JPH0625996A - Base paper for offset printing coated paper - Google Patents

Base paper for offset printing coated paper

Info

Publication number
JPH0625996A
JPH0625996A JP19892592A JP19892592A JPH0625996A JP H0625996 A JPH0625996 A JP H0625996A JP 19892592 A JP19892592 A JP 19892592A JP 19892592 A JP19892592 A JP 19892592A JP H0625996 A JPH0625996 A JP H0625996A
Authority
JP
Japan
Prior art keywords
paper
coated
base paper
pulp
weight
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP19892592A
Other languages
Japanese (ja)
Inventor
Ryuji Ouchi
龍二 大内
Masatoshi Kako
正年 加来
Hisao Osogoshi
久男 獺越
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
New Oji Paper Co Ltd
Original Assignee
New Oji Paper Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by New Oji Paper Co Ltd filed Critical New Oji Paper Co Ltd
Priority to JP19892592A priority Critical patent/JPH0625996A/en
Publication of JPH0625996A publication Critical patent/JPH0625996A/en
Pending legal-status Critical Current

Links

Abstract

PURPOSE:To obtain base paper for offset printing coated paper having excellent folding endurance and improved in blister resistance using an inexpensive material by adding specific amounts of cationic starch and polyacrylamide to pulp and making the mixture into paper. CONSTITUTION:0.3-1.5wt.% cationic starch and 0.1-1.0wt.% acrylamide based on oven-dry weight of pulp are added to pulp and further, light calcium carbonate, aluminium sulfate and a yield improver are added thereto and the mixture is made into paper by a Fourdrinier multicylindrical drier type paper machine, etc., and starch and an additive sizing agent are applied to the resultant paper and the paper is dried to provide objective base paper for offset printing having >=40g/m<2> oven-dry basis weight and excellent blister resistance and folding strength. This base paper is used in order to produce coated paper for offset printing by applying a coating liquid consisting essentially of a pigment and an adhesive to both sides of the base paper in an amount of 6g/m<2> (oven-dry weight) per one side.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明はセルロースパルプからな
る原紙の片面または両面に顔料と接着剤を主成分とする
塗工液をコーターを用いて塗工してなるオフセット印刷
用塗工紙の製造に使用する原紙に関する。さらに詳しく
述べると、本発明は折り割れ強度に優れ、かつ、耐ブリ
スター性が改善された印刷用塗工紙を製造するための原
紙に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to the production of a coated paper for offset printing, which comprises coating a coating liquid containing a pigment and an adhesive as a main component on one or both sides of a base paper made of cellulose pulp using a coater. Regarding the base paper used for. More specifically, the present invention relates to a base paper for producing a coated paper for printing which has excellent folding cracking strength and improved blister resistance.

【0002】[0002]

【従来の技術】近年、出版広告宣伝等の媒体として印刷
物の重要性が再認識され、印刷物のビジュアル化、カラ
ー化、高級化が進められて来ており、それに伴なって顔
料塗工紙(以下、塗工紙という)の需要が増している。
特にその中でも、多色印刷に最も広く使われているオフ
セット印刷用塗工紙の需要が多い。
2. Description of the Related Art In recent years, the importance of printed matter has been re-recognized as a medium for publication, advertisement, etc., and visualization, colorization, and high quality of printed matter have been promoted. Demand for coated paper) is increasing.
In particular, there is a great demand for coated paper for offset printing, which is most widely used for multicolor printing.

【0003】オフセット印刷は版からインキを直接紙に
印刷しないで、一旦ブランケットと称するゴム面に転写
し、ブランケットから紙に印刷し、次いで乾燥して印刷
紙を製造するものである。従来、オフセット印刷用塗工
紙の原紙の原料としては、針葉樹晒クラフトパルプ(N
BKP)、広葉樹晒クラフトパルプ(LBKP)が用い
られていたが、最近になって原価低減、不透明度の改
良、パルプのリサイクル使用などの目的から高歩留りパ
ルプ、古紙を原料とした脱墨古紙パルプが用いられるよ
うになって来たのは周知の通りである。
In offset printing, ink is not directly printed on a plate, but is transferred to a rubber surface called a blanket, printed on the blanket, and then dried to produce a printing paper. Conventionally, as a raw material for base paper of coated paper for offset printing, conifer bleached kraft pulp (N
BKP) and hardwood bleached kraft pulp (LBKP) have been used, but recently, for the purpose of cost reduction, improvement of opacity, recycled use of pulp, etc., high-yield pulp, deinked waste paper pulp made from waste paper It is well known that has come to be used.

【0004】塗工原紙には、目的とする用途に応じて紙
力増強剤やサイズ剤が用いられており、塗工原紙の層間
強度などの強度を改良する目的には、カチオン化デンプ
ン、ポリアクリルアミドが主に用いられ、又、サイズ性
を改良する目的からはアルキルケテンダイマー系サイ
ズ、アルケニル無水コハク酸系サイズ、ロジン系サイズ
が主として用いられ、さらに塗工原紙の表面には、サイ
ズプレス、ゲートロールなどの装置でデンプン、ポリビ
ニルアルコールなどが塗工されている。
Paper-strengthening agents and sizing agents are used in the coated base paper depending on the intended use. For the purpose of improving the strength such as the interlaminar strength of the coated base paper, cationized starch and polysulfate are used. Acrylamide is mainly used, and for the purpose of improving the size property, alkyl ketene dimer size, alkenyl succinic anhydride size, and rosin size are mainly used. Starch, polyvinyl alcohol, etc. are coated with a device such as a gate roll.

【0005】オフセット印刷は水とインキを紙面に印刷
後、115〜125℃で紙を急速に乾燥して印刷紙に仕
上げるが、塗工紙にオフセット印刷を施した場合、高温
で乾燥時に塗工原紙に含まれていた水分が蒸発して塗工
層がふくれた状態、いわゆる「ブリスタリング」が発生
し、印刷紙の価値を低下させるという問題が従来よりあ
った。
In the offset printing, after printing water and ink on the surface of the paper, the paper is rapidly dried at 115 to 125 ° C. to obtain a printed paper. However, when offset printing is applied to the coated paper, the coated paper is dried and dried at a high temperature. There has been a problem that the value of the printing paper is reduced since the water contained in the base paper evaporates and the coating layer swells, so-called “blistering” occurs.

【0006】塗工紙のブリスタリングを改良する方法と
しては、従来より塗工原紙の厚み方向にかかる力に対す
る強度、即ち層間強度を上げる方法がとられて来てい
る。そして、塗工原紙の層間強度の調節は紙力増強剤の
添加率の増減により行われているが、紙力増強剤のうち
カチオン化デンプンが安価で効果も高いためカチン化デ
ンプンの添加率を変えることによって調節する方法が一
般的である。
As a method for improving the blistering of coated paper, conventionally, a method of increasing the strength against the force applied in the thickness direction of the coated base paper, that is, the interlayer strength has been taken. The interlayer strength of the coated base paper is adjusted by increasing or decreasing the addition ratio of the paper strengthening agent. The method of adjusting by changing is common.

【0007】一方、塗工紙を構成する塗工原紙の坪量が
増すと塗工紙の含水量も増すので、オフセット印刷時に
一層ブリスタリングが発生しやすくなり、このブリスタ
リングの発生を防止するために塗工原紙に添加するカチ
オン化デンプンの添加率も一層上げざるを得ない。しか
し、カチオン化デンプンの添加率を上げることによって
塗工原紙の層間強度は所望のレベルに達したとしても、
塗工原紙が硬くなって塗工紙の折り割れ強度が著しく低
下していた。
On the other hand, as the basis weight of the coated base paper constituting the coated paper increases, the water content of the coated paper also increases, so that blistering is more likely to occur during offset printing, and this blistering is prevented. Therefore, the addition rate of the cationized starch added to the coated base paper has to be further increased. However, even if the interlayer strength of the coated base paper reaches a desired level by increasing the addition rate of cationized starch,
The coated base paper became hard and the breaking strength of the coated paper was significantly reduced.

【0008】塗工紙の用途は本、雑誌の表紙や美術印刷
本の用紙など、折って製品に供する場合が多い。塗工紙
が折り割れ強度の低下をきたすと本や雑誌の折り目から
破れが生じ、著しく製品の価値を低下させるという問題
があった。
The coated paper is often used as a product such as a book, a cover of a magazine or a paper of an art print book by folding it. There is a problem that when the coated paper causes a decrease in fold cracking strength, tears occur at the folds of a book or magazine, which significantly reduces the value of the product.

【0009】このようにオフセット印刷用のブリスタリ
ングの発生を抑止するため塗工原紙の層間強度を上げる
と塗工紙の折り割れ強度が低下する傾向があるので、ブ
リスタリングの発生の抑止と折り割れ強度は塗工紙の重
要な品質であるにもかかわらず、塗工紙を製造する上で
は二律背反的な関係にある。
As described above, when the interlayer strength of the coated base paper is increased to suppress the occurrence of blistering for offset printing, the folding crack strength of the coated paper tends to decrease. Although cracking strength is an important quality of coated paper, it has a trade-off relationship in producing coated paper.

【0010】一方、カチオン化デンプンを用いないで、
他の紙力増強剤を用いて塗工紙の層間強度を上げる方法
によっても、耐ブリスター性と折り割れ強度の両特性を
同時に改善することは難しいし、加えて、カチオン化デ
ンプンに比べて紙力増強剤にかかるコストがかさみ、塗
工紙製造上の経済性が悪化するという問題もあった。
On the other hand, without using cationized starch,
It is difficult to improve both the blister resistance and the crease resistance at the same time by using other paper strengthening agents to increase the interlaminar strength of the coated paper. There is also a problem that the cost of the strength enhancer is high and the economical efficiency in manufacturing coated paper is deteriorated.

【0011】[0011]

【発明が解決しようとする課題】本発明者等は、塗工紙
の水分量、透気性、層間強度、米坪及び塗工量と、オフ
セット印刷時のブリスタリングに対する抵抗力(耐ブリ
スター性)と、折り割れ強度の関係と、塗工原紙の紙力
増強剤の種類と効果について研究を行なった。
DISCLOSURE OF THE INVENTION The inventors of the present invention have found that the water content of the coated paper, the air permeability, the interlaminar strength, the basis weight and the coating amount, and the resistance to blistering during offset printing (blister resistance). , And the relationship between the breaking strength and the type and effect of the paper strengthening agent for coated base paper were studied.

【0012】オフセット印刷用塗工紙の耐ブリスター性
を改良するためには塗工原紙の層間強度を上げることが
最も効果があるし、又カチオン化デンプンによる層間強
度の改良効果が高い。
In order to improve the blister resistance of the coated paper for offset printing, it is most effective to increase the interlayer strength of the coated base paper, and the effect of improving the interlayer strength by the cationized starch is high.

【0013】しかし、カチオン化デンプンのみでは、塗
工原紙の絶乾米坪が40g/m2 以上であって、塗工液
が6g/m2 (片面当り、絶乾)以上塗工されているオ
フセット印刷用塗工紙の耐ブリスター性(層間強度)の
改良効果に限界があり、カチオン化デンプンの添加率
(塗工原紙を構成するパルプ絶乾重量当り)がある範囲
を越えると層間強度のより以上の向上は望めないばかり
でなく、塗工紙が弾力性を失って硬くなり折り割れ強度
が著しく低下することが判明した。
However, with only cationized starch, the coated base paper has an absolute dry weight of 40 g / m 2 or more and a coating liquid of 6 g / m 2 (per side, absolute dry) or more. There is a limit to the effect of improving the blister resistance (interlayer strength) of coated paper for offset printing, and if the addition rate of cationized starch (absolute dry weight of pulp constituting the coating base paper) exceeds a certain range, the interlaminar strength It was found that not only further improvement cannot be expected, but also the coated paper loses elasticity and becomes hard, and the folding crack strength is significantly reduced.

【0014】本発明は、絶乾米坪が40g/m2 以上で
あって、塗工液を6g/m2 (片面当り、絶乾)以上塗
工して塗工紙とした場合にすぐれた耐ブリスター性(層
間強度)及びすぐれた折り割れ強度を有するオフセット
印刷用塗工紙を与えることのできる塗工原紙を提供する
ことを目的とし、特に、耐ブリスター性改善のためにカ
チオン化デンプンを使用している該塗工原紙を提供する
ことを目的とする。
The present invention is excellent in the case where the absolute dry rice weight is 40 g / m 2 or more and the coating liquid is applied in an amount of 6 g / m 2 (per side, absolute dry) or more to form a coated paper. The purpose of the present invention is to provide a base paper for coating which is capable of giving a coated paper for offset printing having a blister resistance (interlayer strength) and an excellent folding crack strength, and in particular, a cationized starch is used for improving the blister resistance. The purpose is to provide the coated base paper used.

【0015】[0015]

【課題を解決するための手段】本発明者らは塗工原紙の
絶乾米坪及び塗工量がある範囲を越える塗工紙に関し
て、耐ブリスター性及び折り割れ強度を確保し、さらに
塗工紙製造にかかるコストが低く経済性に優れた塗工紙
を製造するためには塗工原紙の製造に際して、一定量の
カチオン化デンプンと他の紙力増強剤の併用添加が不可
欠であること及び他の紙力増強剤としてはポリアクリル
アミドが有効であることを見い出し本発明を完成するに
到った。
DISCLOSURE OF THE INVENTION The inventors of the present invention have ensured blistering resistance and crease resistance of coated base paper with respect to the coated rice paper having an absolutely dry basis weight and a coating amount exceeding a certain range. In order to produce a coated paper that is low in the cost of producing paper and excellent in economic efficiency, it is essential to add a fixed amount of a cationized starch and another strength enhancer together in the production of the coated base paper, and We have found that polyacrylamide is effective as another paper strengthening agent and completed the present invention.

【0016】本発明は顔料と接着剤を主成分とする塗工
液を、塗工原紙の片面当り6g/m2(絶乾)以上、両面
に塗工してオフセット印刷用塗工紙とするために用いら
れる絶乾米坪40g/m2 以上を有する塗工原紙であっ
て、該塗工原紙は、原紙を構成するパルプの絶乾重量当
り、カチオン化デンプンを0.3〜1.5重量%及びポ
リアクリルアミドを0.1〜1.0重量%用いて製造し
たものであることを特徴とするオフセット印刷用塗工紙
のための原紙に関する。
According to the present invention, a coating liquid containing a pigment and an adhesive as main components is coated on both sides of the coated base paper in an amount of 6 g / m 2 (absolute dryness) or more to form a coated paper for offset printing. A coated base paper having an absolute dry rice basis weight of 40 g / m 2 or more, which is used for the above, wherein the coated base paper has 0.3 to 1.5 of cationized starch per absolute dry weight of pulp constituting the base paper. The present invention relates to a base paper for coated paper for offset printing, which is manufactured by using 0.1% by weight of polyacrylamide and 0.1% by weight of polyacrylamide.

【0017】塗工原紙が絶乾米坪40g/m2 未満の場
合には、塗工原紙に含まれる水分量が低いためにブリス
タリングの発生頻度が大巾に減少するのでカチオン化デ
ンプンの添加率を低く抑えることができ、両面塗工紙の
折り割れ強度の低下を引き起こすことはない。
When the coated base paper is less than 40 g / m 2 of absolutely dry rice, the frequency of blistering is greatly reduced because of the low water content in the coated base paper. The rate can be suppressed to a low level, and the folding crack strength of double-sided coated paper is not reduced.

【0018】また、両面塗工紙の塗工量が片面当り6g
/m2 (絶乾)未満である場合にも、塗工面を通過して
蒸気が逃げるのでブリスタリングの発生は大巾に減少す
る。
The amount of coated double coated paper is 6 g per side.
Even if it is less than / m 2 (absolute dryness), steam escapes through the coated surface, and the occurrence of blistering is greatly reduced.

【0019】これに対して、塗工原紙の絶乾米坪40g
/m2 以上になると紙内に発生する蒸気量が増すため、
ブリスタリングが発生しやすくなる。さらに、塗工原紙
が絶乾米坪40g/m2 以上、及び両面塗工紙の塗工量
が片面当り6g/m2 (絶乾)以上である場合には大巾
にブリスタリングが発生しやすくなるので塗工原紙の層
間強度を上げざるを得ない。
On the other hand, the coated base paper 40 g of dried rice
/ M 2 or more, the amount of steam generated in the paper increases,
Blistering is likely to occur. Furthermore, when the coated base paper is 40 g / m 2 or more of dry-dry rice, and when the coating amount of double-sided coated paper is 6 g / m 2 (absolutely dry) or more per side, blistering occurs greatly. Since it becomes easier, the interlaminar strength of the coated base paper must be increased.

【0020】それ故、本発明は塗工原紙が絶乾米坪40
g/m2 以上、及び両面塗工紙の塗工量が片面6g/m
2 (絶乾)以上である両面塗工紙の耐ブリスター性及び
折り割れ強度の改良のために特に意義がある。前記範囲
を下廻る塗工原紙からなる両面塗工紙は、本発明を適用
せずとも耐ブリスター性及び折り割れ強度が共に所望の
水準内にあるので本発明を適用する必要がない。
Therefore, according to the present invention, the coated base paper is absolutely dry tsubo 40
g / m 2 or more, and coating amount of double-sided coated paper is 6 g / m on one side
It is particularly significant for improving the blister resistance and crease strength of double-sided coated paper that is 2 (absolutely dry) or more. A double-sided coated paper consisting of a coated base paper below the above range does not need to apply the present invention because both the blister resistance and the crease resistance are within desired levels without applying the present invention.

【0021】カチオン化デンプンは安価であり、層間強
度を改良する効果も十分に有しており、経済性を加味し
た両面塗工紙の耐ブリスター性を改良する上で不可欠な
内添紙力増強剤である。本発明のカチオン化デンプンと
は、カチオン基を有している変性デンプンであり、市販
されている種類のもので十分であって、変性の種類は限
定されない。
[0021] Cationized starch is inexpensive and has a sufficient effect of improving the interlaminar strength, and it is indispensable to enhance the internal paper strength for improving the blister resistance of double-sided coated paper considering economy. It is an agent. The cationized starch of the present invention is a modified starch having a cationic group, and a commercially available type is sufficient, and the type of modification is not limited.

【0022】カチオン化デンプンの添加率(パルプの絶
乾重量当り)は0.3〜1.5重量%である。0.3重
量%未満では層間強度が所望のレベルまで上がらない。
又カチオン化デンプンを1.5重量%を越えて添加する
と、塗工原紙が硬くなって弾力性を失ない、両面塗工紙
の折り割れ強度が低下して品質低下を引き起こすので好
ましくない。
The addition rate of cationized starch (per absolute dry weight of pulp) is 0.3 to 1.5% by weight. If it is less than 0.3% by weight, the interlayer strength does not rise to a desired level.
If cationized starch is added in an amount of more than 1.5% by weight, the coated base paper becomes hard and loses its elasticity, and the double-sided coated paper is deteriorated in fold crack strength and deteriorates in quality.

【0023】塗工原紙の絶乾米坪が上がるに従って要求
される層間強度の水準も上がり、カチオン化デンプンの
添加率も上がるが絶乾米坪40g/m2 以上の塗工原紙
からなる塗工紙の折り割れ強度の低下を防ぐためには、
カチオン化デンプンとは異なる、紙の弾力性を失なわし
めない紙力増強剤をカチオン化デンプンと併用すること
が塗工紙の耐ブリスター性と併せて折り割れ強度を改良
する上で不可欠である。
Although the required level of interlaminar strength increases and the addition rate of cationized starch increases as the absolute dry rice basis weight of the coated base paper increases, the coating consisting of the coated base paper having an absolute dry rice basis weight of 40 g / m 2 or more. In order to prevent the strength of the paper from cracking,
It is indispensable to use a paper strength enhancer, which is different from cationic starch and does not impair the elasticity of paper, together with cationic starch in order to improve the crease resistance as well as the blister resistance of coated paper. .

【0024】塗工原紙の層間強度の改良に効果を有する
各種内添紙力増強剤、例えばアニオン性、カチオン性、
ノニオン性または両性のポリアクリルアミド系重合体、
ポリエチレンイミン及びその誘導体、ポリエチレンオキ
サイド、植物ガム、ポリビニルアルコール、カチオン性
ラテックス、カチオン性尿素ホルマリン樹脂、メラミン
ホルマリン樹脂、ポリアミド樹脂等の有機化合物がいづ
れも本発明に適するが、両性のポリアクリルアミド系重
合体が本発明に最も適する。
Various internal paper strength enhancers having an effect of improving the interlaminar strength of the coated base paper, for example, anionic, cationic,
Nonionic or amphoteric polyacrylamide polymer,
Organic compounds such as polyethyleneimine and its derivatives, polyethylene oxide, plant gum, polyvinyl alcohol, cationic latex, cationic urea formalin resin, melamine formalin resin, and polyamide resin are all suitable for the present invention, but amphoteric polyacrylamide-based compounds are preferred. Coalescence is most suitable for the present invention.

【0025】さらに、両性のポリアクリルアミド系重合
体のうち分子量が200万〜300万のものが特にカチ
オン化デンプンとの組合せにおいて紙が硬くならず本発
明に適する。前記ポリアクリルアミド系重合体は、塗工
原紙の層間強度に対する効果が高く、本発明の添加率の
範囲内では、紙の硬化をほとんど伴うことはない。
Further, among the amphoteric polyacrylamide polymers, those having a molecular weight of 2,000,000 to 3,000,000 are suitable for the present invention, especially in combination with cationized starch, because the paper does not become hard. The polyacrylamide polymer has a high effect on the interlaminar strength of the coated base paper, and hardly cures the paper within the range of the addition ratio of the present invention.

【0026】両性で分子量が200〜300万のポリア
クリルアミド系重合体(以下、ポリアクリルアミドとい
う)の添加率は塗工原紙を構成するパルプの絶乾重量当
り0.1〜1.0重量%、好ましくは0.2〜0.8重
量%である。
The addition rate of the polyacrylamide-based polymer (hereinafter referred to as polyacrylamide) having an amphoteric property and a molecular weight of 2 to 3,000,000 is 0.1 to 1.0% by weight based on the absolute dry weight of the pulp constituting the coated base paper, It is preferably 0.2 to 0.8% by weight.

【0027】ポリアクリルアミドの添加率が0.1重量
%未満では併用するカチオン化デンプンの添加率が1.
5重量%を越える可能性があり、塗工紙の折り割れ強度
が低下しかねないので好ましくない。添加率が1.0重
量%を越えても層間強度のより以上の向上は見られない
ので薬品が無駄になり、両面塗工紙製造上の経済性に問
題が生ずるので好ましくない。
When the addition rate of polyacrylamide is less than 0.1% by weight, the addition rate of cationized starch used in combination is 1.
The content may exceed 5% by weight, and the breaking strength of the coated paper may decrease, which is not preferable. Even if the addition rate exceeds 1.0% by weight, no further improvement in the interlaminar strength is observed, so that the chemicals are wasted and the economical efficiency in the production of double-sided coated paper is unfavorable.

【0028】塗工原紙を構成する原料パルプには、カチ
オン化デンプン及びポリアクリルアミドの他に内添助剤
として一般に広く用いられている定着剤、サイズ剤、歩
留り向上剤、ろ水向上剤、さらにpH調整剤、ピッチコ
ントロール剤、スライムコントロール剤、消泡剤等を必
要に応じて適宜添加することもできる。
The raw material pulp constituting the coated base paper contains a fixing agent, a sizing agent, a retention improving agent, a drainage improving agent which are widely used as an internal addition aid in addition to the cationized starch and polyacrylamide. A pH adjusting agent, a pitch control agent, a slime control agent, an antifoaming agent and the like can be appropriately added if necessary.

【0029】本発明の抄紙方法はいわゆる酸性抄紙、中
性抄紙のいづれにも適する。いづれの抄紙法による場合
でも、ポリアクリルアミドとカチオン化デンプンを用い
るためには、パルプ、ブローク、填料からなるパルプス
ラリーに添加するのが最も好ましい。
The papermaking method of the present invention is suitable for both so-called acidic papermaking and neutral papermaking. Whichever papermaking method is used, in order to use the polyacrylamide and the cationized starch, it is most preferable to add them to the pulp slurry comprising pulp, broke and filler.

【0030】印刷用塗工紙は、本発明の塗工原紙の片面
または両面に、顔料と接着剤を主成分とする塗工液を塗
工して製造される。この塗工液組成物は、一般に固形分
濃度が40〜75重量%、好ましくは45〜70重量%
程度の範囲に調整される。塗工原紙上に塗工液を塗工し
て塗工層を形成するに当たっては、塗工液を一度塗りし
た塗工層を形成してもよく、或いは下塗り層及び上塗り
層に分けて多層構造として形成してもよい。多層構造の
場合には、下塗り層と上塗り層の塗工液組成が同一であ
る必要はなく、要求される品質レベルに応じて塗工液組
成を適宜変化させることもできる。
The coated paper for printing is produced by coating one or both surfaces of the coated base paper of the present invention with a coating liquid containing a pigment and an adhesive as main components. The coating composition generally has a solid content of 40 to 75% by weight, preferably 45 to 70% by weight.
Adjusted to a range of degrees. In forming the coating layer by coating the coating liquid on the coating base paper, the coating layer may be formed by applying the coating liquid once, or the coating layer may be divided into an undercoat layer and an overcoat layer to form a multilayer structure. You may form as. In the case of a multi-layer structure, the undercoat layer and the overcoat layer do not have to have the same coating liquid composition, and the coating liquid composition can be appropriately changed according to the required quality level.

【0031】塗工層を形成する方法としては、従来から
慣用されている塗工装置、例えばプレードコーター、ア
エーナイフコーター、ロールコーター、リバースロール
コーター、バーコーター、カーテンコーター、ダイスロ
ットコーター、グラビアコーター、チャンブレックスコ
ーター、ブラシコーター、サイズプレスコーター等の各
種コーターを用いて塗工液を塗工原紙表面に塗工する。
これらの塗工装置はオンマシン或いはオフマシンコータ
ーのいずれの形式で使用してもよい。
The coating layer may be formed by a conventional coating apparatus such as a blade coater, an Aa knife coater, a roll coater, a reverse roll coater, a bar coater, a curtain coater, a die slot coater, and a gravure coater. The coating liquid is applied to the surface of the coated base paper using various coaters such as a coater, a Chambrex coater, a brush coater, and a size press coater.
These coating devices may be used in either on-machine or off-machine coater form.

【0032】塗工原紙への塗工液の塗工量は、通常乾燥
重量で片面当たり2〜50g/m2程度であるが、得ら
れる塗工紙の白紙品質、印刷適性等を考慮すると5〜3
0g/m2 程度の範囲で調節するのが望ましい。また、
このようにして得られた印刷用塗工紙は、水分が通常3
〜10重量%程度の範囲となるよう乾燥した後、オン又
はオフのスーパーカレンダー等に通紙して加圧仕上げが
行われる。
The coating amount of the coating liquid on the coated base paper is usually about 2 to 50 g / m 2 on a dry basis, but it is 5 when considering the quality of blank paper and printability of the obtained coated paper. ~ 3
It is desirable to adjust in the range of about 0 g / m 2 . Also,
The coated paper obtained in this way usually has a water content of 3
After drying so as to be in the range of about 10% by weight, the paper is passed through an on or off super calendar or the like for pressure finishing.

【0033】本発明の塗工原紙を構成するセルロースパ
ルプは針葉樹晒クラフトパルプ(NBKPという)、広
葉樹晒クラフトパルプ(LBKPという)の他に、高歩
留りパルプ、例えばリファイナーグランドパルプ(RG
P)、サーモメカニカルパルプ(TMP)、ストーング
ランドパルプ(GP)及び新聞雑誌古紙、OA古紙(上
質古紙)を原料とした脱墨古紙パルプを挙げることがで
きる。
Cellulose pulp constituting the coated base paper of the present invention includes soft-leaf bleached kraft pulp (referred to as NBKP) and hard-leaf bleached kraft pulp (referred to as LBKP), as well as high-yield pulp such as refiner ground pulp (RG).
P), thermomechanical pulp (TMP), stone ground pulp (GP), used newspapers and newspapers, and deinked used paper pulps made from OA used papers (quality used papers).

【0034】[0034]

【実施例】以下、具体的な実施例により本発明を更に詳
しく説明する。本実施例における部及び%はいづれも重
量部及び重量%である。以下の説明及び実施例は本発明
を例示するものであり本発明を制限するものではない。
EXAMPLES The present invention will be described in more detail with reference to specific examples. All parts and% in the examples are parts by weight and% by weight. The following description and examples are illustrative of the invention and are not limiting of the invention.

【0035】用いたポリアクリルアミドは、分子量26
0万〜280万で両性のポリアクリルアミドであるハリ
マ化成社製のハーマイドEX−360であり、カチオン
化デンプンは王子ナショナル社製のケートFであり、両
者は抄紙前のパルプスラリーへ添加された。カチオン化
デンプン及びポリアクリルアミドの添加率は、以下の実
施例、比較例で示すが、その他に用いたパルプや助剤な
どの条件を次に列記する。
The polyacrylamide used had a molecular weight of 26.
Hermide EX-360 manufactured by Harima Kasei Co., Ltd., which is an amphoteric polyacrylamide having a capacity of 0,000 to 2.8 million, and the cationized starch was Kate F manufactured by Oji National Co., Ltd., both of which were added to the pulp slurry before papermaking. The addition ratios of cationized starch and polyacrylamide are shown in the following Examples and Comparative Examples, and other conditions such as pulp and auxiliaries used are listed below.

【0036】塗工原紙1 フリーネス430ml(C.S.F.)に調節したNB
KP40部及びフリーネス410ml(C.S.F.)
に調節したLBKP60部からなるパルプ(スラリー)
100部に対し軽質炭酸カルシウム10部を加え、さら
にパルプ100部に対しカチオン化デンプン、ポリアク
リルアミド(添加率は、実施例及び比較例で変化させ
た。)、硫酸バンド(自家製)0.5%、歩留り向上剤
(協立有機社製NR−11LH)0.02%を添加し、
長網多筒ドライヤー式抄紙機で抄紙し、サイズプレスで
デンプン(王子コンスターチ社製王子エースA)1.8
g/m2 と外添サイズ剤(荒川化学社製ポリマロン)
0.02g/m2 を塗布し、水分5.5%、絶乾米坪4
2g/m2 の塗工原紙を製造した。
Coated base paper 1 NB adjusted to have a freeness of 430 ml (C.S.F.)
40 parts KP and 410 ml freeness (C.S.F.)
Pulp (slurry) consisting of 60 parts of LBKP adjusted to
Light calcium carbonate (10 parts) was added to 100 parts, and cationized starch, polyacrylamide (addition rate was changed in Examples and Comparative Examples), and sulfuric acid band (homemade) 0.5% to 100 parts of pulp. , Yield improver (NR-11LH manufactured by Kyoritsu Organic Co., Ltd.) 0.02% was added,
Paper is made with a long-net multi-cylinder dryer type paper machine and starch is made with a size press (Oji Ace A manufactured by Oji Constarch Co., Ltd.) 1.8
g / m 2 and external sizing agent (Polymaron manufactured by Arakawa Chemical Co., Ltd.)
0.02g / m 2 was applied and the water content was 5.5%.
A coated base paper of 2 g / m 2 was produced.

【0037】塗工原紙2 フリーネス430ml(C.S.F.)に調節したNB
KP30部及びフリーネス390ml(C.S.F.)
に調節したLBKP70部からなるパルプ(スラリー)
100部に対し軽質炭酸カルシウム4部を加え、さらに
パルプ100部に対しカチオン化デンプン、ポリアクリ
ルアミド(添加率は、実施例及び比較例で変化させ
た。)、硫酸バンド(自家製)0.5%、歩留り向上剤
(協立有機社製NR−11LH)0.02%を添加し、
長鋼多筒ドライヤー式抄紙機で抄紙し、サイズプレスで
デンプン(王子コンスターチ社製)2.5g/m2 及び
外添サイズ剤(荒川化学社製ポリマロン)0.03g/
2 を塗布し、水分5.5%、絶乾米坪90g/m2
塗工原紙を製造した。
Coated base paper 2 NB adjusted to have a freeness of 430 ml (C.S.F.)
30 parts KP and 390 ml freeness (C.S.F.)
Pulp (slurry) consisting of 70 parts of LBKP adjusted to
4 parts of light calcium carbonate was added to 100 parts, and further cationized starch, polyacrylamide (addition rate was changed in Examples and Comparative Examples), and sulfuric acid band (homemade) 0.5% to 100 parts of pulp. , Yield improver (NR-11LH manufactured by Kyoritsu Organic Co., Ltd.) 0.02% was added,
Paper is made with a long-steel multi-cylinder dryer type paper machine, and starch (made by Oji Konstarch Co., Ltd.) 2.5 g / m 2 and external sizing agent (Polymaron made by Arakawa Chemical Co., Ltd.) 0.03 g /
m 2 was applied to produce a coated base paper having a water content of 5.5% and an absolutely dry rice weight of 90 g / m 2 .

【0038】塗工 塗工原紙に、下記組成の塗工液をブレードコーターで両
面に同量塗工し、150℃エアーホイルドライヤーで乾
燥後スーパーカレンダー処理を行った。塗工紙の水分は
5.5重量%であった。 カオリン 60部 重質炭酸カルシウム 40部 デンプン 2.5部 (顔
料100部当り) スチレンブタジエン系ラテックス 11部 (顔
料100部当り)
Coating A coating solution having the following composition was coated on the coated base paper in the same amount on both sides with a blade coater, dried with an air foil dryer at 150 ° C., and then supercalendered. The water content of the coated paper was 5.5% by weight. Kaolin 60 parts Heavy calcium carbonate 40 parts Starch 2.5 parts (per 100 parts pigment) Styrene-butadiene latex 11 parts (per 100 parts pigment)

【0039】塗工原紙及び塗工紙の品質評価は以下の方
法で行なった。 (1)耐ブリスター性 明製作所製のRI印刷テスターでオフセット印刷用イン
キ1mlを練り、塗工紙の両面に印刷し、直後に250
℃で両面から加熱して生じる印刷表面のブリスタリング
状況を目視で評価した。 ◎ : 極めて優れている 〇 : やや優れている △ : 普通 × : やや劣る ×× : 極めて劣る
The quality of the coated base paper and the coated paper was evaluated by the following method. (1) Blister resistance A RI printing tester manufactured by Akira Seisakusho kneads 1 ml of offset printing ink and prints on both sides of coated paper. Immediately after 250
The condition of blistering on the printed surface caused by heating from both sides at ° C was visually evaluated. ◎: Extremely good ○: Slightly excellent △: Normal ×: Slightly inferior XX: Extremely inferior

【0040】(2)層間強度(塗工原紙) 塗工原紙の両面に粘着テープ( Beiersdorf 社製(ドイ
ツ)テサNo4863巾38mm)を均等に圧着し巾2
5mmのたんざく状に断裁した後、たんざくの両面の粘
着テープをテンシロン万能型引張り試験機(東洋ボール
ドイン社製)で引張り、塗工原紙の紙層をはがすために
必要であった引張り強さ(g)で評価した。
(2) Interlaminar strength (coated base paper) Adhesive tape (Tesa No 4863 width 38 mm manufactured by Beiersdorf (Germany) 38 mm width) is evenly pressed on both sides of the coated base paper to give a width of 2
After cutting into a 5 mm strip shape, the adhesive strength on both sides of the strip was pulled with a Tensilon universal tensile tester (manufactured by Toyo Bold-In Co., Ltd.) to remove the paper layer of the coated base paper. (G) was evaluated.

【0041】(3)塗工紙の耐折強度:JIS P81
15に従う。 (サンプル:塗工原紙抄紙機の抄紙方向と平行に断裁) (4)塗工原紙の剛度:JIS P8125に従う。 (サンプル:塗工原紙抄紙機の抄紙方向と平行に断裁)
(3) Folding strength of coated paper: JIS P81
Follow 15. (Sample: Cutting parallel to the papermaking direction of the coated base paper machine) (4) Stiffness of coated base paper: According to JIS P8125. (Sample: Cut parallel to the papermaking direction of the coated base paper machine)

【0042】実施例1 前記塗工原紙1において絶乾パルプ重量当りカチオン化
デンプンを0.3%及びポリアクリルアミドを0.9%
添加した。この塗工原紙に片面当り7g/m2 (絶乾)
の前記塗工液を塗工し、両面塗工紙を製造した。
Example 1 In the coated base paper 1, 0.3% of cationized starch and 0.9% of polyacrylamide per weight of bone-dry pulp were used.
Was added. 7 g / m 2 per side of this coated base paper (dry)
The above-mentioned coating liquid was applied to produce a double-sided coated paper.

【0043】実施例2 前記塗工原紙1において、絶乾パルプ重量当りカチオン
化デンプンを0.3%及びポリアクリルアミドを0.9
%添加した。この塗工原紙に片面当り15g/m2 (絶
乾)の前記塗工液を塗工し、両面塗工紙を製造した。
Example 2 In the coated base paper 1, 0.3% of cationized starch and 0.9% of polyacrylamide per weight of bone-dry pulp were used.
% Added. This coated base paper was coated with 15 g / m 2 (absolutely dry) of the above-mentioned coating solution on each side to produce a double-sided coated paper.

【0044】実施例3 前記塗工原紙1において、絶乾パルプ重量当りカチオン
化デンプンを1.4%及びポリアクリルアミドを0.2
%添加した。この塗工原紙に片面当り7g/m2 (絶
乾)の前記塗工液を塗工し、両面塗工紙を製造した。
Example 3 In the coated base paper 1, 1.4% of cationized starch and 0.2% of polyacrylamide were added per weight of the absolutely dried pulp.
% Added. This coated base paper was coated with 7 g / m 2 (absolutely dry) of the above-mentioned coating solution on each side to produce a double-sided coated paper.

【0045】実施例4 前記塗工原紙1において、絶乾パルプ重量当りカチオン
化デンプンを1.4%及びポリアクリルアミドを0.2
%添加した。この塗工原紙に片面当り15g/m2 (絶
乾)の前記塗工液を塗工し、両面塗工紙を製造した。
Example 4 In the coated base paper 1, 1.4% of cationized starch and 0.2% of polyacrylamide per weight of bone-dry pulp were used.
% Added. This coated base paper was coated with 15 g / m 2 (absolutely dry) of the above-mentioned coating solution on each side to produce a double-sided coated paper.

【0046】実施例5 前記塗工原紙2において、絶乾パルプ重量当りカチオン
化デンプンを0.6%及びポリアクリルアミドを0.9
%添加した。この塗工原紙に片面当り7g/m2 (絶
乾)の前記塗工液を塗工し、両面塗工紙を製造した。
Example 5 In the coated base paper 2, 0.6% of cationized starch and 0.9% of polyacrylamide per weight of bone-dry pulp were used.
% Added. This coated base paper was coated with 7 g / m 2 (absolutely dry) of the above-mentioned coating solution on each side to produce a double-sided coated paper.

【0047】実施例6 前記塗工原紙2において、絶乾パルプ重量当りカチオン
化デンプンを0.6%及びポリアクリルアミドを0.9
%添加した。この塗工原紙に片面当り15g/m2 (絶
乾)の前記塗工液を塗工し、両面塗工紙を製造した。
Example 6 In the coated base paper 2, 0.6% of cationized starch and 0.9% of polyacrylamide per weight of bone-dry pulp were used.
% Added. This coated base paper was coated with 15 g / m 2 (absolutely dry) of the above-mentioned coating solution on each side to produce a double-sided coated paper.

【0048】実施例7 前記塗工原紙2において、絶乾パルプ重量当りカチオン
化デンプンを1.4%及びポリアクリルアミドを0.5
%添加した。この塗工原紙に片面当り7g/m2 (絶
乾)の前記塗工液を塗工し、両面塗工紙を製造した。
Example 7 In the coated base paper 2, cationized starch was 1.4% and polyacrylamide was 0.5% based on the weight of absolutely dry pulp.
% Added. This coated base paper was coated with 7 g / m 2 (absolutely dry) of the above-mentioned coating solution on each side to produce a double-sided coated paper.

【0049】実施例8 前記塗工原紙2において、絶乾パルプ重量当りカチオン
化デンプンを1.4%及びポリアクリルアミドを0.5
%添加した。この塗工原紙に片面当り15g/m2 (絶
乾)の前記塗工液を塗工し、両面塗工紙を製造した。
Example 8 In the coated base paper 2, cationized starch was 1.4% and polyacrylamide was 0.5% based on the weight of absolutely dry pulp.
% Added. This coated base paper was coated with 15 g / m 2 (absolutely dry) of the above-mentioned coating solution on each side to produce a double-sided coated paper.

【0050】比較例1 前記塗工原紙1において、絶乾パルプ重量当りカチオン
化デンプンを0.1%及びポリアクリルアミドを1.2
%添加した以外実施例1と同じようにして塗工紙を製造
した。
COMPARATIVE EXAMPLE 1 In the coated base paper 1, 0.1% of cationized starch and 1.2% of polyacrylamide per weight of bone-dry pulp were used.
A coated paper was produced in the same manner as in Example 1 except that the amount of the added amount was 0.1%.

【0051】比較例2 前記塗工原紙1において、絶乾パルプ重量当りカチオン
化デンプンを0.1%及びポリアクリルアミドを1.2
%添加した以外実施例2と同じようにして塗工紙を製造
した。
Comparative Example 2 In the coated base paper 1, 0.1% of cationized starch and 1.2% of polyacrylamide were used per weight of the absolutely dry pulp.
A coated paper was produced in the same manner as in Example 2 except that the amount of the added amount was 0.1%.

【0052】比較例3 前記塗工原紙1において、絶乾パルプ重量当りカチオン
化デンプンを1.8%添加し、ポリアクリルアミドは添
加しなかったこと以外実施例3と同じようにして塗工紙
を製造した。
Comparative Example 3 A coated paper was prepared in the same manner as in Example 3 except that 1.8% of cationized starch was added to the coated base paper 1 and the polyacrylamide was not added. Manufactured.

【0053】比較例4 前記塗工原紙1において、絶乾パルプ重量当りカチオン
化デンプンを1.8%添加し、ポリアクリルアミドは添
加しなかったこと以外実施例4と同じようにして塗工紙
を製造した。
Comparative Example 4 A coated paper was prepared in the same manner as in Example 4 except that 1.8% of cationized starch was added to the coated base paper 1 and the polyacrylamide was not added. Manufactured.

【0054】比較例5 前記塗工原紙2において、絶乾パルプ重量当りカチオン
化デンプンを0.2%及びポリアクリルアミドを1.4
%添加した以外実施例5と同じようにして塗工原紙を製
造した。
Comparative Example 5 In the coated base paper 2, 0.2% of cationized starch and 1.4% of polyacrylamide were used per weight of bone-dry pulp.
A coated base paper was produced in the same manner as in Example 5 except that the addition amount of 10% was added.

【0055】比較例6 前記塗工原紙2において、絶乾パルプ重量当りカチオン
化デンプンを0.2%及びポリアクリルアミドを1.4
%添加した以外実施例6と同じようにして塗工原紙を製
造した。
Comparative Example 6 In the coated base paper 2, 0.2% of cationized starch and 1.4% of polyacrylamide were used per weight of the absolutely dried pulp.
A coated base paper was produced in the same manner as in Example 6 except that the addition amount of 10% was added.

【0056】比較例7 前記塗工原紙2において、絶乾パルプ重量当りカチオン
化デンプンを2.4%用いポリアクリルアミドは添加し
なかったこと以外実施例7と同じようにして塗工原紙を
製造した。
Comparative Example 7 A coated base paper was produced in the same manner as in Example 7 except that the coated base paper 2 contained 2.4% of cationized starch based on the weight of absolutely dry pulp and no polyacrylamide was added. .

【0057】比較例8 前記塗工原紙2において、絶乾パルプ重量当りカチオン
化デンプンを2.4%用いポリアクリルアミドは添加し
なかったこと以外実施例8と同じようにして塗工原紙を
製造した。
Comparative Example 8 A coated base paper was produced in the same manner as in Example 8 except that the coated base paper 2 contained 2.4% of cationized starch based on the weight of absolutely dry pulp and no polyacrylamide was added. .

【0058】比較例9 フリーネス430ml(C.S.F.)に調節したNB
KP45部及びフリーネス410ml(C.S.F.)
に調節したLBKP55部からなるパルプ(スラリー)
100部に対し軽質炭酸カルシウム10部を加え、さら
に絶乾パルプ重量当りカチオン化デンプン1.3%、硫
酸バンド(自家製)0.5%、歩留り向上剤(協立有機
社製NR−11LH)0.02%を添加した。この紙料
を用いて長網抄紙機で抄紙し、サイズプレスでデンプン
(王子コンスターチ社製)1.5g/m2 及び外添サイ
ズ剤(荒川化学社製ポリマロン)0.02g/m2 を塗
布し、水分5.5%、絶乾米坪38g/m2 の塗工原紙
を製造した。この塗工原紙に片面当り5.5g/m
2 (絶乾)の前記塗工液を塗工し両面塗工紙を製造し
た。
Comparative Example 9 NB adjusted to a freeness of 430 ml (C.S.F.)
KP 45 parts and freeness 410 ml (C.S.F.)
Pulp (slurry) consisting of 55 parts of LBKP adjusted to
10 parts of light calcium carbonate was added to 100 parts, and further 1.3% of cationized starch, 0.5% of sulfuric acid band (homemade), yield improver (NR-11LH manufactured by Kyoritsu Organic Co., Ltd.) based on the weight of absolutely dry pulp 0 0.02% was added. Paper making by Fourdrinier paper machine using this paper stock, starch size press (manufactured by Oji Cornstarch Co., Ltd.) 1.5 g / m 2 and the external sizing agent coated (manufactured by Arakawa Chemical Industries, Ltd. Polymaron) 0.02 g / m 2 Then, a coated base paper having a water content of 5.5% and an absolutely dry tsubo of 38 g / m 2 was produced. 5.5 g / m on each side of this coated base paper
2 (absolutely dry) coating solution was applied to produce double-sided coated paper.

【0059】比較例10 前記塗工原紙2において、絶乾パルプ重量当りカチオン
化デンプンを0.6%及びカチオン変性ポリアミド樹脂
(カイメン1300、デイックハーキュレス社製)を
0.9%添加した。この塗工原紙に片面当り15g/m
2 (絶乾)の前記塗工液を塗工し、両面塗工紙を製造し
た。
Comparative Example 10 To the coated base paper 2, 0.6% of cationized starch and 0.9% of cation-modified polyamide resin (Kaymen 1300, manufactured by Dick Hercules Co., Ltd.) were added per 100% by weight of absolutely dry pulp. 15g / m per side of this coated base paper
2 (absolutely dry) of the above coating liquid was applied to produce double-sided coated paper.

【0060】実施例1〜8、比較例1〜10で製造した
塗工原紙塗工紙の品質評価結果を表1に示す。表1から
分かるように、ポリアクリルアミドを使用しない場合、
紙が硬くなって(剛度が上昇)、折り割れ強度(耐折強
度)が低下するので、塗工紙の耐ブリスター性の評価結
果が低くなる(比較例3、4、7、8参照)。これに対
し適正な範囲のカチオン化デンプンとポリアクリルアミ
ドを併用すると、前記の欠点は解消できる(実施例3、
4、7、8参照)。
Table 1 shows the quality evaluation results of the coated base papers prepared in Examples 1 to 8 and Comparative Examples 1 to 10. As can be seen from Table 1, when polyacrylamide is not used,
Since the paper becomes hard (the rigidity increases) and the folding crack strength (folding strength) decreases, the evaluation result of the blister resistance of the coated paper becomes low (see Comparative Examples 3, 4, 7, and 8). On the other hand, the combination of the cationized starch and polyacrylamide in an appropriate range can eliminate the above-mentioned drawbacks (Example 3,
See 4, 7, 8).

【0061】これに対し、ポリアクリルアミドを本発明
の範囲を越えて増量して併用し、逆にカチオン化デンプ
ンを減少させて耐ブリスター性を同じ水準に維持するこ
とができるが折り割れ強度が悪くなるし、又経済的にも
不利である(比較例1、2、5、6参照)。この場合、
カチオン化デンプンを増量し、ポリアクリルアミドを若
干減少させると品質と経済性にバランスがとれた状態で
耐ブリスター性を改善することができる(実施例1、
2、5、6参照)。
On the other hand, polyacrylamide can be used in an amount exceeding the range of the present invention so as to decrease the amount of cationized starch, and the blister resistance can be maintained at the same level. It is also economically disadvantageous (see Comparative Examples 1, 2, 5, and 6). in this case,
By increasing the amount of cationized starch and decreasing the amount of polyacrylamide slightly, it is possible to improve the blister resistance in a state where quality and economy are balanced (Example 1,
2, 5, 6).

【0062】一方、塗工原紙の絶乾米坪及び塗工量が本
発明の範囲より低い場合、ポリアクリルアミドの併用を
しなくとも耐ブリスター性の評価結果及び折り割れ強度
とも良好であり、本発明を適用する必要は無い(比較例
9参照)。さらに、カチオン化デンプンとポリアクリル
アミド以外の紙力増強剤を組み合わせても折り割れ強度
は低下し、耐ブリスター性を優れた水準にすることがで
きない(比較例10参照)。
On the other hand, when the absolute dry weight of the coated base paper and the coating amount are lower than the ranges of the present invention, the evaluation result of the blister resistance and the crease strength are good even if the polyacrylamide is not used in combination. It is not necessary to apply the invention (see Comparative Example 9). Furthermore, even if a cationized starch and a paper strength enhancer other than polyacrylamide are used in combination, the crease cracking strength is lowered and the blister resistance cannot be made to an excellent level (see Comparative Example 10).

【0063】[0063]

【発明の効果】以上の説明から明らかな如く、本発明
は、内添紙力増強剤としてカチオン化澱粉とポリアクリ
ルアミドを併用し、塗工原紙を構成するパルプ絶乾重量
当りの添加率を夫々0.3〜1.5重量%及び0.1〜
1.0重量%の範囲とすることで塗工紙の折り割れ強度
を向上させ、経済性を維持しながら印刷用塗工紙の耐ブ
リスター性を改良する塗工原紙を提供できるという効果
を奏する。
EFFECTS OF THE INVENTION As is clear from the above description, the present invention uses both cationic starch and polyacrylamide as an internal paper strength enhancer, and the addition ratios per absolute dry weight of the pulp constituting the coated base paper are different from each other. 0.3-1.5% by weight and 0.1
When the content is in the range of 1.0% by weight, there is an effect that it is possible to provide a coated base paper which improves the crease strength of the coated paper and improves the blister resistance of the coated paper for printing while maintaining the economical efficiency. .

【0064】[0064]

【表1】 [Table 1]

───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.5 識別記号 庁内整理番号 FI 技術表示箇所 7199−3B D21H 5/00 Z ─────────────────────────────────────────────────── ─── Continuation of the front page (51) Int.Cl. 5 Identification code Office reference number FI technical display location 7199-3B D21H 5/00 Z

Claims (1)

【特許請求の範囲】[Claims] 【請求項1】 顔料と接着剤を主成分とする塗工液を、
片面当り6g/m2(絶乾)以上、両面に塗工してオフ
セット印刷用塗工紙とするために用いられる絶乾米坪4
0g/m2 以上の原紙であって、該塗工原紙は、該原紙
を構成するパルプの絶乾重量当り、カチオン化デンプン
を0.3〜1.5重量%及びポリアクリルアミドを0.
1〜1.0重量%添加して製造されたものであることを
特徴とするオフセット印刷用塗工紙のための原紙。
1. A coating liquid containing a pigment and an adhesive as main components,
6 g / m 2 (absolute dryness) or more per side, absolutely dry rice tsubo 4 used for coating on both sides to make coated paper for offset printing
It is a base paper of 0 g / m 2 or more, and the coated base paper has 0.3 to 1.5% by weight of cationized starch and 0.1% by weight of polyacrylamide per absolute dry weight of pulp constituting the base paper.
A base paper for coated paper for offset printing, which is produced by adding 1 to 1.0% by weight.
JP19892592A 1992-07-03 1992-07-03 Base paper for offset printing coated paper Pending JPH0625996A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP19892592A JPH0625996A (en) 1992-07-03 1992-07-03 Base paper for offset printing coated paper

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP19892592A JPH0625996A (en) 1992-07-03 1992-07-03 Base paper for offset printing coated paper

Publications (1)

Publication Number Publication Date
JPH0625996A true JPH0625996A (en) 1994-02-01

Family

ID=16399249

Family Applications (1)

Application Number Title Priority Date Filing Date
JP19892592A Pending JPH0625996A (en) 1992-07-03 1992-07-03 Base paper for offset printing coated paper

Country Status (1)

Country Link
JP (1) JPH0625996A (en)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7160608B2 (en) 2003-06-30 2007-01-09 Oji Paper Co., Ltd. Coated paper
JP2007270369A (en) * 2006-03-30 2007-10-18 Nippon Paper Industries Co Ltd Coated paper for offset printing
US7618701B2 (en) 2005-08-01 2009-11-17 Hewlett-Packard Development Company, L.P. Porous pigment coating
JP2010007189A (en) * 2008-06-25 2010-01-14 Daio Paper Corp Highly opaque coated paper
WO2010101131A1 (en) * 2009-03-03 2010-09-10 日本製紙株式会社 Coated paper for printing and manufacturing method therefor
CN106049180A (en) * 2016-06-07 2016-10-26 岳阳林纸股份有限公司 Preparation method of high-bulk offset paper made from all wood pulp
CN114438812A (en) * 2021-12-31 2022-05-06 海南金海浆纸业有限公司 Multipurpose coated paper and production process thereof

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7160608B2 (en) 2003-06-30 2007-01-09 Oji Paper Co., Ltd. Coated paper
US7618701B2 (en) 2005-08-01 2009-11-17 Hewlett-Packard Development Company, L.P. Porous pigment coating
JP2007270369A (en) * 2006-03-30 2007-10-18 Nippon Paper Industries Co Ltd Coated paper for offset printing
JP2010007189A (en) * 2008-06-25 2010-01-14 Daio Paper Corp Highly opaque coated paper
WO2010101131A1 (en) * 2009-03-03 2010-09-10 日本製紙株式会社 Coated paper for printing and manufacturing method therefor
CN106049180A (en) * 2016-06-07 2016-10-26 岳阳林纸股份有限公司 Preparation method of high-bulk offset paper made from all wood pulp
CN114438812A (en) * 2021-12-31 2022-05-06 海南金海浆纸业有限公司 Multipurpose coated paper and production process thereof

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