JPH05328960A - Fruit wine and its production - Google Patents

Fruit wine and its production

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Publication number
JPH05328960A
JPH05328960A JP16193292A JP16193292A JPH05328960A JP H05328960 A JPH05328960 A JP H05328960A JP 16193292 A JP16193292 A JP 16193292A JP 16193292 A JP16193292 A JP 16193292A JP H05328960 A JPH05328960 A JP H05328960A
Authority
JP
Japan
Prior art keywords
fruit
fruit juice
oxygen
conventional method
juice
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP16193292A
Other languages
Japanese (ja)
Other versions
JP3023814B2 (en
Inventor
Masaaki Nagao
公明 長尾
Yoko Sato
陽子 佐藤
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
MANZUWAIN KK
Original Assignee
MANZUWAIN KK
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Filing date
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Abstract

PURPOSE:To obtain an elegant fruit wine, having stable color and luster and good in flavor without adding and using sulfurous CONSTITUTION:A fruit such as grape, apple or peach is crushed and a juice is pressed according to a conventional method to provide a raw fruit juice, which is subjected to contact reaction with oxygen or an oxygen-containing gas such as air. Thereby, a chromogen is presubjected to oxidative polymerization to increase the hue by 100-250% once. The resultant oxidation polymer is then removed by centrifugation and filtration through Celite(R), etc. The obtained clear fruit juice is then subjected to alcoholic fermentation according to a conventional method to afford the objective elegant fruit wine, having stable color and luster and good in flavor without adding sulfurous acid thereto.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は、淡麗かつ色沢が安定
で、風味の良好な、亜硫酸無添加の果実酒に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a fruit liquor that is light and stable in color, has a good flavor, and contains no sulfite.

【0002】[0002]

【従来技術】果実酒は搬入された原料となる果実類を破
砕、搾汁し、得られた生果汁に酵母を添加しアルコール
発酵させて得られるが、該原料となる果実類を常法によ
り破砕、搾汁してその組織を破壊すると、果汁に含まれ
る酸化酵素(ポリフェノールオキシダーゼ、チロシナー
ゼ等)により、同果汁中のポリフェノール特にタンニン
が酵素的に酸化褐変を起こし、酸化臭が強くなり、また
外観、新鮮味が損われ、また原料に付着する性質不明の
野性酵母、乳酸菌が繁殖して風味良好な果実酒が得にく
くなることから、前記果実の破砕、搾汁する工程の前又
はその工程中に亜硫酸が添加使用されている。
2. Description of the Related Art Fruit wine is obtained by crushing and squeezing the fruits that are the raw materials that have been brought in, and adding yeast to the fresh fruit juice obtained and subjecting it to alcohol fermentation. When the tissue is crushed and squeezed to destroy the tissue, the oxidase (polyphenol oxidase, tyrosinase, etc.) contained in the fruit juice causes polyphenols, especially tannin, in the fruit juice to enzymatically brown, and the oxidative odor becomes strong. Appearance and freshness are impaired, and wild yeasts and lactic acid bacteria of unknown properties that adhere to the raw materials are propagated, and it becomes difficult to obtain fruit wine with good flavor, so it is difficult to obtain fruit wine with good flavor, so before or during the process of crushing and squeezing the fruit. Sulfurous acid is added to and used in.

【0003】[0003]

【発明が解決しようとする課題】近年、健康食品或いは
自然食品への関心が高まりを見せてきており、褐変防止
剤や防腐剤等の食品添加物の入らない食品が人気を呼ん
でいるが、果実酒も例外ではない。また、果実酒の製造
法において、この亜硫酸の添加は上記のような理由から
ばかりでなく、添加濃度に伴い果実酒の風味を阻害し、
またアルコール発酵の際、予め選択育種され、添加され
た優良酵母等の生育、繁殖を阻害することから、出来る
限り制限するか、または廃止することが望ましい。
In recent years, interest in health foods and natural foods has been increasing, and foods containing no food additives such as anti-browning agents and preservatives have been popular, Fruit wine is no exception. In addition, in the method for producing fruit liquor, the addition of this sulfurous acid is not only for the reasons described above, but also inhibits the flavor of fruit liquor with the concentration added,
Further, it is desirable to limit or abolish it as much as possible because it inhibits the growth and reproduction of excellent yeast and the like that have been selectively bred and added in advance during alcohol fermentation.

【0004】しかしながら、この亜硫酸の添加を無造作
に制限又は廃止すれば、果汁に含まれる酸化酵素によ
り、同果汁中の色源体であるポリフェノールが酵素的に
酸化褐変を起こし、香味上及び外観、新鮮味が損われ、
また原料に付着する性質不明の野性酵母、乳酸菌がたち
どころに繁殖して風味良好な果実酒が得にくくなる問題
が発生し、得られる果実酒の商品価値を損うものであ
る。また、原料となる果実の破砕、搾汁からアルコール
発酵、製成まで低温管理したり、不活性ガス(窒素ガ
ス、炭酸ガス)を使用して酸化を防止をする方法も検討
されたが、この方法で得られる果実酒は瓶詰後、経日的
に褐変増色し、風味も悪くなるという欠点を有してい
る。
However, if the addition of this sulfurous acid is randomly restricted or eliminated, the oxidase contained in the fruit juice causes polyphenol, which is a color source in the fruit juice, to enzymatically brown, thereby improving the flavor and appearance, The freshness is lost,
Further, wild yeasts and lactic acid bacteria of unknown properties attached to the raw material are apt to propagate in a short period of time, which makes it difficult to obtain fruit wine having a good flavor, which impairs the commercial value of the fruit wine obtained. In addition, methods such as crushing the fruit as a raw material, squeezing juice to alcoholic fermentation, low temperature control from production, and preventing oxidation by using inert gas (nitrogen gas, carbon dioxide gas) were also studied. The fruit liquor obtained by the method has a drawback that after bottling, it is browned and increased in color over time, and the flavor is deteriorated.

【0005】この様に新しい独創的な新技術を導入する
ことなく、亜硫酸の添加を廃止することは、品質を犠牲
にして造られる、宗教上の儀式(例えばミサ用)に使用
される特殊な果実酒を除き、通常の果実酒では常識外の
ことであり、現実に業界においては不可能と考えられ、
実施されていないのが現状である。
Abolishing the addition of sulfurous acid without introducing new and original new technology in this way is a special one used for religious ceremonies (for masses, for example) that is made at the expense of quality. Except for fruit liquor, normal fruit liquor is out of the ordinary, and in reality it is considered impossible in the industry,
Currently, it is not implemented.

【0006】[0006]

【課題を解決するための手段】このような現状に対し
て、本発明者らは、果実類を常法により破砕、搾汁して
生果汁を得、これに酸素または酸素含有気体を強制的に
接触反応せしめ、色源体を予め酸化重合させて色度を一
旦100〜250%増大させ、次いでこの酸化重合物質
を除去して清澄果汁を得、次いでこれに常法により酵母
を接種してアルコール発酵を行うときは、亜硫酸を全く
添加使用することなく従来の果実酒と全く遜色がない、
即ち淡麗かつ色沢が安定で、風味も良好な果実酒が得ら
れることを知り、この知見に基いて本発明を完成した。
[Means for Solving the Problems] Under these circumstances, the present inventors crushed and squeezed fruits by a conventional method to obtain fresh fruit juice, and forcedly added oxygen or oxygen-containing gas thereto. The chromogen is preliminarily oxidatively polymerized to increase the chromaticity once by 100 to 250%, and then the oxidatively polymerized substance is removed to obtain clear fruit juice, which is then inoculated with yeast by a conventional method. When carrying out alcoholic fermentation, there is no difference from conventional fruit liquor without adding and using sulfurous acid at all.
That is, it was found that a fruit liquor with a light and stable color and a good flavor can be obtained, and the present invention was completed based on this finding.

【0007】即ち、本発明は総タンニンが150ppm
以下、且つ総亜硫酸が20ppm以下である果実酒であ
り、また本発明は果実類を常法により破砕、搾汁して生
果汁を得、これに酸素または酸素含有気体を強制的に接
触反応せしめ、色源体を予め酸化重合させて色度を一旦
100〜250%増大させ、次いでこの酸化重合物質を
除去し、得られた果汁を常法によりアルコール発酵させ
ることを特徴とする果実酒の製造法であり、また本発明
は果実類を常法により破砕、搾汁して生果汁を得、これ
に酸素または酸素含有気体を強制的に接触反応せしめ、
色源体を予め酸化重合させて色度を一旦100〜250
%増大させ、次いでこの酸化重合物質を除去して、66
0nmにおける10mmセルの吸光度が0.2以下であ
る清澄果汁を得、次いでこれを常法によりアルコール発
酵させることを特徴とする果実酒の製造法である。
That is, according to the present invention, the total tannin is 150 ppm.
The present invention is a fruit liquor having a total sulfurous acid content of 20 ppm or less, and the present invention is to crush and squeeze fruits by a conventional method to obtain fresh fruit juice, which is forcibly contact-reacted with oxygen or an oxygen-containing gas. The production of fruit liquor characterized in that the color source is preliminarily oxidatively polymerized to increase the chromaticity once by 100 to 250%, then the oxidatively polymerized substance is removed, and the obtained fruit juice is subjected to alcohol fermentation by a conventional method. The present invention is also a method of crushing fruits by a conventional method and squeezing to obtain fresh fruit juice, which is subjected to forced contact reaction with oxygen or oxygen-containing gas,
The chromaticity is once set to 100-250 by pre-oxidizing and polymerizing the color source.
%, Then the oxidatively polymerized material is removed to give 66
A method for producing fruit wine, characterized in that a clear juice having an absorbance of 10 mm cell at 0 nm of 0.2 or less is obtained, and then this is subjected to alcohol fermentation by a conventional method.

【0008】以下本発明を詳細に説明する。本発明に用
いられる原料は、ブドウ、リンゴ、ナシ、モモ、ウメ、
プラム、アンズ、キウイフルーツ、パイナップル、イチ
ゴ、柑橘類等の果実類であり、これらの1種または2種
以上を常法により選果の後洗浄し、そのまま、または必
要により茎、芯、種、皮等の除去処理等の前処理を行な
った後これを破砕、搾汁して得られた生果汁が好適に用
いられる。
The present invention will be described in detail below. Raw materials used in the present invention include grapes, apples, pears, peaches, plums,
Plums, apricots, kiwifruits, pineapples, strawberries, citrus fruits, and the like. One or more of these fruits are selected and washed by a conventional method, and as they are, or if necessary, stems, cores, seeds, and skins. Fresh fruit juice obtained by crushing and squeezing this after performing pretreatment such as removal treatment of the above is preferably used.

【0009】破砕、搾汁の処理はミキサー、ジューサ
ー、カッター、フィニッシャー等により破砕した後、該
破砕物を濾袋に充填し圧搾して搾汁する濾布プレス法、
スクリュープレス法、デイスクプレス法等の通常の装置
を用いて、実施することができる。従来、この破砕、搾
汁の処理中又は処理直後に亜硫酸等の褐変防止剤が添加
されていたが、この発明において添加する必要はない。
なお、果汁の清澄促進と果汁歩合を向上させるために、
必要によりペクチン分解酵素を10〜40ppm添加使
用することが好ましい。
The processing of crushing and squeezing is carried out by a mixer, a juicer, a cutter, a finisher, etc., and then the crushed material is filled in a filter bag and squeezed to squeeze the juice by a filter cloth pressing method,
It can be carried out using an ordinary apparatus such as a screw press method or a disk press method. Conventionally, an anti-browning agent such as sulfurous acid was added during or immediately after the crushing or squeezing treatment, but it is not necessary to add it in the present invention.
In addition, in order to promote the clarification of fruit juice and improve the fruit juice ratio,
If necessary, it is preferable to add 10 to 40 ppm of pectin-degrading enzyme.

【0010】本発明ではこうして得られた生果汁に酸素
または酸素含有気体(空気或いはこれに純酸素を混和し
た高濃度酸素含有ガス等)を吹込むかまたは、両者を激
しく攪拌するなどして、強制的に接触反応せしめ、色源
体を予め酸化重合させて色度を一旦100〜250%増
大させる。ここでいう「色度」とは、光電比色計を用い
た430nmにおける10mmセルの吸光度(OD)を
意味し、「100〜250%増大させた」とは、次の式
により求めた値を意味する。 (B−A)×100÷A 但しB=反応後の色度(OD)、A=初発の色度(O
D)
In the present invention, oxygen or an oxygen-containing gas (such as air or a high-concentration oxygen-containing gas obtained by mixing pure oxygen with air) is blown into the fresh fruit juice thus obtained, or both are vigorously agitated. The reaction is forcibly carried out, and the chromogen is pre-oxidized and polymerized to temporarily increase the chromaticity by 100 to 250%. "Chromaticity" as used herein means the absorbance (OD) of a 10 mm cell at 430 nm using a photoelectric colorimeter, and "increased by 100 to 250%" means the value obtained by the following formula. means. (B−A) × 100 ÷ A, where B = chromaticity (OD) after reaction, A = initial chromaticity (O
D)

【0011】この値は、果実の種類、熟度によっても多
少異なるが、例えばブドウの場合は、生果汁を35〜4
5℃で、60〜90分反応させることにより得られる。
反応は開放系で行なってもよいが、密閉系において行な
うことが好ましい。また、接触させる気体はいずれでも
よいが、空気に比べ高濃度酸素含有ガス、とくに純酸素
ガスは短時間に反応を終了することができ、接触による
風味の劣化が少ないので好ましい。
[0011] This value is somewhat different depending on the type and maturity of the fruit, but in the case of grape, for example, fresh juice of 35 to 4 is used.
It is obtained by reacting at 5 ° C for 60 to 90 minutes.
The reaction may be carried out in an open system, but it is preferably carried out in a closed system. Any gas may be brought into contact, but a gas having a high concentration of oxygen, particularly pure oxygen gas, is preferable as compared with air because the reaction can be completed in a short time and the flavor is less deteriorated by contact.

【0012】次いで得られる反応液は、室温以下、例え
ば10〜15℃に冷却した後、ケイソウ土、セルロース
パウダー、ダイカライト(商品名、三井金属工業社製
造)等の濾過助剤を加え、或いは加えることなく通常の
濾過処理、または遠心分離を行い、反応液中において不
溶性となった褐色の着色物質(酸化重合物質)を除去す
る。
The resulting reaction liquid is then cooled to room temperature or lower, for example, 10 to 15 ° C., and then a filter aid such as diatomaceous earth, cellulose powder, Dicalite (trade name, manufactured by Mitsui Metal Industry Co., Ltd.) is added, or Ordinary filtration or centrifugation is carried out without addition to remove insoluble brown colored substance (oxidized polymerized substance) in the reaction solution.

【0013】このように酸化重合物質を果汁より分離除
去すると、原料由来の新鮮な香りを有する果汁が得ら
れ、またこれをアルコール発酵させると淡麗でかつ色沢
の安定な、香味の非常に優れた果実酒が得られる。そし
て、除去に際し、特に660nmにおける10mmセル
の吸光度が0.2以下、特に0.1以下である清澄果汁
を得るときは、その効果が著しいので好ましい。
By separating and removing the oxidatively polymerized substance from the fruit juice in this way, a fruit juice having a fresh scent derived from the raw material is obtained, and when this is alcohol-fermented, it is beautiful and stable in color and has a very strong flavor. Excellent fruit wine is obtained. Further, when removing, in particular, when a clear juice having a 10 mm cell absorbance at 660 nm of 0.2 or less, particularly 0.1 or less is obtained, its effect is remarkable, which is preferable.

【0014】次いで、このようにして得られた処理果汁
を常法により酒用酵母を添加した後、5〜35℃で7〜
60日間アルコール発酵させる。用いられる酒用酵母と
しては通常の果実酒製造に用いられる酵母、例えばワイ
ン酵母、清酒酵母等が好適な例として挙げられ、この最
も代表的なものとしては例えば、サッカロミセス・セレ
ビシエ、サッカロミセス・バリエタス(Var.)・エ
リプソイデウス等が挙げられる。
Then, the treated fruit juice thus obtained is added with yeast for liquor by a conventional method, and then at 7 to 5 ° C. for 7 to 5 ° C.
Ferment with alcohol for 60 days. Suitable examples of the liquor yeast used include yeasts used in ordinary fruit liquor production, such as wine yeast and sake yeast, and the most typical examples thereof include Saccharomyces cerevisiae and Saccharomyces varietas ( Var.) And Ellipsoideus.

【0015】尚、アルコール発酵の前の処理果汁或い
は、アルコール発酵の途中の醪に糖類、例えば砂糖、グ
ルコース、フラクトース等を添加すれば、製品のアルコ
ール分、エキス分が増加して香味がより改善される。
If sugars such as sugar, glucose and fructose are added to the processed fruit juice before alcohol fermentation or the mash during the alcohol fermentation, the alcohol content and the extract content of the product are increased and the flavor is further improved. To be done.

【0016】アルコール発酵を終了した醪は、常法によ
りオリ引きした後、例えばケイソウ土、セルロースパウ
ダー等を用いての濾過、遠心分離等による清澄濾過を行
なって酵母菌体等を除き、そのまま又は必要により容器
に貯蔵して嫌気的に保ち例えば3〜12ヵ月間、蛋白安
定化、酒石安定化などの製成処理を行ない瓶詰し、製品
とする。
After the alcoholic fermentation is completed, the mash is subjected to a conventional method, followed by filtration using diatomaceous earth, cellulose powder, etc., and clarification filtration by centrifugation etc. to remove yeast cells, etc., or If necessary, the product is stored in a container and kept anaerobically, for example, for 3 to 12 months, subjected to production treatment such as protein stabilization and tartar stabilization, and bottled to obtain a product.

【0017】このようにして得られる本発明の果実酒
は、殆ど無色で透明度が優れていて、淡麗であり、また
新鮮感のある芳香の高い、優れた香味を有し、しかもこ
れらの安定性が極めて良好なものである。
The fruit liquor of the present invention thus obtained is almost colorless, has excellent transparency, is light, has a fresh and highly aromatic scent, and is highly stable. It has very good properties.

【0018】[0018]

【本発明の効果】果実類を常法により破砕、圧搾して生
果汁を得、これに酸素または酸素含有気体を強制的に接
触反応せしめ、色源体を予め酸化重合し色度を一旦10
0〜250%増大させ、次いでこの酸化重合物質を除去
して清澄果汁を得、次いでこれに常法により酵母を接種
してアルコール発酵を行うものであるから、総タンニン
が150ppm以下で且つ総亜硫酸が20ppm以下の
従来全く知られていない果実酒が得られ、また原料果実
に残留する農薬由来の硫黄化合物が、微生物の発酵の過
程で亜硫酸に変化し生成することが時々認められるがこ
れは殆ど無視できるくらい少量(通常は20ppm以
下)であり、本発明では製造工程前或いはその途中にお
いて亜硫酸の添加が全く行なわれないので、亜硫酸によ
る果実酒の風味の変化が防止され、また予め選択育種さ
れた優良酵母等が亜硫酸によって生育、繁殖を阻害され
ることがないので、アルコール発酵が頗る旺盛に行なわ
れるために、風味が非常に良好で、また果実酒における
色源体である総タンニンが150ppm以下にまで除去
されているために、褐変防止剤を添加しなくとも製造後
の製品の淡麗な色沢が安定に保たれる。
EFFECTS OF THE INVENTION Fruits are crushed and squeezed by a conventional method to obtain fresh fruit juice, and oxygen or an oxygen-containing gas is forcibly contact-reacted therewith, and the chromogen is preliminarily oxidatively polymerized to give a chromaticity of 10
The amount of tannin is 150 ppm or less and the total sulfite is increased by increasing the ratio of 0 to 250%, and then removing this oxidatively polymerized substance to obtain a clear fruit juice, which is then inoculated with yeast by a conventional method for alcohol fermentation. It has been found that fruit liquor with a concentration of 20 ppm or less, which has not been known at all, can be obtained, and that sulfur compounds derived from agricultural chemicals that remain in the raw fruit are converted to sulfurous acid during the fermentation process of microorganisms, but this is almost always observed. It is a negligible amount (usually 20 ppm or less), and in the present invention, no sulfurous acid is added before or during the manufacturing process, so that the change in the flavor of fruit wine due to sulfurous acid is prevented, and the selective breeding is performed in advance. Sulfurous acid does not interfere with the growth and reproduction of excellent yeasts, so alcohol fermentation is vigorous and the flavor is excellent. It is always good, and the total tannin, which is a color source in fruit wine, is removed to 150 ppm or less, so that the beautiful color of the product after production can be stably maintained without adding a browning inhibitor. Be done.

【0019】以下、実施例を挙げて本発明をより具体的
に説明する。
Hereinafter, the present invention will be described more specifically with reference to examples.

【実施例1】「 生果汁への通気条件と処理果汁の着色度、果実酒製品
の特徴」 原料として、甲州種ぶどうを搾汁し得られる生果汁を使
用した。上記生果汁を38〜40℃に加温し、その温度
において下記表1記載の通気条件で空気を強制的に吹込
み(接触反応処理し)、処理後の色沢を日立光電光度計
を用いて10mmセルの430nmにおける吸光度(OD)
を求めた。また、得られた反応処理果汁をケイソウ土濾
過し、該処理果汁中の酸化重合物質を除去し、得られた
果汁に、ワイン酵母OC−2(日本醸造協会酵母サッカ
ロミセス・セレビシエ、同協会販売)を2%(容量)相
当加え、半密閉容器にて常法により15〜20℃で2週
間発酵を行なった。発酵終了後、常法によりケイソウ土
による清澄濾過を行ないワインを得た。この製造直後の
色沢(10mmセルの660nmにおける吸光度OD)
と風味の官能検査を行ない、またこれを35℃下で1ヵ
月経過した後、次式によりその増色度を測定した。 (B−A)×100÷A、但しB=1ヵ月経過後の色
沢、A=初発の色沢 それらの結果をまとめて、表1に示す。
[Example 1] "Aeration conditions for fresh fruit juice, coloring degree of treated fruit juice, characteristics of fruit liquor product" As a raw material, fresh fruit juice obtained by squeezing Koshu grape was used. The fresh fruit juice was heated to 38 to 40 ° C., and at that temperature, air was forcibly blown (contact reaction treatment) under the aeration conditions shown in Table 1 below, and the treated color was measured using a Hitachi photoelectric photometer. Absorbance (OD) of 10 mm cell at 430 nm
I asked. Further, the obtained reaction-treated fruit juice was subjected to diatomaceous earth filtration to remove oxidatively polymerized substances in the treated fruit juice, and the obtained fruit juice was added to wine yeast OC-2 (Japanese Sake Association Saccharomyces cerevisiae, sold by the association). 2% (volume) was added and fermentation was carried out in a semi-sealed container at 15 to 20 ° C. for 2 weeks by a conventional method. After the fermentation was completed, clarification filtration with diatomaceous earth was performed by a conventional method to obtain a wine. Irozawa immediately after this production (absorbance OD at 660 nm of 10 mm cell)
The sensory test for flavor was conducted, and after one month at 35 ° C., the degree of color increase was measured by the following formula. (B−A) × 100 ÷ A, where B = color zawa after one month has elapsed, A = color storm of the first time, and the results are summarized in Table 1.

【0020】[0020]

【表1】 [Table 1]

【0021】表1の結果から、果実類を常法により破
砕、圧搾して生果汁を得、これに酸素または酸素含有気
体を強制的に接触反応せしめ、色源体を予め酸化重合し
色度を一旦100〜250%増大させ、次いでこの酸化
重合物質を除去し、次いで得られた果汁を常法によりア
ルコール発酵を行うことにより、色調、透明度が優れ
て、新鮮感のある芳香の高い、優れた香味を有し、しか
もこれら色調の透明度の安定性が極めて良好な果実酒が
得られることが判る。
From the results shown in Table 1, fruits are crushed and squeezed by a conventional method to obtain fresh fruit juice. Oxygen or an oxygen-containing gas is forcibly contact-reacted with this, and the chromogen is preliminarily oxidatively polymerized to obtain chromaticity. Is increased by 100 to 250%, then the oxidatively polymerized substance is removed, and then the obtained fruit juice is subjected to alcohol fermentation by a conventional method, whereby the color tone and transparency are excellent, the freshness is high and the fragrance is excellent. It can be seen that a fruit liquor having an excellent flavor and extremely excellent stability of transparency of these color tones can be obtained.

【0022】[0022]

【実施例2】 「酸化重合物質を除去後の生果汁の濁度と製品果実酒の
風味」原料として、甲州種ぶどうを搾汁し得られる生果
汁を使用した。上記生果汁を38〜40℃に加温し、そ
の温度において空気を強制的に90分間、吹込み(接触
反応処理し)、得られた反応処理果汁を9区分に分け、
第1区分は一晩静置した後、上澄液を採取し、第2〜7
区分は遠心分離(但し、遠心分離の条件を適宜変えて調
製)し、得られる各種濁度を有する上澄液を採取し、そ
して第8区分は上記第2区分で得られる上澄液をケイソ
ウ土を詰めたカラムに通液濾過して濁度の非常に少ない
澄明な液を採取し、区分1〜8のそれぞれ濁度の異なる
処理液を得た。上記で得られた果汁に、ワイン酵母OC
−2(日本醸造協会酵母サッカロミセス・セレビシエ、
同協会販売)を2%(容量)相当ずつ加え、半密閉容器
にて常法により15〜20℃で2週間発酵を行なった。
発酵終了後、常法によりケイソウ土による清澄濾過を行
ないワインを得た。また、比較のため、甲州種ぶどうを
搾汁し得られる生果汁に亜硫酸を40ppm加え、更に
清澄のためペクチナーゼ25ppm加え、一晩静置した
後上澄液を採取し、得られた果汁に、ワイン酵母OC−
2(日本醸造協会酵母サッカロミセス・セレビシエ、同
協会販売)を2%(容量)相当加え、半密閉容器にて常
法により15〜20℃で2週間発酵を行なった。発酵終
了後、常法によりケイソウ土による清澄濾過を行ないワ
インを得た。これに褐変防止のため亜硫酸80ppmを
添加し、対照のワインとした。このようにして得られた
各種ワインの色沢と風味の官能検査を行なった。それら
の結果をまとめて、表2に示す。なお、表中の亜硫酸の
濃度は、1990年6月30日、日本食品衛生協会発
行、「食品衛生検査指針(食品中の食品添加物分析
法)」、第84〜88頁記載の方法「二酸化硫黄及び亜
硫酸塩類試験法(比色法)」により測定した。
Example 2 "Turbidity of Fresh Fruit Juice after Removing Oxidized Polymeric Substance and Flavor of Product Fruit Sake" Raw material juice obtained by squeezing Koshu seed grape was used as a raw material. The above-mentioned fresh fruit juice was heated to 38 to 40 ° C., and at that temperature, air was forcibly blown for 90 minutes (contact reaction processing), and the obtained reaction-treated fruit juice was divided into 9 sections,
The first section was allowed to stand overnight, then the supernatant was collected and
The section is centrifuged (however, the centrifugation conditions are appropriately changed), the resulting supernatants having various turbidities are collected, and the eighth section is the supernatant obtained in the second section. A clear liquid with extremely low turbidity was collected by filtration through a column filled with soil to obtain treatment liquids having different turbidities of categories 1 to 8. To the fruit juice obtained above, wine yeast OC
-2 (Japanese Society of Brewing Yeast Saccharomyces cerevisiae,
2% (volume) equivalent was added by the same association, and fermentation was carried out in a semi-closed container at 15 to 20 ° C. for 2 weeks by a conventional method.
After the fermentation was completed, clarification filtration with diatomaceous earth was performed by a conventional method to obtain a wine. Further, for comparison, 40 ppm of sulfurous acid was added to fresh fruit juice obtained by squeezing Koshu grape, 25 ppm of pectinase was further added for clarification, and the mixture was allowed to stand overnight and the supernatant was collected. Wine yeast OC-
2 (Yeast Sake Saccharomyces cerevisiae, sold by the association) was added in an amount of 2% (volume), and fermented in a semi-sealed container at 15 to 20 ° C. for 2 weeks by a conventional method. After the fermentation was completed, clarification filtration with diatomaceous earth was performed by a conventional method to obtain a wine. To this, 80 ppm of sulfurous acid was added to prevent browning, which was used as a control wine. Sensory tests were performed on the various colors and flavors of the wines thus obtained. The results are summarized in Table 2. The concentration of sulfurous acid in the table is June 30, 1990, published by Japan Food Hygiene Association, "Food Hygiene Inspection Guideline (Food Additives Analysis Method in Foods)", pages 84-88. Sulfur and sulfite test method (colorimetric method) ".

【0023】[0023]

【表2】 [Table 2]

【0024】表2の結果から、果実類を常法により破
砕、圧搾して生果汁を得、これに酸素または酸素含有気
体を強制的に接触反応せしめ、色源体を予め酸化重合さ
せて色度を一旦100〜250%増大させ、次いでこの
酸化重合物質を除去するに際して、660nmにおける
10mmセルの吸光度が0.2以下、特に0.1以下と
なるように調製して得た清澄果汁を用いて、これに常法
により酵母を接種してアルコール発酵を行うときは、色
調、透明度が優れていて、新鮮感のある芳香の高い、優
れた香味を有し、しかもこれら色調、透明度の安定性が
極めて良好な果実酒が得られることが判る。従来、生果
実では、破砕、搾汁によりその組織の破壊を行うと酸化
酵素がポリフェノール類に作用して酵素的酸化褐変を生
じる。この褐変により、香味上及び外観、新鮮味が損わ
れる。従って、いろいろな果実酒製造法においては、組
織が破壊される破砕、搾汁工程前又は工程中に亜硫酸等
の褐変防止剤が添加され、また、更に発酵終了直後の果
実酒に対して再び酸化褐変を防止するために亜硫酸を添
加しなければならないが、これに対して、本発明によれ
ば、この様な亜硫酸を全く添加することなく、上述した
ような高品質の果実酒が得られる。近年健康志向の関心
が高まりをみせているが、ワイン業界においてもその例
外ではなく、このような添加物のない果実酒が得られる
本発明の意義は大きい。
From the results shown in Table 2, fruits are crushed and pressed by a conventional method to obtain fresh fruit juice, and oxygen or an oxygen-containing gas is forcibly contact-reacted therewith, and the color source is preliminarily oxidatively polymerized to obtain a color. When the oxidatively polymerized substance is removed by once increasing the degree of 100-250%, the clear juice obtained by adjusting the absorbance of the 10 mm cell at 660 nm to 0.2 or less, particularly 0.1 or less is used. When yeast is inoculated to this by conventional method and alcohol fermentation is performed, it has excellent color tone and transparency, has a fresh aroma, high aroma and excellent flavor, and the stability of these color tone and transparency is high. It can be seen that a very good fruit wine can be obtained. Conventionally, when crushing and squeezing the tissue of fresh fruit, the oxidase acts on polyphenols to cause enzymatic oxidative browning. This browning impairs flavor, appearance and freshness. Therefore, in various fruit liquor production methods, a browning inhibitor such as sulfurous acid is added before or during the crushing or squeezing process in which the tissue is destroyed, and the fruit liquor immediately after fermentation is oxidized again. Sulfurous acid must be added to prevent browning, whereas the present invention makes it possible to obtain the fruit wine of high quality as described above, without adding such sulfurous acid at all. Although interest in health-consciousness has been increasing in recent years, it is no exception in the wine industry, and the significance of the present invention to obtain such fruit wine without additives is great.

【0025】[0025]

【実施例3】 「酸素含有気体との接触反応の温度と、その温度により
繁殖する野生微生物が及ぼす製品の品質への影響」原料
として、甲州種ぶどうを搾汁し得られる生果汁を使用し
た。上記生果汁に対して、腐造ワインから分離した野生
酵母及び乳酸菌をそれぞれ103個/mlとなるように
添加し、これを表3に記載の如き温度に加温し、その温
度において色度が150%となるまで空気を強制的に吹
込み(接触反応処理し)、得られた反応処理果汁を遠心
分離(3,000r.p.m.で10分処理)し、得ら
れる上澄液をケイソウ土を詰めたカラムに通液濾過して
濁度の非常に少ない澄明な液を採取し、これに、ワイン
酵母OC−2(日本醸造協会酵母サッカロミセス・セレ
ビシエ、同協会販売)を2%(容量)相当ずつ加え、半
密閉容器にて常法により15〜20℃で2週間発酵を行
なった。発酵終了後、常法によりケイソウ土による清澄
濾過を行ないワインを得た。このようにして、酸素含有
気体との接触反応の温度と、その温度により繁殖する野
生酵母及び乳酸菌が及ぼす製品の品質への影響について
調べた。その結果を表3に示す。
[Example 3] "The temperature of the catalytic reaction with oxygen-containing gas and the effect of the wild microorganisms propagated by the temperature on the product quality" The raw fruit juice obtained by squeezing Koshu grape was used as a raw material. .. Wild yeast and lactic acid bacteria separated from rotten wine were added to the above-mentioned fresh fruit juice at a rate of 10 3 cells / ml, and this was heated to a temperature as shown in Table 3 and the chromaticity at that temperature was increased. Is forcibly blown (contact reaction treatment) until the content becomes 150%, and the resulting reaction-treated fruit juice is centrifuged (treatment at 3,000 rpm for 10 minutes) to obtain a supernatant liquid. Was filtered through a column packed with diatomaceous earth to collect a clear liquid with very low turbidity, and wine yeast OC-2 (Japanese brewing association yeast Saccharomyces cerevisiae, sold by the association) was 2%. (Volume) Correspondingly added, fermentation was carried out in a semi-sealed container at 15 to 20 ° C. for 2 weeks by a conventional method. After the fermentation was completed, clarification filtration with diatomaceous earth was performed by a conventional method to obtain a wine. In this way, the temperature of the contact reaction with the oxygen-containing gas and the influence of the wild yeast and lactic acid bacteria that propagate at that temperature on the quality of the product were investigated. The results are shown in Table 3.

【0026】[0026]

【表3】 [Table 3]

【0027】表3の結果から、酸素または酸素含有気体
との接触反応が、35℃よりも低い温度で反応するとき
は、反応時間が長くなり、また野性の好ましくない酵母
や乳酸菌が生存または増殖し、果実酒の発酵に悪影響を
及ぼすため高品質の果実酒を得ることができない。反対
に、45℃を越えるときは、野性の微生物による影響は
なくなるが、生果汁中に含まれる酸化酵素(ポリフェノ
ールオキシダーゼ、チロシナーゼ)が高温のため活性が
阻害されるため、反応時間が長くなる。また、高温度で
の酸化反応により果汁の好ましいフレーバーが逸散し
て、最終製品が芳醇な風味に乏しいものとなる。これに
対して反応温度を35〜45℃で行うと、例え圧搾生果
汁に野性酵母や野性乳酸菌が混入してもこの温度におい
ては死滅または増殖が阻害されるために、殆ど影響を受
けることなく安全に果実酒を得ることができる、また生
果汁中に含まれる酸化酵素が頗る良く働くため、非常に
短時間に反応が終了し、果汁中の好ましいフレーバーの
逸散が防止され、最終製品にまで移行し、芳醇な風味を
有する果実酒を得ることができる。
From the results shown in Table 3, when the catalytic reaction with oxygen or an oxygen-containing gas reacts at a temperature lower than 35 ° C., the reaction time becomes long, and unfavorable yeast or lactic acid bacteria survive or grow. However, high-quality fruit liquor cannot be obtained because it adversely affects the fermentation of fruit liquor. On the other hand, when the temperature exceeds 45 ° C, the influence of wild microorganisms disappears, but the activity of oxidases (polyphenol oxidase, tyrosinase) contained in fresh fruit juice is inhibited due to the high temperature, and the reaction time becomes long. Also, the oxidation reaction at high temperatures dissipates the desirable flavor of the fruit juice, making the final product less mellow in flavor. On the other hand, if the reaction temperature is carried out at 35 to 45 ° C, even if wild yeast or wild lactic acid bacteria is mixed in the raw fresh juice, it will be killed or inhibited at this temperature, so that it is hardly affected. Fruit wine can be safely obtained, and the oxidase contained in fresh fruit juice works extremely well, so the reaction is completed in a very short time, the dissipation of the desirable flavor in the fruit juice is prevented, and it becomes the final product. It is possible to obtain fruit wine having a rich flavor.

【0028】[0028]

【実施例4】「 ブドウを原料とする果実酒の製造」 原料として、甲州種ブドウを常法により破砕、搾汁し得
られる生果汁を使用した。上記ブドウ生果汁にペクチン
分解酵素スクラーゼ(三共株式会社製)を25ppm添
加溶解し、38〜40℃に加温し、その温度において酸
素を強制的に60分吹込み(接触反応処理し)、処理後
の色度を日立光電光度計を用いて10mmセルの430nm
における吸光度(OD)を測定し、色度を150%増大
させた反応処理果汁を得た。次いで、反応処理果汁を遠
心分離(3,000rpmで10分処理)後、ケイソウ
土濾過し、該処理果汁中の酸化重合物質を除去し、得ら
れた果汁に、ワイン酵母OC−2(日本醸造協会酵母サ
ッカロミセス・セレビシエ、同協会販売)を2%(容
量)相当加え、半密閉容器にて常法により15〜20℃
で2週間発酵を行なった。発酵終了後、常法によりケイ
ソウ土による清澄濾過を行ないワインを得た。なお、比
較の為上記破砕、搾汁し得られるブドウの生果汁に酸化
褐変防止と、野性の微生物の繁殖を防止する目的で亜硫
酸を40ppm添加し、また清澄促進の目的のためスク
ラーゼを25ppmとなるように添加溶解し、常法によ
り処理した後遠心分離(3,000rpmで10分処
理)して、清澄な果汁を得、以下上記と全く同様にワイ
ン酵母を加え、発酵を行なった後、ケイソウ土による清
澄濾過を行ない、次いで酸化褐変防止を目的として亜硫
酸をさらに80ppm添加溶解して対照区のワインを得
た。また、比較の為上記破砕、搾汁し得られるブドウの
生果汁にスクラーゼを25ppm添加溶解し、酸素を吹
込むことなくそのまま、上記と同様に遠心分離して、清
澄な果汁を得、ワイン酵母を加え、発酵を行なった後、
ケイソウ土による清澄濾過を行ない比較例のワインを得
た。次に上記で得られる生果汁と3種類の製品ワイン中
の総タンニンを測定し、また3種類の製品ワインを35
℃の温度で1ヵ月保存した後の色沢を測定し、また官能
検査を実施した。その結果を表4に示す。尚、表中の総
タンニンは、フォリン−デニス(Folin−Deni
s)法;O.Folin&W.Denis,J.Bio
l.Chem.,Vol12,239(1912)によ
り測定して求めた。
[Example 4] "Production of fruit liquor using grape as raw material" As a raw material, fresh fruit juice obtained by crushing and squeezing Koshu seed grape by a conventional method was used. 25 ppm of a pectin-degrading enzyme sucrase (manufactured by Sankyo Co., Ltd.) was added to and dissolved in the above-mentioned fresh grape juice, and the mixture was heated to 38 to 40 ° C., and oxygen was forcibly blown for 60 minutes at that temperature (contact reaction treatment), and treated. The subsequent chromaticity was measured using a Hitachi photoelectric photometer at 430 nm in a 10 mm cell.
The absorbance (OD) was measured to obtain a reaction-treated fruit juice having a chromaticity increased by 150%. Then, the reaction-treated fruit juice was centrifuged (treated at 3,000 rpm for 10 minutes), filtered through diatomaceous earth to remove oxidatively polymerized substances in the treated fruit juice, and the obtained fruit juice was added to wine yeast OC-2 (Nippon Brewery Co., Ltd.). 2% (volume) of Yeast Saccharomyces cerevisiae (sold by the association), equivalent to 2% (volume), and in a semi-sealed container at 15 to 20 ° C by a conventional method.
Fermentation was carried out for 2 weeks. After the fermentation was completed, clarification filtration with diatomaceous earth was performed by a conventional method to obtain a wine. For comparison, 40 ppm of sulfurous acid was added to the raw juice of grapes obtained by crushing and squeezing for the purpose of preventing oxidative browning and propagating wild microorganisms, and sucrase was added at 25 ppm for the purpose of promoting clarification. After adding and dissolving as described above, the mixture was treated by a conventional method and then centrifuged (treated at 3,000 rpm for 10 minutes) to obtain a clear fruit juice. After the addition of wine yeast in exactly the same manner as above, fermentation was carried out, Clarification filtration was performed with diatomaceous earth, and then 80 ppm of sulfurous acid was further added and dissolved for the purpose of preventing oxidative browning to obtain a control wine. For comparison, 25 ppm of sucrase was added to and dissolved in fresh grape juice obtained by crushing and squeezing, centrifugation was performed in the same manner as above without blowing oxygen, and clear juice was obtained to obtain wine yeast. After adding and fermenting,
Clarification filtration was performed with diatomaceous earth to obtain a comparative wine. Next, the total tannins in the fresh fruit juice and three kinds of product wines obtained above were measured, and three kinds of product wines were used.
After storing for 1 month at a temperature of ℃, the color was measured and the sensory test was conducted. The results are shown in Table 4. The total tannins in the table are Folin-Deni.
s) method; Folin & W. Denis, J .; Bio
l. Chem. , Vol 12, 239 (1912).

【0029】[0029]

【表4】 [Table 4]

【0030】[0030]

【実施例5】「 リンゴを原料とする果実酒の製造」 原料として、ふじ種リンゴを常法により破砕、搾汁し得
られる生果汁を使用した。上記リンゴ生果汁にペクチン
分解酵素スクラーゼ(三共株式会社製)を25ppm添
加溶解し、38〜40℃に加温し、その温度において酸
素を強制的に60分吹込み(接触反応処理し)、処理後
の色度を日立光電光度計を用いて10mmセルの430nm
における吸光度(OD)を測定し、色度を168%増大
させた反応処理果汁を得た。次いで、反応処理果汁を遠
心分離(3,000rpmで10分処理)後、ケイソウ
土濾過し、該処理果汁中の酸化重合物質を除去し、得ら
れた果汁に、ワイン酵母OC−2(日本醸造協会酵母サ
ッカロミセス・セレビシエ、同協会販売)を2%(容
量)相当加え、半密閉容器にて常法により15〜20℃
で2週間発酵を行なった。発酵終了後、常法によりケイ
ソウ土による清澄濾過を行ないリンゴ果実酒を得た。な
お、比較の為上記破砕、搾汁し得られるリンゴの生果汁
に酸化褐変防止と、野性の微生物の繁殖を防止する目的
で亜硫酸を40ppm添加し、また清澄促進の目的のた
めスクラーゼを25ppmとなるように添加溶解し、常
法により処理した後遠心分離(3,000rpmで10
分処理)して、清澄な果汁を得、以下上記と全く同様に
ワイン酵母を加え、発酵を行なった後、ケイソウ土によ
る清澄濾過を行ない、ついで酸化褐変防止のため亜硫酸
を80ppm添加溶解し、対照区のリンゴ果実酒を得
た。また、比較の為上記破砕、搾汁し得られるリンゴの
生果汁にスクラーゼを25ppm添加溶解し、酸素を吹
込むことなくそのまま、上記と同様に遠心分離して、清
澄な果汁を得、ワイン酵母を加え、発酵を行なった後、
ケイソウ土による清澄濾過を行ない比較例のリンゴ果実
酒を得た。次に上記て得られる生果汁と3種類の製品リ
ンゴ果実酒中の総タンニンを測定し、また3種類の製品
ワインを35℃の温度で1ヵ月保存した後の色沢を測定
し、また官能検査を実施した。その結果を表5に示す。
[Example 5] "Production of fruit liquor using apple as raw material" As a raw material, fresh fruit juice obtained by crushing and squeezing Fuji apple seeds by a conventional method was used. 25 ppm of pectin-degrading enzyme sucrase (manufactured by Sankyo Co., Ltd.) was added to and dissolved in the above apple fresh fruit juice, and the mixture was heated to 38 to 40 ° C., and oxygen was forcibly blown for 60 minutes at that temperature (contact reaction treatment), and treated. The subsequent chromaticity was measured using a Hitachi photoelectric photometer at 430 nm in a 10 mm cell.
The absorbance (OD) was measured to obtain a reaction-treated fruit juice having a chromaticity increased by 168%. Then, the reaction-treated fruit juice was centrifuged (treated at 3,000 rpm for 10 minutes), filtered through diatomaceous earth to remove oxidatively polymerized substances in the treated fruit juice, and the obtained fruit juice was added to wine yeast OC-2 (Nippon Brewery Co., Ltd.). 2% (volume) of Yeast Saccharomyces cerevisiae (sold by the association), equivalent to 2% (volume), and in a semi-sealed container at 15 to 20 ° C by a conventional method.
Fermentation was carried out for 2 weeks. After the fermentation was completed, clarification filtration with diatomaceous earth was performed by an ordinary method to obtain apple fruit liquor. For comparison, 40 ppm of sulfurous acid was added to the fresh apple juice obtained by crushing and squeezing for the purpose of preventing oxidative browning and preventing the growth of wild microorganisms, and sucrase was added at 25 ppm for the purpose of promoting clarification. The solution was added and dissolved as described above, treated by a conventional method, and then centrifuged (10 at 3,000 rpm).
Minute treatment) to obtain clear fruit juice, wine yeast is added in exactly the same manner as above, fermentation is performed, and then clarification filtration is performed with diatomaceous earth, and then 80 ppm of sulfurous acid is added and dissolved to prevent oxidative browning. The apple fruit liquor of the control area was obtained. Further, for comparison, 25 ppm of sucrase was added to and dissolved in fresh apple juice obtained by crushing and squeezing, centrifugation was performed in the same manner as above without blowing oxygen, and clear juice was obtained to obtain wine yeast. After adding and fermenting,
Clarification filtration was performed with diatomaceous earth to obtain apple fruit liquor as a comparative example. Next, the total tannins in the fresh fruit juice obtained above and the three kinds of product apple fruit liquor were measured, and the color sawa was measured after storing the three kinds of product wine at a temperature of 35 ° C for one month. The inspection was carried out. The results are shown in Table 5.

【0031】[0031]

【表5】 [Table 5]

【0032】[0032]

【実施例6】「 モモを原料とする果実酒の製造」 原料として、白鳳種モモを常法により破砕、搾汁し得ら
れる生果汁を使用した。上記モモ生果汁にペクチン分解
酵素スクラーゼ(三共株式会社製)を25ppm添加溶
解し、38〜40℃に加温し、その温度において酸素を
強制的に60分吹込み(接触反応処理し)、処理後の色
度を日立光電光度計を用いて10mmセルの430nmにお
ける吸光度(OD)を測定し、色度を240%増大させ
た反応処理果汁を得た。次いで、反応処理果汁を遠心分
離(3,000rpmで10分処理)後、ケイソウ土濾
過し、該処理果汁中の酸化重合物質を除去し、得られた
果汁に、ワイン酵母OC−2(日本醸造協会酵母サッカ
ロミセス・セレビシエ、同協会販売)を2%(容量)相
当加え、半密閉容器にて常法により15〜20℃で2週
間発酵を行なった。発酵終了後、常法によりケイソウ土
による清澄濾過を行ないモモ果実酒を得た。なお、比較
の為上記破砕、搾汁し得られるモモの生果汁に酸化褐変
防止と、野性の微生物の繁殖を防止する目的で亜硫酸を
40ppm添加し、常法により処理した後遠心分離
(3,000rpmで10分処理)して、清澄な果汁を
得、以下上記と全く同様にワイン酵母を加え、発酵を行
なった後、ケイソウ土による清澄濾過を行ない、次いで
酸化褐変防止のために亜硫酸を80ppm添加溶解し、
対照区のモモ果実酒を得た。また、比較の為上記破砕、
搾汁し得られるモモの生果汁にスクラーゼを25ppm
添加溶解し、酸素を吹込むことなくそのまま、上記と同
様に遠心分離して、清澄な果汁を得、ワイン酵母を加
え、発酵を行なった後、ケイソウ土による清澄濾過を行
ない比較例のモモ果実酒を得た。次に上記て得られる生
果汁と3種類の製品モモ果実酒中の総タンニンを測定
し、また3種類の製品ワインを35℃の温度で1ヵ月保
存した後の色沢を測定し、また官能検査を実施した。そ
の結果を表6に示す。
[Example 6] "Production of fruit liquor using peach as raw material" As a raw material, raw fruit juice obtained by crushing and squeezing white phoenix peach by a conventional method was used. 25 ppm of a pectin-degrading enzyme sucrase (manufactured by Sankyo Co., Ltd.) was added and dissolved in the fresh peach juice and heated to 38 to 40 ° C., and oxygen was forcibly blown for 60 minutes at that temperature (contact reaction treatment), and treated. The subsequent chromaticity was measured for absorbance (OD) at 430 nm of a 10 mm cell using a Hitachi photoelectric photometer to obtain a reaction-treated fruit juice having a chromaticity increased by 240%. Then, the reaction-treated fruit juice was centrifuged (treated at 3,000 rpm for 10 minutes), filtered through diatomaceous earth to remove oxidatively polymerized substances in the treated fruit juice, and the obtained fruit juice was added to wine yeast OC-2 (Nippon Brewery Co., Ltd.). 2% (volume) of Yeast Saccharomyces cerevisiae of the association, sold by the association) was added, and fermentation was carried out in a semi-sealed container at 15 to 20 ° C. for 2 weeks by a conventional method. After completion of fermentation, peach fruit liquor was obtained by carrying out clarification filtration with diatomaceous earth by a conventional method. For the purpose of comparison, 40 ppm of sulfurous acid was added to the fresh peach juice obtained by crushing and squeezing for the purpose of preventing oxidative browning and preventing the growth of wild microorganisms, followed by centrifugation (3, 4). 5,000 rpm for 10 minutes) to obtain a clear fruit juice, followed by adding wine yeast in exactly the same manner as above, fermenting, and then performing clarification filtration with diatomaceous earth, and then 80 ppm of sulfurous acid to prevent oxidative browning. Add and dissolve,
The peach fruit liquor of the control area was obtained. Also, for comparison, the above crushing,
25 ppm sucrase in fresh peach juice obtained by squeezing juice
Add and dissolve, as it is without blowing oxygen, and centrifuge in the same manner as above to obtain a clear fruit juice, add wine yeast and ferment, and then perform clarification filtration with diatomaceous earth to make a peach fruit of a comparative example. I got a drink. Next, the total tannins in the fresh juice obtained above and the three kinds of peach fruit liquor were measured, and the colors of the three kinds of wine were stored for 1 month at 35 ° C. The inspection was carried out. The results are shown in Table 6.

【0033】[0033]

【表6】 [Table 6]

【0034】上記実施例4、5及び6の結果から、いず
れの場合も対照の区分は破砕、搾汁し得られる発酵前の
生果汁に褐変防止と、野性の微生物の繁殖を防止する目
的で亜硫酸を高濃度に添加し、また得られた果実酒に
も、褐変防止のためにさらに亜硫酸を高濃度に添加溶解
しなければならない大きな問題点を有しており、また亜
硫酸の添加を無造作に廃止した比較例の区分は、果汁に
含まれる酸化酵素(ポリフェノールオキシダーゼ、チロ
シナーゼ等)により、同果汁中の色源体であるポリフェ
ノールが酵素的に酸化褐変を起こし、香味上及び外観、
新鮮味が損われ、また、原料に付着する性質不明の野性
酵母、乳酸菌がたちどころに繁殖して風味良好な果実酒
が得にくくなる問題が発生し、得られる果実酒は、淡褐
色を呈し、酸化臭と雑味を有し商品価値を損う欠点を有
しているが、これに対して、本発明の区分はいずれも、
発酵前の生果汁或いは得られた製品果実酒に対して亜硫
酸の添加が全く行なわれないので、亜硫酸による果実酒
の風味の変化が防止され、また予め選択育種された優良
酵母等が亜硫酸によって生育、繁殖を阻害されることが
ないので、アルコール発酵が頗る旺盛に行なわれるため
に、風味が非常に良好で、また果実酒における色源体で
ある総タンニンが150ppm以下にまで除去されてい
るために、亜硫酸を添加しなくとも、製品の褐変が防止
され、淡麗な色沢が長期間安定に保たれることが判る。
From the results of Examples 4, 5 and 6 above, in any case, the control category was for the purpose of preventing browning in the raw fruit juice before fermentation obtained by crushing and squeezing, and preventing the propagation of wild microorganisms. Sulfurous acid is added at a high concentration, and the resulting fruit liquor also has a major problem in that it needs to be dissolved at a high concentration to dissolve it in order to prevent browning. The categories of the abolished comparative examples are that oxidative enzymes (polyphenol oxidase, tyrosinase, etc.) contained in the fruit juice cause polyphenol, which is a color source in the fruit juice, to enzymatically undergo browning, and thus the flavor and appearance are
Freshness is impaired, and wild yeast and lactic acid bacteria of unknown nature that adhere to the raw materials propagate in places and it becomes difficult to obtain fruit wine with a good flavor, and the resulting fruit wine has a light brown color, Although it has a drawback that it has an oxidative odor and a miscellaneous taste and impairs its commercial value, on the other hand, all the categories of the present invention
Sulfurous acid is not added to the raw fruit juice before fermentation or the resulting product fruit liquor at all, so the change in the flavor of fruit liquor due to sulfurous acid is prevented, and excellent yeast etc. selected and bred in advance are grown by sulfite. , Because it does not hinder the reproduction, the alcohol fermentation is performed vigorously and the flavor is very good, and the total tannin, which is the chromogen in fruit wine, is removed to 150 ppm or less. In addition, it can be seen that the browning of the product is prevented and the beautiful color is kept stable for a long period of time without adding sulfurous acid.

Claims (4)

【特許請求の範囲】[Claims] 【請求項1】 総タンニンが150ppm以下、且つ総
亜硫酸が20ppm以下である果実酒。
1. Fruit wine having a total tannin of 150 ppm or less and a total sulfurous acid of 20 ppm or less.
【請求項2】 果実類を常法により破砕、搾汁して生果
汁を得、これに酸素または酸素含有気体を強制的に接触
反応せしめ、色源体を予め酸化重合させて色度を一旦1
00〜250%増大させ、次いでこの酸化重合物質を除
去し、得られた果汁を常法によりアルコール発酵させる
ことを特徴とする果実酒の製造法 。
2. Fruits are crushed and squeezed by a conventional method to obtain fresh fruit juice, and oxygen or an oxygen-containing gas is forcibly contact-reacted therewith, and the chromogen is preliminarily oxidatively polymerized to once obtain the chromaticity. 1
A method for producing fruit liquor, which comprises increasing the amount by 0 to 250%, then removing this oxidatively polymerized substance, and subjecting the obtained fruit juice to alcohol fermentation by a conventional method.
【請求項3】 果実類を常法により破砕、搾汁して生果
汁を得、これに酸素または酸素含有気体を強制的に接触
反応せしめ、色源体を予め酸化重合させて色度を一旦1
00〜250%増大させ、次いでこの酸化重合物質を除
去して、660nmにおける10mmセルの吸光度が
0.2以下である清澄果汁を得、次いでこれを常法によ
りアルコール発酵させることを特徴とする果実酒の製造
法。
3. Fruits are crushed and squeezed by a conventional method to obtain fresh fruit juice, and oxygen or an oxygen-containing gas is forcibly contact-reacted with this, and the chromogen is preliminarily oxidatively polymerized to once obtain the chromaticity. 1
A fruit characterized by increasing the amount of the oxidative polymer by 0 to 250%, and then removing the oxidatively polymerized substance to obtain a clarified fruit juice having an absorbance of 10 mm cell at 660 nm of 0.2 or less, which is then alcohol-fermented by a conventional method. Sake manufacturing method.
【請求項4】 酸素または酸素含有気体との接触反応
が、35〜45℃で行なわれる請求項2または3に記載
の果実酒の製造法。
4. The method for producing fruit wine according to claim 2, wherein the catalytic reaction with oxygen or an oxygen-containing gas is carried out at 35 to 45 ° C.
JP16193292A 1992-05-29 1992-05-29 Fruit wine and its manufacturing method Expired - Lifetime JP3023814B2 (en)

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