JPH05279214A - Organism adhesion-preventing structure - Google Patents

Abstract

PURPOSE:To provide the organism adhesion-preventing structure excellent in antifouling performance and durability, requiring no maintenance and free from toxicity by a simple sticking work. CONSTITUTION:A resin 2 comprising an electric insulating material is adhesively bonded to the inner circumferential wall surface of a cylindrical steel pipe 1. A metal net 5 comprising a beryllium-copper alloy is stuck on the surface of the resin 2. The thin plate 5 of the beryllium-copper alloy is drawn out from a plate product preliminarily rolled in a roll-like shape and subsequently adhesively bonded to the surface of the resin 2. The content of the beryllium in the beryllium-copper alloy is 0.2-2.8wt.%. The beryllium-copper alloy is selected from Be-Cu alloy, Be-Co-Cu alloy, Be-Co-Si-Cu alloy, Be-Ni-Cu alloy, etc.

Description

Detailed Description of the Invention

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an antifouling structure having a function of preventing the adhesion of marine organisms such as barnacles, purple shellfish and algae.

[0002]

2. Description of the Related Art Marine structures that are in contact with seawater are constantly exposed to fouling due to the adhesion of marine life. Therefore, not only the appearance of the ordinary marine structure is deteriorated, but also the functional structure is damaged. For example, in the case of a ship, resistance increases due to the adhesion of marine life to the bottom surface of the hull and the like, and the propulsion speed of the hull decreases. Further, in the case of a thermal power plant, if marine life adheres to the seawater intake pit, the flow of seawater, which is a cooling medium, may be impaired, and power generation may have to be stopped.

For this reason, many techniques for preventing adhesion of marine organisms have been studied, and one of the techniques for preventing adhesion of marine organisms that has been put into practical use is a coating containing cuprous oxide or organic tin. It is a method of applying it to the contact surface of the marine structure with seawater. Further, JP-A-60-209505 discloses a biofouling-preventing pressure-sensitive adhesive body in which a primer layer is provided on one surface of a plate made of copper or a copper alloy, and a pressure-sensitive adhesive layer is formed on the primer layer.

[0004]

However, according to the conventional antifouling method using a paint, even if the paint is applied thickly, the paint is easily peeled off, so that the life of exhibiting a remarkable antifouling effect is about one year. Therefore, a complicated maintenance work of recoating each year is required. In addition, JP-A-60-20950
The marine organism adhesion preventive body disclosed in Japanese Patent Publication No. 5 uses copper or a copper-nickel (Cu-Ni) alloy, and therefore has insufficient corrosion resistance and antifouling performance.

By the way, as a result of many years of experimental research by the present inventor, when a beryllium copper alloy is used for an offshore structure,
It has been found that it exhibits an extremely excellent antifouling effect. It is presumed that this is because beryllium ions act synergistically with copper ions to exert a large repellent effect on marine organisms, and to prevent adhesion and reproduction of marine organisms. That is,
It was found by the present inventor that the beryllium copper alloy has an effect of exhibiting an antifouling function and a continuous action of elution of copper ions.

The object of the present invention is to improve the workability of sticking,
It is an object of the present invention to provide a biofouling prevention structure which has excellent antifouling performance and durability, requires no maintenance, and has no toxicity problem.

[0007]

A biofouling-preventing structure according to the present invention for solving the above-mentioned problems comprises an insulator layer formed on the surface of a metal body, and a beryllium copper alloy is formed on the surface of the insulator layer. Characterized by bonding wire mesh. The beryllium copper alloy has a beryllium content of 0.2 to 2.8.
% By weight, Be-Cu alloy, Be-Co-Cu alloy, Be-Co-Si-Cu alloy or Be-Ni-C
It is characterized in that it is any one alloy selected from the group consisting of u alloys.

The composition of the beryllium copper alloy is, for example,
Be: 0.2 to 1.0% by weight, Co: 2.4 to 2.7
% By weight, balance Cu and unavoidable impurities, Be: 0.2
~ 1.0 wt%, Ni: 1.4-2.2 wt%, balance C
u and unavoidable impurities, Be: 1.0 to 2.0 wt%, Co: 0.2 to 0.6 wt%, balance Cu and unavoidable impurities, Be: 1.6 to 2.8 wt%, Co: 0 ．
4 to 1.0% by weight, Si: 0.2 to 0.35% by weight, balance Cu and inevitable impurities.

The contents of cobalt, nickel and silicon selectively contained in the beryllium copper are preferably in the following ranges. Cobalt (Co): 0.2 to 2.7% by weight Nickel (Ni): 1.4 to 2.2% by weight Silicon (Si): 0.2 to 0.35% by weight Purpose of addition of each element, addition The reason for limiting the upper limit and the lower limit of the range is as follows.

Beryllium (Be): 0.2 to 2.8 wt% Be is added so that when the antifouling structure is immersed in seawater, Be is eluted to exert an antifouling effect and beryllium copper. This is because the properties of the alloy such as strength and corrosion resistance are improved, the manufacturability such as heat treatment property and grain size adjustment is improved, and the formability and castability are improved. Be is 0.
If it is less than 2% by weight, the above effects (1) to (4) are not sufficiently exhibited. When Be exceeds 2.8% by weight, the wrought workability deteriorates and the cost becomes economically expensive.

Cobalt (Co): 0.2 to 2.7 wt% Co is added to form fine CoBe compounds and disperse them in the alloy to obtain mechanical properties, heat treatment properties, grain size adjustment, etc. This is for improving the manufacturability of. Co is 0.2
If it is less than wt%, the above-mentioned effects cannot be sufficiently exhibited.
This is because when Co exceeds 2.7% by weight, the flowability of the molten metal deteriorates, the above properties are hardly improved, and the cost becomes economically expensive.

Nickel (Ni): 1.4 to 2.2 wt% Ni is added to form fine NiBe compounds and disperse them in the alloy to obtain mechanical properties, heat treatment properties, grain size adjustment, etc. This is for improving the manufacturability of. Ni is 1.4
If it is less than wt%, the above-mentioned effects cannot be sufficiently exhibited.
This is because when Ni exceeds 2.2% by weight, the flowability of the molten metal deteriorates, the above characteristics are hardly improved, and the cost becomes economically expensive.

Silicon (Si): 0.2 to 0.35 wt% Si is added to improve the flowability of the beryllium alloy. If Si is less than 0.2% by weight, the effect is not sufficiently exhibited, and if Si is more than 0.35% by weight, the alloy becomes brittle and the toughness deteriorates.

[0014]

According to the biofouling prevention structure of the present invention, an insulator layer is formed on the surface of a metal body, and a wire mesh made of beryllium copper alloy is bonded to the surface of the insulator layer. The work of adhering a wire mesh made of is simple.
Beryllium copper alloy bonded by this method is
It has the effect of repelling marine life in seawater and has the same excellent durability as aluminum bronze and white bronze.

[0015]

Embodiments of the present invention will be described below with reference to the drawings. A first embodiment of the present invention is shown in FIGS. The first embodiment is an example in which the present invention is applied to a pipe for circulating seawater used in a cooling facility of a power plant.

As shown in FIG. 2, the inner peripheral wall surface of the cylindrical iron pipe 1 is made of an electrically insulating material such as glass, concrete,
Desirably, the resin 2 is bonded. Then, the wire net 5 made of beryllium copper is attached to the surface of the resin 2. As shown in FIG. 1, the beryllium-copper wire mesh 5 is pulled out from a pre-wound roll and bonded to the surface of the resin 2. An adhesive is applied to the surface of the resin 2 in advance.

As a result of many years of experimental studies conducted by the present inventor, beryllium copper alloy has an effect of exhibiting an antifouling function and a continuous action of elution of copper ions. The effect of exhibiting the antifouling function and the continuous action of elution of copper ions are described in detail below. Effect of antifouling function The ionization tendency of beryllium, copper and nickel is Be> N
It is known from the literature that i> Cu, indicating that the element on the left side is more likely to elute. In the case of beryllium copper, beryllium elutes first to form a local battery and exerts a biofouling prevention effect by the current effect, and the beryllium ion takes an oxidized form called internal oxidation. This internal oxidation forms a BeO film inside, for example, as shown in FIG. 6, but since this BeO film is porous, copper elution is allowed to form Cu ₂ O + BeO on the surface. It is considered that the antifouling function is exhibited by the elution of this copper ion into seawater.

Sustaining action of copper ion elution The above-described effect of exhibiting the antifouling function has a continuing action of eluting copper ions. That is, beryllium copper has an action of continuing the antifouling function without stopping. A dense surface oxide (Cu ₂ O) is formed on the surface of beryllium copper that comes into contact with seawater. However, as shown in FIG. 6, the internal oxide of porous BeO is formed in the lower layer of the surface oxide. A film of matter is formed. Therefore, the elution of copper into seawater is maintained, and the volume of this film increases due to oxidation. When the volume increase of the film reaches a certain amount, the oxide film on the surface is separated from the porous internal oxide layer. Therefore, it is considered that the electrochemical action and the elution of copper are maintained for a long time.

Further, the continuous action of copper ion elution generated by beryllium copper will be explained as follows by using a schematic diagram shown in FIG. 8 when comparing beryllium copper and cupro nickel. As shown in FIG. 8, when beryllium copper (BeCu) has a certain thickness of a corrosion product (oxide), the corrosion product is exfoliated. Then, the surface of the beryllium copper alloy appears, and the thickness of the corrosion product increases with the progress of corrosion again. Then, the corrosion product is peeled off again when it reaches a certain thickness, which is repeated. On the other hand, the elution of ions is gradually decreased because it is inhibited as the thickness of the corrosion product increases. However, when the corrosion product is peeled off as described above, the surface of the alloy appears and the amount of ion elution increases. Therefore, the increase and decrease of copper ion elution are repeated.

In the beryllium copper of the example of the present invention, the stripping of the oxide film has the effect of sustaining the elution of copper ions. As a result, the amount of marine organisms adhering to the surface of copper beryllium is small or hardly adhered. On the other hand, as shown in FIG. 7, in the case of cupro-nickel (CuNi) of the comparative example, dense nickel oxide NiO ₂ or copper oxide Cu ₂ O is formed in the surface layer over a certain period of time. This is because the elution of copper ions is suppressed as shown in FIG. This is due to ionization tendency (Be>
According to Ni> Cu), in the case of cupro nickel, nickel (Ni) is considered to preferentially elute to form a local battery, which is due to the formation of a dense oxide on the surface as shown in FIG. Therefore, as shown in FIG. 5, in the case of cupro-nickel, the thickness of the corrosion product initially increases with time, but the growth rate of the corrosion product gradually decreases. Along with that, the elution amount of copper ions gradually decreases. Moreover, with Cupro nickel, flaking of corrosion products does not occur as easily as with beryllium copper. Therefore, the elution amount of ions remains at a low level, and the antifouling effect decreases.

The inventors of the present invention have found for the first time that the beryllium-copper alloy has been found to have such remarkable antifouling function and copper ion elution sustaining effect. The present inventor is unaware of any prior art document that refers to or points out. As a practical beryllium copper alloy, 11 alloys having a beryllium content of 0.2 to 0.6% by weight and a beryllium content of 1.8 to 2.0% by weight.
Although various alloys such as No. 25 alloy are specified by JIS, those having a beryllium content of 1.6% or more are preferable from the viewpoint of antifouling effect. If the content of beryllium exceeds 2.8%, beryllium will no longer form a solid solution with copper, so that the antifouling effect is excellent but the wrought workability is gradually reduced.

Next, a second embodiment of the present invention is shown in FIG. The second embodiment is an example in which a punching metal 6 is used instead of the wire net 5 of the first embodiment. Punching metal 6
Is made of a beryllium copper alloy, and a large number of small holes 6c are formed in the foil body 6b. The second embodiment is an example in which an insulating material layer 6 is applied to the inner wall surface 1a of the pipe 1, dried, and then a punching metal 6 made of a beryllium copper alloy is attached. For the attachment, it is desirable to use, for example, an adhesive or a punching metal 6 whose surface is coated with an adhesive.

According to the second embodiment, as in the first embodiment, the corrosion resistance to seawater is good, and the antifouling effect is exhibited. Next, a third embodiment of the present invention is shown in FIG. The third embodiment is an example in which the punching metal 6 of the second embodiment is replaced with a foil body such as expanded metal in which small holes are formed at the time of pulling. Figure 4
As shown in (A), the foil body 8 is made of a beryllium-copper alloy, and a large number of notched small holes 8a are formed in the foil body 6b. When pulled, as shown in FIG. It is transformed into a round small hole 8a.

Next, a fourth embodiment of the present invention is shown in FIG.
The fourth embodiment is an example in which, instead of the punching metal 6 of the second embodiment, a wire mesh body 10 that deforms into a wire mesh shape when pulled is used. The wire mesh body 10 is made of a beryllium copper alloy, and as shown in FIG. 5, when pulled in the arrow direction, the folded wire mesh body 10 is deformed into a mesh shape.

[0025]

As described above, according to the biofouling prevention body of the present invention, the biofouling prevention structure can be attached by a relatively simple operation. According to the biofouling prevention structure attached by this method, excellent corrosion resistance,
The maintenance work is simple, there is no problem of toxicity, and there is an effect of effectively preventing the adhesion of marine life.

[Brief description of drawings]

FIG. 1 is a perspective view showing a wire mesh of a biofouling prevention structure according to a first embodiment of the present invention.

FIG. 2 is a schematic cross-sectional view showing a biological adhesion preventing structure to which the wire net shown in FIG. 1 is adhered.

FIG. 3 is a perspective view showing a punching metal of a biofouling prevention structure according to a second embodiment of the present invention.

FIG. 4A is a perspective view showing a foil body of a biofouling prevention structure according to a third embodiment of the present invention. (B) is a perspective view showing a state in which a tensile force is applied to the foil body.

FIG. 5 is a perspective view showing a wire netting of a biofouling prevention structure according to a fourth embodiment of the present invention.

FIG. 6 is a schematic view showing an oxide film state of beryllium copper according to the example of the present invention.

FIG. 7 is a schematic view showing an oxide film state of cupro nickel of a comparative example.

FIG. 8 is a schematic explanatory diagram comparing changes over time in the amount of copper ions eluted and the thickness of corrosion products for beryllium copper and cupro nickel.

[Explanation of symbols]

 1 Iron pipe (metal body) 5 Wire mesh (beryllium copper alloy) 6 Punching metal (beryllium copper alloy) 8 Foil body (beryllium copper alloy) 10 Wire mesh body (beryllium copper alloy)

Claims (5)

[Claims] 1. A biofouling-preventing structure characterized in that an insulator layer is formed on the surface of a metal body, and a wire net made of a beryllium-copper alloy is adhered to the surface of the insulator layer. 2. The beryllium copper alloy has a beryllium content of 0.2 to 2.8% by weight, and a Be--Cu alloy,
The biofouling-preventing structure according to claim 1, wherein the biofouling-preventing structure is an alloy selected from the group consisting of a Be-Co-Cu alloy, a Be-Co-Si-Cu alloy, and a Be-Ni-Cu alloy. body. 3. The biofouling prevention structure according to claim 1, wherein the insulator layer is made of resin, glass, or concrete. 4. A biofouling-preventing structure characterized in that an insulating layer is formed on the surface of a metal body, and a punching metal-shaped foil made of beryllium copper alloy is bonded to the surface of the insulating layer. 5. An organism attachment preventing structure characterized in that an insulating layer is formed on the surface of a metal body, and an expanded metal or wire mesh-shaped foil made of beryllium copper alloy is adhered to the surface of the insulating layer. ..