JPH0561086B2 - - Google Patents

Info

Publication number
JPH0561086B2
JPH0561086B2 JP57181619A JP18161982A JPH0561086B2 JP H0561086 B2 JPH0561086 B2 JP H0561086B2 JP 57181619 A JP57181619 A JP 57181619A JP 18161982 A JP18161982 A JP 18161982A JP H0561086 B2 JPH0561086 B2 JP H0561086B2
Authority
JP
Japan
Prior art keywords
resin
core
layer
surface layer
extrusion path
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
JP57181619A
Other languages
Japanese (ja)
Other versions
JPS5970524A (en
Inventor
Ryuichi Kitagawa
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Panasonic Electric Works Co Ltd
Original Assignee
Matsushita Electric Works Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Matsushita Electric Works Ltd filed Critical Matsushita Electric Works Ltd
Priority to JP57181619A priority Critical patent/JPS5970524A/en
Publication of JPS5970524A publication Critical patent/JPS5970524A/en
Publication of JPH0561086B2 publication Critical patent/JPH0561086B2/ja
Granted legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25Component parts, details or accessories; Auxiliary operations
    • B29C48/30Extrusion nozzles or dies
    • B29C48/32Extrusion nozzles or dies with annular openings, e.g. for forming tubular articles
    • B29C48/335Multiple annular extrusion nozzles in coaxial arrangement, e.g. for making multi-layered tubular articles
    • B29C48/336Multiple annular extrusion nozzles in coaxial arrangement, e.g. for making multi-layered tubular articles the components merging one by one down streams in the die
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/001Combinations of extrusion moulding with other shaping operations
    • B29C48/0013Extrusion moulding in several steps, i.e. components merging outside the die
    • B29C48/0015Extrusion moulding in several steps, i.e. components merging outside the die producing hollow articles having components brought in contact outside the extrusion die
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/001Combinations of extrusion moulding with other shaping operations
    • B29C48/0013Extrusion moulding in several steps, i.e. components merging outside the die
    • B29C48/0015Extrusion moulding in several steps, i.e. components merging outside the die producing hollow articles having components brought in contact outside the extrusion die
    • B29C48/0016Extrusion moulding in several steps, i.e. components merging outside the die producing hollow articles having components brought in contact outside the extrusion die using a plurality of extrusion dies
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/03Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
    • B29C48/09Articles with cross-sections having partially or fully enclosed cavities, e.g. pipes or channels
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/16Articles comprising two or more components, e.g. co-extruded layers
    • B29C48/18Articles comprising two or more components, e.g. co-extruded layers the components being layers
    • B29C48/21Articles comprising two or more components, e.g. co-extruded layers the components being layers the layers being joined at their surfaces
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25Component parts, details or accessories; Auxiliary operations
    • B29C48/30Extrusion nozzles or dies
    • B29C48/32Extrusion nozzles or dies with annular openings, e.g. for forming tubular articles

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Extrusion Moulding Of Plastics Or The Like (AREA)

Description

【発明の詳細な説明】 本発明は芯材の樹脂と表層の樹脂とが異なる二
層樹脂管を押出成形する二層押出成形金型に関す
るものであつて、本発明の目的とするところは異
種の樹脂の二層成形管を簡単に製造でき、しか
も、表層用樹脂層と芯材用樹脂層とを強固に密着
させることのでき、さらに表層用樹脂層の厚さを
自由に調整できる二層押出成形金型を提供するに
ある。
DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a two-layer extrusion mold for extrusion molding a two-layer resin pipe in which the core resin and the surface resin are different. It is possible to easily manufacture a two-layer molded pipe made of resin, and also it is possible to firmly adhere the surface resin layer and the core resin layer, and furthermore, the thickness of the surface resin layer can be freely adjusted. We provide extrusion molds.

以下本発明を実施例により詳述する。1は金型
本体であつて軸芯方向に貫通する空間2を設けて
ある。空間2の後端には芯材用樹脂入口3を設け
てあり、芯材用樹脂入口3にスクリユーから芯材
用樹脂が送り込まれるようになつている。空間2
にはコア4をスパイダー5にて取付けてあり、コ
ア4と空間2との間に芯材用樹脂押出路6を形成
してある。金型本体1の前部外周には断熱空間1
0を介して表層用金型7を取付けてあり、表層用
金型7には周方向に亘つて環状に樹脂溜り部8を
設けてある。表層用金型7の外周の適所には表層
用樹脂入口26を設けてあつて、この表層用樹脂
入口26と樹脂溜り部8とを連通管路9にて連通
せしめてあり、スクリユーから表層用樹脂入口2
6、連通管路9を介して樹脂溜り部8に表層用樹
脂が供給されるようになつている。樹脂溜り部8
より前内周方向に向けて薄肉筒状の表層用樹脂押
出路11を設けてあり、表層用樹脂押出路11の
途中に副樹脂溜り部12を設けてある。表層用樹
脂押出路11の外周側には表層用樹脂押出路11
の出口14の間隔を調整し得る断面三角状の可撓
片11aを設けてあり、表層用金型7の前面から
螺入した複数本の調整ねじ13の先端を可撓片1
1aに当接してあり、調整ねじ13の螺入量を変
えることにより可撓片11aを撓ませて表層用樹
脂押出路11の出口14の間隔を調整し得るよう
になつている。ここで15は温度コントロールす
るためのオイルのような熱媒体を通す熱媒体通路
である。16は金型本体1に設けた真空引き路で
あつて、一端が表層用樹脂押出路11の出口14
と芯材用樹脂押出路6の出口17との間に開口し
ており、真空引き路16の他端を真空ポンプに連
通せしめてある。表層用金型7の前端より前方に
支持バー18を突設してあり、支持バー18の前
端には支持プレート19を装着してある。この支
持プレート19と表層用金型7との間には中央に
密着用孔24を有する密着プレート20を配設し
てあり、密着プレート20の外周に設けたスライ
ド孔21を支持バー18にスライド自在に被挿し
てある。支持バー18には雄ねじ23を螺刻して
あつて、支持プレート19と密着プレート20と
の間で上記雄ねじ23に密着プレート調整ナツト
26を螺入してあり、密着プレート調整ナツト2
5を螺動させることにより密着プレート20と表
層用樹脂押出路11の出口14との間隔を調整し
得るようになつている。密着プレート20の前方
にはアウトサイジングダイ27を配設してある。
The present invention will be explained in detail below with reference to Examples. Reference numeral 1 denotes a mold body, which is provided with a space 2 passing through it in the axial direction. A core resin inlet 3 is provided at the rear end of the space 2, and the core resin is fed into the core resin inlet 3 from a screw. space 2
A core 4 is attached to the core 4 by a spider 5, and a core resin extrusion path 6 is formed between the core 4 and the space 2. A heat insulating space 1 is provided on the front outer periphery of the mold body 1.
A surface layer mold 7 is attached to the surface layer mold 7 through a hole 0, and a resin reservoir portion 8 is provided in an annular shape in the circumferential direction of the surface layer mold 7. A surface layer resin inlet 26 is provided at a suitable location on the outer periphery of the surface layer mold 7, and the surface layer resin inlet 26 and the resin reservoir 8 are communicated through a communication pipe 9. Resin inlet 2
6. Surface layer resin is supplied to the resin reservoir 8 via the communication pipe 9. Resin reservoir part 8
A thin-walled cylindrical surface layer resin extrusion path 11 is provided toward the front inner circumferential direction, and an auxiliary resin reservoir portion 12 is provided in the middle of the surface layer resin extrusion path 11. On the outer peripheral side of the resin extrusion path 11 for the surface layer, there is a resin extrusion path 11 for the surface layer.
A flexible piece 11a having a triangular cross section is provided to adjust the interval between the outlets 14 of the surface layer mold 7.
1a, and by changing the screwing amount of the adjusting screw 13, the flexible piece 11a can be bent to adjust the interval between the outlets 14 of the surface resin extrusion path 11. Here, 15 is a heat medium passage through which a heat medium such as oil is passed for temperature control. Reference numeral 16 denotes a vacuum passage provided in the mold body 1, one end of which is connected to the outlet 14 of the surface layer resin extrusion passage 11.
and the outlet 17 of the core resin extrusion path 6, and the other end of the vacuum path 16 is communicated with a vacuum pump. A support bar 18 is provided protruding forward from the front end of the surface layer mold 7, and a support plate 19 is attached to the front end of the support bar 18. A contact plate 20 having a contact hole 24 in the center is disposed between the support plate 19 and the surface layer mold 7, and the support bar 18 can be slid through a slide hole 21 provided on the outer periphery of the contact plate 20. It can be inserted freely. The support bar 18 is provided with a male thread 23, and a contact plate adjustment nut 26 is screwed into the male screw 23 between the support plate 19 and the contact plate 20.
By screwing 5, the distance between the contact plate 20 and the outlet 14 of the surface resin extrusion path 11 can be adjusted. An outsizing die 27 is arranged in front of the contact plate 20.

次に上述の如く構成せる二層押出成形金型の動
作を説明する。芯材用樹脂入口3からポリ塩化ビ
ニルのような芯材用樹脂を供給すると芯材用樹脂
押出路6を介して出口17から筒状に押出され、
密着プレート20の密着孔24に至る。この際芯
材用樹脂入口3からの芯材用樹脂の供給圧力及び
供給量を変えると出口17から押出される速度が
変わる。一方表層用樹脂入口26からアクリル、
AAS樹脂等の表層用樹脂が供給されると、表層
用樹脂押出路11を介し、出口14から筒状に押
出されて密着プレート20の密着用孔24に至
り、筒状の表層用樹脂層が筒状の芯材用樹脂層の
外面に密着せられ、二層樹脂管が形成され、アウ
トサイジングダイ27でサイジングされて製品と
なる。表層用樹脂層を芯材用樹脂層に密着させる
際真空引き路16を介して真空引きすることより
間に空気が入いらないように密着させることがで
きる。上記のように押出成形している途中に表層
用樹脂層の肉厚を変えたい場合は密着プレート2
0を密着プレート調整ナツト25にて前後させて
微調整する。この際密着プレート20を前方へ離
すと表層用樹脂層が薄くなる。つまり表層用樹脂
押出路11の押出方向の延長線上(第1図想像
線)上に密着プレート20の密着用孔24がある
と出口14で表層用樹脂層が屈曲せず内厚が最も
厚く、延長線上より前方に位置するに従つて実質
的に出口面積が徐々に小さくなつて肉厚が薄くな
る。また押出成形途中でないときに大きく表層用
樹脂層の厚さを変えるに当つては、調整ねじ13
を調整して出口14間隔を調整することによりで
きる。さらに表層用樹脂の圧力及び供給量を一定
にしておいた状態で芯材用樹脂の押出速度を変え
ると表層用樹脂層の延伸量を変えても表層用樹脂
層の厚さを変えることができる。また表層用金型
7において、樹脂溜り部8と副樹脂溜り部12と
を設けてあるので表層用樹脂の圧力を均一化して
薄肉の押出を安定させることができる。さらに熱
媒体通路15に熱媒体を通すのは芯材用樹脂と表
層用樹脂との温度が異なるため相互の影響を少な
くして各々の樹脂を所定の温度に保つためであ
る。例えば芯材用樹脂がポリ塩化ビニルの場合、
約190℃で、表層用樹脂がアクリル樹脂の場合、
約220℃で表層用樹脂を熱媒体にて高温に保つ。
Next, the operation of the two-layer extrusion mold constructed as described above will be explained. When a core resin such as polyvinyl chloride is supplied from the core resin inlet 3, it is extruded into a cylindrical shape from the outlet 17 through the core resin extrusion path 6.
The contact hole 24 of the contact plate 20 is reached. At this time, if the supply pressure and amount of the core resin from the core resin inlet 3 are changed, the speed at which the core resin is extruded from the outlet 17 will be changed. On the other hand, from the resin inlet 26 for the surface layer, acrylic,
When the surface resin such as AAS resin is supplied, it is extruded into a cylindrical shape from the outlet 14 through the surface resin extrusion path 11 and reaches the adhesion hole 24 of the adhesion plate 20, and the cylindrical surface resin layer is formed. It is brought into close contact with the outer surface of the cylindrical core material resin layer to form a two-layer resin tube, which is sized with an outsizing die 27 to become a product. When the resin layer for the surface layer is brought into close contact with the resin layer for the core material, by evacuating the resin layer through the vacuum passage 16, it is possible to bring the resin layer for the surface layer into close contact with the resin layer for the core material without allowing air to enter between them. If you want to change the thickness of the surface resin layer during extrusion molding as described above, contact plate 2
0 by moving it back and forth using the contact plate adjustment nut 25. At this time, when the contact plate 20 is moved forward, the surface resin layer becomes thinner. In other words, if the adhesion hole 24 of the adhesion plate 20 is located on the extension line of the extrusion direction of the surface resin extrusion path 11 (imaginary line in FIG. 1), the surface resin layer will not bend at the outlet 14 and the inner thickness will be the thickest. Substantially, the outlet area gradually decreases and the wall thickness becomes thinner as the outlet is located further forward than the extension line. In addition, when changing the thickness of the surface resin layer significantly when extrusion is not in progress, use the adjustment screw 13.
This can be done by adjusting the distance between the outlets 14 by adjusting the distance between the outlets 14. Furthermore, by changing the extrusion speed of the core resin while keeping the pressure and supply amount of the surface resin constant, the thickness of the surface resin layer can be changed even if the stretching amount of the surface resin layer is changed. . Furthermore, since the surface layer mold 7 is provided with a resin reservoir 8 and an auxiliary resin reservoir 12, the pressure of the surface layer resin can be made uniform and thin extrusion can be stabilized. Furthermore, the reason why the heat medium is passed through the heat medium passage 15 is to reduce the mutual influence between the core material resin and the surface layer resin, since their temperatures are different, and to maintain each resin at a predetermined temperature. For example, if the core resin is polyvinyl chloride,
At approximately 190℃, if the surface resin is acrylic resin,
The surface resin is kept at a high temperature of approximately 220℃ using a heat medium.

本発明は叙述の如く芯材用樹脂を筒状に押出す
筒状の芯材用樹脂押出路と、この芯材用樹脂押出
路の外周に同芯状に設けられて表層用樹脂を上記
筒状の芯材用樹脂の外周に筒状に押出す表層用樹
脂押出路とを有するもので、芯材用樹脂押出路よ
り筒状の芯材用樹脂層を押出すと共に表層用樹脂
押出路にて筒状の表層用樹脂層を押出して芯材用
樹脂層を被覆できるものであつて、異種の二層樹
脂管を簡単に製造できるものであり、しかも芯材
用樹脂押出路や表層用樹脂押出路の出口の前方に
密着プレートを配設し、表層用樹脂が内面に摺接
することにより芯材用樹脂の外周面に表層用樹脂
を密着させるための密着用孔を密着プレートに芯
材用樹脂押出路の出口に対向するようにこの出口
と略同じ径に穿孔したので、密着プレートの密着
用孔に芯材用樹脂層と表層用樹脂層を通すことに
より密着用孔への摺接にて芯材用樹脂層の外周面
に表層用樹脂層を密着させることができるもので
あつて、芯材用樹脂層と表層用樹脂層とを強固に
密着させることができるものであり、また密着用
孔を有する密着プレートを前後に移動自在に配設
したので、密着プレートを前後させることにより
芯材用樹脂層に表層用樹脂層が密着する位置を前
後に変えて表層用樹脂層の厚さを自由に変えるこ
とができるものであり、さらに表層用樹脂押出路
の出口に出口の間隔を調整するために調整ねじを
設けたので、調整ねじにて表層用樹脂押出路の出
口の間隔を調整することにより表層用樹脂を押出
す厚さを調整することができるものである。
As described above, the present invention includes a cylindrical core resin extrusion path for extruding core resin into a cylindrical shape, and a cylindrical core resin extrusion path provided concentrically on the outer periphery of the core resin extrusion path to extrude surface layer resin into the cylinder. It has a surface layer resin extrusion path that extrudes a cylindrical core resin layer on the outer periphery of the core resin extrusion path. It can be used to extrude a cylindrical surface resin layer and cover it with a core resin layer, and it is easy to manufacture two-layered resin pipes of different types. An adhesion plate is provided in front of the exit of the extrusion path, and adhesion holes are provided in the adhesion plate to allow the surface resin to adhere to the outer peripheral surface of the core resin by sliding the surface resin on the inner surface. Since a hole was made to face the outlet of the resin extrusion path and have approximately the same diameter as this outlet, the core resin layer and the surface resin layer could be passed through the adhesive hole of the adhesive plate to make sliding contact with the adhesive hole. The resin layer for the surface layer can be brought into close contact with the outer peripheral surface of the resin layer for the core material, and the resin layer for the core material and the resin layer for the surface layer can be brought into close contact with each other. Since the adhesion plate with holes is movable back and forth, by moving the adhesion plate back and forth, the position where the surface resin layer adheres to the core resin layer can be changed back and forth, and the thickness of the surface resin layer can be adjusted. can be changed freely, and an adjustment screw is provided at the exit of the surface resin extrusion path to adjust the exit interval, so the adjustment screw can be used to adjust the interval between the exits of the surface resin extrusion path. By doing so, the thickness of the extruded resin for the surface layer can be adjusted.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図は本発明の一実施例の断面図、第2図は
同上の表層用樹脂押出路部分の拡大断面図であつ
て、6は芯材用樹脂押出路、11は表層用樹脂押
出路、20は密着プレート、24は密着用孔であ
る。
FIG. 1 is a cross-sectional view of an embodiment of the present invention, and FIG. 2 is an enlarged cross-sectional view of the same resin extrusion path for the surface layer, in which 6 is the resin extrusion path for the core material, and 11 is the resin extrusion path for the surface layer. , 20 is an adhesion plate, and 24 is an adhesion hole.

Claims (1)

【特許請求の範囲】[Claims] 1 芯材用樹脂を筒状に押出す筒状の芯材用樹脂
押出路と、この芯材用樹脂押出路の外周に同芯状
に設けられて表層用樹脂を上記筒状の芯材用樹脂
の外周で筒状に押出す表層用樹脂押出路と、表層
用樹脂押出路の出口に出口の間隔を調整するため
に設けられた調整ねじと、芯材用樹脂押出路や表
層用樹脂押出路の出口の前方に前後動自在に配設
された密着プレートと、密着プレートに上記芯材
用樹脂押出路の出口と対向するようにこの出口の
径と略同じ径に穿孔されて表層用樹脂が内面に摺
接することにより芯材用樹脂の外周面に表層用樹
脂を密着させるための密着用孔とを具備すること
を特徴とする二層押出成形金型。
1 A cylindrical core resin extrusion path for extruding the core resin into a cylindrical shape, and a cylindrical core resin extrusion path provided concentrically on the outer periphery of this core resin extrusion path to extrude the surface layer resin into the cylindrical core material. A resin extrusion path for the surface layer that extrudes the resin in a cylindrical shape around the outer periphery, an adjustment screw provided at the outlet of the resin extrusion path for the surface layer to adjust the interval between the exits, and a resin extrusion path for the core material and a resin extrusion path for the surface layer. A close contact plate is disposed in front of the outlet of the channel so as to be movable back and forth, and a hole is bored in the close plate to face the outlet of the core resin extrusion channel and have a diameter substantially the same as that of the outlet. 1. A two-layer extrusion mold, characterized in that it is provided with an adhesion hole for bringing a surface layer resin into close contact with an outer circumferential surface of a core resin by slidingly contacting the inner surface of the mold.
JP57181619A 1982-10-15 1982-10-15 Two layer extrusion forming metal mold Granted JPS5970524A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP57181619A JPS5970524A (en) 1982-10-15 1982-10-15 Two layer extrusion forming metal mold

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP57181619A JPS5970524A (en) 1982-10-15 1982-10-15 Two layer extrusion forming metal mold

Publications (2)

Publication Number Publication Date
JPS5970524A JPS5970524A (en) 1984-04-21
JPH0561086B2 true JPH0561086B2 (en) 1993-09-03

Family

ID=16103957

Family Applications (1)

Application Number Title Priority Date Filing Date
JP57181619A Granted JPS5970524A (en) 1982-10-15 1982-10-15 Two layer extrusion forming metal mold

Country Status (1)

Country Link
JP (1) JPS5970524A (en)

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS4947265A (en) * 1972-04-24 1974-05-07

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS4947265A (en) * 1972-04-24 1974-05-07

Also Published As

Publication number Publication date
JPS5970524A (en) 1984-04-21

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