JPH06129579A - Flexible fitting - Google Patents

Flexible fitting

Info

Publication number
JPH06129579A
JPH06129579A JP4276035A JP27603592A JPH06129579A JP H06129579 A JPH06129579 A JP H06129579A JP 4276035 A JP4276035 A JP 4276035A JP 27603592 A JP27603592 A JP 27603592A JP H06129579 A JPH06129579 A JP H06129579A
Authority
JP
Japan
Prior art keywords
joint
elastic body
flexible joint
coating layer
peripheral surface
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP4276035A
Other languages
Japanese (ja)
Other versions
JP2854473B2 (en
Inventor
Osamu Kiso
木曽  治
Hirobumi Kakimoto
博文 柿本
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hayakawa Rubber Co Ltd
Original Assignee
Hayakawa Rubber Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hayakawa Rubber Co Ltd filed Critical Hayakawa Rubber Co Ltd
Priority to JP4276035A priority Critical patent/JP2854473B2/en
Publication of JPH06129579A publication Critical patent/JPH06129579A/en
Application granted granted Critical
Publication of JP2854473B2 publication Critical patent/JP2854473B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Abstract

PURPOSE:To provide an anti-corrosive flexible pipe fitting with which the sealing and flexibility can be held for a long time even though it serves being embedded underground by forming it from a resilient substance as a reaction object of a hardening agent and a main material containing liquid rubber which has a specific hardness and compressive elongativeness. CONSTITUTION:Longitudinally stretching, recesses and projections are formed alternately on the internal and external surfaces of a cylindrical body 2 of pipe fitting made of metal. This body 2 of fitting is deformable in the longitudinal direction and is covered with an anti-corrosive covering layer 4, which is in turn covered with an elastic subatance 5A. The substance 5A having a thickness over 5mm even in its thinnest part, consists of a reaction object of a hardening agent and a main material containing liquid rubber, and has a hardness between 5-60 by A-type hardness meter according to JIS-K-6301. Further, the flexible fitting can be compressed to a length below 70 when its original length is 100, and is capable of elongating to 130 or more.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は、気体、液体、粉体、粒
体を輸送する管体の継手部が存在する部分、即ち、空調
ダクト、ガス管、上下水道、蒸気配管、化学プラント配
管、製粉、充填剤製造工場の輸送配管等の接続を行うた
めの、可撓性継手に関するものである。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a portion in which a joint portion of a pipe for transporting gas, liquid, powder or granules is present, that is, an air-conditioning duct, a gas pipe, water and sewerage, a steam pipe, a chemical plant pipe. The present invention relates to a flexible joint for connecting transportation pipes and the like in a mill for milling and filling agents.

【0002】[0002]

【従来の技術】従来、管体同士を接続する継手の剛性の
高い場合は、管体の芯ずれ等により、管体をつなぐ作業
が困難である。また、管自体の伸縮や振動により、振動
が増幅されたり、継手部への応力増大による破損等が生
じていた。これに対し、ゴムやプラスチックで作られた
可撓性継手は、供用開始当初はその柔軟さ故に非常に管
体のシール効果が優れ、好結果である。しかし、これを
埋設した場合は、土圧や管の伸縮に伴う応力により経時
と共に高分子素材特有のクリープ現象や圧縮永久歪が生
じ、次第にシール機能が失われたり、ジョイント自体が
破損したりする事故が続発するようになった。一方、金
属製可撓継手は、防食や埋設時の土砂や小石による継手
の凹凸部の動きの拘束により可撓性が失われ、金属疲労
により継手部の損傷が生じる欠点があった。
2. Description of the Related Art Conventionally, when a joint for connecting pipes has a high rigidity, it is difficult to connect the pipes due to misalignment of the pipes. Further, due to expansion and contraction and vibration of the pipe itself, the vibration was amplified, and the joint part was damaged due to increased stress. On the other hand, the flexible joint made of rubber or plastic has a very excellent sealing effect on the pipe body due to its flexibility at the beginning of service, which is a good result. However, when it is buried, creeping phenomenon and compression set peculiar to polymer materials occur over time due to earth pressure and stress due to expansion and contraction of pipes, gradually losing the sealing function and damaging the joint itself. Accidents began to occur one after another. On the other hand, the flexible joint made of metal has a drawback in that its flexibility is lost due to corrosion and restraint of movement of the uneven portion of the joint due to earth and sand or small stones at the time of burying, and damage to the joint portion due to metal fatigue.

【0003】[0003]

【発明が解決しようとする課題】本発明の課題は、管体
のシール効果が優れ、地下に埋設してもシール機能が長
期に亘って失われず、耐食性が高く、可撓性を長期に亘
って保持できる可撓性継手を提供することである。
The object of the present invention is to provide an excellent sealing effect on the pipe body, even if it is buried underground, the sealing function is not lost for a long period of time, the corrosion resistance is high, and the flexibility is long-term. It is to provide a flexible joint that can be held.

【0004】[0004]

【課題を解決するための手段】本発明は、金属製の筒状
の継手本体であって、この継手本体の内周面及び外周面
において長手方向に凹部と凸部とが交互に形成されてお
り、長手方向に変形可能な継手本体;この継手本体の外
周面を被覆する防食被覆層;及びこの防食被覆層の外周
を覆う弾性体であって、最も薄い部分でも5mm以上の厚
さを有し、液状ゴムを含む主剤と硬化剤との反応物から
なり、JIS−K−6301に規定するA形硬度計で5以
上、60以下の硬度を有する弾性体を備えた可撓性継手で
あって、可撓性継手の元の長さを100 としたときに70以
下の長さにまで圧縮可能であり、可撓性継手の元の長さ
を100 としたときに130 以上の長さにまで伸張可能であ
る、可撓性継手に係るものである。
DISCLOSURE OF THE INVENTION The present invention is a tubular joint body made of metal, in which concave and convex portions are alternately formed in the longitudinal direction on the inner peripheral surface and the outer peripheral surface of the joint main body. A joint body that is deformable in the longitudinal direction; an anticorrosion coating layer that covers the outer peripheral surface of the joint body; and an elastic body that covers the outer periphery of the anticorrosion coating layer, with the thinnest portion having a thickness of 5 mm or more. However, the flexible joint is composed of a reaction product of a base material containing a liquid rubber and a curing agent, and has an elastic body having a hardness of 5 or more and 60 or less in an A-type hardness meter specified in JIS-K-6301. The original length of the flexible joint can be compressed to 70 or less, and the original length of the flexible joint can be compressed to 130 or more. A flexible joint that is extendable up to.

【0005】また、本発明は、金属製の筒状の継手本体
であって、この継手本体の内周面及び外周面において長
手方向に凹部と凸部とが交互に形成されており、長手方
向に変形可能な継手本体;この継手本体の外周面を被覆
する防食被覆層;この防食被覆層の外周を覆う、非加硫
ゴム組成物からなる弾性体;及びこの弾性体の外周を被
覆するシートを備えた可撓性継手であって、前記弾性体
及び前記シートが、最も薄い部分でも合計で5mm以上の
厚さを有し、前記可撓性継手の元の長さを100 としたと
きに70以下の長さにまで圧縮可能であり、可撓性継手の
元の長さを100 としたときに130 以上の長さにまで伸張
可能である、可撓性継手に係るものである。
Further, the present invention is a tubular joint body made of metal, wherein concave portions and convex portions are alternately formed in a longitudinal direction on an inner peripheral surface and an outer peripheral surface of the joint body. Joint body that can be deformed into: an anticorrosion coating layer that covers the outer peripheral surface of the joint body; an elastic body made of a non-vulcanized rubber composition that covers the outer circumference of the anticorrosion coating layer; and a sheet that covers the outer circumference of the elastic body A flexible joint comprising: the elastic body and the sheet having a total thickness of 5 mm or more even at the thinnest portion, and when the original length of the flexible joint is 100. The present invention relates to a flexible joint which can be compressed to a length of 70 or less and can be extended to a length of 130 or more when the original length of the flexible joint is 100.

【0006】[0006]

【作用】前記問題点を解決する手段として、本発明者等
は次の方法により解決した。継手本体は土圧等で変形し
にくい金属製とし、前後の管体とは熔接等の物理的固定
で完全に管体がシールできる構成とした。継手本体に要
求される可撓性は、これを蛇腹状とすることで、強度が
ありながら可撓性をも備えた構成とした。
The present inventors have solved the above problems by the following method. The joint body is made of metal that is not easily deformed by earth pressure, etc., and the pipe body is completely sealed by welding or other physical fixing to the front and rear pipe bodies. The flexibility required for the joint body is made bellows-shaped, so that the joint body has strength and flexibility.

【0007】また、金属製継手の欠点である腐食を防止
する目的で、一次防食被覆層を設けた。更に継手本体を
凹凸蛇腹状とした時の欠点である、凸部の間に形成され
る凹部への土砂、小石で閉塞され伸縮機能が損われるこ
とを防止する目的で、防食被覆層の外周を弾性体で覆っ
た。
Further, a primary anticorrosive coating layer is provided for the purpose of preventing corrosion which is a drawback of the metal joint. Furthermore, in order to prevent the expansion and contraction function from being impaired by clogging with earth and sand in the concave portion formed between the convex portions, which is a drawback when the joint body is made into an uneven bellows shape, the outer periphery of the anticorrosion coating layer is Covered with an elastic body.

【0008】この弾性体に要求される機能としては、上
記の他に次の機能がある。特に埋設時に於ては、土砂や
小石による基管に達する傷付を防止し、前後に接続され
た管体を伝幡してきた、ポンプの振動や、管体の伸縮、
地上の交通機関等による振動の絶縁をすることによっ
て、凹凸蛇腹状継手本体に与える疲労を減少させる。更
に、防水材を設けることにより長期にわたり水を遮断
し、製造条件上どうしても特に腐食されやすい凹凸蛇腹
状の継手本体を保護することにより、防食効果を高める
機能がある。上記手段により、従来見られなかった長期
安定性の優れた複合継手が得られることを確認し、本発
明を達成した。
The functions required of this elastic body include the following functions in addition to the above. Especially at the time of burying, it prevents damage to the base pipe due to earth and sand and pebbles and propagates the pipes connected to the front and back, vibration of the pump, expansion and contraction of the pipe,
By insulating the vibration from transportation facilities on the ground, the fatigue given to the corrugated joint body is reduced. Further, by providing a waterproof material, water is blocked for a long period of time, and by protecting the joint body having an uneven corrugated shape, which is particularly apt to be corroded under manufacturing conditions, it has a function of enhancing the anticorrosion effect. By the above means, it was confirmed that a composite joint excellent in long-term stability, which was not seen in the past, was obtained, and the present invention was achieved.

【0009】[0009]

【実施例】継手本体は、鉄、銅、アルミニウム、鉛等や
ステンレス、黄銅等の合金から成る金属製である。この
最大圧縮許容量が継手本体の元の長さを100 %としたと
き70%以下の長さまで圧縮でき、最大引張許容量が継手
本体の元の長さを100 %としたとき、130 %以上引張り
を行うことができるという条件を満足することが条件で
ある。つまり最大圧縮許容量が30%以下の場合や最大引
張許容量が30%以下の場合は、例えば地盤沈下等の極端
に大きな変位に追従できず、流出、噴出事故となるおそ
れがある。
EXAMPLES The joint body is made of metal such as iron, copper, aluminum, lead, etc., or alloy such as stainless steel, brass, etc. The maximum compression allowance is 70% or less when the original length of the joint body is 100%, and the maximum tensile allowance is 130% or more when the original length of the joint body is 100%. The condition is that the condition of being able to perform tension is satisfied. That is, when the maximum allowable compression amount is 30% or less or when the maximum tensile allowable amount is 30% or less, extremely large displacements such as ground subsidence cannot be followed, and there is a risk of an outflow or jet accident.

【0010】凹凸蛇腹状金属製継手本体及びその前後に
接続する管は、特に素材面の制約はないものの、コスト
面、防食面、その他特に上水等に於ては有害物質が溶出
しない点で、鉄、ステンレスが好ましい。又、継手本体
の内面をポリエチレン、ポリプロピレン、ポリブテン、
その他のポリマーでライニングして、防食、その他の目
的で使用するものであってもよい。
The concavo-convex bellows-shaped metal joint body and the pipes connected to the front and rear of the joint body are not particularly limited in terms of materials, but in terms of cost, anticorrosion, and especially in clean water, harmful substances are not eluted. , Iron and stainless steel are preferred. In addition, the inner surface of the joint body is polyethylene, polypropylene, polybutene,
It may be used for anticorrosion and other purposes by lining with other polymer.

【0011】又、コスト面、強度面、可撓性の面を考慮
して、凹凸蛇腹状金属製継手本体の部分に使用する板厚
は、その前後の管の板厚とは異なった厚みであって良
い。また、本発明でいう継手本体は、管の長手方向に凹
凸が交互にあって可撓性が発揮できるものであればよ
く、凹部、凸部が管の同一円周上に存在するものであっ
ても、螺旋状になって管の同一円周上に凹部及び凸部が
存在するものであってもよい。
Further, in consideration of cost, strength and flexibility, the plate thickness used for the portion of the concavo-convex bellows-shaped metal joint main body should be different from that of the pipes before and after it. Good to have Further, the joint body referred to in the present invention may be any one as long as it can exhibit flexibility by alternately providing irregularities in the longitudinal direction of the pipe, and the concave portion and the convex portion are present on the same circumference of the pipe. Alternatively, the tube may have a spiral shape, and the recess and the projection may be present on the same circumference of the tube.

【0012】次に防食被覆層について述べる。防食被覆
層は、上記の継手本体の防食を目的として設けるもので
あり、継手本体の最大圧縮変位時及び最大引張変位時に
継手本体に強固に接着し、外部の環境遮断能力の優れた
素材から成るものであればよい。その具体例を挙げる
と、エポキシ、ウレタン、不飽和ポリエステル等の熱硬
化性樹脂をベースとしたものと、ポリエチレン、ポリプ
ロピレン、ポリブテン等の熱可塑性のポリマーをベース
としたものとがあり、いずれも使用できる。又、継手本
体との接着をより強固に安定なものとする目的で、各種
接着助剤を併用することもできる。
Next, the anticorrosion coating layer will be described. The anticorrosion coating layer is provided for the purpose of anticorrosion of the joint body, and is made of a material that adheres firmly to the joint body at the time of maximum compression displacement and maximum tensile displacement of the joint body and has an excellent ability to shut off the external environment. Anything will do. Specific examples thereof include those based on thermosetting resins such as epoxy, urethane and unsaturated polyester, and those based on thermoplastic polymers such as polyethylene, polypropylene and polybutene, both of which are used. it can. Further, various adhesion aids can be used together for the purpose of making the adhesion to the joint body stronger and more stable.

【0013】次に、弾性体について述べる。継手本体は
凹凸部を有する故に、特に地中埋設で使用される場合に
は、土砂、小石等で凹部が覆われ、本来の期待される動
きができなくなり、特に圧縮に対しては、ほとんど可撓
性が発揮できなくなる。防食被覆層の外周を弾性体で覆
うことによって、継手本体に本来期待される動きが発揮
できるようになる。また、小石等による継手本体に達す
る損傷を防止できる。また、防食被覆層を保護すること
により、より長期的に安定な防食効果を発揮することが
できる。
Next, the elastic body will be described. Since the joint body has irregularities, especially when it is used for underground burial, the concave part is covered with earth and sand, pebbles, etc., and the expected movement cannot be achieved. Flexibility cannot be exhibited. By covering the outer periphery of the anticorrosion coating layer with the elastic body, the movement originally expected for the joint body can be exhibited. In addition, damage to the joint body due to pebbles or the like can be prevented. Further, by protecting the anticorrosion coating layer, it is possible to exert a stable anticorrosion effect for a longer period of time.

【0014】また、継手本体がそのまま地中に埋設され
ている場合には、この継手本体の幾つかの凹部や凸部の
うちの1つが局部的に地盤沈下等による応力を受ける
と、その部分に応力が集中する。本発明では、継手本体
の外周を弾性体で覆っているので、地盤沈下等による応
力や変位が、弾性体によって広範囲に分散される。
Further, when the joint body is directly buried in the ground, when one of several concave portions and convex portions of the joint body is locally subjected to stress due to ground subsidence, etc. Stress concentrates on. In the present invention, since the outer circumference of the joint body is covered with the elastic body, stress and displacement due to ground subsidence or the like are dispersed in a wide range by the elastic body.

【0015】弾性体が、液状ゴムを含む主剤と硬化剤と
の反応物からなる場合は、JIS−K−6301に規定され
るA形硬度計で5〜60の硬度とする必要がある。また、
このゴム弾性体は、一番薄い部分でも5mm以上の厚さを
有していなければならない。これが5mm未満の場合に
は、地中の小石等によって、継手本体にまで達する傷の
つくことが多く、この部分が腐食開始点となる。
When the elastic body is composed of a reaction product of a main agent containing a liquid rubber and a curing agent, it is necessary to have a hardness of 5 to 60 with an A type hardness meter specified in JIS-K-6301. Also,
This rubber elastic body must have a thickness of 5 mm or more even in the thinnest part. If it is less than 5 mm, it often causes scratches that reach the joint body due to pebbles in the ground, and this portion becomes the starting point of corrosion.

【0016】弾性体を非加硫ゴム組成物で形成した場合
には、非加硫ゴム組成物が地中に露出していると、クリ
ープや圧縮歪みが生じ易い。このため、弾性体の外周を
シートで被覆する。この場合、弾性体及びシートを、最
も薄い部分でも合計で5mm以上の厚さにする。
When the elastic body is formed of a non-vulcanized rubber composition, if the non-vulcanized rubber composition is exposed in the ground, creep or compressive strain is likely to occur. Therefore, the outer periphery of the elastic body is covered with the sheet. In this case, the elastic body and the sheet have a total thickness of 5 mm or more even in the thinnest part.

【0017】また、弾性体の材料としては、防食被覆層
と容易に剥離せず、この間から土砂、水が界面に入り込
まないこと、土中に長期間埋設しても変質しにくいこと
が要求される。
Further, the material of the elastic body is required not to be easily separated from the anticorrosion coating layer, to prevent soil and water from entering the interface between them, and to be hard to be deteriorated even if buried in the soil for a long time. It

【0018】弾性体を構成する非加硫ゴム組成物として
は、非加硫ゴム、粘着付与樹脂、充填剤、可塑剤等を混
合したものがある。この非加硫ゴムとしては、ポリイソ
ブチレン、再生ブチルゴム、ハロゲン化ブチルゴム、ブ
チルゴム、EPT、エチレンプロピレンゴム、イソプレ
ンゴム、BR、SBR、NBR、クロロプレンゴム、塩
素化ポリエチレン、クロルスルフォン化ポリエチレン、
アクリルゴム、エピクロルヒドリンゴム等を一種又は二
種以上用いることができる。この弾性体を被覆するシー
トは、非加硫ゴム、加硫ゴム、熱可塑性樹脂で形成する
ことができる。
As the non-vulcanized rubber composition constituting the elastic body, there is a mixture of non-vulcanized rubber, tackifying resin, filler, plasticizer and the like. Examples of the non-vulcanized rubber include polyisobutylene, recycled butyl rubber, halogenated butyl rubber, butyl rubber, EPT, ethylene propylene rubber, isoprene rubber, BR, SBR, NBR, chloroprene rubber, chlorinated polyethylene, and chlorosulfonated polyethylene.
Acrylic rubber, epichlorohydrin rubber, etc. may be used alone or in combination of two or more. The sheet covering the elastic body can be formed of non-vulcanized rubber, vulcanized rubber, or thermoplastic resin.

【0019】常温で液状のゴムの具体例としては、シリ
コン、多硫化ゴム、シリコン変性ウレタン、ウレタン、
主鎖骨格をブタジエン、ブタジエン−ニトリル、ブタジ
エン−スチレン、水素添加ブタジエン、イソプレン、ク
ロロプレンとした両末端に官能基を有するもの又は分子
内に二重結合を有するもの、アニリン誘導体、ポリオー
ル、ウレタンアクリルポリオール等を挙げることができ
る。これ等の官能基に応じて、硬化剤を選定する必要が
ある。液状ゴム側の官能基と硬化剤の官能基の組合せ例
を表1に示した。
Specific examples of the rubber which is liquid at room temperature include silicone, polysulfide rubber, silicone modified urethane, urethane,
The main chain skeleton is butadiene, butadiene-nitrile, butadiene-styrene, hydrogenated butadiene, isoprene, chloroprene, which has a functional group at both ends or has a double bond in the molecule, aniline derivative, polyol, urethane acrylic polyol Etc. can be mentioned. It is necessary to select a curing agent according to these functional groups. Table 1 shows examples of combinations of the functional groups on the liquid rubber side and the functional groups of the curing agent.

【0020】[0020]

【表1】 [Table 1]

【0021】上記の中でも、水酸基末端液状ゴムは、硬
化物のゴム弾性、耐水性、環境遮断性、耐久性に優れ、
主剤と硬化剤の混合性、使用可能時間のコントロールを
容易に行うことができ、常温での硬化反応性や貯蔵安定
性及び経済性に優れている。更に、主鎖骨格をブタジエ
ンやクロロプレン等にした場合は、アスファルト等の瀝
青物との相溶性に優れ、それに伴い、耐水性を初めとす
る環境遮断能力が一層向上し、かつ低コスト化にも有効
である。
Among the above, the hydroxyl group-terminated liquid rubber is excellent in rubber elasticity, water resistance, environmental barrier property and durability of the cured product,
It is possible to easily control the mixability of the main agent and the curing agent and the usable time, and it is excellent in curing reactivity at room temperature, storage stability and economical efficiency. Furthermore, when the main chain skeleton is butadiene or chloroprene, etc., it has excellent compatibility with bituminous substances such as asphalt, and along with it, the environmental barrier ability including water resistance is further improved, and cost reduction is also possible. It is valid.

【0022】上記理由から、例示した液状ゴムの中で
も、主鎖骨格中にエーテル結合やエステル結合を含まな
いものが、加水分解の原因をなくす意味に於て好適であ
る。又、1分子中に2個以上の水酸基を有する液状ゴム
と、イソシアネート基を1分子中に2個以上含む硬化剤
という条件は、液状ゴムとイソシアネートが反応して高
分子化したゴム弾性体を得るために必要な条件である。
From the above reasons, among the exemplified liquid rubbers, those not containing an ether bond or an ester bond in the main chain skeleton are preferable in terms of eliminating the cause of hydrolysis. Further, the condition of a liquid rubber having two or more hydroxyl groups in one molecule and a curing agent containing two or more isocyanate groups in one molecule is that a rubber elastic body polymerized by reaction between the liquid rubber and the isocyanate is used. It is a necessary condition to obtain.

【0023】次に硬化剤として一般に用いられるものと
しては、エポキシ化合物、イソシアネート化合物、アジ
リジン化合物、ポリアミン、過酸化物、金属酸化物等が
例示できる。本発明に於ては前記の通り、特にイソシア
ネート化合物を用いた例が好適である。その具体例とし
ては、トルイレンジイソシアネート、ジフェニルメタン
ジイソシアネート、ヘキサメチレンジイソシアネート、
イソホロンジイソシアネート、末端イソシアネート基を
有するプレポリマー及びそれらのブロック品を単独で若
しくは併用して使用する。尚、硬化剤はその配合比率や
粘度を考慮し、可塑剤と併用することもできるが、その
場合は可塑剤は脱水処理したものであることとイソシア
ネートと反応しないことが必要である。
Next, examples of commonly used curing agents include epoxy compounds, isocyanate compounds, aziridine compounds, polyamines, peroxides and metal oxides. In the present invention, as described above, an example using an isocyanate compound is particularly preferable. Specific examples thereof include toluylene diisocyanate, diphenylmethane diisocyanate, hexamethylene diisocyanate,
Isophorone diisocyanate, a prepolymer having a terminal isocyanate group, and block products thereof are used alone or in combination. The curing agent can be used in combination with the plasticizer in consideration of its compounding ratio and viscosity, but in that case, the plasticizer must be dehydrated and not react with isocyanate.

【0024】硬化剤の量を決定する上に於ては、反応モ
ル比で0.6 NCO/OHモル以上、2.0 NCO/OHモ
ル以下であることが必要である。0.6 NCO/OHモル
未満の場合には、非常に柔らかくなり硬度の条件を満足
できなくなったり、ゴム弾性体の系の中で未反応の水酸
基が多くなりすぎるために、耐水性が劣ったり、硬化不
良原因となったりするために好ましくない。逆に、2.0
NCO/OHモルを越える場合には、硬度が高くなりす
ぎたり、引張時に元の長さの130 %以上伸びなくなった
り、コスト面でもコスト高となったりする不具合が生
じ、好ましくない。
In determining the amount of the curing agent, it is necessary that the reaction molar ratio is 0.6 NCO / OH mol or more and 2.0 NCO / OH mol or less. If it is less than 0.6 NCO / OH mol, it becomes very soft and the hardness condition cannot be satisfied, and the unreacted hydroxyl group becomes too much in the rubber elastic system, resulting in poor water resistance and curing. It is not preferable because it may cause a defect. Conversely, 2.0
If it exceeds NCO / OH mol, the hardness becomes too high, 130% or more of the original length cannot be stretched at the time of pulling, and the cost becomes high, which is not preferable.

【0025】なお、イソシアネート基のモル数を水酸基
のモル数で除した反応モル比(NCO/OH)とは、水
酸基末端液状ジエン系ゴム中の水酸基の重量百分率で示
す水酸基含有率と、イソシアネート系硬化剤のイソシア
ネート含有率によって決まる値である。これは、下式に
よって算出される。
The reaction molar ratio (NCO / OH) obtained by dividing the number of moles of isocyanate groups by the number of moles of hydroxyl groups is the hydroxyl group content indicated by the weight percentage of hydroxyl groups in the hydroxyl group-terminated liquid diene rubber and the isocyanate group. It is a value determined by the isocyanate content of the curing agent. This is calculated by the following formula.

【0026】反応モル比(NCO/OH)={(水酸基
末端液状ジエン系ゴムの重量×水酸基含有率)/(イソ
シアネート系硬化剤の重量×イソシアネート基含有
率)}×(NCOの分子量)/(OHの分子量)。 ここで、(NCOの分子量)/(OHの分子量)=42/
17=2.47である。
Reaction molar ratio (NCO / OH) = {(weight of hydroxyl group-terminated liquid diene rubber × hydroxyl group content) / (weight of isocyanate curing agent × isocyanate group content)} × (molecular weight of NCO) / ( OH molecular weight). Here, (molecular weight of NCO) / (molecular weight of OH) = 42 /
17 = 2.47.

【0027】ここで主剤を構成する成分について若干説
明する。本発明でいう、常温で液状を呈するゴムを反応
して得られるゴム弾性体を達成する上に於ては、液状ゴ
ムとその硬化剤が必須成分とすれば、この必須成分のみ
で可能である。しかし、ゴム弾性体を形成する上での作
業性、経済性、ゴム弾性体にしてからの長期耐久性、硬
度、圧縮及び引張に対しての物性値等を考慮すると、瀝
青物、可塑剤は必須成分となる。更にゴム工業や塗料工
業等で一般に使用される充填剤、老化防止剤、触媒、粘
着付与樹脂、ワックス類、顔料、界面活性剤、カップリ
ング剤等は、用途や必要性能や機能を付与するために、
適宜使用すればよい。
Here, the components constituting the main agent will be briefly described. In the present invention, in achieving a rubber elastic body obtained by reacting a rubber that is liquid at room temperature, if liquid rubber and its curing agent are essential components, only this essential component is possible. . However, in consideration of workability in forming a rubber elastic body, economy, long-term durability after being made into a rubber elastic body, hardness, physical properties against compression and tension, etc., bituminous products and plasticizers are It becomes an essential ingredient. Further, fillers, antioxidants, catalysts, tackifying resins, waxes, pigments, surfactants, coupling agents and the like generally used in the rubber industry, coating industry and the like are used for imparting applications, necessary performances and functions. To
It may be used as appropriate.

【0028】又、弾性体と防食被覆層とをより確実にシ
ールするためには、防食被覆層の外周に非加硫ゴム粘弾
性体からなる防水材を弾性体の両端近傍に巻着した上
に、弾性体を形成させることが望ましい。
In order to more reliably seal the elastic body and the anticorrosion coating layer, a waterproof material made of non-vulcanized rubber viscoelastic body is wound around the outer periphery of the anticorrosion coating layer near both ends of the elastic body. First, it is desirable to form an elastic body.

【0029】弾性体が、液状ゴムを含む主剤と硬化剤と
の反応物からなる場合には、弾性体の硬度をJIS−K
−6301のA形で5〜60とする。これが5以下の場合は、
柔らかすぎて損傷を受けやすく、又、土砂、小石に押さ
れて伸縮挙動の障害となりやすいために不適当である。
逆に60以上の硬い場合には、圧縮に対しては大きな応力
でないと挙動しなくなり、振動等の変位の少ない挙動に
対する緩和がなくなるので不適当であり、引張時にはゴ
ム弾性体の破断等が生じやすくなり、不適当である。
When the elastic body is composed of a reaction product of a main agent containing liquid rubber and a curing agent, the hardness of the elastic body is JIS-K.
-6301 A type is 5-60. If this is 5 or less,
It is unsuitable because it is too soft and easily damaged, and it is easily pressed by earth and sand and pebbles to hinder the expansion and contraction behavior.
On the other hand, if it is harder than 60, it will not behave unless it is a large stress against compression, and it will be unsuitable because there will be no relaxation for behavior with little displacement such as vibration. It is easy and inappropriate.

【0030】弾性体の外周面に周方向に向って溝を設け
ると、可撓性継手の伸張に対して弾性体が一層追随し易
くなる。ただし、継手本体の隣り合う凸部間の距離に対
する溝の深さの比が40%を超えると、この溝に土、砂、
小石が詰まり易くなり、溝が閉塞する。このため、弾性
体の伸縮挙動がさまたげられ易くなり、弾性体が有効に
機能しにくくなるため、不適当である。
When the groove is provided on the outer peripheral surface of the elastic body in the circumferential direction, the elastic body can more easily follow the expansion of the flexible joint. However, if the ratio of the depth of the groove to the distance between the adjacent convex parts of the joint body exceeds 40%, soil, sand,
Pebbles are more likely to be clogged and the groove is blocked. For this reason, the expansion and contraction behavior of the elastic body tends to be obstructed, and the elastic body becomes difficult to function effectively, which is unsuitable.

【0031】図1、図2、図3は、いずれも本発明の実
施例に係る可撓性継手を示す断面図である。図1の例に
おいては、金属製の筒状の継手本体2の一方の端部2aに
管1Aが連結され、他方の端部2dに管1Bが連結されてい
る。この継手方向の内周面及び外周面において長手方向
に凹部と凸部とが交互に設けられており、継手本体2は
長手方向に伸縮可能である。外周面側からみると、リン
グ状の凸部2bと凹部2cとが、長手方向に向って交互に設
けられている。
1, 2, and 3 are sectional views showing a flexible joint according to an embodiment of the present invention. In the example of FIG. 1, the pipe 1A is connected to one end 2a of the metal tubular joint body 2 and the pipe 1B is connected to the other end 2d. The inner peripheral surface and the outer peripheral surface in the joint direction are provided with recesses and protrusions alternately in the longitudinal direction, and the joint body 2 is expandable and contractable in the longitudinal direction. When viewed from the outer peripheral surface side, ring-shaped convex portions 2b and concave portions 2c are provided alternately in the longitudinal direction.

【0032】継手本体2の外周面を被覆するように、防
食被覆層4が設けられている。更に、防食被覆層4の外
周を、弾性体5Aが覆っている。この弾性体5Aの外形は略
円筒形状であるが、端部5bにおいては徐々に直径が小さ
くなっている。本体5aの内側には、突起5cと溝5dとが交
互に設けられる。突起2bの部分が溝5dに挿入され、凹部
3の部分に突起5cが挿入される。防食被覆層4と弾性体
5Aとは隙間なく接合されている。
An anticorrosion coating layer 4 is provided so as to cover the outer peripheral surface of the joint body 2. Further, the elastic body 5A covers the outer periphery of the anticorrosion coating layer 4. The outer shape of the elastic body 5A is substantially cylindrical, but the diameter is gradually reduced at the end 5b. The protrusions 5c and the grooves 5d are alternately provided inside the main body 5a. The protrusion 2b is inserted into the groove 5d, and the recess 5c is inserted into the protrusion 5c. Anticorrosion coating layer 4 and elastic body
It is joined to 5A without any gap.

【0033】図2の例においては、弾性体5Bの本体5aの
外周面に、4個のリング形状の溝5eが等間隔に設けられ
ている。各溝5eの断面形状は、底の浅い台形状である。
各溝5eは、各凹部2cの位置に設けられている。また、端
部2aにおいて、防食被覆層4と端部5bとの界面に、リン
グ状の防水材6Aが設置されている。端部2dにおいて、防
食被覆層4と端部5bとの界面に、リング状の防水材6Bが
設けられている。図1、図2における弾性体5A,5Bは、
液状ゴムを含む主剤と硬化剤との反応物からなる。
In the example of FIG. 2, four ring-shaped grooves 5e are provided at equal intervals on the outer peripheral surface of the main body 5a of the elastic body 5B. Each groove 5e has a trapezoidal shape with a shallow bottom.
Each groove 5e is provided at the position of each recess 2c. A ring-shaped waterproof material 6A is provided at the interface between the anticorrosion coating layer 4 and the end 5b at the end 2a. At the end 2d, a ring-shaped waterproof material 6B is provided at the interface between the anticorrosion coating layer 4 and the end 5b. The elastic bodies 5A and 5B in FIGS. 1 and 2 are
It consists of a reaction product of a main agent containing liquid rubber and a curing agent.

【0034】図3に示す可撓性継手においては、弾性体
15が非加硫ゴム組成物からなる。弾性体15の本体15a の
外形は略円柱状であり、本体15a の両端に、端に行くに
従って直径の徐々に小さくなる端部15b が設けられてい
る。本体15a の内側に、突起15c と溝15d とが交互に設
けられている。弾性体15の外側面が、シート7によって
被覆されている。
In the flexible joint shown in FIG. 3, an elastic body is used.
15 consists of a non-vulcanized rubber composition. The main body 15a of the elastic body 15 has a substantially cylindrical outer shape, and both ends of the main body 15a are provided with ends 15b whose diameter gradually decreases toward the ends. Protrusions 15c and grooves 15d are alternately provided inside the main body 15a. The outer surface of the elastic body 15 is covered with the sheet 7.

【0035】次に、可撓性継手の製造方法について、図
1、図3のものを例にとって述べる。 図1:継手本体2に防食被覆層4を形成する。次いで型
枠を組み、防食被覆層4と型枠との間に形成された空間
に、主剤と硬化剤との混合物を充填する。次いで、架橋
反応を進行させ、可撓性継手を脱型する。上記混合物を
作製するには、液状ゴムや瀝青物、可塑剤その他の充填
剤や老化防止剤等を混和し、インクロールを2回通過さ
せて主剤成分とし、硬化剤と混合する。
Next, a method for manufacturing the flexible joint will be described with reference to FIGS. 1 and 3 as an example. FIG. 1: The anticorrosion coating layer 4 is formed on the joint body 2. Next, the mold is assembled, and the space formed between the anticorrosion coating layer 4 and the mold is filled with a mixture of the main agent and the curing agent. Next, a crosslinking reaction is allowed to proceed and the flexible joint is demolded. To prepare the above mixture, liquid rubber, bitumen, a plasticizer and other fillers, an anti-aging agent and the like are mixed, passed through an ink roll twice to form a main component, and mixed with a curing agent.

【0036】図3:ブチルゴム、再生ブチルゴム、ポリ
イソブチレン、ハロゲン化ブチルゴム、アクリルゴム、
エピクロルヒドリンゴム等を一種又は併用して、例えば
加圧ニーダー等で粘着付与樹脂、充填剤、可塑剤等と混
練し、防食被覆層4と粘着、接着する非加硫ゴム組成物
を、押出機又はプレス機で成形して得る。その後、防食
被覆層4の上から、前記方法で得た成形体ゴムを、空気
が入らないように圧着して接着し、その上からシート7
を貼付け、弾性体15とすることができる。図4は、この
成形体15A を示す斜視図である。
FIG. 3: Butyl rubber, recycled butyl rubber, polyisobutylene, halogenated butyl rubber, acrylic rubber,
One kind or a combination of epichlorohydrin rubber and the like, for example, a non-vulcanized rubber composition that is kneaded with a tackifier resin, a filler, a plasticizer, etc. by a pressure kneader or the like and adheres and adheres to the anticorrosion coating layer 4 using an extruder or Obtained by molding with a press. Then, the molded rubber obtained by the above method is pressure-bonded onto the anticorrosion coating layer 4 so as not to let air in, and the sheet 7 is placed thereon.
Can be attached to form the elastic body 15. FIG. 4 is a perspective view showing the molded body 15A.

【0037】次に、実験結果について述べる。 (試料の作製)図1〜図3に示す継手本体2を製造し
た。ただし、継手本体2の内径を100 mmとし、凸部2bの
数を5つとし、隣り合う凸部の頂点間の距離を30mmと
し、凹部2cの深さを25mmとした。この継手本体2の両端
に、直管1A,1Bをそれぞれ熔接し、全長を310 mmとし
た。この外周面に、厚さ2mmのポリエチレンライニング
4を設けた。
Next, experimental results will be described. (Preparation of Sample) The joint body 2 shown in FIGS. 1 to 3 was manufactured. However, the inner diameter of the joint body 2 was 100 mm, the number of the convex portions 2b was 5, the distance between the vertices of the adjacent convex portions was 30 mm, and the depth of the concave portion 2c was 25 mm. Straight pipes 1A and 1B were welded to both ends of the joint body 2 to have a total length of 310 mm. A polyethylene lining 4 having a thickness of 2 mm was provided on this outer peripheral surface.

【0038】図4に示す成形体15A を、再生ブチルゴム
系の非加硫ゴム組成物で作製した。この成形体15A を上
記の継手本体2の上に、気泡が入らないように圧着しな
がら貼り付けた。この弾性体15の外周に、厚さ2mmの糊
付き加硫ブチルゴムシート7を貼り付け、図3に示す構
造体を得た。凸部2bの頂点部分における弾性体15の厚さ
(最も薄い部分の厚さ)が1mmのものを比較例1とし、
3mmのものを実施例1とし、13mmのものを実施例2とし
た。
A molded body 15A shown in FIG. 4 was produced from a regenerated butyl rubber-based non-vulcanized rubber composition. This molded body 15A was attached onto the above-mentioned joint body 2 while being pressure-bonded so that air bubbles would not enter. A vulcanized butyl rubber sheet 7 with a thickness of 2 mm was attached to the outer periphery of the elastic body 15 to obtain the structure shown in FIG. A comparative example 1 has a thickness (thickness of the thinnest portion) of the elastic body 15 at the apex of the convex portion 2b of 1 mm,
The one having a thickness of 3 mm was used as Example 1 and the one having a thickness of 13 mm was used as Example 2.

【0039】また、液状ポリブタジエン系の液状物とイ
ソシアネート系硬化剤とを混合した。上記の継手本体1
に型枠を取り付け、上記混合物を型枠内の空洞部分に充
填し、これを硬化させ、図1又は図2に示す可撓性継手
を製造した。
Further, a liquid polybutadiene liquid and an isocyanate curing agent were mixed. The above fitting body 1
The mold was attached to, and the above mixture was filled in the cavity in the mold, and this was cured to manufacture the flexible joint shown in FIG. 1 or 2.

【0040】イソシアネート基と水酸基との反応モル比
は、表2に示すように変更した。表2に示す例のうち、
実施例3,4、比較例2は、図1に示す構造体であり、
凸部2bの頂点における弾性体5Aの肉厚(最も薄い部分の
肉厚)を、3,5又は20mmとした。実施例5,6、比較
例3,4は、図2に示す構造体であり、凸部2bの頂点間
の距離に対する溝5eの深さの比率を30%又は50%とし
た。比較例5は、弾性体を全く設けなかった例である。
The reaction molar ratio between the isocyanate group and the hydroxyl group was changed as shown in Table 2. Of the examples shown in Table 2,
Examples 3, 4 and Comparative Example 2 are the structures shown in FIG.
The thickness of the elastic body 5A (the thickness of the thinnest portion) at the apex of the convex portion 2b was set to 3, 5 or 20 mm. The structures of Examples 5 and 6 and Comparative Examples 3 and 4 are the structures shown in FIG. 2, and the ratio of the depth of the groove 5e to the distance between the vertices of the protrusions 2b is 30% or 50%. Comparative Example 5 is an example in which no elastic body is provided.

【0041】各例の可撓性継手について、次の試験を行
った。 (圧縮試験)各供試体を圧縮し、元の長さの50%の長さ
とし、剥離、ゴム層の破断等異常発生の有無及び異常発
生時の元の長さからの比率を求めた。これを、「最大圧
縮変形量」として、表2に示した。
The following tests were conducted on the flexible joints of the respective examples. (Compression test) Each specimen was compressed to have a length of 50% of the original length, and the presence or absence of abnormalities such as peeling and rupture of the rubber layer, and the ratio from the original length when abnormalities occurred were obtained. This is shown in Table 2 as "maximum compression deformation amount".

【0042】(引張試験)各試験体を引張り、元の長さ
を100 %としたとき元の長さの150 %となるように引張
り、剥離、ゴム層の破断等の異常の有無を調査した。ま
た、異常発生時の元の長さからの比率を求めた。これ
を、「最大引張変形量」として、表2に示した。
(Tensile Test) Each test piece was pulled so as to be 150% of the original length when the original length was 100%, and the presence or absence of abnormalities such as peeling and breakage of the rubber layer was investigated. . Moreover, the ratio from the original length at the time of occurrence of abnormality was obtained. This is shown in Table 2 as "maximum tensile deformation amount".

【0043】(塩水噴霧試験)各供試体について、それ
ぞれ弾性体にステンレス板に達するクロスカットを入
れ、塩水を1000時間噴霧した。そして、目視により、異
常の有無を判定した。発錆等の異常が発生した場合は
「×」とし、異常がない場合は「○」とした。
(Salt Water Spray Test) For each test piece, a cross cut reaching the stainless steel plate was put in each elastic body, and salt water was sprayed for 1000 hours. Then, the presence or absence of abnormality was visually determined. When an abnormality such as rusting occurred, it was marked with "x", and when there was no abnormality, it was marked with "○".

【0044】(伸縮障害)各例の構造体を箱の中に入
れ、各直管1A,1Bを箱から出した。箱の中に砂を充填
し、元の長さの50%の長さにまで圧縮した。試験後、箱
から可撓性継手をとり出した。溝5e又は3へ砂がくいこ
み伸縮の障害となったものを伸縮障害「有」とし、障害
を受けなかったものを「無」とした。
(Stretching Disorder) The structure of each example was put in a box, and the straight pipes 1A and 1B were taken out of the box. The box was filled with sand and compressed to 50% of its original length. After the test, the flexible joint was taken out from the box. The sand that entered the groove 5e or 3 and interfered with the expansion and contraction was defined as "existence", and the one that was not damaged was defined as "absence".

【0045】(耐久性試験)実施例1,2、比較例1で
用いた再生ブチルゴム系加硫ゴム組成物を2mm厚シート
に成形した。次いで実施例3,4、比較例2で用いた液
状ポリブタジエン系液状物とイソシアネート硬化剤とか
ら2mm厚シートを作製し、7日間室温養生、7日間50℃
養生を行った。何れのシートもJIS−K−6301の1号
ダンベル片に打抜いた。各々80℃×90%RHにて1カ
月、60℃水中にて3カ月、60℃気中にて3カ月又はウエ
ザー1000時間処理した。この後で常温での引張応力、伸
び率、硬度をn=4で測定した。各々元の物性の保持率
が70%以上あるか否かで判定し、保持率70%以上を
「○」,70%未満を「×」とした。
(Durability Test) The regenerated butyl rubber vulcanized rubber compositions used in Examples 1 and 2 and Comparative Example 1 were molded into a 2 mm thick sheet. Then, a 2 mm thick sheet was prepared from the liquid polybutadiene liquid used in Examples 3 and 4 and Comparative Example 2 and an isocyanate curing agent, and was cured at room temperature for 7 days and at 50 ° C. for 7 days.
I got a cure. Both sheets were punched out into JIS-K-6301 No. 1 dumbbell pieces. Each of them was treated at 80 ° C. × 90% RH for 1 month, 60 ° C. in water for 3 months, 60 ° C. in air for 3 months, or weathered for 1000 hours. After that, tensile stress, elongation and hardness at room temperature were measured at n = 4. Judgment was made based on whether or not the retention rate of the original physical properties was 70% or more, and the retention rate of 70% or more was designated as "○", and the retention rate of less than 70% was designated as "x".

【0046】(1000回伸縮試験)各例の可撓性継手につ
いて、元の長さの50%にまで圧縮することと、150 %の
長さにまで伸張させることとを1000回繰り返した。この
結果、異常がなかった場合「○」と表示した。
(Flexibility Test for 1000 Times) With respect to the flexible joint of each example, compression to 50% of the original length and extension to 150% of the length were repeated 1000 times. As a result, when there was no abnormality, "○" was displayed.

【0047】(振動減衰効果)各例の可撓性継手の両端
から10mmの所を吊し、一方の端面から30mmの所にピック
アップを取り付け、この一方の端部を加振した。振動応
答の各ピーク値の1/10に減衰するまでの時間を計測し
た。
(Vibration damping effect) The flexible joint of each example was hung at a position 10 mm from both ends, a pickup was attached at a position 30 mm from one end face, and the one end was vibrated. The time until it attenuated to 1/10 of each peak value of the vibration response was measured.

【0048】(騒音防止効果)各例の可撓性継手の一端
にフランジを取り付けた。また、工場内のゴム粉末空気
輸送管の一部にフランジを取り付け、このフランジを可
撓性継手のフランジにボルトで固定した。そして、ゴム
粉末の空気輸送音を測定した。
(Noise prevention effect) A flange was attached to one end of the flexible joint of each example. Further, a flange was attached to a part of the rubber powder pneumatic transportation pipe in the factory, and this flange was fixed to the flange of the flexible joint with a bolt. Then, the air transport sound of the rubber powder was measured.

【0049】[0049]

【表2】 [Table 2]

【0050】[0050]

【表3】 [Table 3]

【0051】ここで、上記の実験における各弾性体の配
合を示す。まず、弾性体15を構成する非加硫ゴム組成物
の配合を示す。
Here, the composition of each elastic body in the above experiment will be shown. First, the composition of the non-vulcanized rubber composition forming the elastic body 15 will be described.

【0052】[0052]

【表4】 [Table 4]

【0053】次いで、加硫ゴムシート7の配合を示す。Next, the composition of the vulcanized rubber sheet 7 will be shown.

【0054】[0054]

【表5】 [Table 5]

【0055】次いで、液状ゴムを含む主剤の配合を、下
に示す。
Next, the composition of the main component containing the liquid rubber is shown below.

【0056】[0056]

【表6】 [Table 6]

【0057】イソシアネート系硬化剤としては、日本ポ
リウレタン株式会社の「ミリオネートMTL」を用い
た。
As the isocyanate curing agent, "Millionate MTL" manufactured by Nippon Polyurethane Industry Co., Ltd. was used.

【0058】実施例及び比較例で示したとおり、防食被
覆層に対して一番薄い部分のゴム弾性体の肉厚は5mm以
上が必要であり、5mm未満の場合は比較例1,2で示す
ように塩水噴霧性が悪くなる。つまり小石等による傷付
きを受け易く、その傷の部分から発錆が生じる危険性が
高いことを示すものである。従って、5mm以上であれば
傷も付きにくく、傷を受けたとしても容易に発錆しない
ために長期にわたって使用することができる。
As shown in Examples and Comparative Examples, the thinnest portion of the rubber elastic body with respect to the anticorrosion coating layer needs to have a wall thickness of 5 mm or more. As described above, the salt sprayability deteriorates. In other words, this indicates that it is easily damaged by pebbles and the like, and there is a high risk of rusting from the scratched portion. Therefore, if it is 5 mm or more, it is difficult to be scratched, and even if it is scratched, it does not easily rust and can be used for a long time.

【0059】最大圧縮変形量は50%の圧縮に対しても実
施例では何れも異常が生じておらず、比較例4で異常が
生じた。又、最大引張変形量は150 %引張に対しても実
施例では何れも異常は発生しなかった。比較例4では12
0 %引張時に異常が発生した。これは、反応モル比が2.
0 モルを越え、硬度も63と高く本発明の範囲外になった
ためである。反応モル比は実施例5,6に示す如く0.6
NCO/OHモル〜2.0 NCO/OHモルの範囲では異
常なく、これは硬度も5〜60の範囲に入っている。又、
凸部頂点間長さに対する溝の深さの比も40%以下とな
り、伸縮障害も発生していない。
Even when the maximum compression deformation amount was 50%, no abnormality occurred in any of the Examples, and an abnormality occurred in Comparative Example 4. In addition, no abnormality occurred in any of the examples even when the maximum tensile deformation amount was 150%. 12 in Comparative Example 4
Abnormality occurred at 0% tension. This has a reaction molar ratio of 2.
This is because it exceeds 0 mol and the hardness is as high as 63, which is outside the range of the present invention. The reaction molar ratio was 0.6 as shown in Examples 5 and 6.
There is no abnormality in the range of NCO / OH mol to 2.0 NCO / OH mol, and the hardness is in the range of 5 to 60. or,
The ratio of the depth of the groove to the length between the vertices of the convex portions was 40% or less, and no expansion / contraction failure occurred.

【0060】一方比較例3に示すように0.6 NCO/O
Hモル以下のときは硬度も低すぎて測定できず、伸縮障
害も受けている。又、ウエザーを始め80℃,90%RH×
1カ月,60℃温水×3カ月でも悪い結果となった。又、
伸縮障害は、柔らかいために受けるだけでなく、凸部間
の長さに対する溝の深さの比率が大きく影響し、比較例
4でも示す通り、硬度の大きい場合でも伸縮障害を受け
ている。
On the other hand, as shown in Comparative Example 3, 0.6 NCO / O
When the amount is less than H mol, the hardness is too low to be measured and the stretch failure occurs. Also, including the weather, 80 ℃, 90% RH ×
One month, 60 ℃ warm water × 3 months also gave bad results. or,
The expansion / contraction failure is not only caused by the softness, but also the ratio of the groove depth to the length between the convex portions has a great influence, and as shown in Comparative Example 4, the expansion / contraction failure is caused even when the hardness is high.

【0061】[0061]

【発明の効果】以上に述べたように、本発明により、耐
久性に優れる金属製可撓性継手本体により充分な強度を
得、継手本体の腐食や損傷を一次防食被覆層及び充分な
肉厚を有する弾性体によって防止し、防食をより確実に
した。しかも、弾性体により継手本体の凹部をシールし
たために、土中埋設時には土砂等により伸縮を阻害され
ないという特徴も生じ、長期にわたり安定な伸縮継手と
しての機能を有すると共に、万一の地盤沈下に対しても
非常に安全である。又、弾性体により継手本体の凹凸部
を拘束しているために、ポンプからの振動、管体の伸
縮、地上の交通機関からの振動も吸収し、可撓性継手の
耐久性向上に役立つ。又、管内を粉体や粒体を通す場合
には、可撓継手部に衝突する音が著しく低減され、工場
騒音の防止にも有効である。
As described above, according to the present invention, a metal flexible joint body having excellent durability is provided with sufficient strength to prevent corrosion and damage of the joint body as a primary anticorrosion coating layer and a sufficient thickness. It was prevented by an elastic body having a to make the corrosion prevention more reliable. Moreover, since the recess of the joint body is sealed by the elastic body, there is a feature that expansion and contraction is not obstructed by earth and sand etc. when buried in the soil, and it has a function as a stable expansion joint for a long period of time, and in case of ground subsidence But it's very safe. Further, since the concavo-convex portion of the joint body is restrained by the elastic body, vibrations from the pump, expansion and contraction of the pipe body, and vibrations from transportation facilities on the ground are also absorbed, which is useful for improving the durability of the flexible joint. In addition, when powder or granules are passed through the pipe, the sound colliding with the flexible joint is significantly reduced, which is also effective in preventing factory noise.

【0062】以上の如く、本発明の可撓性継手を、気
体、液体、粉体、粒体を輸送する管の継手部に使うこと
により、地盤沈下時の安全性のレベルアップ、埋設時の
可撓性確保、防食性の確保、振動減衰効果の高さ、騒音
低下等の機能を付与できるメリットがある。
As described above, by using the flexible joint of the present invention in the joint portion of a pipe for transporting gas, liquid, powder, and granules, the safety level at the time of subsidence of the ground is improved, and at the time of burial. There are merits that functions such as ensuring flexibility, ensuring anticorrosion, high vibration damping effect, and noise reduction can be added.

【図面の簡単な説明】[Brief description of drawings]

【図1】本発明の実施例に係る可撓性継手を長手方向に
切ってみた断面図である。
FIG. 1 is a cross-sectional view of a flexible joint according to an embodiment of the present invention, taken along a longitudinal direction.

【図2】可撓性継手を長手方向に切ってみた断面図であ
る。
FIG. 2 is a cross-sectional view of a flexible joint taken along the longitudinal direction.

【図3】可撓性継手を長手方向に切ってみた断面図であ
る。
FIG. 3 is a cross-sectional view of a flexible joint taken along the longitudinal direction.

【図4】成形体15A を示す破断斜視図である。FIG. 4 is a cutaway perspective view showing a molded body 15A.

【符号の説明】[Explanation of symbols]

1A,1B 直管 2 継手本体 2a,2d 端部 2b 凸部 2c 凹部 4 防食被覆層 5A,5B 主剤と硬化剤との反応物からなる弾性体 5e 溝 6A,6B 防水材 7 シート 15 非加硫ゴム組成物からなる弾性体 1A, 1B Straight pipe 2 Joint body 2a, 2d End part 2b Convex part 2c Concave part 4 Anticorrosion coating layer 5A, 5B Elastic body composed of reaction product of base compound and curing agent 5e Groove 6A, 6B Waterproof material 7 Sheet 15 Unvulcanized Elastic body made of rubber composition

Claims (6)

【特許請求の範囲】[Claims] 【請求項1】 金属製の筒状の継手本体であって、この
継手本体の内周面及び外周面において長手方向に凹部と
凸部とが交互に形成されており、長手方向に変形可能な
継手本体;この継手本体の外周面を被覆する防食被覆
層;及びこの防食被覆層の外周を覆う弾性体であって、
最も薄い部分でも5mm以上の厚さを有し、液状ゴムを含
む主剤と硬化剤との反応物からなり、JIS−K−6301
に規定するA形硬度計で5以上、60以下の硬度を有する
弾性体を備えた可撓性継手であって、 可撓性継手の元の長さを100 としたときに70以下の長さ
にまで圧縮可能であり、可撓性継手の元の長さを100 と
したときに130 以上の長さにまで伸張可能である、可撓
性継手。
1. A tubular joint body made of metal, wherein concave portions and convex portions are alternately formed in the longitudinal direction on the inner peripheral surface and the outer peripheral surface of the joint body, and the joint body is deformable in the longitudinal direction. A joint body; an anticorrosion coating layer that covers the outer peripheral surface of the joint body; and an elastic body that covers the outer periphery of the anticorrosion coating layer,
Even the thinnest part has a thickness of 5 mm or more, and consists of a reaction product of a main agent containing liquid rubber and a curing agent. JIS-K-6301
A flexible joint provided with an elastic body having a hardness of 5 or more and 60 or less according to the A-type hardness meter specified in 1., and a length of 70 or less when the original length of the flexible joint is 100. A flexible joint that is compressible up to and can be stretched to a length of 130 or more, given the original length of the flexible joint as 100.
【請求項2】 前記主剤が、瀝青物、水酸基を1分子当
り2個以上有する液状ゴム及び可塑剤を必須構成成分と
しており、前記硬化剤が、1分子当り2個以上のイソシ
アネート基を有する硬化剤であり、イソシアネート基の
モル数を水酸基のモル数で除した反応モル比(NCO/
OH)が0.6 以上、2.0 以下である、請求項1記載の可
撓性継手。
2. A curing agent having a bituminous substance, a liquid rubber having 2 or more hydroxyl groups per molecule and a plasticizer as essential constituents, and a curing agent having 2 or more isocyanate groups per molecule. The reaction molar ratio (NCO /
The flexible joint according to claim 1, wherein OH) is 0.6 or more and 2.0 or less.
【請求項3】 前記弾性体の外周面に周方向に向って溝
が設けられ、前記継手本体の隣り合う凸部間の距離に対
する前記溝の深さの比が40%以内である、請求項1記載
の可撓性継手。
3. A groove is provided on an outer peripheral surface of the elastic body in a circumferential direction, and a ratio of a depth of the groove to a distance between adjacent convex portions of the joint body is within 40%. The flexible joint according to 1.
【請求項4】 前記弾性体の長さ方向の端部近傍におい
て、前記防食被覆層と前記弾性体との界面に、非加硫ゴ
ム系粘弾性体からなる防水材が設けられている、請求項
1の可撓性継手。
4. A waterproof material made of a non-vulcanized rubber viscoelastic body is provided at an interface between the anticorrosion coating layer and the elastic body in the vicinity of an end portion in the longitudinal direction of the elastic body. Item 1. A flexible joint according to item 1.
【請求項5】 金属製の筒状の継手本体であって、この
継手本体の内周面及び外周面において長手方向に凹部と
凸部とが交互に形成されており、長手方向に変形可能な
継手本体;この継手本体の外周面を被覆する防食被覆
層;この防食被覆層の外周を覆う、非加硫ゴム組成物か
らなる弾性体;及びこの弾性体の外周を被覆するシート
を備えた可撓性継手であって、 前記弾性体及び前記シートが、最も薄い部分でも合計で
5mm以上の厚さを有し、前記可撓性継手の元の長さを10
0 としたときに70以下の長さにまで圧縮可能であり、可
撓性継手の元の長さを100 としたときに130 以上の長さ
にまで伸張可能である、可撓性継手。
5. A tubular joint body made of metal, wherein concave portions and convex portions are alternately formed in a longitudinal direction on an inner peripheral surface and an outer peripheral surface of the joint body, and the joint body is deformable in the longitudinal direction. A joint body; an anticorrosion coating layer that covers the outer peripheral surface of the joint body; an elastic body made of a non-vulcanized rubber composition that covers the outer periphery of the anticorrosion coating layer; and a sheet that covers the outer periphery of the elastic body. A flexible joint, wherein the elastic body and the sheet have a total thickness of 5 mm or more even in the thinnest portion, and the original length of the flexible joint is 10 mm.
A flexible joint that is compressible to a length of 70 or less when 0 and stretched to 130 or more when the original length of the flexible joint is 100.
【請求項6】 前記弾性体の長さ方向の端部近傍におい
て、前記防食被覆層と前記弾性体との界面に、非加硫ゴ
ム系粘弾性体からなる防水材が設けられている、請求項
5記載の可撓性継手。
6. A waterproof material made of a non-vulcanized rubber viscoelastic body is provided at an interface between the anticorrosion coating layer and the elastic body in the vicinity of an end portion in the longitudinal direction of the elastic body. Item 5. The flexible joint according to Item 5.
JP4276035A 1992-10-14 1992-10-14 Flexible joint structure Expired - Fee Related JP2854473B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP4276035A JP2854473B2 (en) 1992-10-14 1992-10-14 Flexible joint structure

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP4276035A JP2854473B2 (en) 1992-10-14 1992-10-14 Flexible joint structure

Publications (2)

Publication Number Publication Date
JPH06129579A true JPH06129579A (en) 1994-05-10
JP2854473B2 JP2854473B2 (en) 1999-02-03

Family

ID=17563879

Family Applications (1)

Application Number Title Priority Date Filing Date
JP4276035A Expired - Fee Related JP2854473B2 (en) 1992-10-14 1992-10-14 Flexible joint structure

Country Status (1)

Country Link
JP (1) JP2854473B2 (en)

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS4718811U (en) * 1971-04-02 1972-11-02
JPS62264932A (en) * 1986-05-13 1987-11-17 Hayakawa Rubber Co Ltd Manufacture of binding type vibration damping tubular material

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS4718811U (en) * 1971-04-02 1972-11-02
JPS62264932A (en) * 1986-05-13 1987-11-17 Hayakawa Rubber Co Ltd Manufacture of binding type vibration damping tubular material

Also Published As

Publication number Publication date
JP2854473B2 (en) 1999-02-03

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