JPH0545416B2 - - Google Patents
Info
- Publication number
- JPH0545416B2 JPH0545416B2 JP9404185A JP9404185A JPH0545416B2 JP H0545416 B2 JPH0545416 B2 JP H0545416B2 JP 9404185 A JP9404185 A JP 9404185A JP 9404185 A JP9404185 A JP 9404185A JP H0545416 B2 JPH0545416 B2 JP H0545416B2
- Authority
- JP
- Japan
- Prior art keywords
- base material
- deodorizing
- flocked
- piles
- sterilizing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000463 material Substances 0.000 claims description 46
- 230000001877 deodorizing effect Effects 0.000 claims description 16
- 230000001954 sterilising effect Effects 0.000 claims description 12
- 239000000853 adhesive Substances 0.000 claims description 10
- 230000001070 adhesive effect Effects 0.000 claims description 10
- 239000003899 bactericide agent Substances 0.000 claims description 4
- 230000000844 anti-bacterial effect Effects 0.000 claims description 2
- 239000002781 deodorant agent Substances 0.000 claims 1
- 235000019645 odor Nutrition 0.000 description 9
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 5
- 239000006260 foam Substances 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 4
- 239000003814 drug Substances 0.000 description 4
- 229940079593 drug Drugs 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000004744 fabric Substances 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 3
- 230000007721 medicinal effect Effects 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- 244000052616 bacterial pathogen Species 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 230000005923 long-lasting effect Effects 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000004745 nonwoven fabric Substances 0.000 description 2
- 238000004659 sterilization and disinfection Methods 0.000 description 2
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 241000588724 Escherichia coli Species 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- 239000002211 L-ascorbic acid Substances 0.000 description 1
- 235000000069 L-ascorbic acid Nutrition 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- 239000004640 Melamine resin Substances 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 235000011114 ammonium hydroxide Nutrition 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 229960005070 ascorbic acid Drugs 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 238000004332 deodorization Methods 0.000 description 1
- 230000000249 desinfective effect Effects 0.000 description 1
- OSVXSBDYLRYLIG-UHFFFAOYSA-N dioxidochlorine(.) Chemical compound O=Cl=O OSVXSBDYLRYLIG-UHFFFAOYSA-N 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 229910001448 ferrous ion Inorganic materials 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 238000010097 foam moulding Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- -1 iron ions Chemical class 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000003206 sterilizing agent Substances 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
Description
【発明の詳細な説明】
〔産業上の利用分野〕
この発明は、厨房又は自動車の車室等に内装材
として使用することによつて、優れた殺菌又は消
臭効果が得られるようにした植毛材に関するもの
である。[Detailed Description of the Invention] [Industrial Application Field] The present invention is directed to a flocked hair that can be used as an interior material for kitchens, automobile cabins, etc. to provide excellent sterilizing or deodorizing effects. It is related to materials.
一般に、安定化クロラインシオキサイド
（ClO2）を主成分とするローシヤツト（商品名）
は強力な殺菌・消毒性及び脱臭性を有し、又第一
鉄イオンからなる鉄の二価イオンとＬ−アスコル
ビン酸の化合物であるアニコ（商品名）も悪臭の
成分を選択的に吸収して消臭効果に優れていると
ころから、これらは何れも殺菌並びに消臭剤とし
て広く利用されているものである。
In general, low-shut (trade name) whose main component is stabilized chlorine oxide (ClO 2 )
has strong sterilizing/disinfecting and deodorizing properties, and Aniko (trade name), a compound of divalent iron ions consisting of ferrous ions and L-ascorbic acid, also selectively absorbs malodorous components. All of these are widely used as sterilizing and deodorizing agents because of their excellent deodorizing effects.
而して、近年、上述したような殺菌・消臭剤を
ウレタンフオームや不織布繊維に対し、その溶融
樹脂段階で予め混入させておくことによつて殺
菌・消臭性を付与するようにした内装材が一部で
研究・開発されているが、これらは何れもその薬
効を高めようとして薬剤量を増大すると、生地自
体に薬剤の成分である塩素や鉄分等の色素が沈着
して美観を著しく損なう恐れが有るため、このよ
うな使用態様では猶、充分な殺菌・消臭効果が得
られなかつたものである。 In recent years, interior decorations have been developed in which sterilizing and deodorizing agents such as those mentioned above are mixed into urethane foam and nonwoven fibers in advance at the molten resin stage to impart sterilizing and deodorizing properties. Some materials have been researched and developed, but when the amount of chemicals used in these materials is increased in an attempt to enhance their medicinal efficacy, pigments such as chlorine and iron, which are ingredients of the chemicals, are deposited on the fabric itself, which significantly impairs its aesthetic appearance. Since there is a risk of damage, sufficient sterilizing and deodorizing effects cannot be obtained in this manner of use.
そこで本発明は、ウレタンフオームや不織布、
編、織地などからなる基材の表面に接着剤を介し
て多数のパイルを静電植毛してなる植毛材につい
て、基材とパイルに消臭剤又は殺菌在のうち少な
くとも一方を含有乃至は塗布するにあたり、上記
パイル側に基材側より即効性の高い消臭、殺菌剤
を用いるという手段を用いた。
Therefore, the present invention focuses on urethane foam, nonwoven fabric,
For flocking materials made by electrostatically flocking a large number of piles on the surface of a base material made of knitted fabric, woven fabric, etc., using an adhesive, the base material and the piles may contain or be coated with at least one of a deodorizing agent or a sterilizing agent. In doing so, we used a method of using a deodorizing and bactericidal agent on the pile side that has a more immediate effect than the base material side.
本発明の植毛材において、パイルに含有乃至は
塗布された消臭剤や殺菌剤は基材側の薬剤に比べ
て即効性が悪く、これが多数のパイルによる表面
積の拡大によつて更にその薬効が促進されるた
め、迅速な消臭、殺菌が行える。一方、基材に含
有乃至は塗布された薬剤は、上記パイルのような
表面積の拡大による薬効の促進がなく、またパイ
ル側の薬剤に比べて遅効性であるため、当該基材
による消臭、殺菌は長時間持続するという作用を
奏する。
In the flocked material of the present invention, the deodorizing agent or bactericide contained in or applied to the piles has poor immediate effect compared to the chemicals on the base material side, and the expansion of the surface area due to the large number of piles further improves the medicinal efficacy. This allows for rapid deodorization and sterilization. On the other hand, the drug contained in or applied to the base material does not promote the medicinal effect by expanding the surface area like the pile, and is slow-acting compared to the drug on the pile side, so the base material can deodorize and Sterilization has a long-lasting effect.
以下、その構成を図面に示す３〜４の実施例に
従つて更に具体的に説明する。
Hereinafter, the structure will be explained in more detail according to three to four embodiments shown in the drawings.
（その１）
ウレタンフオームからなる基材１の表面に250
ｇ／m2の割合でアクリル樹脂接着剤２をコーテイ
ングした後、予め溶融樹脂段階で上記ローシヤツ
トを混入してなる３デニール、長さ1.2mmの多数
のナイロンパイル３を上記基材１の接着面に電気
植毛することにより、植毛材を得た。(Part 1) 250 ml on the surface of base material 1 made of urethane foam.
After coating with the acrylic resin adhesive 2 at a ratio of g/m 2 , a large number of nylon piles 3 of 3 denier and 1.2 mm in length, which have been mixed with the above-mentioned low shaft in advance at the melting resin stage, are applied to the adhesive surface of the base material 1. A flocked material was obtained by electro-flocking.
これを厨房用内装材として使用したところ、雑
菌や黴等の発生が殆ど見られず、また厨房に特有
の臭気も充分に除去し得たものである。 When this was used as an interior material for a kitchen, almost no germs or mold were observed, and the odor peculiar to kitchens was sufficiently removed.
（その２）
表面にローシヤツトの2000PPM溶液を0.3ml塗
布してなる不織布を基材１として、その表面にメ
ラミン樹脂接着剤２を150ｇ／m2の割合で塗布し、
更に、予め表面に上記アニコをスプレーで塗布し
てなる多数の微小パイル３を上記接着剤２を介し
て電気織毛した。(Part 2) Base material 1 is a nonwoven fabric whose surface is coated with 0.3 ml of 2000 PPM solution of Low Shat, and melamine resin adhesive 2 is coated on the surface at a rate of 150 g/m 2 .
Further, a large number of fine piles 3, which had been previously sprayed with the above Anico on the surface, were electrically woven with the adhesive 2 interposed therebetween.
このようにして得られた植毛材を靴の内張材と
して使用したところ、悪臭の発生が確実に抑制出
来た。 When the flocked material thus obtained was used as a shoe lining material, it was possible to reliably suppress the generation of bad odors.
（その３）
塩化ビニールシートからなる基材１の表面に、
アクリル系エマルジヨンにローシヤツト0.5％と
アンモニア水の25％水溶液を３％配合して粘度
2500cpsとした接着剤２を塗布し、デイツプ式に
より予め上記アニコを含浸させた多数のパイル３
を電気植毛して植毛材を得た。(Part 3) On the surface of the base material 1 made of vinyl chloride sheet,
Add 0.5% Low Shat and 3% aqueous solution of ammonia water to acrylic emulsion to reduce viscosity.
A large number of piles 3 are coated with adhesive 2 at 2500 cps and pre-impregnated with the above Anico using a dip method.
A flocked material was obtained by electro-flocking.
この植毛材によつておしめカバーを作成して使
用したところ、排泄物の臭気が充分に抑制され、
又大腸菌も殆ど発見できなかつた。 When a diaper cover was made and used with this flocked material, the odor of excrement was sufficiently suppressed.
Also, almost no E. coli was found.
（その４）
予め溶融樹脂段階でローシヤツトを混入した
上、発泡成形して得られたウレタンフオームを基
材１とし、その表面に上記ローシヤツトを含有し
た接着剤２を塗布し、更にその接着面に上記アニ
コをスプレー又はデイツプしてなるパイルを電気
植毛した。(Part 4) The base material 1 is a urethane foam obtained by mixing low-shut in advance in the molten resin stage and then foam-molding the base material.Adhesive 2 containing the low-shut described above is applied to the surface of the urethane foam, and then the adhesive surface is A pile made by spraying or dipping the above Aniko was electro-flocked.
本実施例の植毛材はパイルに即効性のアニコを
使用したところで、パイルの表面積の拡大と相俟
つて迅速な消臭効果が得られた。一方、基材に混
入されたローシヤツトは上記アニコより緩やかに
作用したため、植毛材全体として迅速且つ持続性
のある消臭、殺菌効果を奏した。 In the flocking material of this example, when immediate-acting Anico was used for the pile, a rapid deodorizing effect was obtained due to the expansion of the surface area of the pile. On the other hand, since the Low Shat mixed in the base material acted more slowly than the above-mentioned Anico, the flocked material as a whole exhibited a rapid and long-lasting deodorizing and sterilizing effect.
上記構成の植毛材を工業用フイルターとして植
毛乾燥機の排気口に取付けたところ、アンモニア
臭、アミン臭、アクリルのフリーモノマー臭など
の悪臭の発生が殆ど見られなかつた。尚、上記基
材１は各実施例に揚げられた素材の他に編織物或
いは紙などを使用することも自由である。 When the flocked material having the above structure was attached as an industrial filter to the exhaust port of a flocked dryer, almost no odor such as ammonia odor, amine odor, or acrylic free monomer odor was observed. Note that, in addition to the materials mentioned in each embodiment, the base material 1 may be made of knitted fabric, paper, or the like.
叙上の構成に係る本発明の植毛材は、パイル側
に含有乃至は塗布された基材側より即効性の高い
消臭、殺菌剤が、パイルの表面積の拡大によつ
て、更にその薬効が促進されるため、植毛材の使
用当初から顕著な消臭、殺菌効果を奏する一方、
基材側の薬剤は上記パイル側に比べて緩やかに作
用するため、長時間薬効が持続する。従つて、従
来のこの種植毛材に比較して本発明の植毛材は使
用当初から顕著且つ持続的な消臭、殺菌効果を有
するという格別の利点がある。又かくすることよ
つて、薬剤の色素が付着するという弊害も全く発
生することがないものである。
In the flocked material of the present invention having the above structure, the deodorizing and bactericidal agent contained or applied to the pile side is more immediately effective than the base material side, and the medicinal effect is further enhanced by expanding the surface area of the pile. As a result, the flocking material has a remarkable deodorizing and sterilizing effect from the beginning of its use, while
Since the drug on the base material side acts more slowly than on the pile side, the medicinal effect lasts for a long time. Therefore, compared to conventional flocking materials of this type, the flocking material of the present invention has a particular advantage in that it has a remarkable and lasting deodorizing and sterilizing effect from the beginning of use. In addition, by doing so, there is no problem of adhesion of the dye of the drug.
従つて、本発明の植毛材を一般家庭やレストラ
ンの厨房、又は自動車の車室など悪臭や雑菌の繁
殖し易い場所に内装材などとして利用することに
より、臭気の除去と衛生が確保できる他、おしめ
カバーや履物などの雑貨にも幅広く適用し得て高
い実効が得られるという優れた利点が得られるも
のである。 Therefore, by using the flocked material of the present invention as an interior material in places where bad odors and germs are likely to grow, such as ordinary homes, restaurant kitchens, and car cabins, it is possible to eliminate odors and ensure hygiene. It has the excellent advantage that it can be widely applied to miscellaneous goods such as diaper covers and footwear, and is highly effective.
第１図は本発明の植毛材の縦断面図である。
尚、図中、１……基材、２……接着剤、３……
パイル。
FIG. 1 is a longitudinal sectional view of the flocked material of the present invention. In addition, in the figure, 1...base material, 2...adhesive, 3...
pile.
Claims (1)
静電植毛してなる植毛材において、基材とパイル
に消臭剤又は殺菌剤のうち少なくとも一方を含有
乃至は塗布するにあたり、上記パイル側に基材側
より即効性の高い消臭、殺菌材を用いたことを特
徴とする植毛材。1. In a flocked material formed by electrostatically flocking a large number of piles on the surface of a base material via an adhesive, when containing or applying at least one of a deodorant or a bactericide to the base material and the piles, the piles are A flocked material characterized by using a deodorizing and sterilizing material on the side that is more quickly effective than the base material side.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP9404185A JPS61252141A (en) | 1985-04-30 | 1985-04-30 | Implanting material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP9404185A JPS61252141A (en) | 1985-04-30 | 1985-04-30 | Implanting material |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS61252141A JPS61252141A (en) | 1986-11-10 |
| JPH0545416B2 true JPH0545416B2 (en) | 1993-07-09 |
Family
ID=14099482
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP9404185A Granted JPS61252141A (en) | 1985-04-30 | 1985-04-30 | Implanting material |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS61252141A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2006116882A (en) * | 2004-10-25 | 2006-05-11 | Inoac Corp | Manufacturing method of flocked article |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62175918U (en) * | 1986-04-28 | 1987-11-09 | ||
| JPH0661886B2 (en) * | 1989-03-13 | 1994-08-17 | 中越パルプ工業株式会社 | Deodorant |
-
1985
- 1985-04-30 JP JP9404185A patent/JPS61252141A/en active Granted
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2006116882A (en) * | 2004-10-25 | 2006-05-11 | Inoac Corp | Manufacturing method of flocked article |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS61252141A (en) | 1986-11-10 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EXPY | Cancellation because of completion of term |