JPH0585771A - Composition for hollow glass sphere - Google Patents
Composition for hollow glass sphereInfo
- Publication number
- JPH0585771A JPH0585771A JP6914992A JP6914992A JPH0585771A JP H0585771 A JPH0585771 A JP H0585771A JP 6914992 A JP6914992 A JP 6914992A JP 6914992 A JP6914992 A JP 6914992A JP H0585771 A JPH0585771 A JP H0585771A
- Authority
- JP
- Japan
- Prior art keywords
- hollow glass
- glass
- weight
- composition
- glass spheres
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C11/00—Multi-cellular glass ; Porous or hollow glass or glass particles
- C03C11/002—Hollow glass particles
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Glass Compositions (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
【０００１】[0001]
【産業上の利用分野】本発明は、中空ガラス球用組成
物、特に合成樹脂の強化、軽量化に有用な中空ガラス球
用組成物に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a composition for hollow glass spheres, and more particularly to a composition for hollow glass spheres which is useful for strengthening synthetic resin and reducing weight.
【０００２】[0002]
【従来の技術】中空ガラス球は、各種合成樹脂にその強
化と軽量化のために充填材として用いられいる。この種
の中空ガラス球には、合成樹脂の射出成型時あるいは加
圧成型時の圧力によって破壊しないように高い耐圧強度
が必要であり、また、合成樹脂の強化という立場から合
成樹脂との十分な密着性が必要である。2. Description of the Related Art Hollow glass spheres are used as fillers in various synthetic resins in order to strengthen and reduce their weight. This kind of hollow glass sphere requires high pressure resistance so as not to be broken by the pressure during injection molding or pressure molding of synthetic resin, and from the standpoint of strengthening synthetic resin, it is sufficient Adhesion is required.
【０００３】従来、上記用途に用いられる中空ガラス球
として種々のガラスが市販されて実用に供されている。Various glasses have hitherto been put on the market for practical use as hollow glass spheres used for the above purposes.
【０００４】[0004]
【発明が解決しようとする課題】しかしながら、上記従
来の中空ガラス球は、耐圧強度が不十分であり合成樹脂
の成型時その高い圧力のために破壊してしまう場合があ
った。また、中空ガラス球と合成樹脂との密着性は、中
空ガラス球のアルカリ溶出量の如何によるが、従来の中
空ガラス球は耐水性が悪くガラスよりアルカリが溶出し
て合成樹脂との密着性が阻害され、そのために強化の作
用が十分ではなかった。However, the above-mentioned conventional hollow glass spheres have insufficient pressure resistance and may be broken due to the high pressure during molding of synthetic resin. Further, the adhesion between the hollow glass spheres and the synthetic resin depends on the amount of alkali elution of the hollow glass spheres, but the conventional hollow glass spheres have poor water resistance and the alkali is leached out of the glass, resulting in poor adhesion to the synthetic resin. It was inhibited and, as a result, the strengthening effect was not sufficient.
【０００５】本発明は上記事情に鑑みてなされたもので
あり、本発明の目的は、高い耐圧強度を有し、合成樹脂
との密着性に優れた中空ガラス球用組成物を提供するこ
とにある。The present invention has been made in view of the above circumstances, and an object of the present invention is to provide a composition for hollow glass spheres, which has high pressure resistance and is excellent in adhesion to a synthetic resin. is there.
【０００６】[0006]
【課題を解決するための手段】本発明の中空ガラス球用
組成物は、重量％で以下の組成、 ＳｉＯ2 ４０〜５９ Ｒ2 Ｏ ２〜１７ （Ｒ2 ＯはＬｉ2 Ｏ、Ｎａ2 Ｏ、Ｋ2 Ｏから選ばれた一
者または二者以上） Ｂ2 Ｏ3 １〜２５ ＲＯ ５〜２５ （ＲＯはＣａＯ、ＭｇＯ、ＢａＯ、ＺｎＯ、ＳｒＯから
選ばれた一者または二以上） ＲＯ2 ６〜４０ （ＲＯ2 はＴｉＯ2、ＺｒＯ2 から選ばれた一者または二
者） Ａｌ2 Ｏ3 ０〜１３ Ｐ2 Ｏ5 ０〜３ ＳＯ3 ０．１〜１．０ からなることを特徴とする。更に好ましくは ＳｉＯ2 ４２〜５８ Ｒ2 Ｏ ３〜１６ （Ｒ2 ＯはＬｉＯ2 、Ｎａ2 Ｏ、Ｋ2 Ｏから選ばれた一
者または二者以上） Ｂ2 Ｏ3 ３〜２３ ＲＯ ６〜２２ （ＲＯはＣａＯ、ＭｇＯ、ＢａＯ、ＺｎＯ、ＳｒＯから
選ばれた一者または二者以上） ＲＯ2 ７〜２６ （ＲＯ2 はＴｉＯ2 、ＺｒＯ2 から選ばれた一者または
二者以上） Ａｌ2 Ｏ3 ０〜１１ Ｐ2 Ｏ5 ０〜２ ＳＯ3 ０．２〜０．８ からなることを特徴とする。The composition for hollow glass spheres of the present invention has the following composition by weight%: SiO 2 40 to 59 R 2 O 2 to 17 (R 2 O is Li 2 O and Na 2 O). , One or two or more selected from K 2 O) B 2 O 3 1 to 25 RO 5 to 25 (RO is one or more selected from CaO, MgO, BaO, ZnO, and SrO) RO 2 6 to 40 (RO 2 is one or two selected from TiO 2 and ZrO 2 ) Al 2 O 3 0 to 13 P 2 O 5 0 to 3 SO 3 0.1 to 1.0 And More preferably, SiO 2 42 to 58 R 2 O 3 to 16 (R 2 O is one or more selected from LiO 2 , Na 2 O and K 2 O) B 2 O 3 3 to 23 RO 6 to 22 (RO is one or more selected from CaO, MgO, BaO, ZnO and SrO) RO 2 7 to 26 (RO 2 is one or more selected from TiO 2 and ZrO 2 ) Al 2 O 3 0 to 11 P 2 O 5 0 to 2 SO 3 0.2 to 0.8.
【０００７】上記した本発明の組成を有する中空ガラス
球は次のようにして製造される。まず、シリカ、アルミ
ナ、硼酸等のガラス原料及び発泡材としての芒硝を目標
組成になるよう調合したガラスバッチを１３００℃で２
時間溶融してガラスを製作する。次いでこのガラスを粉
砕、分級して５３μｍ以下のガラス粉にし、その後この
ガラス粉を１４００℃程度の火炎中に通過させて再溶融
し前記芒硝によりガラス中に溶解したＳＯ3 からＳＯ2
ガスを発生させ中空ガラス球とする。最後にこの中空ガ
ラス球を水に入れて浮上する中空ガラス球を採取する。
このようにして得られた中空ガラス球は、肉厚が０．５
〜２０μｍ、直径が１〜１３０μｍであった。The hollow glass sphere having the above-mentioned composition of the present invention is manufactured as follows. First, a glass batch prepared by mixing glass raw materials such as silica, alumina, boric acid and the like and Glauber's salt as a foaming material so as to have a target composition at 2300 ° C.
It is melted for a time to make glass. Next, this glass was crushed and classified to a glass powder of 53 μm or less, and then this glass powder was passed through a flame at about 1400 ° C. to be remelted and SO 3 to SO 2 dissolved in the glass with the above-mentioned Glauber's salt.
Gas is generated to form hollow glass spheres. Finally, the hollow glass spheres are placed in water and the floating hollow glass spheres are collected.
The hollow glass spheres thus obtained have a wall thickness of 0.5.
It was -20 μm and the diameter was 1-130 μm.
【０００８】[0008]
【作用】中空ガラス球の耐圧強度は、下記式で表され
る。The pressure resistance of the hollow glass sphere is expressed by the following formula.
【０００９】[0009]
【数１】 [Equation 1]
【００１０】この式において、Ｐは耐圧強度、Ｅはガラ
スのヤング率、ｔは肉厚、ｒは半径、νはガラスのポア
ソン比を示す。この式から明らかなように、肉厚と半径
が同じ同一形状の中空ガラス球であればその耐圧強度は
ガラスのヤング率とポアソン比とで決定されるところ、
ポアソン比はどのガラスでもほぼ同一であるので、中空
ガラス球の耐圧強度は実質的にガラスのヤング率にのみ
依ることになる。従って、本発明では、ヤング率を耐圧
強度の指標とする。In this equation, P is the compressive strength, E is the Young's modulus of glass, t is the wall thickness, r is the radius, and ν is the Poisson's ratio of the glass. As is clear from this formula, if the hollow glass spheres of the same shape with the same wall thickness and radius, the pressure resistance is determined by the Young's modulus and Poisson's ratio of the glass,
Since the Poisson's ratio is almost the same for all glasses, the compressive strength of the hollow glass sphere substantially depends only on the Young's modulus of the glass. Therefore, in the present invention, Young's modulus is used as an index of pressure resistance.
【００１１】中空ガラス球の製造上具備すべき条件は次
の通りである。まず、不均質なガラスであると中空ガラ
ス球の耐圧強度が著しく低くなるため、溶融の際、溶融
性が良好であり、ガラスに結晶が析出する失透現象がな
く、しかも溶融ガラス中に不溶解なゴールが発生しない
ことが必要である。また、ガラス粉を再溶融して中空ガ
ラス球にする際、球が破壊しない程度の適切な量のガス
を発生することが必要がある。The conditions that must be met for the production of hollow glass spheres are as follows. First of all, if the glass is inhomogeneous, the hollow glass spheres have a significantly low compressive strength, so the meltability is good during melting, there is no devitrification phenomenon in which crystals precipitate in the glass, and there is no It is necessary that no melting goals occur. Further, when remelting the glass powder into hollow glass spheres, it is necessary to generate an appropriate amount of gas such that the spheres are not broken.
【００１２】上記の製造上の条件以外に中空ガラス球に
要求される特性としては、先記したように高い耐圧強
度、すなわちそれの指標とされる高いヤング率を有する
こと、ガラスからのアルカリ溶出量が少ないことが必要
である。In addition to the above manufacturing conditions, the properties required of the hollow glass sphere are, as mentioned above, high compressive strength, that is, high Young's modulus as an index thereof, and alkali elution from glass. It needs to be small.
【００１３】本発明の中空ガラス球用組成物は、ガラス
の組成を構成する成分を適切なものに選択し、且つその
成分の含有量を特定範囲にすることにより上記中空ガラ
ス球の製造上の条件ならびに中空ガラス球としての特性
を満足させたものである。以下にそのガラス組成の限定
理由を説明する。The composition for hollow glass spheres of the present invention is suitable for producing the above-mentioned hollow glass spheres by appropriately selecting the components constituting the composition of the glass and setting the content of the components in a specific range. It satisfies the conditions and the characteristics as a hollow glass sphere. The reasons for limiting the glass composition will be described below.
【００１４】ＳｉＯ2 は、ガラスのネットワークフォー
マーを形成する成分であり、４０重量％より少ないとガ
ラスのアルカリ溶出量が増加し、５９重量％より多いと
溶融性が悪化する。より好ましくはＳｉＯ2 は４２重量
％から５８重量％である。SiO 2 is a component forming a glass network former. If it is less than 40% by weight, the amount of alkali elution of glass increases, and if it exceeds 59% by weight, the meltability deteriorates. More preferably, SiO 2 is 42 wt% to 58 wt%.
【００１５】Ｒ2 Ｏは、Ｌｉ2 Ｏ、Ｎａ2 Ｏ、Ｋ2 Ｏか
ら選ばれた一者または二者以上の成分であり、ガラスの
融剤として用いられ、２重量％より少ないとガラスの溶
融性が低下し、１７重量％を超えるとガラスのアルカリ
溶出量が増加する。より好ましくはＲ2 Ｏは３重量％か
ら１６重量％である。R 2 O is one or more components selected from Li 2 O, Na 2 O and K 2 O, and is used as a flux for glass. Meltability decreases, and when it exceeds 17% by weight, the amount of alkali elution of glass increases. More preferably R 2 O is 3% to 16% by weight.
【００１６】Ｂ2 Ｏ3 は、１重量％より少ないとガラス
の溶融性が低下すると共にガラスのアルカリ溶出量が多
くなり、２５重量％より多いと中空ガラス球の耐圧強度
が低下する。より好ましくはＢ2 Ｏ3 は３重量％から２
３重量％である。If the content of B 2 O 3 is less than 1% by weight, the melting property of the glass is lowered and the amount of alkali elution of the glass is increased, and if it is more than 25% by weight, the pressure resistance of the hollow glass sphere is lowered. More preferably B 2 O 3 is from 3% by weight to 2
It is 3% by weight.
【００１７】ＲＯはＣａＯ、ＭｇＯ、ＢａＯ、ＺｎＯ、
ＳｒＯから選ばれた一者または二者以上の成分であり、
５重量％より少ないとガラスの溶融性が悪化し、２５重
量％を超えるとガラスが失透して好ましくない。より好
適には、ＲＯは６重量％から２２重量％である。RO is CaO, MgO, BaO, ZnO,
One or more components selected from SrO,
If it is less than 5% by weight, the meltability of the glass is deteriorated, and if it exceeds 25% by weight, the glass is devitrified, which is not preferable. More preferably, RO is 6% to 22% by weight.
【００１８】ＲＯ2 は、ＴｉＯ2 、ＺｒＯ2 から選ばれ
た一者または二者の成分であり、６重量％より少ない場
合は中空ガラス球の耐圧強度が低下すると共にガラスか
らのアルカリ溶出量が増加し、４０重量％より多い場合
はガラスが失透する。より好ましくはＲＯ2 は７重量％
から２６重量％である。RO 2 is one or two components selected from TiO 2 and ZrO 2. If it is less than 6% by weight, the pressure resistance of the hollow glass spheres is lowered and the amount of alkali elution from the glass is reduced. If it increases, and if it exceeds 40% by weight, the glass devitrifies. More preferably RO 2 is 7% by weight
To 26% by weight.
【００１９】Ａｌ2 Ｏ3 は多すぎる場合、溶融性の低下
を招くため上限を１３重量％とする。より好ましくはＡ
ｌ2 Ｏ3は１１重量％以下である。If the amount of Al 2 O 3 is too large, the melting property is lowered, so the upper limit is made 13% by weight. More preferably A
The l 2 O 3 content is 11% by weight or less.
【００２０】Ｐ2 Ｏ5 はＳＯ3 のガラスへの溶解を促進
させる成分であるが、３重量％を超えると溶融ガラスに
不溶解物のゴールが発生する。Ｐ2 Ｏ5 のより好ましい
組成範囲は２重量％以下である。P 2 O 5 is a component that accelerates the dissolution of SO 3 in glass, but if it exceeds 3% by weight, the goal of insoluble matter is generated in the molten glass. A more preferable composition range of P 2 O 5 is 2% by weight or less.
【００２１】ＳＯ3 はＳＯ2 ガスを発生させて中空ガラ
ス球を作る成分であり、０．１重量％より少ないと中空
ガラス球とならず、１重量％より大きいと溶融ガラスに
不溶解物のゴールが生じる。ＳＯ3 のより好適な組成範
囲は０．２重量％から０．８重量％である。SO 3 is a component that generates SO 2 gas to form hollow glass spheres. If it is less than 0.1% by weight, it does not become a hollow glass sphere, and if it is more than 1% by weight, it is an insoluble matter in molten glass. Goal occurs. A more preferable composition range of SO 3 is 0.2% by weight to 0.8% by weight.
【００２２】[0022]
【実施例】次に、本発明の実施例について説明する。EXAMPLES Next, examples of the present invention will be described.
【００２３】[0023]
【表１】 [Table 1]
【００２４】表１の試料Ｎｏ．１〜Ｎｏ．１３は、本発
明の中空ガラス球のガラス組成を示しており、同表下段
にはこれら試料のヤング率とアルカリ溶出量を示してあ
る。尚、ヤング率はＪＩＳ Ｒ１６０２の超音波パルス
法で、アルカリ溶出量はＪＩＳ Ｒ３５０２で測定し
た。Sample No. 1 in Table 1 1-No. 13 shows the glass composition of the hollow glass sphere of the present invention, and the Young's modulus and alkali elution amount of these samples are shown in the lower part of the table. The Young's modulus was measured by the ultrasonic pulse method of JIS R1602, and the alkali elution amount was measured by JIS R3502.
【００２５】表１から本発明のガラスはヤング率が高
く、アルカリ溶出量が低いことがわかる。It can be seen from Table 1 that the glass of the present invention has a high Young's modulus and a low alkali elution amount.
【００２６】[0026]
【発明の効果】以上説明したように、本発明の中空ガラ
ス球用組成物はヤング率が高く、アルカリ溶出量が少な
いため、耐圧強度及び合成樹脂との密着性が良好であ
り、特に合成樹脂の強化と軽量化に最適である。As described above, since the composition for hollow glass spheres of the present invention has a high Young's modulus and a small amount of alkali elution, it has good pressure resistance and good adhesion to synthetic resins. Ideal for strengthening and reducing weight.
Claims (2)
者または二者以上） Ｂ2 Ｏ3 １〜２５ ＲＯ ５〜２５ （ＲＯはＣａＯ、ＭｇＯ、ＢａＯ、ＺｎＯ、ＳｒＯから
選ばれた一者または二以上） ＲＯ2 ６〜４０ （ＲＯ2 はＴｉＯ2、ＺｒＯ2 から選ばれた一者または二
者） Ａｌ2 Ｏ3 ０〜１３ Ｐ2 Ｏ5 ０〜３ ＳＯ3 ０．１〜１．０ からなることを特徴とする中空ガラス球用組成物。1. A composition, by weight, having the following composition: SiO 2 40 to 59 R 2 O 2 to 17 (R 2 O is one or more selected from Li 2 O, Na 2 O and K 2 O) B 2 O 3 1 to 25 RO 5 to 25 (RO is one or more selected from CaO, MgO, BaO, ZnO, and SrO) RO 2 6 to 40 (RO 2 is selected from TiO 2 and ZrO 2 One or two) Al 2 O 3 0 to 13 P 2 O 5 0 to 3 SO 3 0.1 to 1.0, a composition for hollow glass spheres.
者または二者以上） Ｂ2 Ｏ3 ３〜２３ ＲＯ ６〜２２ （ＲＯはＣａＯ、ＭｇＯ、ＢａＯ、ＺｎＯ、ＳｒＯから
選ばれた一者または二者以上） ＲＯ2 ７〜２６ （ＲＯ2 はＴｉＯ2 、ＺｒＯ2 から選ばれた一者または
二者） Ａｌ2 Ｏ3 ０〜１１ Ｐ2 Ｏ5 ０〜２ ＳＯ3 ０．２〜０．８ からなる請求項１の中空ガラス球用組成物。2. The following composition by weight%: SiO 2 42 to 58 R 2 O 3 to 16 (R 2 O is one or more selected from Li 2 O, Na 2 O and K 2 O) B 2 O 3 3-23 RO 6-22 (RO is one or more selected from CaO, MgO, BaO, ZnO and SrO) RO 2 7 to 26 (RO 2 is selected from TiO 2 and ZrO 2 One or two) Al 2 O 3 0 to 11 P 2 O 5 0 to 2 SO 3 0.2 to 0.8 The composition for hollow glass spheres according to claim 1.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP6914992A JPH0585771A (en) | 1991-03-29 | 1992-02-18 | Composition for hollow glass sphere |
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP9327391 | 1991-03-29 | ||
| JP3-93273 | 1991-03-29 | ||
| JP6914992A JPH0585771A (en) | 1991-03-29 | 1992-02-18 | Composition for hollow glass sphere |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH0585771A true JPH0585771A (en) | 1993-04-06 |
Family
ID=26410334
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP6914992A Pending JPH0585771A (en) | 1991-03-29 | 1992-02-18 | Composition for hollow glass sphere |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0585771A (en) |
Cited By (11)
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|---|---|---|---|---|
| US6245700B1 (en) | 1999-07-27 | 2001-06-12 | 3M Innovative Properties Company | Transparent microspheres |
| US6335083B1 (en) | 1997-04-18 | 2002-01-01 | 3M Innovative Properties Company | Transparent beads and their production method |
| US6514892B1 (en) | 1997-04-18 | 2003-02-04 | 3M Innovative Properties Company | Transparent beads and their production method |
| KR100431727B1 (en) * | 1997-09-29 | 2004-09-04 | 삼성코닝 주식회사 | Substrate glasses for plasma display panel |
| US7524779B2 (en) | 2003-06-11 | 2009-04-28 | 3M Innovative Properties Company | Microspheres having a high index of refraction |
| CN104891804A (en) * | 2015-05-19 | 2015-09-09 | 郑州圣莱特空心微珠新材料有限公司 | Hollow glass bead and preparation method thereof |
| JP5810086B2 (en) * | 2010-08-05 | 2015-11-11 | 日本板硝子株式会社 | Glass filler |
| JP2016525057A (en) * | 2013-07-18 | 2016-08-22 | スリーエム イノベイティブ プロパティズ カンパニー | Glass microbubbles, original products, and methods for producing them |
| JP2019026543A (en) * | 2017-08-04 | 2019-02-21 | 太平洋セメント株式会社 | Oxide hollow particles |
| CN114106548A (en) * | 2021-12-17 | 2022-03-01 | 宁波瑞隆新材料科技有限公司 | Anti-aging PC (polycarbonate) and ABS (acrylonitrile butadiene styrene) composite material as well as preparation method and application thereof |
| EP4082979A4 (en) * | 2019-12-27 | 2023-01-18 | Nichias Corporation | Inorganic fibers, inorganic fiber product, method for manufacturing inorganic fiber product, composition for manufacturing inorganic fibers, method for manufacturing inorganic fibers |
-
1992
- 1992-02-18 JP JP6914992A patent/JPH0585771A/en active Pending
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6511739B2 (en) | 1997-04-18 | 2003-01-28 | 3M Innovative Properties Company | Transparent beads and their production method |
| US6335083B1 (en) | 1997-04-18 | 2002-01-01 | 3M Innovative Properties Company | Transparent beads and their production method |
| US6514892B1 (en) | 1997-04-18 | 2003-02-04 | 3M Innovative Properties Company | Transparent beads and their production method |
| KR100431727B1 (en) * | 1997-09-29 | 2004-09-04 | 삼성코닝 주식회사 | Substrate glasses for plasma display panel |
| US6479417B2 (en) | 1999-07-27 | 2002-11-12 | 3M Innovative Properties Company | Glass-ceramic microspheres that impart yellow color to retroreflected light |
| US6245700B1 (en) | 1999-07-27 | 2001-06-12 | 3M Innovative Properties Company | Transparent microspheres |
| US6461988B2 (en) | 1999-07-27 | 2002-10-08 | 3M Innovative Properties Company | Transparent microspheres |
| US7524779B2 (en) | 2003-06-11 | 2009-04-28 | 3M Innovative Properties Company | Microspheres having a high index of refraction |
| JP5810086B2 (en) * | 2010-08-05 | 2015-11-11 | 日本板硝子株式会社 | Glass filler |
| JP2016525057A (en) * | 2013-07-18 | 2016-08-22 | スリーエム イノベイティブ プロパティズ カンパニー | Glass microbubbles, original products, and methods for producing them |
| CN104891804A (en) * | 2015-05-19 | 2015-09-09 | 郑州圣莱特空心微珠新材料有限公司 | Hollow glass bead and preparation method thereof |
| JP2019026543A (en) * | 2017-08-04 | 2019-02-21 | 太平洋セメント株式会社 | Oxide hollow particles |
| EP4082979A4 (en) * | 2019-12-27 | 2023-01-18 | Nichias Corporation | Inorganic fibers, inorganic fiber product, method for manufacturing inorganic fiber product, composition for manufacturing inorganic fibers, method for manufacturing inorganic fibers |
| CN114106548A (en) * | 2021-12-17 | 2022-03-01 | 宁波瑞隆新材料科技有限公司 | Anti-aging PC (polycarbonate) and ABS (acrylonitrile butadiene styrene) composite material as well as preparation method and application thereof |
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