JPH05341123A - Polarizing plate and liquid crystal display - Google Patents

Polarizing plate and liquid crystal display

Info

Publication number
JPH05341123A
JPH05341123A JP4153879A JP15387992A JPH05341123A JP H05341123 A JPH05341123 A JP H05341123A JP 4153879 A JP4153879 A JP 4153879A JP 15387992 A JP15387992 A JP 15387992A JP H05341123 A JPH05341123 A JP H05341123A
Authority
JP
Japan
Prior art keywords
polarizing plate
coating layer
liquid crystal
crystal display
laminated
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP4153879A
Other languages
Japanese (ja)
Inventor
Shigetoshi Hayashi
成年 林
Hitoshi Kikui
仁 菊井
Keizo Ichinose
圭三 一ノ瀬
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sumitomo Chemical Co Ltd
Original Assignee
Sumitomo Chemical Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sumitomo Chemical Co Ltd filed Critical Sumitomo Chemical Co Ltd
Priority to JP4153879A priority Critical patent/JPH05341123A/en
Publication of JPH05341123A publication Critical patent/JPH05341123A/en
Pending legal-status Critical Current

Links

Landscapes

  • Liquid Crystal (AREA)
  • Polarising Elements (AREA)

Abstract

PURPOSE:To eliminate the generation of moire stripe of a normally white type liquid crystal display, and obtain the faceplate easy to be seen by specifying the mean height of projecting parts of the surface of a coating layer in a polarizing plate coated with a glaring preventing function layer. CONSTITUTION:A protecting film is attached to both surfaces of a polarizer, and a hard coating layer made of the composition, which includes the ultraviolet rays hardening type resin and inorganic particle and/or organic particle, is laminated on the other surface of one protecting film, which is not attached to the polarizer. As the ultraviolet rays hardening type resin, the resin, which has the excellent adhesion with the protecting film and a high coating hardness and the excellent chemical resistance and which is hardened easily by the ultraviolet rays, is desirably used. The mean height of projecting parts of the surface of a hard coating layer is set at 7m or less. A glaring preventing polarizing plate, which is thereby obtained, is used for the upper polarizing plate and laminated on a liquid crystal coating device so that the hard coating layer is positioned as the top surface, and under the condition that a back light is lighted, the moire stripe is not generated in a transmission type display to obtain the faceplate easy to be seen.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は、偏光板および液晶表示
装置に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a polarizing plate and a liquid crystal display device.

【0002】[0002]

【従来の技術および発明が解決しようとする課題】偏光
板は液晶表示装置に広く用いられ、表示画面の大型化、
用途分野の拡大と共に、多くの機能が要求されている。
携帯用のパソコンやワ─プロでは液晶表示画面に外光が
反射して表示が見にくくなるのを防ぐため、防眩機能層
を被覆した偏光板が多く用いられている。防眩機能層は
偏光板上面に紫外線硬化型樹脂と無機及び/あるい有機
粒子を含む組成物で硬化被覆したものである。防眩機能
層付き偏光板を液晶表示装置上面に積層した場合、外光
反射は抑制できる。しかしながらノ─マリ─ホワイト方
式の液晶表示では防眩効果はあるものの、モアレ縞が発
生するという問題が起こる。これまでの防眩機能層付き
偏光板では充分に視認性の高い画面にはなっていない。
2. Description of the Related Art Polarizing plates are widely used in liquid crystal display devices to increase the size of the display screen.
Many functions are required as the field of use expands.
In a portable personal computer or a word processor, a polarizing plate coated with an antiglare function layer is often used in order to prevent external light from being reflected on a liquid crystal display screen to make it difficult to see the display. The antiglare functional layer is formed by curing and coating the upper surface of the polarizing plate with a composition containing an ultraviolet curable resin and inorganic and / or organic particles. When a polarizing plate with an antiglare function layer is laminated on the upper surface of a liquid crystal display device, reflection of external light can be suppressed. However, although the normally white liquid crystal display has an antiglare effect, it causes a problem that moire fringes occur. The polarizing plate with the antiglare function layer so far does not have a sufficiently high visibility screen.

【0003】本発明者らは、防眩機能層を被覆した偏光
板において、該被覆層表面凸部の平均高さを制御するこ
とで、ノ─マリ─ホワイト方式の液晶表示装置でもモア
レ縞の発生はなく、非常に見やすい画面が得られること
を見出し本発明にいたった。
In the polarizing plate coated with the antiglare function layer, the inventors of the present invention control the average height of the convex portions on the surface of the coating layer to prevent moire fringes even in a normally white liquid crystal display device. The inventors have found that a screen that does not occur and is very easy to see is obtained, and the present invention has been completed.

【0004】[0004]

【課題を解決するための手段】即ち、本発明は、紫外線
硬化型樹脂ならびに無機粒子および/または有機粒子を
含有する組成物からなる硬化被覆層を片面に積層してな
る偏光板であって、かつ該被覆層表面の凸部の平均高さ
が7μm以下であることを特徴とする防眩用偏光板と、
それを用いた液晶表示装置に関するものである。
That is, the present invention provides a polarizing plate comprising a cured coating layer composed of a composition containing an ultraviolet curable resin and inorganic particles and / or organic particles laminated on one side, And the polarizing plate for antiglare, wherein the average height of the convex portions on the surface of the coating layer is 7 μm or less,
The present invention relates to a liquid crystal display device using the same.

【0005】以下、本発明を詳細に説明する。本発明に
使用する紫外線硬化型樹脂としては例えば、紫外線硬化
型エポキシアクリレ─ト系樹脂等、トリアセチルセルロ
─ス等の保護フィルムとの密着性が良好で、紫外線で容
易に硬化でき、被覆硬度、耐薬品性が高ければどのよう
な樹脂でもよい。
The present invention will be described in detail below. Examples of the UV-curable resin used in the present invention include UV-curable epoxy acrylate resin and the like, which have good adhesion to a protective film such as triacetyl cellulose, and which can be easily cured by UV to form a coating. Any resin may be used as long as it has high hardness and chemical resistance.

【0006】本発明に使用される無機粒子、有機粒子と
しては、例えば無定形シリカ粉末、ポリカ─ボネ─ト粒
子等が挙げられ、これらは併用してもよい。
The inorganic particles and organic particles used in the present invention include, for example, amorphous silica powder, polycarbonate particles and the like, which may be used in combination.

【0007】本発明の偏光板に用いられる偏光子は通常
のものが使用され、例えば、ポリビニルアルコール系フ
ィルム、ポリビニルホルマールフィルム、ポリビニルア
セタールフィルム、ポリ(エチレン─酢酸)共重合体系
ケン化フィルムの如き親水性高分子フィルムに沃素及び
/または二色性染料を吸着配向せしめた沃素系及び/ま
たは染料系偏光フィルム、ポリビニルアルコール系フィ
ルムを脱水処理するか、或いはポリ塩化ビニルフィルム
を脱塩酸処理するかしてポリエンを配向せしめたポリエ
ン系偏光フィルムが挙げられる。
As the polarizer used in the polarizing plate of the present invention, a usual one is used, and examples thereof include polyvinyl alcohol films, polyvinyl formal films, polyvinyl acetal films, and poly (ethylene-acetic acid) copolymer saponified films. Whether the iodine- and / or dye-based polarizing film or polyvinyl alcohol-based film in which iodine and / or dichroic dye is adsorbed and oriented on the hydrophilic polymer film is dehydrated, or the polyvinyl chloride film is dehydrochlorinated Then, a polyene-based polarizing film obtained by orienting the polyene is exemplified.

【0008】偏光子の保護フィルムとして通常は透明性
に優れたトリアセチルセルロ─スフィルム(厚さは約5
0μm〜200μm)が使用され、該フィルムは偏光子
の両面にポリビニルアルコ─ル系接着剤で貼合する。本
発明の防眩用偏光板の片方の保護フィルムには偏光子と
貼り合わせない面に紫外線硬化型樹脂と無機粒子および
/または有機粒子を含有する組成物を硬化被覆させたも
のを用いる。
A triacetyl cellulose film (having a thickness of about 5) which is usually excellent in transparency as a protective film for a polarizer.
0 μm to 200 μm) is used, and the film is laminated on both surfaces of the polarizer with a polyvinyl alcohol adhesive. As one of the protective films of the antiglare polarizing plate of the present invention, one having an ultraviolet curable resin and a composition containing inorganic particles and / or organic particles cured and coated on the surface not bonded to the polarizer is used.

【0009】硬化被覆層表面の凸部の平均高さを7μm
以下にすることが必要であり、好ましくは5μm以下と
する。該防眩用偏光板を上偏光板として、硬化被覆層を
上面にして液晶表示装置に積層し、バックライト点灯
下、透過型で表示を見ると、モアレ縞は発生せず、非常
に見やすい画面となる。
The average height of the protrusions on the surface of the cured coating layer is 7 μm.
It is necessary to make it below, and preferably it is 5 μm or less. When the display is laminated in a liquid crystal display device with the cured coating layer as the upper polarizing plate and the cured coating layer as the upper polarizing plate, and a transmissive display is viewed under a backlight, a screen that is very easy to see without moire fringes. Becomes

【0010】[0010]

【発明の効果】本発明によれば、ノ─マリ─ホワイト方
式の液晶表示装置でもモアレ縞の発生はなく、非常に視
認性のよい表示画面となる。
According to the present invention, even in a normally white liquid crystal display device, moire fringes do not occur, and a display screen with excellent visibility can be obtained.

【0011】[0011]

【実施例】以下、実施例により本発明をさらに詳細に説
明するが、本発明は実施例に限定されるものではない。
本発明で示される凸部の平均高さは表面粗さ計(サ─フ
コム570A─3DF/東洋精密株式会社製)で測定し
た。
EXAMPLES The present invention will be described in more detail with reference to examples below, but the present invention is not limited to the examples.
The average height of the convex portions shown in the present invention was measured with a surface roughness meter (Surfcom 570A-3DF / manufactured by Toyo Seimitsu Co., Ltd.).

【0012】実施例1 無定形シリカ粉末(サイロイド244、富士デビンソン
社製)と紫外線硬化型エポキシアクリレ─ト系樹脂とか
らなる硬化被覆層を積層したトリアセチルセルロ─スフ
ィルム(山陽国策パルプ社製・商品名TAC−HA−
5、該硬化被覆層表面凸部の平均高さは3μmである)
を、ヨウ素系偏光子の片面に貼合し、逆の面は通常のト
リアセチルセルロースフィルムを貼合して防眩用偏光板
を得る。該防眩用偏光板を、液晶表示装置の上面に積層
し、バックライト点灯下、透過型で表示を見るとモアレ
縞は発生せず、非常に見やすい画面となる。
Example 1 A triacetyl cellulose film (Sanyo Kokusaku Pulp Co., Ltd.) in which a cured coating layer composed of amorphous silica powder (Cyroid 244, manufactured by Fuji Devinson) and an ultraviolet curable epoxy acrylate resin was laminated. Product name: TAC-HA-
5, the average height of the convex portions on the surface of the cured coating layer is 3 μm)
Is bonded to one surface of an iodine-based polarizer, and the other surface is bonded to a normal triacetyl cellulose film to obtain an antiglare polarizing plate. When the antiglare polarizing plate is laminated on the upper surface of the liquid crystal display device and the display is viewed in a transmissive mode under lighting of a backlight, moire fringes do not occur and the screen becomes very easy to see.

【0013】実施例2 ポリカ─ボネ─ト樹脂ビ─ズと紫外線硬化型樹脂とから
なる硬化被覆層(該硬化被覆層表面凸部の平均高さは3
μmである)を用いる以外は実施例1と同様に実験を行
い、防眩用偏光板を得る。該防眩用偏光板を液晶表示装
置の上面に積層し、バックライト点灯下、透過型で表示
を見るとモアレ縞は発生せず、非常に見やすい画面とな
る。
Example 2 A cured coating layer comprising a polycarbonate resin bead and an ultraviolet curable resin (the average height of the convex portions on the surface of the cured coating layer is 3).
The same experiment as in Example 1 is carried out except that the antiglare polarizing plate is obtained. When the antiglare polarizing plate is laminated on the upper surface of the liquid crystal display device and the display is viewed in a transmissive mode with the backlight lit, no moire fringes occur and the screen becomes very easy to see.

【0014】比較例1 硬化被覆層表面凸部の平均高さが8μmである以外は実
施例1と同様に実験を行い、防眩用偏光板を得る。該防
眩機能付き偏光板を、液晶表示装置の上面に積層し、バ
ックライト点灯下、透過型で表示を見るとモアレ縞が発
生し、非常に見にくい画面となる。
Comparative Example 1 An antiglare polarizing plate was obtained by conducting the same experiment as in Example 1 except that the average height of the convex portions on the surface of the cured coating layer was 8 μm. When the polarizing plate with an antiglare function is laminated on the upper surface of a liquid crystal display device and a display is viewed with a transmissive display under lighting of a backlight, moire fringes are generated, which makes the screen very difficult to see.

Claims (2)

【特許請求の範囲】[Claims] 【請求項1】紫外線硬化型樹脂ならびに無機粒子および
/または有機粒子を含有する組成物からなる硬化被覆層
を片面に積層してなる偏光板であって、かつ該被覆層表
面の凸部の平均高さが7μm以下であることを特徴とす
る防眩用偏光板。
1. A polarizing plate comprising a cured coating layer composed of a composition containing an ultraviolet curable resin and inorganic particles and / or organic particles laminated on one side, and the average of the convex portions on the surface of the coating layer. A polarizing plate for antiglare, which has a height of 7 μm or less.
【請求項2】紫外線硬化型樹脂ならびに無機粒子および
/または有機粒子を含有する組成物からなる硬化被覆層
を片面に積層してなる偏光板であって、かつ該被覆層表
面の凸部の平均高さが7μm以下である防眩用偏光板を
積層してなる液晶表示装置。
2. A polarizing plate comprising a cured coating layer composed of a composition containing an ultraviolet curable resin and inorganic particles and / or organic particles laminated on one side, and the average of the convex portions on the surface of the coating layer. A liquid crystal display device comprising a stack of antiglare polarizing plates having a height of 7 μm or less.
JP4153879A 1992-06-12 1992-06-12 Polarizing plate and liquid crystal display Pending JPH05341123A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP4153879A JPH05341123A (en) 1992-06-12 1992-06-12 Polarizing plate and liquid crystal display

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP4153879A JPH05341123A (en) 1992-06-12 1992-06-12 Polarizing plate and liquid crystal display

Publications (1)

Publication Number Publication Date
JPH05341123A true JPH05341123A (en) 1993-12-24

Family

ID=15572108

Family Applications (1)

Application Number Title Priority Date Filing Date
JP4153879A Pending JPH05341123A (en) 1992-06-12 1992-06-12 Polarizing plate and liquid crystal display

Country Status (1)

Country Link
JP (1) JPH05341123A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100386856B1 (en) * 1998-12-14 2003-06-09 엔이씨 엘씨디 테크놀로지스, 엘티디. Liquid crystal display device
KR100471193B1 (en) * 2002-09-18 2005-03-10 스마트전자 주식회사 Element with protection membrane and manufacturing method thereof
US7341355B2 (en) 2003-08-13 2008-03-11 Sumitomo Chemical Company, Limited Anti-glare optical film and process for preparing the same

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100386856B1 (en) * 1998-12-14 2003-06-09 엔이씨 엘씨디 테크놀로지스, 엘티디. Liquid crystal display device
KR100471193B1 (en) * 2002-09-18 2005-03-10 스마트전자 주식회사 Element with protection membrane and manufacturing method thereof
US7341355B2 (en) 2003-08-13 2008-03-11 Sumitomo Chemical Company, Limited Anti-glare optical film and process for preparing the same

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