JPH0528089B2 - - Google Patents
Info
- Publication number
- JPH0528089B2 JPH0528089B2 JP60215274A JP21527485A JPH0528089B2 JP H0528089 B2 JPH0528089 B2 JP H0528089B2 JP 60215274 A JP60215274 A JP 60215274A JP 21527485 A JP21527485 A JP 21527485A JP H0528089 B2 JPH0528089 B2 JP H0528089B2
- Authority
- JP
- Japan
- Prior art keywords
- aluminum
- film
- chloropicrin
- absorbent
- plastic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 28
- 229910052782 aluminium Inorganic materials 0.000 claims description 26
- LFHISGNCFUNFFM-UHFFFAOYSA-N chloropicrin Chemical compound [O-][N+](=O)C(Cl)(Cl)Cl LFHISGNCFUNFFM-UHFFFAOYSA-N 0.000 claims description 20
- 230000002745 absorbent Effects 0.000 claims description 17
- 239000002250 absorbent Substances 0.000 claims description 17
- 239000004033 plastic Substances 0.000 claims description 11
- 229920003023 plastic Polymers 0.000 claims description 11
- -1 hydrotalcite compound Chemical class 0.000 claims description 7
- 229960001545 hydrotalcite Drugs 0.000 claims description 6
- 229910001701 hydrotalcite Inorganic materials 0.000 claims description 6
- 238000004898 kneading Methods 0.000 claims description 5
- 239000002689 soil Substances 0.000 description 7
- 239000002985 plastic film Substances 0.000 description 6
- 229920006255 plastic film Polymers 0.000 description 6
- 238000010586 diagram Methods 0.000 description 3
- GDVKFRBCXAPAQJ-UHFFFAOYSA-A dialuminum;hexamagnesium;carbonate;hexadecahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Al+3].[Al+3].[O-]C([O-])=O GDVKFRBCXAPAQJ-UHFFFAOYSA-A 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 229910018626 Al(OH) Inorganic materials 0.000 description 2
- 238000010030 laminating Methods 0.000 description 2
- 239000004611 light stabiliser Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- SWZOQAGVRGQLDV-UHFFFAOYSA-N 4-[2-(4-hydroxy-2,2,6,6-tetramethylpiperidin-1-yl)ethoxy]-4-oxobutanoic acid Chemical compound CC1(C)CC(O)CC(C)(C)N1CCOC(=O)CCC(O)=O SWZOQAGVRGQLDV-UHFFFAOYSA-N 0.000 description 1
- 241001124076 Aphididae Species 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- OWYWGLHRNBIFJP-UHFFFAOYSA-N Ipazine Chemical compound CCN(CC)C1=NC(Cl)=NC(NC(C)C)=N1 OWYWGLHRNBIFJP-UHFFFAOYSA-N 0.000 description 1
- 229910019440 Mg(OH) Inorganic materials 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 241000607479 Yersinia pestis Species 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 230000000593 degrading effect Effects 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 238000003958 fumigation Methods 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 150000003839 salts Chemical group 0.000 description 1
Landscapes
- Protection Of Plants (AREA)
- Catching Or Destruction (AREA)
- Laminated Bodies (AREA)
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は光反射剤としてアルミニウムを含有す
るアルミニウムマルチフイルムに関するもので、
地上に敷いてその地温上昇を抑制したり、アブラ
ムシの飛来防止等に用いるものである。[Detailed Description of the Invention] [Industrial Application Field] The present invention relates to an aluminum multi-film containing aluminum as a light reflecting agent.
It is used to suppress the rise in soil temperature by laying it on the ground, and to prevent aphids from flying in.
上記アルミニウムマルチフイルムとしてはポリ
エチレン、ポリプロピレン、ポリ塩化ビニル等の
プラスチツク中にアルミニウム粉、箔片等を練り
込むか、プラスチツクフイルム表面にアルミニウ
ムの膜を塗布、蒸着またはアルミ箔膜を貼合して
いた。一方、畑の土中の菌、害虫を消毒するた
め、クロルピクリン（CCl3NO2）１０を土１１
中に注入くん蒸することが行われているが、これ
を土中に注入した後はその気体を地中に保持する
ため第４図示のように10日位プラスチツクフイル
ム１２をかけ、充分に消毒した後フイルムをはが
してマルチフイルムを再びかけていた。しかしこ
のフイルムのかけ直し作業は面倒であるので、ク
ロルピクリン注入後直ちにアルミニウムマルチフ
イルムをかぶせている。
The above-mentioned aluminum multi-film is made by kneading aluminum powder, foil pieces, etc. into plastic such as polyethylene, polypropylene, or polyvinyl chloride, or by coating, vapor-depositing, or laminating an aluminum film on the surface of the plastic film. . On the other hand, in order to disinfect bacteria and pests in the soil of the field, 10 parts of chloropicrin (CCl 3 NO 2 ) was added to 11 parts of the soil.
Fumigation is carried out by injecting the gas into the soil, and after injecting this into the soil, in order to retain the gas underground, a plastic film 12 is covered for about 10 days as shown in Figure 4 to thoroughly disinfect the soil. I peeled off the rear film and reapplied the multi-film. However, since it is troublesome to reapply the film, an aluminum multi-film is placed immediately after the injection of chloropicrin.
しかし上記クロルピクリンのガスは塩素系のガ
スであるためそれがアルミニウムと反応して
AlCl3となり、更にこれがAl（OH）3と変化すると
考えられるが、このAl（OH）3は屈折率がプラス
チツクとほぼ同じであるのでプラスチツクフイル
ム中のアルミニウムの反射力が消えたり或いはフ
イルム表面のアルミニウムが変質して剥離、散逸
する欠点があつた。
However, since the chloropicrin gas mentioned above is a chlorine-based gas, it reacts with aluminum.
It is thought that this becomes AlCl 3 and then changes to Al(OH) 3 , but since this Al(OH) 3 has almost the same refractive index as plastic, the reflective power of the aluminum in the plastic film may disappear or the film surface may The problem was that the aluminum deteriorated, peeled off, and dissipated.
本発明はかかる欠点を除去するためプラスチツ
クとアルミニウムとよりなるアルミニウムマルチ
フイルムにおいて更にクロルピクリンの吸収剤を
加えたものである。
In order to eliminate such drawbacks, the present invention provides an aluminum multi-film made of plastic and aluminum to which an absorbent of chloropicrin is further added.
上記クロルピクリンの吸収剤はハイドロタルサ
イト類（Mg6R2（OH）16CO34H2O（Ｒ＝Al、Cr、
Fe））或いはその合成物（例えばMg4.5Al2
（OH）13CO33.5H2O）又はステアリン酸Ca、Ca
（OH）2、CaCO3、K2CO3、MgCO3、Mg（OH）2
等である。 The absorbent for the above chloropicrin is hydrotalcites (Mg 6 R 2 (OH) 16 CO 3 4H 2 O (R=Al, Cr,
Fe)) or its composites (e.g. Mg 4.5 Al 2
(OH) 13 CO 3 3.5H 2 O) or Ca stearate, Ca
(OH) 2 , CaCO 3 , K 2 CO 3 , MgCO 3 , Mg(OH) 2
etc.
上記クロルピクリン吸収剤はAl粉等を練り込
んだフイルムに対してはプラスチツクとアルミニ
ウムとに同時に混練して使用する。又、Al塗布
あるいは蒸着フイルム等にあつては、プラスチツ
クに吸収剤を混練したフイルムを基材として使用
する。或いは又、プラスチツクとAlよりなるフ
イルムの内面（地表面側）に濃縮した状態で吸収
剤を塗布又は高濃度に混練したプラスチツクをラ
ミネートする方法で用いることが出来る。 The above-mentioned chloropicrin absorbent is used by kneading it with plastic and aluminum at the same time for a film mixed with Al powder or the like. In the case of Al-coated or vapor-deposited films, a film prepared by kneading an absorbent into plastic is used as the base material. Alternatively, the absorbent can be applied in a concentrated state to the inner surface (ground surface side) of a film made of plastic and Al, or the absorbent can be laminated with highly concentrated plastic kneaded.
上記クロルピクリンの吸収剤がクロルピクリン
と反応するのでアルミニウムは保護されるもので
ある。
The aluminum is protected because the chloropicrin absorbent reacts with the chloropicrin.
第１図乃至第３図は本発明の夫々異なつた３つ
の実施例の説明図である。
1 to 3 are explanatory diagrams of three different embodiments of the present invention.
第１図示のフイルム１ａはそのプラスチツク素
材中にアルミニウム粉末２とハイドロタルサイト
３を２％混練したものである。 The film 1a shown in the first figure is made by kneading 2% of aluminum powder 2 and hydrotalcite 3 into the plastic material.
第２図示のフイルム１ｂはアルミニウムを混練
したプラスチツクフイルム４の下面にクロルピク
リン吸収剤の層５を塗布したものである。このク
ロルピクリン吸収剤は前記したアルミニウムより
反応性の強い金属の塩及びハイドロタルサイト類
化合物等である。 The film 1b shown in the second figure is a plastic film 4 kneaded with aluminum and coated with a layer 5 of chloropicrin absorbent on the lower surface thereof. This chloropicrin absorbent is a salt of a metal more reactive than the above-mentioned aluminum, a hydrotalcite compound, or the like.
第３図示のフイルム１ｃは上記アルミニウムを
有するプラスチツクフイルム６の下面すなわち土
に接する側にハイドロタルサイトを有するプラス
チツクフイルム７をラミネートしたものである。 The film 1c shown in FIG. 3 is obtained by laminating a plastic film 7 containing hydrotalcite on the lower surface of the plastic film 6 containing aluminum, that is, the side that contacts the soil.
上記クロルピクリン吸収剤３としてハイドロタ
ルサイト類化合物を用いた場合、その量は0.1
ｇ／m2〜2.0ｇ／m2好ましくは0.2ｇ／m2〜1.0ｇ／
m2であり他のクロルピクリン吸収剤に比較して優
れた効果を示した。 When a hydrotalcite compound is used as the chloropicrin absorbent 3, the amount is 0.1
g/ m2 ~ 2.0g/ m2 preferably 0.2g/ m2 ~ 1.0g/
m 2 and showed superior effects compared to other chloropicrin absorbents.
また、クロルピクリンによりベース樹脂自身も
劣化が促進されるが、その対策としてフイルムの
耐候性を向上する為に一般的に用いられる手法、
即ち、各種の紫外線吸収剤や光安定剤等を0.1〜
2.0重量％程度添加使用してもよい。 In addition, chloropicrin accelerates the deterioration of the base resin itself, but as a countermeasure, methods commonly used to improve the weather resistance of the film are:
In other words, various ultraviolet absorbers, light stabilizers, etc.
It may be used in an amount of about 2.0% by weight.
特に、光安定剤として、その分子量が1000以上
のヒンダードアミン系化合物（チバ・ガイギー
社、商品名：TINUVIN−622やCHIMASSORB
−944等）と前記ハイドロタルサイト類化合物を
併用添加すれば、アルミニウム保護とフイルム耐
候性の保持向上の両面で特に良好である。 In particular, hindered amine compounds with a molecular weight of 1000 or more (Ciba Geigy, product name: TINUVIN-622 and CHIMASSORB) are used as light stabilizers.
-944, etc.) and the above-mentioned hydrotalcite compounds are particularly effective in both protecting aluminum and improving the weather resistance of the film.
以上のように本発明によれば上記クロルピクリ
ンの吸収剤がクロルピクリンと反応するのでアル
ミニウムは保護され、アルミニウムは劣化消散す
ることなく、長くその反射機能を保持するもので
ある。
As described above, according to the present invention, since the chloropicrin absorbent reacts with chloropicrin, aluminum is protected, and the aluminum retains its reflective function for a long time without degrading and dissipating.
第１図乃至第３図は本発明の夫々異なつた３つ
の実施例の説明図、第４図はその使用状態の説明
図である。
１ａ，１ｂ，１ｃ……フイルム、２……アルミ
ニウム粉末、３……ハイドロタルサイト類化合物
（クロルピクリン吸収剤）。
1 to 3 are explanatory diagrams of three different embodiments of the present invention, and FIG. 4 is an explanatory diagram of the usage state thereof. 1a, 1b, 1c...Film, 2...Aluminum powder, 3...Hydrotalcite compound (chloropicrin absorbent).
Claims (1)
ン吸収剤とよりなるアルミニウムマルチフイル
ム。 ２ 上記クロルピクリン吸収剤はハイドロタルサ
イト類化合物である特許請求の範囲第１項記載の
アルミニウムマルチフイルム。 ３ 上記クロルピクリン吸収剤をプラスチツクと
アルミニウムとに混練してなる特許請求の範囲第
１項記載のアルミニウムマルチフイルム。 ４ 上記クロルピクリン吸収剤をプラスチツクと
アルミニウムとよりなるフイルムの内面に濃縮し
てなる特許請求の範囲第１項記載のアルミニウム
マルチフイルム。[Claims] 1. An aluminum multi-film made of plastic, aluminum, and a chloropicrin absorbent. 2. The aluminum multifilm according to claim 1, wherein the chloropicrin absorbent is a hydrotalcite compound. 3. The aluminum multi-film according to claim 1, which is obtained by kneading the chloropicrin absorbent with plastic and aluminum. 4. The aluminum multi-film according to claim 1, wherein the chloropicrin absorbent is concentrated on the inner surface of a film made of plastic and aluminum.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP60215274A JPS6274222A (en) | 1985-09-27 | 1985-09-27 | Aluminum mulching film |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP60215274A JPS6274222A (en) | 1985-09-27 | 1985-09-27 | Aluminum mulching film |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6274222A JPS6274222A (en) | 1987-04-06 |
| JPH0528089B2 true JPH0528089B2 (en) | 1993-04-23 |
Family
ID=16669596
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP60215274A Granted JPS6274222A (en) | 1985-09-27 | 1985-09-27 | Aluminum mulching film |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6274222A (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3613897B2 (en) * | 1996-03-29 | 2005-01-26 | セイコーエプソン株式会社 | Liquid crystal display device and equipment using the same |
| US20060115616A1 (en) * | 2002-12-04 | 2006-06-01 | Biotrans Uk Limited | Protectors for protecting timber poles against subsoil decay |
| JP2016000026A (en) * | 2013-11-06 | 2016-01-07 | 協和化学工業株式会社 | Hothouse and heat-retention cover having heat retaining properties and transparency |
-
1985
- 1985-09-27 JP JP60215274A patent/JPS6274222A/en active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS6274222A (en) | 1987-04-06 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| EXPY | Cancellation because of completion of term |