JPH0596675A - Sandwiched board - Google Patents

Sandwiched board

Info

Publication number
JPH0596675A
JPH0596675A JP29244091A JP29244091A JPH0596675A JP H0596675 A JPH0596675 A JP H0596675A JP 29244091 A JP29244091 A JP 29244091A JP 29244091 A JP29244091 A JP 29244091A JP H0596675 A JPH0596675 A JP H0596675A
Authority
JP
Japan
Prior art keywords
core material
adhesive
fire resistance
adhesive agent
separation layer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP29244091A
Other languages
Japanese (ja)
Inventor
Sue Koseki
寿衛 小関
Hideki Takiguchi
英喜 滝口
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IG Technical Research Inc
Original Assignee
IG Technical Research Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by IG Technical Research Inc filed Critical IG Technical Research Inc
Priority to JP29244091A priority Critical patent/JPH0596675A/en
Publication of JPH0596675A publication Critical patent/JPH0596675A/en
Pending legal-status Critical Current

Links

Landscapes

  • Building Environments (AREA)
  • Laminated Bodies (AREA)

Abstract

PURPOSE:To obtain inexpensively a light sandwiched bard having long-sized sandwich panel structure where fire resistance, sound insulating properties and vibration-damping properties are improved drastically. CONSTITUTION:A core material 6 having specific structure is stuck inbetween an incombustible base 1 and a clad steel sheet 2 through an adhesive agent, made into a composite board, the core material 6 is formed of a fire-resistant resol type phenolic foam 8 and inorganic light aggregate 7, and the incombustible base 1 and core material 6 are integrated with the adhesive agent by making use of heat-resistant nonwoven fabric having various functions for a separation layer 9. Then since the same becomes structure where a resin component and adhesive agent component forming the subject of the core material 6 react with each other, this is light sandwiched board where strong adhesion and a cost reduction are contrived and moreover this can be accepted for fire resistance for one hour and possesses heat insulating properties, sound insulating properties and vibration damping properties.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は建築、構築物の耐火内外
壁材、耐火間仕切り材、耐火遮音材とし有用で、かつ軽
量で耐火性、機械強度のあるサンドイッチ板に関するも
のである。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a sandwich plate which is useful as a fireproof inner / outer wall material for buildings and structures, a fireproof partitioning material, a fireproof soundproofing material, and is lightweight, fireproof and mechanically strong.

【0002】[0002]

【従来の技術】一般に耐熱性のある内、外壁用複合板と
しては、実開昭57−185535号公報、実開昭
58−1538号公報、実開昭63−15444号公
報、および特公平2−18230号公報、等が知られ
ている。
2. Description of the Related Art Generally, heat-resistant inner and outer wall composite plates are disclosed in Japanese Utility Model Publication Nos. 57-185535, 58-1538, 63-15444, and JP-B-2. No. 18230, etc. are known.

【0003】[0003]

【発明が解決しようとする課題】しかしながら、これら
複合板においては、下記するような諸点において大きな
欠点があった。すなわち、前記の複合板では不織布が
ガラス繊維等の薄い不織布であり、フェノールフォーム
が反対面、所謂、不燃基材と接着する面に漏洩して脆い
板状の接着面となるため別途接着剤が必要であり、接着
力の強度を十分に発揮することができない構造となる不
利があった。
However, these composite plates have major drawbacks in the following points. That is, in the above composite plate, the non-woven fabric is a thin non-woven fabric such as glass fiber, and the phenol foam leaks to the opposite surface, that is, the surface that adheres to the so-called non-combustible base material to form a brittle plate-shaped adhesive surface. It is necessary, and there is a disadvantage that the structure cannot fully exhibit the strength of the adhesive force.

【0004】前記の複合板では軽量骨材を細密に敷設
し、これをフェノールフォームで不燃基材と一体化し、
耐火性を改善する構成であるが、芯材となるフェノール
フォーム自体の接着力があまり強くなく、不燃基材から
芯材となるフェノールフォームが剥離する欠点があっ
た。
In the above composite board, a lightweight aggregate is laid finely and is integrated with a non-combustible base material by phenol foam,
Although it has a structure that improves fire resistance, it has a drawback that the phenol foam itself, which is the core material, does not have a very strong adhesive force and the phenol foam, which is the core material, is peeled from the non-combustible base material.

【0005】前記に示す複合板は硼酸ナトリウムを含
浸させた不燃シートとフェノールフォームを一体に固着
し、かつ上記不燃シート上に接着剤を介して不燃性の不
通気層を一体に固着した建築用板である。しかしこの
際、フェノールフォームの原料の不織布への含浸が表面
のみになりやすく、かつアルカリと酸の反応系のためフ
ォーム形成を阻害し、接着力の低下を招いていた。
The above-mentioned composite plate is a building in which a non-combustible sheet impregnated with sodium borate and a phenol foam are integrally fixed, and a non-combustible impermeable layer is integrally fixed on the non-combustible sheet via an adhesive. It is a plate. At this time, however, impregnation of the raw material of the phenol foam into the non-woven fabric is likely to occur only on the surface, and the reaction system of alkali and acid hinders the foam formation, resulting in a decrease in adhesive strength.

【0006】また、前記の複合板は面材と骨材含有の
フェノールフォームを一体化した構造であり、かつ面材
と芯材の一体化に融着を利用しているため、接着力に不
安があった。さらに、前記した〜に示す複合板はフ
ェノールフォームと面材の一体化のための接着力に欠
け、かつ耐熱的にもより高い、例えば耐火1時間の防火
試験等に合格できない弱点があった。
Further, since the composite plate has a structure in which a face material and an aggregate-containing phenol foam are integrated and fusion is used to integrate the face material and the core material, the adhesive strength is uncertain. was there. Further, the above-mentioned composite plates (1) to (3) were lacking in adhesive strength for integrating the phenol foam and the face material, and had higher heat resistance, for example, a weakness that they could not pass a fireproof test for 1 hour of fire resistance.

【0007】[0007]

【課題を解決するための手段】本発明はこのような欠点
を除去し、かつ遮音性を強化するため、少なくとも鉛箔
を有するクラッド鋼板と特殊性能の分離層と耐火、耐熱
性のある芯材と分離層と不燃基材間に芯材の一成分と化
学反応する接着剤を介して一体に固着した耐火、断熱、
遮音性があり、しかも強度もすぐれたサンドイッチ板を
提案するものである。
In order to eliminate such drawbacks and to enhance sound insulation, the present invention has at least a clad steel plate having a lead foil, a separation layer having special performance, and a core material having fire resistance and heat resistance. And fire resistance, heat insulation, which is integrally fixed between the separation layer and the non-combustible base material through an adhesive that chemically reacts with one component of the core material,
We propose a sandwich plate that has sound insulation and excellent strength.

【0008】[0008]

【実施例】以下に、図面を用いて本発明に係るサンドイ
ッチ板の一実施例について詳細に説明する。すなわち、
図1は本発明に係るサンドイッチ板Aの代表的な一例を
示す断面図であり、1は不燃基材、2はクラッド鋼板、
6は芯材、7は無機軽量骨材、9は分離層、10は接着
剤層である。
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS An embodiment of the sandwich plate according to the present invention will be described in detail below with reference to the drawings. That is,
FIG. 1 is a sectional view showing a typical example of a sandwich plate A according to the present invention, in which 1 is a non-combustible base material, 2 is a clad steel plate,
6 is a core material, 7 is an inorganic lightweight aggregate, 9 is a separation layer, and 10 is an adhesive layer.

【0009】さらに説明すると、不燃基材1としては、
例えば表面処理鋼板、ステンレス板、ガルバリウム鋼
板、ガルファン、アルミニウム板、チタン板、ホーロー
鋼板、フッ素樹脂塗装鋼板、銅板等の一種をプレス成
形、ロール成形、押出成形等したものである。2はクラ
ッド鋼板で外側に剛性のある金属薄板3と樹脂層4と内
側となる約30〜100ミクロンの鉛箔5とを一体に形
成した構造であり、主に遮音性と防振性を強化したもの
である。
To explain further, as the non-combustible base material 1,
For example, a surface-treated steel plate, a stainless steel plate, a galvalume steel plate, a galfan, an aluminum plate, a titanium plate, a enamel steel plate, a fluororesin coated steel plate, a copper plate or the like is press-formed, roll-formed, extruded or the like. Reference numeral 2 is a clad steel plate, which has a structure in which a thin metal plate 3 having rigidity, a resin layer 4, and a lead foil 5 of about 30 to 100 microns, which is the inner side, are integrally formed, and mainly the sound insulation and the vibration isolation are enhanced. It was done.

【0010】芯材6は約10〜100mm位で無機軽量
骨材7と無機軽量骨材7間の空間を充填するフェノール
フォーム8とから形成したものである。また、上記骨材
7は細密充填、あるいは分散、もしくは一方に偏在させ
たものである。
The core material 6 is formed of an inorganic lightweight aggregate 7 and a phenolic foam 8 filling a space between the inorganic lightweight aggregates 7 at about 10 to 100 mm. The aggregate 7 is densely packed, dispersed, or unevenly distributed in one side.

【0011】さらに説明すると、無機軽量骨材7は圧縮
強度の強化、耐火性、および防音性の向上を図るのに役
立つものであり、その具体例としては、パーライト粒、
ガラスビーズ、シラスバルーン、ケイ酸カルシウム粒、
タルク粒等の1種以上からなるもので、その粒径は1〜
20mmφ位である。
To further explain, the inorganic lightweight aggregate 7 is useful for enhancing the compressive strength, the fire resistance and the soundproofing. Specific examples thereof include pearlite grains,
Glass beads, shirasu balloon, calcium silicate particles,
It consists of one or more kinds of talc grains, etc.
It is about 20 mmφ.

【0012】フェノールフォーム8はレゾールタイプで
無機軽量骨材7と分離層9とを一体にその反応、発泡時
の自己接着性で接着すると共に、断熱性、防火性の強化
と後記する接着剤との化学反応にその縮合水が有効に作
用し、接着力をより一層、強くするものである。特に、
フェノールフォーム8は耐火性を難燃剤、無機粒体等の
添加によって従前より大幅に改善した組成のものであ
る。
Phenol foam 8 is of the resol type and adheres together the inorganic lightweight aggregate 7 and the separation layer 9 by their reaction, self-adhesiveness at the time of foaming, and strengthens the heat insulating property and the fireproofing property and the adhesive described later. The condensed water effectively acts on the chemical reaction of, and the adhesive strength is further strengthened. In particular,
Phenol foam 8 has a composition in which fire resistance is significantly improved by adding flame retardants, inorganic particles, and the like.

【0013】分離層9は図2に拡大して示すように主に
フェノールフォーム形成の際の化学反応で生ずる縮合
水、水蒸気の吸水、吸湿することによる放散機能と上記
反応系のコントロール機能(反応状態の遅延)と離形機
能と吸水機能と補強機能と面材機能と防火層の強化機能
とアンカ機能を具備する不織布から構成したものであ
る。
As shown in the enlarged view of FIG. 2, the separation layer 9 is mainly composed of condensed water produced by a chemical reaction in the formation of phenol foam, water absorption of water vapor, a diffusion function by absorbing moisture and a control function of the above reaction system (reaction). It is composed of a non-woven fabric having a function of delaying the state), a releasing function, a water absorbing function, a reinforcing function, a face material function, a fireproof layer reinforcing function and an anchor function.

【0014】上記不織布としては厚さが0.3〜5mm
位、目付は40〜300g/m2 であり、材料としては
ポリエステル系、ナイロン系、炭素繊維、アラミド繊維
等の1種からなる。特に、その不織布の空隙と厚さが上
記した機能のうち、フェノールフォーム反応時の縮合水
の外部への逃げと縮合水による接着性低下の防止と反応
状態のコントロールによって最適状態でフェノールフォ
ーム8と接着剤とが不織布を浸透する間にコントロール
でき、不燃基材1と分離層9とを一体化するのに役立つ
ものである。
The nonwoven fabric has a thickness of 0.3 to 5 mm.
The unit and basis weight are 40 to 300 g / m 2 , and the material is one type such as polyester type, nylon type, carbon fiber and aramid fiber. In particular, among the functions of the voids and the thickness of the non-woven fabric described above, the phenol foam 8 is optimally controlled by escaping the condensed water to the outside during the phenol foam reaction, preventing the adhesive water from lowering the adhesiveness, and controlling the reaction state. It can be controlled while the adhesive penetrates the non-woven fabric, and serves to integrate the non-combustible substrate 1 and the separation layer 9.

【0015】接着剤層10は不燃基材1、クラッド鋼板
2と分離層9とを一体に、かつ物理的および化学的反応
によって接着するものである。接着剤の一例としては水
と反応する成分を含有する樹脂、フェノール成分と反応
する成分を含有する樹脂、および接着剤として有効なも
の等である。
The adhesive layer 10 bonds the incombustible base material 1, the clad steel plate 2 and the separation layer 9 together and by a physical and chemical reaction. Examples of the adhesive include a resin containing a component that reacts with water, a resin containing a component that reacts with a phenol component, and an adhesive effective.

【0016】接着剤の具体例としてはエラストマー型エ
ポキシ樹脂、ウレタン樹脂、フェノール樹脂、ポリエス
テル樹脂、イソシアネート等のエマルジョンタイプ、ホ
ットメルトタイプ、等の1種以上を用いるものである。
Specific examples of the adhesive include one or more of an elastomer type epoxy resin, urethane resin, phenol resin, polyester resin, emulsion type such as isocyanate, hot melt type and the like.

【0017】次に本発明に係るサンドイッチ板の製造法
の一例を簡単に説明すると、図1に示すサンドイッチ板
Aを製造すると仮定し、不燃基材1として0.5mm厚
のカラー鋼板を成形機で樋状に成形し、その底面内面に
接着剤を塗布し、その上に分離層9、ポリエステル系繊
維の不織布を積層した後、パーライト粒とフェノールフ
ォーム原料を積層し、次に上記と同じ不織布を積層し、
接着剤、60ミクロン鉛箔−樹脂−0.35mm厚の鋼
板の構成としたクラッド鋼板2の順に積層し、キュアし
て一体に形成した。このサンドイッチ板Aの密度は10
0kg/m3 、耐火性はJIS−A−1304号の耐火
1時間の試験に合格し、遮音性は単にフォームだけの芯
材としたサンドイッチ板に比し、約5〜30dBだけ改
善されていた。
An example of the method for manufacturing a sandwich plate according to the present invention will be briefly described below. Assuming that the sandwich plate A shown in FIG. 1 is manufactured, a color steel plate having a thickness of 0.5 mm is formed as a non-combustible base material 1 by a molding machine. To form a gutter shape, apply an adhesive to the inner surface of the bottom surface, and then laminate the separation layer 9 and a nonwoven fabric of polyester fiber on it, then laminate the perlite particles and the phenol foam raw material, and then the same nonwoven fabric as above. Stack the
An adhesive, a 60-micron lead foil, a resin, and a clad steel plate 2 having a structure of a steel plate having a thickness of 0.35 mm were laminated in this order and cured to be integrally formed. The density of this sandwich plate A is 10
0 kg / m 3 , the fire resistance passed the JIS-A-1304 fire resistance 1 hour test, and the sound insulation was improved by about 5 to 30 dB as compared with the sandwich plate having only the foam as the core material. ..

【0018】以上説明したのは本発明に係るサンドイッ
チ板の一実施例にすぎず、図3に示すようにクラッド鋼
板2を両面に用いたサンドイッチ板Aとすることもでき
る。また、サンドイッチ板Aとしては図4、図5、図
6、図7および図8に示す形状とすることもできる。な
お、分離層9、無機軽量骨材7、接着剤層10は省略し
て示す。また、イはパッキング材である。
The above description is merely one embodiment of the sandwich plate according to the present invention, and a sandwich plate A using both sides of the clad steel plates 2 as shown in FIG. 3 can be used. Further, the sandwich plate A may have the shape shown in FIGS. 4, 5, 6, 7 and 8. The separation layer 9, the inorganic lightweight aggregate 7, and the adhesive layer 10 are omitted. Further, a is a packing material.

【0019】[0019]

【発明の効果】上述したように本発明に係るサンドイッ
チ板によれば、(1)不燃基材クラッド鋼板と芯材の主
体間に耐熱性、含浸性、補強性のある分離層を介在さ
せ、かつ分離層を接着剤と上記主体の含浸により強化し
て機械強度と経済性(コスト)を向上できる。(2)分
離層は耐熱性のある不織布のため接着剤と主体の原液が
共に含浸してアンカー効果と反応時に生ずる縮合水とイ
ソシアネートの水との反応による化学縮合による吸水機
能と撒水機能でより接着力が強化されることにより不燃
基材と芯材の一体化を促進できる。(3)分離層は主体
の反応系をより接着力が向上するタイミングに厚さと繊
維間を通過する間にコントロールできる。(4)パーラ
イト粒の無機軽量骨材を細密充填し、かつその骨材の空
間に耐火性のあるフェノールフォームを充填し一体化し
たためJIS−A−1304号の耐火1時間試験に合格
できる。(5)断熱性はALCの4倍以上、比重は0.
3〜0.5と軽量である。(6)クラッド鋼板は防振性
と遮音性の改善に大幅に役立つと共に、強度の向上にも
寄与する。等の特徴、効果がある。
As described above, according to the sandwich plate of the present invention, (1) a heat-resistant, impregnating and reinforcing separating layer is interposed between the main body of the non-combustible base material clad steel plate and the core material, In addition, the mechanical strength and economical efficiency (cost) can be improved by strengthening the separation layer by the impregnation of the adhesive and the above main body. (2) Since the separation layer is a heat-resistant non-woven fabric, both the adhesive and the undiluted solution of the main body are impregnated together, and the anchor effect and the water-absorption function and the water-sprinkling function due to the chemical condensation caused by the reaction of the isocyanate with the water generated during the reaction By strengthening the adhesive force, the integration of the non-combustible base material and the core material can be promoted. (3) The separation layer can control the thickness of the main reaction system and the time during passage between fibers at the timing when the adhesive force is further improved. (4) Since the inorganic lightweight aggregate of pearlite grains is closely packed and the space of the aggregate is filled with and integrated with a phenolic foam having fire resistance, the fireproof 1-hour test of JIS-A-1304 can be passed. (5) Adiabatic property is 4 times or more that of ALC, and specific gravity is 0.
It is as light as 3 to 0.5. (6) The clad steel plate greatly contributes to the improvement of vibration isolation and sound insulation, and also contributes to the improvement of strength. There are features and effects.

【図面の簡単な説明】[Brief description of drawings]

【図1】本発明に係るサンドイッチ板の一例を示す断面
図である。
FIG. 1 is a sectional view showing an example of a sandwich plate according to the present invention.

【図2】図1で用いたサンドイッチ板の一部を抽出拡大
して示す説明図である。
FIG. 2 is an explanatory view showing a part of the sandwich plate used in FIG. 1 by extracting and enlarging it.

【図3】本発明に係るサンドイッチ板のその他の実施例
を示す断面図である。
FIG. 3 is a sectional view showing another embodiment of the sandwich plate according to the present invention.

【図4】本発明に係るサンドイッチ板のその他の実施例
の略図である。
FIG. 4 is a schematic view of another embodiment of the sandwich plate according to the present invention.

【図5】本発明に係るサンドイッチ板のその他の実施例
の略図である。
FIG. 5 is a schematic view of another embodiment of the sandwich plate according to the present invention.

【図6】本発明に係るサンドイッチ板のその他の実施例
の略図である。
FIG. 6 is a schematic view of another embodiment of the sandwich plate according to the present invention.

【図7】本発明に係るサンドイッチ板のその他の実施例
の略図である。
FIG. 7 is a schematic view of another embodiment of the sandwich plate according to the present invention.

【図8】本発明に係るサンドイッチ板のその他の実施例
の略図である。
FIG. 8 is a schematic view of another embodiment of the sandwich plate according to the present invention.

【符号の説明】[Explanation of symbols]

A サンドイッチ板 1 不燃基材 2 クラッド鋼板 3 金属薄板 4 樹脂層 5 鉛箔 6 芯材 7 無機軽量骨材 8 フェノールフォーム 9 分離層 10 接着剤層 A Sandwich plate 1 Non-combustible base material 2 Clad steel plate 3 Metal thin plate 4 Resin layer 5 Lead foil 6 Core material 7 Inorganic lightweight aggregate 8 Phenol foam 9 Separation layer 10 Adhesive layer

───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.5 識別記号 庁内整理番号 FI 技術表示箇所 B32B 27/42 101 7016−4F E04B 1/94 R 2118−2E ─────────────────────────────────────────────────── ─── Continuation of front page (51) Int.Cl. 5 Identification code Office reference number FI technical display location B32B 27/42 101 7016-4F E04B 1/94 R 2118-2E

Claims (1)

【特許請求の範囲】[Claims] 【請求項1】 不燃基材と芯材となるフェノールフォー
ム間に分離層を介在させたサンドイッチ板において、上
記分離層は耐熱性のある合成繊維からなる厚さ0.1m
m以上の不織布で形成し、該不織布と不燃基材間に水と
反応する成分の接着剤層を介在させ、かつ不織布に接着
剤を含浸させて一体化し、また前記不織布とフェノール
フォームとの一体化をフェノールフォーム形成時の自己
接着性とその含浸により固着すると共に、芯材を無機軽
量骨材と耐火性を強化したフェノールフォームで形成
し、かつ表、裏面材となる不燃基材の少なくとも一方を
鉛箔を内側に用いたクラッド鋼板で形成したことを特徴
とするサンドイッチ板。
1. A sandwich plate in which a separation layer is interposed between a non-combustible base material and a phenol foam as a core material, wherein the separation layer is made of heat-resistant synthetic fiber and has a thickness of 0.1 m.
m or more non-woven fabric, an adhesive layer of a component that reacts with water is interposed between the non-woven fabric and the non-combustible base material, and the non-woven fabric is impregnated with an adhesive to be integrated, and the non-woven fabric and the phenol foam are integrated. At least one of the non-combustible base material that becomes the front and back materials by forming the core material with inorganic lightweight aggregate and phenol foam with enhanced fire resistance A sandwich plate characterized by being formed by a clad steel plate using lead foil inside.
JP29244091A 1991-10-11 1991-10-11 Sandwiched board Pending JPH0596675A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP29244091A JPH0596675A (en) 1991-10-11 1991-10-11 Sandwiched board

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP29244091A JPH0596675A (en) 1991-10-11 1991-10-11 Sandwiched board

Publications (1)

Publication Number Publication Date
JPH0596675A true JPH0596675A (en) 1993-04-20

Family

ID=17781824

Family Applications (1)

Application Number Title Priority Date Filing Date
JP29244091A Pending JPH0596675A (en) 1991-10-11 1991-10-11 Sandwiched board

Country Status (1)

Country Link
JP (1) JPH0596675A (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2371059A (en) * 2000-11-11 2002-07-17 Refrigeration Const Serv Ltd Fire resistant panel
GB2458743A (en) * 2008-01-16 2009-10-07 Kingspan Res & Dev Ltd Composite insulation panel for buildings, having at least four layers
CN101879793A (en) * 2010-06-25 2010-11-10 苏州浩海高分子材料研究所有限公司 Ultrathin stone phenolic aldehyde composite finished product thermal insulation decorating plate
CN102031836A (en) * 2011-01-11 2011-04-27 汪路 Ultrathin stone multilayer three-dimensional sandwich flame-retardant composite heat insulation board
CN102121301A (en) * 2011-01-11 2011-07-13 汪路 Composite type multilayer three-dimensional sandwich flame-retardant heat-preserving decorative sheet
CN102140824A (en) * 2011-01-11 2011-08-03 汪路 Surface-painted multilayer three-dimensional sandwiched flame-retardant composite heat preservation plate

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2371059A (en) * 2000-11-11 2002-07-17 Refrigeration Const Serv Ltd Fire resistant panel
EP1207239A3 (en) * 2000-11-11 2003-09-03 Refrigeration Construction Services Limited Improvements in or relating to fire resistant panels
GB2458743A (en) * 2008-01-16 2009-10-07 Kingspan Res & Dev Ltd Composite insulation panel for buildings, having at least four layers
GB2458743B (en) * 2008-01-16 2012-09-05 Kingspan Res & Dev Ltd A composite panel
CN101879793A (en) * 2010-06-25 2010-11-10 苏州浩海高分子材料研究所有限公司 Ultrathin stone phenolic aldehyde composite finished product thermal insulation decorating plate
CN102031836A (en) * 2011-01-11 2011-04-27 汪路 Ultrathin stone multilayer three-dimensional sandwich flame-retardant composite heat insulation board
CN102121301A (en) * 2011-01-11 2011-07-13 汪路 Composite type multilayer three-dimensional sandwich flame-retardant heat-preserving decorative sheet
CN102140824A (en) * 2011-01-11 2011-08-03 汪路 Surface-painted multilayer three-dimensional sandwiched flame-retardant composite heat preservation plate

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