JPH0553241A - Silver halide photographic sensitive material - Google Patents

Abstract

PURPOSE:To facilitate decoloring and/or eluting by forming a hydrophilic colloidal layer contg. a specified compd. as an oil compsn. and/or a polymer latex compsn. CONSTITUTION:A hydrophilic colloidal layer contg. at least one kind of compd. represented by the formula as an oil compsn. and/or a polymer latex compsn. is formed. In the formula, R<21> is alkyl, aryl, -COOR<27>, -COR<27>, -CONR<27>R<28>, -CN, -OR<27>, -NR<27>R<28> or -N(R<27>)COR<28>, R<22> is alkyl, phenyl, substd. phenyl or a heterocyclic group, each of R<23>-R<25> is H, alkyl or aryl, R<26> is H, alkyl, phenyl, substd. phenyl or amino, each of R<27> and R<28> is H, alkyl or aryl and R<29> is alkyl or aryl.

Description

Detailed Description of the Invention

[0001]

FIELD OF THE INVENTION The present invention relates to a silver halide photographic light-sensitive material having a dyed layer, and a hydrophilic material containing a dye which is photochemically inert and is easily decolorized and / or eluted by photographic processing. The present invention relates to a silver halide photographic light-sensitive material having a photosensitive colloid layer.

[0002]

2. Description of the Related Art In a silver halide photographic light-sensitive material, a photographic emulsion layer and other hydrophilic colloid layers are often colored for the purpose of absorbing light in a specific wavelength range. When it is necessary to control the spectral composition of light to be incident on the photographic emulsion layer, a coloring layer is usually provided on the side farther from the support than the photographic emulsion layer. Such a colored layer is called a filter layer. When there are multiple photographic emulsion layers, the filter layer may be located between them.

Light scattered during or after passing through the photographic emulsion layer is reflected on the interface between the emulsion layer and the support or on the surface of the light-sensitive material on the side opposite to the emulsion layer and re-enters the photographic emulsion layer. A coloring layer called an antihalation layer is provided between the photographic emulsion layer and the support or on the surface of the support opposite to the photographic emulsion layer for the purpose of preventing blurring or halation of an image based on the image. When there are a plurality of photographic emulsion layers, an antihalation layer may be placed between those layers. Coloring of the photographic emulsion layer is also carried out in order to prevent a reduction in image sharpness due to light scattering in the photographic emulsion layer (this phenomenon is generally called irradiation).

These hydrophilic colloid layers to be colored usually contain a dye. This dye needs to satisfy the following conditions. (1) It has a proper spectral absorption according to the purpose of use. (2) Photochemically inert. That is, it should not adversely affect the performance of the silver halide photographic emulsion layer in a chemical sense, such as a reduction in sensitivity, latent image regression, or fog. (3) It should not be decolorized during photographic processing or be dissolved in the processing solution or washing water to leave no harmful coloring on the photographic light-sensitive material after processing. (4) Do not diffuse from the dyed layer to other layers. (5) Excellent stability over time in solution or photographic material, and not discoloration or fading.

Particularly when the colored layer is a filter layer,
Alternatively, in the case of an antihalation layer placed on the same side as the photographic emulsion layer of the support, those layers are selectively colored so that the other layers are not substantially colored. Often needed. This is because otherwise, not only the harmful spectroscopic effect on other layers is exerted, but also the effect as a filter layer or an antihalation layer is eliminated. However, when the dye-added layer and other hydrophilic colloid layers come into contact with each other in a wet state,
It often happens that some of the dye diffuses from the former to the latter. Many efforts have been made to prevent the diffusion of such dyes.

For example, a method in which a hydrophilic polymer having a charge opposite to that of a dissociated anionic dye is allowed to coexist in a layer as a mordant and the dye is localized in a specific layer by interaction with a dye molecule is described in US Pat. , 548,564, 4,124,386, 3,625,694 and the like.

Further, a method of dyeing a specific layer with a water-insoluble dye solid is disclosed in JP-A-56-12639 and JP-A-5-12639.
5-155350, 55-155351, 63
No. 27838, No. 63-197943, European Patent No. 15,601, No. 274,723, No. 276,56.
6, U.S. Pat. No. 4,803,15.
No. 0, World Patent No. WO88 / 04794 and the like. The compounds described in Japanese Patent Application No. 1-307363 are hardly soluble in oil and difficult to disperse, or do not discolor even when dissolved in oil. In addition, a method of dyeing a specific layer using fine particles of a metal salt having a dye adsorbed thereon is disclosed in US Pat.
9,088, 2,496,841, 2,49
No. 6,843, JP-A-60-45237 and the like.

However, when these improved methods are used, the decolorization and / or the elution rate of the dye during the development processing is slow, so that the processing is accelerated, the processing solution composition is improved, or the photographic emulsion composition is improved. When various factors were changed, it was difficult to eliminate the residual color contamination due to the dye.

Various water-soluble monomethine merocyanine dyes having a sulfo group, a salt of a sulfo group, a salt of a carboxy group or the like as a substituent are also known (JP-A 2-1).
65135, Japanese Patent Laid-Open No. 1-196041, Japanese Patent Laid-Open No. 1-19
6040, JP-A-62-242933, JP-A-55-9
6941, U.S. Pat. No. 3,627,532) and the like, they diffuse to other layers and it is difficult to selectively dye only a specific layer.

[0010]

SUMMARY OF THE INVENTION Therefore, an object of the present invention is to selectively dye only a specific layer in a photographic light-sensitive material, and to remove a dye which is rapidly decolorized and / or eluted during development processing as an oil or polymer latex. To provide a photographic light-sensitive material containing as a composition.

[0011]

As a result of various investigations by the present inventors, the object of the present invention was achieved by a silver halide photographic light-sensitive material containing at least one compound represented by the following general formula (1). I found that. General formula (1)
A silver halide photographic light-sensitive material having a hydrophilic colloid layer containing at least one compound represented by the formula (1) as an oil composition and / or a polymer latex composition is preferable.

[0012]

[Chemical 2]

In the formula, R ²¹ is an alkyl group, an aryl group, or -C
^{OOR 27, -COR 27, -CONR 27} R 28, -CN, -
Represents OR ²⁷ , -NR ²⁷ R ²⁸ , -N (R ²⁷ ) COR ²⁸ ,
R ²² is an alkyl group, a phenyl group, or a substituted phenyl group (substituents are —CONHSO ₂ R ₂₉ , —SO ₂ NHCOR ₂₉ , —
CONHCOR ₂₉ , a halogen atom, or -COOR
₂₉ ) or a heterocyclic group, R ²³ , R ²⁴ and R ^{25 each} represent a hydrogen atom, an alkyl group or an aryl group, and R ²⁴ and R ²⁵ are 6
You may form a member ring. R ²⁶ is a hydrogen atom, an alkyl group,
Phenyl group, substituted phenyl group (substituent is -CONHSO
_{2 R 29, -SO 2 NHCOR 29} , -CONHCOR 29,
Halogen atom, -COOR ₂₉ , OR ₂₉ or OH),
Or an amino group, R ²⁷ and R ²⁸ each represent a hydrogen atom, an alkyl group or an aryl group, and R ²⁹ represents an alkyl group or an aryl group. However, the compound represented by the general formula (1) must not have a sulfo group, a salt of a sulfo group, a carboxy group, or a salt of a carboxy group as a substituent.

When the dye used in the present invention is used as an oil composition and / or a polymer latex composition, the dye may be a sulfonic acid, a sulfonic acid salt, or a sulfonic acid salt as a substituent.
It is preferably free of carboxylic acid salts, and organic solvents having a boiling point of about 30 ° C. to about 150 ° C., for example, lower alkyl acetates such as ethyl acetate and butyl acetate, ethyl propionate, secondary butyl alcohol, methyl isobutyl. It is preferable to have a high solubility in ketones, β-ethoxyethyl acetate, methyl cellosolve acetate, and water-soluble solvents such as alcohols such as methanol and ethanol.

Next, the compound of the general formula (1) used in the present invention will be explained in detail. The alkyl group represented by R ²¹ may have a substituent, and is preferably an alkyl group having 1 to 8 carbon atoms, such as methyl, ethyl, propyl and
Butyl, normal butyl, 1-methylcyclopropyl,
Chloromethyl, trifluoromethyl, ethoxycarbonylmethyl and the like are preferable.

The aryl group represented by R ²¹ may have a substituent and is preferably an aryl group having 6 to 13 carbon atoms, for example, phenyl, 4-methoxyphenyl, 4-acetylaminophenyl, 4-methane. Sulfonamidophenyl and 4-benzenesulfonamidophenyl are preferred.

The alkyl group represented by R ²² may have a substituent and is preferably an alkyl group having 1 to 18 carbon atoms, such as methyl, 2-cyanoethyl, 2-hydroxyethyl, 2-acetoxyethyl and the like. preferable.

The phenyl group or substituted phenyl group represented by R ²² is preferably a phenyl group having 6 to 22 carbon atoms, for example, phenyl, 2-methoxy-5-ethoxycarbonylphenyl, 3,5-di (ethoxycarbonyl) phenyl,
4-di (ethoxycarbonylmethyl) aminocarbonylphenyl, 4-normaloctyloxycarbonylphenyl, 4-butanesulfonamidocarbonylphenyl,
4-methanesulfonamidocarbonylphenyl, 3-sulfamoylphenyl, 4-methanesulfonamidophenyl, 4-methanesulfonamidosulfonylphenyl,
4-Acetylsulfamoylphenyl, 4-propionylsulfamoylphenyl, 4-N-ethylcarbamoylsulfamoylphenyl and the like are preferable.

The heterocyclic group represented by R ²² is pyridyl, 4-hydroxy-6-methylpyrimidin-2-yl, 4-hydroxy-6-tert-butylpyrimidin-2-.
And sulfolan-3-yl.

The alkyl group represented by R ²³ , R ²⁴ and R ²⁵ is preferably an alkyl group having 1 to 6 carbon atoms, for example, methyl, ethyl or propyl. A methyl group is particularly preferable.

The aryl group represented by R ²³ , R ²⁴ and R ²⁵ is preferably an aryl group having 6 to 13 carbon atoms, and particularly preferably a phenyl group. The 6-membered ring formed by R ²⁴ and R ²⁵ may be saturated, unsaturated or heterocyclic, but a benzene ring is particularly preferable.

The alkyl group represented by R ²⁶ may have a substituent, and is preferably an alkyl group having 1 to 18 carbon atoms,
For example, methyl, ethyl, ethoxycarbonylmethyl, tert-butoxycarbonylmethyl, ethoxycarbonylethyl, dimethylaminomethyl, 2-cyanoethyl, 3-acetamidopropyl, 3-propionylaminopropyl, 3-benzenesulfonamidopropyl, 3-propanesulfonamido. Propyl and the like are preferred.

The phenyl group or substituted phenyl group represented by R ²⁶ is preferably a phenyl group having 6 to 22 carbon atoms, for example, phenyl, 2-methoxy-5-ethoxycarbonylphenyl, 4-di (ethoxycarbonylmethyl) aminocarbonylphenyl. , 4-normaloctyloxycarbonylphenyl, 4-hydroxyethoxycarbonylphenyl, 4-propanesulfonamidophenyl, 4-butanesulfonamidocarbonylphenyl, 4-methanesulfonamidocarbonylphenyl, 4-acetylsulfamoylphenyl are preferred.

The amino group represented by R ²⁶ is preferably a dialkylamino group, for example, dimethylamino and diethylamino.

The alkyl group represented by R ²⁷ , R ²⁸ and R ²⁹ may have a substituent, and is preferably an alkyl group having 1 to 12 carbon atoms, such as methyl, ethyl, octyl, dodecyl, cyclohexyl and ethoxy. Carbonylmethyl, ethoxycarbonylethyl, 2-hydroxyethyl, 2-ethoxyethyl, 2-methanesulfonamidoethyl, cyanoethyl, 2,2,3,3-tetrafluoropropyl,
Chloroethyl, bromoethyl, acetoxyethyl, dimethylaminoethyl and the like are preferable.

The aryl group represented by R ²⁷ , R ²⁸ and R ²⁹ may have a substituent and is preferably an aryl group having 6 to 12 carbon atoms, such as phenyl, 4-methoxyphenyl,
3-methylphenyl is preferred.

However, the compound represented by the general formula (1) must not have a sulfo group, a salt of a sulfo group, a carboxy group, or a salt of a carboxy group as a substituent.

The compound represented by the general formula (1) preferably has a dissociative group other than the above. Preferred dissociative substituted sulfonylamino groups as examples of the group (e.g., _{CH 3 SO 2 NH-, H 5} C 6 -SO 2 NH-), acyl sulfamoyl group, acylsulfamoyl group, a sulfonylcarbamoyl group, Karubamoirusuru There is a famoyl group.

Specific examples of the compound represented by the general formula (1) are shown below, but the invention is not limited thereto.

[0030]

[Chemical 3]

[0031]

[Chemical 4]

[0032]

[Chemical 5]

[0033]

[Chemical 6]

[0034]

[Chemical 7]

[0035]

[Chemical 8]

[0036]

[Chemical 9]

[0037]

[Chemical 10]

[0038]

[Chemical 11]

[0039]

[Chemical formula 12]

[0040]

[Chemical 13]

[0041]

[Chemical 14]

[0042]

[Chemical 15]

[0043]

[Chemical 16]

[0044]

[Chemical 17]

[0045]

[Chemical 18]

[0046]

[Chemical 19]

[0047]

[Chemical 20]

[0048]

[Chemical 21]

[0049]

[Chemical formula 22]

[0050]

[Chemical formula 23]

[0051]

[Chemical formula 24]

[0052]

[Chemical 25]

[0053]

[Chemical formula 26]

[0054]

[Chemical 27]

[0055]

[Chemical 28]

[0056]

[Chemical 29]

[0057]

[Chemical 30]

[0058]

[Chemical 31]

[0059]

[Chemical 32]

[0060]

[Chemical 33]

[0061]

[Chemical 34]

[0062]

[Chemical 35]

[0063]

[Chemical 36]

[0064]

[Chemical 37]

[0065]

[Chemical 38]

[0066]

[Chemical Formula 39]

[0067]

[Chemical 40]

The compound represented by the general formula (1) is disclosed in
-165135, JP-A-1-196041, JP-A-1-
196040, JP-A-62-242933, JP-A-55.
It is possible to synthesize it by the method described in US Pat.

For example, pyrazolone represented by the general formula (2) and the aldehyde represented by the general formula (3) in an organic solvent (eg, methanol, ethanol, isopropanol, acetonitrile, DMF, pyridine, acetic acid, acetic anhydride) at room temperature. It can be synthesized by mixing under reflux conditions. At this time, a catalyst (for example, piperidine, glycine, β-alanine, p-toluenesulfonic acid, ammonium acetate, triethylamine) may be added.

[0070]

[Chemical 41]

[0071]

[Chemical 42]

A synthesis example is shown below. Synthesis example of compound D-15

To a mixture of 3-ethoxycarbonyl-1- (4-sulfophenyl) pyrazolone sodium salt (33.4 g), triethylamine (11.1 g) and DMF (200 ml) was added dropwise benzoyl chloride (15.5 g) under ice-cooling.
Stir at room temperature for hours. Acetone was added, and the precipitated crystals were collected by filtration and dried to obtain 36.5 g of 5-benzoyloxy-3-ethoxycarbonyl-1- (4-sulfophenyl) -virazole triethylamine salt.

36.5 g of the protected pyrazolone obtained above
22.1 g of phosphorus oxychloride was added to a mixture of 10 ml of acetonitrile with 108 ml of ice-cooling, 43 ml of N, N-dimethylacetamide was further added, and the mixture was stirred at room temperature for 2 hours. The reaction mixture was poured into 300 g of ice water, and the precipitated crystals were collected by filtration and dried to obtain 18.5 g of 5-benzoyloxy-3-ethoxycarbonyl-1- (4-chlorosulfonylphenyl) pyrazole.

0.6 g of sodium hydride (60%),
0.4 g of acetamide was slowly added to a mixture of 5 ml of N, N-dimethylacetamide under ice cooling. Sulfonyl chloride 2.2 as described above under ice cooling to the above mixture
g and 5 ml of N, N-dimethylacetamide were added, and the mixture was stirred at room temperature for 1 hour. 10 ml of ethanol was added to the above reaction mixture, heated under reflux for 2 hours, and then poured into dilute hydrochloric acid. It was extracted with ethyl acetate, dried and concentrated to give 3-ethoxycarbonyl-1- (4-acetylaminosulfonylphenyl) pyrazolone.

A mixture of the pyrazolone, 4.1 g of 1- (4-ethoxycarbonylphenyl) -3-formyl-2,5-dimethylpyrrole and 30 ml of ethanol was heated and stirred for 4 hours. The reaction mixture was diluted with ethyl acetate, washed with brine, dried and concentrated. The crude product was purified by column chromatography and recrystallized from isopropanol to obtain 0.6 g of compound D-15 λmax 436.
nm (AcOEt).

When the compound of the general formula (1) is used as a filter dye or an antihalation dye, any effective amount can be used, but the optical density should be in the range of 0.05 to 3.5. Preference is given to using.
The time of addition may be any step before coating.

The compound of the general formula (1) according to the present invention can be used in any of the emulsion layer and other hydrophilic colloid layers.

The oil of the dye and / or the polymer latex composition used in the present invention can be dispersed by the following method.

A method in which a compound is dissolved in an oil, that is, a liquid having a high boiling point having a boiling point of about 160 ° C. or more and which is substantially insoluble in water, is added to a hydrophilic colloid solution and dispersed. Examples of the high boiling point solvent include, for example, phthalic acid alkyl esters (dibutyl phthalate, dioctyl phthalate, etc.), phosphoric acid esters (diphenyl phosphate, triphenyl phosphate) as described in US Pat. No. 2,322,027. , Tricresyl phosphate, dioctyl butyl phosphate), citric acid ester (eg acetyl citrate tributyl), benzoic acid ester (eg octyl benzoate), alkylamide (eg diethyllaurylamide), fatty acid ester (eg dibutoxy) Ethyl succinate, diethyl azelate), trimesic acid esters (for example, tributyl trimesic acid) and the like can be used. Also, the boiling point is about 30 ℃
To an organic solvent of about 150 ° C., for example, a lower alkyl acetate such as ethyl acetate or butyl acetate, ethyl propionate, secondary butyl alcohol, methyl isobutyl ketone, β-ethoxyethyl acetate, methyl cellosolve acetate or a solvent which is easily dissolved in water, For example, alcohol such as methanol or ethanol can be used.

Here, the use ratio of the dye and the high boiling point solvent is preferably 10 to 1/10 (weight ratio).

A method of incorporating the dye and other additives of the present invention as a polymer latex composition for filling a photographic emulsion layer and other hydrophilic colloid layers. Examples of the polymer latex include polyurethane polymers and polymers polymerized from vinyl monomers [suitable vinyl monomers include acrylic acid esters (methyl acrylate, ethyl acrylate, butyl acrylate, hexyl acrylate, octyl acrylate, dodecyl acrylate, glycidyl acrylate, etc.). , Α-substituted acrylate (methyl methacrylate, butyl methacrylate, octyl methacrylate, glycidyl methacrylate, etc.), acrylamide (butyl acrylamide, hexyl acrylamide, etc.), α-substituted acrylamide (butyl methacrylamide, dibutyl methacrylamide, etc.), vinyl ester ( Vinyl acetate, vinyl butyrate, etc.),
Vinyl halides (vinyl chloride, etc.), vinylidene halides (vinylidene chloride, etc.), vinyl ethers (vinyl methyl ether, vinyl octyl ether, etc.), styrene, X-substituted styrenes (α-methylstyrene, etc.), nuclear-substituted styrenes (hydroxy). Styrene, chlorostyrene, methylstyrene, etc.), ethylene, propylene, butylene,
Examples thereof include butadiene and acrylonitrile. These may be used alone or in combination of two or more,
Other vinyl monomers may be mixed as a minor component. Other vinyl monomers include itaconic acid, acrylic acid, methacrylic acid, hydroxyalkyl acrylate, hydroxyalkyl methacrylate, sulfoalkyl acrylate, sulfoalkyl methacrylate, styrene sulfonic acid, and the like. ] Etc. can be used.

These filled polymer latexes are disclosed in JP-B-51-39853, JP-A-51-59943 and JP-A-51-59943.
No. 3-137131, No. 54-32552, No. 54-
107941, 55-133465, 56-1
9043, 56-19047, 56-1268.
It can be manufactured according to the method described in No. 30 and No. 58-149038.

Here, the use ratio of the dye and the polymer latex is preferably 10 to 1/10 (weight ratio).

A method of using the hydrophilic polymer in place of the high boiling point solvent or in combination with the high boiling point solvent. Regarding this method, for example, US Pat. No. 3,619,195,
It is described in West German Patent 1,957,467.

A method of dissolving a compound using a surfactant. Useful surfactants are oligomers and polymers. Details of this polymer are described on pages 19 to 27 of the specification of JP-A-60-158437.

Further, for example, a hydrosol of a hydrophilic polymer described in JP-B-51-39835 may be added to the hydrophilic colloid dispersion obtained above. Gelatin is a typical hydrophilic colloid, but any of those conventionally known as those usable for photography can be used.

The silver halide emulsion used in the present invention is
Silver bromide, silver iodobromide, silver iodochlorobromide, silver chlorobromide and silver chloride are preferred. Gelatin is a typical hydrophilic colloid, but any of those conventionally known as those usable for photography can be used.

The light-sensitive material of the present invention may have at least one silver halide emulsion layer of a blue color-sensitive layer, a green color-sensitive layer and a red color-sensitive layer provided on a support. There is no particular limitation on the number and order of layers of the silver halide emulsion layer and the non-photosensitive layer. As a typical example, a silver halide photographic light-sensitive material having at least one light-sensitive layer composed of a plurality of silver halide emulsion layers having substantially the same color sensitivity but different sensitivities on a support. And the photosensitive layer is blue light, green light,
And a unit light-sensitive layer having color sensitivity to red light, and in a multilayer silver halide color photographic light-sensitive material, the unit light-sensitive layers are generally arranged in order from the support side to the red-color-sensitive layer and green. The color sensitive layer and the blue color sensitive layer are installed in this order. However, the order of installation may be reversed depending on the purpose, or the order of installation may be such that different photosensitive layers are sandwiched between the same color-sensitive layers. A non-photosensitive layer such as various intermediate layers may be provided between the above-described silver halide photosensitive layers and as the uppermost layer and the lowermost layer. The intermediate layer includes JP-A Nos. 61-43748 and 59-113.
No. 438, No. 59-113440, No. 61-20037, No. 61-20038 may contain a coupler, a DIR compound, and the like, and a color mixing inhibitor may be used as is usually used. May be included. The plural silver halide emulsion layers constituting each unit light-sensitive layer preferably use a two-layer constitution of a high-sensitivity emulsion layer and a low-sensitivity emulsion layer as described in West German Patent No. 1,121,470 or British Patent No. 923,045. be able to. Usually, it is preferable that the layers are arranged so that the sensitivities are gradually lowered toward the support, and a non-photosensitive layer may be provided between each halogen emulsion layer. In addition,
57-112751, 62-200350, 62-206541, 62-2
As described in No. 06543, a low-sensitivity emulsion layer may be provided on the side farther from the support, and a high-sensitivity emulsion layer may be provided on the side closer to the support. As a specific example, from the side farthest from the support,
Low sensitivity blue photosensitive layer (BL) / High sensitivity blue photosensitive layer (BH) / High sensitivity green photosensitive layer (GH) / Low sensitivity green photosensitive layer (GL) / High sensitivity red photosensitive layer (RH) / Low sensitivity red photosensitive layer (RL) order, or BH / BL / GL / GH / RH / RL order, or BH / BL / GH /
It can be installed in the order of GL / RL / RH. In addition,
As described in JP-A-55-34932, the blue-sensitive layer / GH / RH / GL / RL may be arranged in this order from the side farthest from the support. Also, JP-A-56-25738 and 62-63936
It is also possible to arrange the layers in the order of blue-sensitive layer / GL / RL / GH / RH from the side farthest from the support, as described in the specification. Further, as described in JP-B-49-15495, the upper layer is a silver halide emulsion layer having the highest sensitivity, the middle layer is a silver halide emulsion layer having a lower sensitivity, and the lower layer is more sensitive than the middle layer. An example is an arrangement in which a silver halide emulsion layer having a low degree of sensitivity is arranged and three layers having different sensitivities are sequentially lowered toward the support. Even when it is composed of three layers having different sensitivities, as described in JP-A-59-202464, a medium-sensitivity emulsion from the side distant from the support in the same color-sensitive layer. The layers may be arranged in the order of high-speed emulsion layer / low-speed emulsion layer. In addition, they may be arranged in the order of high-speed emulsion layer / low-speed emulsion layer / medium-speed emulsion layer, or low-speed emulsion layer / medium-speed emulsion layer / high-speed emulsion layer. Also, in the case of four layers or more, the arrangement may be changed as described above. In order to improve color reproducibility, U.S. Pat.Nos. 4,663,271 and 4,70
5,744, 4,707,436, JP-A-62-160448, 6
3- It is preferable to dispose the donor layer (CL) having a multi-layer effect having a spectral sensitivity distribution different from that of the main photosensitive layer such as BL, GL and RL described in the specification of 89850 adjacent to or in proximity to the main photosensitive layer. . As described above, various layer configurations and arrangements can be selected according to the purpose of each light-sensitive material.

The preferred silver halide contained in the photographic emulsion layer of the photographic light-sensitive material used in the present invention contains about 30 mol% or less of silver iodide, silver iodobromide, silver iodochloride, or iodochlorobromide. It is silver. Particularly preferred is silver iodobromide or silver iodochlorobromide containing from about 2 mol% to about 10 mol% silver iodide. Silver halide grains in photographic emulsions have regular crystals such as cubes, octahedra and tetradecahedrons, grains having irregular crystal forms such as spheres and plates, twin planes, etc. It may have a crystal defect of, or a composite form thereof. The grain size of silver halide is about
It may be fine particles of 0.2 μm or less or large-sized grains having a projected area diameter of up to about 10 μm, and may be a polydisperse emulsion or a monodisperse emulsion. The silver halide photographic emulsion which can be used in the present invention is, for example, Research Disclosure (RD) N.
o.17643 (December 1978), pp. 22-23, "I. Emulsion production (Emu
lsion preparation and types) ”, and the same No.18716
(Nov. 1979), p. 648, ibid. No. 307105 (Nov. 1989), 863.
-886, and Graphide, Physics and Chemistry of Photography, published by Paul Montel (P.Glafkides, Chemie etPh.
isique Photographique, PaulMontel, 1967), "Photographic Emulsion Chemistry" by Duffin, published by Focal Press (GF Duf
fin, Photographic Emulsion Chemistry (Focal Press,
1966)), "Manufacturing and coating of photographic emulsions" by Zelikmann et al., Published by Focal Press (VL Zelikman et al., Making a
nd Coating Photographic Emulsion, Focal Press, 196
It can be prepared using the method described in 4).

Monodisperse emulsions described in US Pat. Nos. 3,574,628 and 3,655,394 and British Patent 1,413,748 are also preferable. Further, tabular grains having an aspect ratio of about 3 or more can be used in the present invention. Tabular grains are described in Gutoff, PhotographicScience by Gatov.
and Engineering), Vol. 14, pp. 248-257 (1970);
U.S. Pat.Nos. 4,434,226, 4,414,310, 4,433,0
It can be easily prepared by the methods described in 48, 4,439,520 and British Patent 2,112,157. The crystal structure may be uniform, may have a different halogen composition between the inside and the outside, may have a layered structure, and may have a different composition by epitaxial bonding. Alternatively, it may be bonded to a compound other than silver halide such as silver rhodanide and lead oxide. Also, a mixture of particles having various crystal forms may be used. The above emulsion may be either a surface latent image type which forms a latent image mainly on the surface, an internal latent image type which forms a latent image inside the grain or a type which has a latent image both on the surface and inside, but a negative type emulsion. It is necessary to be. Among the internal latent image type emulsions, core / shell type internal latent image type emulsions described in JP-A-63-264740 may be used. The method for preparing this core / shell type internal latent image type emulsion is described in JP-A-59-133542. The thickness of the shell of this emulsion varies depending on the development process and the like, but is preferably 3 to 40 nm, particularly preferably 5 to 20 nm.

As the silver halide emulsion, those which are physically ripened, chemically ripened and spectrally sensitized are usually used. Additives used in such a process are described in Research Disclosure No. 17643, No. 18716 and No. 307105, and the corresponding portions are summarized in the table below. The light-sensitive material of the present invention comprises two or more kinds of emulsions having different characteristics of at least one of the grain size, grain size distribution, halogen composition, grain shape and sensitivity of the light-sensitive silver halide emulsion.
It can be mixed and used in the same layer. US Patent No.
No. 4,082,553, the surface of which is covered with a silver halide grain, U.S. Pat. No. 4,626,498, JP-A-59-214852, the inside of which is covered with a silver halide grain, and a colloidal silver is a photosensitive halogenated photosensitive grain. It can be preferably used for a silver emulsion layer and / or a substantially light-insensitive hydrophilic colloid layer. The fogged silver halide grain inside or on the surface means a silver halide grain that enables uniform (non-imagewise) development regardless of the unexposed area and exposed area of the light-sensitive material. .. A method for preparing a silver halide grain whose inside or surface is fogged is described in U.S. Pat.
It is described in No. 9-214852. The silver halide forming the inner nucleus of a core / shell type silver halide grain having a fogged inside may have the same halogen composition or different halogen compositions. As the silver halide having the inside or surface of the grain fogged, any of silver chloride, silver chlorobromide, silver iodobromide and silver chloroiodobromide can be used. There is no particular limitation on the grain size of these fogged silver halide grains, but as the average grain size,
0.01 to 0.75 μm, particularly 0.05 to 0.6 μm is preferable. Also,
The grain shape is not particularly limited and may be regular grains or polydisperse emulsion, but monodisperse (at least 95% of the weight or number of silver halide grains is within ± 40% of the average grain size) It is preferable that the particles have a particle size of

In the present invention, it is preferable to use a non-photosensitive fine grain silver halide. The non-photosensitive fine grain silver halide is a fine grain of silver halide which is not exposed to light during imagewise exposure for obtaining a dye image and is not substantially developed in the developing treatment, and it is preferable that the fog is not fogged in advance. .. The fine grain silver halide has a silver bromide content of 0 to 100 mol%, and may optionally contain silver chloride and / or silver iodide. Preferred is one containing 0.5 to 10 mol% of silver iodide. Fine grain silver halide has an average grain size (average diameter of circles in the projected area)
Is preferably 0.01 to 0.5 μm, more preferably 0.02 to 0.2 μm. The fine grain silver halide can be prepared in the same manner as in the case of ordinary photosensitive silver halide. In this case, the surface of the silver halide grain does not need to be optically sensitized nor spectral sensitization. However, prior to adding this to the coating liquid, it is preferable to add a known stabilizer such as a triazole-based, azaindene-based, benzothiazolium-based, mercapto-based compound or zinc compound in advance. Colloidal silver can be preferably contained in the layer containing the fine grain silver halide grains. Coated silver amount of the light-sensitive material of the present invention is preferably 6.0 g / m ² or less, 4.5 g / m ² or less is most preferred.

Known photographic additives that can be used in the present invention are also described in the above three Research Disclosures, and the relevant portions are shown in the following table. Types of additives RD17643 RD18716 RD307105 1. Chemical sensitizer, page 23, page 648, right column, page 866 2. Sensitivity enhancer, page 648, right column 3. Spectral sensitizer, page 23 to 24, page 648, right column 866 to 868 Color sensitizer ~ page 649 right column 4.whitening agent page 24 647 page right column 868 page 5.fogging prevention page 24 ~ 25 page 649 page right column 868 ~ 870 agent, stabilizer 6.light absorber, 25 ~ Page 26 Page 649 Right column Page 873 Filter ~ Page 650 Left column Dye, UV absorber 7. Stain 25 Page Right column 650 Page Left column 872 Inhibitor ~ Right column 8. Dye image Page 25 650 Page Left column 872 Stabilizer 9. Hardener page 26 page 651 left column 874 to 875 10. Binder page 26 page 651 left column 873 to 874 page 11. Plasticizer, page 27 650 page right column 876 lubricant 12. Coating aid, 26 to 27 Page 650 page right column 875 to 876 surface active agent 13. static page 27 page 650 right column 876 to 877 inhibitor 14. matting agent page 878 to 879

Further, in order to prevent deterioration of photographic performance due to formaldehyde gas, it is preferable to add to the light-sensitive material a compound capable of reacting with formaldehyde described in US Pat. Nos. 4,411,987 and 4,435,503. .. In the light-sensitive material of the present invention, US Pat.
No. 4,788,132, JP-A-62-18539, JP-A 1-28
It is preferable to contain the mercapto compound described in No. 3551. A compound which, in the light-sensitive material of the present invention, releases a fog agent, a development accelerator, a silver halide solvent or a precursor thereof as described in JP-A 1-106052, irrespective of the amount of developed silver produced by development processing. Is preferably contained. Various color couplers can be used in the present invention, and specific examples thereof include Research Disclosure Nos. 17643, VII-C to G, and 307105, VII.
-C to G. Examples of yellow couplers include U.S. Pat.Nos. 3,933,501, 4,022,620, 4,326,024, and 4,401,752.
No. 4,248,961, Japanese Patent Publication No. 58-10739, British Patent No. 1,425,020, No. 1,476,760, U.S. Patent No. 3,973,
Those described in 968, 4,314,023, 4,511,649, European Patent 249,473A and the like are preferable.

As the magenta coupler, 5-pyrazolone compounds and pyrazoloazole compounds are preferable, and US Pat. Nos. 4,310,619, 4,351,897 and European Patent 73,63 are preferred.
6, U.S. Pat.Nos. 3,061,432, 3,725,067,
Research Disclosure No. 24220 (June 1984
Mon), JP-A-60-33552, Research Disclosure No. 24230 (June 1984), JP-A-60-43659, 61-71.
No. 2238, No. 60-35730, No. 55-118034, No. 60-185951
U.S. Pat.Nos. 4,500,630, 4,540,654, and
Those described in 4,556,630 and WO88 / 04795 are particularly preferable. Examples of cyan couplers include phenol-based and naphthol-based couplers, and US Pat.
52,212, 4,146,396, 4,228,233, and
4,296,200, 2,369,929, 2,801,171,
No. 2,772,162, No. 2,895,826, No. 3,772,002
No. 3, No. 3,758,308, No. 4,334,011, No. 4,32
7,173, West German Patent Publication No. 3,329,729, European Patent No. 12
1,365A, 249,453A, U.S. Pat.No. 3,446,622
No. 4,333,999, 4,775,616, 4,45
No. 1,559, No. 4,427,767, No. 4,690,889, No.
Those described in 4,254,212, 4,296,199, JP-A-61-42658 and the like are preferable. Furthermore, JP-A-64-553,
Pyrazoloazole couplers described in JP-A 64-554, 64-555 and 64-556, and imidazole couplers described in US Pat. No. 4,818,672 can also be used. Typical examples of polymerized dye-forming couplers are described in US Pat.
3,451,820, 4,080,211 and 4,367,282,
No. 4,409,320, No. 4,576,910, British patent 2,1
No. 02,137, European Patent No. 341,188A and the like.

Examples of couplers in which the color forming dye has an appropriate diffusibility include US Pat. No. 4,366,237 and British Patent 2,125,
570, European Patent 96,570, West German Patent (Publication) 3,
Those described in No. 234,533 are preferable. Colored couplers to correct unwanted absorption of colored dyes are
Disclosure No.17643, Item VII-G, No.30710
Item VII-G, US Pat. No. 4,163,670, Japanese Examined Patent Publication No. 57-3
9413, U.S. Pat.Nos. 4,004,929, 4,138,258,
Those described in British Patent No. 1,146,368 are preferred. Further, a coupler for correcting unnecessary absorption of a coloring dye by a fluorescent dye released at the time of coupling described in U.S. Pat.No. 4,774,181, and a dye capable of reacting with a developing agent described in U.S. Pat.No. 4,777,120 to form a dye. It is also preferable to use a coupler having a precursor group as a leaving group. Compounds that release a photographically useful residue upon coupling are also preferably used in the present invention. DIR couplers that release development inhibitors are disclosed in the above-mentioned RD 17643, VII-F and 307105 and VII-F patents, JP-A-57-151944, 57-154234, and JP-A-57-154234. 60-184248, 6
3-37346, 63-37350, U.S. Patents 4,248,962, 4,
Those described in No. 782,012 are preferable. RD No.1144
The bleaching accelerator releasing couplers described in JP-A No. 24241/1997, JP-A No. 61-201247, etc. are effective for shortening the processing time having a bleaching ability, and particularly, the tabular silver halide grains described above. The effect is great when it is added to the photosensitive material using. Examples of couplers that release a nucleating agent or a development accelerator imagewise during development include British Patent 2,097,140.
No. 2,131,188, JP-A-59-157638, and JP-A-59-170.
Those described in No. 840 are preferable. In addition, JP-A-60-1070
No. 29, No. 60-252340, JP-A No. 1-49440, No. 1-45687.
By the redox reaction with the oxidant of the developing agent described in No.
Compounds that release a fogging agent, a development accelerator, a silver halide solvent and the like are also preferable.

Other compounds that can be used in the light-sensitive material of the present invention include competitive couplers described in US Pat. No. 4,130,427 and US Pat. Nos. 4,283,472 and 4,3.
38,393, 4,310,618 and the like, multi-equivalent couplers, DIR redox compound releasing couplers, DIR coupler releasing couplers, DIR coupler releasing redox compounds described in JP-A-60-185950 and JP-A-62-24252. Alternatively, DIR redox-releasing redox compounds, couplers releasing dyes that undergo color restoration after withdrawal described in European Patents 173,302A and 313,308A, ligand-releasing couplers described in U.S. Pat. -75747 couplers releasing leuco dyes, U.S. Pat.
Examples thereof include couplers that release the fluorescent dye described in No. 181.

The coupler used in the present invention can be introduced into the light-sensitive material by various known dispersion methods. Examples of the high boiling point solvent used in the oil-in-water dispersion method are described in US Pat. No. 2,322,027. Specific examples of the high-boiling organic solvent having a boiling point of 175 ° C. or higher at atmospheric pressure used in the oil-in-water dispersion method include phthalic acid esters (dibutyl phthalate, dicyclohexyl phthalate, di-2-ethylhexyl phthalate, decyl phthalate, bisyl phthalate). (2,4-di-t-amylphenyl) phthalate, bis (2,4-di-t-amylphenyl)
Isophthalate, bis (1,1-diethylpropyl) phthalate, etc., phosphoric acid or phosphonic acid esters (triphenyl phosphate, tricresyl phosphate,
2-ethylhexyl diphenyl phosphate, tricyclohexyl phosphate, tri-2-ethylhexyl phosphate, tridodecyl phosphate, tributoxyethyl phosphate, trichloropropyl phosphate, di
-2-Ethylhexylphenylphosphonate, etc., Benzoic acid esters (2-ethylhexylbenzoate, dodecylbenzoate, 2-ethylhexyl-p-hydroxybenzoate, etc.), Amides (N, N-diethyldodecaneamide, N, N-diethyllauryl) Amides, N-tetradecylpyrrolidone, etc.), alcohols or phenols (isostearyl alcohol, 2,4-di-tert-amylphenol, etc.), aliphatic carboxylic acid esters (bis (2-ethylhexyl) sebacate, dioctyl azetase Rate, glycerol tributyrate, isostearyl lactate,
Trioctyl citrate, etc., aniline derivatives (N, N-
Dibutyl-2-butoxy-5-tert-octylaniline) and hydrocarbons (paraffin, dodecylbenzene, diisopropylnaphthalene, etc.) and the like. The auxiliary solvent has a boiling point of about 30 ° C or higher, preferably 50 ° C.
Organic solvents with temperatures above 160 ° C can be used. Typical examples are ethyl acetate, butyl acetate, ethyl propionate,
Examples thereof include methyl ethyl ketone, cyclohexanone, 2-ethoxyethyl acetate, dimethylformamide and the like. The steps and effects of the latex dispersion method and specific examples of the latex for impregnation are described in US Pat. No. 4,199,363, West German Patent Application (OLS) Nos. 2,541,274 and 2,541,230.

In the color light-sensitive material of the present invention, phenethyl alcohol, JP-A-63-257747 and JP-A-62-272248,
And 1,2-benzisothiazolin-3-one described in JP-A-1-80941, n-butyl p-hydroxybenzoate,
It is preferable to add various preservatives or antifungal agents such as phenol, 4-chloro-3,5-dimethylphenol, 2-phenoxyethanol, and 2- (4-thiazolyl) benzimidazole. The present invention can be applied to various color light-sensitive materials. Typical examples include color negative films for general use or movies, color reversal films for slides or televisions, color papers, color positive films and color reversal papers.
Suitable supports that can be used in the present invention are, for example, the above-mentioned R
D. No.17643, page 28, No.18716, page 647 From right column 648
It is described on the left column of the page and on page 879 of the same No. 307105. In the light-sensitive material of the present invention, the total thickness of all hydrophilic colloid layers on the emulsion layer side is preferably 28 μm or less, more preferably 23 μm or less, further preferably 18 μm or less, particularly preferably 16 μm or less. Also, the film swelling speed T
_1/2 is preferably 30 seconds or less, more preferably 20 seconds or less.
The film thickness means a film thickness measured under a humidity condition of 25 ° C. and a relative humidity of 55% (2 days), and the film swelling rate T _1/2 can be measured according to a method known in the art. For example, Photographic Science and Engineering (Photog
r.Sci.Eng.), No. 2, No. 2, pages 124 to 129 can be measured using a swellometer (swelling meter), and T _1/2 is 30 ° C. in a color developer. , 90% of the maximum swollen film thickness reached after 3 minutes and 15 seconds of treatment is defined as the saturated film thickness, and is defined as the time required to reach 1/2 of the saturated film thickness. Membrane swelling speed T
_1/2 can be adjusted by adding a hardening agent to gelatin as a binder or changing the aging condition after coating. The swelling rate is preferably 150 to 400%. The swelling ratio can be calculated from the maximum swollen film thickness under the conditions described above according to the formula: (maximum swollen film thickness-film thickness) / film thickness. The light-sensitive material of the present invention is preferably provided with a hydrophilic colloid layer (referred to as a back layer) having a total dry film thickness of 2 μm to 20 μm on the side opposite to the side having the emulsion layer.
In this back layer, the above-mentioned light absorber, filter dye,
It is preferable to contain an ultraviolet absorber, an antistatic agent, a hardener, a binder, a plasticizer, a lubricant, a coating aid, a surface active agent and the like. The swelling ratio of this back layer is 150-500
% Is preferred.

The color photographic light-sensitive material according to the present invention has the RD. No.17643, pages 28 to 29, No. 18716, 651 left column to right column, and No. 307105, pages 880 to 881 can be developed by a usual method. The color developing solution used in the development processing of the light-sensitive material of the present invention is preferably an alkaline aqueous solution containing an aromatic primary amine type color developing agent as a main component. As this color developing agent,
Aminophenol compounds are also useful, but p-phenylenediamine compounds are preferably used, and typical examples thereof include 3-methyl-4-amino-N, N diethylaniline and 3-methyl-4-amino-N-. Ethyl-N-β-hydroxyethylaniline, 3-methyl-4-amino-N-ethyl-N-β-methanesulfonamidoethylaniline, 3-methyl-4-amino-N
-Ethyl-β-methoxyethylaniline and their sulfates, hydrochlorides or p-toluenesulfonates. Among these, especially 3-methyl-4-amino-N
-Ethyl-N-β-hydroxyethylaniline sulfate is preferred. Two or more kinds of these compounds can be used in combination depending on the purpose. The color developer is an alkali metal carbonate,
It contains a pH buffer such as borate or phosphate, a chloride salt, a bromide salt, an iodide salt, a development inhibitor such as a benzimidazole, a benzothiazole or a mercapto compound, or an antifoggant. It is common. If necessary, hydroxylamine, diethylhydroxylamine, sulfite, hydrazines such as N, N-biscarboxymethylhydrazine, phenylsemicarbazides, triethanolamine, various preservatives such as catecholsulfonic acids, ethylene glycol, Organic solvent such as diethylene glycol, benzyl alcohol,
Development accelerators such as polyethylene glycol, quaternary ammonium salts, amines, dye-forming couplers, competing couplers, auxiliary developing agents such as 1-phenyl-3-pyrazolidone, tackifiers, aminopolycarboxylic acids, aminopolyphosphones. Acid, alkylphosphonic acid, various chelating agents represented by phosphonocarboxylic acid, for example, ethylenediaminetetraacetic acid, nitrilotriacetic acid, diethylenetriaminepentaacetic acid, cyclohexanediaminetetraacetic acid, hydroxyethyliminodiacetic acid, 1-hydroxyethylidene- 1,1-diphosphonic acid, nitrilo-N, N, N-trimethylenephosphonic acid,
Representative examples include ethylenediamine-N, N, N, N-tetramethylenephosphonic acid, ethylenediamine-di (o-hydroxyphenylacetic acid) and salts thereof.

When the reversal process is carried out, black and white development is usually carried out and then color development is carried out. In this black-and-white developer, known black-and-white developing agents such as dihydroxybenzenes such as hydroquinone, 3-pyrazolidones such as 1-phenyl-3-pyrazolidone or aminophenols such as N-methyl-p-aminophenol are used alone. Alternatively, they can be used in combination. The pH of these color developing solution and black-and-white developing solution is generally 9-12. The replenishing amount of these developing solutions depends on the color photographic light-sensitive material to be processed, but is generally 3 liters or less per square meter of the light-sensitive material, and 500 ml or less by reducing the bromide ion concentration in the replenishing solution. You can also When the replenishment amount is reduced, it is preferable to prevent the liquid evaporation and air oxidation by reducing the contact area with the air in the processing tank. The contact area between the photographic processing liquid and air in the processing tank can be represented by the aperture ratio defined below. That is, aperture ratio = [contact area between treatment liquid and air (cm ² )] ÷ [volume of treatment liquid (cm ³ )] The above aperture ratio is preferably 0.1 or less, and more preferably 0.001 to 0.05. Is. As a method for reducing the aperture ratio in this way, in addition to providing a cover such as a floating lid on the photographic processing liquid surface of the processing tank, a method using a movable lid described in JP-A-1-82033 is disclosed. The slit development processing method described in 63-216050 can be mentioned. Reducing the aperture ratio is not limited to both the color development and black and white development steps, but also the subsequent steps such as bleaching, bleach-fixing,
It is preferably applied in all steps such as fixing, washing with water, and stabilization. Further, the amount of replenishment can be reduced by using a means for suppressing the accumulation of bromide ions in the developing solution. The color development processing time is usually set to 2 to 5 minutes, but the processing time can be further shortened by setting the temperature and high pH and using the color developing agent at a high concentration.

The photographic emulsion layer after color development is usually bleached. The bleaching process may be performed at the same time as the fixing process (bleach-fixing process) or separately. Further, in order to speed up the processing, a processing method of bleach-fixing processing after bleaching processing may be used. Further, treatment with two continuous bleach-fixing baths, fixing treatment before the bleach-fixing treatment, or bleaching treatment after the bleach-fixing treatment can be optionally carried out. As the bleaching agent, compounds of polyvalent metals such as iron (III), peracids, quinones, nitro compounds and the like are used. Typical bleaching agents include organic complex salts of iron (III), such as ethylenediaminetetraacetic acid, diethylenetriaminepentaacetic acid, cyclohexanediaminetetraacetic acid, methyliminodiacetic acid, 1,3-diaminopropanetetraacetic acid and glycol etherdiaminetetraacetic acid. Polycarboxylic acids or complex salts of citric acid, tartaric acid, malic acid and the like can be used. Of these, aminopolycarboxylic acid iron (III) complex salts such as ethylenediaminetetraacetic acid iron (III) complex salt and 1,3-diaminopropanetetraacetic acid iron (III) complex salt are preferable from the viewpoint of rapid treatment and prevention of environmental pollution. .. Further, the aminopolycarboxylic acid iron (III) complex salt is particularly useful in both the bleaching solution and the bleach-fixing solution. The pH of a bleaching solution or a bleach-fixing solution using these aminopolycarboxylic acid iron (III) complex salts is usually 4.0 to 8, but a lower pH can be used for speeding up the processing.

If necessary, a bleaching accelerator can be used in the bleaching solution, the bleach-fixing solution and their pre-bath.
Specific examples of useful bleach accelerators are described in the following specifications: US Pat. No. 3,893,858, West German Patent 1,290,812.
No. 2,059,988, JP-A No. 53-32736, No. 53-57831
No. 53, No. 53-37418, No. 53-72623, No. 53-95630, No. 53
-95631, 53-104232, 53-124424, 53-141
623, 53-28426, Research Disclosure
No. 17129 (July 1978), etc., a compound having a mercapto group or a disulfide group; JP-A-50-140129
Thiazolidine derivatives described in JP-B-45-8506, JP-A-52-20832, JP-A-53-32735, and US Pat. No. 3,706,561.
Thiourea derivative described in Japanese Patent No. 1,127,715,
Iodide salt described in JP-A-58-16,235; West German Patent No. 966,
Polyoxyethylene compounds described in JP-A Nos. 410 and 2,748,430; polyamine compounds described in JP-B-45-8836; Other JP-A-49-40,943, 49-59,644, 53-94,92
No. 7, No. 54-35,727, No. 55-26,506, No. 58-163,940
Compounds described in No. 1; bromide ions and the like can be used. Among them, a compound having a mercapto group or a disulfide group is preferable from the viewpoint of having a large accelerating effect, and in particular, US Pat.
3,858, West German Patent 1,290,812, JP-A-53-95,630
Compounds described in US Pat. Further, U.S. Pat.
The compounds described in No. 834 are also preferable. These bleaching accelerators may be added to the light-sensitive material. These bleaching accelerators are particularly effective when bleach-fixing a color light-sensitive material for photographing. In addition to the above compounds, the bleaching solution and the bleach-fixing solution preferably contain an organic acid for the purpose of preventing bleach stain. Particularly preferred organic acid has an acid dissociation constant (pKa) of 2
A compound of -5, specifically acetic acid, propionic acid,
Hydroxyacetic acid and the like are preferred. Examples of the fixing agent used in the fixing solution and the bleach-fixing solution include thiosulfates, thiocyanates, thioether compounds, thioureas, and a large amount of iodide salts, but thiosulfates are generally used. In particular, ammonium thiosulfate can be used most widely. Further, the combined use of thiosulfate and thiocyanate, thioether compounds, thiourea and the like is also preferable. Preservatives for fixers and bleach-fixers include sulfites, bisulfites, carbonyl bisulfite adducts or European Patent No. 294
The sulfinic acid compounds described in No. 769A are preferable. Furthermore,
It is preferable to add various aminopolycarboxylic acids and organic phosphonic acids to the fixing solution and the bleach-fixing solution for the purpose of stabilizing the solution. In the present invention, the fixing solution or the bleach-fixing solution has a pH of
For adjustment, a compound having a pKa of 6.0 to 9.0, preferably an imidazole such as imidazole, 1-methylimidazole, 1-ethylimidazole, and 2-methylimidazole.
It is preferable to add 1 to 10 mol / l.

The total desilvering time is preferably as short as possible so long as no desilvering failure occurs. Preferred time is 1 to 3 minutes
Minutes, more preferably 1 minute to 2 minutes. The treatment temperature is 25 ° C to 50 ° C, preferably 35 ° C to 45 ° C. In the preferable temperature range, the desilvering rate is improved and the stain generation after the processing is effectively prevented. In the desilvering process, it is preferable that the stirring is strengthened as much as possible.
As a specific method for strengthening stirring, a method of impinging a jet of a processing solution on the emulsion surface of the light-sensitive material described in JP-A-62-183460, or stirring using a rotating means of JP-A-62-183461 is used. Method of improving the effect, further moving the photosensitive material while the emulsion surface is in contact with the wiper blade provided in the solution to make the emulsion surface turbulent to further improve the stirring effect, circulation of the entire processing solution There is a method of increasing the flow rate. Such a stirring improving means is effective for any of the bleaching solution, the bleach-fixing solution and the fixing solution. It is considered that the improvement of the stirring speeds up the supply of the bleaching agent and the fixing agent into the emulsion film and, as a result, increases the desilvering rate. Further, the above-mentioned stirring improving means is more effective when a bleaching accelerator is used, and it is possible to remarkably increase the accelerating effect and eliminate the fixing inhibiting effect of the bleaching accelerator. The automatic processor used for the light-sensitive material of the present invention is disclosed in JP-A-60-191257.
No. 60-191258 and No. 60-191259. The above-mentioned JP-A-6
As described in No. 0-191257, such a conveying means can significantly reduce the carry-in of the treatment liquid from the front bath to the rear bath, and is highly effective in preventing the performance deterioration of the treatment liquid. Such effects are particularly effective in shortening the processing time in each step and reducing the amount of processing liquid replenishment.

The silver halide color photographic light-sensitive material of the present invention is generally washed with water and / or stabilized after the desilvering treatment. The amount of rinsing water in the rinsing process depends on the characteristics of the photosensitive material (for example, depending on the materials used such as couplers), application, and further, the rinsing water temperature, the number of rinsing tanks (number of stages), replenishment system such as countercurrent, forward flow, and other various conditions. It can be set in a wide range.
Of these, the relationship between the number of washing tanks and the water volume in the multi-stage countercurrent system is described in the Journal of the Society of Motion Picture a
nd Television Engineers, Volume 64, pp. 248-253 (May 1955 issue). According to the multi-stage counter-current method described in the above literature, the amount of washing water can be significantly reduced, but due to the increase in the residence time of water in the tank, bacteria propagate, and the suspended matter produced adheres to the photosensitive material, etc. Problems arise. In the processing of the color light-sensitive material of the present invention, such a problem is solved by a method described in JP
The method of reducing calcium ion and magnesium ion described in No. 62-288,838 can be used very effectively. Further, isothiazolone compounds and siabendazoles described in JP-A-57-8,542, chlorine-based bactericides such as chlorinated sodium isocyanurate, and other benzotriazoles, etc., Hiroshi Horiguchi "Chemistry of antibacterial and fungicide" (1986) Sankyo Publishing, edited by Sanitary Engineering Society, "Microbial sterilization, sterilization, and antifungal technology"
(1982) The sterilizing agents described in “Encyclopedia of Antibacterial and Antifungal Agents” (1986) edited by Japan Society of Industrial Technology and Antifungal Society can also be used. The pH of the washing water in processing the light-sensitive material of the present invention is 4
-9, preferably 5-8. The washing water temperature and washing time can also be set variously depending on the characteristics of the photosensitive material, application, etc.
Generally, 15 seconds to 45 degrees Celsius for 20 seconds to 10 minutes, preferably 25 to 40 degrees Celsius
The range from 30 seconds to 5 minutes is selected with. Further, the light-sensitive material of the present invention can be directly processed with a stabilizing solution instead of the above washing with water. In such stabilization treatment, all known methods described in JP-A-57-8543, JP-A-58-14834 and JP-A-60-220345 can be used. Further, there is a case where further stabilization treatment is carried out after the water washing treatment, and an example thereof is a stabilizing bath containing a dye stabilizer and a surfactant, which is used as a final bath of a color light-sensitive material for photographing. be able to. Examples of dye stabilizers include aldehydes such as formalin and glutaraldehyde, N-methylol compounds, hexamethylenetetramine, and aldehyde sulfite adducts. Various chelating agents and antifungal agents can also be added to this stabilizing bath.

The overflow solution accompanying the washing with water and / or the replenishment of the stabilizing solution can be reused in other steps such as the desilvering step. In the processing using an automatic processor, etc., when the above processing solutions are concentrated by evaporation,
It is preferable to correct the concentration by adding water. The silver halide color light-sensitive material of the present invention may contain a color developing agent for the purpose of simplifying and accelerating the processing. For incorporation, it is preferable to use various precursors of color developing agents. For example, indoaniline-based compounds described in U.S. Pat. Metal salt complexes described, JP-A-53-135
Urethane compounds described in No. 628 can be mentioned.
The silver halide color light-sensitive material of the present invention contains various types of 1-phenyl-3-methyl-3-phenyl-3-(-3-phenyl) -3-phenyl-3- (phenyl-3-phenyl) -3- (phenyl) -3-phenyl-3-(-3-phenyl) -3- (phenyl) -3- (phenyl) -3- (phenyl) -3-phenyl-3-(-3-phenyl) -3- (phenyl) -3-phenyl-3-(-3-phenyl-3-phenyl-3-phenyl-3- (phenyl-3-phenyl-3-phenyl-3-phenyl-3-phenyl-3-phenyl-3-phenyl-3-phenyl-3-phenyl-3-phenyl-3-phenyl-3-fluoro-3-bromo-3-chloro-3-bromo-3-bromo-3-amino-3-bromo-3-amino-3-bromo-3-amino-3-bromo-3-amino-3-phenyl-3-phenyl-3-bromo-3-octyl-3-bromo-3-bromo-3-bromo-3-octyl-3-bromo-3-bromo-3-octyl-3-bromo-3-bromo-3-bromo-3-octyl-3-phenyl-3-bromo-3-bromo-3-bromo-3-bromo-3-octyl-3-phenyl-3-chloro-3-bromo-3-bromo-3-bromo-3-bromo-3-bromo-3-bromo-3-bromo-3-bromo-3-bromo-3-bromo-3-bromo-3-bromo-3-bromo-3-bromo-3-bromo-3-bromo-3-bromo-3-bromo-3-bromo-3-bromo-3-bromo-3-bromo-3-bromo-3-bromo-3-bromo-3-bromo-3-bromo-3-bromo-3-bromo-3-bromo-3-bromo-3-bromo-3-bromo-3-bromo-3-bromo-3-bromo-3-bromo-3-bromo-3-bromo-3-bromo-3-bromo-3-bromo-3-bromo 3-bromo-3-bromo-3-bromo-3-bromo-3-bromo-3-bromo-3-bromo-3-bromo-3-bromo-3-bromo-3-bromo-3-bromo-3-bromo-3-bromo-3-bromo-3- did lead;
You may incorporate pyrazolidones. Typical compounds are JP-A-56-64339, JP-A-57-144547, and JP-A-58-115438.
No. etc. Various treatment liquids in the present invention are 10
Used at -50 ° C. Normally, a temperature of 33 ° C to 38 ° C is standard, but a higher temperature accelerates the processing to shorten the processing time, and a lower temperature lowers the image quality to improve the stability of the processing liquid. be able to. The silver halide light-sensitive material of the present invention is US Pat. No. 4,500,626,
JP-A-60-133449, JP-A-59-218443, JP-A-61-238056
And the photothermographic material described in European Patent No. 210,660A2.

[0108]

EXAMPLES The present invention will be described in more detail with reference to examples below, but the present invention is not limited thereto. Example 1 On a subbed cellulose triacetate film support,
Each layer having the composition shown below was applied in multiple layers to prepare Sample 101, which is a multilayer color light-sensitive material. (Photosensitive layer composition) The numbers corresponding to the respective components indicate the coating amount in g / m ² , and for silver halide, the coating amount in terms of silver. However, with respect to the sensitizing dye, the coating amount is shown in mol unit per mol of silver halide in the same layer.

(Sample 101) First layer (antihalation layer) Black colloidal silver Silver 0.18 Gelatin 1.40

Second layer (intermediate layer) 2,5-di-t-pentadecylhydroquinone 0.18 EX-1 0.18 EX-3 0.020 EX-12 2.0 × 10 ^-3 U-10 0.060 U-2 0.080 U-3 0.10 HBS-1 0.10 HBS-2 0.020 gelatin 1.04

Third Layer (First Red Sensitive Emulsion Layer) Emulsion A Silver 0.25 Emulsion B Silver 0.25 Sensitizing Dye I 6.9 × 10 ⁻⁵ Sensitizing Dye II 1.8 × 10 ⁻⁵ Sensitizing Dye III 3.1 × 10 ⁻⁴ EX-2 0.17 EX-10 0.020 EX-14 0.17 U-1 0.070 U-2 0.050 U-3 0.070 HBS-1 0. 060 gelatin 0.87

Fourth Layer (Second Red Sensitive Emulsion Layer) Emulsion G Silver 1.00 Sensitizing Dye I 5.1 × 10 ⁻⁵ Sensitizing Dye II 1.4 × 10 ⁻⁵ Sensitizing Dye III 2.3 × 10 ^-4 EX-2 0.20 EX-3 0.050 EX-10 0.015 EX-14 0.20 EX-15 0.050 U-1 0.070 U-2 0.050 U-3 0. 070 gelatin 1.30

Fifth Layer (Third Red Sensitive Emulsion Layer) Emulsion D Silver 1.60 Sensitizing Dye I 5.4 × 10 ⁻⁵ Sensitizing Dye II 1.4 × 10 ⁻⁵ Sensitizing Dye III 2.4 × 10 ^-4 EX-2 0.097 EX-3 0.010 EX-4 0.080 HBS-1 0.22 HBS-2 0.10 Gelatin 1.63

Sixth layer (intermediate layer) EX-5 0.040 HBS-1 0.020 gelatin 0.80

Seventh Layer (First Green Sensitive Emulsion Layer) Emulsion A Silver 0.15 Emulsion B Silver 0.15 Sensitizing Dye IV 3.0 × 10 ⁻⁵ Sensitizing Dye V 1.0 × 10 ⁻⁴ Sensitizing Dye VI 3.8 × 10 ⁻⁴ EX-1 0.021 EX-6 0.26 EX-7 0.030 EX-8 0.025 HBS-1 0.10 HBS-3 0.010 Gelatin 0.63

Eighth Layer (Second Green Sensitive Emulsion Layer) Emulsion C Silver 0.45 Sensitizing Dye IV 2.1 × 10 ⁻⁵ Sensitizing Dye V 7.0 × 10 ⁻⁵ Sensitizing Dye VI 2.6 × 10 ^-4 EX-6 0.094 EX-7 0.026 EX-8 0.018 HBS-1 0.16 HBS-3 8.0 × 10 ^-3 gelatin 0.50

Ninth Layer (Third Green Sensitive Emulsion Layer) Emulsion E Silver 1.20 Sensitizing Dye IV 3.5 × 10 ⁻⁵ Sensitizing Dye V 8.0 × 10 ⁻⁵ Sensitizing Dye VI 3.0 × 10 ^-4 EX-1 0.013 EX-11 0.065 EX-13 0.019 HBS-1 0.25 HBS-2 0.10 Gelatin 1.54

10th layer (yellow filter layer) Yellow colloidal silver Silver 0.050 EX-5 0.12 HBS-1 0.08 gelatin 0.95

Eleventh Layer (First Blue Sensitive Emulsion Layer) Emulsion A Silver 0.080 Emulsion B Silver 0.070 Emulsion F Silver 0.070 Sensitizing Dye VII 3.5 × 10 ⁻⁴ EX-8 0.042 EX -9 0.72 HBS-1 0.28 Gelatin 1.10

Twelfth Layer (Second Blue Sensitive Emulsion Layer) Emulsion G Silver 0.45 Sensitizing Dye VII 2.1 × 10 ⁻⁴ EX-9 0.15 EX-10 7.0 × 10 ⁻³ HBS-1 0.050 Gelatin 0.78

Thirteenth Layer (Third Blue Sensitive Emulsion Layer) Emulsion H Silver 0.77 Sensitizing Dye VII 2.2 × 10 ⁻⁴ EX-9 0.20 HBS-1 0.070 Gelatin 0.69

Fourteenth Layer (First Protective Layer) Emulsion I Silver 0.20 U-4 0.11 U-5 0.17 HBS-1 5.0 × 10 ^-2 Gelatin 1.00

Fifteenth layer (second protective layer) H-1 0.40 B-1 (diameter 1.7 μm) 5.0 × 10 ⁻² B-2 (diameter 1.7 μm) 0.10 B-30 .10 S-1 0.20 Gelatin 1.20

Furthermore, all layers have preservability, processability, pressure resistance,
W-1, W-2, W-3, B-4, B-5, F- for improving the antifungal / antibacterial property, antistatic property and coating property.
1, F-2, F-3, F-4, F-5, F-6, F-
7, F-8, F-9, F-10, F-11, F-12,
F-13, and iron salt, lead salt, gold salt, platinum salt, iridium salt, and rhodium salt are contained.

[0125]

[Table 1]

[0126]

[Chemical 43]

[0127]

[Chemical 44]

[0128]

[Chemical 45]

[0129]

[Chemical 46]

[0130]

[Chemical 47]

[0131]

[Chemical 48]

[0132]

[Chemical 49]

[0133]

[Chemical 50]

[0134]

[Chemical 51]

[0135]

[Chemical 52]

[0136]

[Chemical 53]

[0137]

[Chemical 54]

[0138]

[Chemical 55]

Then, in place of the yellow colloidal silver of the 10th layer of Sample 101, Compound A was applied in an amount of 0.20 g / m ² to obtain Sample 102. Compound A is dissolved in a high-boiling organic solvent HBS-1 (0.7 times by weight of compound A by weight) and ethyl acetate, and an emulsified dispersion is carried out in gelatin using a suitable amount of a surfactant by a conventional method. Using.

[0140]

[Chemical 56]

Further, in the same manner as in Sample 102, except that the compounds D-3, D-4, D-15 and D-22 according to the present invention were used in an equimolar amount with the compound A instead of the compound A. Samples 103 to 106 were prepared. The sample thus obtained was exposed to white light through an optical wedge and then processed by the method described below using an automatic processor (the cumulative replenishment amount of the liquid was previously set to 3 times the mother liquid tank capacity).
Processed until doubled). Processing method (A) Step Processing time Processing temperature Replenishment amount Tank capacity Color development 3 minutes 15 seconds 38 ° C 33 ml 20 liters Bleach 6 minutes 30 seconds 38 ° C 25 ml 40 liters Water washing 2 minutes 10 seconds 24 ° C 1200 ml 20 liters Settling 4 minutes 20 seconds 38 ℃ 25 ml 30 liters Water wash (1) 1 minute 05 seconds 24 ℃ From (2) to (1) 10 liter countercurrent piping method Water wash (2) 1 minute 00 seconds 24 ℃ 1200 Milliliter 10 liters Stability 1 minute 05 seconds 38 ℃ 25 milliliters 10 liter Dry 4 minutes 20 seconds 55 ℃ Replenishment amount per 35mm width 1m length The composition of the processing solution is described below. (Color developer) Mother liquor (g) Replenisher (g) Diethylenetriaminepentaacetic acid 1.0 1.1 1-Hydroxyethylidene-1,1-diphosphonic acid 3.0 3.2 Sodium sulfite 4.0 4.0 Potassium carbonate 30.0 37.0 Potassium bromide 1.4 0.7 Potassium iodide 1.5 mg-Hydroxylamine sulfate 2.4 2.8 4- [N-ethyl-N-β-hydroxyethylamino] -2-methylani Phosphosulfate 4.5 5.5 Add 1.0 liter of water 1.0 liter pH 10.05 10.10 (bleaching solution) Mother liquor (g) Replenisher (g) Ethylenediaminetetraacetic acid ferric sodium trihydrate 100. 0 120.0 Ethylenediaminetetraacetic acid disodium salt 10.0 10.0 Ammonium bromide 140.0 160.0 Ammonium nitrate 30.0 35.0 Anne Near water (27%) 6.5 ml 4.0 ml Add water 1.0 liter 1.0 liter pH 6.0 5.7 (fixer) mother liquor (g) replenisher (g) ethylenediaminetetraacetic acid disodium salt 0.5 0.7 Sodium sulfite 7.0 8.0 Sodium bisulfite 5.0 5.5 Ammonium thiosulfate aqueous solution (70%) 170.0 ml 200.0 ml Add water 1.0 liter 1.0 liter pH 6.7 6.6 (Stable solution) Mother liquor (g ) Replenisher (g) Formalin (37%) 2.0 ml 3.0 ml Polyoxyethylene-p-monononyl phenyl ether (average degree of polymerization 10) 0.3 0.45 Ethylenediaminetetraacetic acid disodium salt 0.05 0.08 Water In addition, 1.0 liter 1.0 liter pH 5.8-8.0 5.0-8.0 Each sample Perform density measurement, the density of fog portion of the blue-sensitive layer (D _B (min)) is read as a relative value to the sample 101, it was applied to the evaluation of bleaching of (△ D _B (min)) dye. Further, the sensitivity of the green-sensitive layer was expressed by the logarithm of the reciprocal of the exposure amount giving (fog + 0.2), and evaluated by the relative value to Sample 101. The obtained results are shown in Table 1. As is clear from Table 1, in the sample according to the present invention, sample 1
A D _B (min) equivalent to 01 is given. That is, it shows that the decolorizing property is excellent. Further, in the sample of the present invention,
The sensitivity of the green-sensitive layer can be remarkably increased. This is because the dye of the present invention has excellent absorption characteristics. Table 1

[0142]

[Table 2]

[0143] Using samples prepared in Example 1, where except for changing the processing steps shown processing below were evaluated in the same manner as in Example 1, Sample 102, further D _B (min ) Becomes large, and there is a problem in decolorization, whereas in the sample of the present invention, D _B (min) was no problem and the sensitivity of the green-sensitive layer was increased, as in Example 1. Processing method Step B Processing time Processing temperature ^* Replenishment amount Tank capacity Color development 3 minutes 15 seconds 37.8 ℃ 25 ml 10 liter Bleach 45 seconds 38 ℃ 5 milliliter 4 liter Bleach fixing (1) 45 seconds 38 ℃ − 4 liter Bleach fixing ( 2) 45 seconds 38 ℃ 30 ml 4 liters Water wash (1) 20 seconds 38 ℃ −2 liters Water wash (2) 20 seconds 38 ℃ 30 ml 2 liters Stability 20 seconds 38 ℃ 20 ml 2 liters Dry 1 minute 55 ℃ * Replenishment amount is 35mm width 1m length per length. Each of the bleach-fixing and washing steps is a counter-current method from (2) to (1), and the bleaching solution overflow solution is bleach-fixing (2) Introduced to. In the above processing, the amount of the bleach-fixing solution brought into the washing step was 2 ml per 1 m length of the light-sensitive material having a width of 35 mm. (Color developer) Mother liquor (g) Replenisher (g) Diethylenetriaminepentaacetic acid 5.0 6.0 Sodium sulfite 4.0 5.0 Potassium carbonate 30.0 37.0 Potassium bromide 1.3 0.5 Iodide Potassium 1.2 mg-hydroxylamine sulfate 2.0 3.6 4- [N-ethyl-N-β-hydroxyethylamino] -2-methylaniline sulfate 4.7 6.2 Water was added to 1.0 liter 1.0 liter pH 10.00 10.15 (bleaching solution) Mother liquor (g) Replenishing solution (g) 1,3-Diaminopropanetetraacetic acid ferric ammonium monohydrate 144.0 206.0 1,3-Diaminopropanetetraacetic acid 2 .8 4.0 Ammonium bromide 84.0 120.0 Ammonium nitrate 17.5 25.0 Ammonia water (27%) 10.0 1.8 Acetic acid (98%) 51.1 73. 1.0 liter by adding water 1.0 liter pH 4.3 3.4 (bleach-fixing solution) Mother liquor (g) Replenisher (g) Ethylenediaminetetraacetic acid Ammonium dihydrate 50.0- Ethylenediaminetetraacetic acid disodium salt 5.0 25.0 Ammonium sulfite 12.0 20.0 Ammonium thiosulfate aqueous solution (700 g / liter) 290.0 ml 320.0 ml Ammonia water (27%) 6.0 ml 15.0 ml Water was added to 1.0 liter 1.0 liter pH 6.8 8. 0 (Washing water) mother liquor, replenisher common Tap water is H type strongly acidic cation exchange resin (Amberlite IR-120B manufactured by Rohm and Haas) and OH type strongly basic anion exchange resin (Amberlite IRA-4).
00) packed in a mixed bed column to treat calcium and magnesium ions at a concentration of 3 mg / liter or less, and then 20 mg of sodium isocyanurate dichloride /
L and 150 mg / L of sodium sulfate were added. The pH of this liquid was in the range of 6.5-7.5. (Stabilizer) Common to mother liquor and replenisher (Unit: g) Formalin (37%) 1.2 ml Surfactant 0.4 C ₁₀ H ₂₁ --O-(CH ₂ CH ₂ O) ₁₀ --H Ethylene glycol 1.0 In addition 1.0 liter pH 5.7-7.0

Example 3 Samples 201 to 204 were prepared in the same manner as in Example 1.
However, HBS-1 was used in a 1.2-fold amount. Further, those having poor solubility were dissolved by adding a small amount of DMF. Samples 201 to 204 are processed in the same manner as in Example 1,
Similar evaluation was performed. The results are shown in Table 2. As is clear from Table 2, the sample of the present invention has a small D _B (min) and an excellent decolorizing property. Also, the sensitivity of the green-sensitive layer is increased.

[0145]

[Table 3]

─────────────────────────────────────────────────── ───

[Procedure amendment]

[Submission date] October 9, 1991

[Procedure Amendment 1]

[Document name to be amended] Statement

[Name of item to be corrected] Claim 1

[Correction method] Change

[Correction content]

[Chemical 1] In the formula, R ²¹ is an alkyl group, an aryl group, or —COO.
^{R 27, -COR 27, -CONR 27} R 28, -C
N, -OR ²⁷ , -NR ²⁷ R ²⁸ , -N (R ²⁷ ) C
Represents an OR ²⁸ , R ²² is an alkyl group, a phenyl group, a substituted phenyl group (the substituents are —CONHSO ₂ R ₂₉ , —S
O ₂ NHCOR _29, -CONHCOR _29, represents a halogen atom or -COOR _29), or a heterocyclic ^{group, R 23, R 24, R} 25 is a hydrogen atom, an alkyl group,
It represents an aryl group, and R ²⁴ and R ²⁵ may form a 6-membered ring. R ²⁶ is a hydrogen atom, an alkyl group, a phenyl group,
Substituted phenyl group (the substituent is -CONHSO ₂ R _29, -
SO ₂ NHCOR _29, -CONHCOR _29, halogen atom, a _-COOR 29, _{OR 29} or OH), or an amino ^group, R ^{27, R 28} are each a hydrogen atom,
It represents an alkyl group or an aryl group, and R ²⁹ represents an alkyl group or an aryl group. However, the compound represented by formula (1) is a sulfo group, a salt of a sulfo group, a carboxy group
It should not have a salt of the carboxy group as a substituent.

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[Chemical 42]

Claims (2)

[Claims] 1. A silver halide photographic light-sensitive material having a hydrophilic colloid layer containing at least one compound represented by the following general formula (1) as an oil composition and / or a polymer latex composition. [Chemical 1] In the formula, R ²¹ is an alkyl group, an aryl group, —COOR ²⁷ , —
COR ²⁷ , -CONR ²⁷ R ²⁸ , -CN, -OR ²⁷ , -N
R ²⁷ R ²⁸ represents —N (R ²⁷ ) COR ²⁸ , and R ²² represents an alkyl group, a phenyl group, a substituted phenyl group (the substituent is —CON
HSO ₂ R ₂₉ , -SO ₂ NHCOR ₂₉ , -CONHCO
R ₂₉ , a halogen atom, or —COOR ₂₉ ), or a heterocyclic group, R ²³ , R ²⁴ , and R ²⁵ represent a hydrogen atom, an alkyl group, and an aryl group, and R ²⁴ and R ²⁵ form a 6-membered ring. You may. R ²⁶ is a hydrogen atom, an alkyl group, a phenyl group,
Substituted phenyl group (the substituent is -CONHSO ₂ R _29, -S
O ₂ NHCOR _29, -CONHCOR _29, represents a halogen atom, -COOR _29, OR ₂₉ or OH), or an amino group, R ^27, R ²⁸ each represent a hydrogen atom, an alkyl group or an aryl group, R ²⁹ is alkyl Represents a group or an aryl group. However, the compound represented by the general formula (1) must not have a sulfo group, a salt of a sulfo group, a carboxy group, or a salt of a carboxy group as a substituent. 2. A silver halide photographic light-sensitive material having at least one red-sensitive emulsion layer, green-sensitive emulsion layer, blue-sensitive emulsion layer and non-light-sensitive hydrophilic colloid layer on a support, said non-light-sensitive hydrophilic layer. The silver halide color photograph according to claim 1, wherein the colloid layer is a yellow filter layer containing at least one compound represented by the general formula (1) as an oil composition and / or a polymer latex composition. Photosensitive material.