JPH06270344A - Deodorizing seal used to be bonded to timepiece - Google Patents

Abstract

PURPOSE:To provide a deodorizing seal capable of removing the offensive smell of the hand or arm generated by sweat when the deodorizing seal is used in the state bonded to the surface of a portable timepiece by imparting deodorizing function to the transparent seal used to be the bonded to a timepiece having an image such as a calendar recorded thereon. CONSTITUTION:A hologram image 12 is recorded on a transparent film 11 and a reflecting layer 13 such as a metal membrane is provided on the hologram image to form a hologram image forming layer and, next, a self-adhesive layer 14 is formed on the reflecting layer 13 and a separately formed deodorizer added film is bonded to the layer 14 to form a deodorant layer 15. Further, a self-adhesive 14 is applied to pasteboard 16 coated with a release agent to be bond to the obtained laminated film to form a laminated sheet having deodorizing function. As the transparent film 11 on which the hologram image 12 is formed, an extremely thin film having relatively flexible material quality is used.

Description

Detailed Description of the Invention

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a hologram calendar sticker having a deodorizing function using a transparent hologram, and particularly when the hologram calendar sticker is used by being stuck on the surface of a mobile watch or the like, it is generated by sweat or the like. The present invention relates to a deodorant sticker for affixing a watch that can remove odors from hands and arms.

[0002]

2. Description of the Related Art Conventionally, a hologram calendar using a transparent hologram is attached to a transparent protective plate of a portable watch or the like using an adhesive layer so that both the dial and the calendar of the watch can be seen. It has become. That is, when the watch dial is viewed, it can be seen through the transparent hologram forming layer, and when the watch dial is viewed from an angle of about 45 °, the calendar of the hologram image can be viewed. . Most hologram calendars are used by sticking about one month on the transparent protective plate of the watch, but hologram calendars are pasted on a backing sheet that has been subjected to adhesive processing and making a cut for each month for one year Therefore, after January, the method of selecting the necessary month calendar from the mount and replacing it with the previous month's calendar was taken.

[0003]

A conventional sticker attached to a timepiece protects the glass surface of the timepiece and uses a transparent hologram calendar so that both the time and the calendar can be seen. No deodorizing function is provided to eliminate the odor caused by sweating.

[0004]

[Means for Solving the Problems] In a transparent sticker for sticking such as a watch in which a transparent hologram image such as a calendar is recorded on a transparent film or sheet, a deodorant layer and an adhesive layer are provided on the transparent sticker to provide a deodorant function. It is configured so that it can be attached and attached to a watch or the like. Hereinafter, it will be described in more detail with reference to the drawings. The conventional transparent hologram calendar for sticking clocks is made by recording a hologram image calendar on a transparent film, forming a reflective layer of a metal thin film on this, applying an adhesive, and pasting release paper. However, according to the present invention, in order to add a deodorizing function to the structure shown in FIG.
And the configuration shown in FIG. That is, in the case of FIG. 1, the hologram image 12 is recorded on the transparent film 11,
A reflection layer 13 such as a metal thin film is provided on the hologram image to form a hologram image forming layer, and then the adhesive layer 1
4 was formed, and a deodorant-added film prepared separately was laminated to form a deodorant layer 15. Further, the pressure sensitive adhesive 14 was applied to the mount 16 coated with the release agent, and the laminated films were stuck together to produce a laminated sheet having a deodorizing function. In addition, when a transparent film 11 for recording the hologram image 12 is made of a relatively soft material or a very thin film and the hologram image forming layer is easily affected by the outside, in order to protect it from damage due to external force, As a protective film, a film having high mechanical strength is attached to the upper layer of transparent film 11 (the side opposite to the hologram image forming layer) with an adhesive to produce a transparent hologram calendar seal. At the time of use, the transparent hologram calendar seal having the above deodorizing function is peeled off from the mount and attached to the watch. In this state, the transparent film 11 on which the hologram image on the upper surface is recorded acts as a protective function and cannot exert the deodorizing function, but when the film is peeled off, the protective function is lost and the deodorizing function is exerted. Therefore,
If you get an odor due to perspiration, grab the transparent film 11,
If this is peeled off, it is peeled off between the pressure-sensitive adhesive layer 14 and the deodorant layer 15, and the deodorant layer 15 remaining on the watch side is exposed on the surface to absorb the odor.

In the case of FIG. 2, a hologram image 12 is recorded on the transparent film 11, and a reflection layer 13 such as a metal thin film is provided on the hologram image to form a hologram image forming layer. Further, an adhesive 17 is applied to the upper layer of the transparent film 11 (on the side opposite to the hologram image forming layer), and the above deodorant-added film is attached to the adhesive layer 17 to form a deodorant layer 15 to produce a laminated film. To do. Next, the pressure sensitive adhesive 14 is applied to the protective film 18, the laminated films are bonded together, and the mount paper 16 coated with the release agent is subjected to pressure sensitive adhesive processing to bond the hologram image forming surface of the transparent film 11 to each other. A laminated sheet having a deodorizing function was produced. In use, as in the case of FIG. 1, the mount 1
The transparent hologram calendar sticker having the deodorizing function is peeled off from 6 and attached to a watch. Next, if the transparent protective film 18 on the upper surface is peeled off, the deodorizing function can be exerted. In the configuration of FIG. 2, even if the transparent protective film 18 is peeled off, the hologram image remains, so if the deodorant layer 15 is made of a transparent film, the deodorant function is maintained and the timepiece dial and calendar are kept. You can see both.

In order to produce a deodorant-added film, a film-forming resin such as polyethylene, polypropylene, ethylene-vinyl acetate copolymer, etc., and a porous material such as Celite, zeolite, molecular sieve, activated alumina, silica, acid clay, etc. Fine minerals, or chemical deodorants such as calcium oxide, potassium chlorate, sodium bromate, potassium bromate, sodium hypochlorite, etc., or fine powders of chemical deodorants adsorbed on porous inorganic substances (0.5 ~ 30 μm) 0.1
5% is added and kneaded, and a film is formed by a T-die method or an inflation method. In order to enhance the deodorizing effect of the deodorizing film, the particles of the deodorizing agent may be made larger and the addition amount may be increased.
If the added amount is increased, the transparency will be reduced. Therefore, it is necessary to determine the addition amount and the particle size depending on the purpose of use. Further, if a bactericidal agent or an antibacterial agent is added in place of the deodorant to produce an antibacterial film and used for the above-mentioned seal, it can be used as a bacteriostatic seal for a transparent protective plate of a watch.

As the material of the transparent film for recording the hologram image, polyolefin resin such as polyethylene and polypropylene, polystyrene resin, polyester resin, acrylic resin, (meth) acrylic acid ester resin, vinyl chloride resin, ethylene Vinyl acetate copolymers, cellulosics, etc. can be used. The resin can be used as the material of the protective film.

[0008]

According to the present invention, it is possible to eliminate the odor generated by the sweating action and the like and to alleviate the unpleasant sensation only by attaching the sticker to the portable watch or the like.

[0009]

EXAMPLES Next, the present invention will be described in detail based on examples. The first example shows the case where a porous inorganic material is used for the deodorant layer. Particle size 1 for low density polyethylene
2% of powder of molecular sieve having a thickness of μm was added and kneaded, and a deodorant-added film having a thickness of 30 μm was produced by an inflation method. Next, as shown in FIG. 1, a polyethylene terephthalate film (hereinafter referred to as a PET film) 25 μm was used as a transparent film 11, and a hologram image 12 of a calendar recorded by a relief hologram method and a reflection layer 13 made of a metal thin film were formed on one surface of the film. Is formed, and the acrylic adhesive 14 is applied thereon in an amount of 30 μm as a dry coating amount. After the drying, the deodorant-added film 15 is laminated, and the silicone-treated mount 16 is coated with the acrylic adhesive as described above. After being applied to and dried, the laminated film was laminated on the surface of the deodorant layer 15 to prepare a transparent hologram calendar sheet 1 having a deodorizing function having the configuration shown in FIG. As shown in FIG. 3, the transparent hologram calendar sheet having the deodorizing function was provided with a notch 19 every month as shown in FIG. 3 so that it could be easily peeled off when it was attached to a timepiece. In the calender sheet 1 having the deodorizing function, the PET film and the backing sheet act as protective functions, and the deodorizing function is maintained in the storage state. Also, even if the hologram calendar sticker 2 is peeled off from the mount and attached to the mobile watch, the PET film on which the hologram image is formed acts as a protective function, and the deodorizing function cannot be exerted. It disappears, and it comes to exert the deodorizing function. Therefore, when an odor is generated due to sweating or the like, the film is peeled off so that the deodorant layer absorbs the odor.

The second embodiment shows the case of using a material in which a chemical deodorant is impregnated in an inorganic material. First, a zeolite having a particle size of 1 μm was immersed in a potassium bromate solution, and the dry weight of the zeolite was made to contain about 5% potassium bromate. This zeolite was added to low density polyethylene in an amount of 1% and kneaded to prepare a 20 μm deodorant-added film by an inflation method. Next, in the same manner as in Example 1, the hologram image 12 of the calendar and the reflective layer 13 made of a metal thin film are formed on the PET film 11, and the adhesive 17 is applied to the side opposite to the hologram image forming surface to add the deodorant. Film 15 was laminated. Furthermore, in order to maintain the deodorant function for a long time in the storage state of the deodorant layer, an adhesive was applied to a PET film 12 μm as a protective film in the same manner as in the first example, and the deodorant-added film surface of the laminated film was applied. Pasted together At the same time, a transparent hologram calendar sheet 1 having the structure shown in FIG. 2 was prepared by applying a pressure sensitive adhesive to a mount 16 coated with a release agent on the hologram image forming surface of the laminated film and laminating it. Further, as in the first embodiment, the transparent hologram calendar sheet having the above deodorizing function is provided with a notch 19 every month as shown in FIG. 3 so that it can be easily peeled off when it is attached to a timepiece. When the calendar sticker 2 having the deodorizing function is peeled from the mount and attached to the mobile watch, the hologram calendar remains even if the PET film 18 of the protective film is peeled off to exert the deodorizing function. You can see both the dial and the calendar.

[0011]

EFFECTS OF THE INVENTION According to the present invention, the odor caused by sweating or the like can be absorbed and the unpleasant sensation can be alleviated by simply attaching the calendar sticker having the deodorizing function to the portable timepiece. By adding a deodorizing function to the calendar seal, it can be differentiated from the conventional calendar seal and the image of hygiene can be improved.

[Brief description of drawings]

FIG. 1 is a sectional view showing a structure of a calendar sheet according to a first embodiment.

FIG. 2 is a sectional view showing a structure of a calendar sheet according to a second embodiment.

FIG. 3 is a plan view of a calendar sheet according to the present invention.

FIG. 4 is a plan view of a hologram calendar seal according to the present invention.

[Explanation of symbols]

 1 Calendar Sheet 2 Hologram Calendar Sticker 11 Transparent Film 12 Hologram Image 13 Reflective Layer 14 Adhesive Layer 15 Deodorant Layer 16 Mount 17 Adhesive Layer 18 Transparent Protective Film 19 Notch

Claims (1)

[Claims] 1. A deodorant sticker for timepiece sticking, comprising a transparent film or sheet having a transparent hologram image such as a calendar recorded thereon for sticking a watch or the like, wherein the transparent sticker is provided with a deodorizing function.