JPH0561385B2 - - Google Patents
Info
- Publication number
- JPH0561385B2 JPH0561385B2 JP62251413A JP25141387A JPH0561385B2 JP H0561385 B2 JPH0561385 B2 JP H0561385B2 JP 62251413 A JP62251413 A JP 62251413A JP 25141387 A JP25141387 A JP 25141387A JP H0561385 B2 JPH0561385 B2 JP H0561385B2
- Authority
- JP
- Japan
- Prior art keywords
- cotton
- coated
- ceramic
- synthetic resin
- thickness
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229920000742 Cotton Polymers 0.000 claims description 43
- 239000000919 ceramic Substances 0.000 claims description 42
- 239000000843 powder Substances 0.000 claims description 27
- 229920003002 synthetic resin Polymers 0.000 claims description 17
- 239000000057 synthetic resin Substances 0.000 claims description 17
- 239000011248 coating agent Substances 0.000 claims description 7
- 238000000576 coating method Methods 0.000 claims description 7
- 239000000835 fiber Substances 0.000 claims description 6
- 239000002245 particle Substances 0.000 claims description 5
- 239000000126 substance Substances 0.000 claims description 4
- 210000002268 wool Anatomy 0.000 claims description 4
- 238000004519 manufacturing process Methods 0.000 claims description 3
- 239000007921 spray Substances 0.000 claims description 2
- 238000005507 spraying Methods 0.000 claims 1
- 239000010410 layer Substances 0.000 description 21
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 9
- 239000011247 coating layer Substances 0.000 description 8
- 229920005989 resin Polymers 0.000 description 8
- 239000011347 resin Substances 0.000 description 8
- 230000000694 effects Effects 0.000 description 5
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 238000005524 ceramic coating Methods 0.000 description 3
- 239000002657 fibrous material Substances 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- IUYLTEAJCNAMJK-UHFFFAOYSA-N cobalt(2+);oxygen(2-) Chemical compound [O-2].[Co+2] IUYLTEAJCNAMJK-UHFFFAOYSA-N 0.000 description 2
- IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(II) oxide Inorganic materials [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 description 2
- 239000000395 magnesium oxide Substances 0.000 description 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 2
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000004753 textile Substances 0.000 description 2
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000001877 deodorizing effect Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 description 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 229910052845 zircon Inorganic materials 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 description 1
Description
【発明の詳細な説明】
［産業上の利用分野］
この発明は、主に布団に用いるためのセラミツ
クコーテイングわたに関する。DETAILED DESCRIPTION OF THE INVENTION [Industrial Field of Application] The present invention relates to ceramic coated cotton mainly used for futons.
［従来の技術］
従来より、ジルコン（酸化ジルコニウム）また
はチタニア（二酸化チタン）を主成分とした、赤
外線輻射効率の良好なセラミツク微粉を含有した
繊維素材が知られている（特開昭61−12908号公
報）。[Prior Art] Fiber materials containing ceramic fine powder with good infrared radiation efficiency and mainly composed of zircon (zirconium oxide) or titania (titanium dioxide) have been known (Japanese Patent Application Laid-Open No. 12908-1983). Publication No.).
［発明が解決しようとする課題］
しかるに、従来の技術はつぎに示す欠点があつ
た。[Problems to be Solved by the Invention] However, the conventional technology has the following drawbacks.
(1) セラミツク微粉が繊維素材に強固に固着され
ていないので、繊維素材の洗濯によりセラミツ
ク微粉が脱落し易い。(1) Since the ceramic fine powder is not firmly fixed to the textile material, the ceramic fine powder easily falls off when the textile material is washed.
(2) セラミツク微粉を分散させたＯ／Ｗ型エマル
ジヨン染液中に繊維素材を入れ、この繊維素材
を用いて布団わたとしているので重い。(2) Fiber material is placed in an O/W type emulsion dye solution containing fine ceramic powder dispersed, and this fiber material is used to make the futon, so it is heavy.
本発明の目的は、軽くて、洗濯により脱落し難
い特性を有するとともに、熱の吸収量が多く、こ
の吸収した熱を遠赤外線、赤外線として長時間放
出できるセラミツクコーテイングわたの提供、お
よびその製造方法の提供にある。 The object of the present invention is to provide ceramic coated cotton that is light and does not easily come off when washed, absorbs a large amount of heat, and can emit the absorbed heat as far infrared rays and infrared rays for a long period of time, and a method for manufacturing the same. It is provided by.
［課題を解決するための手段］
上記目的を達成するため、本発明はつぎの構成
を採用した。[Means for Solving the Problems] In order to achieve the above object, the present invention employs the following configuration.
(1) セラミツクコーテイングわたは、綿花、化学
繊維、羊毛、絹などのわたの繊維表面に、合成
樹脂を10μ〜100μの厚さでコーテイングし、そ
の上に平均粒径0.1μ〜10μのセラミツク粉末を
混入させた合成樹脂を20μ〜200μの厚さでコー
テイングし、さらにその上に合成樹脂を10μ〜
100μの厚さでコーテイングしてなる。(1) Ceramic coated cotton is made by coating the surface of cotton, chemical fibers, wool, silk, etc. with synthetic resin to a thickness of 10μ to 100μ, and then coating ceramic powder with an average particle size of 0.1μ to 10μ on top. The synthetic resin mixed with
It is coated with a thickness of 100μ.
(2) セラミツクコーテイングわたは、綿花、化学
繊維、羊毛、絹などのわたを可動台の上に載置
し、前記可動台を往移動させながら、わたの上
方に配される第１のノズルから溶融状態の合成
樹脂を吹き付け、わたの繊維表面に厚さ10μ〜
100μの下層を形成し、同様に、前記可動台を
復移動させながら、平均粒径0.1μ〜10μのセラ
ミツク粉末を混入した溶融状態の合成樹脂を、
わたの上方に配される第２のノズルから吹き付
け、前記下層表面に厚さ20μ〜200μの中層を形
成し、さらに、前記可動台を往移動させなが
ら、第１のノズルから溶融状態の合成樹脂の吹
き付け、前記中層表面に厚さ10μ〜100μの上層
を形成して製造される。(2) Ceramic coated cotton is produced by placing cotton, chemical fiber, wool, silk, etc. on a movable table, and while moving the movable table back and forth, a first nozzle placed above the cotton is applied. Spray molten synthetic resin onto the cotton fiber surface to a thickness of 10 μm or more.
A molten synthetic resin mixed with ceramic powder having an average particle size of 0.1 to 10 μ was formed to form a lower layer of 100 μ, and while moving the movable table back and forth,
The synthetic resin is sprayed from a second nozzle placed above the cotton to form a middle layer with a thickness of 20 μm to 200 μm on the surface of the lower layer, and while the movable table is moved back and forth, the synthetic resin in a molten state is sprayed from the first nozzle. is sprayed to form an upper layer with a thickness of 10μ to 100μ on the surface of the middle layer.
［作用および発明の効果］
本発明はつぎに述べる作用および効果を奏す
る。[Actions and Effects of the Invention] The present invention provides the following actions and effects.
（請求項１について）
(1) セラミツクコーテイングわたは、コーテイン
グされるセラミツク粉末により、熱の吸収量が
増大し、この吸収した熱エネルギーが遠赤外
線、赤外線などを熱源として長時間放射され
る。(Regarding Claim 1) (1) Ceramic coated cotton increases the amount of heat absorbed by the coated ceramic powder, and the absorbed thermal energy is radiated for a long time using far infrared rays, infrared rays, etc. as a heat source.
数値限定の理由はつぎの理由による。セラミ
ツク粉末の平均粒径が0.1μ〜10μの範囲のもの
が上記効果を顕著に奏する。セラミツク粉末入
りの中側樹脂厚が0.1μ未満であるとコーテイン
グされるセラミツク粉末量が少なくなり上記効
果が少ない。 The reason for the numerical limitation is as follows. Ceramic powder having an average particle size in the range of 0.1 μm to 10 μm significantly exhibits the above effects. If the thickness of the inner resin containing ceramic powder is less than 0.1 μm, the amount of ceramic powder coated will be small and the above effect will be small.
(2) 合成樹脂の下層、セラミツク粉末を合成樹脂
に混入した中層、合成樹脂の上層の３層コーテ
イングであるため、セラミツク粉末がわたに強
固に固着でき、洗濯などによつても脱落し難
い。(2) Since the coating is made of three layers: a lower layer of synthetic resin, a middle layer of ceramic powder mixed into the synthetic resin, and an upper layer of synthetic resin, the ceramic powder can firmly adhere to the cotton and will not easily fall off even when washed.
(3) わたの繊維の表面のみにセラミツクが存在
し、セラミツク繊維わたのごとく、わたの繊維
全体がセラミツクでないので軽い。(3) Ceramic exists only on the surface of the cotton fibers, and unlike ceramic fiber cotton, the entire cotton fibers are not made of ceramic, so it is light.
数値限定の理由はつぎの理由による。 The reason for the numerical limitation is as follows.
下側、上側の樹脂厚が10μ未満であると、下側
樹脂とわた繊維、および上側樹脂と中側樹脂との
固着性に劣りセラミツク粉末が脱落し易い。 If the thickness of the lower and upper resins is less than 10 μm, the adhesiveness between the lower resin and the cotton fibers, and between the upper resin and the middle resin will be poor, and the ceramic powder will easily fall off.
下側、上側樹脂厚が100μを越えたり、中側樹
脂厚が200μを越えたりすると、樹脂やセラミツ
ク粉末の重さによりわたの重量が増大する。 If the lower and upper resin thicknesses exceed 100μ or the middle resin thickness exceeds 200μ, the weight of the lining increases due to the weight of the resin and ceramic powder.
（請求項２について）
(1) 可動台を１往復半移動するだけでわた繊維に
セラミツク粉末がコーテイングできるのでコー
テイング効率が高く、低コストで製造できる。(Regarding Claim 2) (1) Since the cotton fibers can be coated with ceramic powder by just moving the movable table one and a half times, the coating efficiency is high and manufacturing can be done at low cost.
(2) わたの表面近傍のみ、わた繊維の表面にセラ
ミツク粉末をコーテイングするようにすれば、
セラミツクコーテイングわたの重量の増加はさ
らに少なくて済み、柔らかさも保てる。(2) If the surface of the cotton fibers is coated with ceramic powder only near the surface of the cotton,
Ceramic coated cotton requires less weight increase and maintains its softness.
［実施例］
つぎに、本発明を図に示す一実施例に基づき説
明する。[Example] Next, the present invention will be explained based on an example shown in the drawings.
本実施例の布団（図示せず）は、セラミツクコ
ーテイングわた１を用いている。セラミツクコー
テイングわた１は、わたの繊維２の表面に、アク
リルのコーテイング層（下層）３を設け、その表
面にセラミツク粉末入りのアクリルのコーテイン
グ層（中層）４を成形し、さらにその表面にアク
リルのコーテイング層（上層）５を成形してな
る。 The futon (not shown) of this example uses ceramic coated cotton 1. Ceramic coated cotton 1 has an acrylic coating layer (lower layer) 3 on the surface of cotton fibers 2, an acrylic coating layer (middle layer) 4 containing ceramic powder on the surface, and an acrylic coating layer (middle layer) 4 on the surface. It is formed by molding a coating layer (upper layer) 5.
第３図Ａ，Ｂ，Ｃは、わたにセラミツクコーテ
イングを施す工程を示す。 Figures 3A, B, and C show the process of applying a ceramic coating to cotton.
(A) わた１０を可動台２０上に載置させ、可動台
２０をノズル１１から噴射して、下層のコーテ
イングを施す。(A) The cotton 10 is placed on the movable table 20, and the movable table 20 is sprayed from the nozzle 11 to apply the lower layer coating.
(B) つぎに、同様にして、可動台２０を移動させ
ながら、セラミツク粉末を混入させた溶融アク
リルをノズル１２から噴射して中層のコーテイ
ングを施す。(B) Next, in the same manner, while moving the movable table 20, molten acrylic mixed with ceramic powder is injected from the nozzle 12 to apply a middle layer coating.
(C) さらに、(B)と同様な工程で上層をコーテイン
グする。(C) Furthermore, coat the upper layer using the same process as in (B).
(D) わた１０の表と裏とに、(A)〜(C)の工程を行
う。(D) Perform steps (A) to (C) on the front and back sides of cotton 10.
つぎに実施例の効果を述べる。 Next, the effects of the embodiment will be described.
(1) 布団は日向に干した後に使用する場合、暖か
さの持続時間が長く、かつ人の健康に好影響が
ある。(1) If a futon is used after being dried in the sun, it will stay warm for a longer time and have a positive impact on human health.
(2) セラミツク粉末を溶融アクリルに混入し、わ
た１０に３層コーテイングしているので、セラ
ミツク粉末をわた１０に強固に固着でき、洗濯
などによつてもセラミツク粉末が脱落し難い。(2) Since ceramic powder is mixed into molten acrylic and coated on the cotton 10 in three layers, the ceramic powder can be firmly fixed to the cotton 10 and is difficult to fall off even when washed.
(3) わたの繊維２の表面のみにセラミツク粉末が
存在し、わたの繊維２全体がセラミツクではな
いので、布団は、軽く、かつ保温性、吸湿性も
損なわれない。(3) Ceramic powder exists only on the surface of the cotton fibers 2, and the entire cotton fibers 2 are not made of ceramic, so the futon is light and does not impair heat retention or moisture absorption.
(4) 布団は、セラミツク粉末による消臭効果があ
る。(4) The futon has a deodorizing effect using ceramic powder.
本発明は上記実施例以外につぎの実施態様を含
む。 The present invention includes the following embodiments in addition to the above embodiments.
ａ セラミツク粉末は、赤外線の全波長領域に亘
つて放射率の高いものや遠赤外線選択放射タイ
プのものでつぎに掲げるものが使用できる。二
酸化マンガン（MnO2）、酸化アルミニウム
（Al2O3）、酸化第一コバルト（CoO）、酸化第
二鉄（Fe2O3）、二酸化珪素（SiO2）、酸化マグ
ネシウム（MgO）、これらの混合物。a Ceramic powders that have a high emissivity over the entire infrared wavelength region and those that selectively emit far infrared rays can be used as listed below. Manganese dioxide (MnO 2 ), aluminum oxide (Al 2 O 3 ), cobaltous oxide (CoO), ferric oxide (Fe 2 O 3 ), silicon dioxide (SiO 2 ), magnesium oxide (MgO), these blend.
ｂ 合成樹脂としてアクリルを用い、コーテイン
グ層を上、中、下の３層とし、セラミツク粉末
のわたの繊維２への固着力を増大させている
が、合成樹脂として他のプラスチツクまたはエ
ラストマーが使用できる。b Acrylic is used as the synthetic resin, and the coating layer is made up of three layers: upper, middle, and lower, to increase the adhesion of the ceramic powder to the cotton fibers 2, but other plastics or elastomers can be used as the synthetic resin. .
第１図は本発明にかかるセラミツクコーテイン
グわたの表面部分の拡大断面図、第２図はその繊
維の長手方向の断面図、第３図のＡ，Ｂ，Ｃは、
わたにセラミツクコーテイングを施す工程図であ
る。
図中、１……セラミツクコーテイングわた、２
……わたの繊維、３……アクリルのコーテイング
層（下層）、４……セラミツク粉末入りのアクリ
ルのコーテイング層（中層）、５……アクリルの
コーテイング層（上層）、１０……わた、２０…
…可動台、１１……ノズル（第１のノズル）、１
２……ノズル（第２のノズル）。
Fig. 1 is an enlarged sectional view of the surface portion of the ceramic coated cotton according to the present invention, Fig. 2 is a sectional view in the longitudinal direction of the fibers, and A, B, and C in Fig. 3 are:
It is a process diagram of applying ceramic coating to cotton. In the figure, 1... Ceramic coating cotton, 2
... Cotton fiber, 3 ... Acrylic coating layer (lower layer), 4 ... Acrylic coating layer containing ceramic powder (middle layer), 5 ... Acrylic coating layer (upper layer), 10 ... Cotton, 20 ...
...Movable stand, 11... Nozzle (first nozzle), 1
2... Nozzle (second nozzle).
Claims (1)
表面に、 合成樹脂を10μ〜100μの厚さでコーテイング
し、その上に平均粒径0.1μ〜10μのセラミツク粉
末を混入させた合成樹脂を20μ〜200μの厚さでコ
ーテイングし、さらにその上に合成樹脂を10μ〜
100μの厚さでコーテイングしてなるセラミツク
コーテイングわた。 ２ 綿花、化学繊維、羊毛、絹などのわたを可動
台の上に載置し、 前記可動台を往移動させながら、わたの上方に
配される第１のノズルから溶融状態の合成樹脂を
吹き付け、わたの繊維表面に厚さ10μ〜100μの下
層を形成し、 同様に、前記可動台を復移動させながら、平均
粒径0.1μ〜10μのセラミツク粉末を混入した溶融
状態の合成樹脂を、わたの上方に配される第２の
ノズルから吹き付け、前記下層表面に厚さ20μ〜
200μの中層を形成し、 さらに、前記可動台を往移動させながら、第１
のノズルから溶融状態の合成樹脂の吹き付け、前
記中層表面に厚さ10μ〜100μの上層を形成して なるセラミツクコーテイングわたの製造方法。[Claims] 1. The surface of cotton fibers such as cotton, chemical fibers, wool, silk, etc. is coated with a synthetic resin to a thickness of 10μ to 100μ, and ceramic powder with an average particle size of 0.1μ to 10μ is coated on top. The mixed synthetic resin is coated with a thickness of 20μ to 200μ, and on top of that, the synthetic resin is coated with a thickness of 10μ to 200μ.
Ceramic coated cotton with a 100μ thick coating. 2. Cotton, chemical fibers, wool, silk, etc., are placed on a movable table, and while the movable table is moved back and forth, molten synthetic resin is sprayed from a first nozzle placed above the cotton. , a lower layer with a thickness of 10 μm to 100 μm is formed on the surface of the cotton fibers, and similarly, while moving the movable table back and forth, a molten synthetic resin mixed with ceramic powder with an average particle size of 0.1 μm to 10 μm is applied to the cotton fibers. Spray from a second nozzle placed above to a thickness of 20 μm to the surface of the lower layer.
A middle layer of 200 μm was formed, and while the movable table was moved back and forth, the first
A method for producing ceramic coated cotton comprising spraying a molten synthetic resin from a nozzle, and forming an upper layer with a thickness of 10 to 100 microns on the surface of the middle layer.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP25141387A JPH0197268A (en) | 1987-10-05 | 1987-10-05 | Ceramic coating cotton |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP25141387A JPH0197268A (en) | 1987-10-05 | 1987-10-05 | Ceramic coating cotton |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH0197268A JPH0197268A (en) | 1989-04-14 |
| JPH0561385B2 true JPH0561385B2 (en) | 1993-09-06 |
Family
ID=17222473
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP25141387A Granted JPH0197268A (en) | 1987-10-05 | 1987-10-05 | Ceramic coating cotton |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0197268A (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH01292175A (en) * | 1988-05-14 | 1989-11-24 | Takatome Sangyo Kk | Production of fiber having attached ceramic |
| KR100455862B1 (en) * | 2001-10-19 | 2004-11-08 | 주식회사 기원실업 | Far infrared ray emitting material coated fabrics |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60244535A (en) * | 1984-05-19 | 1985-12-04 | 内外特殊染工株式会社 | Cloth-like article and manufacture thereof |
| JPS6112908A (en) * | 1984-06-28 | 1986-01-21 | Hoton Ceramic Kk | Textile product containing ceramic powder |
-
1987
- 1987-10-05 JP JP25141387A patent/JPH0197268A/en active Granted
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60244535A (en) * | 1984-05-19 | 1985-12-04 | 内外特殊染工株式会社 | Cloth-like article and manufacture thereof |
| JPS6112908A (en) * | 1984-06-28 | 1986-01-21 | Hoton Ceramic Kk | Textile product containing ceramic powder |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0197268A (en) | 1989-04-14 |
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