler represented by the above general formula [Y-I] may be combined at R ₁ , R ₃ or Y ₁ part to form a bis form.

Particularly preferred as the yellow coupler of the present invention is a compound represented by the following general formula [YV].

[0071]

[Chemical 8]

Where R ₁ , R ₂ , R ₃ , n, J and p are
Each has the same meaning as R ₁ , R ₂ , R ₃ , and n in the general formula [Y-I] and J and p in the general formula [Y-II], and the same ones are exemplified. R ₇ is an alkylene group, an arylene group, an alkylenearylene group, an arylenealkylene group or —A—V ₁ —B— (A and B each represent an alkylene group, an arylene group, an alkylenearylene group or an arylenealkylene group, and V ₁ Represents a divalent linking group), and R ₈ represents an alkyl group, a cycloalkyl group, an aryl group or a heterocyclic group. P represents a bonding group having a carbonyl or sulfonyl unit.

X ₂ represents a group capable of splitting off upon coupling with the oxidized product of the developing agent.

In the general formula [YV], R ₇ , A or B
As the alkylene group represented by, for example, methylene, ethylene, trimethylene, butylene, hexylene, methylmethylene, ethylethylene, 1-methylethylene, 1-methyl-2-ethylethylene, 2-decylethylene, 3-hexylpropylene, etc. And straight-chain or branched groups. The alkylene group includes those having a substituent (for example, an aryl group), and examples thereof include 1-benzylethylene, 2-phenylethylene, 3-naphthylpropylene and the like.

Examples of the arylene group include phenylene and naphthylene, and the arylene group includes those having a substituent.

Examples of the alkylenearylene group include methylenephenylene and the like, and examples of the arylenealkylene group include phenylenemethylene and the like, each of which has a substituent. Examples of the divalent linking group represented by V ₁ include groups such as -O- and -S-.

Of the alkylene group, arylene group, alkylenearylene group, arylenealkylene group and -A-V ₁ -B-represented by R ₇ , an alkylene group is particularly preferable.

The alkyl group represented by R ₈ is, for example, ethyl, butyl, hexyl, octyl, 2-ethylhexyl,
Examples thereof include linear or branched ones such as dodecyl, hexadecyl, 2-hexyldecyl and octadecyl. Examples of the cycloalkyl group include cyclohexyl and the like.

Examples of the aryl group include phenyl and naphthyl. Examples of the heterocyclic group include pyridyl and the like.

The alkyl group, cycloalkyl group, aryl group and heterocyclic group represented by R ₈ include those further having a substituent.

The substituent is not particularly limited, but those exemplified as the substituent for R ₅ can be mentioned. However,
As a substituent of R ₈ , an organic group having a dissociative hydrogen atom (for example, a phenolic hydrogen atom) having a pKa value of 9.5 or less is not preferable.

P represents a bonding group having a carbonyl or sulfonyl unit, preferably a group represented by the following group [Y-VI], and preferably a bonding group represented by (6) to (9).

Group [Y-VI] (1) -COO-, (2) -N (R) CO-, (3)
−CON (R) −, (4) −N (R) CON (R ′) −, (5) −N (R)
_{COO-, (6) -SO 2 -} , (7) -N (R) SO 2 -,
(8) —SO ₂ N (R) —, (9) —N (R) SO ₂ N (R ′) — In the formula, R and R ′ are each a hydrogen atom, an alkyl group, an aryl group or a heterocyclic group. Represents

The groups represented by R and R'include the above R
_The groups exemplified in ₅ can be mentioned, and these groups include those having a substituent. Examples of the substituent include those exemplified as the above-mentioned substituents of R ₅ . R and R'are preferably hydrogen atoms.

The yellow coupler represented by the above general formula [Y-I] of the present invention is preferably 1 × 10 ⁻³ to 1 mol, and more preferably 1 × 10 ⁻² mol to 1 mol of silver halide.
It can be used in a range of 8 × 10 ^-1 mol.

Next, specific examples of the yellow coupler represented by the general formula [Y-I] are shown.

[0087]

[Chemical 9]

[0088]

[Chemical 10]

[0089]

[Chemical 11]

[0090]

[Chemical 12]

As a cyan coupler which can be preferably used in the color light-sensitive material of the present invention, JP-A-4-11 is known.
The general formula (C-I) and (C
-II) can be mentioned. Specific compounds include those described as CC-1 to CC-9 on pages 18 to 21 of the same specification.

As the magenta coupler which can be preferably used in the color light-sensitive material according to the present invention, JP-A-4-
Examples thereof include couplers represented by formula (M-I) described on page 12 of 114152. Specific compounds include those described as MC-1 to MC-7 on pages 13 to 16 of the same specification.

When the oil-in-water type emulsion dispersion method is used to add the coupler used in the color light-sensitive material of the present invention, it is usually added to a water-insoluble high-boiling point organic solvent having a boiling point of 150 ° C. or higher, if necessary. And a low-boiling point and / or water-soluble organic solvent are also used in combination to dissolve, and a surfactant is emulsified and dispersed in a hydrophilic binder such as an aqueous gelatin solution. As a dispersing means, a stirrer, a homogenizer, a colloid mill, a flow jet mixer, an ultrasonic disperser or the like can be used. After the dispersion or at the same time as the dispersion, a step of removing the low boiling point organic solvent may be added. As the high-boiling organic solvent that can be used for dissolving and dispersing the coupler, it is preferable to use the high-boiling organic solvent represented by the above general formula [H] in at least one layer of the color light-sensitive material of the present invention. Examples of the high boiling point organic solvent represented by the general formula [H] include the following compounds.

Trioctylphosphine oxide Tridodecylphosphine oxide Triphenylphosphine oxide Tri-p-butylphenylphosphine oxide Triphenylphosphate diphenyl-p-tolylphosphate Di-p-tolyl-phenylphosphate tricresyl Phosphate Trioctyl Phosphate Tridodecyl Phosphate In the present invention, phthalic acid esters such as dioctyl phthalate are preferably used in addition to the high boiling point solvent.

Further, instead of the method using a high boiling point organic solvent, the coupler and the water-insoluble and organic solvent-soluble polymer compound are dissolved in a low boiling point and / or water-soluble organic solvent, if necessary, to prepare a gelatin aqueous solution or the like. It is also possible to employ a method of emulsifying and dispersing by using various dispersing means using a surfactant in a hydrophilic binder. The water-insoluble organic solvent-soluble polymer used at this time is poly (Nt-
Butyl acrylamide) and the like.

The compound (d-11) described on page 33 of JP-A-4-114152 and the compound (A'-1) described on page 35 of the specification for the purpose of shifting the absorption wavelength of the color forming dye. Can be used. Besides, the fluorescent dye-releasing compounds described in US Pat. No. 4,774,187 can also be used.

Dyes having absorption in various wavelength regions can be used in the color light-sensitive material according to the present invention for the purpose of preventing irradiation.

In the color light-sensitive material of the present invention, it is advantageous to use gelatin as a binder, but if necessary, other gelatin, gelatin derivatives, graft polymers of gelatin and other polymers, proteins other than gelatin are used. A hydrophilic colloid such as a sugar derivative, a cellulose derivative, a synthetic hydrophilic polymer such as a homopolymer or a copolymer can also be used.

The support used in the color light-sensitive material of the present invention may be made of any material, such as white pigment-containing polyethylene-coated paper, baryta paper, vinyl chloride sheet, white pigment-containing polypropylene and polyethylene terephthalate. A support or the like can be used. Above all, a support having a polyolefin resin layer containing a white pigment on its surface is preferable.

As the white pigment used for the reflective support, inorganic and / or organic white pigments can be used, and preferably inorganic white pigments are used. For example, alkaline earth metal sulfates such as barium sulfate, alkaline earth metal carbonates such as calcium carbonate, finely divided silicic acid, silicas such as synthetic silicates, calcium silicate, alumina,
Alumina hydrate, titanium oxide, zinc oxide, talc, clay and the like can be mentioned. The white pigment is preferably barium sulfate or titanium oxide. The amount of the white pigment contained in the water-resistant resin layer on the surface of the reflective support is preferably 10% by weight or more, more preferably 13% by weight or more as the content in the water-resistant resin layer. Is preferred, and more preferably 15% by weight or more. The degree of dispersion of the white pigment in the water-resistant resin layer of the paper support according to the present invention can be determined according to
It can be measured by the method described in Japanese Patent No. 28640. When measured by this method, the degree of dispersion of the white pigment is preferably 0.20 or less, more preferably 0.15 or less, and even more preferably 0.10 or less as the coefficient of variation described in the above publication.

The color light-sensitive material according to the present invention may be subjected to corona discharge, ultraviolet ray irradiation, flame treatment or the like on the support surface, if necessary, and then directly or undercoat layer (adhesiveness of the support surface,
Applied through one or more undercoat layers for improving antistatic properties, dimensional stability, abrasion resistance, hardness, antihalation properties, friction properties and / or other properties) Good.

When coating a photographic light-sensitive material using a silver halide emulsion, a thickener may be used in order to improve coatability. As the coating method, extrusion coating and curtain coating, which can simultaneously coat two or more layers, are particularly useful.

As the aromatic primary amine developing agent used in the present invention, the compound represented by the above general formula [D] is used. The following compounds can be given as examples of the representative compounds represented by the general formula [D].

CD-1) N, N-diethyl-p-phenylenediamine CD-2) 2-amino-5-diethylaminotoluene CD-3) 2-amino-5- (N-ethyl-N-laurylamino) toluene CD -4) 4-Amino-3-methyl-N-ethyl-N- (β-butoxyethyl) aniline CD-5) 2-Methyl-4- (N-ethyl-N- (β-hydroxyethyl) amino) aniline CD -6) 4-Amino-3-methyl-N-ethyl-N- (β- (methanesulfonamido) ethyl) -aniline CD-7) N- (2-amino-5-diethylaminophenylethyl) methanesulfonamide CD -8) N, N-Dimethyl-p-phenylenediamine CD-9) 4-Amino-3-methyl-N-ethyl-N-methoxyethylaniline CD-10) 4-Amino-3-methyl-N-ethyl- N- (β-ethoxyethyl) aniline CD-11) 4-amino-N-ethyl-N- (β-ethoxyethyl)
To the aniline color developer, a known developer component compound can be added in addition to the color developing agent. Usually pH
A buffering alkali agent, a chloride ion, a development inhibitor such as benzotriazole, a preservative, and a chelating agent are used.

The color light-sensitive material of the present invention, after color development,
Bleached and fixed. The bleaching process may be performed simultaneously with the fixing process. After the fixing process, a washing process is usually performed. Further, as a substitute for the water washing treatment, a stabilizing treatment may be performed. As a development processing apparatus used for the development processing of the color photosensitive material of the present invention, even if it is a roller transport type that conveys the photosensitive material by sandwiching it between rollers arranged in a processing tank, the photosensitive material is fixed to a belt. It may be an endless belt method of conveying, but a method of forming the processing tank in a slit shape and supplying the processing liquid to the processing tank and conveying the photosensitive material, a spray method of spraying the processing liquid, and a processing A web method by contact with a carrier impregnated with a liquid, a method by a viscous treatment liquid, or the like can also be used. The roller transport type is preferable in terms of stability and convenience and cost.

[0106]

EXAMPLES The present invention will be described in detail below with reference to examples, but the present invention is not limited thereto.

Example 1 (Preparation method of blue-sensitive silver chlorobromide emulsion) Sodium thiosulfate emulsion having an average particle size of 0.7 μm and a silver bromide content of 80 mol% was optimally used at 57 ° C. Sensitize and sensitize dye (BS-1)
And STAB-1 was added as a stabilizer to obtain Em-B1.

Emulsion Em-B2 (increased sensitizing dye amount) was used under the same conditions except that the sensitizing dye amount was 1.2 times, and the grain size was changed from 0.7 μm to 0.95.
Em-B3 was prepared under the same conditions except that the thickness was changed to μm.

(Preparation method of green-sensitive silver chlorobromide emulsion) A silver chlorobromide emulsion having an average grain size of 0.5 μm and a silver bromide content of 80 mol% was optimally sensitized at 59 ° C. with sodium thiosulfate. , Sensitizing dye (GS-1) and STAB-1 as a stabilizer,
Obtained Em-G1.

(Preparation method of red-sensitive silver chlorobromide emulsion) Sodium thiosulfate, sensitizing dye (RS-1) and phenol were added to a silver chlorobromide emulsion having an average particle size of 0.4 μm and a silver bromide content of 80 mol%. Optimally sensitized at 60 ° C using resin, STA as a stabilizer
B-1 was added to obtain Em-R1.

(Preparation method of blue-sensitive silver chloride emulsion) In 1000 ml of 2% gelatin aqueous solution kept at 40 ° C., the following (solution A) and (solution B) were adjusted to pAg = 6.5 and pH = 3.0 for 30 minutes. And added simultaneously, and then the following (solution C) and (solution D) were added to pAg =
Simultaneous addition was carried out over 180 minutes while controlling 7.3 and pH = 5.5.

At this time, the pAg was controlled by the method described in JP-A-59-45437, and the pH was controlled by using an aqueous solution of sulfuric acid or sodium hydroxide.

(Solution A) Water is added to 3.42 g of sodium chloride and 0.03 g of potassium bromide to make 200 ml. (Solution B) Add water to 10 g of silver nitrate to make 200 ml.

(C liquid) Water is added to 102.7 g of sodium chloride and 1.0 g of potassium bromide to make 600 ml. (Solution D) Add water to 300 g of silver nitrate to make 600 ml.

After the addition is completed, Demol N manufactured by Kao Atlas Co., Ltd.
Desalination was performed using a 5% aqueous solution of magnesium sulfate and a 20% aqueous solution of magnesium sulfate, and then mixed with a gelatin aqueous solution to obtain an average particle size of 0.
A monodisperse cubic emulsion EMP-1 having a particle diameter distribution variation coefficient of 0.07 and a silver chloride content of 99.5 mol% was obtained.

The following compounds were used for EMP-1 above.
Optimal chemical sensitization was carried out at ℃ to obtain a blue-sensitive silver halide emulsion (Em-B4).

Sodium thiosulfate 0.8 mg / mol AgX chloroauric acid 0.5 mg / mol AgX stabilizer STAB-1 6 × 10 ⁻⁴ mol / mol AgX sensitizing dye BS-1 4 × 10 ⁻⁴ mol / mol AgX sensitization Dye BS-2 1 × 10 ⁻⁴ mol / mol AgX Em-G2 and Em-R2 were prepared by the following method. In addition,
The structures of the stabilizer and the sensitizing dye are shown below.

(Preparation Method of Green-Sensitive Silver Chloride Emulsion) Addition Time of (A Solution) and (B Solution) and (C Solution) and (D Solution)
The same as EMP-1 except that the addition time was changed to an average particle size of 0.43 μm, a coefficient of variation of 0.08, and a silver chloride content of 99.5%.
A monodisperse cubic emulsion EMP-2 of was obtained.

The following compounds were used for the above EMP-2:
Optimum chemical sensitization at ℃, green sensitive silver chloride emulsion (Em-
G2) got.

Sodium thiosulfate 1.5 mg / mol AgX chloroauric acid 1.0 mg / mol AgX stabilizer STAB-1 6 × 10 ⁻⁴ mol / mol AgX sensitizing dye GS-1 4 × 10 ⁻⁴ mol / mol AgX (red Method for preparing sensitive silver chloride emulsion) Average particle size 0.50 μm in the same manner as EMP-1 except that the addition time of (A solution) and (B solution) and the addition time of (C solution) and (D solution) were changed. , Emulsion monodisperse cubic emulsion with coefficient of variation of 0.08 and silver chloride content of 99.5%
-3 was obtained.

Further, the following metal compounds were added to the above (C liquid).

K ₂ IrCl ₆ 3.8 × 10 ^-8 mol / mol AgX K ₄ Fe (CN) ₆ 1.2 × 10 ^-5 mol / mol AgX For the above EMP-3, the following compounds were used to optimize the chemistry. Sensitization was carried out to obtain a red-sensitive silver halide emulsion (Em-R2).

Sodium thiosulfate 1.8 mg / mol AgX chloroauric acid 2.0 mg / mol AgX stabilizer STAB-1 6 × 10 ⁻⁴ mol / mol AgX sensitizing dye RS-2 1 × 10 ⁻⁴ mol / mol AgX (halogen Preparation of silver halide color light-sensitive material) As a support, a paper support (thickness: 230 μm) having a surface coated with polyethylene containing titanium oxide and a back surface coated with polyethylene is provided with the following first to seventh layers. Further, a back layer was coated on the back surface to prepare a color light-sensitive material sample 1.

The addition amount is shown in g / m ² . However, the silver halide emulsion is shown in terms of silver equivalent.

Layer composition Coating amount Seventh layer Gelatin 1.0 (Protective layer) Silica (average particle size 3 μm) 0.03 Color mixing inhibitor (HQ-2) 0.01 Color mixing inhibitor (HQ-3) 0.01 Sixth layer Gelatin 0.4 ( Intermediate layer) UV absorber (UV-1) 0.2 UV absorber (UV-2) 0.2 UV absorber (UV-3) 0.2 Color mixing inhibitor (HQ-1) 0.01 Solvent (SO-3) 0.2 PVP 0.2 Irager Anti-dye (AI-1) 0.07 Fifth layer Gelatin 1.3 (red sensitive layer) Red-sensitive silver chlorobromide emulsion spectrally sensitized with sensitizing dye (RS-1) Em-R1 (Br 80 mol%, Cl 20 mol%) 0.22 Cyan coupler (C-1) 0.3 Solvent (SO-1) 0.15 Color mixing inhibitor (HQ-1) 0.02 Fourth layer Gelatin 0.6 (Intermediate layer) Color mixing inhibitor (HQ-1) 0.01 Color mixing inhibitor (HQ-2) 0.01 Solvent (SO-3) 0.2 Irradiation prevention dye (AI-2) 01 Third layer Gelatin 1.2 (Green-sensitive layer) Green-sensitive silver chlorobromide emulsion Em-G1 (Br 80 mol%, Cl 20 mol%) 0.35 Magenta coupler (spectral sensitized with sensitizing dye (GS-1) M-1) 0.2 Color tone adjusting agent (MY-1) 0.05 Color mixing inhibitor (HQ-1) 0.02 Solvent (SO-1) 0.4 Second layer gelatin 0.6 (Intermediate layer) Color mixing inhibitor (HQ-1) 0.02 Solvent ( SO-3) 0.2 Anti-irradiation dye (AI-3) 0.03 First layer Gelatin 1.2 (blue-sensitive layer) Blue-sensitive silver chlorobromide emulsion Em-B1 spectrally sensitized with a sensitizing dye (BS-1) (Br 80 mol%, Cl 20 mol%) 0.35 Yellow coupler (EX-Y1) 0.4 Color mixing inhibitor (HQ-1) 0.02 Solvent (SO-1) 0.38 Back layer Gelatin 6.0 Silica (average particle size 3 μm) 0.1 SA-1 and SA-2 were used as coating aids, and H-1 was used as a hardener.

The blue photosensitive emulsion used in the first layer, the green photosensitive emulsion in the third layer, the red photosensitive emulsion in the fifth layer and the coupler in each layer were replaced by equimolar amounts as shown in Table 1 and Table 2, respectively. Table 2
Each sample shown in was prepared.

Sample 10 has a yellow colloidal silver layer (YC) in the middle of the fourth layer and the third layer with the fifth layer and the first layer being exchanged.
Layer), and further, an intermediate layer was provided between the third layer and the newly provided YC layer to form a total of 9 layers.

Yellow layer Gelatin 0.42 (colloidal silver layer) Yellow colloidal silver 0.1 Color mixture inhibitor (HQ-2) 0.04 Solvent (SO-2) 0.049 PVP 0.047 Intermediate layer gelatin 0.54 Color mixture inhibitor (HQ-2) 0.055 Solvent (SO -2) 0.072 The structures of the compounds used are shown below.

[0129]

[Chemical 13]

[0130]

[Chemical 14]

[0131]

[Chemical 15]

[0132]

[Chemical 16]

PVP: Polyvinylpyrrolidone SO-1: Trioctyl phosphate SO-2: Dioctyl phthalate SO-3: Di (2-ethylhexyl) sebacate HQ-1: 2,5-di-t-butylhydroquinone HQ-2: 2 , 5-Di-t-octylhydroquinone HQ-3: 2-methyl-5-hexadecenylhydroquinone SA-1: Sodium di (2-ethylhexyl) sulfosuccinate SA-2: Di (2,2 sulfosuccinate) , 3,3,4,4,5,5-Octafluoropentyl) sodium STAB-1: 1- (3-acedamido) phenyl-5-mercaptotetrazole H-1: 2,4-dichloro-6-hydroxy-s -Triazine / sodium These obtained samples were exposed by a conventional method and treated in the treatment step 1 shown below.

(Processing step 1) Processing step Processing temperature time Color development 35.0 ± 0.3 ° C 120 seconds Bleach fixing 35.0 ± 0.5 ° C 45 seconds Stabilization 30-34 ° C 90 seconds Dry 60-80 ° C 30 seconds (Coloring developer ) Benzyl alcohol 15 ml Ce ₂ (SO ₄ ) ₃ 0.015 g Ethylene glycol 8.0 ml Potassium sulfite 2.5 g Potassium bromide 0.6 g Sodium chloride 0.2 g Potassium carbonate 25.0 g 4-Hydroxy-6-methyl-1,3,3a, 7- Tetrazaindene 0.1g Hydroxylamine sulfate 5.0g Diethylenetriamine pentasodium acetate 2.0g 4-Amino-N-ethyl-N- (β-hydroxyethyl) aniline sulfate 4.5g Optical brightener (4,4'-diaminostilbene Disulfonic acid derivative) 1.0 g Potassium hydroxide 2.0 g Diethylene glycol 15.0 ml Add water to make the total volume 1 l and adjust the pH to 10.15.

(Bleach-fixing solution) Diethylenetriamine 5 ferric ammonium acetate 90.0 g Diethylenetriamine 5 acetic acid 3.0 g Ammonium thiosulfate (70% aqueous solution) 180 ml Ammonium sulfite (40% aqueous solution) 27.5 ml 3-Mercapto-1,2,4-triazole Adjust the pH to 7.1 with 0.15 g potassium carbonate or glacial acetic acid and add water to make the total volume 1 l. (Stabilizing solution) O-Phenylphenol 0.3g Potassium sulfite (50% aqueous solution) 12ml Ethylene glycol 10g 1-Hydroxyethylidene-1,1-disulfonic acid 2.5g Bismuth chloride 0.2g Zinc sulfate 7-hydrate 0.7g Ammonium hydroxide (28% aqueous solution) 2.0 g Polyvinylpyrrolidone (K-17) 0.2 g Optical brightener (4,4'-diaminostilbene disulfonic acid derivative) 2.0 g Add water to make the total volume 1 l, and add ammonium hydroxide or sulfuric acid to pH. To 7.5. The stabilization treatment was a countercurrent system with a two tank structure.

The processed samples were evaluated as follows. The results are shown in Table 2.

The hue is measured by the color difference meter CR- manufactured by Minolta.
Performed using 121.

Δθ represents an angle deviation on the ab plane of the Lab color table when the dot gain is increased from the standard density by 3.

ΔL represents a deviation of L when the dot gain is increased by 3 from the standard density. Note that the standard print yellow density is 0.96 to 1.09, and the standard print dot gain (50% halftone dot 133 line / inch) is 22. The density is based on the standard print dot gain. Represents the solid density of.

[0140]

[Table 1]

[0141]

[Table 2]

As shown in Table 2, when the dot gain is increased by using the color light-sensitive material having the gradation and the sensitivity difference of the present invention, the hue deviation (Δθ) is small and the lightness is decreased (Δ
L) was low.

The samples 13, 14, 15 were treated in the same manner as in the treatment step 2 shown below, and evaluated in the same manner.
The effect of the present invention was obtained.

(Processing step 2) Processing step Processing temperature Time Color development 35.0 ± 0.3 ° C. 45 seconds Bleach fixing 35.0 ± 0.5 ° C. 45 seconds Water washing 30-34 ° C. 90 seconds Drying 60-80 ° C. 60 seconds Shown in.

(Color developer) Pure water 800 ml Triethanolamine 10 g N, N-diethylhydroxylamine 5 g Potassium bromide 0.02 g Potassium chloride 2 g Potassium sulfite 0.3 g 1-Hydroxyethylidene-1,1-diphosphonic acid 1.0 g Ethylenediamine tetra Acetic acid 1.0 g Catechol-3,5-diphosphonate disodium 1.0 g 4-Amino-N-ethyl-N- (β-hydroxyethyl) aniline sulfate 4.5 g Optical brightener (4,4'-diaminostilbene sulfonic acid Derivative) 1.0 g Potassium carbonate 27 g Add water to make the total volume 1 liter and adjust to pH = 10.10.

(Bleach-fixing solution) ethylenediaminetetraacetic acid ammonium ferric dihydrate 60 g ethylenediaminetetraacetic acid 3 g ammonium thiosulfate (70% aqueous solution) 100 ml ammonium sulfite (40% aqueous solution) 27.5 ml Adjust to pH = 5.7 with potassium carbonate or glacial acetic acid.

(Washing liquid) 5-chloro-2-methyl-4-isothiazolin-3-one 1.0 g Ethylene glycol 1.0 g 1-Hydroxyethylidene-1,1-diphosphonic acid 2.0 g Ethylenediaminetetraacetic acid 1.0 g Ammonium hydroxide ( 20% aqueous solution) 3.0 g Optical brightener (4,4'-diaminostilbene sulfonic acid derivative) 1.5 g Water is added to bring the total volume to 1 liter, and pH is adjusted to 7.0 with sulfuric acid or potassium hydroxide.

Further, when a sample using a support having the same layer structure as Samples 1, 4, 7, 9 and 11 and a thickness of 130 μm was prepared and the same evaluation was carried out, the effect of the present invention was obtained.

Example 2 Furthermore, the amount of the sensitizing dye added during the chemical sensitization of Em-B4, Em-G2, and Em-R2 was increased by 10% to obtain high-sensitivity emulsion emulsions Em-B5 and Em-B5.
-G3 and Em-R3 were created. Samples 18, 19 and 20 were prepared by adjusting the coating amount of emulsion with the composition of Em-5. Samples 20-25 are Em
-B4 and Em-B5, Em-G2 and Em-G3, and Em-R2 and Em-R3 were mixed and used, and the gradation was adjusted by changing the mixing ratio. The prepared sample was exposed in the same manner as in Example 1 and treated in the treatment step 2, and in the same manner as in Example 1, the hue shift (Δθ) and the decrease in lightness (ΔL) were evaluated. Further, the solid density was measured and evaluated, and the results are also shown in Table 3. In Table 3, DR, DG, DB, and DK represent solid densities of cyan, magenta, yellow, and black, respectively.

[0150]

[Table 3]

As shown in Table 3, by adjusting the main gradation and the shoulder gradation within the range of the present invention, the solid density of each color of yellow, magenta, cyan and black is close to the standard value and the black density is sufficient. Higher and higher contrast images were obtained.
In particular, when the shoulder gradation is 1.8 or more, the tightness of black becomes very good, the hue shift (Δθ) and the decrease in lightness are small, and the image quality is improved.

[0152]

EFFECTS OF THE INVENTION When a color proof is prepared from halftone image information obtained by color separation and halftone image conversion using a silver halide color light-sensitive material, the image quality is not deteriorated.
A method of making a color proof with adjustable dot gain was obtained.

Continuation of front page (51) Int.Cl. ⁵ Identification code Office reference number FI Technical display location G03C 7/42 G03F 3/10 B 8004-2H

Claims (9)

[Claims] 1. A blue light-sensitive silver halide emulsion layer containing a yellow coupler, a green light-sensitive silver halide emulsion layer containing a magenta coupler, and a red light-sensitive silver halide containing a cyan coupler on a reflective support. In a silver halide color light-sensitive material having an emulsion layer and forming a yellow dot image by blue light, the sensitivity of the blue light-sensitive silver halide emulsion layer to blue light is (S _B ) _B , and the green light-sensitive halogen is When the sensitivity of the silver halide emulsion layer to blue light is (S _G ) _B and the sensitivity of the red light-sensitive silver halide emulsion layer to blue light is (S _R ) _B , the following sensitivity ratios are obtained: _G ) _B / (S _B ) _B ≤0.1 (S _R ) _B / (S _B ) _B ≤0.1 and the main gradation of the yellow image (the minimum density of the yellow image
(Dmin) +0.5 ~ average density between minimum density + 1.1) is 1.7 ~
A method for producing a color proof using a silver halide color light-sensitive material, characterized in that it is 2.8. 2. The color proof making method according to claim 1, wherein the wavelength of the blue light is 350 to 500 nm. 3. The method for producing a color proof according to claim 1, wherein the main gradation is 2.0 to 2.6. 4. The method for producing a color proof,
Shoulder gradation of yellow image (Minimum density of yellow image (Dmin)
2. The method for producing a color proof according to claim 1, wherein a silver halide color light-sensitive material is characterized in that the average gradation between +1.4 and the minimum density +1.7) is 1.6 or more. 5. The main gradation of 1.7 to 2.8 shown in claim 1.
Is determined by processing in the following processing steps. (Processing step) Processing temperature Time Color development 35.0 ± 0.3 ℃ 45 seconds Bleach fixing 35.0 ± 0.5 ℃ 45 seconds Water wash 30-34 ℃ 90 seconds Dry 60-80 ℃ 60 seconds (Color developer) Pure water 800ml Triethanolamine 10g N, N-Diethylhydroxylamine 5g Potassium bromide 0.02g Potassium chloride 2g Potassium sulfite 0.3g 1-Hydroxyethylidene-1,1-diphosphonic acid 1.0g Ethylenediaminetetraacetic acid 1.0g Catechol-3,5-diphosphonate disodium 1.0 g 4-Amino-N-ethyl-N- (β-hydroxyethyl) aniline sulfate 4.5g Optical brightener (4,4'-diaminostilbene sulfonic acid derivative) 1.0g Potassium carbonate 27g Add water to make 1 Adjust to pH = 10.10 in liters. (Bleach-fixing solution) Ethylenediaminetetraacetic acid ammonium ferric dihydrate 60 g Ethylenediaminetetraacetic acid 3 g Ammonium thiosulfate (70% aqueous solution) 100 ml Ammonium sulfite (40% aqueous solution) 27.5 ml Add water to bring the total volume to 1 liter and add potassium carbonate or Adjust to pH = 5.7 with glacial acetic acid. (Washing liquid) 5-chloro-2-methyl-4-isothiazolin-3-one 1.0 g Ethylene glycol 1.0 g 1-Hydroxyethylidene-1,1-diphosphonic acid 2.0 g Ethylenediaminetetraacetic acid 1.0 g Ammonium hydroxide (20% aqueous solution) ) 3.0 g Optical brightener (4,4'-diaminostilbene sulfonic acid derivative) 1.5 g Water is added to bring the total volume to 1 liter, and pH is adjusted to 7.0 with sulfuric acid or potassium hydroxide. 6. The blue-sensitive silver halide emulsion layer, the green-sensitive silver halide emulsion layer and the red-sensitive silver halide emulsion layer each have at least a silver chloride content of 80% or more. The method for producing a color proof according to claim 1, wherein the silver halide color light-sensitive material is 7. A silver halide color light-sensitive material containing a yellow coupler represented by the following general formula [Y-I] in the blue light-sensitive silver halide emulsion layer. How to make a color proof. [Chemical 1] In the formula, R ₁ represents an alkyl group, a cycloalkyl group or an aryl group, R ₂ represents an alkyl group, a cycloalkyl group, an acyl group or an aryl group, and R ₃ represents a group capable of substituting on the benzene ring. n represents 0 or 1. X ₁ represents a hydrogen atom or a group capable of splitting off upon coupling with an oxidized product of a developing agent, and Y ₁ represents an organic group. 8. The silver halide color light-sensitive material according to claim 1, wherein at least one layer of the silver halide color light-sensitive material contains a high boiling point solvent represented by the following general formula [H]. How to make a color proof. [Chemical 2] In the formula, R ₁₁ , R ₁₂ , and R ₁₃ each represent an alkyl group, a cycloalkyl group, or an aryl group, and p, q, and r each represent 0 or 1. 9. A silver halide color light-sensitive material according to claim 1, 3, 4, 6, 7 or 8 is represented by the following general formula [D]:
A method for producing a color proof, which comprises treating with a color developing solution containing [Chemical 3] In the formula, R ₂₁ represents a hydrogen atom or an alkyl group, R ₂₂ represents an alkyl group, and R ₂₃ represents an alkylene group.