JPH0525278B2 - - Google Patents
Info
- Publication number
- JPH0525278B2 JPH0525278B2 JP61030862A JP3086286A JPH0525278B2 JP H0525278 B2 JPH0525278 B2 JP H0525278B2 JP 61030862 A JP61030862 A JP 61030862A JP 3086286 A JP3086286 A JP 3086286A JP H0525278 B2 JPH0525278 B2 JP H0525278B2
- Authority
- JP
- Japan
- Prior art keywords
- aluminum
- cylinder
- lubricant
- vtr
- molded product
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- -1 alkyl ether phosphoric acid ester Chemical class 0.000 claims description 17
- 239000000314 lubricant Substances 0.000 claims description 17
- 239000010687 lubricating oil Substances 0.000 claims description 15
- 238000010273 cold forging Methods 0.000 claims description 13
- 230000002209 hydrophobic effect Effects 0.000 claims description 13
- 150000002903 organophosphorus compounds Chemical class 0.000 claims description 10
- 150000003008 phosphonic acid esters Chemical class 0.000 claims description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 16
- 229910052782 aluminium Inorganic materials 0.000 description 15
- 238000005520 cutting process Methods 0.000 description 12
- 229910000838 Al alloy Inorganic materials 0.000 description 10
- 150000002894 organic compounds Chemical class 0.000 description 10
- 239000000463 material Substances 0.000 description 8
- 238000000034 method Methods 0.000 description 8
- 239000003921 oil Substances 0.000 description 8
- 239000000344 soap Substances 0.000 description 8
- 239000000956 alloy Substances 0.000 description 7
- 238000006243 chemical reaction Methods 0.000 description 6
- 239000007788 liquid Substances 0.000 description 6
- 238000003754 machining Methods 0.000 description 6
- 239000002245 particle Substances 0.000 description 6
- 206010010904 Convulsion Diseases 0.000 description 5
- 229910052751 metal Inorganic materials 0.000 description 5
- 239000002184 metal Substances 0.000 description 5
- 239000004033 plastic Substances 0.000 description 5
- 229920003023 plastic Polymers 0.000 description 5
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
- 239000000654 additive Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 238000005242 forging Methods 0.000 description 3
- 230000001050 lubricating effect Effects 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000002480 mineral oil Substances 0.000 description 3
- 235000010446 mineral oil Nutrition 0.000 description 3
- 229910052698 phosphorus Inorganic materials 0.000 description 3
- 239000011574 phosphorus Substances 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 230000003746 surface roughness Effects 0.000 description 3
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 2
- 230000001680 brushing effect Effects 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 238000007598 dipping method Methods 0.000 description 2
- ILRSCQWREDREME-UHFFFAOYSA-N dodecanamide Chemical compound CCCCCCCCCCCC(N)=O ILRSCQWREDREME-UHFFFAOYSA-N 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 239000002932 luster Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- LYRFLYHAGKPMFH-UHFFFAOYSA-N octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(N)=O LYRFLYHAGKPMFH-UHFFFAOYSA-N 0.000 description 2
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- JPGXOMADPRULAC-UHFFFAOYSA-N 1-[butoxy(butyl)phosphoryl]oxybutane Chemical compound CCCCOP(=O)(CCCC)OCCCC JPGXOMADPRULAC-UHFFFAOYSA-N 0.000 description 1
- CXPIOTOKMJNFSA-UHFFFAOYSA-N 12-hydroxy-n-[6-(12-hydroxyoctadecanoylamino)hexyl]octadecanamide Chemical compound CCCCCCC(O)CCCCCCCCCCC(=O)NCCCCCCNC(=O)CCCCCCCCCCC(O)CCCCCC CXPIOTOKMJNFSA-UHFFFAOYSA-N 0.000 description 1
- ALDZNWBBPCZXGH-UHFFFAOYSA-N 12-hydroxyoctadecanamide Chemical compound CCCCCCC(O)CCCCCCCCCCC(N)=O ALDZNWBBPCZXGH-UHFFFAOYSA-N 0.000 description 1
- IRPGOXJVTQTAAN-UHFFFAOYSA-N 2,2,3,3,3-pentafluoropropanal Chemical compound FC(F)(F)C(F)(F)C=O IRPGOXJVTQTAAN-UHFFFAOYSA-N 0.000 description 1
- JJJOZVFVARQUJV-UHFFFAOYSA-N 2-ethylhexylphosphonic acid Chemical compound CCCCC(CC)CP(O)(O)=O JJJOZVFVARQUJV-UHFFFAOYSA-N 0.000 description 1
- PZRWFKGUFWPFID-UHFFFAOYSA-N 3,9-dioctadecoxy-2,4,8,10-tetraoxa-3,9-diphosphaspiro[5.5]undecane Chemical compound C1OP(OCCCCCCCCCCCCCCCCCC)OCC21COP(OCCCCCCCCCCCCCCCCCC)OC2 PZRWFKGUFWPFID-UHFFFAOYSA-N 0.000 description 1
- KLZUFWVZNOTSEM-UHFFFAOYSA-K Aluminum fluoride Inorganic materials F[Al](F)F KLZUFWVZNOTSEM-UHFFFAOYSA-K 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- PHQBTXISHUNQQN-UHFFFAOYSA-N OP(O)OP(O)O.C(CCCCCCCC)C(C(C(O)(C1=CC=CC=C1)CCCCCCCCC)(CO)CO)O Chemical compound OP(O)OP(O)O.C(CCCCCCCC)C(C(C(O)(C1=CC=CC=C1)CCCCCCCCC)(CO)CO)O PHQBTXISHUNQQN-UHFFFAOYSA-N 0.000 description 1
- MOABYHZDQQELLG-UHFFFAOYSA-N OP(O)OP(O)O.C(CCCCCCCCCCCC)C(O)(C(CO)(CO)CO)CCCCCCCCCCCCC Chemical compound OP(O)OP(O)O.C(CCCCCCCCCCCC)C(O)(C(CO)(CO)CO)CCCCCCCCCCCCC MOABYHZDQQELLG-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 229920002396 Polyurea Polymers 0.000 description 1
- TVIPECTUCRNDNZ-UHFFFAOYSA-M [Na+].NC(=O)C1=CC=C(C([O-])=O)C=C1 Chemical compound [Na+].NC(=O)C1=CC=C(C([O-])=O)C=C1 TVIPECTUCRNDNZ-UHFFFAOYSA-M 0.000 description 1
- YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- 239000002199 base oil Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 239000000306 component Substances 0.000 description 1
- 239000008358 core component Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 150000005690 diesters Chemical class 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000010696 ester oil Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- ALBYIUDWACNRRB-UHFFFAOYSA-N hexanamide Chemical compound CCCCCC(N)=O ALBYIUDWACNRRB-UHFFFAOYSA-N 0.000 description 1
- 229910000040 hydrogen fluoride Inorganic materials 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 229940116335 lauramide Drugs 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- FPLIHVCWSXLMPX-UHFFFAOYSA-M lithium 12-hydroxystearate Chemical compound [Li+].CCCCCCC(O)CCCCCCCCCCC([O-])=O FPLIHVCWSXLMPX-UHFFFAOYSA-M 0.000 description 1
- HGPXWXLYXNVULB-UHFFFAOYSA-M lithium stearate Chemical compound [Li+].CCCCCCCCCCCCCCCCCC([O-])=O HGPXWXLYXNVULB-UHFFFAOYSA-M 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- CWQXQMHSOZUFJS-UHFFFAOYSA-N molybdenum disulfide Chemical compound S=[Mo]=S CWQXQMHSOZUFJS-UHFFFAOYSA-N 0.000 description 1
- 229910052982 molybdenum disulfide Inorganic materials 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- XPLOQMVUXWZLET-UHFFFAOYSA-N n-hexylphosphonate ethyl ester Chemical compound CCCCCC[P@@](O)(=O)OCC XPLOQMVUXWZLET-UHFFFAOYSA-N 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 229920001515 polyalkylene glycol Polymers 0.000 description 1
- 229920001083 polybutene Polymers 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- RYYKJJJTJZKILX-UHFFFAOYSA-M sodium octadecanoate Chemical compound [Na+].CCCCCCCCCCCCCCCCCC([O-])=O RYYKJJJTJZKILX-UHFFFAOYSA-M 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 229940037312 stearamide Drugs 0.000 description 1
- QQBLOZGVRHAYGT-UHFFFAOYSA-N tris-decyl phosphite Chemical compound CCCCCCCCCCOP(OCCCCCCCCCC)OCCCCCCCCCC QQBLOZGVRHAYGT-UHFFFAOYSA-N 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 238000005491 wire drawing Methods 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Landscapes
- Forging (AREA)
- Lubricants (AREA)
Description
〔産業上の利用分野〕
本発明は、VTR用シリンダーに係り、特にア
ルミニウムあるいはアルミニウム合金材で冷間鍛
造加工されるビデオテープレコーダ用シリンダー
に関する。
〔従来の技術〕
アルミニウムあるいはアルミニウム合金は、ビ
デオテープレコーダ用シリンダーに限らず、軽量
で外観品質が良いことから家電品、自動車、通信
器、光学装置などの部品あるいはサツシ、食缶等
に広く用いられるている。これら部品の多くは生
産性の高い鍛造加工法によつて製造されている。
特に、経済性、部品の寸法精度等の点でメリツト
の大きい冷間鍛造による加工が主流になりつつあ
る。一般にこれらの成型品は外観が重視されるた
め寸法精度、表面状態、光沢性等に対する要求が
高く、潤滑剤に対して高性能のものが要求され
る。
従来、アルミニウムあるいはアルミニウム合金
等の冷間鍛造加工では、鉱油をベース油とし、こ
れに脂肪酸、脂肪酸エステル、高級エステル等の
油性向上剤やトリクレジルホスフアイト、トリデ
シルホスフアイト等の燐酸エステル系極圧剤また
はグラフアイト、二硫化モリブデン等の固体潤滑
剤を配合した潤滑油が用いられている。
これらの潤滑油はいずれも変形量が少ない低加
工度の圧延、伸線加工等に適用されるが、ビデオ
テープレコーダの心臓部品であるシリンダーは、
複雑な形状の超精密部品である。シリンダーの形
状は、複雑で塑性変形量が極めて大きいため塑性
変形がスムーズに行われず偏肉や割れが発生しや
すい。塑性変形がスムーズに行われた場合でも加
工面では、高面圧と高温となり潤滑油の潤滑性
(摩擦係数)や耐荷重性、耐熱性が十分でないと
変形がスムーズに行われず所定寸法の成型品が得
られないばかりでなく表面の荒れ、片肉、割れや
焼付き等が発生し正常な成型品が得られない場合
が多い。
このため塑性変形をよりスムーズにするため金
型及びアルミニウム素材を加熱して成形する温間
鍛造加工法が広く採用されているが所定寸法の成
形品が得られない。
一方、冷間鍛造加工でシリンダーを成形するに
は、アルミニウム素材表面を弗化水素、けい弗化
アルミ等で化成皮膜処理を施した後、その表面に
金属石鹸皮膜処理する潤滑処理剤を被覆してから
加工する方法がある。この場合の潤滑剤は、加工
度が高い場合や複雑な形状の加工品に対しても焼
付けや表面の荒れ、片肉、割れ等が無く正常な成
形品が得られる。
しかし、上述潤滑処理剤によつて成形品表面は
濃灰色の皮膜で覆われ、しかもこの皮膜は強固に
付着しているため、外観品質が悪くアルミニウム
特有の光沢を得るためには機械による切削加工が
必要である。また、加工の際、脱落した潤滑処理
剤が金型内に残留堆積するため成形品の寸法精度
が低下する。
このように良好な成形品が得られたとしても表
面状態が悪く切削加工による機械仕上げによる加
工部分が多く、多大な労力と時間を要するので生
産コストが高くなる。
アルミニウムあるいはアルミニウム合金材の冷
間鍛造においては生産コストの低減から材料費、
人件費などの削減が強くなつてきており、出来れ
ば鍛造後、機械加工による切削加工仕上げを極力
省略できるような高い寸法精度で外観品質のよい
成形品を得たいという要望が強くなつてきてい
る。
〔発明が解決しようとする課題〕
上記の従来技術は、それぞれ特長を有するもの
であるが、VTR用シリンダーのように塑性変形
が大きく新生面の出現や変形熱等が高い加工品に
おいては液体潤滑剤の場合、寸法精度、耐焼付き
性、表面の面荒れや光沢性に問題がある。また、
化成皮膜処理+金属石鹸皮膜処理においては、煩
雑な処理工程でかつ、廃液処理など多くの付随作
業を有し、多大な労力と経費を必要とする。その
上成形品表面は濃い灰色となりアルミニウム特有
の光沢が得られないため、機械加工が必要といつ
た問題がある。
本発明の目的は、液体潤滑剤の利点をいかし、
化成皮膜処理+金属石鹸皮膜処理などを必要とせ
ず、単にアルミニウムあるいはアルミニウム合金
素材表面あるいは金型面に液体潤滑剤を公知の方
法で供給するのみで機械加工による切削加工部分
の大幅な削減を図つた冷間鍛造加工によるVTR
用シリンダーの成形品を提供することにある。
〔課題を解決するための手段〕
上記目的を達成するために、本発明では、
VTR用シリンダーにおいて、VTRシリンダーを
冷間鍛造加工する際に、有機リン化合物としてポ
リオキシアルキレンアルキルエーテルの燐酸エス
テル、アルキルペンタエリスリトールジホスフア
イト、ホスホン酸エステルから選ばれた1種以上
と、滑剤質を有する粉末状有機化合物から選ばれ
る1種以上とを含有する疎水性液体潤滑剤を用
い、該疎水性液体潤滑剤が外表面に形成されてい
ることを特徴とするVTR用シリンダー、とした
ものである。
本発明のアルミニウムあるいはアルミニウム合
金材からなるVTR用シリンダーの冷間鍛造加工
によるVTR用シリンダーの成形品は、下記の有
機リン化合物から選ばれた1種以上と滑剤質の粉
末状有機化合物の群より選ばれる1種以上とを疎
水性液体に含有させた疎水性液体潤滑剤をアルミ
ニウムあるいはアルミニウム合金素材表面あある
いは金型加工面にハケ塗り、スプレー、浸漬など
の公知の方法で供給するのみで、加工時の焼付き
を防止し、VTR用シリンダーの成形品表面の外
観品質(特に光沢性)や寸法精度を大幅に向上さ
せ機械加工での切削加工部分を大幅に削減したも
のである。これによつて材料費や切削工程の削
減、人件費の低減によりVTR用シリンダーの低
コスト化に多きな効果がある。
本発明における有機リン化合物としては、ポリ
オキシエチレン、ポリオキシプロピレンまたは、
ポリオキシブチレン誘導体の末端をリン酸エステ
ル化したポリオキシアルキレンアルキルエーテル
燐酸、アルキルペンタエリスリトールジホスフア
イト、ホスホン酸エステルなどである。これら有
機リン化合物の具体例としては、ポリオキシエチ
レンラウリルエーテル燐酸エステル、ポリオキシ
エチレントリデシルエーテル燐酸エステル、ポリ
オキシエチレンノニルフエニルエーテル燐酸エス
テル、ジトリデシルペンタエリスリトール・ジホ
スフアイト、ジステアリルペンタエリスリトー
ル・ジホスフアイト、ジノニルフエニルペンタエ
リスリトール・ジホスフアイト、ジブチル・ブチ
ルホスホネート、ジ(2−エチルヘキシル)2−
エチルヘキシルホスホネート、2−エチルヘキシ
ルホスホン酸モノマーエチルヘキシルエステルな
ど例示される。
また、滑剤質の粉末状有機化合物としては、粒
径0.5〜300μmのステアリン酸リチウム、12ヒド
ロキシステアリン酸リチウム、アルミニウムコン
プレツクス石鹸、リチウムコプレツクス石鹸等の
金属石鹸やポリウレア、ナトリウムテレフタラメ
ートなどの非石鹸、ヘキサンアミド、ラウリンア
ミド、ステアリンアミド、N−ヒドロキシエチル
12−ヒドロキシステアリンアミド、N,N′−ヘ
キサメチレンビス12−ヒドロキシステアリンアミ
ドなどの合成ワツクスが例示される。
上記有機リン化合物及び滑剤質の粉末状有機化
合物の添加剤を含有させる疎水性液体としては、
有機リン化合物、滑剤質の粉末状有機化合物を摩
擦面に供給できる物であれば良い。一般には、鉱
油または合成油が使用できる。合成油としては、
αオレフイン油、モノまたはジエステル油、ポリ
オールエステル油、ポリブテン油、ポリアルキレ
ングリコール油、フツ素油、シリコーン油等が例
示されその性状は、加工条件や作業条件に応じて
適宜決めることが出来るが、概ね40℃における粘
度が5mm2/s(cSt)以上が好ましい。
疎水性液体に配合される上記有機リン化合物、
滑剤質の粉末状有機化合物の配合割合及び、粒径
の大きさは、加工率、加工形状、加工温度等に応
じて任意に選択すればよいが、添加剤の合計が通
常5〜20重量%、そして疎水性液体80〜95重量%
が好ましい。
本発明に配合される有機リン化合物と滑剤質の
粉末状有機化合物との配合量が極端に少ない場合
は摩擦面に十分な潤滑皮膜が形成れされないため
VTR用シリンダーの外観品質や寸法精度の成形
品が得られない。加工条件によつては焼付きを起
こす場合がある。また、多すぎもそれ以上の効果
が認められないので上記した配合割合が好まし
い。
滑剤質の粒径は、加工条件によつて異なるが、
一般に粒径が大きくなると粒子の展着層が厚くな
り成形品表面の光沢性が低下する。光沢性を向上
させる場合、小さな粒子を用いると良い。
本発明の冷間鍛造加工によるVTR用シリンダ
ーの成形品は、上記添加剤配合の疎水性液体潤滑
剤をハケ塗り、スプレー、浸漬などの公知の方法
によつて冷間鍛造加工しようとするアルミニウム
あるいはアルミニウム合金素材の表面あるいは金
型加工面に供給することによつて目的を達成でき
る。
〔実施例〕
以下、本発明の一実施例を示すが、本発明はこ
の実施例に限定されない。
実施例 1
40℃における粘度が10mm2/s(cSt)の疎水性液
体の鉱油に有機リン化合物及び粉末状有機化合物
の滑剤質を第1表に示す配合割合の疎水性液体潤
滑剤を第1図に示す素材形状のJIS規格A2218ア
ルミニウム合金材表面にスプレー方式で塗布した
後、成形用金型に挿入して冷間鍛造加工で第2図
に示す形状のビデオテープレコーダー用シリンダ
ーを500個成形した。成形品の表面状態(光沢
性)、寸法精度および切削加工量を測定した。
第1表の実験例1〜19のうち、実験例1〜6は
リン化合物又は粉末状有機化合物をそれぞれ単独
で用いた例であり、また、実験例16〜19は本発明
で規定した以外のリン化合物を用いた例であり、
本発明の実施例は実験例7〜15である。
その測定結果を第2表に示す。本発明の実施例
は、加工後の表面には添加剤の反応によつて生成
した潤滑膜が形成され、焼付きの発生はなく正常
な成形品が得られ表面状態(光沢性)は鏡面で寸
法精度も良好であつた。また、機械加工による切
削加工量も極めて少ない。しかし、亜リン酸エス
テル及びリン酸エステルを配合した疎水性液体潤
滑剤は、スジ状のキズが無数見られ焼付き寸前で
あつた。成形品の表面状態(光沢性)はやや良好
であつたが、片肉が見られ寸法精度が悪く、切削
加工量も多い。
シリンダーの外周面1は磁気テープと接するた
め、切削研磨によつて鏡面に仕上げが必要である
が、それ以外2,3,4,5のところは、鏡面で
寸法精度が良好であれは切削研磨せず反応皮膜を
形成したままでもそのまま使用できる。
比較例 1
潤滑油:鉱油
比較例 2
潤滑剤皮膜組成(化成皮膜処理)
フツ化アルミ皮膜+金属石鹸(主成分:ステア
リン酸ソーダ)
[Industrial Field of Application] The present invention relates to a cylinder for a VTR, and more particularly to a cylinder for a videotape recorder that is cold-forged from aluminum or an aluminum alloy material. [Prior Art] Aluminum or aluminum alloys are widely used not only for cylinders for video tape recorders, but also for parts of home appliances, automobiles, communications devices, optical devices, etc., as well as for sashes, food cans, etc. due to their light weight and good appearance quality. It's being done. Many of these parts are manufactured using the highly productive forging process.
In particular, cold forging is becoming mainstream as it has great advantages in terms of economy, dimensional accuracy of parts, etc. In general, appearance of these molded products is important, so there are high requirements for dimensional accuracy, surface condition, gloss, etc., and high performance lubricants are required. Conventionally, in cold forging of aluminum or aluminum alloys, mineral oil is used as a base oil, and oiliness improvers such as fatty acids, fatty acid esters, and higher esters, and phosphate esters such as tricresyl phosphite and tridecyl phosphite are added to this oil. Lubricating oils containing extreme pressure agents or solid lubricants such as graphite and molybdenum disulfide are used. All of these lubricants are used for low-deformation rolling, wire drawing, etc., where the amount of deformation is small, but the cylinder, which is the core component of a video tape recorder,
It is an ultra-precision part with a complex shape. The shape of the cylinder is complex and the amount of plastic deformation is extremely large, so plastic deformation does not occur smoothly and uneven thickness and cracks are likely to occur. Even if plastic deformation occurs smoothly, the surface pressure and high temperature will be high on the machined surface, and if the lubricating oil does not have sufficient lubricity (friction coefficient), load capacity, and heat resistance, deformation will not occur smoothly and it will not be possible to form the specified dimensions. In many cases, not only the molded product cannot be obtained, but also a normal molded product cannot be obtained due to surface roughness, partial thickness, cracks, and seizures. For this reason, a warm forging method in which a mold and an aluminum material are heated and formed is widely adopted in order to make plastic deformation smoother, but a molded product of a predetermined size cannot be obtained. On the other hand, in order to form a cylinder by cold forging, the surface of the aluminum material is treated with a chemical conversion film using hydrogen fluoride, aluminum silicate, etc., and then the surface is coated with a lubricating agent that forms a metal soap film. There is a way to process it after that. The lubricant used in this case allows a normal molded product to be obtained without baking, surface roughness, partial thickness, cracks, etc. even when the processing degree is high or the processed product has a complicated shape. However, the surface of the molded product is covered with a dark gray film due to the above-mentioned lubricating agent, and this film is firmly attached, resulting in poor appearance quality and requiring mechanical cutting to obtain the luster unique to aluminum. is necessary. Furthermore, during processing, the lubricating agent that falls off remains and accumulates in the mold, reducing the dimensional accuracy of the molded product. Even if such a good molded product is obtained, the surface condition is poor and many parts are mechanically finished by cutting, which requires a great deal of labor and time, resulting in high production costs. Cold forging of aluminum or aluminum alloy materials reduces production costs, reduces material costs,
There is a growing need to reduce labor costs, and there is a growing desire to obtain molded products with high dimensional accuracy and good appearance quality, so that if possible, cutting and finishing by machining after forging can be omitted as much as possible. . [Problems to be Solved by the Invention] The above-mentioned conventional technologies each have their own advantages, but liquid lubricants are not suitable for processed products that undergo large plastic deformation such as cylinders for VTRs and are subject to the appearance of new surfaces and high heat of deformation. In this case, there are problems with dimensional accuracy, seizure resistance, surface roughness, and gloss. Also,
The chemical conversion film treatment + metal soap film treatment is a complicated treatment process and involves many incidental operations such as waste liquid treatment, requiring a great deal of labor and expense. Furthermore, the surface of the molded product becomes dark gray and does not have the luster characteristic of aluminum, so machining is required. The purpose of the present invention is to take advantage of the advantages of liquid lubricants,
There is no need for chemical conversion film treatment + metal soap film treatment, etc., and by simply supplying liquid lubricant to the aluminum or aluminum alloy material surface or mold surface using a known method, the number of cutting parts by machining can be significantly reduced. VTR made by cold forging
Our objective is to provide molded cylinders for [Means for Solving the Problem] In order to achieve the above object, the present invention includes the following:
When cold forging VTR cylinders, one or more organic phosphorus compounds selected from polyoxyalkylene alkyl ether phosphoric acid esters, alkyl pentaerythritol diphosphites, and phosphonic acid esters, and a lubricant A cylinder for a VTR, characterized in that the hydrophobic liquid lubricant is formed on the outer surface of the cylinder, using a hydrophobic liquid lubricant containing at least one kind selected from powdered organic compounds having the following: It is. The molded product of the VTR cylinder made by cold forging of the VTR cylinder made of aluminum or aluminum alloy material of the present invention is made of one or more selected from the following organic phosphorus compounds and a powdered organic compound with lubricant properties. Simply supplying a hydrophobic liquid lubricant containing one or more selected lubricants in a hydrophobic liquid to the surface of aluminum or aluminum alloy material or the machined surface of a mold using a known method such as brushing, spraying, or dipping. This prevents seizure during machining, greatly improves the appearance quality (especially gloss) and dimensional accuracy of the molded product surface of VTR cylinders, and greatly reduces the amount of cutting required during machining. This has the effect of reducing the cost of VTR cylinders by reducing material costs, cutting processes, and labor costs. As the organic phosphorus compound in the present invention, polyoxyethylene, polyoxypropylene or
These include polyoxyalkylene alkyl ether phosphoric acid, alkyl pentaerythritol diphosphite, and phosphonic acid ester, which are polyoxybutylene derivatives whose ends are phosphoric acid esterified. Specific examples of these organic phosphorus compounds include polyoxyethylene lauryl ether phosphate, polyoxyethylene tridecyl ether phosphate, polyoxyethylene nonyl phenyl ether phosphate, ditridecyl pentaerythritol diphosphite, and distearyl pentaerythritol diphosphite. , dinonylphenyl pentaerythritol diphosphite, dibutyl butylphosphonate, di(2-ethylhexyl)2-
Examples include ethylhexylphosphonate and 2-ethylhexylphosphonic acid monomer ethylhexyl ester. Powdered organic compounds with lubricant properties include lithium stearate with a particle size of 0.5 to 300 μm, lithium 12-hydroxystearate, metal soaps such as aluminum complex soap and lithium complex soap, polyurea, and sodium terephthalamate. non-soap, hexanamide, lauramide, stearamide, N-hydroxyethyl
Examples include synthetic waxes such as 12-hydroxystearamide and N,N'-hexamethylenebis12-hydroxystearamide. The hydrophobic liquid containing the above-mentioned organic phosphorus compound and lubricant powder organic compound additives is as follows:
Any material that can supply an organic phosphorus compound or a lubricating powdery organic compound to the friction surface may be used. Generally, mineral or synthetic oils can be used. As a synthetic oil,
Examples include α-olefin oil, mono- or diester oil, polyol ester oil, polybutene oil, polyalkylene glycol oil, fluorine oil, silicone oil, etc. The properties can be determined as appropriate depending on processing conditions and working conditions, but generally speaking The viscosity at 40° C. is preferably 5 mm 2 /s (cSt) or more. The above organic phosphorus compound blended into the hydrophobic liquid,
The blending ratio and particle size of the lubricant powder organic compound may be arbitrarily selected depending on the processing rate, processing shape, processing temperature, etc., but the total amount of additives is usually 5 to 20% by weight. , and hydrophobic liquid 80-95% by weight
is preferred. If the amount of the organic phosphorus compound and lubricant powder organic compound blended in the present invention is extremely small, a sufficient lubricating film will not be formed on the friction surface.
It is not possible to obtain a molded product with good appearance quality and dimensional accuracy for VTR cylinders. Depending on the processing conditions, seizure may occur. Further, if the amount is too large, no further effect will be observed, so the above-mentioned blending ratio is preferable. The particle size of the lubricant varies depending on the processing conditions, but
Generally, as the particle size increases, the spread layer of the particles becomes thicker and the glossiness of the surface of the molded product decreases. When improving gloss, it is better to use small particles. The molded product of a cylinder for a VTR produced by cold forging of the present invention is produced by applying a hydrophobic liquid lubricant containing the above-mentioned additives to aluminum or aluminum to be cold forged by a known method such as brushing, spraying, or dipping. The purpose can be achieved by supplying it to the surface of the aluminum alloy material or the processed surface of the mold. [Example] An example of the present invention will be shown below, but the present invention is not limited to this example. Example 1 A hydrophobic liquid lubricant was added to hydrophobic liquid mineral oil with a viscosity of 10 mm 2 /s (cSt) at 40°C, containing an organic phosphorus compound and a powdered organic compound in the proportions shown in Table 1. After coating the surface of the JIS standard A2218 aluminum alloy material in the shape shown in the figure using a spray method, it is inserted into a mold and cold forged to form 500 cylinders for video tape recorders in the shape shown in Figure 2. did. The surface condition (gloss), dimensional accuracy, and cutting amount of the molded product were measured. Among Experimental Examples 1 to 19 in Table 1, Experimental Examples 1 to 6 are examples in which a phosphorus compound or a powdered organic compound is used alone, and Experimental Examples 16 to 19 are examples in which a phosphorus compound or a powdered organic compound is used alone. This is an example using a phosphorus compound,
Examples of the present invention are Experimental Examples 7 to 15. The measurement results are shown in Table 2. In the example of the present invention, a lubricating film generated by the reaction of additives is formed on the surface after processing, and a normal molded product is obtained without seizure, and the surface condition (gloss) is mirror-like. The dimensional accuracy was also good. Additionally, the amount of cutting required by machining is extremely small. However, the hydrophobic liquid lubricant containing phosphite and phosphate ester had numerous streak-like scratches and was on the verge of seizing. Although the surface condition (gloss) of the molded product was somewhat good, there was some thickness, poor dimensional accuracy, and a large amount of cutting. Since the outer circumferential surface 1 of the cylinder is in contact with the magnetic tape, it needs to be finished to a mirror surface by cutting and polishing, but other parts 2, 3, 4, and 5 can be cut and polished if they are mirror-finished and have good dimensional accuracy. It can be used as is without forming a reaction film. Comparative example 1 Lubricating oil: Mineral oil Comparative example 2 Lubricant film composition (chemical conversion film treatment) Aluminum fluoride film + metal soap (main component: sodium stearate)
【表】【table】
【表】【table】
【表】【table】
以上の結果からVTR用シリンダーを冷間鍛造
加工する際、本発明の液体潤滑剤を用いて冷間鍛
造加工を行うと表面性状、寸法精度が極めて良好
であり切削加工が低減できる。更に、材料費、人
件費などの切削と生産コスト低減に大きな効果が
ある。
From the above results, when cold forging cylinders for VTRs, if the liquid lubricant of the present invention is used for cold forging, the surface quality and dimensional accuracy are extremely good, and cutting work can be reduced. Furthermore, it has a great effect on reducing cutting and production costs such as material costs and labor costs.
第1図は冷間鍛造用アルミニウム素材の断面
図、第2図は冷間鍛造加工によつて成形した
VTR用シリンダーの断面図である。
Figure 1 is a cross-sectional view of an aluminum material for cold forging, and Figure 2 is a cross-sectional view of the aluminum material formed by cold forging.
FIG. 3 is a sectional view of a VTR cylinder.
Claims (1)
ーを冷間鍛造加工する際に、有機リン化合物とし
てポリオキシアルキレンアルキルエーテルの燐酸
エステル、アルキルペンタエリスリトールジホス
フアイト、ホスホン酸エステルから選ばれた1種
以上と、滑剤質を有する粉末状有機化合物から選
ばれる1種以上とを含有する疎水性液体潤滑剤を
用い、該疎水性液体潤滑剤が外表面に形成されて
いることを特徴とするVTR用シリンダー。1. When cold forging a VTR cylinder, one or more organic phosphorus compounds selected from polyoxyalkylene alkyl ether phosphoric acid ester, alkyl pentaerythritol diphosphite, and phosphonic acid ester, and a lubricant are used. 1. A cylinder for a VTR, characterized in that the hydrophobic liquid lubricant is formed on the outer surface of the cylinder, and the hydrophobic liquid lubricant is formed on the outer surface of the cylinder.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP3086286A JPS62190292A (en) | 1986-02-17 | 1986-02-17 | Cylinder for vtr |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP3086286A JPS62190292A (en) | 1986-02-17 | 1986-02-17 | Cylinder for vtr |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS62190292A JPS62190292A (en) | 1987-08-20 |
JPH0525278B2 true JPH0525278B2 (en) | 1993-04-12 |
Family
ID=12315534
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP3086286A Granted JPS62190292A (en) | 1986-02-17 | 1986-02-17 | Cylinder for vtr |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS62190292A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0992441A (en) * | 1995-09-22 | 1997-04-04 | Ngk Spark Plug Co Ltd | Manufacture of side electrode for spark plug |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2002149099A (en) * | 2000-11-13 | 2002-05-22 | Tanaka:Kk | Bulletin board |
CN103897780B (en) * | 2014-03-12 | 2015-10-21 | 贵州旭阳石化科技有限公司 | Wireline antioxygen wearing face barrier cream |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5436303A (en) * | 1977-08-27 | 1979-03-17 | Nippon Keikinzoku Sougou Kenki | Lubricant for processing aluminium |
JPS5665095A (en) * | 1979-11-02 | 1981-06-02 | Nikkei Giken:Kk | Lubricating oil for cold rolling of aluminum |
JPS59126498A (en) * | 1983-01-06 | 1984-07-21 | Nippon Light Metal Co Ltd | Lubrication oil for cold rolling of aluminum |
-
1986
- 1986-02-17 JP JP3086286A patent/JPS62190292A/en active Granted
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5436303A (en) * | 1977-08-27 | 1979-03-17 | Nippon Keikinzoku Sougou Kenki | Lubricant for processing aluminium |
JPS5665095A (en) * | 1979-11-02 | 1981-06-02 | Nikkei Giken:Kk | Lubricating oil for cold rolling of aluminum |
JPS59126498A (en) * | 1983-01-06 | 1984-07-21 | Nippon Light Metal Co Ltd | Lubrication oil for cold rolling of aluminum |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0992441A (en) * | 1995-09-22 | 1997-04-04 | Ngk Spark Plug Co Ltd | Manufacture of side electrode for spark plug |
Also Published As
Publication number | Publication date |
---|---|
JPS62190292A (en) | 1987-08-20 |
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