JPH06182345A - Water purification device - Google Patents

Water purification device

Info

Publication number
JPH06182345A
JPH06182345A JP34014592A JP34014592A JPH06182345A JP H06182345 A JPH06182345 A JP H06182345A JP 34014592 A JP34014592 A JP 34014592A JP 34014592 A JP34014592 A JP 34014592A JP H06182345 A JPH06182345 A JP H06182345A
Authority
JP
Japan
Prior art keywords
aluminum
electrode plates
plates
water
electrode
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP34014592A
Other languages
Japanese (ja)
Inventor
Kunio Asai
邦夫 浅井
Hiroshi Matsumura
浩史 松村
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Tonen General Sekiyu KK
Original Assignee
Tonen Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tonen Corp filed Critical Tonen Corp
Priority to JP34014592A priority Critical patent/JPH06182345A/en
Publication of JPH06182345A publication Critical patent/JPH06182345A/en
Pending legal-status Critical Current

Links

Abstract

PURPOSE:To eliminate the necessity of wiring connection work with a power source at the time of replacing an aluminum plate and utilize effectively power source electricity. CONSTITUTION:A device comprises an electrolysis cell 4 circulating waste water, a couple of electrode plates 5a and 5b provided in the electrolysis cell 4, a plurality of aluminum plates 6 disposed between the electrode plates 5a and 5b, and solar battery 7 connected with the electrode plates 5a and 5b.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は、洗濯廃水、工場廃水、
食品廃水、家庭用廃水等の種々の廃水から汚濁物質を除
去するための水浄化装置に関する。
BACKGROUND OF THE INVENTION The present invention relates to laundry wastewater, factory wastewater,
The present invention relates to a water purification device for removing pollutants from various wastewater such as food wastewater and household wastewater.

【0002】[0002]

【従来の技術】洗濯廃水、工場廃水、食品廃水、家庭用
廃水等の種々の廃水中には、濁り、着色成分、細菌類、
藻類などが1μmから1nm程度の寸法のコロイド成分
として存在する。これらのコロイド成分は、水中で通
常、負の電荷を帯びており、2つの粒子が接近しても互
いに反発し、また、粒子の表面には親水性により水分子
を引き付けているため、安定した状態で水中に分散して
存在する。
BACKGROUND OF THE INVENTION Various kinds of wastewater such as laundry wastewater, factory wastewater, food wastewater, household wastewater, etc. are turbid, colored components, bacteria,
Algae and the like exist as colloidal components having a size of about 1 μm to 1 nm. These colloidal components are usually negatively charged in water, repel each other when two particles are close to each other, and have a hydrophilic property to attract water molecules to the surface of the particles, so that they are stable. It exists in the state dispersed in water.

【0003】このようなコロイドの安定状態をくずして
粒子を相互に接触させ集塊、すなわち凝集させるため
に、コロイド粒子と反対の電荷をもったイオンなどの微
粒子を水に加える凝集剤が知られている。一般に使用さ
れている凝集剤は、容易に加水分解して正電荷の水酸化
物のポリマーとなる金属塩、例えばアルミや鉄の塩であ
り、コロイドの表面の負の電荷を加えた凝集剤の正の電
荷により中和させ、粒子相互間を分子間力によって結合
させるとともに、ポリマーの成分がその架橋作用により
コロイド粒子双方に吸着することにより、コロイド粒子
を凝集させるものである。
In order to destroy the stable state of such colloids and bring the particles into contact with each other to agglomerate, that is, to agglomerate, a flocculant for adding fine particles such as ions having an opposite charge to the colloidal particles to water is known. ing. Commonly used flocculants are metal salts that easily hydrolyze into positively charged hydroxide polymers, such as aluminum and iron salts. It is neutralized by a positive charge, and the particles are bound to each other by an intermolecular force, and the component of the polymer is adsorbed to both the colloidal particles due to its cross-linking action, whereby the colloidal particles are aggregated.

【0004】従来、前記アルミニウム塩による水浄化装
置としては、廃水中に多数のアルミ板を平行に並べ、ア
ルミ板を交互に正極、負極となるように直流電源に並列
に接続し、それぞれのアルミ板から電気分解によりアル
ミイオンを発生させ、これが水中の水酸イオンと結合し
て加水分解重合し、正電荷のポリマーイオンを発生させ
る方式が知られている。
Conventionally, as a water purifier using the above-mentioned aluminum salt, a large number of aluminum plates are arranged in parallel in wastewater, and the aluminum plates are connected in parallel to a DC power source so as to alternately serve as a positive electrode and a negative electrode. A method is known in which aluminum ions are generated from a plate by electrolysis, and the aluminum ions are combined with hydroxide ions in water to be hydrolytically polymerized to generate positively charged polymer ions.

【0005】[0005]

【発明が解決しようとする課題】しかしながら、上記従
来の水浄化装置においては、アルミ板が消耗品であるた
めに、所定期間毎に新規なアルミ板と交換する必要があ
るが、アルミ板を交互に正極、負極となるように直流電
源に接続しているため、交換時にその配線接続作業に多
大の労力を要するという問題を有している。また、アル
ミイオン発生に必要な電極電圧は1.662Vであるの
で、それ以上の電圧をもつ一般の電源では電力を有効に
利用できず、その大部分を水の抵抗で消費してしまうと
いう問題を有している。
However, in the above-mentioned conventional water purifying apparatus, since the aluminum plate is a consumable item, it is necessary to replace it with a new aluminum plate every predetermined period. In addition, since the positive and negative electrodes are connected to the DC power source, there is a problem that a great deal of labor is required for the wiring connection work at the time of replacement. Further, since the electrode voltage required for generating aluminum ions is 1.662V, a general power supply having a voltage higher than that cannot effectively use electric power, and most of it is consumed by water resistance. have.

【0006】本発明は上記問題を解決するものであっ
て、アルミ板の交換時における電源との配線接続作業を
不要とすることができ、かつ、電源の出力特性に合わせ
て有効に電力を消費することができる水浄化装置を提供
することを目的とする。
The present invention is intended to solve the above-mentioned problems, and it is possible to eliminate the work of wiring connection to a power source when replacing an aluminum plate, and to effectively consume power in accordance with the output characteristics of the power source. It is an object of the present invention to provide a water purification device that can do the above.

【0007】[0007]

【課題を解決するための手段】そのために本発明の水浄
化装置は、廃水が循環される電解槽4と、該電解槽4内
に設けられる1対の電極板5a、5bと、これら1対の
電極板5a、5b間に複数配置されるアルミ板6と、前
記1対の電極板5a、5bに接続される太陽電池7とを
備えることを特徴とする。なお、上記構成に付加した番
号は、理解を容易にするために図面と対比させるための
もので、これにより本発明の構成が何ら限定されるもの
ではない。
To this end, the water purifying apparatus of the present invention comprises an electrolytic cell 4 in which waste water is circulated, a pair of electrode plates 5a, 5b provided in the electrolytic cell 4, and a pair of these. 1. A plurality of aluminum plates 6 are arranged between the electrode plates 5a and 5b, and a solar cell 7 connected to the pair of electrode plates 5a and 5b. It should be noted that the numbers added to the above configurations are for comparison with the drawings for easy understanding, and the configurations of the present invention are not limited thereby.

【0008】[0008]

【作用】本発明においては、電解槽4内において、電極
板5a、5bのみが正極、負極となるように直流電源に
接続され、それぞれのアルミ板6から電気分解によりア
ルミイオンを発生させ、これが水中の水酸イオンと結合
して加水分解重合し、正電荷のポリマーイオンを発生さ
せ、廃水中のコロイド成分を凝集する。
In the present invention, in the electrolytic cell 4, only the electrode plates 5a and 5b are connected to the DC power source so that they serve as the positive electrode and the negative electrode, and aluminum ions are generated from each aluminum plate 6 by electrolysis. It binds to the hydroxide ion in water and undergoes hydrolysis polymerization to generate positively charged polymer ions, and aggregates the colloidal components in the waste water.

【0009】[0009]

【実施例】以下、本発明の実施例を図面を参照しつつ説
明する。図1は本発明の水処理装置の1実施例を示す構
成図であり、図2は図1の電解槽を示し、図2(A)は
電解槽の平面図、図2(B)は図2(A)のB−B線に
沿って矢印方向に見た断面図である。
Embodiments of the present invention will be described below with reference to the drawings. 1 is a configuration diagram showing one embodiment of a water treatment apparatus of the present invention, FIG. 2 shows the electrolytic cell of FIG. 1, FIG. 2 (A) is a plan view of the electrolytic cell, and FIG. 2 (B) is a diagram. It is sectional drawing seen in the arrow direction along the BB line of 2 (A).

【0010】図1において、洗濯廃水、工場廃水、食品
廃水、家庭用廃水等の種々の廃水は、供給管1から池ま
たは廃水貯留槽2に貯められる。廃水貯留槽2は、ポン
プ3を介して電解槽4に配管接続され、廃水貯留槽2内
の廃水は、ポンプ3により電解槽4に送られ、ここで浄
化された後、廃水貯留槽2内に戻るように循環される。
In FIG. 1, various kinds of waste water such as laundry waste water, factory waste water, food waste water, household waste water, etc. are stored from a supply pipe 1 into a pond or a waste water storage tank 2. The wastewater storage tank 2 is pipe-connected to the electrolysis tank 4 via the pump 3, and the wastewater in the wastewater storage tank 2 is sent to the electrolysis tank 4 by the pump 3 and purified there, and then the wastewater storage tank 2 Is circulated back to.

【0011】電解槽4内には、両端にステンレスまたは
カーボンからなる電極板5a、5bが配置され、両電極
板5a、5b間に多数のアルミ板6が配置されている。
そして、両電極板5a、5bおよびポンプ3は、直流電
源の太陽電池7に接続されている。なお、アルミ板6は
電源に接続されない。
Electrode plates 5a and 5b made of stainless steel or carbon are arranged at both ends in the electrolytic cell 4, and a large number of aluminum plates 6 are arranged between the electrode plates 5a and 5b.
The electrode plates 5a and 5b and the pump 3 are connected to the solar battery 7 of the DC power supply. The aluminum plate 6 is not connected to the power supply.

【0012】図2は、電極板5a、5bおよびアルミ板
6の支持構造を示し、電解槽4内には、絶縁材料からな
る一対の矩形状の支持フレーム8a、8bが固定され、
支持フレーム8a、8bに形成される溝9内に電極板5
a、5bおよびアルミ板6が挿入固定される。両電極板
5a、5bは、電解槽4の外壁に設けた電極端子10
a、10bに配線接続されている。
FIG. 2 shows a support structure for the electrode plates 5a, 5b and the aluminum plate 6, and a pair of rectangular support frames 8a, 8b made of an insulating material are fixed in the electrolytic cell 4.
The electrode plate 5 is provided in the groove 9 formed in the support frames 8a and 8b.
The a and 5b and the aluminum plate 6 are inserted and fixed. Both electrode plates 5a and 5b are electrode terminals 10 provided on the outer wall of the electrolytic cell 4.
Wired to a and 10b.

【0013】上記構成からなる本発明の作用について説
明する。廃水貯留槽2内の廃水は、ポンプ3により電解
槽4に送られ、ここで浄化された後、廃水貯留槽2内に
戻るように循環される。電解槽4内においては、電極板
5a、5bのみが正極、負極となるように直流電源に接
続され、それぞれのアルミ板6から電気分解によりアル
ミイオンを発生させ、これが水中の水酸イオンと結合し
て加水分解重合し、正電荷のポリマーイオンを発生さ
せ、廃水中のコロイド成分を凝集するようにしている。
所定期間毎に新規なアルミ板と交換する場合には、アル
ミ板6を支持フレーム8a、8bから取り外して新規な
アルミ板6と交換する。その際、アルミ板6には配線が
なされていないため、配線接続作業を不要とすることが
できる。
The operation of the present invention having the above structure will be described. The waste water in the waste water storage tank 2 is sent to the electrolysis tank 4 by the pump 3, purified there, and then circulated so as to return to the waste water storage tank 2. In the electrolytic cell 4, only the electrode plates 5a and 5b are connected to a DC power source so that they serve as a positive electrode and a negative electrode, and aluminum ions are generated by electrolysis from the respective aluminum plates 6, which combine with hydroxide ions in water. Then, it is hydrolyzed and polymerized to generate positively charged polymer ions, so that the colloid components in the waste water are aggregated.
When replacing with a new aluminum plate every predetermined period, the aluminum plate 6 is removed from the support frames 8a and 8b and replaced with a new aluminum plate 6. At this time, since the aluminum plate 6 is not wired, wiring work can be omitted.

【0014】また、個々のアルミ板6にはその枚数によ
って電源電圧の何分の一かの電圧しかかからないため、
水の抵抗で無駄に電力を消費することがない。
Since each aluminum plate 6 receives only a fraction of the power supply voltage depending on the number of aluminum plates 6,
Water resistance does not waste power.

【0015】[0015]

【発明の効果】以上の説明から明らかなように本発明に
よれば、廃水が循環される電解槽と、該電解槽内に設け
られる1対の電極板と、これら1対の電極板間に複数配
置されるアルミ板と、前記1対の電極板に接続される太
陽電池とを備える構成のため、アルミ板の交換時におけ
る電源との配線接続作業を不要とすることができる。ま
た、直流電源として太陽電池を用いるため、池、湖沼等
の水浄化において電源の保守、管理を容易にすることが
でき、さらに、アルミ板の枚数その他を最適に設計する
ことにより、太陽電池の出力を有効に利用できるため、
太陽電池の面積を小さくすることができる。
As is apparent from the above description, according to the present invention, an electrolytic cell in which waste water is circulated, a pair of electrode plates provided in the electrolytic cell, and between the pair of electrode plates. Due to the configuration including a plurality of arranged aluminum plates and solar cells connected to the pair of electrode plates, it is possible to eliminate the need for wiring connection work with the power source when replacing the aluminum plates. In addition, since a solar cell is used as a DC power source, maintenance and management of the power source can be facilitated in the purification of water in ponds, lakes and marshes. Furthermore, by optimizing the number of aluminum plates and other factors, Because the output can be used effectively,
The area of the solar cell can be reduced.

【図面の簡単な説明】[Brief description of drawings]

【図1】本発明の水処理装置の1実施例を示す構成図で
ある。
FIG. 1 is a configuration diagram showing an embodiment of a water treatment device of the present invention.

【図2】図1の電解槽を示し、図2(A)は電解槽の平
面図、図2(B)は図2(A)のB−B線に沿って矢印
方向に見た断面図である。
FIG. 2 shows the electrolytic cell of FIG. 1, FIG. 2 (A) is a plan view of the electrolytic cell, and FIG. 2 (B) is a sectional view taken along the line BB of FIG. Is.

【符号の説明】[Explanation of symbols]

1…供給管、2…池または廃水貯留槽、3…ポンプ、4
…電解槽 5a、5b…電極板、6…アルミ板、7…太陽電池 8a、8b…支持フレーム、9…溝、10a、10b…
電極端子
1 ... Supply pipe, 2 ... Pond or wastewater storage tank, 3 ... Pump, 4
Electrolyzer 5a, 5b ... Electrode plate, 6 ... Aluminum plate, 7 ... Solar cell 8a, 8b ... Support frame, 9 ... Groove, 10a, 10b ...
Electrode terminal

Claims (1)

【特許請求の範囲】[Claims] 【請求項1】廃水が循環される電解槽と、該電解槽内に
設けられる1対の電極板と、これら1対の電極板間に複
数配置されるアルミ板と、前記1対の電極板に接続され
る太陽電池とを備えることを特徴とする水浄化装置。
1. An electrolytic cell in which waste water is circulated, a pair of electrode plates provided in the electrolytic cell, a plurality of aluminum plates arranged between the pair of electrode plates, and the pair of electrode plates. And a solar cell connected to the water purification device.
JP34014592A 1992-12-21 1992-12-21 Water purification device Pending JPH06182345A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP34014592A JPH06182345A (en) 1992-12-21 1992-12-21 Water purification device

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP34014592A JPH06182345A (en) 1992-12-21 1992-12-21 Water purification device

Publications (1)

Publication Number Publication Date
JPH06182345A true JPH06182345A (en) 1994-07-05

Family

ID=18334161

Family Applications (1)

Application Number Title Priority Date Filing Date
JP34014592A Pending JPH06182345A (en) 1992-12-21 1992-12-21 Water purification device

Country Status (1)

Country Link
JP (1) JPH06182345A (en)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102583660A (en) * 2012-01-19 2012-07-18 华东理工大学 Electrolytic process for wastewater treatment by solar photovoltaic generation energy
US8834445B2 (en) 2006-01-20 2014-09-16 Oculus Innovative Sciences, Inc. Methods of treating or preventing peritonitis with oxidative reductive potential water solution
US8840873B2 (en) 2005-03-23 2014-09-23 Oculus Innovative Sciences, Inc. Method of treating second and third degree burns using oxidative reductive potential water solution
US9168318B2 (en) 2003-12-30 2015-10-27 Oculus Innovative Sciences, Inc. Oxidative reductive potential water solution and methods of using the same
CN106006860A (en) * 2016-07-22 2016-10-12 北京航空航天大学 High-salinity organic wastewater treatment device powered by solar energy
US9498548B2 (en) 2005-05-02 2016-11-22 Oculus Innovative Sciences, Inc. Method of using oxidative reductive potential water solution in dental applications
US10342825B2 (en) 2009-06-15 2019-07-09 Sonoma Pharmaceuticals, Inc. Solution containing hypochlorous acid and methods of using same

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9168318B2 (en) 2003-12-30 2015-10-27 Oculus Innovative Sciences, Inc. Oxidative reductive potential water solution and methods of using the same
US9642876B2 (en) 2003-12-30 2017-05-09 Sonoma Pharmaceuticals, Inc. Method of preventing or treating sinusitis with oxidative reductive potential water solution
US10016455B2 (en) 2003-12-30 2018-07-10 Sonoma Pharmaceuticals, Inc. Method of preventing or treating influenza with oxidative reductive potential water solution
US8840873B2 (en) 2005-03-23 2014-09-23 Oculus Innovative Sciences, Inc. Method of treating second and third degree burns using oxidative reductive potential water solution
US9498548B2 (en) 2005-05-02 2016-11-22 Oculus Innovative Sciences, Inc. Method of using oxidative reductive potential water solution in dental applications
US8834445B2 (en) 2006-01-20 2014-09-16 Oculus Innovative Sciences, Inc. Methods of treating or preventing peritonitis with oxidative reductive potential water solution
US9782434B2 (en) 2006-01-20 2017-10-10 Sonoma Pharmaceuticals, Inc. Methods of treating or preventing inflammation and hypersensitivity with oxidative reductive potential water solution
US10342825B2 (en) 2009-06-15 2019-07-09 Sonoma Pharmaceuticals, Inc. Solution containing hypochlorous acid and methods of using same
CN102583660A (en) * 2012-01-19 2012-07-18 华东理工大学 Electrolytic process for wastewater treatment by solar photovoltaic generation energy
CN106006860A (en) * 2016-07-22 2016-10-12 北京航空航天大学 High-salinity organic wastewater treatment device powered by solar energy

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