JPH05295044A - Graft polymer-containing resin composition - Google Patents

Abstract

PURPOSE:To obtain the subject composition useful for molded articles, etc., having excellent surface peeling resistance, flowability and heat resistance by polymerizing a specific monomer in the presence of an olefinic polymer suspended in water and a specific polymerization initiator in a specific ratio under a specific condition. CONSTITUTION:(A) 100 pts.wt. olefinic polymer suspended in a finely granulated state in water, (B) 5-200 pts.wt. monomer comprising 70-100wt.% alkyl (meth) acrylate and 0-30wt.% copolymerizable compound and 0.01-5 pts.wt. based on 100 pts. wt. component B of a radical polymerization initiator (e.g. cyclohexanone peroxide) having a decomposition temperature of 10 hours-half-life of 80-200 deg.C are heated under a condition not substantially causing the decomposition of the radical polymerization initiator and not starting the polymerization of the component B to impregnate the component B into the component A >=70wt.%, and the temperature of the suspension is raised and the components are polymerized to give the objective composition.

Description

Detailed Description of the Invention

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a graft polymer-containing resin composition and a thermoplastic resin composition containing the same, in which peeling of a resin molded product from the surface layer does not occur even under high shear.

[0002]

2. Description of the Related Art Recently, a method of alloying polymers having different properties to modify a resin has been actively studied. For example, an alloy of a polyolefin and a styrene resin or a vinyl chloride resin is alloyed with an ethylene-vinyl acetate copolymer (JP-A-60-3).
6178), a method of alloying with a polyethylene-EPDM modified product (JP-A-63-304039, JP-A-1-165640).
Japanese Patent Laid-Open Publication No. 2-199127, a method of alloying with a block of polypropylene and styrene resin.
No. 2-199128 and No. 2-199129), a method of alloying with a modified polypropylene obtained by impregnating and polymerizing a monomer in polypropylene (Japanese Patent Laid-Open No. 52-89155) and the like have been reported.

[0003]

Among these methods,
The method described in JP-A-52-89155 is useful, but there is a problem that the compatibility between the polymers is insufficient and the surface layer peeling of the resin molded product occurs under high shear such as injection molding.

[0004]

In order to solve the above-mentioned problems, the inventors of the present invention have conducted extensive studies and as a result, in the above-mentioned conventional technique, the impregnation speed of the monomer into the polymer is slow, so that the polymer is converted into the polymer. The monomer is polymerized before the impregnation of, and the idea that the effect as a compatibilizing agent becomes low as a result of a decrease in the graft ratio is reached.
In a thermoplastic resin composition consisting of a styrene resin and / or a vinyl chloride resin and an olefin resin, an olefin polymer suspended in fine particles as a compatibilizer,
Surprisingly no peeling of the surface of the injection-molded product occurs when the graft polymer-containing resin composition in which the alkyl (meth) acrylate is rapidly impregnated under heating and polymerized with a specific radical polymerization initiator is used. This has led to the completion of the present invention.

That is, according to the present invention, 100 parts by weight of an olefin polymer (a) suspended in water in a particulate form (part by weight, hereinafter the same), 70 to 100% by weight of alkyl (meth) acrylate (% by weight, the same hereinafter) And compounds 0 to 30 copolymerizable therewith
% Of the monomer (b) consisting of 5 to 200 parts and 0.01 to 5 parts of the monomer (b) to 100 parts, the radical polymerization initiation with a decomposition temperature of 80 to 200 ° C., which results in a half-life of 10 hours. The agent is heated under conditions such that the radical polymerization initiator does not substantially decompose and the monomer (b) does not initiate polymerization, and the olefin polymer
Graft polymer-containing resin composition obtained by impregnating 70% or more of monomer (b) in (a) and then polymerizing by raising the temperature of the suspension, and thermoplastic resin other than olefin resin 0.5 to 200 parts of the graft polymer-containing resin composition (D) according to claim 1 to 100 parts of a resin mixture (C) of 5 to 95% of (A) and 5 to 95% of an olefin resin (B). The present invention relates to a thermoplastic resin composition blended.

[0006]

EXAMPLES Olefinic polymer (a) used in the present invention
Is a component used as a processing method such as injection molding, sheet molding, film molding, etc. for home appliances, OA equipment housing materials, automobile interior materials, precision electrical component materials, etc. Impregnated with a monomer (b) consisting of a compound copolymerizable with
Used as a polymerized product.

The olefin polymer is a polymer having a proportion of units derived from an olefin monomer such as ethylene, propylene, butene, pentene, hexene and heptene of 80% or more, preferably 90% or more, Examples of the monomer other than the olefin-based monomer include methyl (meth) acrylate, ethyl (meth) acrylate, and glycidyl (meth) acrylate-based alkyl (meth) acrylate.

Specific examples of the olefin polymer (a) include polypropylene, a copolymer of propylene and α-olefin, ethylene-propylene rubber, propylene-butene copolymer, and maleic anhydride-modified polypropylene. Among these, ethylene and / or polypropylene polymers or copolymers are particularly preferable.

The polymerization form of the olefin polymer (a) is not particularly limited and may be, for example, a crystalline polymer, a block polymer or a random polymer, and these polymers are mixed and used. You may. In addition, unless the required properties such as peeling resistance and heat distortion resistance are impaired,
Other polymers may be mixed and used.

Regarding the particle size of the olefin polymer (a), etc., usually, the olefin polymer (a) is suspended in water,
In order to impregnate and polymerize the monomer (b), fine particles,
Specifically, the particle size is 0.5 to 100 μm, preferably 1 to 50 μm.
It is preferable that m is in the form of fine particles from the viewpoint that the content of the graft polymer is increased and the effect of improving the peel resistance of the molded article is increased.

The molecular weight of the olefin-based polymer (a) is not particularly limited, but it is usually about 10 to 8,000,000, preferably about 10 to 500,000.

Specific examples of the alkyl (meth) acrylate include those having 1 to 8 carbon atoms such as methyl (meth) acrylate, ethyl (meth) acrylate, butyl (meth) acrylate and 2-ethylhexyl (meth) acrylate. Alkyl (meth) acrylates, and functional group-containing alkyl (meth) acrylates having 1 to 8 carbon atoms such as glycidyl (meth) acrylate and 2-hydroxy (meth) acrylate can be mentioned. Methyl (meth) acrylate, ethyl (meth) acrylate and the like are preferable from the viewpoint of not reducing the deformability.

A compound copolymerizable with an alkyl (meth) acrylate, which is obtained by impregnating and polymerizing the olefin polymer (a) with an alkyl (meth) acrylate, is used for improving heat distortion resistance and melt viscosity. It is a component.

The above-mentioned alkyl (meth) acrylates may be used alone or in combination of two or more kinds, and a compound polymerizable with them may be added in the range of less than 30%.

Specific examples of the copolymerizable compound include aromatic vinyl compounds such as styrene, p-methylstyrene, α-methylstyrene, chlorostyrene and β-isopropenylnaphthalene, acrylonitrile,
Vinyl cyanide compounds such as methacrylonitrile, N-
N- such as phenylmaleimide and N-butylmaleimide
Examples thereof include substituted maleimide compounds.

The proportion of alkyl (meth) acrylate in the monomer (b) is 70 to 100%, preferably 80 to 100%.
If the amount of the alkyl (meth) acrylate is less than 70%, peeling resistance is deteriorated, which is not preferable.

The monomer (b) is an olefin polymer
(a) 5 to 200 parts, preferably 10 to 150 parts are used per 100 parts. If the proportion of the olefin-based polymer (a) is outside this range, the peel resistance will be reduced.

To obtain the composition of the present invention, the olefin polymer (a) is impregnated with the monomer (b) and polymerized.
At that time, it is preferable from the viewpoint of peeling resistance that the olefin polymer (a) is impregnated with the monomer (b) in an amount of 70% or more, preferably 85% or more and polymerized.

Olefin-based polymer (a) of the monomer (b)
The impregnation is carried out by heating to a temperature at which the polymerization initiator used for polymerizing the monomer (b) is not substantially decomposed and the polymerization does not start.

As the above-mentioned polymerization initiator, one having a decomposition temperature of 80 to 200 ° C. for obtaining a half-life of 10 hours, preferably one in the range of 90 to 180 ° C. is preferably used. Among them, the olefin polymer (a) is about 100 μm
In the case of the following fine particles, those in the range of 90 to 180 ° C. and in the case of larger particles or pellets mentioned above, the range of 140 to 200 ° C. is particularly preferable. If the decomposition temperature is lower than 80 ° C, the graft ratio will decrease due to homopolymerization of the monomer during impregnation, and if it exceeds 200 ° C, the radical generation amount will be small and the graft ratio will decrease. Also, the peel resistance is lowered.

Examples of such a polymerization initiator include cyclohexanone peroxide (97 ° C. (decomposition temperature for obtaining a half-life of 10 hours, the same applies hereinafter)), 2,5-dimethyl-2,5-di- Benzoyl peroxyhexane (100
C), t-butyl peroxybenzoate (104 C),
Di-t-butyldiperoxyphthalate (105 ° C), methyl ethyl ketone peroxide (109 ° C), dicumyl peroxide (117 ° C), di-t-butylperoxide (124 ° C), 1,1,3,3 -Tetramethylbutyl hydroperoxide (153 ° C), 2,5-dimethylhexane-2,5-dihydroperoxide (154 ° C),
Cumene hydroperoxide (158 ° C.), t-butyl hydroperoxide (167 ° C.) and the like can be mentioned.
Two or more kinds of these polymerization initiators may be used in combination.

The above-mentioned polymerization initiator is 0. 0 per 100 parts of the monomer (b).
01 to 5 parts, preferably 0.05 to 3 parts are used. If the amount used is less than the above range, the peeling resistance will decrease, and if it exceeds the above range, the mechanical strength will decrease significantly.

Polymerization after the olefin polymer is impregnated with the monomer (b) is carried out by raising the temperature of the suspension.

The suspension is basically the same as the suspension used in the aqueous suspension polymerization of vinyl monomers, and the olefin polymer (a) particles and preferably a polymerization initiator are previously dissolved. The obtained monomer (b) and a suspending agent that can be used in aqueous suspension polymerization, such as methylcellulose, polyvinyl alcohol, polyvinylpyrrolidone, alkylbenzene sulfonate, or a sparingly soluble inorganic substance such as calcium phosphate or magnesium oxide. In the presence, it is stirred and dispersed in an aqueous medium.

The concentrations of the olefin polymer (a) and the monomer (b) in the aqueous suspension are not particularly limited as long as the suspension system is uniformly stirred, but generally, with respect to 100 parts of water. The total amount of olefin polymer (a) and monomer (b) is 10 to 10
A range of 0 copy is adopted.

The aqueous suspension is heated under the condition that the polymerization initiator used is not decomposed to impregnate the particles of the olefin polymer (a) with the monomer (b). The conditions of impregnation are preferably in the range of 70 to 120 ° C., which is about 10 to 20 ° C. lower than the decomposition temperature of the polymerization initiator, in view of the balance between promotion of impregnation and avoidance of homopolymerization of the monomer (b), and Is carried out by stirring for 1 to 5 hours, particularly preferably 1 to 3 hours.

Impregnation is carried out by stirring the suspension until 70% or more, preferably 85% or more of the monomer (b) is impregnated or attached to the particles of the olefin polymer (a).

After the impregnation step, the temperature of the suspension is further raised with stirring to polymerize the impregnated vinyl monomer.
The polymerization temperature is a temperature at which decomposition of the polymerization initiator to be used efficiently occurs, generally 90 to 200 ° C, and particularly preferably 110 to 180 ° C. Further, if the polymer itself is thermally decomposed, the physical properties are impaired, so that the temperature is preferably 180 ° C. or lower.

The temperature during the polymerization is not necessarily constant, and may be changed in two stages or more depending on the stable state of the suspension, the polymerization state of the monomer (b), and the formation state of the graft polymer. Good. The polymerization time is usually 3 to 10 hours and 3 to 8
Time is preferred.

After the completion of polymerization, olefin polymer particles
Since the shape of (a) is maintained almost as it is, it is possible to obtain the graft polymer-containing resin composition in the form of particles by cooling and then treating in the same manner as an ordinary suspension.

The graft polymer resin composition thus obtained is mixed with other resins such as a styrene resin and a vinyl chloride resin, and the graft polymer resin composition is processed by injection molding, film molding, sheet molding or the like. The method can be used for automobile interior materials, home appliances, OA equipment housing materials and the like.

When used as the above-mentioned improving agent, modifying agent, and compatibilizing agent for polymer alloys, the graft polymer-containing resin composition of the present invention is a rubber-like EPR or EPD.
Since it is not an impact modifier such as M but a compatibilizer, it is not necessary to maintain a constant particle size in the formulation, and it is preferable that it is in a dispersed state like a surfactant.

Next, the use of the graft polymer-containing resin composition of the present invention as a compatibilizer will be described.

The graft polymer-containing resin composition (D) of the present invention comprises a thermoplastic resin (A) 5 other than an olefin resin.
0.1% per 100 parts of resin mixture (C) in a thermoplastic resin mixture (C) consisting of ˜95% and olefinic resin (B) 95-5%.
By blending 5 to 200 parts, preferably 5 to 50 parts,
It is possible to obtain a thermoplastic resin composition having excellent peel resistance, fluidity, and heat distortion resistance.

Thermoplastic resin other than the olefin resin
(A) is a resin that is more excellent in thermal deformation resistance under high load than olefin resins.

Thermoplastic resin other than the olefin resin
Specific examples of (A) include styrene resins, vinyl chloride resins, polyester resins, polycarbonate resins, polyamide resins, polyphenylene oxide resins, and the like. Of these, styrene-based resins and vinyl chloride-based resins are particularly preferable in terms of economy.

As the styrene resin, 10 to 85% of aromatic vinyl compound, 15 to 40% of vinyl cyanide compound and N
A styrene-based resin obtained by copolymerizing 0 to 50% of a substituted maleimide compound and 0 to 20% of another vinyl compound copolymerizable therewith is particularly preferable.

Examples of the aromatic vinyl compound used in the styrene resin include styrene, α-methylstyrene, methylstyrene, chlorostyrene, β-isopropenylnaphthalene and the like.

Examples of the vinyl cyanide compound include acrylonitrile and methacrylonitrile.

Examples of the N-substituted maleimide compound include N-phenylmaleimide, N-methylmaleimide, N-ethylmaleimide, N-propylmaleimide,
N-isopropylmaleimide, N-butylmaleimide,
Examples thereof include N-isobutyl maleimide, N-tert-butyl maleimide, N-cyclohexyl maleimide and the like.

Other vinyl compounds copolymerizable with the above-mentioned monomers include, for example, methyl (meth) acrylate,
Examples thereof include ethyl (meth) acrylate, butyl (meth) acrylate, glycidyl methacrylate, 2-hydroxyethyl methacrylate, 2-ethylhexyl methacrylate and methacrylic acid.

Examples of the vinyl chloride resin include polyvinyl chloride and vinyl chloride copolymers having a vinyl chloride content of 80% or more. Examples of the monomer copolymerized with vinyl chloride include monovinylidene compounds such as ethylene and vinyl acetate.

Thermoplastic resin other than the olefin resin
(A) can be polymerized by a known method, and the kind and operation thereof are not particularly limited. After completion of the polymerization, the target powder can be obtained by a known method.

The olefin resin (B) in the present invention is
Used to improve the fluidity and chemical resistance of the thermoplastic resin (A).

Specific examples of the olefin resin include:
For example, polypropylene, copolymer of propylene and α-olefin, high density polyethylene, medium density polyethylene, low density polyethylene, copolymer of ethylene and α-olefin, polybutene, poly-4-methylpentene-1.
Such as polyolefins or oligomers thereof, ethylene-propylene rubber, ethylene-propylene-diene rubber, ethylene-vinyl acetate copolymer, butyl rubber, butadiene rubber, propylene-buden copolymer, ethylene-acrylic acid ester copolymer, etc. Examples thereof include polyolefin-based elastomers, mixtures of two or more thereof, and / or polymers of the above-mentioned olefins having functional groups such as carboxylic acids, amines, amides, and imides that are reactive with epoxy groups. Among these, polypropylene and a copolymer containing 50% or more of propylene are preferable.

The olefin resin (B) can be polymerized by a known method, and the kind and operation thereof are not particularly limited. After completion of the polymerization, particles having a desired size can be obtained by a known method.

The thermoplastic resin (A) and an olefin resin
Resin mixture (C) with (B) has a weight ratio of (A) / (B) = 5/95
It is preferably ˜95 / 5, and more preferably 15/85 to 85/15. If this ratio is less than 5/95%, the heat resistance of the molded product under high load will be reduced, and if it exceeds 95/5, the fluidity will be significantly reduced.

The thermoplastic resin composition of the present invention is preferably a powdery or pelletized thermoplastic resin (A) other than the above-mentioned olefinic resin, preferably a fine particled or pelletized olefinic resin (B). It can be obtained by blending the graft polymer-containing resin composition (D) of the present invention having a function as a modifier (compatibilizer) and, if necessary, a compounding agent used.

The operation of the blending is not particularly limited, and it is uniformly mixed by a commonly used mixer such as a Henschel mixer or a tumbler.

The above-mentioned optional additives are those used to improve the properties of the thermoplastic resin composition of the present invention, and are generally well known impact modifiers and processability improvers. U, as well as agents, antioxidants, heat stabilizers and lubricants
V-absorbers, pigments, antistatic agents, flame retardants, flame retardant aids, etc. are also included in the compounding agents. You may use these together. In particular, styrene resin, phenolic antioxidant used for olefin resin, phosphite stabilizer, tin stabilizer compounded in vinyl chloride resin, lead stabilizer, various fatty acid ester metal soaps, waxes, etc. The internal and external lubricants of
When the thermoplastic resin composition of the present invention is used for molding, it is used to obtain a higher performance product.

The present invention will be described below based on specific examples, but these examples do not limit the present invention.

Example 1 (b) Production of graft polymer-containing resin composition (D) In a 20 liter polymerization machine equipped with a stirrer, under a nitrogen atmosphere, water was added.
200 parts, sodium alkylbenzene sulfonate 0.1
Parts, calcium phosphate 2 parts, fine-grained propylene-based polymer of Table 1 (Chemipearl manufactured by Mitsui Petrochemical Co., Ltd.) (a-1) 60
Parts, 40 parts of methyl methacrylate, and 0.5 parts of di-t-butyl peroxide were added, and the temperature was raised to 95 ° C. After impregnating at 95 ° C. for 1 hour, the temperature was raised to 130 ° C. and polymerization was carried out for 5 hours.

After the completion of the polymerization, the composition was dehydrated and dried to obtain a graft polymer-containing resin composition (D-1).

Grafting efficiency was measured by solvent fractionation (dissolving the graft polymer-containing composition in hot xylene, adding methyl ethyl ketone and filtering the precipitate).
A homopolymer was separated, and residual MMA was measured by gas chromatography and calculated according to the following formula.

[0055]

[Equation 1]

Grafting efficiency of the obtained (D-1) was measured. The measurement results are shown in Table 2.

(B) Production of thermoplastic resin 40 parts of ABS resin (A-1) shown in Table 3, 60 parts of propylene polymer (Hipol J-600 manufactured by Mitsui Petrochemical Co., Ltd.), resin composition containing graft polymer 10 parts of (D-1) was blended with a super mixer, and pellets were produced with a 44 m / m twin-screw extruder.

A test piece was molded from the pellets using a 5 ounce injection molding machine under the conditions of a screw rotation speed of 80 rpm and a nozzle set temperature of 230 ° C.

The test pieces of the obtained molded product were tested for surface layer peeling resistance, heat resistance and fluidity resistance. The results are shown in Table 5.
Shown in.

The surface layer releasability of the molded product was evaluated by using the above-mentioned molding machine, and the releasability from the gate portion of a flat plate molded product having a thickness of 2.5 mm was evaluated. Evaluation is made by the visual 5-point method, and the maximum is 5 points.
The lowest was 1 point. That is, the evaluation shows that the larger the number, the better the surface layer peeling resistance.

The heat resistance is 18.6 based on the ASTM (D-256) standard.
The heat distortion temperature under a load of kg / cm ² was evaluated.

The fluidity was 3 mm in thickness using the above molding machine.
The evaluation was made by the flow distance in a mosquito coiled mold having a width of 10 mm.

[0063]

[Table 1]

[0064]

[Table 2]

[0065]

[Table 3]

[0066]

[Table 4]

[0067]

[Table 5]

Examples 2 to 4 Comparative Examples 1 and 2 Using the materials shown in Tables 1 to 4, thermoplastic resin compositions having the compositions shown in Table 5 and test pieces thereof were prepared in the same manner as in Example 1 (b). It was made by the method.

Example 5 40 parts of a vinyl chloride resin (A-4) in Table 4, 60 parts of a propylene polymer (Hipol J-600 manufactured by Mitsui Petrochemical Co., Ltd.), a resin composition containing a graft polymer (D-1) ) 10 parts, 2 parts of dibutyl tin malate as a stabilizer and 1 part of polyethylene wax as a lubricant were blended with a super mixer, and pellets were produced with a 44 m / m twin-screw extruder.

A test piece was molded from the pellet with a 5-ounce injection molding machine under the conditions of a screw rotation speed of 80 rpm and a nozzle set temperature of 170 ° C.

Example 6, Comparative Examples 3 and 4 Using the materials shown in Tables 1 to 4, thermoplastic resin compositions having the compositions shown in Table 5 and test pieces thereof were prepared in the same manner as in Example 5. .

Comparative Example 5 Using the materials shown in Tables 1 to 4, a thermoplastic resin composition having the composition shown in Table 5 and a test piece thereof were prepared in the same manner as in Example 1.

Example 7 (a) Production of Graft Polymer-Containing Resin Composition (D) The fine-grained propylene-based polymer used in Example 1 was used as Hipol J900 manufactured by Mitsui Petrochemical Co., Ltd. (a-2 in Table 1). Then, impregnation was carried out in the same manner as in Example 1 except that the polymerization initiator was changed to cumene hydroperoxide, and then the temperature was raised to 140 ° C. and the polymerization was carried out for 5 hours.

After the polymerization was completed, the composition was dehydrated and dried to obtain a graft polymer-containing resin composition (D-4).

(B) Production of thermoplastic resin Pellets were obtained and test pieces were molded in the same manner as in Example 1 except that D-1 in Example 1 was changed to D-4.

Examples 8 to 11 and Comparative Examples 6 to 7 Using the materials having the compositions shown in Tables 1 to 4, the thermoplastic resin compositions shown in Table 5 and their test pieces were prepared in the same manner as in Example 7. It was made.

Example 12 40 parts of polyvinyl chloride (A-3) shown in Table 4, 60 parts of polypropylene resin (Hipol J-900 manufactured by Mitsui Petrochemical Co., Ltd.), and graft polymer-containing composition (D-4) 10 Parts, 2 parts of dibutyl tin malate as a stabilizer and 1 part of polyethylene wax as a lubricant were blended with a super mixer, and pellets were produced with a 44 m / m twin-screw extruder.

From the pellets on a 5 ounce injection molding machine,
A test piece was molded under the conditions of a screw rotation speed of 80 rpm and a nozzle set temperature of 170 ° C.

Examples 13 and 14, Comparative Examples 8 and 9 Using the materials shown in Tables 1 to 4, thermoplastic resin compositions having the compositions shown in Table 5 and test pieces thereof were prepared in the same manner as in Example 12. Molded.

From the results shown in Table 5, it can be seen that the thermoplastic resin compositions of the present invention represented by Examples are particularly excellent in surface layer peeling resistance and fluidity, and also have good heat resistance.

[0081]

The thermoplastic resin obtained by blending the graft polymer-containing resin composition of the present invention with a mixture of an olefin resin and a thermoplastic resin other than the olefin resin has a surface layer peeling resistance of a molded article. It also has improved flowability and heat resistance.

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Claims (11)

[Claims] 1. An olefinic polymer (a) 100 parts by weight suspended in water in a particulate form, an alkyl (meth) acrylate.
70 to 100% by weight and compounds 0 to 30 copolymerizable therewith
% Of monomer (b) 5 to 200 parts by weight and monomer
(b) 0.01 to 5 parts by weight relative to 100 parts by weight of a radical polymerization initiator having a decomposition temperature of 80 to 200 ° C., which has a half-life of 10 hours, does not substantially decompose the radical polymerization initiator, In addition, the temperature of the suspension is raised after heating the monomer (b) so that the polymerization does not start and impregnating the olefin polymer (a) with 70% by weight or more of the monomer (b). A resin composition containing a graft polymer obtained by polymerization. 2. The resin composition according to claim 1, wherein the decomposition temperature at which the radical polymerization initiator has a half-life of 10 hours is 140 to 200 ° C. 3. The average particle diameter of the olefin polymer (a) is
The composition according to claim 1, which is 0.5 to 100 µ. 4. The average particle size of the olefin polymer (a) is
The composition according to claim 1, which has a size of 1 to 50 µ. 5. The composition according to claim 1, 2 or 3, wherein the olefin polymer (a) is a polymer or copolymer of ethylene and / or propylene. 6. A thermoplastic resin other than an olefin resin
(A) 5 to 95% by weight and olefin resin (B) 5 to 95% by weight
A thermoplastic resin composition comprising 0.5 to 200 parts by weight of the graft polymer-containing resin composition (D) according to claim 1 based on 100 parts by weight of the resin mixture (C). 7. A thermoplastic resin other than an olefin resin
The thermoplastic resin composition according to claim 5, wherein (A) is a styrene resin and / or a vinyl chloride resin. 8. A thermoplastic resin other than an olefin resin
(A) is an aromatic vinyl compound 10 to 85% by weight, a vinyl cyanide compound 15 to 40% by weight, and an N-substituted maleimide compound 0.
7. The thermoplastic resin composition according to claim 5, which is a styrene resin obtained by copolymerizing 50% by weight and 0 to 20% by weight of another vinyl compound copolymerizable therewith. 9. A thermoplastic resin other than an olefin resin
7. The thermoplastic resin composition according to claim 5, wherein (A) is a vinyl chloride resin containing 80% by weight or more of vinyl chloride or a chlorinated vinyl chloride resin after chlorinating the vinyl chloride resin. 10. A thermoplastic resin other than an olefin resin
(A) is an aromatic vinyl compound 10 to 85% by weight, a vinyl cyanide compound 15 to 40% by weight, and an N-substituted maleimide compound 0.
To 50% by weight and 5 to 95 parts by weight of a styrene resin copolymerized with 0 to 20% by weight of another vinyl compound copolymerizable therewith, and a vinyl chloride resin comprising 80% by weight or more of vinyl chloride, or The thermoplastic resin composition according to claim 5 or 6, which is a resin mixture with 5 to 95 parts by weight of a chlorinated vinyl chloride resin after being chlorinated. 11. The thermoplastic resin composition according to claim 5, wherein the olefin resin (B) is a resin obtained by polymerizing a monomer having a propylene content of 50% by weight or more.