JPH06198246A - Method for executing acid resistant and heat resistant lining - Google Patents

Abstract

PURPOSE:To provide an acid- and heat-resistant lining executing method using a practical lining material which has high corrosion resistance for a long period at high temperature by forming a specified penetration preventive layer as a first layer on the surface which needs acid resistance and heat resistance and forming a specified porous heat insulating layer on the first layer. CONSTITUTION:As a lining material for acid- and heat-resistant lining executing method, a penetration preventive layer 3 consisting of a thermosetting resin, which is hardened at normal temperature and mixed with flakes, is formed on the surface, e.g. the surface of a steel sheet 1, which needs acid resistance and heat resistance. Further on the layer, a porous heat insulating and protective layer 6 of a resin mortar prepared by mixing a thermosetting resin, e.g. phenol resin, which has high acid resistance and heat resistance and is hardened at normal temperature, with powder of a porous stone, e.g. Kokaseki (soda rhyolite). In this way, the flake lining is protected by forming the porous heat insulating and protective layer 6 and moreover since the thermal expansion coefficient of the heat insulating and protective layer 6 becomes close to that of the steel sheet 1, the lining can have high durability at high temperature.

Description

Detailed Description of the Invention

2. An acid-resistant and heat-resistant porous heat-insulating layer comprising a resin mortar containing an acid-resistant and heat-resistant thermosetting resin and 50 to 80% by weight of porous stone powder having a particle size of 0.2 to 3.0 mmφ. The acid-resistant and heat-resistant lining construction method according to claim 1, which is provided by using.

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention is used as a flue gas desulfurization device, an exhaust gas treatment device, a flue, a stack, a steel plate surface, and other various plants for corrosive high-temperature gas and for corrosion and corrosion protection of a portion accompanied by abrasion. The present invention relates to an acid resistant and heat resistant lining method.

[0002]

2. Description of the Related Art Conventionally, as shown in (1) [FIG. 2], a heat-curable thermosetting phenolic resin (2) having excellent acid resistance and heat resistance is used for the surface requiring acid resistance and heat resistance, for example, 0.2 ~ 0.4mm after applying on steel plate (1) surface
A phenol resin coating material that is baked and cured to a film thickness of a certain extent has existed for a long time. (2) As shown in FIG. 3, a room temperature-curable thermosetting resin mixed with glass flakes, carbon flakes, mica flakes, etc. There is a heat resistant permeation preventive layer with a thickness of about 2 mm, a so-called free reclining layer (3). (3) As shown in [FIG. 4], a room temperature curing type thermosetting phenol resin having excellent acid resistance and heat resistance and its reinforcing material are further provided on the flaking layer (3) of [FIG. 3]. It is also known to provide a so-called FRP lining layer (4), which is an acid-resistant and heat-resistant protective layer having a total thickness of about 3 to 5 mm using glass fibers or carbon fibers as the above. (4) As shown in [Fig. 5], a brick or anti-fire stone with excellent acid resistance and heat resistance is laminated on the flake lining layer (3) to protect the flake lining layer 60 to 300 mm thick. It is also known to provide a degree of britz lining layer (5).

[0003]

A heat-curable phenol coating material excellent in acid resistance and heat resistance as shown in FIG. 2 has heat resistance up to 180 ° C. and is oxidized by hot sulfuric acid. The surface layer of the coating is carbonized to form a corrosion resistant film. However, since the heat-curable phenol resin contains a solvent, water vapor is generated during the heat-curing due to the scattering of the solvent or the curing reaction, and bubbles are easily generated inside the coating to easily cause pinholes. Further, since the shrinkage during curing is large, fine cracks may occur in the corner portion having a small radius. As described above, since the heat-curable phenol coating material has various difficulties during construction, the film thickness is limited to about 0.2 to 0.4 mm, and the heat-curable thermosetting phenol resin has flexibility. Since it is scarce, if the film thickness is large, there are various problems that cracking is likely to occur due to thermal shock of rapid heating and cooling.

Further, the flake lining material shown in FIG. 3 has a heat resistance limit of 150 ° C. even when a novolak type vinyl ester resin having the highest heat resistance is used. Again 15
With hot sulfuric acid at 0 ° C or higher, oxidation from the surface layer deteriorates to cause cracking, which makes long-term durability difficult.

Further, the corrosion-resistant lining formed by the combination of the flake lining shown in FIG. 4 and the room-temperature curing type FRP lining is an excellent lining which is protected from hot sulfuric acid by the phenol FRP lining layer. However, if the lining layer becomes thick, there is a problem that peeling occurs between the laminated layers at 150 ° C. or higher due to the influence of shrinkage strain and thermal expansion at room temperature curing.

Further, the lining which protects the flake lining shown in FIG. 5 with bricks or anti-fire stones having excellent acid resistance, heat resistance and heat insulation is the most ideal lining, but the lining price is expensive. Since the weight is heavy, there is a problem in designing the body to be lined, and the construction period becomes extremely long.

In view of various problems to be solved by the above conventional lining materials, the present invention has an object to provide a new highly acid resistant and heat resistant lining method.

[0008]

The present invention provides a first layer of a permeation preventive layer made of a room temperature curable thermosetting resin in which flakes are mixed on a surface requiring acid resistance and heat resistance, for example, a steel plate surface,
An acid resistance comprising a thermosetting resin having high acid resistance and high heat resistance and porous stone powder such as anti-fire stone, and an acid resistance characterized by providing a second layer of a heat resistant porous heat insulating layer thereon; The present invention relates to a heat resistant lining method. Furthermore,

As shown in FIG. 1, the present invention provides a room temperature curing type thermosetting resin layer obtained by mixing flakes on a surface requiring acid resistance and heat resistance, for example, a steel plate surface, that is, a penetration preventing layer (3). Provided,
A resin mortar in which a room temperature curable thermosetting resin having excellent acid resistance and heat resistance (for example, phenol resin) and porous stone (for example, anti-fire stone) powder are mixed is applied thereon, and a heat insulating protective layer ( The present invention relates to an acid-resistant and heat-resistant lining method, which is characterized by the provision of 6).

As the room temperature curable resin for the flaking layer used in the present invention, a vinyl ester resin or an unsaturated polyester resin can be used. As the flakes to be mixed, glass flakes, carbon flakes,
Mica flakes and the like can be used. The content of flakes is preferably 10 to 40% by weight, and if it is less than 10% by weight, the apparent path is shortened, the permeation is accelerated, and the permeation resistance effect is reduced. On the other hand, if it exceeds 40% by weight, the workability is deteriorated and the air bubbles entrapped in the compound remain in the coating film without being completely exhausted.

The uppermost acid-resistant, heat-resistant and heat-insulating layer of the present invention is made of a mixed powder of a powder of a cold-setting type phenol resin or the like and a porous stone (for example, anti-fire stone). A resin mortar having a ratio of 50 to 80% by weight is preferably used. If the mixed powder is less than 50% by weight, a layer having a large amount of resin and hardened will not be porous, and the heat insulating effect will be poor and the spooling will be likely to occur. Further, when the mixed powder exceeds 80%, the tackiness of the compound becomes extremely small, which makes it difficult to construct walls and the like.

[0012]

As described above, the present invention protects the flake lining, which is the permeation preventive layer, by providing the heat insulating layer having porosity. Further, since the heat insulating layer according to the present invention has a thermal expansion coefficient close to that of a steel sheet, it can withstand a high temperature of 200 ° C. with a thickness of 5 mm.

[0013]

【Example】

Example 1 The test piece of the lining of the present invention shown in FIG. 1 was prepared as follows. 30% by weight of glass flakes with a particle size of 0.5 to 2.5 mm on a steel plate (1) that has been sandblasted.
The mixed novolak type vinyl ester room temperature curing type resin binder (3) was applied with a trowel to a thickness of 1 mm and left at room temperature for 24 hours. After repeating this twice, a room temperature curing type phenol resin was mixed with 0.2-3.0 mmφ anti-fire stone powder etc. at a ratio of 1: 2.5 by weight to the resin.
It was applied to a thickness of 5 mm on average and left at room temperature for 7 days.

[0014]

COMPARATIVE EXAMPLE 1 The phenol coating test piece shown in FIG. 2 was prepared as follows. Apply the heat-curable phenolic resin to the sandblasted steel plate (1) three times,
Heat cured for 30 minutes in a 130 ° C heating oven (thickness 0.08m
m). This was repeated 3 times and finally heat-cured at 200 ° C for 1 hour to form the second layer (2) (thickness 0.2-0.3m).
m).

[0015]

[Comparative Example 2] The flaking line test piece shown in FIG. 3 was prepared as follows. A flaking layer (2 mm thick) shown in (3) of FIG. 1 was laminated on a steel plate (1) that had been sandblasted, and left at room temperature for 7 hours.

[0016]

COMPARATIVE EXAMPLE 3 The lining test piece shown in FIG. 4 was prepared as follows. Flake lining layer (2 mm thick) shown in (3) of [Fig. 1] on a steel plate (1) sandblasted.
After being laminated for 24 hours, a glass cloth was further laminated thereon with a room temperature curable thermosetting phenol resin (4) to have a thickness of 2 mm, and then left at room temperature for 7 hours. The following two types of tests were performed on the above four types of test pieces.

[0017]

[Test 1] The lining surface of the above-mentioned test piece (one-sided construction) was attached to the inside in a constant temperature bath, the inside was heated to 200 ° C., and the other side was brought into contact with room temperature. It was heated for 8 hours in the daytime and allowed to cool at night. This was repeated. The test results are shown in [Table 1].

[0018]

[Table 1]

[0019]

[Test 2] 70% sulfuric acid at 165 ° C for the above test piece (both sides installed)
Sulfuric acid resistance test was carried out by immersing in, and the test results are shown in Table 2.

[0020]

[Table 2] As shown in [Table 1] and [Table 2], it was confirmed that the lining material obtained by the method of the present invention has excellent heat resistance and sulfuric acid resistance.

[0021]

EFFECTS OF THE INVENTION Conventional linings or coatings are flue gas desulfurizers that come into contact with high temperature and high concentration sulfuric acid due to chemical deterioration of the resin itself or defects during construction as shown in [Table 1] and [Table 2]. It was not sufficient as an anticorrosion lining for equipment, chimneys, flues, etc. Further, in the case of a construction method in which a heat insulating layer made of acid-resistant, heat-resistant brick, anti-fire stone, etc. is provided, the performance can be sufficiently guaranteed, but the price is extremely high, and the construction period is long, which is not a practical lining method in the usual case. The combination of the room temperature curable thermosetting resin flake lining of the present invention, the room temperature curable thermosetting resin and the like and the protective lining of the mixed resin mortar such as the porous stone powder makes it possible to use the conventional method as described above. A method has been completed that improves the drawbacks of the method and provides a practical lining material that has long-term corrosion resistance at high temperatures.
By using the lining material obtained by the lining method of the present invention, the scope of application can be greatly expanded.

[Brief description of drawings]

FIG. 1 is an example in which the resin mortar lining in which porous stone powder is added is further applied to the flake lining of the present invention.

FIG. 2 Conventional phenol coating for steel plate.

FIG. 3 shows a case where conventional flaking is applied.

FIG. 4 shows a case where a phenol FRP lining is further applied on the flake lining shown in FIG.

FIG. 5 shows a diagram in which a bullet lining is further laminated on the conventional flake lining of FIG.

[Explanation of symbols]

 1. Steel plate 2. Phenol coating layer 3. Free reclining layer 4. Phoenix FRP lining layer 5. Britz lining layer 6. Room temperature curable thermosetting resin mortar lining layer

─────────────────────────────────────────────────── ───

[Procedure amendment]

[Submission date] April 2, 1993

[Procedure Amendment 1]

[Document name to be amended] Statement

[Correction target item name] Full text

[Correction method] Change

[Correction content]

[Document name] Statement

[Title of Invention] Acid-resistant and heat-resistant lining method

[Claims]

Detailed Description of the Invention

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention is used as a flue gas desulfurization device, an exhaust gas treatment device, a flue, a stack, a steel plate surface, and other various plants for corrosive high-temperature gas and for corrosion and corrosion protection of a portion accompanied by abrasion. The present invention relates to an acid resistant and heat resistant lining method.

[0002]

2. Description of the Related Art Conventionally, as shown in (1) [FIG. 2], a heat-curable thermosetting phenolic resin (2) having excellent acid resistance and heat resistance is applied to a surface requiring acid resistance and heat resistance, for example, a steel plate ( 1) After applying to the surface, 0.
A phenol resin coating material that has been baked and cured to a film thickness of about 2 to 0.4 mm has existed for a long time. (2) As shown in FIG. 3, a room temperature-curable thermosetting resin mixed with glass flakes, carbon flakes, mica flakes or the like, for example, about 1.5 to 2 mm composed of novolak type vinyl ester resin. There is a thick heat resistant permeation preventive layer, the so-called flare lining layer (3). (3) As shown in [FIG. 4], a room temperature-curable thermosetting phenolic resin having excellent acid resistance and heat resistance and glass fiber or a reinforcing material therefor on the flaking layer (3) of [FIG. Acid-resistant and heat-resistant protective layer using carbon fiber with a total thickness of about 3 to 5 mm, so-called FRP lining layer (4)
It is also known to provide. (4) As shown in FIG. 5, bricks or anti-fire stones having excellent acid resistance and heat resistance are laminated on the flare lining layer (3) to protect the flare lining layer 60 to 300.
It is also known to provide a britz lining layer (5) with a thickness of about mm.

[0003]

[Fig. 2]

[0004]

[Figure 3]

[0005]

[Figure 4]

[0006]

[Figure 5]

[0007]

The heat-curable phenol coating material having excellent acid resistance and heat resistance as shown in FIG. 2 has heat resistance up to 180 ° C. and the surface of the coating is oxidized by the action of hot sulfuric acid. The layer is carbonized to form a corrosion resistant coating. However, since the heat-curable phenol resin contains a solvent, water vapor is generated due to the scattering of the solvent or the curing reaction at the time of heat-curing, and bubbles are easily generated inside the coating to easily cause pinholes. Further, since the shrinkage during curing is large, fine cracks may occur at the corners with small radius. As described above, since the heat-curable phenol coating material has various difficulties at the time of construction, the film thickness is limited to about 0.2 to 0.4 mm, and the heat-curable thermosetting phenol resin is poor in flexibility. When the film thickness is large, there are various problems that cracks are likely to occur due to thermal shock of rapid heating and cooling.

Further, the flaking material shown in FIG. 3 has a heat resistance limit of 150 ° C. even when a novolak type vinyl ester resin having the highest heat resistance is used. Further, when hot sulfuric acid at 150 ° C. or higher is oxidized from the surface layer and deteriorates to cause cracking, long-term durability is difficult.

Further, the corrosion-resistant lining obtained by the combination of the flare lining shown in FIG. 4 and the room temperature-curable phenol FRP lining is an excellent lining that is protected from hot sulfuric acid by the phenol FRP lining layer. If the thickness becomes thicker, there is a problem that peeling occurs between the laminated layers at 150 ° C. or higher due to the influence of shrinkage strain and thermal expansion at the time of room temperature curing.

Further , the lining for protecting the flare lining shown in FIG. 5 with bricks or anti-fire stones having excellent acid resistance, heat resistance and heat insulation is the most ideal lining, but the lining price is expensive and the weight is heavy. Since it is heavy, there is a problem in designing the body to be lined, and there is a problem that the construction period becomes extremely long.

In view of various problems to be solved by the conventional lining materials described above, it is an object of the present invention to provide a new highly acid resistant and heat resistant lining method.

[0012]

The present invention provides a first layer of a permeation-preventing layer composed of a room temperature-curable thermosetting resin mixed with flakes on a surface requiring acid resistance and heat resistance, for example, a steel plate surface,
An acid resistance comprising a thermosetting resin having high acid resistance and high heat resistance and porous stone powder such as anti-fire stone, and an acid resistance characterized by providing a second layer of a heat resistant porous heat insulating layer thereon; The present invention relates to a heat resistant lining method. Furthermore,

In the present invention, as shown in FIG. 1, a room temperature-curable thermosetting resin layer prepared by mixing flakes on a surface requiring acid resistance and heat resistance, for example, a steel plate surface, that is, a penetration preventing layer (3), A resin mortar in which a room temperature curable thermosetting resin (for example, phenol resin) having excellent acid resistance and heat resistance and porous stone (for example, anti-fire stone) powder are mixed is applied thereon, and a heat insulating protective layer (6) is applied. The present invention relates to an acid resistant and heat resistant lining construction method.

[0014]

[Figure 1]

As the room temperature curable resin for the flaking layer used in the present invention, a vinyl ester resin or an unsaturated polyester resin can be used. Glass flakes, carbon flakes,
Mica flakes can be used. The content of flakes is preferably 10 to 40% by weight, and if it is less than 10% by weight, the apparent path is shortened, the permeation is accelerated, and the permeation resistance effect is reduced. On the other hand, if it exceeds 40% by weight, the workability is deteriorated and the air bubbles entrapped in the compound do not completely escape and remain in the coating film.

The top layer of the oxidation of the present invention, heat-resistant, heat-insulating layer is made of mixed powder of powder or the like of the cold-setting phenolic resins and a porous stone (e.g. Fire-stone, etc.), the proportion of porous stone powder to be mixed A resin mortar having 50 to 80% by weight is preferably used. If the mixed powder is less than 50% by weight, the resin content is large and the cured layer is not porous, and the heat insulating effect is poor and spalling is likely to occur. On the other hand, if the mixed powder exceeds 80%, the adhesiveness of the compound becomes extremely small, which makes it difficult to construct a wall or the like.

[0017]

As described above, the present invention protects the flare lining, which is the permeation preventive layer, by providing the heat insulating layer having porosity. Further, since the heat insulating layer according to the present invention has a thermal expansion coefficient close to that of a steel plate, it can withstand a high temperature of 200 ° C. with a thickness of 5 mm.

[0018]

EXAMPLES Example 1 A test piece of the lining of the present invention shown in FIG. 1 was prepared as follows. Apply the novolak type vinyl ester room temperature curing type resin composite (3) with 30% by weight of glass flakes having a particle size of 0.5 to 2.5 mm to the sandblasted steel plate (1) with a trowel to a thickness of 1 mm. Left for 24 hours. After repeating this twice,
A resin mortar (6) prepared by mixing cold-curing type phenol resin with 0.2 to 3.0 mmφ anti-fire stone powder etc. at a ratio of 1: 2.5 by weight to the resin was applied once with an iron to an average thickness of 5 mm. It was left at room temperature for 7 days.

[0019]

[Embodiment 2] Approximately 20 high temperature gas inlets of a wet flue gas desulfurizer
The lining method of the present invention was applied to 0 m ² with a total thickness of 7 mm, and the exhaust gas temperature was operated at 170 to 180 ° C. for 5 years.
As a result, no abnormality was recognized only by the discoloration of the coating film.

[0020]

[Example 3] A lining method of the present invention was applied to a reheated portion of an outlet gas of a gas cleaning tower in an urban refuse incinerator for about 100 m ² with a total thickness of 7 mm. Gas temperature 180-2
After operating at 00 ° C for 4 years, the coating film was only discolored and no abnormality was observed.

[0021]

[Example 4] Exhaust gas flue of a thermal power plant (4 m x 5 m x 5
The lining method of the present invention was applied to a 0 ml) inner layer with a thickness of 7 mm. After operating for 5 years at an exhaust gas temperature of 170 to 180 ° C., the coating film was only discolored and no abnormality was observed.

[0022]

Comparative Example 4 The phenol coating test piece shown in FIG. 2 was prepared as follows. The heat-curable phenol resin was applied three times to the steel plate (1) that had been sandblasted and heat-cured for 30 minutes in a heating furnace at 130 ° C. (thickness 0.08 mm). Repeat this 3 times and finally 200 ℃
Then, it was heat-cured for 1 hour to prepare a second layer (2) (thickness: 0.2 to 0.3 mm).

[0023]

[Comparative Example 2] The flaking line test piece shown in FIG. 3 was prepared as follows. A flaking layer (2 mm thick) shown in (3) of FIG. 1 was laminated on the steel plate (1) that had been sandblasted, and left standing at room temperature for 7 hours.

[0024]

COMPARATIVE EXAMPLE 3 The lining test piece shown in FIG. 4 was prepared as follows. Steel plate sandblasted (1)
The flaking layer (2 m) shown in (3) of [Fig. 1]
m) was laminated and left for 24 hours, and a glass cloth was further laminated thereon with a room temperature curable thermosetting phenol resin (4) to have a thickness of 2 mm, and then left at room temperature for 7 hours. The following two types of tests were performed on the above four types of test pieces.

[0025]

[Test 1] The lining surface of the above-mentioned test piece (single-sided construction) was attached to the inside in a constant temperature bath, the inside was heated to 200 ° C., and the other side was brought into contact with room temperature. It was heated for 8 hours in the daytime and allowed to cool at night. This was repeated. The test results are shown in [Table 1].

[0026]

[Table 1]

[0027]

[Test 2] 70% sulfuric acid, 16
Sulfuric acid resistance test was conducted by immersing in 5 ° C. and the test results are shown in [Table 2].

[0028]

[Table 2] As shown in [Table 1] and [Table 2], it was confirmed that the lining material obtained by the method of the present invention has excellent heat resistance and sulfuric acid resistance.

[0029]

As shown in [Table 1] and [Table 2], the conventional linings or coatings use a flue gas desulfurization device that comes into contact with high temperature and high concentration sulfuric acid due to chemical deterioration of the resin itself or defects during construction. It was not enough as an anticorrosion lining for chimneys and flues. Further, in the case of a construction method in which a heat insulating layer made of acid-resistant, heat-resistant brick, anti-fire stone, etc. is provided, the performance can be sufficiently guaranteed, but the price is extremely high, and the construction period is long, which is not a practical lining method in the usual case. The combination of the room temperature-curable thermosetting resin flake lining of the present invention, the room temperature-curing thermosetting resin, etc., and the protective lining with the mixed resin mortar, such as porous stone powder, is used for the first time in the conventional method as described above. A method of improving the defects and providing a practical lining material having long-term corrosion resistance at high temperature has been completed.
By using the lining material obtained by the lining method of the present invention, the scope of application can be greatly expanded.

[Brief description of drawings]

FIG. 1 shows an example in which a phenol resin mortar lining in which porous stone powder is further added is applied to the flare lining of the present invention.

FIG. 2 Conventional phenol coating for steel plate.

FIG. 3 shows the case where conventional flaking is applied.

FIG. 4 shows a case where a phenol FRP lining is further applied on the flare lining shown in FIG.

FIG. 5 shows a diagram in which a bullet lining is further laminated on the conventional flare lining of FIG.

[Explanation of symbols] 1. Steel plate 2. Phenol coating layer 3. Flare lining layer 4. Phoenix FRP lining layer 5. Britz lining layer 6. Room temperature curable thermosetting resin mortar lining layer

[Procedure amendment]

[Submission date] December 28, 1993

[Procedure Amendment 2]

[Document name to be amended] Statement

[Correction target item name] Full text

[Correction method] Change

[Correction content]

[Document name] Statement

[Title of Invention] Acid-resistant and heat-resistant lining method

[Claims]

Detailed Description of the Invention

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention is used as a flue gas desulfurization device, an exhaust gas treatment device, a flue, a stack, a steel plate surface, and other various plants for corrosive high-temperature gas and for corrosion and corrosion protection of a portion accompanied by abrasion. The present invention relates to an acid resistant and heat resistant lining method.

[0002]

2. Description of the Related Art Conventionally, as shown in (1) [FIG. 2], a heat-curable thermosetting phenolic resin (2) having excellent acid resistance and heat resistance is applied to a surface requiring acid resistance and heat resistance, for example, a steel plate ( 1) After applying to the surface, 0.
A phenol resin coating material that has been baked and cured to a film thickness of about 2 to 0.4 mm has existed for a long time. (2) As shown in FIG. 3, a room temperature-curable thermosetting resin mixed with glass flakes, carbon flakes, mica flakes or the like, for example, about 1.5 to 2 mm composed of novolak type vinyl ester resin. There is a thick heat resistant permeation preventive layer, the so-called flare lining layer (3). (3) As shown in [FIG. 4], a room temperature-curable thermosetting phenolic resin having excellent acid resistance and heat resistance and glass fiber or a reinforcing material therefor on the flaking layer (3) of [FIG. Acid-resistant and heat-resistant protective layer using carbon fiber with a total thickness of about 3 to 5 mm, so-called FRP lining layer (4)
It is also known to provide. (4) As shown in FIG. 5, bricks or anti-fire stones having excellent acid resistance and heat resistance are laminated on the flare lining layer (3) to protect the flare lining layer 60 to 300.
It is also known to provide a britz lining layer (5) with a thickness of about mm.

[0003]

The heat-curable phenol coating material having excellent acid resistance and heat resistance as shown in FIG. 2 has heat resistance up to 180 ° C. and the surface of the coating is oxidized by the action of hot sulfuric acid. The layer is carbonized to form a corrosion resistant coating. However, since the heat-curable phenol resin contains a solvent, water vapor is generated due to the scattering of the solvent or the curing reaction at the time of heat-curing, and bubbles are easily generated inside the coating to easily cause pinholes. Further, since the shrinkage during curing is large, fine cracks may occur at the corners with small radius. As described above, since the heat-curable phenol coating material has various difficulties at the time of construction, the film thickness is limited to about 0.2 to 0.4 mm, and the heat-curable thermosetting phenol resin is poor in flexibility. When the film thickness is large, there are various problems that cracks are likely to occur due to thermal shock of rapid heating and cooling.

Further, in the flaking material shown in FIG. 3, the heat resistance is limited to 150 ° C. even when the novolak type vinyl ester resin having the highest heat resistance is used. Further, when hot sulfuric acid at 150 ° C. or higher is oxidized from the surface layer and deteriorates to cause cracking, long-term durability is difficult.

Further, the corrosion-resistant lining by the combination of the flare lining shown in FIG. 4 and the room temperature curing type phenol FRP lining is an excellent lining which is protected from hot sulfuric acid by the phenol FRP lining layer. If the thickness becomes thicker, there is a problem that peeling occurs between the laminated layers at 150 ° C. or higher due to the influence of shrinkage strain and thermal expansion at the time of room temperature curing.

Further, the lining which protects the flare lining shown in FIG. 5 with bricks or anti-fire stones having excellent acid resistance, heat resistance and heat insulation is the most ideal lining, but the lining price is expensive and the weight is heavy. Since it is heavy, there is a problem in designing the body to be lined, and there is a problem that the construction period becomes extremely long.

In view of various problems to be solved by the above conventional lining materials, the present invention has an object to provide a new highly acid resistant and heat resistant lining method.

[0008]

The present invention provides a first layer of a permeation-preventing layer composed of a room temperature-curable thermosetting resin mixed with flakes on a surface requiring acid resistance and heat resistance, for example, a steel plate surface,
An acid resistance comprising a thermosetting resin having high acid resistance and high heat resistance and porous stone powder such as anti-fire stone, and an acid resistance characterized by providing a second layer of a heat resistant porous heat insulating layer thereon; The present invention relates to a heat resistant lining method. Furthermore,

As shown in FIG. 1, the present invention provides a room temperature-curable thermosetting resin layer, ie, a permeation-preventing layer (3) prepared by mixing flakes on a surface requiring acid resistance and heat resistance, for example, a steel plate surface, A resin mortar in which a room temperature curable thermosetting resin (for example, phenol resin) having excellent acid resistance and heat resistance and porous stone (for example, anti-fire stone) powder are mixed is applied thereon, and a heat insulating protective layer (6) is applied. The present invention relates to an acid resistant and heat resistant lining construction method.

As the room temperature curable resin used in the present invention, a vinyl ester resin or an unsaturated polyester resin can be used. Glass flakes, carbon flakes,
Mica flakes can be used. The content of flakes is preferably 10 to 40% by weight, and if it is less than 10% by weight, the apparent path is shortened, the permeation is accelerated, and the permeation resistance effect is reduced. On the other hand, if it exceeds 40% by weight, the workability is deteriorated and the air bubbles entrapped in the compound do not completely escape and remain in the coating film.

The acid-resistant, heat-resistant and heat-insulating layer of the uppermost layer of the present invention is made of a mixed powder of a powder of a cold-setting type phenol resin or the like and a porous stone (for example, anti-fire stone), and the ratio of the mixed porous stone powder. A resin mortar having 50 to 80% by weight is preferably used. If the mixed powder is less than 50% by weight, the resin content is large and the cured layer is not porous, and the heat insulating effect is poor and spalling is likely to occur. On the other hand, if the mixed powder exceeds 80%, the adhesiveness of the compound becomes extremely small, which makes it difficult to construct a wall or the like.

[0012]

As described above, the present invention protects the flare lining, which is the permeation preventive layer, by providing the heat insulating layer having porosity. Further, since the heat insulating layer according to the present invention has a thermal expansion coefficient close to that of a steel plate, it can withstand a high temperature of 200 ° C. with a thickness of 5 mm.

[0013]

【Example】

Example 1 A test piece of the lining of the present invention shown in FIG. 1 was prepared as follows. Apply the novolak type vinyl ester room temperature curing type resin composite (3) with 30% by weight of glass flakes having a particle size of 0.5 to 2.5 mm to the sandblasted steel plate (1) with a trowel to a thickness of 1 mm. Left for 24 hours. After repeating this twice,
A resin mortar (6) prepared by mixing cold-curing type phenol resin with 0.2 to 3.0 mmφ anti-fire stone powder etc. at a ratio of 1: 2.5 by weight to the resin was applied once with an iron to an average thickness of 5 mm. It was left at room temperature for 7 days.

[0014]

[Embodiment 2] Approximately 20 high temperature gas inlets of a wet flue gas desulfurizer
The lining method of the present invention was applied to 0 m ² with a total thickness of 7 mm, and the exhaust gas temperature was operated at 170 to 180 ° C. for 5 years.
As a result, no abnormality was recognized only by the discoloration of the coating film.

[0015]

[Example 3] A lining method of the present invention was applied to a reheated portion of an outlet gas of a gas cleaning tower in an urban refuse incinerator for about 100 m ² with a total thickness of 7 mm. Gas temperature 180-2
After operating at 00 ° C for 4 years, the coating film was only discolored and no abnormality was observed.

[0016]

[Example 4] Exhaust gas flue of a thermal power plant (4 m x 5 m x 5
The lining method of the present invention was applied to the inner surface of 0 ml) to a thickness of 7 mm. After operating for 5 years at an exhaust gas temperature of 170 to 180 ° C., the coating film was only discolored and no abnormality was observed.

[0017]

[Comparative Example 1] A phenol coating test piece shown in FIG. 2 was prepared as follows. The heat-curable phenol resin was applied three times to the steel plate (1) that had been sandblasted and heat-cured for 30 minutes in a heating furnace at 130 ° C. (thickness 0.08 mm). Repeat this 3 times and finally 200 ℃
Then, it was heat-cured for 1 hour to prepare a second layer (2) (thickness: 0.2 to 0.3 mm).

[0018]

[Comparative Example 2] The flaking line test piece shown in FIG. 3 was prepared as follows. A flaking layer (2 mm thick) shown in (3) of FIG. 1 was laminated on the steel plate (1) that had been sandblasted, and left standing at room temperature for 7 hours.

[0019]

[Comparative Shark Example 3] The test piece of the lining shown in FIG. 4 was prepared as follows. Steel plate sandblasted (1)
The flaking layer (2 m) shown in (3) of [Fig. 1]
m) was laminated and left for 24 hours, and a glass cloth was further laminated thereon with a room temperature curable thermosetting phenol resin (4) to have a thickness of 2 mm, and then left at room temperature for 7 hours. The following two types of tests were performed on the above four types of test pieces.

[0020]

[Test 1] The lining surface of the above-mentioned test piece (single-sided construction) was attached to the inside in a constant temperature bath, the inside was heated to 200 ° C., and the other side was brought into contact with room temperature. It was heated for 8 hours in the daytime and allowed to cool at night. This was repeated. The test results are shown in [Table 1].

[0021]

[Table 1]

[0022]

[Test 2] 70% sulfuric acid, 16
Sulfuric acid resistance test was conducted by immersing in 5 ° C. and the test results are shown in [Table 2].

[0023]

[Table 2] As shown in [Table 1] and [Table 2], it was confirmed that the lining material obtained by the method of the present invention has excellent heat resistance and sulfuric acid resistance.

[0024]

As shown in [Table 1] and [Table 2], the conventional linings or coatings use a flue gas desulfurization device that comes into contact with high temperature and high concentration sulfuric acid due to chemical deterioration of the resin itself or defects during construction. It was not enough as an anticorrosion lining for chimneys and flues. Further, in the case of a construction method in which a heat insulating layer made of acid-resistant, heat-resistant brick, anti-fire stone, etc. is provided, the performance can be sufficiently guaranteed, but the price is extremely high, and the construction period is long, which is not a practical lining method in the usual case. The combination of the room temperature-curable thermosetting resin flake lining of the present invention, the room temperature-curing thermosetting resin, etc., and the protective lining with the mixed resin mortar, such as porous stone powder, is used for the first time in the conventional method as described above. A method of improving the defects and providing a practical lining material having long-term corrosion resistance at high temperature has been completed.
By using the lining material obtained by the lining method of the present invention, the scope of application can be greatly expanded.

[Brief description of drawings]

FIG. 1 shows an example in which a phenol resin mortar lining in which porous stone powder is further added is applied to the flare lining of the present invention.

FIG. 2 Conventional phenol coating for steel plate.

FIG. 3 shows the case where conventional flaking is applied.

FIG. 4 shows a case where a phenol FRP lining is further applied on the flare lining shown in FIG.

FIG. 5 shows a diagram in which a bullet lining is further laminated on the conventional flare lining of FIG.

[Explanation of symbols] 1. Steel plate 2. Phenol coating layer 3. Flare lining layer 4. Phoenix FRP lining layer 5. Britz lining layer 6. Room temperature curable thermosetting resin mortar lining layer

Claims (1)

[Claims] 1. A first layer of a permeation preventive layer comprising a room temperature curable thermosetting resin mixed with flakes on a surface requiring acid resistance and heat resistance, and further heat resistance is provided on the first layer. An acid-resistant and heat-resistant lining construction method, characterized in that an acid-resistant and heat-resistant porous heat insulating layer comprising an acid-resistant thermosetting resin and porous stone powder is provided.