JPH05301751A - Complex cement admixture - Google Patents
Complex cement admixtureInfo
- Publication number
- JPH05301751A JPH05301751A JP13197792A JP13197792A JPH05301751A JP H05301751 A JPH05301751 A JP H05301751A JP 13197792 A JP13197792 A JP 13197792A JP 13197792 A JP13197792 A JP 13197792A JP H05301751 A JPH05301751 A JP H05301751A
- Authority
- JP
- Japan
- Prior art keywords
- powder
- cement admixture
- cement
- silica
- admixture
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B20/00—Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials
- C04B20/10—Coating or impregnating
- C04B20/1055—Coating or impregnating with inorganic materials
- C04B20/1066—Oxides, Hydroxides
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Glanulating (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
Abstract
Description
【０００１】[0001]
【産業上の利用分野】本発明は、セメントスラリー中へ
添加された際に分散性が良好で、かつ溶解性に優れた複
合セメント混和剤に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a composite cement admixture which has excellent dispersibility and solubility when added to a cement slurry.
【０００２】[0002]
【従来の技術】現在、セメント混和剤としては、流動化
剤、ＡＥ剤、ＡＥ減水剤、高性能ＡＥ減水剤、硬化促進
剤、凝結遅延剤、分離低減剤、防錆剤、膨張剤、ポリマ
ー混和剤、収縮低減剤、着色剤、補強剤等が使用されて
おり、その使用に当たっては、コンクリート、モルタル
等のセメント配合物の標準調合に合わせて、セメント混
和剤を添加している。なお、これらセメントへの添加物
においては、むしろ“セメント混和材”と呼ぶ方が適当
であったり、現実に“セメント混和材”として市販され
ているものもあるが、本発明においてはこれらも含めて
“セメント混和剤”と呼ぶ。2. Description of the Related Art Currently, cement admixtures include superplasticizers, AE agents, AE water reducing agents, high-performance AE water reducing agents, hardening accelerators, setting retarders, separation reducing agents, rust preventives, swelling agents, polymers. Admixtures, shrinkage-reducing agents, coloring agents, reinforcing agents, etc. are used, and in using them, cement admixtures are added in accordance with the standard formulation of cement formulations such as concrete and mortar. Of these additives to cement, it is rather more appropriate to call them "cement admixtures", and some are actually marketed as "cement admixtures", but in the present invention, these are also included. Called "cement admixture".
【０００３】これら混和剤は、多くの場合液状混和剤と
して、コンクリート、モルタル等のセメント配合物に添
加される。また、特にスランプ低下防止用の混和剤とし
て、強度低下や乾燥収縮によるひび割れ発生の防止を目
的として、水分を除いた粉体ないし顆粒状の混和剤が提
案されている（特開昭５８−１２５６５２号公報）。These admixtures are often added as liquid admixtures to cement mixes such as concrete and mortar. Further, as an admixture for preventing slump reduction, a powder or granular admixture without water is proposed for the purpose of preventing the occurrence of cracks due to strength reduction and drying shrinkage (Japanese Patent Laid-Open No. 58-125652). Publication).
【０００４】しかし、粉体ないし顆粒状混和剤は、固体
としてコンクリート、モルタル等の水／無機物スラリー
中に添加されるために、完全に溶解させることは困難で
あり、これら混和剤の性能を十分に発揮させることが難
しかった。However, since the powdery or granular admixture is added as a solid to water / inorganic slurry such as concrete or mortar, it is difficult to completely dissolve the admixture, and the performance of these admixtures is insufficient. It was difficult to make the best use of.
【０００５】特に、最近混和剤として用いられることが
多くなった高分子界面活性剤は、コンクリート、モルタ
ル、セメントスラリー等のセメント組成物中へ溶解する
際に、通常の溶解方法では水分によって粉体表面が粘着
性を持った膜となり、その粒子同士が凝集して粘性膜が
不透水層となり、いわゆるダマの状態になってしまう。
その結果、分散性が悪化し、溶解速度が著しく低下して
しまうため、分散性が著しく悪い場合はスランプが低下
しなくなり、また、ダマがコンクリート、モルタル、セ
メントスラリー中に残存し、硬化後の表面に斑点状のダ
マが残って表面美感を損ねる等の問題があった。In particular, polymer surfactants, which have recently been often used as an admixture, are powdered by water when dissolved in a cement composition such as concrete, mortar or cement slurry by a usual dissolution method. The surface becomes a sticky film, and the particles agglomerate to make the viscous film an impermeable layer, resulting in a so-called lump.
As a result, the dispersibility is deteriorated and the dissolution rate is significantly reduced, so that the slump does not decrease when the dispersibility is extremely poor, and the lump remains in the concrete, mortar, and cement slurries. There was a problem that speckled lumps remained on the surface, impairing the surface aesthetics.
【０００６】[0006]
【発明が解決しようとする課題】本発明者らは、上記の
如き従来技術の問題点を解決すべく鋭意研究の結果、あ
る特定の微粉体を配合すれば、コンクリート、モルタ
ル、セメントスラリー等のセメント配合物中での分散性
・溶解性不良の問題が解決できることを見いだした。DISCLOSURE OF THE INVENTION As a result of intensive research to solve the problems of the prior art as described above, the present inventors have found that if a certain fine powder is added, concrete, mortar, cement slurry, etc. We have found that the problems of poor dispersibility and solubility in cement compounds can be solved.
【０００７】すなわち本発明は、水溶性の混和剤をコン
クリート、モルタル、セメントスラリー等のセメント配
合物中に溶解する際に、分散性・溶解性が良好で、混和
剤が溶け残りを生じない複合セメント混和剤を提供する
ものである。That is, according to the present invention, when a water-soluble admixture is dissolved in a cement mixture such as concrete, mortar or cement slurry, the dispersibility / solubility is good, and the admixture does not leave an undissolved composite. A cement admixture is provided.
【０００８】[0008]
【課題を解決するための手段】本発明の複合セメント混
和剤は、水溶性のセメント混和剤粉体を、シリカ系微粉
体で被覆したことを特徴とする。The composite cement admixture of the present invention is characterized in that a water-soluble cement admixture powder is coated with a silica-based fine powder.
【０００９】[0009]
【発明の実施態様】本発明で用いられる水溶性のセメン
ト混和剤粉体は、粉体となりうるセメント混和剤をすべ
て包含し、例えば、流動化剤、ＡＥ剤、ＡＥ減水剤、高
性能ＡＥ減水剤、硬化促進剤、凝結遅延剤、分離低減
剤、防錆剤、膨張剤、ポリマー混和剤、収縮低減剤、着
色剤、補強剤等である。BEST MODE FOR CARRYING OUT THE INVENTION The water-soluble cement admixture powder used in the present invention includes all cement admixtures capable of forming powders, for example, fluidizers, AE agents, AE water reducing agents, high-performance AE water reducing agents. Agents, curing accelerators, setting retarders, separation reducing agents, rust preventives, swelling agents, polymer admixtures, shrinkage reducing agents, coloring agents, reinforcing agents and the like.
【００１０】特に効果が顕著であるのは、水への溶解性
が比較的悪い水溶性高分子粉体を使用したセメント混和
剤である。水溶性高分子粉体の例としては、合成高分子
であるポリスチレンスルホン酸またはこれらの塩（ナト
リウム塩、カルシウム塩等）、ナフタレンスルホン酸塩
ホルマリン縮合物（ナトリウム塩、カルシウム塩等）、
ポリアクリル酸系高分子、ポリアクリルアミド系高分子
およびその部分加水物、ポリビニルアルコール系高分子
等が挙げられる。また半合成高分子としては、メチルセ
ルロースやヒドロキシエチルセルロース等のセルロース
系高分子、デンプン、リグニン系高分子、天然高分子系
では、各種糖類、ガム等に代表される植物粘質物、微生
物発酵による粘質物、動物タンパク等が挙げられる。Particularly effective is a cement admixture using a water-soluble polymer powder having a relatively poor solubility in water. Examples of the water-soluble polymer powder include polystyrene sulfonic acid which is a synthetic polymer or a salt thereof (sodium salt, calcium salt, etc.), naphthalene sulfonate formalin condensate (sodium salt, calcium salt, etc.),
Examples thereof include polyacrylic acid type polymers, polyacrylamide type polymers and partial hydrolysates thereof, polyvinyl alcohol type polymers and the like. In addition, as semi-synthetic polymers, cellulosic polymers such as methyl cellulose and hydroxyethyl cellulose, starch, lignin-based polymers, natural polymer systems, various sugars, plant mucilage represented by gums, mucilage produced by microbial fermentation. , Animal proteins and the like.
【００１１】本発明で用いられるシリカ系微粉体として
は、例えば、シリカフューム、シリカフラワー、ホワイ
トカーボン、ゼオライト、ベントナイト、タルク等が挙
げられる。Examples of the silica-based fine powder used in the present invention include silica fume, silica flour, white carbon, zeolite, bentonite, talc and the like.
【００１２】（ａ）セメント混和剤粉体と（ｂ）シリカ
系微粉体との混合量は、重量比で（ａ）：（ｂ）＝９
９：１〜５０：５０の範囲が好ましく、より好ましくは
９５：５〜６０：４０である。The mixing amount of (a) cement admixture powder and (b) silica-based fine powder is (a) :( b) = 9 by weight ratio.
The range of 9: 1 to 50:50 is preferable, and the range of 95: 5 to 60:40 is more preferable.
【００１３】セメント混和剤粉体の平均粒径は、１μｍ
〜５ｍｍが好適であり、好ましくは１μｍ〜３ｍｍであ
る。このように、本発明のセメント混和剤粉体では、通
常の粉末状物の他に顆粒状や塊状に近いものも包含す
る。The average particle size of the cement admixture powder is 1 μm
˜5 mm is suitable, and preferably 1 μm to 3 mm. As described above, the cement admixture powder of the present invention includes not only ordinary powdery materials but also powders close to granules and lumps.
【００１４】本発明のシリカ系微粉体の平均粒径は０．
０１〜１００μｍのものが好適であり、好ましくは０．
０３〜５０μｍである。また、（ａ）セメント混和剤粉
体の平均粒径と（ｂ）シリカ系微粉体の平均粒径の比
は、（ｂ）／（ａ）＝０．０００１〜１の範囲が好適で
あり、さらに好ましくは０．００１〜０．１の範囲であ
る。The average particle size of the silica-based fine powder of the present invention is 0.
It is preferably from 0.1 to 100 μm, more preferably from 0.
It is from 03 to 50 μm. Further, the ratio of the average particle diameter of the (a) cement admixture powder and the average particle diameter of the (b) silica-based fine powder is preferably in the range of (b) / (a) = 0.0001 to 1, More preferably, it is in the range of 0.001 to 0.1.
【００１５】シリカ系微粉体によるセメント混和剤粉体
の被覆は、表面被覆率が１０％以上で効果を発揮する
が、特に５０〜１００％の被覆率が好ましく、より好ま
しくは８０〜１００％である。The coating of the cement admixture powder with the fine silica powder is effective when the surface coverage is 10% or more, but a coverage of 50 to 100% is particularly preferable, and 80 to 100% is more preferable. is there.
【００１６】本発明の複合セメント混和剤を製造するに
は、セメント混和剤粉体とシリカ系微粉体とを混合すれ
ばよく、通常の粉体の乾式ブレンド方法をそのまま適用
できる。In order to produce the composite cement admixture of the present invention, the cement admixture powder and the silica-based fine powder may be mixed, and the usual dry blending method of powder can be applied as it is.
【００１７】また本発明の複合セメント混和剤は、セメ
ント混和剤粉体に対して少しづつシリカ系微粉体を混合
していく方法、シリカ系微粉体に対して少しづつセメン
ト混和剤粉体を混合していく方法、両者を一括に混合す
る方法のいずれでも製造できる。The composite cement admixture of the present invention is a method in which a silica-based fine powder is mixed little by little with a cement admixture powder, and a cement-based admixture powder is mixed little by little with a silica-based fine powder. It can be manufactured by either a method of mixing the two or a method of mixing the both together.
【００１８】製造に使用する混合機は、撹拌容器や撹拌
羽根の形状、材質等は特に問題とはならず、水平円筒型
混合機、傾斜円筒型混合機、Ｖ型混合機、正立方体型混
合機、二重円錐型混合機、リボン型混合機、スクリュー
混合機等の従来一般に使用されているもので差し支えな
く、それらを用いて１０分間程度撹拌・混合すればよ
い。この混合時に、セメント混和剤粉体に対してシリカ
系微粉体が静電気的に付着すると、セメント混和剤粉体
の被覆が均一となり、被覆率を高めることができる。よ
って、セメント混和剤粉体とシリカ系微粉体とは、その
混合時に両者が逆極性（異符号）に帯電する組合せが好
ましい。There is no particular problem with the shape and material of the agitating vessel and the agitating blade in the mixer used in the production, and the horizontal cylinder type mixer, the inclined cylinder type mixer, the V type mixer, the cubic cube type mixer are used. A machine, a double cone type mixer, a ribbon type mixer, a screw mixer or the like which has been conventionally used may be used, and these may be used for stirring and mixing for about 10 minutes. When the silica-based fine powder electrostatically adheres to the cement admixture powder during this mixing, the cement admixture powder is uniformly coated, and the coverage can be increased. Therefore, it is preferable that the cement admixture powder and the silica-based fine powder have a combination of being charged with opposite polarities (different signs) during mixing.
【００１９】なお本発明の複合セメント混和剤粉体は、
混和剤粉体とシリカ系微粉体の組み合わせであるが、こ
れら複数組み合わせて混合し組成物としても、充分に効
果を発揮する。本発明の複合セメント混和剤が良好な分
散性を示して溶解するのは、以下のような作用機構によ
るものと考えられる。The composite cement admixture powder of the present invention is
Although it is a combination of the admixture powder and the silica-based fine powder, it is possible to sufficiently exhibit the effect even if a composition is prepared by combining a plurality of these. The reason why the composite cement admixture of the present invention exhibits good dispersibility and dissolves is considered to be due to the following action mechanism.
【００２０】（１） セメント混和剤粉体表面を覆うシ
リカ系微粉体皮膜の濡れ性により個々の粒子が充分に濡
らされる。 （２） 水に接することによりセメント混和剤粉体表面
に発生する表面粘性を、シリカ系微粉体皮膜が抑制して
粒子同士の凝集を防止し、ダマの発生を防ぐ。 上記２つの作用が同時に促進され、シリカ系微粉体を添
加しない通常の単一系の溶解より著しく溶解性が高めら
れる。(1) The individual particles are sufficiently wetted by the wettability of the silica-based fine powder film covering the surface of the cement admixture powder. (2) The silica-based fine powder film suppresses the surface viscosity generated on the surface of the cement admixture powder by coming into contact with water, and the particles are prevented from agglomerating to prevent lumps. The above two actions are promoted at the same time, and the solubility is remarkably enhanced as compared with the usual single-system dissolution in which no silica-based fine powder is added.
【００２１】[0021]
【発明の効果】本発明に従うと、セメント混和剤粉体を
完全にセメントスラリー中に溶解することができるた
め、面倒な製造過程やコストの高い改質を行なうことな
く、入手の容易なシリカ系微粉体と簡便な製造方法に
て、従来の問題点であった粉体粒子同士の凝集やダマの
問題を防止して、セメント混和剤の性能を完全に発揮せ
しめることができる。EFFECTS OF THE INVENTION According to the present invention, the cement admixture powder can be completely dissolved in the cement slurry, and therefore, the silica-based system which is easily available without a troublesome manufacturing process and costly modification. A fine powder and a simple production method can prevent the problems of agglomeration of powder particles and lumps, which have been problems in the past, and allow the cement admixture to exhibit its full performance.
【００２２】また本発明によれば、溶解性の問題を生じ
ることなく、セメント混和剤を粉体として添加できるた
め、水溶液として添加した場合のように水分の増加がな
く、コンクリートの強度低下や乾燥収縮によるひび割れ
発生等が防止できる。Further, according to the present invention, since the cement admixture can be added as a powder without causing a problem of solubility, the water content does not increase as in the case of adding it as an aqueous solution, and the strength of concrete is decreased and the concrete is dried. The occurrence of cracks due to shrinkage can be prevented.
【００２３】[0023]
【実施例】後記表３に示すセメント混和剤粉体とシリカ
系微粉体とを、合計１００ｇになるように表３に示す比
率にて撹拌混合して複合セメント混和剤を製造した。撹
拌混合は、リボン型撹拌羽根を取り付けた新東科学
（株）製のスリーワンモーターを用い、５分間行なっ
た。これらの混和剤を下記の評価方法に従って評価した
結果を表３（複合セメント混和剤の組成）および表４
（評価結果）に示した。EXAMPLES The cement admixture powder shown in Table 3 below and the silica-based fine powder were agitated and mixed at a ratio shown in Table 3 so that the total amount was 100 g to produce a composite cement admixture. The stirring and mixing were performed for 5 minutes using a three-one motor manufactured by Shinto Kagaku Co., Ltd. equipped with a ribbon-type stirring blade. The results of evaluating these admixtures according to the following evaluation methods are shown in Table 3 (composition of composite cement admixtures) and Table 4.
The results are shown in (Evaluation results).
【００２４】また、各種複合セメント混和剤中の各粉体
の帯電状態（符号）を箔検電器（東京前川科学社製）を
用いて測定したところ、いずれもセメント混和剤粉体が
十（プラス）に帯電し、シリカ系微粉体が−（マイナ
ス）に帯電していた。The charge state (sign) of each powder in the various composite cement admixtures was measured using a foil electroscope (manufactured by Tokyo Maekawa Kagaku Co., Ltd.). ), And the silica-based fine powder was negatively (-) charged.
【００２５】（１） セメント混和剤粉体表面のシリカ
系微粉体による被覆率 セメント混和剤粉体表面のシリカ系微粉体による被覆率
は、オリンパス社製透過型顕微鏡を用い、ビデオ撮影し
た画像を処理して算出した。(1) Coverage of Cement Admixture Powder Surface with Silica-based Fine Powder The coverage of the cement admixture powder surface with silica-based fine powder was obtained by video recording an image using an Olympus transmission microscope. Calculated by processing.
【００２６】［評価結果］ 被覆率 ◎：８０％以上 ○：１０％以上８０％未満 ×：１０％未満[Evaluation Results] Coverage A: 80% or more O: 10% or more and less than 80% X: Less than 10%
【００２７】（２） コンクリートスラリー中への溶解
性（溶け残りダマ量） 製造された複合セメント混和剤１００ｇを５０リットル
のコンクリートスラリーに添加し、傾胴式ミキサー（丸
東製作所製）で１分間撹拌し、得られたコンクリートス
ラリーを縦１ｍ、横１ｍ、深さ５ｃｍの型枠に流し込
み、一昼夜後の硬化表面に観察された溶け残り（ダマ）
個数で評価を行なった。使用したコンクリートスラリー
の調合を表１に示す。(2) Solubility in Concrete Slurry (Amount of Undissolved Dama) 100 g of the produced composite cement admixture was added to 50 liters of concrete slurry, and the mixture was mixed for 1 minute with a tilting mixer (Maruto Seisakusho). After stirring, the resulting concrete slurry was poured into a formwork of 1 m in length, 1 m in width, and 5 cm in depth, and the unmelted residue (damage) observed on the cured surface after one day and night.
The number of pieces was evaluated. Table 1 shows the formulation of the concrete slurry used.
【００２８】[0028]
【表１】表１：コンクリートスラリーの調合 水 ：水道水 167 kg/m3 セメント ：小野田セメント(株)製， 比重3.16 320 kg/m3 細骨材 ：川砂 富士川産 FM＝2.30，比重2.65 815 kg/m3 粗骨材 ：砕石 木更津産 FM＝6.80，比重2.60 996.4 kg/m3 粗骨材の最大寸法 20mm ＡＥ減水剤：ポゾリスNo.70 0.35kg/m3 ＡＥ剤 ：ヴィンソル 0.02kg/m3 スランプ ： 15.0cm [Table 1] Table 1: Mixing water of concrete slurry : Tap water 167 kg / m 3 Cement: Onoda Cement Co., Ltd., specific gravity 3.16 320 kg / m 3 Fine aggregate: Kawasago Fujikawa FM = 2.30, specific gravity 2.65 815 kg / m 3 Coarse aggregate: Crushed stone Kisarazu FM = 6.80, specific gravity 2.60 996.4 kg / m 3 Maximum size of coarse aggregate 20mm AE water reducing agent: Pozzolith No.70 0.35kg / m 3 AE agent: Vinsol 0.02kg / m 3 Slump: 15.0cm
【００２９】（３） 流動化性 セメント混和剤粉体として、ポリスチレンスルホン酸カ
ルシウム、ポリスチレンスルホン酸ナトリウム、ポリス
チレンスルホン酸カルシウムとグルコン酸ナトリウムの
配合品(８５：１５)配合品を用い、そのコンクリートス
ラリーにおける流動化性を測定した。(3) Fluidity As a cement admixture powder, a concrete slurry of calcium polystyrene sulfonate, sodium polystyrene sulfonate, a mixture of calcium polystyrene sulfonate and sodium gluconate (85:15) was used. Was measured for fluidity.
【００３０】ベースコクリートスラリーは、日本建築学
会建築工事標準仕様書に準拠して製造し、スランプは８
ｃｍになるように調合した。その調合を表２に示す。そ
れらに、複合セメント混合剤中のセメント混和剤粉体が
５０ｇとなるように添加し、ベースコンクリートスラリ
ー製造と同じ条件で６０秒撹拌して、そのときのスラン
プを測定した。The base cocrete slurry is manufactured in conformity with the building construction standard specifications of the Japan Institute of Architecture, and the slump is 8
Prepared to be cm. The formulation is shown in Table 2. The cement admixture powder in the composite cement admixture was added to them so as to be 50 g, and the mixture was stirred for 60 seconds under the same conditions as in the production of the base concrete slurry, and the slump at that time was measured.
【００３１】[0031]
【表２】表２：コンクリートスラリーの調合 水 ：水道水 163 kg/m3 セメント ：普通ポルトランドセメント 日本セメント(株)製， 比重3.16 320 kg/m3 細骨材 ：鹿島産 FM＝2.64， 比重2.63 836 kg/m3 粗骨材 ：青梅産 FM＝6.68， 比重2.64 930 kg/m3 粗骨材の最大寸法 20mm ＡＥ剤 ：ヴィンソル 0.064kg/m3 [Table 2] Table 2: Mixing water of concrete slurry : Tap water 163 kg / m 3 Cement: Ordinary Portland Cement, manufactured by Nippon Cement Co., Ltd., specific gravity 3.16 320 kg / m 3 Fine aggregate: Kashima FM = 2.64, specific gravity 2.63 836 kg / m 3 Coarse aggregate: Ome FM = 6.68, specific gravity 2.64 930 kg / m 3 Maximum size of coarse aggregate 20mm AE agent: Vinsol 0.064kg / m 3
【００３２】[0032]
【表３】 複合セメント混和剤 セメント混和剤粉体(A) シリカ系微粉体(B) 平均 平均 粒径 粒径 組成 名 称 (μm) 名 称 (μm) (Ａ：Ｂ) 実施例１ ＰＳＳ・Ｃａ 90 シリカフューム 1.4 70：30 実施例２ ＰＳＳ・Ｃａ 90 ホワイトカーボン 0.2 90：10 実施例３ ＰＳＳ・Ｃａ 50 シリカフューム 1.4 70：30 実施例４ ＰＳＳ・Ｎａ 90 シリカフューム 1.4 75：25 実施例５ ＰＳＳ・Ｎａ 90 シリカフューム 1.4 50：50 実施例６ ＰＳＳ・Ca＋ＧＡ・Na 90 シリカフューム 1.4 75：25 実施例７ ＰＳＳ・Ca＋ＧＡ・Na 90 ホワイトカーボン 0.2 90：10 比較例１ ＰＳＳ・Ｃａ 90 無添加 − 100：0 比較例２ ＰＳＳ・Ca＋ＧＡ・Na 90 無添加 − 100：0 ＰＳＳ・Ｃａ：ポリスチレンスルホン酸カルシウム ＰＳＳ・Ｎａ：ポリスチレンスルホン酸ナトリウム ＰＳＳ・Na＋ＧＡ・Na：ポリスチレンスルホン酸カルシウ
ム：グルコン酸ナトリウム＝８５：１５の配合品 シリカヒューム：日本重化学（株）製（ポゾミックス
Ｐ） ホワイトカーボン：徳山曹達（株）製（トクシール）[Table 3] Composite cement admixture Cement admixture powder (A) Silica-based fine powder (B) Average Average particle size Particle size CompositionName (μm) Name (μm) (A: B) Example 1 PSS / Ca 90 silica fume 1.4 70:30 Example 2 PSS / Ca 90 white carbon 0.2 90:10 Example 3 PSS / Ca 50 silica fume 1.4 70:30 Example 4 PSS / Na 90 silica fume 1.4 75:25 Example 5 PSS / Na 90 silica fume 1.4 50:50 Example 6 PSS / Ca + GA / Na 90 silica fume 1.4 75:25 Example 7 PSS / Ca + GA / Na 90 white carbon 0.2 90:10 Comparative example 1 PSS / Ca 90 no addition − 100: 0 Comparative Example 2 PSS / Ca + GA / Na 90 No Addition-100: 0 PSS / Ca: Calcium polystyrene sulfonate PSS / Na: Sodium polystyrene sulfonate PSS / Na + GA / Na: Calcium polystyrene sulfonate
Mu: Sodium gluconate = 85:15 blended silica fume: Nippon Heavy Chemical Co., Ltd. (Pozomix
P) White carbon: Tokuyama Soda Co., Ltd. (Tokushiru)
【００３３】[0033]
【表４】 被覆状態 コンクリート表面の 流動化性 溶け残りダマ量(個) (スランプ：cm) 実施例１ ◎ 0 18.5 実施例２ ○ 2 18.0 実施例３ ◎ 0 18.5 実施例４ ◎ 0 18.0 実施例５ ◎ 0 17.0 実施例６ ◎ 0 18.5 実施例７ ○ 1 17.0 比較例１ − 12 15.0 比較例２ − 10 15.5 [Table 4] Covered condition Fluidity of concrete surface Unmelted lump amount (pieces) (slump: cm) Example 1 ◎ 0 18.5 Example 2 ○ 2 18.0 Example 3 ◎ 0 18.5 Example 4 ◎ 0 18.0 Example 5 ◎ 0 17.0 Example 6 ◎ 0 18.5 Example 7 ○ 1 17.0 Comparative Example 1-12 15.0 Comparative Example 2-10 15.5
───────────────────────────────────────────────────── フロントページの続き (72)発明者 長瀬 公一 東京都新宿区西新宿１−25−１ 大成建設 株式会社内 ─────────────────────────────────────────────────── ─── Continuation of the front page (72) Inventor Koichi Nagase 1-25-1 Nishishinjuku, Shinjuku-ku, Tokyo Taisei Corporation
Claims (2)
系微粉体で被覆したことを特徴とする複合セメント混和
剤。1. A composite cement admixture characterized in that a water-soluble cement admixture powder is coated with silica fine powder.
〜５ｍｍ、シリカ系微粉体の平均粒径が０．０１μｍ〜
１００μｍであり、セメント混和剤粉体とシリカ系微粉
体の重量比が９９：１〜５０：５０の範囲にある請求項
１に記載の複合セメント混和剤。2. The average particle diameter of the cement admixture powder is 1 μm.
~ 5 mm, the average particle size of the fine silica powder is 0.01 μm ~
The composite cement admixture according to claim 1, wherein the composite admixture for cement is 100 μm, and the weight ratio of the cement admixture powder and the fine silica powder is in the range of 99: 1 to 50:50.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4131977A JP2563035B2 (en) | 1992-04-24 | 1992-04-24 | Composite cement admixture |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4131977A JP2563035B2 (en) | 1992-04-24 | 1992-04-24 | Composite cement admixture |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH05301751A true JPH05301751A (en) | 1993-11-16 |
| JP2563035B2 JP2563035B2 (en) | 1996-12-11 |
Family
ID=15070659
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP4131977A Expired - Lifetime JP2563035B2 (en) | 1992-04-24 | 1992-04-24 | Composite cement admixture |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2563035B2 (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH06239652A (en) * | 1993-02-15 | 1994-08-30 | Denki Kagaku Kogyo Kk | Powdery cement dispersant and its production |
| JP2006232651A (en) * | 2005-02-22 | 2006-09-07 | Matsumoto Yushi Seiyaku Co Ltd | Admixture for extrusion molding of cement and extrusion molded cement product |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20080139701A1 (en) | 2004-12-02 | 2008-06-12 | Sika Ltd | Powdered Polycarboxylic Acid-Based Cement Dispersant and Dispersant Composition Containing the Dispersant |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS632845A (en) * | 1986-06-19 | 1988-01-07 | 日本重化学工業株式会社 | Concrete admixing agent and manufacture |
| JPS63123844A (en) * | 1986-11-11 | 1988-05-27 | 大阪瓦斯株式会社 | Dry-state carbon short fiber raw material treated with aggregation prevention and manufacture |
| JPH0360450A (en) * | 1989-07-20 | 1991-03-15 | Sandoz Ag | Dried mixture for epoxy cement concrete |
-
1992
- 1992-04-24 JP JP4131977A patent/JP2563035B2/en not_active Expired - Lifetime
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS632845A (en) * | 1986-06-19 | 1988-01-07 | 日本重化学工業株式会社 | Concrete admixing agent and manufacture |
| JPS63123844A (en) * | 1986-11-11 | 1988-05-27 | 大阪瓦斯株式会社 | Dry-state carbon short fiber raw material treated with aggregation prevention and manufacture |
| JPH0360450A (en) * | 1989-07-20 | 1991-03-15 | Sandoz Ag | Dried mixture for epoxy cement concrete |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH06239652A (en) * | 1993-02-15 | 1994-08-30 | Denki Kagaku Kogyo Kk | Powdery cement dispersant and its production |
| JP2006232651A (en) * | 2005-02-22 | 2006-09-07 | Matsumoto Yushi Seiyaku Co Ltd | Admixture for extrusion molding of cement and extrusion molded cement product |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2563035B2 (en) | 1996-12-11 |
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