JPH05307250A - Silver halide color photographic sensitive material - Google Patents

Abstract

PURPOSE:To obtain a silver halide color photographic sensitive material improved in yellow color development performance and superior in maintenance of color balance image and storage stability of an image after processing. CONSTITUTION:The silver halide color photographic sensitive material has, on a base, at least each one of silver halide emulsion layers containing cyan, magenta, and yellow couplers, respectively, and different from each other in color sensitivity, and at least one nonphotosensitive layer on a support. At least one of the yellow color-developing silver halide emulsion layers contains at least one kind of the yellow couplers represented by the formula and at least one of the nonphotosensitive hydrophilic colloidal layers contains at least one kind of ultraviolet absorber being liquid at normal temperature and at least one kind of homo-car co-polymer insoluble in water.

Description

Detailed Description of the Invention

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a silver halide color photographic light-sensitive material excellent in color developability and storability of color images.

[0002]

2. Description of the Related Art In a silver halide color photographic light-sensitive material, a combination of yellow, magenta and cyan couplers is usually used as a photographic coupler which reacts with an oxidized product of an aromatic primary amine developing agent to form a coloring dye. Has been. In response to the demand for rapid processing in recent years, a processing solution that uses a silver chlorobromide emulsion having a high silver chloride content in a light-sensitive material and does not use sulfite or benzyl alcohol that is contained in a color developing agent of a normal color paper. A new system using a processing liquid that does not use is developed and is being introduced to the market.

In a color photograph, when such a rapid processing is applied, the color-forming property of a specific coupler is inferior to that of other couplers, so that the color balance of the three colors due to yellow, magenta and cyan color-developing dyes is lost after the photographic processing. In some cases, the color fading of a specific dye image deteriorates under light irradiation and the color balance after fading changes, and the white background, which is a non-image area, may be colored during storage in a dark place. It is natural that the color light-sensitive material used for direct appreciation has good color balance of the three colors immediately after the photographic processing in light of the purpose of recording and storage, and it can be stored under both light irradiation and dark storage. It is necessary that the degree of fading (light fading, dark fading) is small, and that the coloring of the white background is kept small. Therefore, such changes caused by applying rapid processing are a big problem.

Many attempts have been made to improve image storability. For example, JP-A-3-24541 discloses a method of using a dispersion prepared by compatibilizing a cyan coupler and a polymer latex as a means for improving light fastness of a cyan dye image, and JP-A-3-192347 discloses halogen substitution. Disclosed is a method of adding hydroquinones to a cyan color-forming layer to simultaneously satisfy processing dependency and light fastness, and JP-A-63-264748 discloses a method of emulsifying and dispersing an ultraviolet absorber together with a specific hydrophobic polymer. Has been done. According to these methods, the light fastness of the cyan image is certainly improved, but the effect is not sufficient, and the color balance of the three colors is lost after the above rapid processing. It turned out that there was no improvement.

[0005]

DISCLOSURE OF THE INVENTION The inventors of the present invention have found that a non-photosensitive hydrophilic colloid layer containing a combination of a UV absorber which is liquid at room temperature and a water-insoluble polymer is contained above the photosensitive layer farthest from the support. It has been found that not only the light fastness of the color image is improved but also the color developability of the pivaloyl yellow coupler is improved by coating it on the coating system. The color developability of the coupler was not sufficient and further improvement was required. Therefore, an object of the present invention is to provide a silver halide color photographic light-sensitive material which has improved yellow color development due to rapid processing of the silver halide color photographic light-sensitive material and which is excellent in color balance and image storability after processing. is there.

[0006]

As a result of intensive studies, the present inventor has found that the following silver halide color photographic light-sensitive material can solve the above-mentioned problems, and has completed the present invention.

(1) A silver halide color photographic light-sensitive material having at least one yellow, magenta and cyan color-forming silver halide emulsion layers each having different color sensitivity from each other and at least one non-photosensitive hydrophilic colloid layer on a support. In the material, at least one layer of the yellow color-forming silver halide emulsion layer contains at least one yellow coupler represented by the following general formula (I), and at least one layer of the non-photosensitive hydrophilic colloid layer is liquid at room temperature. A silver halide color photographic light-sensitive material characterized by containing at least one kind of ultraviolet absorber and at least one kind of water-insoluble homopolymer or copolymer,

[0008]

[Chemical 3] (In the formula, X represents an organic residue necessary for forming a nitrogen-containing heterocyclic group together with a nitrogen atom, Y represents an aryl group or a heterocyclic group, and Z represents the coupling of this coupler with an oxidized product of a developing agent. Represents a group that leaves when it reacts.)
(2) The above-mentioned non-photosensitive hydrophilic colloid layer containing an ultraviolet absorber which is liquid at room temperature and a water-insoluble polymer is coated above the cyan color-forming silver halide emulsion (the side farther from the support). (1) The silver halide color photographic light-sensitive material according to the item (1), and (3) the compound represented by the following general formula (II) does not substantially coexist with a solid or liquid ultraviolet absorber at room temperature. 2. The silver halide color photographic light-sensitive material as described in the item (1) or (2), wherein the hydrophilic colloid layer contained in (1) is coated below and adjacent to the cyan color forming silver halide emulsion layer.

[0009]

[Chemical 4] (In the formula, R ₂₁ , R ₂₂ , R ₂₃ and R ₂₄ may be the same or different and each represents a hydrogen atom or a substituent, provided that R _{21 to} R
_At least one of ₂₄ must be a substituent. )

The specific constitution of the present invention will be described in detail below. The coupler represented by formula (I) is described in detail below. The nitrogen-containing heterocyclic ring represented by A is either a saturated or unsaturated, monocyclic or condensed ring, substituted or unsubstituted, having 1 or more carbon atoms, preferably 1 to 20 and particularly preferably 2 to 12 carbon atoms. It may be. In addition to the nitrogen atom, an oxygen atom, a sulfur atom or a phosphorus atom may be contained in the ring. Each of these heteroatoms may include one or more. The number of ring members is a 3-membered ring or more, preferably a 3- to 12-membered ring, and particularly preferably a 5- or 6-membered ring. Specific examples of the heterocyclic group represented by A include pyrrolidino, piperidino, morpholino, 1-imidazolidinyl, 1-pyrazolyl, 1-piperazinyl, 1-indolinyl, 1,2,3,4-tetrahydroquinoxaline-1.
-Yl, 1-pyrrolinyl, pyrazolidin-1-yl,
2,3-dihydro-1-indazolyl, isoindoline-2-yl, 1-indolyl, 1-pyrrolyl, benzothiazin-4-yl, 4-thiazinyl, benzodiazin-
1-yl, aziridin-1-yl, benzoxazine-
4-yl, 2,3,4,5-tetrahydroquinolyl, phenoxyxazin-10-yl and the like can be mentioned.
When Y represents an aromatic group in the general formula (I), it is a substituted or unsubstituted aromatic group having 6 or more carbon atoms, preferably 6 to 10 carbon atoms. Particularly preferred is phenyl or naphthyl.

When Y in the general formula (I) represents a heterocyclic group, it is a saturated or unsaturated, substituted or unsubstituted heterocyclic group having 1 or more carbon atoms, preferably 1 to 10 carbon atoms, particularly preferably 2 to 5 carbon atoms. Is. Preferred examples of the hetero atom are a nitrogen atom, a sulfur atom or an oxygen atom. The number of ring members is preferably a 5- or 6-membered ring, but it may be more. It may be either a monocyclic ring or a condensed ring. When Y represents a heterocyclic group, specifically, for example, 2-pyridyl, 4-
Examples include pyrimidyl, 5-pyrazolyl, 8-quinolyl, 2-furyl or 2-pyrrolyl.

When the group represented by A and the group represented by Y in the general formula (I) each have a substituent, examples of the substituent include a halogen atom (eg, fluorine atom, chlorine atom), an alkoxycarbonyl group. (C2-30, preferably 2-20. For example, methoxycarbonyl, dodecyloxycarbonyl, hexadecyloxycarbonyl), aryloxycarbonyl group (for example, phenyloxycarbonyl), acylamino group (C2-30,
Preferably 2-20. For example, acetamide, tetradecanamide, 2- (2,4-di-t-amylphenoxy)
Butanamide, benzamide), sulfonamide group (having 1 to 30 carbon atoms, preferably 1 to 20. For example, methanesulfonamide, dodecanesulfonamide, hexadecanesulfonamide, benzenesulfonamide), carbamoyl group (having 2 to 30 carbon atoms, preferably 2 to 20. For example, N
-Butylcarbamoyl, N, N-diethylcarbamoyl), a sulfamoyl group (having 1 to 30, preferably 1 to 20 carbon atoms. For example, N-butylsulfamoyl, N-dodecylsulfamoyl, N-hexadecylsulfamoyl, N-3- (2,4-di-t-amylphenoxy) butylsulfamoyl), alkoxy group (having 1 to 3 carbon atoms)
0, preferably 1-20. For example, methoxy, dodecyloxy), N-acyl sulfamoyl group (having 2 to 3 carbon atoms)
0, preferably 2-20.

For example, N-propanoylsulfamoyl,
N-tetradecanoylsulfamoyl), a sulfonyl group (having 1 to 30 carbon atoms, preferably 1 to 20. For example, methanesulfonyl, octanesulfonyl, dodecanesulfonyl), an alkoxycarbonylamino group (having 1 to 3 carbon atoms).
0, preferably 1-20. For example, methoxycarbonylamino, tetradecyloxycarbonylamino), cyano group, nitro group, carboxyl group, aryloxy group (C6-20, preferably 6-10. For example, phenoxy, 4-chlorophenoxy), alkylthio group (carbon Number 1 to 30, preferably 1 to 20. For example, methylthio,
Dodecylthio), an ureido group (having 1 to 30 carbon atoms, preferably 1 to 20 carbon atoms, for example, phenylureido), an aryl group (as defined when Y represents an aromatic group), a heterocyclic group (Y is an aromatic group). Synonymous with the explanation when expressing
Sulfo group, alkyl group (having 1 to 30 carbon atoms, preferably 1
20 straight chain, branched, cyclic, saturated, unsaturated, substituted or unsubstituted. For example, methyl, ethyl, isopropyl, cyclopropyl, trifluoromethyl, cyclopentyl, dodecyl, 2-hexyloctyl), an acyl group (having 1 carbon atom)
-30, preferably 2-20. For example, acetyl, benzoyl), an arylthio group (having 6 to 20 carbon atoms, preferably 6 to 10 carbon atoms, for example, phenylthio), a sulfamoylamino group (having 0 to 30 carbon atoms, preferably 0 to 20 carbon atoms.
N-butylsulfamoylamino, N-dodecylsulfamoylamino), N-acylcarbamoyl group (having 2 to 30 carbon atoms, preferably 2 to 20 carbon atoms, for example, N-dodecanoylcarbamoyl), N-sulfonylcarbamoyl group (carbon Number 1 to 30, preferably 2 to 20. For example, N-hexadecanesulfonylcarbamoyl, N-benzenesulfonylcarbamoyl, N- (2-octyloxy-5-t-.
Octylbenzenesulfonyl) carbamoyl), N-sulfamoylcarbamoyl group (C1-C30, preferably 1-20. For example, N- (ethylsulfamoyl).
Carbamoyl, N- {3- (2,4-di-t-amylphenoxy) propylsulfamoyl} carbamoyl),
N-sulfonylsulfamoyl group (0 to 30 carbon atoms, preferably 1 to 20. For example, N-dodecanesulfonylsulfamoyl, N-benzenesulfonylsulfamoyl), N-carbamoylsulfamoyl group (1 carbon atoms ~
30, preferably 1-20. For example, N- (ethylcarbamoyl) sulfamoyl, N- {3- (2,4-di-t
-Amylphenoxy) propylcarbamoyl} sulfamoyl), N- (N-sulfonylcarbamoyl) sulfamoyl group (having 1 to 30, preferably 1 to 20 carbon atoms, for example, N-dodecanesulfonylcarbamoyl) sulfamoyl, N- (2-octyloxy-). 5-t-octylbenzenesulfonylcarbamoyl) sulfamoyl), 3
-Sulfonylureido group (having 1 to 30 carbon atoms, preferably 1 to 20. For example, 3-hexadecanesulfonylureido, 3-benzenesulfonylureido), 3-acylureido group (having 2 to 30 carbon atoms, preferably 2 to 20. For example, 3-acetylureido, 3-benzoylureido), 3-acylsulfamide group (having 1 to 30 carbon atoms, preferably 1 to 20. For example, 3-propionylsulfamide, 3- (2,4-dichlorobenzoyl) sulfamide. ), 3-sulfonylsulfamide group (having 0 to 3 carbon atoms)
0, preferably 1-20. For example, 3-methanesulfonylsulfamide, 3- (2-methoxyethoxy-5-t-
Octylbenzenesulfonyl) sulfamide), a hydroxyl group, an acyloxy group (having 1 to 30 carbon atoms, preferably 1 to 20. For example, propanoyloxy, tetradecanoyloxy), a sulfonyloxy group (having 0 to 30 carbon atoms,
Preferably 0-20. Dodecanesulfonyloxy, 2-
Octyloxy-5-t-octylbenzenesulfonyloxy).

When the group represented by A has a substituent, preferred examples of the substituent include those listed above.
Examples thereof include a halogen atom, an alkoxy group, an acylamino group, a carbamoyl group, an alkyl group, a sulfonamide group and a nitro group, but unsubstituted ones are also preferable examples.

When the group represented by Y has a substituent, preferred examples of the substituent include halogen atom, alkoxycarbonyl group, sulfamoyl group, carbamoyl group, sulfonyl group, sulfonamide group, acylamino group, alkoxy group and aryl. Oxy group, N-acylcarbamoyl group, N-sulfonylcarbamoyl group, N-sulfamoylcarbamoyl group, N-sulfonylsulfamoyl group,
Examples thereof include N-acylsulfamoyl group, N-carbamoylsulfamoyl group, and N- (N-sulfonylcarbamoyl) sulfamoyl group.

The group represented by Z in the general formula (I) may be any conventionally known coupling-off group. Preferable Z is a nitrogen-containing heterocyclic group bonded to the coupling position at a nitrogen atom, an aromatic oxy group,
Examples thereof include an aromatic thio group, a heterocyclic oxy group, a heterocyclic thio group, an acyloxy group, a carbamoyloxy group, an alkylthio group and a halogen atom. These leaving groups are photographic useful groups or precursors thereof (for example, development inhibitors, development accelerators, desilvering accelerators, fogging agents, dyes, hardeners, couplers, developing agent oxidant scavengers, fluorescent dyes, It may be either a developing agent or an electron transfer agent) or a non-photographic useful group. When Z represents a nitrogen-containing heterocycle,
Specifically, it is a monocyclic or condensed-ring, substituted or unsubstituted heterocyclic group. Examples thereof include succinimide, maleinimide, phthalimide, diglycolimide, pyrrino, pyrazolyl, imidazolyl, 1,2,4-triazol-1-yl (or 4-yl), 1-tetrazolyl, indolyl, benzopyrazolyl, benzimidazolyl. , Benzotriazolyl, imidazolidin-2,4-dione-3-yl (or 1-yl), oxazolidin-
2,4-dione-3-yl, thiazolidin-2,4-dione-3-yl, imidazolidin-2-one-1-yl, oxazolin-2-one-3-yl, thiazolin-
2-on-3-yl, benzooxazolidin-2-one-3-yl-, 1,24-triazolidine-3,5-dione-4-yl, 2-pyridon-1-yl, morpholine-3,5- Dione-4-yl, 1,2,3-triazol-1-yl or 2-imidazolidin-5-one are mentioned.

When these heterocyclic groups have a substituent,
Examples of the substituent include the substituents enumerated above as the substituents that the group A may have. When Z represents a nitrogen-containing heterocyclic group, it is preferably 1-pyrazolyl, imidazolyl, 1,2,3-triazol-1-yl, benzotriazolyl, 1,2,4-triazole-
1-yl, oxazolidin-2,4-dione-3-yl, 1,2,4-triazodiline-3,5-dione-4
-Yl or imidazolidin-2,4-dione-3-
It ’s ill. These include cases where they have a substituent.
When Z represents an aromatic oxy group, it is preferably a substituted or unsubstituted phenoxy group. When it has a substituent,
Examples of the substituent include the substituents enumerated as the substituents which the group represented by Y may have. The preferred substituent that the phenoxy group has is a case where at least one substituent is an electron-withdrawing substituent, and examples thereof include a sulfonyl group, an alkoxycarbonyl group, a sulfamoyl group, a halogen atom, a carboxyl group, a carbamoyl group, and an acyl group. Or a nitro group is an example. When Z represents an aromatic thio group, it is preferably a substituted or unsubstituted phenylthio group. When it has a substituent, examples of the substituent include the substituents enumerated as the substituents which the group represented by Y may have. The preferred substituent which the phenylthio group has is a case where at least one of the substituents is an alkyl group, an alkoxy group, a sulfonyl group, an alkoxycarbonyl group, a sulfamoyl group, a halogen atom, a carbamoyl group or a nitro group.

When Z represents a heterocyclic oxy group, the heterocyclic group has the same meaning as when Y represents a heterocyclic group. When Z represents a heterocyclic thio group, a 5- or 6-membered unsaturated heterocyclic thio group is a preferred example. For example, tetrazolylthio group, 1,3,4-thiadiazolylthio group, 1,3,4-oxadiazolylthio group, 1,
Examples thereof include a 3,4-triazolylthio group, a benzimidazolylthio group, a benzothiazolylthio group, and a 2-pyridylthio group. Examples of the case where these have a substituent include the substituents enumerated as the substituents which may be possessed when Y represents a heterocyclic group. Among these, preferred substituents are aromatic groups, alkyl groups, alkylthio groups, acylamino groups, alkoxycarbonyl groups and aryloxycarbonyl groups. When Z represents an acyloxy group, specifically, an aromatic acyloxy group (having 7 to 11 carbon atoms, preferably a benzoyloxy group),
Alternatively, it is an aliphatic acyloxy group (having 2 to 20 carbon atoms, preferably 2 to 10 carbon atoms) and may have a substituent. Specific examples of the substituent include the substituents enumerated as the substituents that Y may have when Y represents an aromatic group. A preferable substituent is a case where at least one substituent is a halogen atom, a nitro group, an aryl group, an alkyl group or an alkoxy group.

When Z represents a carbamoyloxy group,
It is an aliphatic, aromatic, heterocyclic or unsubstituted carbamoyloxy group having 1 to 30 carbon atoms, preferably 1 to 20 carbon atoms. For example, N, N-diethylcarbamoyloxy, N-
Phenylcarbamoylmorpholinocarbonyloxy, 1
-Imidazolylcarbonyloxy or N, N-dimethylcarbamoyloxy. Here, the detailed description of the alkyl group, aromatic group and heterocyclic group is the same as that defined in the description of Y above. When Z represents an alkylthio group, it is an alkylthio group having 1 to 30 carbon atoms, preferably 1 to 20 carbon atoms. The detailed description of the alkyl group has the same meaning as defined in the description of Y above.

Preferred as the group represented by Z in the general formula (I) are a 5- to 6-membered nitrogen-containing heterocyclic group (bonded to the coupling position at a nitrogen atom), an aromatic oxy group, 5
And a 6-membered heterocyclic oxy group or a 5- or 6-membered heterocyclic thio group. An aromatic group is preferable as the group represented by Y in formula (I). Particularly preferred is a phenyl group having at least one substituent at the ortho position. As the description of the substituent, those described as the substituent that may be possessed when Y is an aromatic group are mentioned. When the group represented by Y in the general formula (I) is a phenyl group having at least one substituent at the ortho position, the substituent at the ortho position is particularly preferably a halogen atom, an alkoxy group, an alkyl group or It is an aryloxy group. Among the couplers represented by the general formula (I), a particularly preferred coupler is represented by the following general formula (Ia).

[0021]

[Chemical 5] In the formula, Y and Z have the same meanings as described in the general formula (I), and X ₁ represents an organic residue necessary for forming a nitrogen-containing heterocycle together with —C (R ₁ R ₂ ) —N—. And R ₁ and R ₂ each represent a hydrogen atom or a substituent.

Preferred ranges and specific examples of Y and Z in the general formula (Ia) are the same as those described in the general formula (I). Specific examples of the heterocyclic group represented by B in the general formula (Ia) and examples of the substituents include those described in the description of A in the general formula (I). Further, their preferable ranges are also synonymous. Particularly preferably, these nitrogen-containing heterocyclic groups are benzene condensed rings. Among the couplers represented by the general formula (Ia), an even more preferred coupler is represented by the following general formula (I-
It is shown in b).

[0023]

[Chemical 6] In the formula, R ₃ represents a hydrogen atom or a substituent, and R ₄ ,
R ₅ and R ₆ represent a substituent. Z has the same meaning as described in the general formula (I), and m and n are 0 respectively.
Represents an integer from 1 to 4. When m and n each represent an integer of 2 or more, R ₄ and R ₆ thereof may be the same or different, or may be bonded to each other.

In the general formula (Ib), when R ₃ and R ₄ represent a substituent, examples of the substituents are represented by the general formula (I).
The same as the example of the substituent when the group represented by A has a substituent. Preferred examples of R ₃ are hydrogen atom, alkyl group and aryl group, and preferred examples of R ₄ are halogen atom, alkoxy group, acylamino group, carbamoyl group, alkyl group, sulfonamide group or nitro group. .. m is preferably an integer from 0 to 2,
Particularly preferably 0 or 1. General formula (Ib)
In the above, examples of the substituents represented by R ₅ and R ₆ are the same as the examples of the substituent when the group represented by Y in the general formula (I) has a substituent. R ₅ is preferably a halogen atom, an alkoxy group, an alkyl group or an aryloxy group, and a preferable example of R _{6 is} a preferable example of the substituent when the group represented by Y in the general formula (I) has a substituent. The same as those listed above. n is preferably an integer of 0 to 2, more preferably 1 or 2.

General formulas (I), (Ia) and (Ib)
The coupler represented by may form a dimer or a multimer in which X, Y and Z are bonded to each other via a divalent or divalent or higher valent group. In this case, the number of carbon atoms shown in each of the above substituents may be out of the specified range. Specific examples of the coupler represented by formula (I) are shown below, but the couplers are not limited to these.

[0026]

[Table 1]

[0027]

[Table 2]

[0028]

[Table 3]

[0029]

[Table 4]

[0030]

[Table 5]

[0031]

[Table 6]

[0032]

[Table 7]

[0033]

[Table 8]

[0034]

[Table 9]

[0035]

[Table 10]

[0036]

[Table 11]

[0037]

[Table 12]

[0038]

[Table 13]

[0039]

[Table 14]

[0040]

[Table 15]

[0041]

[Table 16]

[0042]

[Table 17]

[0043]

[Table 18]

[0044]

[Chemical 7]

[0045]

[Chemical 8]

The compound of the present invention can be synthesized by a generally known method or a method similar thereto. For example, it can be synthesized by the following synthesis route.

[0047]

[Chemical 9]

In the formula, X, Y and Z have the same meanings as described in the general formula (I). R ₁₀ represents a halogen atom (for example, a chlorine atom), —OH, an alkoxy group (for example, methoxy, ethoxy), or a phenoxy group (for example, phenoxy, 4-nitrophenoxy). Hal
Represents halogen. Under the reaction conditions of (a), R ₁₀ is O.
When it is H, a dehydration condensing agent (for example, N, N-dicyclohexylcarbodiimide, N, N-diisopropylcarbodiimide) is used. When R ₁₀ is a halogen atom, the reaction is carried out in the presence of a dehydrohalogenating agent. As the dehydrohalogenating agent, an organic base (eg, triethylamine, diisopropylethylamine, pyridine, guanidine, butoxy potassium), an inorganic base (eg, sodium hydroxide, potassium hydroxide, sodium hydride, potassium carbonate) and the like are used. 3 → 4
In the reaction of, a halogenating agent is used as (b).
For example, bromine, chlorine, N-bromosuccinimide, N-chlorosuccinimide and the like. In the reaction of 4 → final product, a dehydrohalogenating agent is generally used as (c). Examples include the above-mentioned organic bases or inorganic bases. A reaction solvent is generally used in each reaction. For example, chlorine-based solvents (for example, dichloromethylene), aromatic-based solvents (for example, benzene, chlorobenzene, toluene), amide-based solvents (for example, N, N-).
Dimethylformamide, N, N-dimethylacetamide, N-methylpyrrolidone), nitrile solvents (eg acetonitrile, propionitrile), ether solvents (eg tetrahydrofuran, ethylene glycol diethyl ether), sulfone solvents (eg dimethyl sulfone, Sulfolane) or a hydrocarbon solvent (for example, cyclohexane, normal hexane).

It can be synthesized by a method other than the above-mentioned synthesis route. For example, J. Org, Ch
em. , 29 , 2932 (1964). In some cases, the functional group may be further converted from 5 to induce the final target product. The change of the synthetic route or the additional reaction can be appropriately selected. The specific synthesis method is described below. Other exemplified compounds can be similarly synthesized.

Synthesis Example 1. Synthesis of Exemplified Compound (54) It was synthesized by the following synthesis method.

[0051]

[Chemical 10]

3.5 g of compound 6 and 14 g of 7 were dissolved in 100 ml of N, N-dimethylformamide and 100 ml of acetonitrile. To this solution, 40 ml of an acetonitrile solution in which 6 g of N, N'-dicyclohexylcarbodiimide was dissolved was added dropwise at room temperature. After reacting for 2 hours, the precipitated N, N'-dicyclohexylurea was filtered off. The filtrate was poured into 500 ml of water and ethyl acetate was added to 50
Extracted with 0 ml. The oil layer was collected using a separating funnel and washed with water, and then the oil layer was dried with Glauber's salt. The solvent was distilled off under reduced pressure, and hexane was added to the residue for crystallization. 17.2 g
I got 8. 16 g of 8 was mixed with 150 ml of dichloromethane. 10 ml of dichloromethane containing 4.8 g of bromine
The solution of was added dropwise under ice cooling (5 ° C to 10 ° C). After reacting for 10 minutes, the mixture was transferred to a separating funnel and washed with water. The oil layer (solution containing 9) was taken and used as it was in the next step. 8.1 g of 5,5-dimethyl-2,4-dioxo-1,3-oxazolidine and 8.8 ml of triethylamine were added to N, N-
It was added to 160 ml of dimethylformamide. The dichloromethane solution of 9 obtained above was added dropwise to this solution at room temperature. After reacting for 1 hour, 500 ml of ethyl acetate was added, and the mixture was transferred to a separating funnel and washed with water. After neutralization with diluted hydrochloric acid, the mixture was washed with water again, and the oil layer was separated. The solvent was distilled off under reduced pressure, and the residue was separated and purified by column chromatography. Silica gel was used as the packing material, and ethyl acetate / hexane (1/1) was used as the eluent. Target Exemplified Compound (5
The wax-containing Exemplified Compound (54) was collected in 15.2 by collecting the fraction containing 4) and distilling off the solvent under reduced pressure.
g was obtained.

Synthesis Example 2, Synthesis of Exemplified Compound (2) Synthesis was carried out in the same manner as in Synthesis Example 1 above. However, instead of 7, an equimolar amount of the following 10 was used.

[0054]

[Chemical 11]

The final product was purified by column chromatography to obtain 18.3 g of Wax-like Exemplified Compound (2). Two or more kinds of yellow carburetors represented by the general formula (I) can be used in combination, and can also be used in combination with a yellow cuddler other than the present invention. The yellow duller of the present invention is usually 0.1 to 1 mol per mol of silver halide in the silver halide emulsion layer forming the photosensitive layer.
It is contained in an amount of 1.0 mol, more preferably 0.1 to 0.5 mol. General formula (II) used in the present invention
The compound represented by is a compound which is usually used in a photographic light-sensitive material as a color mixing inhibitor, and is preferably an oil-soluble compound. In the compound represented by the general formula (II), examples of the substituent represented by R ₂₁ and R ₂₂ include a substituted or unsubstituted alkyl group, a substituted or unsubstituted alkenyl group, a substituted or unsubstituted aryl group, and a substituted group. Alternatively, an unsubstituted acyl group, a substituted or unsubstituted cycloalkyl group, a sulfonic acid group, a halogen atom or a heterocyclic group is preferable. Examples of the alkyl group include methyl, ethyl, n-propyl, n-butyl, n-amyl, i-amyl, n-octyl, n-dodecyl, and n-octadecyl groups, and particularly 1 to 1 carbon atoms. 32 alkyl groups are preferred.

The alkenyl group includes, for example, allyl, octenyl and oleyl groups, and particularly has 2 to 3 carbon atoms.
Two alkenyl groups are preferred. Examples of the aryl group include phenyl and naphthyl groups. Examples of the acyl group include acetyl, octanoyl, and lauroyl groups. Examples of the halogen atom include fluorine, chlorine and bromine atoms. Examples of the cycloalkyl group include a cyclohexyl group. Examples of the heterocyclic group include imidazolyl, furyl, pyridyl, triazinyl and thiazoyl groups. In the general formula (II), the carbon atom number of groups represented by R ₂₁ and R ₂₂ are preferably the sum is 8 or more, groups represented by R ₂₁ and / or R ₂₂ are nondiffusible It is preferably a group capable of imparting.

In the general formula (II), R ₂₃ and R ₂₄
Examples of the substituent represented by are halogen atom, alkyl group, aryl group, cycloalkyl group, alkoxy group, aryloxy group, arylthio group, acyl group, alkylacylamino group, arylacylamino group, alkylcarbamoyl group, arylcarbamoyl group. Group, alkylsulfonamide group, arylsulfonamide group, alkylsulfamoyl group, arylsulfamoyl group, alkylsulfonyl group, arylsulfonyl group, nitro group,
Examples thereof include a cyano group, an alkyloxycarbonyl group, an aryloxycarbonyl group, an alkylacyloxy group and an arylacyloxy group. In the general formula (II), specific examples of the halogen atom, alkyl group, aryl group, acyl group and cycloalkyl group represented by R ₂₃ and R ₂₄ are the same as those mentioned for R ₂₁ and R _22. I can list things.

As the alkoxy group, for example, methoxy,
Examples include ethoxy and dodecyloxy groups, examples of aryloxy groups include phenoxy groups, examples of alkylthio groups include methylthio, n-butylthio, and n-dodecylthio groups, and examples of arylthio groups include: Examples thereof include a phenylthio group, examples of the alkylacylamino group include an acetylacylamino group, examples of the arylacylamino group include a benzoylamino group, and examples of the alkylcarbamoyl group include a methylcarbamoyl group. The arylcarbamoyl group includes, for example, a phenylcarbamoyl group, and the alkylsulfonamide group includes, for example, a methylsulfonamide group,
Examples of the arylsulfonamide group include a phenylsulfonamide group, examples of the alkylsulfamoyl group include a methylsulfamoyl group, and examples of the arylsulfamoyl group include a phenylsulfamoyl group. Examples of the alkylsulfonyl group include a methylsulfonyl group,
Examples of the arylsulfonyl group include a phenylsulfonyl group, examples of the alkyloxycarbonyl group include a methyloxycarbonyl group,
Examples of the aryloxycarbonyl group include a phenyloxycarbonyl group, examples of the alkylacyloxy group include an acetyloxy group, and examples of the arylacyloxy group include a benzoyloxy group.

These substituents represented by R ₂₁ , R ₂₂ , R ₂₃ and R ₂₄ are further alkyl groups, aryl groups, aryloxy groups, alkylthio groups, cyano groups, acyloxy groups, alkoxycarbonyl groups, acyl groups and sulfamoyl. It may be further substituted with a group, a hydroxy group, a nitro group, an amino group, a heterocyclic group or the like. Specific examples of the compound represented by the general formula (II) include the following compounds.

[0060]

[Chemical formula 12]

[0061]

[Chemical 13]

[0062]

[Chemical 14]

The non-photosensitive layer below the cyan color-forming silver halide emulsion layer preferably contains at least one compound represented by the general formula (II) dispersed in the form of oil droplets. It is also preferable that they are emulsified and dispersed in the form of being dissolved in a high boiling point organic solvent. Furthermore, it is also preferable to simultaneously contain the compound of general formula (II) and a polymer compound such as polyacrylamide. The total amount of the compound represented by the general formula (II) is generally 5 mg / m ² or more and 2500 mg / m ² or more.
It is preferably ² or less, more preferably 10 mg / m
^{It is 2} or more and 1500 mg / m ² or less. In the present invention, it is preferable that the non-photosensitive layer coated above the cyan color-forming silver halide emulsion layer does not substantially contain the compound represented by the general formula (II). The term "substantially free from" means less than 160 mg / m ² , preferably 100 mg / m ² or less, and it is particularly preferred not to contain at all. Further, the amount of the compound represented by the general formula (II) used in the non-photosensitive layer coated below and adjacent to the cyan color forming silver halide emulsion layer is 5 mg / m ² or more and 1000 mg / m ² or less. Preferably, it is more preferably 10 mg / m ² or more and 500 mg
/ m ² or less.

In the present invention, the non-photosensitive layer coated below and adjacent to the cyan color-forming silver halide emulsion layer contains a compound represented by the general formula (II), and an ultraviolet ray which is solid or liquid at room temperature. Absorbent substantially coexists (especially coemulsification)
Not preferably. "Substantially does not coexist" means
Preferably less than 150 mg / m ² , more preferably 100 mg
/ m ² or less, and it is particularly preferable not to contain it at all.
In the present invention, it is necessary to use at least one type of ultraviolet absorber that is liquid at room temperature. The normal temperature here means 30 degrees Celsius. The ultraviolet absorber of the present invention which is liquid at room temperature may be a single compound or a mixture. The mixture may be composed of structural isomers, an ultraviolet absorber which is solid at room temperature by itself, or a combination which becomes liquid at room temperature when used together.

Any UV absorber may be used as the UV absorber in the present invention, but thiazolidone-based, benzotriazole-based, acrylonitrile-based, benzophenone-based, and aminobutadiene-based UV absorbers are preferably used. The agent is, for example, US Pat.
No. 23,859, No. 2,685,512, No. 2,
No. 739,888, No. 2,784,087, No. 2,748,021, No. 3,004,896, No. 3,052,636, No. 3,215,530,
No. 3,253,921, No. 3,533,794
No. 3, No. 3,692,525, No. 3,705,80
No. 5, No. 3,707, 375, No. 3,738, 8
No. 37, No. 3,754,919, British Patent No. 1,8
No. 21,355. More preferably, a benzotriazole-based compound is used, and further, a 2- (2′-hydroxyphenyl) benzotriazole-based compound represented by the following general formula (III) is preferable.

[0066]

[Chemical 15] (In the formula, R ₁₁ , R ₁₂ , R ₁₃ , R ₁₄ , R ₁₅ and R ₁₆ may be the same or different and each represents a hydrogen atom or a substituent, each of which is a hydrogen atom, a halogen atom, a nitro group, a hydroxyl group, It represents an alkyl group, an alkoxy group, an aryl group, an aryloxy group, an acylamino group, a carbamoyl group or a sulfo group, and R ₃₅ and R ₃₆ may be linked to each other to form a 6-membered ring.

In the ultraviolet absorber represented by the above general formula (III), the details of the atoms and the substituents represented by R ₁₁ , R ₁₂ , R ₁₃ , R ₁₄ , R ₁₅ and R ₁₆ are described in JP-A No. 1988/1988. 58-
221844, 59-46646, and 59-10.
No. 9055, Japanese Patent Publication No. 36-10466, No. 42-2
No. 6187, No. 48-5496, No. 48-41572.
U.S. Pat. Nos. 3,754,919 and 4,220,7.
No. 11 and the like. In the present invention, it is necessary to use a liquid ultraviolet absorber at room temperature, but it is also possible to use a solid ultraviolet absorber at room temperature together. However, in order to prevent the precipitation of the ultraviolet absorber and to reduce the amount of the high boiling point organic solvent that promotes the sweating phenomenon, the amount of the liquid ultraviolet absorber added at room temperature is 3% of the total amount of the ultraviolet absorber added.
0 wt% or more is preferable, and 50 wt% or more is more preferable. Table 19 shows specific examples of the ultraviolet absorber which is preferably used in the present invention and which is liquid at room temperature, but the ultraviolet absorber which can be used in the present invention and which is liquid at room temperature is not limited thereto.

[0068]

[Table 19]

The following table shows some specific examples of the present invention and the ultraviolet absorbers other than the present invention which are preferably used in combination with the liquid ultraviolet absorber of the present invention, but the present invention is not limited to these. Not something.

[0070]

[Table 20]

[0071]

[Table 21]

[0072]

[Table 22]

[0073]

[Table 23]

[0074]

[Table 24]

[0075]

[Table 25]

In the present invention, the total amount of the ultraviolet absorber contained in the non-photosensitive layer coated above the cyan color forming silver halide emulsion layer is 1000 mg / m ² or less and 150 mg / m ² or less.
m ² or more is preferable, and more preferably 600 mg / m ²
The following is 150 mg / m ² or more. The amount of gelatin contained in the non-photosensitive layer is preferably 3.0 g or less, and more preferably 2.5 g or less with respect to 1.0 g of the ultraviolet absorber. The layer structure of the silver halide color photographic light-sensitive material of the present invention is preferably a yellow color-forming layer, a magenta color-forming layer, a cyan color-forming layer, and at least one of UV absorbers which are liquid at room temperature, alone or insoluble in water from the support side. The order is a non-photosensitive hydrophilic colloid layer containing a polymer.

The term "coated above a layer" as used in the present invention means that the layer is coated on the side opposite to the support side with respect to the layer, and the layer is interposed via another hydrophilic layer. It can also include an aspect in which the coating is applied. "Coating below the layer" in the present invention means
It is used in the same meaning as above except that it is coated on the support side with respect to the layer. More specifically, “coated above the cyan color-forming silver halide emulsion layer” means that a thin non-photosensitive hydrophilic layer (which may include a blur) may be added to this emulsion layer. A non-photosensitive layer containing the compound of the general formula (III) and the polymer of the present invention may be applied, but preferably, the non-photosensitive layer is not provided via the general formula (I
II) and a non-photosensitive layer containing the polymer of the present invention is applied directly. Further, it is also preferable that the ultraviolet absorber which is solid or liquid at room temperature is contained in the cyan color forming silver halide emulsion layer for stabilizing the cyan image.

Specific examples of the water-insoluble polymer used in the present invention will be described in detail below. (A) Vinyl Polymer As the monomer forming the vinyl polymer of the present invention, acrylic acid esters, specifically methyl acrylate,
Ethyl acrylate, n-propyl acrylate, isopropyl acrylate, n-butyl acrylate, isobutyl acrylate, sec-butyl acrylate, t
ert-butyl acrylate, amyl acrylate, hexyl acrylate, 2-ethylhexyl acrylate, octyl acrylate, tert-octyl acrylate, 2-chloroethyl acrylate, 2-bromoethyl acrylate, 4-chlorobutyl acrylate, cyanoethyl acrylate, 2-acetoxyethyl acrylate , Dimethylaminoethyl acrylate, benzyl acrylate, methoxybenzyl acrylate, 2-chlorocyclohexyl acrylate, cyclohexyl acrylate, furfuryl acrylate, tetrahydrofurfuryl acrylate, phenyl acrylate, 5-hydroxypentyl acrylate, 2,2-dimethyl-3-
Hydroxypropyl acrylate, 2-methoxyethyl acrylate, 3-methoxybutyl acrylate, 2-
Ethoxyethyl acrylate, 2-iso-propoxy acrylate, 2-butoxyethyl acrylate, 2-
(2-Methoxyethoxy) ethyl acrylate, 2-
Examples thereof include (2-butoxyethoxy) ethyl acrylate, ω-methoxypolyethylene glycol acrylate (additional mol number n = 9), 1-bromo-2-methoxyethyl acrylate, 1,1-dichloro-2-ethoxyethyl acrylate. In addition, the following monomers can be used.

N-propyl methacrylate, isopropyl methacrylate, n-butyl methacrylate, isobutyl methacrylate, sec-butyl methacrylate,
tert-butyl methacrylate, amyl methacrylate, hexyl methacrylate, cyclohexyl methacrylate, benzyl methacrylate, chlorobenzyl methacrylate, octyl methacrylate, stearyl methacrylate, sulfopropyl methacrylate, N-ethyl-N-phenylaminoethyl methacrylate, 2-
(3-phenylpropyloxy) ethyl methacrylate, dimethylaminophenoxyethyl methacrylate,
Furfuryl methacrylate, tetrahydrofurfuryl methacrylate, phenyl methacrylate, cresyl methacrylate, naphthyl methacrylate, 2-hydroxyethyl methacrylate, 4-hydroxybutyl methacrylate, triethylene glycol monomethacrylate,
Dipropylene glycol monomethacrylate, 2-methoxyethyl methacrylate, 3-methoxybutyl methacrylate, 2-acetoxyethyl methacrylate, 2-
Acetoacetoxyethyl methacrylate, 2-ethoxyethyl methacrylate, 2-iso-propoxyethyl methacrylate, 2-butoxyethyl methacrylate,
2- (2-methoxyethoxy) ethyl methacrylate,
2- (2-ethoxyethoxy) ethyl methacrylate,
2- (2-butoxyethoxy) ethyl methacrylate,
ω-methoxy polyethylene glycol methacrylate (additional mol number n = 6), allyl methacrylate, methacrylic acid dimethylaminoethyl methyl chloride salt and the like can be mentioned.

Vinyl esters: Specific examples thereof include:
Vinyl acetate, vinyl propionate, vinyl butyrate, vinyl isobutyrate, vinyl caproate,
Vinyl chloroacetate, vinyl methoxyacetate,
Vinyl phenylacetate, vinyl benzoate, vinyl salicylate, etc .; acrylamides; for example, acrylamide, methylacrylamide, ethylacrylamide, propylacrylamide, butylacrylamide, tert-butylacrylamide, cyclohexylacrylamide, benzylacrylamide, hydroxymethylacrylamide,
Methoxyethyl acrylamide, dimethylaminoethyl acrylamide, phenyl acrylamide, dimethyl acrylamide, diethyl acrylamide, β-cyanoethyl acrylamide, N- (2-acetoacetoxyethyl) acrylamide, diacetone acrylamide, etc .;

Methacrylamides; for example, methacrylamide, methylmethacrylamide, ethylmethacrylamide, propylmethacrylamide, butylmethacrylamide, tert-butylmethacrylamide, cyclohexylmethacrylamide, benzylmethacrylamide, hydroxymethylmethacrylamide, methoxyethylmethacryl. Amide, dimethylaminoethyl methacrylamide, phenyl methacrylamide, dimethyl methacrylamide, diethyl methacrylamide, β-cyanoethyl methacrylamide, N- (2-acetoacetoxyethyl)
Methacrylamide, etc .; Olefins: For example, dicyclopentadiene, ethylene, propylene, 1-butene, 1-pentene, vinyl chloride, vinylidene chloride, isoprene, chloroprene, butadiene, 2,3-dimethylbutadiene, etc .; Styrenes:
For example, styrene, methylstyrene, dimethylstyrene, trimethylstyrene, ethylstyrene, isopropylstyrene, chloromethylstyrene, methoxystyrene, acetoxystyrene, chlorostyrene, dichlorostyrene, bromostyrene, vinyl benzoic acid methyl ester, etc .;

Vinyl ethers: for example, methyl vinyl ether, butyl vinyl ether, hexyl vinyl ether, methoxyethyl vinyl ether, dimethylaminoethyl vinyl ether, etc .; Others, butyl crotonic acid, hexyl crotonic acid, dimethyl itaconate, dibutyl itaconate, diethyl maleate, etc. Dimethyl maleate, dibutyl maleate, diethyl fumarate, dimethyl fumarate, dibutyl fumarate, methyl vinyl ketone, phenyl vinyl ketone, methoxyethyl vinyl ketone, glycidyl acrylate, glycidyl methacrylate, N-vinyl oxazolidone, N-vinyl pyrrolidone, acrylonitrile. , Methacrylonitrile, vinylidene chloride, methylenemalonnitrile, vinylidene, etc. That.

Regarding the monomers used in the polymer of the present invention (for example, the above-mentioned monomers), two or more kinds of monomers are used as comonomers with each other according to various purposes (for example, solubility improvement). Further, in order to adjust the solubility, monomers having an acid group as exemplified below are also used as comonomers in the range in which the copolymer does not become water-soluble. Acrylic acid: Methacrylic acid: Itaconic acid: Maleic acid: Monoalkyl itaconate, such as monomethyl itaconate, monoethyl itaconate, monobutyl itaconate; Monoalkyl maleate, such as monomethyl maleate, monoethyl maleate, monobutyl maleate Etc .; citraconic acid: styrene sulfonic acid: vinyl benzyl sulfonic acid: vinyl sulfonic acid: acryloyloxyalkyl sulfonic acid, such as acryloyloxymethyl sulfonic acid, acryloyloxyethyl sulfonic acid, acryloyloxypropyl sulfonic acid; methacryloyloxyalkyl sulfonic acid , For example, methacryloyloxymethyl sulfonic acid, methacryloyloxyethyl sulfonic acid, methacryloyloxypropyl sulfonic acid, etc .; Amidoalkyl sulfonic acids such as 2-acrylamido-2-methylethane sulfonic acid, 2-acrylamido-2-methylpropane sulfonic acid, 2-acrylamido-2-methylbutane sulfonic acid and the like; methacrylamidoalkyl sulfonic acids such as 2 -Methacrylamido-2-methylethanesulfonic acid, 2-methacrylamido-2-methylpropanesulfonic acid, 2-methacrylamido-2-methylbutanesulfonic acid and the like;

These acids are alkali metal (eg N 2
a, K, etc.) or a salt of ammonium ion. A copolymer using the hydrophilic monomers (here, those which become water-soluble when made into a homopolymer) among the vinyl monomers mentioned above and other vinyl monomers used in the present invention as comonomers. May be used as long as it does not become water-soluble. The ratio of the hydrophilic monomer in the copolymer is not particularly limited, but is usually preferably 4
It is 0 mol% or less, more preferably 20 mol% or less, and further preferably 10 mol% or less. The polymer of the present invention is
The repeating unit preferably has a —CO— bond or a phenyl group, more preferably a methacrylate-based, acrylate-based or styrene-based polymer. Also usually
Copolymers of two or more kinds of monomers are preferable, and particularly preferable are copolymers of methacrylate-based, acrylate-based, and styrene-based monomers with other monomers as listed above. Further, it is of course possible to use two or more polymers in combination.

(B) Polyester Resin Obtained by Condensing Polyhydric Alcohol with Polybasic Acid As the polyhydric alcohol, HO--R ₁ --OH (R ₁ is a hydrocarbon chain having 2 to about 12 carbon atoms, particularly Aliphatic hydrocarbon chain)
And a polyalkylene glycol having the following structure are effective, and as the polybasic acid, HOO
Those having C—R ₂ —COOH (R ₂ represents a mere bond or a hydrocarbon chain having 1 to about 12 carbon atoms) are effective. Specific examples of the polyhydric alcohol include ethylene glycol, diethylene glycol, triethylene glycol, 1,2-propylene glycol, 1,3-propylene glycol, trimethylolpropane, 1,4.
-Butane diol, isobutylene diol, 1,5-pentane diol, neopentyl glycol, 1,6-hexane diol, 1,7-heptane diol, 1,8-
Octanediol, 1,9-nonanediol, 1,10
-Decanediol, 1,11-undecanediol,
1,12-dodecanediol, 1,13-tridecanediol, 1,4-diol, glycerin, diglycerin, triglycerin, 1-methylglycerin, erythritol, mannitol, sorbit and the like can be mentioned. Specific examples of polybasic acids include oxalic acid, succinic acid, glutaric acid, adipic acid, pimelic acid, corkic acid, azelaic acid, sebacic acid, nonanedicarboxylic acid, decanedicarboxylic acid, undecanedicarboxylic acid, dodecanedicarboxylic acid, fumaric acid. Acid, maleic acid, itaconic acid, citraconic acid, phthalic acid, isophthalic acid, terephthalic acid, tetrachlorophthalic acid, methaconic acid, isohymeric acid, cyclopentadiene-maleic anhydride adduct, rosin-maleic anhydride adduct and the like. To be (C) Others Polyester obtained by, for example, the following ring-opening polymerization

[0086]

[Chemical 16] In the formula, m represents an integer of 4 to 7. The —CH ₂ — chain may be branched.

Suitable monomers which can be used to make this polyester include β-propiolactone, ε-caprolactone, dimethylpropiolactone and the like. The polymer most preferably used in the present invention is a water-insoluble and organic solvent-soluble polymer containing a repeating unit having a —CO— bond or a phenyl group in the side chain in the molecule. Some specific examples of the polymer used in the present invention are shown below, but the present invention is not limited thereto.

The following proportionals represent molar ratios. Specific examples Polymer type P-1) Polyvinyl acetate P-2) Polyvinyl propionate P-3) Polymethyl methacrylate P-4) Polyethyl methacrylate P-5) Poly n-butyl methacrylate P-6) Polyisobutyl methacrylate P- 7) Polyisopropyl methacrylate P-8) Polymethyl chloroacrylate P-9) Poly (2-tert-butylphenyl acrylate) P-10) Poly (4-tert-butylphenyl acrylate) P-11) n-Butyl methacrylate- N-vinyl-2-pyrrolidone copolymer (90:10) P-12) Methyl methacrylate-vinyl chloride copolymer (70:30) P-13) Methyl methacrylate-styrene copolymer (50:50) P- 14) Methyl methacrylate-ethyl acrylate copolymer (50:50) P-15) n-Butyl methacrylate-methyl methacrylate-styrene copolymer (50:30:20) P-16) Vinegar Vinyl-acrylamide copolymer (85:15) P-17) Vinyl chloride-vinyl acetate copolymer (65:35) P-18) Methyl methacrylate-acrylonitrile copolymer (65:35) P-19) Di Acetone acrylamide-methyl methacrylate copolymer (50:50) P-20) Ethyl methacrylate-n-butyl acrylate copolymer (70:30)

P-21) Methyl methacrylate-cyclohexyl methacrylate copolymer (50:50) P-22) N-tert-butylmethacrylamide-methyl methacrylate-acrylic acid copolymer (60:30:10) P-23 ) Methyl methacrylate-styrene-vinyl sulfonamide copolymer (70:20:10) P-24) Methyl methacrylate-phenyl vinyl ketone copolymer (70:30) P-25) n-butyl acrylate-methyl methacrylate-n -Butyl methacrylate copolymer (35:35:30) P-26) n-butyl methacrylate-pentyl methacrylate-N-vinyl-2-pyrrolidone copolymer (38:38:24) P-27) methyl methacrylate-n -Butyl methacrylate-isobutyl methacrylate-acrylic acid copolymer (37: 29: 25: 9) P-28) n-butyl methacrylate-acrylic acid (95: 5) P-29) methyl methacrylate-a Acrylic acid copolymer (95: 5) P-30) Benzyl methacrylate - acrylic acid copolymer (90:10)

P-31) n-butyl methacrylate-methyl methacrylate-benzyl methacrylate-acrylic acid copolymer (35: 35: 25: 5) P-32) n-butyl methacrylate-methyl methacrylate-benzyl methacrylate copolymer ( 35:35:30) P-33) Cyclohexyl methacrylate-methyl methacrylate-n-propyl methacrylate copolymer (37:29:34) P-34) Polypentyl methacrylate P-35) Methyl methacrylate-n-butyl methacrylate copolymer Combined (65:35) P-36) Vinyl acetate-vinyl propionate copolymer (75:25) P-37) n-butyl methacrylate-3-acryloxybutane-1-sodium sulfonate polymer (97: 3) P-38) n-butyl methacrylate-methyl methacrylate-acrylic amide copolymer (35:35:30) P-39) n-butyl methacrylate-methyl methacrylate Acrylate - vinyl chloride copolymer (37:36:27) P-40) n- butyl methacrylate - styrene copolymer (90:10)

P-41) Methyl methacrylate-N-vinyl-2-pyrrolidone copolymer (90:10) P-42) n-Butyl methacrylate-vinyl chloride copolymer (90:10) P-43) n- Butyl methacrylate-styrene copolymer (70:30) P-44) Poly (N-sec-butyl acrylamide) P-45) Poly (N-tert-butyl acrylamide) P-46) Diacetone acrylamide-methyl methacrylate copolymer Polymer (62:38) P-47) Polycyclohexyl methacrylate-methyl methacrylate copolymer (60:40) P-48) N-tert-butylacrylamide-methyl methacrylate copolymer (40:60) P-49) Poly (Nn-butyl acrylamide) P-50) Poly (tert-butyl methacrylate) -N-tert-butyl acrylamide copolymer (50:50)

P-51) tert-butylmethacrylate-methylmethacrylate copolymer (70:30) P-52) poly (N-tert-butylmethacrylamide) P-53) N-tert-butylacrylamide-methylmethacrylate copolymer Polymer (60:40) P-54) Methyl methacrylate-acrylonitrile copolymer (70:30) P-55) Methyl methacrylate-vinyl methyl ketone copolymer (38:62) P-56) Methyl methacrylate-styrene Copolymer (75:25) P-57) Methyl methacrylate-hexyl methacrylate copolymer (70:30) P-58) Poly (benzyl acrylate) P-59) Poly (4-biphenyl acrylate) P-60) Poly (4-butoxycarbonylphenyl acrylate)

P-61) Poly (tert-butyl acrylate) P-62) Poly [3-chloro-2,2-bis (chloromethyl) propyl acrylate] P-63) Poly (2-chlorophenyl acrylate) P-64 ) Poly (4-chlorophenyl acrylate) P-65) Poly (pentachlorophenyl acrylate) P-66) Poly (4-cyanobenzyl acrylate) P-67) Poly (4-cyanoethyl acrylate) P-68) Poly (4-cyano) Phenyl acrylate) P-69) Poly (cyclohexyl acrylate) P-70) Poly (2-ethoxycarbonylphenyl acrylate) P-71) Poly (3-ethoxycarbonylphenyl acrylate) P-72) Poly (4-ethoxycarbonylphenyl acrylate) ) P-73) Poly (hexadecyl acrylate) P-74) Poly (2-methoxycarbonylphenylac) Rate)

P-75) Poly (3-methoxycarbonylphenyl acrylate) P-76) Poly (4-methoxycarbonylphenyl acrylate) P-77) Poly (4-methoxyphenyl acrylate) P-78) Poly (3,5 -Dimethyladamantyl acrylate) P-79) Poly (3-dimethylaminophenyl acrylate) P-80) Polyvinyl-tert-butyrate P-81) Poly (2-naphthyl acrylate) P-82) Poly (phenyl acrylate) P-83 ) Poly (m-tolyl acrylate) P-84) Poly (o-tolyl acrylate) P-85) Poly (p-tolyl acrylate) P-86) Poly (N, N-dibutyl acrylamide) P-87) Poly (iso Hexyl acrylamide) P-88) Poly (isooctyl acrylamide) P-89) Poly (N-methyl-N-phenyl acrylamide) P-90) Poly (adama Methyl methacrylate)

P-91) Poly (benzyl methacrylate) P-92) Poly (2-bromoethyl methacrylate) P-93) Poly (2-N-tert-butylaminoethyl methacrylate) P-94) Poly (sec-butyl) Methacrylate) P-95) Poly (tert-butyl methacrylate) P-96) Poly (2-chloroethyl methacrylate) P-97) Poly (2-cyanoethyl methacrylate) P-98) Poly (2-cyanomethylphenyl methacrylate) P -99) Poly (4-cyanophenyl methacrylate) P-100) Poly (cyclohexyl methacrylate) P-101) Poly (2-ethylsulfinyl ethyl methacrylate) P-102) Poly (hexadecyl methacrylate) P-103) Poly (2 -Hydroxypropyl methacrylate) P-104) Poly (4-methoxycarbonylphenyl methacrylate) P-105) (3,5-Dimethyladamantylmethacrylate) P-106) Poly (dimethylaminoethylmethacrylate) P-107) Poly (3,3-dimethylbutylmethacrylate) P-108) Poly (3,3-dimethyl-2-butylmethacrylate) ) P-109) Poly (3,5,5-trimethylhexyl methacrylate) P-110) Poly (tetradecyl methacrylate)

P-111) Poly (4-butoxycarbonylphenylmethacrylamide) P-112) Poly (4-carboxyphenylmethacrylamide) P-113) Poly (4-ethoxycarbonylphenylmethacrylamide) P-114) Poly ( 4-Methoxycarbonylphenylmethacrylamide) P-115) Poly (butylbutoxycarbonylmethacrylate) P-116) Poly (butylchloroacrylate) P-117) Poly (butylcyanoacrylate) P-118) Poly (cyclohexylchloroacrylate) P -119) Poly (ethylchloroacrylate) P-120) Poly (ethylethoxycarbonylmethacrylate) P-121) Poly (ethylethacrylate) P-122) Poly (ethylfluoromethacrylate) P-123) Poly (isobutylchloroacrylate) ) P-124) Poly (isopropylchloroacrylate) P-125) Li-cyclohexyl acrylamide P-126) Poly (p-tert-butylstyrene)

[0097] The coating amount of the polymer contained in the non-light-sensitive layer to be coated above the cyan color forming silver halide emulsion layer in the present invention is preferably 2000 mg / m ² or less 5 mg / m ²
Or more, more preferably 1000 mg / m ² or less 10 mg
/ m ² or more. The amount of the polymer contained in the non-photosensitive layer used in the present invention is 1.0 g of the ultraviolet absorber.
On the other hand, it is preferably 5 mg or more and 5000 mg or less, and more preferably 10 mg or more and 3000 mg or less.

The polymer used in the present invention is preferably one having a relatively high glass transition temperature (Tg) in order to improve the light fastness of the ultraviolet absorber and the emulsion stability. Specifically, a polymer having Tg of 0 ° C. or higher is preferable, and 50 ° C. or higher is more preferable. When a polymer is used together with a UV absorber which is liquid at room temperature as in the present invention, gelatin coating is applied without deteriorating the physical properties of the film such as the perspiration phenomenon observed during storage of the light-sensitive material, as compared with the case where the polymer is not used together. The amount can be reduced, resulting in improved suitability for rapid processing.

The ultraviolet absorber-containing non-photosensitive layer of the present invention contains an anti-staining agent in addition to the ultraviolet absorber and the polymer.
It may contain stabilizers for ultraviolet absorbers,
Further, these additives may be contained as an emulsified dispersion in the form of being dissolved in a high boiling point organic solvent. The color photographic light-sensitive material of the present invention is constituted by coating at least one yellow color-forming silver halide emulsion layer, magenta color-forming silver halide emulsion layer and cyan color-forming silver halide emulsion layer on a support. .. In these light-sensitive emulsion layers, silver halide emulsions having sensitivity in respective wavelength regions, and dyes having a complementary color relationship with the light to be exposed-namely, yellow for blue, magenta for green and cyan for red-
By incorporating a so-called color coupler for forming the colorant, color reproduction by the subtractive color method can be performed. However, the color sensitivity of the photosensitive layer and the hue developed by the coupler may not correspond to each other as described above.

As the silver halide emulsion used in the present invention, a silver bromide emulsion or a silver iodobromide emulsion can be used, but silver chloride, silver chloroiodide or chlorobromide having a silver chloride content of 90 mol% or more. It is preferable to use the one made of silver or silver chloroiodobromide. The silver iodide content is preferably 1 mol% or less, more preferably 0.2 mol% or less.

The halogen composition of the emulsion may be different or the same between the grains, but it is preferable to use an emulsion having the same halogen composition between the grains because it is easy to make the properties of each grain uniform. Regarding the halogen composition distribution inside the silver halide emulsion grains, the so-called uniform structure grains having the same composition in any portion of the silver halide grains, or the core inside the silver halide grains and the shell surrounding it (Shell) [a single layer or a plurality of layers] particles having a so-called laminated structure having a different halogen composition or a structure having a portion having a different halogen composition inside or on the surface of the particle (edge of the particle when present on the particle surface, It is possible to appropriately select and use particles having a structure in which parts having different compositions are bonded to a corner or a surface. In order to obtain high sensitivity, it is advantageous to use either of the latter two particles rather than the particles having a uniform structure, and it is also preferable from the viewpoint of pressure resistance. When the silver halide grains have the above structure, the boundary between different portions in the halogen composition is an unclear boundary because a mixed crystal is formed due to the composition difference even if the boundary is clear. It may also be one that positively has a continuous structural change.

A so-called high silver chloride emulsion having a high silver chloride content is preferably used for a light-sensitive material suitable for rapid processing.
In the present invention, those having a silver chloride content of 90 mol% or more are used, but those having a higher silver chloride content can also be preferably used. The silver chloride content is more preferably 95 mol% or more, particularly preferably 98 mol% or more. In such a high silver chloride emulsion, the silver bromide-rich phase is layered or non-layered inside the silver halide grain and / or as described above.
Alternatively, those having a structure localized on the surface are preferable. The halogen composition of the localized phase preferably has a silver bromide content of at least 10 mol%, more preferably more than 20 mol%. These localized phases can be present inside the particles, on the edges, corners or on the surface of the particles, but those present at the corners of the particles are particularly preferred. On the other hand, it is also preferable to use grains having a uniform structure in which the distribution of the halogen composition in the grains is small, for the purpose of suppressing the sensitivity decrease when the photographic material receives pressure.

The average grain size of the silver halide grains contained in the silver halide emulsion used in the present invention (the grain size is defined by the diameter of the circle equivalent to the projected area of the grain and the number average thereof is taken) is 0. 1 μm to 2 μm is preferable. Further, the particle size distribution thereof is preferably a so-called monodisperse coefficient of variation coefficient (standard deviation of particle size distribution divided by average particle size) of 20% or less, preferably 15% or less. At this time, it is also preferable to use the above monodisperse emulsion by blending it in the same layer for the purpose of obtaining a wide latitude, or to perform multi-layer coating. The shape of silver halide grains contained in a photographic emulsion is one having a regular crystal form such as a cube, a tetradecahedron or an octahedron, an irregular shape such as a sphere or a plate. ) Those having a crystalline form or those having a composite form thereof can be used. It may also be a mixture of those having various crystal forms. In the present invention, among these, 50% or more, preferably 70% or more, more preferably 9% or more of the particles having the above-mentioned regular crystal form are used.
It is better to contain 0% or more. In addition to these, tabular grains having an average aspect ratio (circular equivalent diameter / thickness) of 5 or more, preferably 8 or more have a projected area of 50% of all grains.
Emulsions exceeding the above can also be preferably used.

The emulsion used in the present invention is described by P. Glafkides C.
himie et Phisique Photographique (published by Paul Montel, 1
967), GF Duffin Photographic Emulsion Chem
istry (Focal Press, 1966), VL Zelikman
et al by Making and Coating Photographic Emulsion
(Focal Press, Inc., 1964) and the like. That is, any of an acidic method, a neutral method, an ammonia method and the like may be used, and as a method for reacting a soluble silver salt and a soluble halogen salt, any method such as a one-sided mixing method, a simultaneous mixing method, and a combination thereof may be used. You may use. It is also possible to use a method of forming particles in an atmosphere in which silver ions are excessive (so-called reverse mixing method). As one form of the simultaneous mixing method, a method of keeping pAg constant in the liquid phase in which silver halide is produced, that is, a so-called controlled double jet method can be used. According to this method, a silver halide emulsion having a regular crystal form and a substantially uniform grain size can be obtained.

The silver halide emulsion used in the present invention has various properties for the purpose of improving sensitivity, reciprocity law property, temperature / humidity dependency during exposure, latent image storability, etc. in the process of emulsion grain formation or physical ripening. Polyvalent metal ion impurities can be introduced. Examples of the compound used include salts of cadmium, zinc, lead, copper, thallium, etc., or salts or complex salts of Group VIII elements iron, ruthenium, rhodium, palladium, osmium, iridium, platinum and the like. it can. In particular, the above Group VIII element can be preferably used. The amount of addition of these compounds may vary depending on the purpose, but silver halide 1
It is preferably 10 ^-9 to 10 ^-2 mol per mol. The silver halide emulsion used in the present invention is chemically and spectrally sensitized. For the chemical sensitization, sulfur sensitization represented by the addition of an unstable sulfur compound or selenium sensitization, noble metal sensitization represented by gold sensitization, reduction sensitization and the like can be used alone or in combination.

Spectral sensitization is carried out for the purpose of imparting spectral sensitivity in a desired light wavelength region to the emulsion of each layer in the light-sensitive material of the present invention. In the present invention, it is preferable to add a dye that absorbs light in a wavelength range corresponding to the desired spectral sensitivity-a spectral sensitizing dye. The spectral sensitizing dye used at this time is, for example, Heter by FM Harmer.
ocyclic compounds −Cyanine dyes and related compo
unds (John Wiley & Sons [New York, London], 19
64). Specific examples of compounds and the spectral sensitization method are disclosed in JP-A-62-1
Those described in the upper right column on page 22 to page 38 of the specification of Japanese Patent Publication No. 215272 are preferably used. To the silver halide emulsion used in the present invention, various compounds or precursors thereof are added for the purpose of preventing fog during the manufacturing process of the light-sensitive material, storage or photographic processing, or stabilizing photographic performance. be able to. Specific examples of these compounds are described in JP-A-62-215272, No. 3,
Those described on pages 9 to 72 are preferably used.

The emulsion used in the present invention may be any type of so-called surface latent image type emulsion in which a latent image is mainly formed on the surface of a grain, or so-called internal latent image type emulsion in which a latent image is mainly formed inside the grain. May be The gelatin used in the present invention is preferably gelatin that has been subjected to deionization treatment. Gelatin usually contains a large amount of calcium ions and is often contained at 5000 ppm or more. The deionized gelatin used in the present invention preferably has a calcium ion content of 500 ppm or less. Deionized gelatin is 10% by weight based on total gelatin
It is preferably used as described above, more preferably 20% by weight or more, and particularly preferably 50% by weight or more. Such gelatin may be used in any layer. In the light-sensitive material according to the present invention, in order to improve the sharpness of an image or the like, a hydrophilic colloid layer is added to EP 0,3
No. 37,490A2, pages 27 to 76, the dyes which can be decolorized by processing (among others, oxonol dyes) have an optical reflection density of 0.7 at 680 nm.
12% by weight or more (more preferably 14% by weight) of titanium oxide added in an amount of 0 or more, or surface-treated with a dihydric or tetravalent alcohol (eg, trimethylolethane) in the water resistant resin layer of the support. (Wt% or more) is preferable.

Photographic additives such as cyan, magenta and yellow couplers which can be used in the present invention are preferably used by dissolving them in a high boiling point organic solvent. The high boiling point organic solvent has a melting point of 100 ° C. or lower and a boiling point of 140 ° C. The above-mentioned water-immiscible compound can be used as long as it is a good solvent for the coupler. The melting point of the high boiling point organic solvent is preferably 80 ° C. or lower. The boiling point of the high boiling point organic solvent is preferably 160 ° C. or higher,
More preferably, it is 170 ° C. or higher. Details of these high boiling point organic solvents are described in JP-A-62-215272, page 137, lower right column to page 114, upper right column. Cyan, magenta or yellow couplers are also loadable latex polymers in the presence or absence of the above high boiling organic solvents (see, for example, US Pat.
No. 03,716) or dissolved with a water-insoluble and organic solvent-soluble polymer to be emulsified and dispersed in a hydrophilic colloid aqueous solution.

Preferably US Pat. No. 4,857,449
Columns 7 to 15 and international publication WO88 / 00723
The homopolymers or copolymers described on pages 12 to 30 of the publication are used, more preferably the use of methacrylate-based or acrylamide-based polymers, especially acrylamide-based polymers, from the viewpoint of color image stabilization and the like. In addition, the light-sensitive material according to the present invention includes a coupler and a European Patent EP.
It is preferable to use a color image-storing improving compound as described in No. 0,277,589A2. In particular, it is preferably used in combination with a pyrazoloazole coupler. That is, the compound (F) which chemically bonds with the aromatic amine developing agent remaining after the color development processing to form a chemically inactive and substantially colorless compound and / or the fragrance remaining after the color development processing. The use of the compound (G), which forms a chemically inactive and substantially colorless compound by chemically bonding with an oxidant of a group amine color developing agent, simultaneously or solely, for example, in storage after processing. It is preferable in order to prevent stains and other side effects due to the formation of a coloring dye due to the reaction of the coupler with the color developing agent remaining in the film or its oxidant.

In order to prevent various molds and bacteria which propagate in the hydrophilic colloid layer and deteriorate the image, the light-sensitive material according to the present invention has an anti-mold property as described in JP-A-63-271247. It is preferable to add an agent. As the support used in the present invention, usually, a transparent film such as a cellulose triacetate film or polyethylene terephthalate used in a photographic light-sensitive material, a baryta paper, a polyethylene-coated paper or a transparent support provided with a reflective layer or in combination with a reflective substance. A reflective support such as a body can be used. In addition to the above transparent film, a white polyester support or a support provided with a layer containing a white pigment on the side having a silver halide emulsion layer may be used for displays. When such a support is used, it is preferable to set the transmission density of the support in the range of 0.35 to 0.8 so that the display can be viewed with both reflected light and transmitted light. Further, in order to further improve the sharpness, it is preferable to coat an antihalation layer on the silver halide emulsion layer coated side or the back side of the support. The "reflective support" that can be preferably used in the present invention is one that enhances the reflectivity and makes the dye image formed in the silver halide emulsion layer clear, and such a reflective support includes A support coated with a hydrophobic resin containing a light-reflecting substance such as titanium oxide, zinc oxide, calcium carbonate or calcium sulfate, or a support containing a hydrophobic resin containing a light-reflecting substance dispersed therein. Is included. For example, baryta paper; polyethylene-coated paper; polypropylene-based synthetic paper; transparent support provided with a reflective layer or in combination with a reflective material (eg, glass plate, polyethylene terephthalate film, cellulose acetate such as triacetate cellulose or cellulose nitrate, polyamide Film, polycarbonate film,
Polystyrene film, vinyl chloride resin, etc.).

The light-sensitive material according to the present invention may be exposed to visible light or infrared light. The exposure method may be low illuminance exposure or high illuminance short time exposure, and in the latter case, a laser scanning exposure method in which the exposure time per pixel is shorter than 10 ⁻⁴ seconds is preferable. Further, it is preferable to use the band stop filter described in U.S. Pat. No. 4,880,726 upon exposure. As a result, the light color mixture is removed, and the color reproducibility is significantly improved. The color photographic light-sensitive material of the present invention is preferably subjected to color development after exposure, bleach-fixing, and washing treatment (or stabilization treatment).
Bleaching and fixing may be performed separately instead of the one bath as described above. When the color photographic light-sensitive material of the present invention is used, processing from color development to water washing (or stabilization) can be performed within 4 minutes. More preferably, it is within 3 minutes.

Silver halide emulsions and other materials (additives etc.) and photographic constituent layers (layer arrangement etc.) applied to the light-sensitive material according to the present invention, and processing methods applied for processing this light-sensitive material. As the treatment additives, those described in the following patent publications, particularly European Patent EP 0,355,660A2 (JP-A-2-139544) are preferably used.

[0113]

[Table 26]

[0114]

[Table 27]

[0115]

[Table 28]

[0116]

[Table 29]

Further, diphenylimidazole type cyan couplers described in JP-A-2-33144, European Patent EP
No. 3,333,185A2, 3-hydroxypyridine type cyan coupler (among others, coupler (42) listed as a specific example, which is a 4-equivalent coupler having a chlorine-releasing group to form a 2-equivalent compound, or coupler (6 And (9) are particularly preferable) and the cyclic active methylene cyan couplers described in JP-A-64-32260 (coupler examples 3, 8, and 34 listed as specific examples are particularly preferable) alone. It may be used or may be used.
Alternatively, any of these couplers may be used in combination with the coupler represented by the general formula (C). Further, as a processing method of a silver halide color light-sensitive material using a high silver chloride emulsion having a silver chloride content of 90 mol% or more, JP-A 2-20 is known.
The method described in No. 7250, page 27, upper left column to page 34, upper right column is preferably applied. ..

[0118]

The present invention will be described in more detail based on the following examples, but the invention is not intended to be limited thereto. Example 1 A surface of a paper support laminated on both sides with polyethylene was provided with a gelatin subbing layer containing sodium dodecylbenzenesulfonate after being subjected to corona discharge treatment, and various photographic constituent layers were further applied to form a layer shown below. A multilayer color photographic paper (Sample 101) having the constitution was produced. The coating liquid was prepared as follows.

Preparation of coating liquid for first layer Yellow coupler (ExY) 153 g, color image stabilizer (Cpd-1) 15 g, color image stabilizer (Cpd-2) 7.
5 g, color image stabilizer (Cpd-3) 16 g, color image stabilizer (Cpd-11) 3.8 g were dissolved by adding ethyl acetate 30 cc and solvent (Solv-1) and solvent (Solv-2) 25 g respectively. This solution was added with 10% sodium dodecylbenzenesulfonate (60 cc) and citric acid (10 g).
An emulsified dispersion A was prepared by adding 1000 g of a 10% aqueous gelatin solution containing ## STR3 ## and emulsifying and dispersing. On the other hand, a silver chlorobromide emulsion B (a cube, a 6: 4 mixture of a large size emulsion B1 having an average grain size of 0.88 μ and a small size emulsion B2 having a grain size of 0.70 μ (silver molar ratio). The variation coefficient of the grain size distribution is 0.08 and 0.10, respectively, and each size emulsion contained 0.3 mol% of silver bromide in a part of the grain surface, and the rest was composed of silver halide grains in which silver chloride was prepared. The above emulsified dispersion A and this silver chlorobromide emulsion B were mixed and dissolved to prepare a coating solution for the first layer having the composition shown below.

Preparation of coating liquid for sixth layer 10.0 g of ultraviolet absorber (UV-3) and 15 g of ethyl acetate
A solution in which ml is heated to 60 ° C. and completely dissolved is referred to as solution A. To this solution A, 90 g of a 15% gelatin aqueous solution containing 10% sodium dodecylbenzenesulfonate was added and emulsified and dispersed. Water and a gelatin aqueous solution were added to this emulsified dispersion, and the amounts shown in Table 33 were applied. In Samples 102 to 117, the polymer and the solvent (S
olv-7) or the compound represented by the general formula (II), the above-mentioned A dissolved according to the composition of Table 33 is used.
A liquid similar to the liquid was prepared and used for the preparation of the samples shown in Table 33.

The coating solutions for the second to fifth and seventh layers were prepared in the same manner as the coating solution for the first layer and the coating solution for the sixth layer. As the gelatin hardening agent for each layer, 1-oxy-3,
5-Dichloro-s-triazine sodium salt was used.
Further, Cpd-15 and Cpd-16 were added to each layer so that the total amounts were 25.0 mg / m ² and 50.0 mg / m ² , respectively. The following spectral sensitizing dyes were used in the silver chlorobromide emulsion of each photosensitive emulsion layer.

[0122]

[Table 30]

[0123]

[Table 31]

[0124]

[Table 32]

For the blue-sensitive emulsion layer, the green-sensitive emulsion layer and the red-sensitive emulsion layer, 1- (5-methylureidophenyl)-
5-mercaptotetrazole with silver halide 1
3.4 × 10 ⁻⁴ mol, 9.7 × 10 ⁻⁴ mol per mol,
5.5 × 10 ⁻⁴ mol was added. Moreover, 4-hydroxy-6-methyl-1,3,3 is added to the blue-sensitive layer and the green-sensitive layer.
1 × 10 ⁻⁴ mol and 2 × 10 ⁻⁴ mol of a, 7-tetrazaindene were added per mol of silver halide, respectively. In addition, the following dyes (the amount in parentheses indicates the coating amount) were added to the emulsion layer to prevent irradiation.

[0126]

[Chemical 17]

(Layer Structure) The composition of each layer is shown below. The numbers represent the coating amount (g / m ² ). The silver halide emulsion represents the coating amount in terms of silver. Support: Polyethylene laminated paper [Polyethylene on the first layer side contains white pigment (TiO ₂ ) and bluish dye (ultraviolet)] First layer (blue sensitive emulsion layer) Silver chlorobromide emulsion B 0.27 Gelatin 1.37 Yellow coupler (ExY) 0.79 Color image stabilizer (Cpd-1) 0.08 Color image stabilizer (Cpd-2) 0.04 Color image stabilizer (Cpd-3) 0.08 Solvent ( Solv-1) 0.13 Solvent (Solv-2) 0.13 Second layer (color mixing prevention layer) Gelatin 0.99 Color mixing inhibitor (Cpd-4) 0.08 Solvent (Solv-2) 0.25 Solvent ( Solv-3) 0.25

Third Layer (Green-Sensitive Emulsion Layer) Silver chlorobromide emulsion (cubic, 6: 4 mixture of large size emulsion G1 having an average grain size of 0.55 μ and small size emulsion G2 having a grain size of 0.39 μ (Ag mol) The coefficient of variation of the grain size distribution is 0.10 and 0.08, respectively. For each size emulsion, 0.8 mol% of AgBr is locally contained in a part of the grain surface and the rest is silver chloride grains containing silver chloride. 0.13 Gelatin 1.45 Magenta coupler (ExM) 0.16 Color image stabilizer (Cpd-6) 0.15 Color image stabilizer (Cpd-2) 0.03 Color image stabilizer (Cpd-7) 0.01 color image stabilizer (Cpd-8) 0.01 color image stabilizer (Cpd-9) 0.08 solvent (Solv-3) 0.50 solvent (Solv-4) 0.15 solvent (Solv-5) ) 0.15

Fourth Layer (Color Mixing Prevention Layer) Gelatin 1.41 Color mixing inhibitor (Cpd-4) 0.10 Color image stabilizer (Cpd-5) 0.02 Ultraviolet absorber (UV-1) 0.47 Solvent (Solv-8) 0.24 Fifth layer (red-sensitive emulsion layer) Silver chlorobromide emulsion (cubic, large size emulsion R1 with average grain size 0.58μ and small size emulsion R2 with 0.45μ 7: 3 mixture (Ag molar ratio) Coefficients of variation of grain size distribution are 0.09 and 0.11, and each size emulsion contains 0.6 mol% AgBr locally in a part of grain surface and the rest is silver chloride. 0.20 Gelatin 0.85 Cyan coupler (ExC) 0.33 UV absorber (UV-2) 0.18 Color image stabilizer (Cpd-1) 0.30 Color image stabilizer (Cpd) -8) 0.01 Color image stabilizer (Cpd -9) 0.01 Color image stabilizer (Cpd-10) 0.15 Color image stabilizer (Cpd-11) 0.15 Color image stabilizer (Cpd-12) 0.01 Solvent (Solv-1) 01 Solvent (Solv-6) 0.22

6th layer (UV absorbing layer) Gelatin 0.50 (see Table 33) 7th layer (Protective layer) Gelatin 1.13 Acrylic modified copolymer of polyvinyl alcohol (Modification degree 17%) 0.15 Liquid paraffin 0.03 Color image stabilizer (Cpd-13) 0.01 Specific examples of the compound used here are shown below.

[0131]

[Chemical 18]

[0132]

[Chemical 19]

[0133]

[Chemical 20]

[0134]

[Chemical 21]

[0135]

[Chemical formula 22]

[0136]

[Chemical formula 23]

[0137]

[Chemical formula 24]

[0138]

[Chemical 25]

[0139]

[Chemical formula 26]

[0140]

[Chemical 27]

[0141]

[Chemical 28]

[0142]

[Chemical 29]

Further, samples 102 to 115 were prepared by changing the composition of the yellow coupler of the first layer and the composition of the sixth layer as shown in Table 33 with respect to sample 101. here,
When the yellow coupler of the present invention was used instead of Sample 101, the addition amount of the coupler of the present invention and silver chlorobromide emulsion B was changed to 70% (molar ratio) to prepare a coating solution for the first layer. ..

[0144]

[Table 33]

First, a sensitometer (FWH type manufactured by Fuji Photo Film Co., Ltd., color temperature of a light source of 3200K) was used as a sample 101.
Was used to provide a gradation exposure of three-color separation for sensitometry. The exposure time at this time is 0.1 seconds, and the exposure amount is 250C.
I went to become an MS. The exposed sample was subjected to color development processing using a paper processor using the following processing steps and solutions having the processing solution compositions.

Treatment Step Temperature Time Replenisher ^* Tank Capacity Color Development 35 ° C. 30 seconds and 45 seconds 161 ml 17 liters Bleach-fix 30-35 ° C. 45 seconds 215 ml 17 liters Rinse 30 ° C. 90 seconds 350 ml 10 liters Dry 70-80 ℃ 60 seconds * Replenishment amount per 1 m ² of light-sensitive material

The composition of each processing solution is as follows. Color developer Tank solution Replenisher Water 800ml 800ml Ethylenediamine-N, N, N ', N'-tetramethylenephosphonic acid 1.5g 2.0g Kaurum bromide 0.025g-Triethanolamine 8.0g 12.0g Sodium chloride 1.4 g-potassium carbonate 25 g 25 g N-ethyl-N- (β-methanesulfonamidoethyl) -3-methyl-4-aminoaniline sulfate 5.0 g 7.0 g N, N-bis (carboxymethyl) hydrazine 4. 0 g 5.0 g N, N-di (sulfoethyl) hydroxyl amine 1Na 4.0 g 5.0 g Optical brightener (WHITEX 4B, Sumitomo Chemical Co., Ltd.) 1.0 g 2.0 g Water was added to 1000 ml 1000 ml pH (25 ° C) ) 10.05 10.45

Bleach-fixing solution (same as tank solution and replenisher) Water 400 ml Ammonium thiosulfate (700 g / liter) 100 ml Sodium sulfite 17 g Ethylenediaminetetraacetic acid iron (III) ammonium 55 g Ethylenediaminetetraacetate disodium 5 g Ammonium bromide 40 g Water was added. 1000 ml pH (25 ° C) 6.0 Rinse solution (tank solution and replenisher are the same) Ion-exchanged water (calcium and magnesium are below 3 ppm each)

Then, the samples 102 to 117 were exposed to light in the same manner as the sample 101, and color development processing was performed in the above processing step. 30 in the treated sample
The maximum color density (D ^{30 "} ) in the second development process was used as a guide for the color development speed. That is, the larger this value, the better the color development of the yellow coupler and the better the color balance after processing. Further, the following evaluation was performed on the sample processed by the development for 45 seconds (light fastness) Xenon fading tester (about 100,000 lux).
The density decrease rate (%) of the cyan color-developing dye at the initial density of 2.0 after 20 days of light irradiation was shown. All the results are shown in Table 34.

[0150]

[Table 34]

Looking at Comparative Samples 102 to 105 in which the ultraviolet absorber and / or the polymer which is liquid at room temperature are used together with the comparative sample 101 using the comparative coupler, the liquid ultraviolet absorber and the polymer are used in combination. In Comparative Samples 104 and 105, the color development rate of the yellow coupler is improved as compared with Samples 101 to 103, but Samples 106 to 115, which are combinations of the present invention, are yellow due to the combined use of the liquid ultraviolet absorber and the polymer. It can be seen that the effect of improving the color developability of the coupler becomes more remarkable. This significantly improves the color balance of cyan, magenta and yellow. Furthermore, in Samples 106 to 113 in which the compound represented by the general formula (II) is not used in combination, Sample 1 containing this
It can be seen that the light fastness of the cyan dye is improved as compared with 14 and 115. On the other hand, using the same exposed sample as above, using the above-mentioned processing step and processing composition solution, continuous processing was carried out until the tank capacity for color development was replenished to twice, and the developing processing solutions in running equilibrium state were respectively treated. It was made. It was confirmed that the effects of the present invention can be obtained even when the same test as described above is performed using this paper treatment liquid.

Example 2 Samples 107, 108 and 114 prepared in Example 1, and
Samples 201, 202, and 203 prepared in the same manner except that the fourth layer of each sample was changed to the configuration shown below had a rinse time of 90 seconds when subjected to the same exposure and treatment as in Example 1. , 150 seconds, 210 seconds, and change the time from color development to the end of rinsing 3
The yellow density of the white background portion after leaving for 8 days under the condition of 80 ° C. and 70% RH was measured for the samples of 4 minutes, 5 minutes, and 5 minutes, and the change amount was shown as the degree of white background coloring.

Fourth Layer (Color Mixing Prevention Layer) Gelatin 1.05 Color Image Stabilizer (Cpd-4) 0.10 Color Image Stabilizer (Cpd-5) 0.02 Solvent (Solv-2) 0.18 Solvent ( Solv-3) 0.18

[0154]

[Table 35]

As shown in Table 35, in the samples 201, 202 and 203 containing no ultraviolet absorber in the fourth layer, the degree of non-coloring of the white background at a total processing time of 5 minutes consisting of a rinsing time of 210 seconds was measured. It can be seen that the rapid processing property is excellent, even after the short-time processing of 90 minutes and the total processing time of 3 minutes. On the other hand, using the same exposed sample as described above, using the above-mentioned processing step and processing composition solution, continuous processing was carried out until the tank capacity of the color developing solution was replenished to twice, and a developing processing solution in a running equilibrium state was obtained. Each was produced. It was confirmed that the effects of the present invention can be obtained even when the same test as described above is performed using this paper treatment liquid.

[0156]

According to the present invention, a silver halide color photographic light-sensitive material having excellent rapid processability can be obtained, and at the same time, the light fastness of a dye image after rapid processing and the non-coloring property of a white background are improved.

Claims (3)

[Claims] 1. A silver halide color photographic light-sensitive material having at least one yellow, magenta and cyan color-forming silver halide emulsion layers each having different color sensitivity from each other and at least one non-photosensitive hydrophilic colloid layer on a support. In, at least one layer of the yellow color-forming silver halide emulsion layer contains at least one yellow coupler represented by the following general formula (I), and at least one layer of the non-photosensitive hydrophilic colloid layer is liquid at room temperature. A silver halide color photographic light-sensitive material comprising at least one ultraviolet absorber and at least one water-insoluble homopolymer or copolymer. [Chemical 1] (In the formula, X represents an organic residue necessary for forming a nitrogen-containing heterocyclic group together with a nitrogen atom, Y represents an aryl group or a heterocyclic group, and Z represents the coupling of this coupler with an oxidized product of a developing agent. Represents a group that leaves when it reacts.) 2. A non-photosensitive hydrophilic colloid layer containing a UV absorber which is liquid at room temperature and a water-insoluble polymer is coated on the cyan color forming silver halide emulsion (on the side farther from the support). 2. The silver halide color photographic light-sensitive material according to claim 1, wherein 3. A compound represented by the following general formula (II):
2. A hydrophilic colloid layer, which is contained substantially without coexistence with a solid or liquid ultraviolet absorber at room temperature, is provided below and adjacent to a cyan color forming silver halide emulsion layer. Or the silver halide color photographic light-sensitive material described in 2. [Chemical 2] (In the formula, R ₂₁ , R ₂₂ , R ₂₃ and R ₂₄ may be the same or different and each represents a hydrogen atom or a substituent, provided that R _{21 to} R
_At least one of ₂₄ must be a substituent. )