JPH05276887A - Oil-in-water type emulsion for whipping cream - Google Patents
Oil-in-water type emulsion for whipping creamInfo
- Publication number
- JPH05276887A JPH05276887A JP4105877A JP10587792A JPH05276887A JP H05276887 A JPH05276887 A JP H05276887A JP 4105877 A JP4105877 A JP 4105877A JP 10587792 A JP10587792 A JP 10587792A JP H05276887 A JPH05276887 A JP H05276887A
- Authority
- JP
- Japan
- Prior art keywords
- oil
- fat
- water emulsion
- emulsion
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Dairy Products (AREA)
- Grain Derivatives (AREA)
Abstract
Description
【0001】[0001]
【産業上の利用分野】本発明は、ホイップクリーム用水
中油型乳化物に関する。更に詳しくは、本発明は、乳味
を一層強く感じることができる、ホイップクリーム用水
中油型乳化物(コンパウンドクリーム)に関する。FIELD OF THE INVENTION The present invention relates to an oil-in-water emulsion for whipped cream. More specifically, the present invention relates to an oil-in-water emulsion (compound cream) for whipped cream, which allows the milky taste to be felt more strongly.
【0002】[0002]
【従来の技術】水中油型乳化物である生クリームは、口
あたり、口どけなどの食感が良く、また比較的さっぱり
とした乳味感を有しており、風味も非常に良好であるた
め、従来からホイップクリームなどに使用されている。
しかし、生クリームは、高価で、品質の一定したものが
供給されにくく、またホイップさせるのに技術を要し、
更にホイップしたものは、不安定で、所謂「造花」など
が作りにくく、温度や振動によってその造形物が変形す
るなど、使用しにくい欠点を持っている。2. Description of the Related Art Fresh cream, which is an oil-in-water type emulsion, has a good mouthfeel, mouthfeel and the like, a relatively refreshing milky taste, and a very good flavor. Therefore, it has been conventionally used for whipped cream and the like.
However, fresh cream is expensive, it is difficult to supply a constant quality product, and it requires a technique to whipped it.
Furthermore, the whipped product is unstable, and it is difficult to make so-called "artificial flowers", and the molded product is deformed due to temperature and vibration.
【0003】上記のような欠点を改良したものとして、
植物脂に無脂乳固形分、乳化剤などを加えて調製した純
植物性の合成クリーム(フィルドクリーム)、植物脂に
生クリームあるいは乳脂肪分を加えて、両者の特性を調
合したコンパウンドクリームが種々提案されているが、
近年では、食感などの点からコンパウンドクリームが主
流となっている。コンパウンドクリームは、通常、乳
脂、植物脂、及び乳化剤などからなる配合の油性成分
と、脱脂乳などの無脂乳固形分及び乳化剤などからなる
配合の水性成分とを混合し、予備乳化、滅菌、均質化、
冷却、充填、エージングの各工程を経て製造される。上
記のような製造法で得られたコンパウンドクリームは、
上記のように起泡性(ホイップ性)、保型性、離水耐性
などの物性面では、確かに、生クリームに比べ優れた特
性を示すが、これを用いてなるホイップクリームの食
感、風味の点においては、なお十分とはいえない。特
に、植物脂が含まれているため、一般に乳味がそれほど
強く感じられないといった問題がある。As an improved version of the above drawbacks,
Various pure vegetable synthetic creams (filled creams) prepared by adding non-fat milk solids and emulsifiers to vegetable fats, and compound creams prepared by adding fresh cream or milk fat to vegetable fats and combining the characteristics of both Has been proposed,
In recent years, compound cream has become the mainstream in terms of texture and the like. Compound cream is usually mixed with an oil component of a mixture of milk fat, vegetable fat, and an emulsifier, and an aqueous component of a mixture of non-fat milk solids such as skim milk and an emulsifier, pre-emulsification, sterilization, Homogenization,
It is manufactured through the steps of cooling, filling, and aging. The compound cream obtained by the above production method is
As mentioned above, in terms of physical properties such as foaming property (whipped property), shape retention property, and water separation resistance, it certainly shows superior characteristics to fresh cream, but the texture and flavor of whipped cream using this cream In terms of, it is still not sufficient. In particular, since it contains vegetable fat, there is a problem that the milky taste is not felt so strongly.
【0004】[0004]
【発明が解決しようとする課題】本発明は、天然の生ク
リームに代わる材料を用いて、生クリームを使用して得
たホイップクリームのような強い乳味感を有し、またそ
の口どけなどから受ける良好な食感、風味を有するホイ
ップクリーム用水中油型乳化物を提供することを目的と
する。DISCLOSURE OF THE INVENTION The present invention has a strong milky taste like a whipped cream obtained by using a fresh cream by using a material replacing the natural fresh cream, and its mouthfeel etc. The object is to provide an oil-in-water emulsion for whipped cream, which has a good texture and flavor received from
【0005】[0005]
【課題を解決するための手段】乳化物は、ホイップして
多数の気泡を取り込ませることによってその中の油滴
(脂肪球:エマルジョン粒子)の解乳化や脂肪球の破壊
が起り、これによって脂肪球の凝集が発生する。凝集し
た脂肪球(凝集脂肪球)の多くは気泡の表面に吸着し、
そしてその一部は連鎖による網目構造(ネットワーク)
を形成する。また脂肪球は、遊離脂肪ともなって上記の
ようにネットワークを形成している凝集脂肪球の回りに
集まるものもあり、あたかも凝集脂肪球と凝集脂肪球を
結びつける接着剤のような働きをし、ネットワークを強
固にする。このような構造により、気泡が安定化され、
良好なホイップクリームが得られると考えられている。[Means for Solving the Problems] When an emulsion is whipped to take in a large number of bubbles, the oil droplets (fat globules: emulsion particles) in the emulsion are demulsified and fat globules are destroyed. Sphere aggregation occurs. Most of aggregated fat globules (aggregated fat globules) are adsorbed on the surface of bubbles,
And a part of it is a network structure with a chain.
To form. There are also fat globules that gather around the aggregated fat globules that form a network as described above together with free fat, and act as an adhesive that links aggregated fat globules to aggregated fat globules, To strengthen. With this structure, the bubbles are stabilized,
It is believed that a good whipped cream is obtained.
【0006】本発明者は、天然の生クリームの代わりに
なる材料を用いた乳脂の脂肪球と植物脂の脂肪球とが混
合された乳化物をホイップした場合、乳脂の脂肪球から
より早く乳味を感受できれば、より強く乳味を感じるこ
とができ、それに従って、食感、風味も改良され、より
生クリームの食感、風味に近付くであろうとの着想に基
づいて更に検討を重ねた。その結果、乳脂の脂肪球の耐
破壊強度が植物脂の脂肪球の耐破壊強度より低いような
乳化物を使用した場合には、植物脂に比べ乳脂による凝
集した脂肪球ができ易く、従って、乳味の流出が容易に
行われ、また凝集した脂肪球の気泡表面への移動による
水相部の水分濃度が高くなり、これらの両者の作用によ
って、目的とする乳味感のある、食感、風味の良好なホ
イップクリームが得られることを見い出し、本発明を完
成させた。When the present inventor whipped an emulsion in which fat globules of milk fat and fat globules of vegetable fat were mixed using a material which replaces natural fresh cream, the fat globules of milk fat were milked more quickly. If the taste can be sensed, a stronger milky taste can be felt, and accordingly, the texture and flavor are improved, and further studies were conducted based on the idea that the texture and flavor of fresh cream would be closer to the taste. As a result, when using an emulsion in which the breaking strength of fat globules of milk fat is lower than the breaking strength of fat globules of vegetable fat, aggregated fat globules due to milk fat are more likely to be formed than vegetable fat, therefore, Outflow of milkiness is facilitated, and the water concentration in the water phase part increases due to the movement of aggregated fat globules to the surface of bubbles, and the action of both of these increases the desired milky taste and texture. It was found that a whipped cream with a good flavor was obtained, and the present invention was completed.
【0007】本発明は、植物脂を主成分とする油脂の油
滴を含む水中油型乳化物と、乳脂を主成分とする油脂の
油滴であって、その油滴の耐破壊強度(破壊されにく
さ)が上記の植物脂の油滴の耐破壊強度に比較して低い
油滴を含む水中油型乳化物とを混合してなるホイップク
リーム用水中油型乳化物にある。The present invention relates to an oil-in-water emulsion containing oil droplets of oils and fats containing vegetable oil as a main component, and oil droplets of oils and fats containing milk oils as a main component, the fracture resistance strength (breakage) of the oil droplets. The oil-in-water emulsion for whipped cream obtained by mixing with the oil-in-water emulsion containing oil droplets whose oil resistance is lower than the breaking resistance of the oil droplets of the above-mentioned vegetable fat.
【0008】以下に本発明のホイップクリーム用水中油
型乳化物(以下単に、本発明の乳化物と称す)について
説明する。本発明の乳化物は、例えば、以下の工程で製
造することができる。 (I)植物脂を主成分とする油脂の油滴を含む水中油型
乳化物(A)を調製する工程; (II)乳脂を主成分とする油脂の油滴を含む水中油型乳
化物(B)を調製する工程; (III)得られた上記乳化物(A)と(B)を混合する工
程;そして、 (IV)得られた混合物を、滅菌、均質化、冷却、充填、
エージングの各処理を行う工程。 なお、上記(IV)の工程の各処理のうち、滅菌、均質
化、冷却の各処理は、上記水中油型乳化物(A)、
(B)の調製状態に応じて、適宜変更し得る。例えば、
水中油型乳化物(A)、(B)の各調製工程おいて、乳
化物(A)、(B)の処理が冷却まで終了している場合
には、これら一連の処理は省いてもよい。すなわち、上
記(IV)の工程の処理は、充填、エージングのみの処理
で良い。The oil-in-water emulsion for whipped cream of the present invention (hereinafter simply referred to as the emulsion of the present invention) will be described below. The emulsion of the present invention can be produced, for example, by the following steps. (I) A step of preparing an oil-in-water emulsion (A) containing oil droplets of an oil or fat containing a vegetable fat as a main component; (II) An oil-in-water emulsion containing oil droplets of an oil or fat containing a milk fat as a main component ( B); (III) mixing the obtained emulsions (A) and (B); and (IV) sterilizing, homogenizing, cooling, filling,
A step of performing each treatment of aging. In addition, among the respective treatments of the above step (IV), the respective treatments of sterilization, homogenization and cooling are carried out by the above oil-in-water emulsion (A),
It can be appropriately changed depending on the preparation state of (B). For example,
In the preparation steps of the oil-in-water emulsion (A) and (B), when the treatment of the emulsions (A) and (B) is completed until cooling, these series of treatments may be omitted. .. That is, the treatment of the above step (IV) may be treatment of only filling and aging.
【0009】以下に、各工程を更に詳細に説明する。Each step will be described in more detail below.
【0010】上記(I)の工程の水中油型乳化物(A)
の調製は、植物脂を主成分とする油脂及び乳化剤などが
配合されてなる油性成分(油性液)に、脱脂乳などの乳
蛋白質、安定剤、及び乳化剤などが配合されてなる水性
成分(水性液)を添加混合し、予備乳化、均質化の処理
によりなされる。また、上記(II)の工程の水中油型乳
化物(B)の調製は、乳脂を主成分とする油脂及び乳化
剤などが配合されてなる油性成分(油性液)に、脱脂乳
などの乳蛋白質、安定剤、及び乳化剤などが配合されて
なる水性成分(水性液)を添加混合し、上記と同様な各
処理でなされる。なお、上記(I)、(II)のそれぞれ
の工程において、更に、滅菌、均質化、冷却の各処理を
施してもよいことは、前述した通りである。上記水中油
型乳化物(A)及び(B)中の油脂含量は、それぞれ3
0〜60重量%の範囲、好ましくは35〜55重量%の
範囲、更に好ましくは、40〜45重量%の範囲であ
る。Oil-in-water emulsion (A) of the above step (I)
The preparation of is an oily component (oil-based liquid) composed of an oil and fat and an emulsifier mainly containing vegetable fat, a milk protein such as skim milk, a stabilizer, and an aqueous component composed of an emulsifier, etc. Liquid) is added and mixed, and pre-emulsification and homogenization are performed. In addition, the preparation of the oil-in-water emulsion (B) in the above step (II) is carried out by adding an oil component (oil-based liquid) containing an oil and fat containing milk fat as a main component and an emulsifier to a milk protein such as skim milk. An aqueous component (aqueous liquid) containing a stabilizer, a stabilizer, an emulsifier and the like is added and mixed, and each treatment is performed in the same manner as above. As described above, in each of the steps (I) and (II), sterilization, homogenization and cooling may be further performed. The oil and fat content in each of the oil-in-water emulsions (A) and (B) is 3
The range is 0 to 60% by weight, preferably 35 to 55% by weight, and more preferably 40 to 45% by weight.
【0011】上記水中油型乳化物(A)及び(B)の調
製に使用される主要成分について説明する。上記植物
脂、乳脂は、従来から水中油型乳化物に使用されている
ものでれば特に制限なく利用できる。植物脂としては、
例えば、大豆油、綿実油、コーン油、ひまわり油、サフ
ラワー油、パーム油、パーム核油、菜種油、カポック
油、ヤシ油及びこれらの硬化油を挙げることができる。
これらの中では、大豆硬化油とヤシ硬化油が好ましい。
また乳脂は、通常生クリームからチャーニングして得た
バターを溶解し、水分を除いたものが使用される。The main components used for preparing the above oil-in-water emulsions (A) and (B) will be described. The above-mentioned vegetable fats and milk fats can be used without particular limitation as long as they have been conventionally used in oil-in-water emulsions. As vegetable fat,
Examples thereof include soybean oil, cottonseed oil, corn oil, sunflower oil, safflower oil, palm oil, palm kernel oil, rapeseed oil, kapok oil, coconut oil and hydrogenated oils thereof.
Of these, hardened soybean oil and hardened coconut oil are preferred.
The milk fat used is usually one obtained by dissolving butter obtained by churning fresh cream to remove water.
【0012】上記乳化剤は、従来公知のものの中から選
ばれるが、乳化剤は、その特性によって、乳化を安定化
させるもの、乳化を破壊し、凝集を促進させるもの、気
泡を安定に取り込むものに分けられ、通常、これらの乳
化剤を組み合わせて使用する。特に、本発明において
は、乳化剤により、脂肪球の耐破壊強度も変化するため
(乳化剤は、脂肪球の界面に蛋白質と共に吸着(配向)
し、膜を形成する)、これらのことを考慮に入れて選択
することが好ましい。上記水中油型乳化物(A)の調製
には、例えば、以下の乳化剤が好ましく使用できる。レ
シチン、グリセリン脂肪酸エステル、プロピレングリコ
ール脂肪酸エステル、ソルビタン脂肪酸エステル、ポリ
グリセロール脂肪酸エステル、ショ糖脂肪酸エステル。
本発明においては、特に、レシチンとショ糖脂肪酸エス
テルの併用が好ましい。また、上記水中油型乳化物
(B)の調製には、例えば、以下の乳化剤が好ましく使
用できる。レシチン、グリセリン脂肪酸エステル、プロ
ピレングリコール脂肪酸エステル、ソルビタン脂肪酸エ
ステル、ポリグリセロール脂肪酸エステル、ショ糖脂肪
酸エステル。本発明においては、特に、レシチンとショ
糖脂肪酸エステルの併用が好ましい。これらの乳化剤は
その合計含有量が、それぞれ水中油型乳化物(A)及び
(B)中に、0.1〜2.5重量%の範囲(更に好まし
くは、0.3〜1.5重量%の範囲)で使用されること
が好ましい。なお、本発明の乳化物の調製に際しては、
上記以外の任意成分(例えば、呈味剤、増粘剤など)を
添加してもよい。これらを添加する場合にも、上記の成
分と同様に親油性の添加物は油性液中に、そして親水性
の添加物は水性液中に添加される。The above-mentioned emulsifiers are selected from conventionally known ones. Depending on their characteristics, the emulsifiers are classified into those that stabilize the emulsification, those that destroy the emulsification and promote aggregation, and those that stably take in air bubbles. In general, these emulsifiers are used in combination. In particular, in the present invention, the emulsifier also changes the fracture resistance of fat globules (the emulsifier is adsorbed (orientated) along with the protein on the interface of fat globules).
Then, a film is formed), and it is preferable to select in consideration of these things. For the preparation of the oil-in-water emulsion (A), for example, the following emulsifiers can be preferably used. Lecithin, glycerin fatty acid ester, propylene glycol fatty acid ester, sorbitan fatty acid ester, polyglycerol fatty acid ester, sucrose fatty acid ester.
In the present invention, it is particularly preferable to use lecithin in combination with sucrose fatty acid ester. Further, for the preparation of the oil-in-water emulsion (B), for example, the following emulsifiers can be preferably used. Lecithin, glycerin fatty acid ester, propylene glycol fatty acid ester, sorbitan fatty acid ester, polyglycerol fatty acid ester, sucrose fatty acid ester. In the present invention, it is particularly preferable to use lecithin in combination with sucrose fatty acid ester. The total content of these emulsifiers is in the range of 0.1 to 2.5% by weight (more preferably 0.3 to 1.5% by weight) in the oil-in-water emulsions (A) and (B), respectively. % Range). In the preparation of the emulsion of the present invention,
You may add optional components other than the above (for example, a flavoring agent, a thickener, etc.). When these are added, the lipophilic additive is added to the oily liquid and the hydrophilic additive is added to the aqueous liquid similarly to the above components.
【0013】上記水中油型乳化物(B)中の乳脂の油滴
(脂肪球)の耐破壊強度は、上記水中油型乳化物(A)
中の植物脂の油滴(脂肪球)の耐破壊強度に比較して低
くなるように調製されている。すなわち、乳脂の脂肪球
が、植物脂の脂肪球に比べ壊れ易く形成されている。脂
肪球の耐破壊強度は、脂肪球の粒子径によるところが大
きい。一般に、脂肪球の粒子径が小さい程、耐破壊強度
は大で、脂肪球の粒子径が大きくなるにつれてその耐破
壊強度も小さくなる。従って、乳脂の脂肪球の粒子径を
植物脂の脂肪球のそれに比べ大きく設定することが、本
発明の実施においては有効な方法である。具体的な方法
としては、上記それぞれの水中油型乳化物を調製する際
の均質化処理において、通常、ホモゲナイザーのような
加圧式均質機(高圧にされた処理液体が均質バルブを通
過して低圧部へ流れる際に脂肪球が粉砕される機構)が
使用されるが、この均質機の設定圧力(均質化圧力/乳
化圧力)を種々変化させることにより、植物脂の脂肪
球、及び乳脂の脂肪球の粒子径の各々をコントロール
し、植物脂の脂肪球に比べ乳脂の脂肪球が壊れ易くなる
ように構成することができる。また、上記均質化圧力を
ほぼ同等に設定して植物脂の脂肪球の粒子径と乳脂の脂
肪球の粒子径がほぼ同じ粒子径となるように調製した場
合には、前述したように使用する乳化剤の選択が有効な
方法である。The breaking strength of oil droplets (fat globules) of milk fat in the oil-in-water emulsion (B) is determined by the oil-in-water emulsion (A).
It is adjusted to be lower than the breaking resistance strength of oil droplets (fat globules) of vegetable fat inside. That is, the fat globules of milk fat are formed more easily than the fat globules of vegetable fat. The breaking strength of fat globules largely depends on the particle size of fat globules. Generally, the smaller the particle size of fat globules, the greater the fracture strength, and the larger the particle size of fat globules, the smaller the fracture resistance. Therefore, setting the particle size of fat globules of milk fat larger than that of fat globules of vegetable fat is an effective method in the practice of the present invention. As a specific method, in the homogenization treatment when preparing each of the above oil-in-water emulsions, a pressure type homogenizer such as a homogenizer is usually used (a high pressure treated liquid passes through a homogenizing valve and a low pressure). The mechanism by which fat globules are crushed when flowing to the part) is used. By varying the set pressure (homogenization pressure / emulsification pressure) of this homogenizer, the fat globules of vegetable fat and fat of milk fat can be changed. By controlling each particle diameter of the spheres, the fat globules of milk fat can be more easily broken than the fat globules of vegetable fat. Further, when the homogenizing pressure is set to be substantially equal to each other, when the particle size of fat globules of vegetable fat and the particle size of fat globules of milk fat are adjusted to be substantially the same, use as described above. Selecting an emulsifier is an effective method.
【0014】ところで、肪肪球の粒子径は、水中油型乳
化物の乳化安定性やホイップ性に影響を及ぼす。一般
に、均質化圧力の低い乳化物(粒子径は比較的大きくな
り、0.3〜20μmの範囲)は、乳化安定性が低く、
温度変化、振動等の外部環境によって乳化物が増粘や固
化を起す、所謂ボテが生じ易く、またホイップしてもオ
ーバーランの低いものとなり、一方均質化圧力の高い乳
化物(粒子径は比較的小さくなり、0.3〜8μmの範
囲)は、乳化安定性が高い(所謂ボテは生じにくくなる
が)が、ホイップ時間が長くかかり、オーバーランは高
いが、保型性の弱いものになるという性質がある。従っ
て、上記均質化圧力を設定する場合には、乳化安定性や
ホイップ性が良好に保たれるように考慮することが好ま
しい。以上の観点から、水中油型乳化物(A)及び
(B)のそれぞれの乳化物を調製する場合には、下記の
ような脂肪球の粒子径となるように、均質化圧力を設定
することが好ましい。乳脂の脂肪球の粒子径は、1.5
μm〜8.0μmの範囲(好ましくは、2.0μm〜
5.0μmの範囲)、及び植物脂の脂肪球の粒子径は、
0.3μm〜5.0μmの範囲(好ましくは、0.5μ
m〜2.5μmの範囲)となるように調製する(ただ
し、乳脂の脂肪球の粒子径≧植物脂の脂肪球の粒子径の
関係を維持する)。本発明においては、乳脂の脂肪球の
粒子径が、脂肪球の粒子径に対して、1.1〜5倍(さ
らに好ましくは、2.0〜3.0倍)となるように均質
化圧力を設定することが好ましい。なお、乳脂の脂肪球
と植物脂の脂肪球の両方の粒子径を比較的大きな粒子径
(5.0〜8.0μm)に揃えた場合にも、乳味を強く
感じるホイップクリームが得られる。しかし、このよう
な粒子径の範囲に設定すると、前述したように、ボテが
生じ易く、好ましくない。The particle size of the fat globules affects the emulsion stability and whipping property of the oil-in-water emulsion. Generally, an emulsion having a low homogenization pressure (particle size becomes relatively large, 0.3 to 20 μm) has low emulsion stability,
The emulsion tends to thicken or solidify due to external environment such as temperature change and vibration, so-called bloating is likely to occur, and the overrun is low even when whipped, while the emulsion with high homogenization pressure (particle size is compared In the range of 0.3 to 8 μm), the emulsion stability is high (so-called bloating is less likely to occur), but the whipping time is long and the overrun is high, but the shape retention is weak. There is a property. Therefore, when setting the homogenizing pressure, it is preferable to consider so that the emulsion stability and the whipping property are kept good. From the above viewpoints, when preparing each of the oil-in-water emulsions (A) and (B), the homogenizing pressure should be set so that the particle size of fat globules is as follows. Is preferred. The particle size of fat globules of milk fat is 1.5
The range of μm to 8.0 μm (preferably 2.0 μm to
5.0 μm range), and the particle size of fat globules of vegetable fat is
Range of 0.3 μm to 5.0 μm (preferably 0.5 μm
m) to 2.5 μm) (however, the relationship of the particle size of fat globules of milk fat ≧ the particle size of fat globules of vegetable fat is maintained). In the present invention, the homogenizing pressure is such that the particle size of fat globules of milk fat is 1.1 to 5 times (more preferably 2.0 to 3.0 times) the particle size of fat globules. Is preferably set. Even when the particle diameters of both the fat globules of milk fat and the fat globules of vegetable fat are made relatively large (5.0 to 8.0 μm), a whipped cream with a strong milky taste can be obtained. However, if the particle size is set within such a range, as described above, it is easy to cause bloating, which is not preferable.
【0015】上記(III)の工程の混合物の調製は、上記
のように調製された各水中油型乳化物(A)と(B)と
の混合によって達成される。この混合操作では、各乳化
物中の脂肪球が余り壊されることなく、各水中油型乳化
物(A)及び(B)の調製直後の乳化状態が維持される
ように行われ、従って、高速攪拌は必要ない。上記水中
油型乳化物(A)と水中油型乳化物(B)との混合は、
乳化物(A)と乳化物(B)との比(重量比)が、2
0:80〜75:25の範囲で行うことが好ましい。The preparation of the mixture in the above step (III) is accomplished by mixing the respective oil-in-water emulsions (A) and (B) prepared as described above. This mixing operation is performed so that the fat globules in each emulsion are not so much destroyed and the emulsified state of each oil-in-water emulsion (A) and (B) immediately after preparation is maintained. No stirring is required. Mixing of the oil-in-water emulsion (A) and the oil-in-water emulsion (B)
The ratio (weight ratio) of the emulsion (A) and the emulsion (B) is 2
It is preferably performed in the range of 0:80 to 75:25.
【0016】上記(IV)の工程の最終製造物である本発
明の乳化物の調製は、上記で得た混合物を、滅菌、均質
化(再均質化)、冷却、充填、エージングの各処理が施
されることによって達成される。これらの処理におい
て、滅菌処理後の均質化処理(再均質化処理)は、滅菌
により壊された脂肪球を整える処理で、上記乳化物
(A)及び(B)の調製時に行った均質化処理の条件よ
りも低い条件(10〜50kg/cm2 )で行われる。
上記工程(I)〜(IV)で得られる本発明の乳化物は、
植物脂と乳脂との比(重量比)が、植物脂:乳脂=7
5:25〜20:80の範囲にあることが好ましい。な
お、本発明の乳化物の調製は、上記二成分(水中油型乳
化物(A)及び(B))による方法に限定されない。す
なわち、上記工程(I)及び(II)で、植物脂または乳
脂を含む複数の水中油型乳化物(A1 、A2 、・・)お
よび(B1 、B2 、・・)をそれぞれ調製し、これらを
用いて実施してもよい。The preparation of the emulsion of the present invention which is the final product of the above step (IV) is carried out by subjecting the mixture obtained above to sterilization, homogenization (rehomogenization), cooling, filling and aging. It is achieved by being applied. In these treatments, the homogenization treatment (rehomogenization treatment) after the sterilization treatment is a treatment for adjusting fat globules destroyed by the sterilization, and is a homogenization treatment performed when the emulsions (A) and (B) are prepared. The conditions (10 to 50 kg / cm 2 ) lower than the above conditions are used.
The emulsion of the present invention obtained in the above steps (I) to (IV) is
The ratio (weight ratio) of vegetable fat to milk fat is: vegetable fat: milk fat = 7
It is preferably in the range of 5:25 to 20:80. The preparation of the emulsion of the present invention is not limited to the method using the above two components (oil-in-water emulsions (A) and (B)). In other words, prepared in the step (I) and (II), a plurality of oil-in-water emulsion comprising vegetable fat or milk fat (A 1, A 2, ·· ) and (B 1, B 2, ·· ) , respectively However, you may implement using these.
【0017】[0017]
【実施例】以下に、本発明の実施例、及び比較例を記載
し、本発明を更に具体的に説明する。ただし、本発明は
これらの例に限定されない。尚、「%」は重量%を表
す。EXAMPLES Hereinafter, the present invention will be described more specifically by describing Examples of the present invention and Comparative Examples. However, the present invention is not limited to these examples. In addition, "%" represents weight%.
【0018】[実施例1] (水中油型乳化物(A)の調製) 下記配合の油性液(油相)と水性液(水相)を調製した。 (油相)大豆硬化油(融点32℃) 30.0% ヤシ硬化油(融点34℃) 15.0% 大豆レシチン(市販大豆レシチン) 1.0% ショ糖脂肪酸エステル(HLB3) 0.2% (水相)脱脂粉乳 4.0% ヘキサメタリン酸ナトリウム 0.1% ショ糖脂肪酸エステル(HLB11) 0.1% 水 49.60% 上記溶液を混合攪拌して水中油型の予備乳化物を得た。
次いで、この予備乳化物をホモゲナイザー(特殊機化工
業(株)製)で65℃の温度下、100kg/cm2 の
圧力で均質化処理を行い、植物脂の油滴を含む水中油型
乳化物(A)を製造した。[Example 1] (Preparation of oil-in-water emulsion (A)) An oil liquid (oil phase) and an aqueous liquid (water phase) having the following formulations were prepared. (Oil phase) Hardened soybean oil (melting point 32 ° C) 30.0% Hardened coconut oil (melting point 34 ° C) 15.0% Soybean lecithin (commercial soybean lecithin) 1.0% Sucrose fatty acid ester (HLB3) 0.2% (Aqueous phase) skim milk powder 4.0% sodium hexametaphosphate 0.1% sucrose fatty acid ester (HLB11) 0.1% water 49.60% The above solution was mixed and stirred to obtain an oil-in-water type preliminary emulsion. ..
Then, this preliminary emulsion is homogenized with a homogenizer (manufactured by Tokushu Kika Kogyo Co., Ltd.) at a temperature of 65 ° C. and a pressure of 100 kg / cm 2 , and an oil-in-water emulsion containing oil droplets of vegetable fat is obtained. (A) was produced.
【0019】 (水中油型乳化物(B)の調製) 下記配合の油性液(油相)と水性液(水相)を調製した。 (油相)バターオイル 45.0% 大豆レシチン(市販大豆レシチン) 0.2% ショ糖脂肪酸エステル(HLB3) 0.2% (水相)脱脂粉乳 4.0% ヘキサメタリン酸ナトリウム 0.1% 水 50.5% 上記溶液を混合攪拌して水中油型の予備乳化物を得た。
次いで、この予備乳化物をホモゲナイザーで65℃の温
度下、30kg/cm2 の圧力で均質化処理を行い、乳
脂の油滴を含む水中油型乳化物(B)を製造した。(Preparation of Oil-in-Water Emulsion (B)) An oily liquid (oil phase) and an aqueous liquid (water phase) having the following composition were prepared. (Oil phase) Butter oil 45.0% Soy lecithin (commercial soy lecithin) 0.2% Sucrose fatty acid ester (HLB3) 0.2% (Aqueous phase) nonfat dry milk 4.0% Sodium hexametaphosphate 0.1% Water 50.5% The above solution was mixed and stirred to obtain an oil-in-water type preliminary emulsion.
Next, this preliminary emulsion was homogenized with a homogenizer at a temperature of 65 ° C. and a pressure of 30 kg / cm 2 to produce an oil-in-water emulsion (B) containing oil droplets of milk fat.
【0020】(ホイップクリーム用水中油型乳化物の調
製)上記で得られた水中油型乳化物(A)と水中油型乳
化物(B)を、60:40(重量比)の割合で混合し、
混合物を得た。そしてこの混合物を145℃、2秒間U
HT滅菌処理(アルファラバル社製VTIS滅菌装置)
し、70℃にて、20kg/cm2 の圧力で再均質化処
理をした。均質化処理後の乳化物を8℃に冷却後、無菌
充填して、本発明に従うホイップクリーム用水中油型乳
化物を製造した。(Preparation of oil-in-water emulsion for whipped cream) The oil-in-water emulsion (A) and the oil-in-water emulsion (B) obtained above were mixed at a ratio of 60:40 (weight ratio). ,
A mixture was obtained. Then, this mixture is subjected to U at 145 ° C. for 2 seconds.
HT sterilization (Alpha Laval VTIS sterilizer)
Then, rehomogenization treatment was performed at 70 ° C. under a pressure of 20 kg / cm 2 . The homogenized emulsion was cooled to 8 ° C. and then aseptically filled to produce an oil-in-water emulsion for whipped cream according to the present invention.
【0021】[実施例2〜4]上記実施例1において、
水中油型乳化物(A)と水中油型乳化物(B)とを調製
する際の均質化工程における圧力を下記の表1のように
変更した以外は、上記実施例1と同様な方法で、本発明
に従うホイップクリーム用水中油型乳化物を製造した。[Embodiments 2 to 4] In the above Embodiment 1,
In the same manner as in Example 1 above, except that the pressure in the homogenization step in preparing the oil-in-water emulsion (A) and the oil-in-water emulsion (B) was changed as shown in Table 1 below. , An oil-in-water emulsion for whipped cream according to the present invention was prepared.
【0022】[比較例1〜5]上記実施例1において、
水中油型乳化物(A)と水中油型乳化物(B)とを調製
する際の均質化工程における圧力を下記の表1のように
変更した以外は、上記実施例1と同様な方法で、比較用
のホイップクリーム用水中油型乳化物を製造した。上記
実施例(1〜4)及び比較例(1〜5)の水中油型乳化
物の調製工程における上記乳化物(A)及び(B)の均
質化処理条件(kg/cm2)、及び得られた乳化物の粒子径
(μm)は、下記の表1の通りである。Comparative Examples 1 to 5 In the above Example 1,
In the same manner as in Example 1 above, except that the pressure in the homogenization step in preparing the oil-in-water emulsion (A) and the oil-in-water emulsion (B) was changed as shown in Table 1 below. , An oil-in-water emulsion for whipped cream for comparison was produced. Homogenization treatment conditions (kg / cm 2 ) of the emulsions (A) and (B) in the process of preparing the oil-in-water emulsions of the above Examples (1 to 4) and Comparative Examples (1 to 5), and The particle diameter (μm) of the obtained emulsion is as shown in Table 1 below.
【0023】[0023]
【表1】 表1 ──────────────────────────────────── 水中油型乳化物(A) 水中油型乳化物(B) 均質化圧力 粒子径 均質化圧力 粒子径 (kg/cm2) (μm) (kg/cm2) (μm) ──────────────────────────────────── 実施例1 100 0.94 30 3.0 実施例2 60 1.8 30 3.0 実施例3 30 2.7 30 3.0 実施例4 100 0.94 60 1.9 ──────────────────────────────────── 比較例1 60 1.8 60 1.9 比較例2 30 2.7 60 1.9 比較例3 100 0.94 100 0.95 比較例4 60 1.8 100 0.95 比較例5 30 2.7 100 0.95 ────────────────────────────────────[Table 1] Table 1 ──────────────────────────────────── Oil-in-water emulsion (A) Oil-in-water emulsion (B) Homogenization pressure Particle size Homogenization pressure Particle size (kg / cm 2 ) (μm) (kg / cm 2 ) (μm) ─────────────── ────────────────────── Example 1 100 0.94 30 3.0 Example 2 60 1.8 30 3.0 3.0 Example 3 30 2. 7 30 3.0 Example 4 100 0.94 60 1.9 ─────────────────────────────────── Comparative Example 1 60 1.8 60 1.9 Comparative Example 2 30 2.7 60 1.9 Comparative Example 3 100 0.94 100 0.95 Comparative Example 4 60 1.8 100 0.95 Comparative Example 5 30 2.7 100 0.95 ───────── ───────────────────────────
【0024】[ホイップクリーム用水中油型乳化物とし
ての評価]上記で得られた各ホイップクリーム用水中油
型乳化物の乳化(液)安定性を調べ、評価した。 (乳化安定性の評価法)300ミリリットルの三角フラ
スコに200gの上記水中油型乳化物を入れ、20℃に
保温しながら、往復振とう器にて1分間に115ストロ
ークの振とうをかけた時の可塑化に要する時間(ただ
し、上限を24時間とした) また、上記各ホイップクリーム用水中油型乳化物を5℃
で72時間熟成後、縦型ミキサーを用いてホイップして
得たホイップクリームを作る際のホイップ特性(オーバ
ーラン、ホイップ時間)を調べ、評価した。 (ホイップ特性の評価法) (1)ホイップ時間:縦型ミキサーを使用し、700R
PMで1リットルの水中油型乳化物をホイップした時の
最適ホイップ状態になるまで時間 (2)オーバーラン(%):次式で示されるホイップに
よる容積増加割合 更に得られたホイップクリームの風味及び食感を専門パ
ネラー15名による官能テストを行って、評価した。風
味及び食感についての官能テストは、専門パネラー15
名中、12名以上が下記のランク分けに基づいて乳味を
感じたかどうについて調べた。 (食感、風味の評価法) A:乳味を特に強く感じた。 B:乳味を強く感じた。 C:乳味を普通に感じた。 D:乳味を感じない。 以上の結果をまとめて下記の表2に示す。[Evaluation as oil-in-water emulsion for whipped cream] The emulsion (liquid) stability of each of the oil-in-water emulsions for whipped cream obtained above was examined and evaluated. (Emulsification stability evaluation method) When 200 g of the above oil-in-water emulsion was put in a 300 ml Erlenmeyer flask and shaken for 115 strokes per minute with a reciprocal shaker while keeping the temperature at 20 ° C. Of the oil-in-water emulsion for each whipped cream at 5 ° C
After aging for 72 hours, the whipping characteristics (overrun, whipping time) when making a whipped cream obtained by whipped using a vertical mixer were examined and evaluated. (Evaluation method of whipping characteristics) (1) Whipping time: 700R using a vertical mixer
Time until the optimum whipping state is reached when 1 liter of oil-in-water emulsion is whipped with PM (2) Overrun (%): Volume increase rate due to whipping shown by the following formula Further, the flavor and texture of the obtained whipped cream were evaluated by performing a sensory test by 15 expert panelists. Sensory tests for flavor and texture are done by specialized panel 15
Based on the following ranking, 12 or more people among the names examined whether they felt milky taste. (Evaluation method of texture and flavor) A: Milky taste was felt particularly strongly. B: The milky taste was strongly felt. C: Milky taste was felt normally. D: No milky taste is felt. The above results are summarized in Table 2 below.
【0025】[0025]
【表2】 表2 ──────────────────────────────────── (ホイップ特性) 乳化安定性 ホイップ時間 オーバーラン 食感風味の評価 ──────────────────────────────────── 実施例1 24hr 4’18” 124 A 実施例2 24hr 4’03” 113 A 実施例3 8hr 3’06” 96 B 実施例4 24hr 4’22” 131 B ──────────────────────────────────── 比較例1 24hr 4’11” 128 C 比較例2 12hr 3’37” 108 C 比較例3 24hr 15’20” 220 D 比較例4 24hr 9’35” 187 D 比較例5 20hr 4’32” 129 D ────────────────────────────────────[Table 2] Table 2 ──────────────────────────────────── (Whipped characteristics) Emulsion stability Whip Time overrun Evaluation of mouthfeel flavor ──────────────────────────────────── Example 1 24 hr 4 ′ 18 "124 A Example 2 24 hr 4'03" 113 A Example 3 8 hr 3'06 "96 B Example 4 24 hr 4'22" 131 B ───────────────── ──────────────────── Comparative Example 1 24 hr 4′11 ″ 128 C Comparative Example 2 12 hr 3′37 ″ 108 C Comparative Example 3 24 hr 15′20 ″ 220 D Comparative Example 4 24 hr 9'35 "187 D Comparative Example 5 20 hr 4'32" 129 D ────────────────── ───────────────────
【0026】上記表2に示された結果から明らかなよう
に、本発明の方法に従って得られたホイップクリーム用
水中油型乳化物(実施例1〜4)を利用することによ
り、乳味をより強く感じ、風味食感ともに非常に良好な
ホイップクリームが得られる。As is clear from the results shown in Table 2 above, by utilizing the oil-in-water emulsions for whipped cream (Examples 1 to 4) obtained according to the method of the present invention, the milk taste was enhanced. A whipped cream having a very good feeling and flavor and texture is obtained.
【0027】[0027]
【発明の効果】本発明の方法で得られたホイップクリー
ム用水中油型乳化物は、乳化安定性が高く、またホイッ
プクリームを調製する際のホイップ特性も極めて良い。
特に、これを使用して得たホイップクリームは、天然の
生クリームを使用して得たホイップクリームのような強
い乳味感を有し、またその口どけなどから受ける食感、
風味が非常に良好である。The oil-in-water emulsion for whipped cream obtained by the method of the present invention has high emulsion stability and has very good whipped characteristics when preparing a whipped cream.
In particular, the whipped cream obtained using this has a strong milky taste like the whipped cream obtained using a natural fresh cream, and the texture received from its mouth, etc.,
Very good flavor.
Claims (1)
水中油型乳化物と、乳脂を主成分とする油脂の油滴であ
って、その油滴の耐破壊強度が上記の植物脂の油滴の耐
破壊強度に比較して低い油滴を含む水中油型乳化物とを
混合してなるホイップクリーム用水中油型乳化物。1. An oil-in-water emulsion containing oil droplets of oils and fats containing vegetable oil as a main component and oil droplets of oils and fats containing milk oil as a main component, wherein the puncture resistance strength of the oil droplets is the above-mentioned plant. An oil-in-water emulsion for whipped cream, which is prepared by mixing an oil-in-water emulsion containing oil droplets lower in breaking strength than oil oil droplets.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP04105877A JP3112558B2 (en) | 1992-03-31 | 1992-03-31 | Oil-in-water emulsion for whipped cream |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP04105877A JP3112558B2 (en) | 1992-03-31 | 1992-03-31 | Oil-in-water emulsion for whipped cream |
Publications (2)
Publication Number | Publication Date |
---|---|
JPH05276887A true JPH05276887A (en) | 1993-10-26 |
JP3112558B2 JP3112558B2 (en) | 2000-11-27 |
Family
ID=14419171
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP04105877A Expired - Lifetime JP3112558B2 (en) | 1992-03-31 | 1992-03-31 | Oil-in-water emulsion for whipped cream |
Country Status (1)
Country | Link |
---|---|
JP (1) | JP3112558B2 (en) |
Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH10127245A (en) * | 1996-10-30 | 1998-05-19 | Ajinomoto General Foods Inc | Production of emulsified fat having flavor of dairy productlike flavor |
KR100351637B1 (en) * | 1999-04-22 | 2002-09-10 | 동서유지 주식회사 | Compound type whipping cream composition containing milk fat and whey protein |
JP2009254353A (en) * | 2008-03-19 | 2009-11-05 | Kaneka Corp | New fresh cream and method for producing the same |
JP2009278969A (en) * | 2008-04-25 | 2009-12-03 | Kaneka Corp | Foamable oil-in-water type emulsion |
JPWO2010113696A1 (en) * | 2009-03-30 | 2012-10-11 | 不二製油株式会社 | Foamable oil-in-water emulsion and method for producing the same |
WO2013080924A1 (en) * | 2011-12-01 | 2013-06-06 | 株式会社カネカ | Foamable oil-in-water-type emulsified oil or fat composition |
WO2017150384A1 (en) * | 2016-03-01 | 2017-09-08 | 株式会社明治 | Method for producing foamable oil-in-water emulsion |
WO2017154650A1 (en) * | 2016-03-11 | 2017-09-14 | 株式会社 明治 | Foamable oil-in-water type emulsion composition and method for producing same |
JP2017201926A (en) * | 2016-05-11 | 2017-11-16 | 株式会社カネカ | Edible foaming cream and edible whipped cream |
JP2017201927A (en) * | 2016-05-11 | 2017-11-16 | 株式会社カネカ | Edible foaming cream and edible whipped cream |
JP2018088912A (en) * | 2016-11-30 | 2018-06-14 | 和光食品株式会社 | Soybean milk-containing oil-in-water type emulsion, and method for producing the same |
-
1992
- 1992-03-31 JP JP04105877A patent/JP3112558B2/en not_active Expired - Lifetime
Cited By (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH10127245A (en) * | 1996-10-30 | 1998-05-19 | Ajinomoto General Foods Inc | Production of emulsified fat having flavor of dairy productlike flavor |
KR100351637B1 (en) * | 1999-04-22 | 2002-09-10 | 동서유지 주식회사 | Compound type whipping cream composition containing milk fat and whey protein |
JP2009254353A (en) * | 2008-03-19 | 2009-11-05 | Kaneka Corp | New fresh cream and method for producing the same |
JP2009278969A (en) * | 2008-04-25 | 2009-12-03 | Kaneka Corp | Foamable oil-in-water type emulsion |
JPWO2010113696A1 (en) * | 2009-03-30 | 2012-10-11 | 不二製油株式会社 | Foamable oil-in-water emulsion and method for producing the same |
WO2013080924A1 (en) * | 2011-12-01 | 2013-06-06 | 株式会社カネカ | Foamable oil-in-water-type emulsified oil or fat composition |
CN103957721A (en) * | 2011-12-01 | 2014-07-30 | 株式会社钟化 | Foamable oil-in-water-type emulsified oil or fat composition |
JPWO2013080924A1 (en) * | 2011-12-01 | 2015-04-27 | 株式会社カネカ | Foamable oil-in-water emulsified oil composition |
WO2017150384A1 (en) * | 2016-03-01 | 2017-09-08 | 株式会社明治 | Method for producing foamable oil-in-water emulsion |
WO2017154650A1 (en) * | 2016-03-11 | 2017-09-14 | 株式会社 明治 | Foamable oil-in-water type emulsion composition and method for producing same |
JP2017158512A (en) * | 2016-03-11 | 2017-09-14 | 株式会社明治 | Foaming oil-in-water type emulsion composition and manufacturing method therefor |
JP2017201926A (en) * | 2016-05-11 | 2017-11-16 | 株式会社カネカ | Edible foaming cream and edible whipped cream |
JP2017201927A (en) * | 2016-05-11 | 2017-11-16 | 株式会社カネカ | Edible foaming cream and edible whipped cream |
JP2018088912A (en) * | 2016-11-30 | 2018-06-14 | 和光食品株式会社 | Soybean milk-containing oil-in-water type emulsion, and method for producing the same |
Also Published As
Publication number | Publication date |
---|---|
JP3112558B2 (en) | 2000-11-27 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US4515825A (en) | Low fat spread and process for producing same | |
US4555411A (en) | Process for producing a reduced fat spread | |
US4513017A (en) | Process for producing a spread starting from a bimodal dispersed phase | |
JP3112558B2 (en) | Oil-in-water emulsion for whipped cream | |
US3490919A (en) | Fatty emulsions and their preparation | |
US4540593A (en) | Reduced fat spread and a process for the production thereof | |
EP0098663B1 (en) | Process for the production of a reduced fat spread | |
JP6628606B2 (en) | Whipped compound cream containing fresh cream | |
RU2253273C2 (en) | Food product, method for obtaining food product and using it as fat for frying | |
JPS594107B2 (en) | Foaming oil-in-water emulsified fat | |
EP0139398B1 (en) | Margarine products or spreads and method for their manufacture | |
US11412751B2 (en) | Edible aerated water-in-oil emulsions | |
JP2000333602A (en) | Oil-in-water type emulsified oil and fat composition | |
JP3105636B2 (en) | Oil-in-water emulsion for whipped cream | |
JPH07177858A (en) | Production of oil-in-water type emulsion | |
JP2008035743A (en) | Foamable oil-in-water type emulsified oil and fat composition | |
EP0347007B1 (en) | Cream, churned margarine-like product made therefrom and method of manufacturing them | |
EP3376876A1 (en) | Process for preparing fat continuous emulsions low in fat | |
JPH02182149A (en) | Cream, product made by churning milk therefrom, and making thereof | |
JPH07177857A (en) | Production of oil-in-water type emulsion | |
JP6774216B2 (en) | Edible foaming cream and edible whipped cream | |
JPWO2004041002A1 (en) | Low oil foaming oil-in-water emulsion | |
JPH07108A (en) | Oil-in-water type emulsion for preparing whip cream | |
JPH08256716A (en) | Oil-in-water type emulsion for low-oil whipping cream and its production | |
JP3526803B2 (en) | Oil-in-water emulsified fat composition |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20000822 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20080922 Year of fee payment: 8 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20080922 Year of fee payment: 8 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20090922 Year of fee payment: 9 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20090922 Year of fee payment: 9 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20100922 Year of fee payment: 10 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20110922 Year of fee payment: 11 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20120922 Year of fee payment: 12 |
|
EXPY | Cancellation because of completion of term | ||
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20120922 Year of fee payment: 12 |