JPH05221746A - Inorganic lightweight decorative laminated sheet and its production - Google Patents

Inorganic lightweight decorative laminated sheet and its production

Info

Publication number
JPH05221746A
JPH05221746A JP5895192A JP5895192A JPH05221746A JP H05221746 A JPH05221746 A JP H05221746A JP 5895192 A JP5895192 A JP 5895192A JP 5895192 A JP5895192 A JP 5895192A JP H05221746 A JPH05221746 A JP H05221746A
Authority
JP
Japan
Prior art keywords
natural stone
plate
inorganic
inorganic lightweight
thickness
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP5895192A
Other languages
Japanese (ja)
Inventor
Taku Kitahama
卓 北浜
Masahiro Hashiba
正博 橋場
Yoshinori Shimojo
芳範 下條
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
JSP Corp
Original Assignee
JSP Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by JSP Corp filed Critical JSP Corp
Priority to JP5895192A priority Critical patent/JPH05221746A/en
Publication of JPH05221746A publication Critical patent/JPH05221746A/en
Pending legal-status Critical Current

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Abstract

PURPOSE:To easily produce an inorganic lightweight decorative laminated sheet which is excellent in workability and has a large dimension by constituting the surface of a plurality of pieces of natural slates or sheets like a natural stone. CONSTITUTION:An inorganic lightweight sheet 22 whose thickness is 7-90mm per one piece is formed of the mixture of inorganic aggregate consisting of SHIRASU (pumiceous sand) baloon as a main component, water glass and a hardening agent thereof. An inorganic lightweight decorative lamianted sheet 20 is constituted of the inorganic lightweight sheet 22 and a plurality of pieces of natural slates or plates 4 like a natural stone having 3-20mm thickness which are laminated and bonded thereon. Void parts 21 satisfying the following formulas (1) and (2) are interposed between the adjacent natural slates or the plates 4 like the natural stone. 0<t/T<=0.8 (1). 1.5<=T/w<=10 (2) (however T shows thickness of natural slate or plate like natural stone and t shows depth of void part and w shows width of void part).

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は、表面が複数個の天然石
板又は天然石様板からなる無機軽量化粧板及びその製造
方法に関するものである。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an inorganic lightweight decorative board having a plurality of natural stone boards or natural stone-like boards and a method for producing the same.

【0002】[0002]

【従来技術及びその問題点】近年、建築物の壁材や床材
において、高級感や自然感を得るために、天然石が賞用
されるようになってきた。しかし、このような天然石は
そのコストが高いとい難点がある上、比重が大きいため
に、その厚みを20〜30mmとした場合、重量が1m
2当り60kg以上となり、施工性が悪いという問題を
含む。また、石材の施工には専門技術が必要であるが、
慢性的ともいえる石工職人の不足は工期を遅らせるとと
もに、更には小規模ビルや店舗、住宅まで手が回らない
状況になっている。こうした職人不足を背景に、最近で
は、天然石を厚さ5〜10mmに薄切りし、裏面に軽重
量のバックアップ材を貼り合せたものが施工性の良い薄
切り天然石複合パネルとして開発されている。この天然
石複合パネルは、バックアップ材としてFRPシート、
アルミニウムハニカムコア、セラミック材料、合板等を
含むものであるが、いずれのものも人手による貼合せタ
イプで、製造コストがかかり、高価であるという問題が
ある他、熱による線膨張率の違いによる反りの発生等の
問題をかかえていた。そこで、発明者らは、先に、作業
コストや反りの問題を解決すべく、シラスバルーンを主
成分とする水ガラス硬化体をバックアップ材として使用
して化粧板を提案した(特願平2−275792号参
照)。しかし、この化粧板の場合は、化粧板製造に際し
ての作業コスト等の問題は解決できたものの化粧板施工
の際の作業には、やはり熟練技術を要するもので、施工
の問題を解決するには至っておらず、ある限られた小さ
な寸法のものしか実用化されていないのが現状である。
2. Description of the Related Art In recent years, natural stones have come to be favored in wall materials and floor materials of buildings in order to obtain a high-class feeling and a natural feeling. However, such a natural stone has a drawback that its cost is high, and since it has a large specific gravity, its weight is 1 m when its thickness is 20 to 30 mm.
It is more than 60 kg per 2 including the problem of poor workability. In addition, although specialized technology is required for stone construction,
The shortage of masons, which can be said to be chronic, delays the construction period, and even small-scale buildings, shops, and houses are inaccessible. Against the background of such a shortage of craftsmen, recently, a thin natural stone composite panel having good workability has been developed by slicing natural stone into a thickness of 5 to 10 mm and attaching a backing material of light weight to the back surface. This natural stone composite panel is a FRP sheet as a backup material,
Although it includes aluminum honeycomb core, ceramic material, plywood, etc., all of them are of a type to be manually attached, and there is a problem that they are expensive to manufacture and expensive, and warpage occurs due to difference in linear expansion coefficient due to heat. Had problems such as. Then, the present inventors previously proposed a decorative plate using a water glass cured product containing shirasu balloon as a main component as a backup material in order to solve the problems of working cost and warpage (Japanese Patent Application No. 2- 275792). However, in the case of this veneer, although problems such as the work cost in manufacturing the veneer could be solved, the work at the time of applying the veneer still requires skilled technology, and in order to solve the problem of construction The situation is that only a limited small size has been put to practical use.

【0003】[0003]

【発明が解決しようとする課題】本発明は、前記問題点
を解決し、表面が複数個の天然石板又は天然石様板から
なる施工性にすぐれ、大寸法のものも容易に得ることの
できる無機軽量化粧板及びその製造方法を提供すること
をその課題とする。
DISCLOSURE OF THE INVENTION The present invention solves the above-mentioned problems, has excellent workability in that the surface is made of a plurality of natural stone plates or natural stone-like plates, and an inorganic material of large size can be easily obtained. It is an object of the present invention to provide a lightweight decorative board and a manufacturing method thereof.

【0004】[0004]

【課題を解決するための手段】本発明者らは、前記課題
を解決すべく鋭意研究を重ねた結果、本発明を完成する
に至った。即ち、本発明によれば、シラスバルーンを主
成分とする無機骨材と水ガラスと水ガラス硬化剤との混
合物から形成された一個の厚み7〜90mmの無機質軽
量板と、その上に積層接着させた複数個の厚み3〜20
mmの天然石板又は天然石様板とからなり、該隣接する
天然石板又天然石様板の間には、下記式(1)及び
(2)を満足する空隙部が介在することを特徴とする無
機軽量化粧板が提供される。 O<t/T≦0.8 (1) 1.5≦T/w≦10 (2) (但し、Tは天然石板又は天然石様板の厚みを示し、t
は空隙部の深さを示し、wは空隙部の幅を示す) また、本発明によれば、下記式(1)及び(2)を満足
する仕切部材により内部が複数の区画に分割された型枠
のその各区画内に、該区画の平面形状に対応させた平面
形状の天然石板又は天然石様板をその上面に接着剤を塗
布して載置するとともに、その接着部塗布面上に硬化剤
を含む水ガラスで表面被覆したシラスバルーンを主成分
とする無機骨材を層状に積層し、常温又は加熱下におい
て加圧し、前記硬化剤と水ガラスを反応させることを特
徴とする無機軽量化粧板の製造方法が提供される。 O<t′/T≦0.8 (1) 1.5≦T/w′≦10 (2) (但し、Tは天然石様又は天然石様板の厚みを示し、
t′は仕切部材の高さを示し、w′は仕切部材の幅を示
す)
The present inventors have completed the present invention as a result of intensive studies to solve the above problems. That is, according to the present invention, one inorganic lightweight plate having a thickness of 7 to 90 mm formed from a mixture of an inorganic aggregate containing shirasu balloon as a main component, water glass, and a water glass curing agent, and laminating and adhering thereon. Multiple thicknesses 3-20
mm natural stone board or natural stone-like board, and an inorganic light-weight decorative board characterized in that a space satisfying the following formulas (1) and (2) is interposed between the adjacent natural stone boards or natural stone-like boards. Will be provided. O <t / T ≦ 0.8 (1) 1.5 ≦ T / w ≦ 10 (2) (where T is the thickness of the natural stone plate or the natural stone-like plate, t
Indicates the depth of the void, and w indicates the width of the void) Further, according to the present invention, the inside is divided into a plurality of partitions by the partition member that satisfies the following formulas (1) and (2). Inside each of the sections of the mold, a flat natural stone plate or natural stone-like plate corresponding to the flat shape of the section is applied with an adhesive on its upper surface and placed, and cured on the adhesive-coated surface. Inorganic lightweight makeup characterized by laminating a layer of inorganic aggregate mainly composed of shirasu balloon surface-coated with water glass containing a curing agent, pressurizing at room temperature or under heating, and reacting the curing agent with water glass A method of making a plate is provided. O <t '/ T≤0.8 (1) 1.5≤T / w'≤10 (2) (where T represents the thickness of natural stone or natural stone-like plate,
(t 'indicates the height of the partition member, and w'indicates the width of the partition member)

【0004】本発明で用いる天然石板又は天然石様板
(以下、これらを単に表面板とも言う)としては、大理
石、御影石といった天然石はもとより、アクリル樹脂を
用いた人造大理石、人工象牙等が用いられる。
Natural stone plate or natural stone-like plate used in the present invention
Examples of natural stones such as marble and granite, as well as artificial marble and artificial ivory, which are made of acrylic resin, are used as (hereinafter, simply referred to as surface plates).

【0005】本発明における無機質軽量板素材として用
いる無機骨材は、シラスバルーンを主成分として、その
他必要に応じ、パーライト、ヒル石、その他の軽量骨材
を含有する。無機骨材中のシラスバルーンの含有率は、
50重量%以上、好ましくは80〜100重量%であ
る。シラスバルーンとしては、市販品をそのまま用いる
ことができるが、本発明においては、微細粒子と粗大粒
子との混合物を用いるのが好ましい。本発明において用
いる特に好ましいシラスバルーンは、粒径63μm以下
の成分(以下、A成分という)含有率が15〜55重量
%、粒径177〜420μmの範囲の成分(以下、B成
分という)含有率が25〜65重量%及び粒子63μm
を超え177μ未満の成分含有率と420μmを超え6
00μm未満の成分(以下、両者併せてC成分という)
含有率が0〜40重量%の粒度分布を有するものであ
る。A成分が15重量%未満であったり、B成分が65
重量%を超えたりすると得られる軽量板は、収縮変形が
大きくなったり、表面に凹凸が目立つようになる。ま
た、A成分が55重量%を超えたり、B成分が25重量
%未満であると得られる軽量板は、収縮変形が大きくな
ると共に反り易くなり、場合によっては(B成分が0に
近づくと)クラックが発生したものとなる。また、C成
分が40重量%を超えると得られる軽量板は収縮変形の
大きなものとなる。
The inorganic aggregate used as the inorganic lightweight board material in the present invention contains shirasu balloon as a main component and, if necessary, pearlite, leucite, and other lightweight aggregates. The content rate of Shirasu balloon in the inorganic aggregate is
It is 50% by weight or more, preferably 80 to 100% by weight. As the shirasu balloon, commercially available products can be used as they are, but in the present invention, it is preferable to use a mixture of fine particles and coarse particles. A particularly preferred silas balloon used in the present invention has a content of a component having a particle size of 63 μm or less (hereinafter referred to as A component) in the range of 15 to 55% by weight, and a component having a particle size of 177 to 420 μm in the range (hereinafter referred to as B component). 25-65% by weight and particles 63 μm
Over 177 μm and component content over 420 μm 6
Component less than 00 μm (hereinafter, both are collectively referred to as C component)
It has a particle size distribution with a content of 0 to 40% by weight. A component is less than 15% by weight, B component is less than 65%
When the weight percentage is exceeded, the lightweight plate obtained has large shrinkage deformation, and the surface becomes prominently uneven. Further, the lightweight plate obtained when the amount of A component exceeds 55% by weight and the amount of B component is less than 25% by weight tends to warp as the shrinkage deformation increases, and in some cases (when B component approaches 0). A crack has occurred. Further, when the C component exceeds 40% by weight, the lightweight plate obtained has large shrinkage deformation.

【0006】本発明で用いる水ガラスは、ケイ酸ナトリ
ウムやケイ酸カリウムあるいはケイ酸リチウム等のケイ
酸アルカリ金属塩の水溶液を意味し、例えばJIS 1
号規格品、JIS 2号規格品、JIS 3号規格品等
として市販されているものである。水ガラス硬化剤とし
ては、従来公知のもの、例えば、リン酸、ホウ酸等の無
機酸及びその塩、ケイフッ化ナトリウム等のけいフッ化
物、酸化亜鉛や酸化マグネシウム、炭酸カルシウム、硫
酸カルシウム等の金属酸化物や金属塩、酢酸エステル等
が挙げられる。
The water glass used in the present invention means an aqueous solution of an alkali metal silicate such as sodium silicate, potassium silicate or lithium silicate, and for example JIS 1
No. standard product, JIS No. 2 standard product, JIS No. 3 standard product, etc. are commercially available. As the water glass curing agent, conventionally known ones, for example, inorganic acids such as phosphoric acid and boric acid and salts thereof, silicofluorides such as sodium silicofluoride, metals such as zinc oxide and magnesium oxide, calcium carbonate and calcium sulfate. Examples thereof include oxides, metal salts and acetic acid esters.

【0007】本発明における無機質軽量板を製造するた
めの成形材料は、水ガラス、硬化剤及びシラスバルーン
の混合物からなる。水ガラスの使用割合は、シラスバル
ーン100重量部に対し、固形分(ケイ酸アルカリ金属
塩)換算量で30〜150重量部、好ましくは40〜1
30重量部である。水ガラスの使用割合が上記下限値未
満の場合は、接合材としての効果に劣り、得られる軽量
板は強度が著しく低下し、実用性のないものとなる。一
方、上記上限値を超える場合は、未反応水ガラスの割合
が多くなり、このため得られる軽量板は収縮を伴ない、
クラックを生じたものとなる。水ガラスの硬化剤は、シ
ラスバルーン100重量部に対し、10〜40重量部、
好ましくは15〜30重量部である。硬化剤の使用量が
上記下限値未満の場合は、未反応水ガラスの割合が多く
なり、このため得られる軽量板は収縮を伴ない、クラッ
クを生じたものとなる。一方、上記上限値を超える場合
は、上記硬化剤と、空気中の炭酸ガス及び水分との反応
割合が著しく多くなり、いわゆる白華現象が認められ、
得られる軽量板やこの軽量板の表面に積層した表面板の
表面には白い粉が斑点状に析出するため商品価値が著し
く低下する。
The molding material for producing the inorganic lightweight board in the present invention comprises a mixture of water glass, a curing agent and Shirasu balloon. The amount of water glass used is 30 to 150 parts by weight, preferably 40 to 1 in terms of solid content (alkali metal silicate) based on 100 parts by weight of Shirasu balloon.
30 parts by weight. If the proportion of water glass used is less than the above lower limit, the effect as a bonding material will be poor, and the resulting lightweight plate will have a markedly reduced strength, making it impractical. On the other hand, when the upper limit is exceeded, the proportion of unreacted water glass increases, and thus the resulting lightweight plate does not shrink,
It will be cracked. The curing agent for water glass is 10 to 40 parts by weight with respect to 100 parts by weight of Shirasu balloon,
It is preferably 15 to 30 parts by weight. If the amount of the curing agent used is less than the above lower limit value, the proportion of unreacted water glass increases, so that the resulting lightweight plate is accompanied by shrinkage and has cracks. On the other hand, when it exceeds the upper limit, the curing agent, the reaction rate of carbon dioxide gas and moisture in the air is significantly increased, so-called white flower phenomenon is observed,
White powder is spotted on the surface of the obtained lightweight plate or the surface plate laminated on the surface of the lightweight plate, so that the commercial value is significantly reduced.

【0008】本発明においては、無機質軽量板の機械的
強度を高めるために、前記成形材料には、高分子バイン
ダーを併用することができる。この高分子バインダーと
しては、水溶性高分子又は高分子ラテックスを用いるこ
とができる。水溶性高分子としては、水溶性の尿素/ホ
ルムアミド樹脂やグアナミン樹脂の他、ポリビニルアル
コール、ポリビニルピロリドン等が用いられる。高分子
ラテックスとしては、スチレン/ブダジエン系ラテック
ス、アクリル系ラテックス、塩化ビニリデン系ラテック
ス、塩化ビニル系ラテックス、酢酸ビニル系ラテックス
等が用いられる。高分子バインダーの使用割合は、シラ
スバルーン100重量部に対し、固形分換算で0.5重
量部以上、好ましくは1〜10重量部の割合で用いるの
がよい。高分子バインダーの使用割合が多くなると軽量
板の不燃性が損われるようになるので、不燃性軽量板を
得る点からは、その高分子バインダー使用割合は5重量
部以下にするのがよい。
In the present invention, in order to enhance the mechanical strength of the inorganic lightweight plate, a polymeric binder may be used in combination with the molding material. A water-soluble polymer or polymer latex can be used as the polymer binder. Examples of the water-soluble polymer include water-soluble urea / formamide resin and guanamine resin, as well as polyvinyl alcohol and polyvinylpyrrolidone. As the polymer latex, styrene / budadiene type latex, acrylic type latex, vinylidene chloride type latex, vinyl chloride type latex, vinyl acetate type latex and the like are used. The polymer binder is used in an amount of 0.5 parts by weight or more, preferably 1 to 10 parts by weight in terms of solid content, based on 100 parts by weight of Shirasu balloon. When the proportion of the polymer binder used is large, the nonflammability of the lightweight plate is impaired. Therefore, from the viewpoint of obtaining a nonflammable lightweight plate, the proportion of the polymer binder used is preferably 5 parts by weight or less.

【0009】本発明で用いる前記成形材料には、無機質
軽量板のクラック発生を防止し、かつ機械的強度を高め
るために、さらに、補強繊維を併用することができる。
補強繊維としては、ビニロン繊維、アクリル繊維、アラ
ミド繊維、ポリエステル繊維、ポリアミド繊維、セルロ
ース繊維、木綿、炭素繊維等の合成繊維や天然繊維の
他、金属繊維、アルミナ繊維、ガラス繊維、セッコウウ
ィスカー等の各種金属及び無機繊維が用いられる。その
繊維の太さは、1〜100μm、好ましくは3〜60μ
mであり、その繊維長は、1mm以上、好ましくは3〜
20mmである。補強繊維の使用割合は、シラスバルー
ン100重量部に対し、0.1〜10重量部、好ましく
は0.5〜5重量部である。
The molding material used in the present invention may further contain a reinforcing fiber in order to prevent the occurrence of cracks in the inorganic lightweight plate and to enhance the mechanical strength.
Examples of the reinforcing fiber include vinylon fiber, acrylic fiber, aramid fiber, polyester fiber, polyamide fiber, cellulose fiber, cotton, carbon fiber and other synthetic fibers and natural fibers, as well as metal fiber, alumina fiber, glass fiber, gypsum whiskers and the like. Various metals and inorganic fibers are used. The thickness of the fiber is 1 to 100 μm, preferably 3 to 60 μm.
m, and the fiber length is 1 mm or more, preferably 3 to
It is 20 mm. The proportion of the reinforcing fiber used is 0.1 to 10 parts by weight, preferably 0.5 to 5 parts by weight, based on 100 parts by weight of the Shirasu balloon.

【0010】さらに、前記成形材料には、その増粘化
や、成形硬化する際の収縮防止のために、未発泡のシラ
ス粉粒体や、マイカ、カオリン等の無機粉末を併用する
ことができる。このような無機粉末の平均粒径は、70
μm以下、好ましくは0.1〜30μmである。また、
このような無機粉体の使用割合は、シラスバルーン10
0重量部に対し、30重量部以下、好ましくは20重量
部以下である。また、超微粒子の二酸化ケイ素をカップ
リング処理したものをシラスバルーン100重量部に対
して3〜20重量部程度添加することにより、発水性の
付与、機械的強度アップをはかることができる。
Further, the above-mentioned molding material may be used in combination with unexpanded shirasu powder or an inorganic powder such as mica or kaolin in order to increase its viscosity and prevent shrinkage during molding and curing. .. The average particle size of such inorganic powder is 70
It is not more than μm, preferably 0.1 to 30 μm. Also,
The use ratio of such inorganic powder is as follows.
It is 30 parts by weight or less, preferably 20 parts by weight or less, relative to 0 parts by weight. Further, by adding about 3 to 20 parts by weight of ultrafine particles obtained by coupling silicon dioxide to 100 parts by weight of Shirasu balloon, it is possible to impart water repellency and increase mechanical strength.

【0011】次に、本発明の無機軽量化粧板を好ましく
製造する方法について、図面を参照して説明する。図1
は本発明で用いる成形用型枠の1つの実施例についての
構造説明図で、図1(a)は平面図、図1(b)は図1
(a)におけるA−A°側断面図を示す。図1におい
て、1は型枠を示し、2、3は仕切部材を示す。t′は
仕切部材の高さ、w′は仕切部材の幅を示す。この型枠
1においては、その内部は仕切部材2、3により4個の
区画10,11,12,13に分割されている。本発明
においては、この型枠の各割分区画10,11,12,
13内に、図2に示すように、上面に接着剤5を塗布し
た表面板4を載置する。表面板の形状は、その区画の形
状と対応させる。この場合、仕切部材2,3の高さt′
と表面板4の厚みTとの関係を、0<t′/T≦0.
8、好ましくは0.1<t′/T≦0.5の関係に保持
する。この関係式において、t′/Tが0となると、得
られる化粧板において隣接する表面板の間に空隙部がな
くなることから、仕上げ施工における目地剤塗布が不可
能となるので好ましくなく、一方、t′/T>0.8と
なると、空隙部の深さが大きくなりすぎるため、曲げ強
度が弱くなり、この空隙部の個所で破損しやすくなるの
で好ましくない。また、仕切部材2、3においては、そ
の表面板の厚みTと幅w′との関係を、1.5≦T/
w′≦10、好ましくは、4≦T/w′≦10の関係に
なるように保持するのが好ましい。T/w′が1.5よ
り小さくなると、化粧板を養生する際に曲げ強度が不足
するため、化粧板が表面板の荷重により破損しやすくな
る等の問題が生じるようになるで好ましくなく、また、
化粧板が高級感にもかけるようになる。一方、T/w′
が10を超えると、表面板の寸法精度がきびしく要求さ
れ、表面板の加工に手間がかかるようになり、また養生
時に発生する残留応力を緩和することが難しくなり、反
りやクラック発生を生じるようになるので好ましくな
い。
Next, a method for preferably manufacturing the inorganic lightweight decorative board of the present invention will be described with reference to the drawings. Figure 1
1A and 1B are structural explanatory views of one embodiment of a molding form used in the present invention, FIG. 1A is a plan view, and FIG. 1B is FIG.
The sectional view on the AA side in (a) is shown. In FIG. 1, reference numeral 1 indicates a mold, and reference numerals 2 and 3 indicate partition members. t'denotes the height of the partition member, and w'denotes the width of the partition member. The interior of the mold 1 is divided into four sections 10, 11, 12, and 13 by partition members 2 and 3. In the present invention, each divided section 10, 11, 12,
As shown in FIG. 2, the surface plate 4 having the upper surface coated with the adhesive 5 is placed in the inside 13. The shape of the face plate corresponds to the shape of the section. In this case, the height t ′ of the partition members 2 and 3
And the thickness T of the surface plate 4 are 0 <t '/ T≤0.
8, preferably 0.1 <t ′ / T ≦ 0.5. In this relational expression, when t '/ T is 0, it is not preferable because the voids are eliminated between the adjacent surface plates in the obtained decorative plate, which makes it impossible to apply the jointing agent in the finishing work. On the other hand, t' When /T>0.8, the depth of the void becomes too large, the bending strength becomes weak, and the portion of the void easily breaks, which is not preferable. Further, in the partition members 2 and 3, the relationship between the thickness T of the surface plate and the width w ′ is 1.5 ≦ T /
It is preferable to maintain the relationship of w'≤10, preferably 4≤T / w'≤10. If T / w ′ is less than 1.5, the bending strength is insufficient when the decorative board is cured, and the decorative board is liable to be damaged by the load of the surface board, which is not preferable. Also,
The veneer will also look luxurious. On the other hand, T / w '
When the value exceeds 10, the dimensional accuracy of the surface plate is severely required, it takes time and labor to process the surface plate, and it becomes difficult to reduce the residual stress generated during curing, and warping and cracking may occur. Is not desirable.

【0012】表面板4の上面に塗布する接着剤5として
は、エポキシ樹脂や、ウレタン樹脂等の高分子系接着剤
も使用し得るが、好ましくは、無機系接着剤、例えば、
水ガラス系接着剤を用いる。この水ガラス系接着剤は、
水ガラスに硬化剤を含有させ、必要に応じ、無機粉体を
添加させたものである。この場合の水ガラス及び硬化剤
としては前記で示したものが挙げられる。無機粉体とし
ては、カオリン、白土、シラス、ケイソウ土、セピオラ
イト、ゼオライト、シリカ、マイカ等の各種のものが挙
げられる。この水ガラス系接着剤は、その粘度を、前記
した軽量板の製造に際して用いる場合の硬化剤を含む水
ガラスの粘度よりも高く保持するのが作業性の点で好ま
しい。その他、より好ましく接着剤としてアルミナ系、
シリカ系、シリカ・アルミナ系、マグネシア系の無機系
接着剤が使用される。接着剤の塗布量は、接着剤の粘
度、接着力等によって異なるが、例えばアルミナ系無機
接着剤を使用する場合は、300〜500g/m2の塗
布量となる。
As the adhesive 5 applied to the upper surface of the surface plate 4, polymer adhesives such as epoxy resin and urethane resin can be used, but preferably inorganic adhesives such as
A water glass adhesive is used. This water glass adhesive
A water glass is mixed with a curing agent and, if necessary, inorganic powder is added. Examples of the water glass and the curing agent in this case include those described above. Examples of the inorganic powder include various materials such as kaolin, clay, shirasu, diatomaceous earth, sepiolite, zeolite, silica and mica. From the viewpoint of workability, it is preferable that the viscosity of the water glass adhesive is kept higher than the viscosity of water glass containing a curing agent used in the production of the above-mentioned lightweight plate. Others, more preferably an alumina-based adhesive,
Silica-based, silica-alumina-based, and magnesia-based inorganic adhesives are used. The amount of adhesive applied varies depending on the viscosity and adhesive strength of the adhesive, but when an alumina-based inorganic adhesive is used, the amount applied is 300 to 500 g / m 2 .

【0013】前記のようにして各分割区画内に載置され
た表面板4の接着剤塗布面5の上には、図3に示すよう
に、水ガラス、硬化剤及び無機骨材の混合物からなる成
形材料6を層状に充填し、常温又は加熱下において加圧
成形する。加圧成形後、得られた成形物を成形型枠から
取り出し、この加圧成形物を常温又は加熱下で硬化させ
るのが好ましい。この加圧成形においては、成形物を成
形型枠内において硬化させることもできるが、加圧成形
物は固形物であり、取扱い容易なものであることから、
成形物を成形型枠から取出し、これを常温又は加熱下に
保持して硬化させるのが好ましい。加圧成形に際しての
圧力は、0.05〜15kg/cm2G、好ましくは3
〜12kg/cm2Gである。成形物を加熱下で硬化さ
せる場合、30℃以上、好ましくは80℃以下の温度条
件が採用され、その硬化時間は、通常、相対温度40〜
80%の条件下で、1〜3時間である。成形物の加熱硬
化体は、そのまま製品として使用し得るが、さらに硬化
反応を進行させて機械的強度を向上させるため、常温又
は常温付近の温度で、相対温度40〜100%で選択さ
れる一定条件下で14〜90日、好ましくは30〜60
日程度保持して使用するのが好ましい。
As shown in FIG. 3, a mixture of water glass, a curing agent and an inorganic aggregate is formed on the adhesive application surface 5 of the face plate 4 placed in each divided section as described above. The resulting molding material 6 is filled in layers and pressure-molded at room temperature or under heating. After pressure molding, it is preferable to take out the obtained molded product from the molding frame and cure the pressure molded product at room temperature or under heating. In this pressure molding, the molded product can be cured in the molding frame, but since the pressure molded product is a solid substance and is easy to handle,
It is preferable to take out the molded product from the molding frame and hold it at room temperature or under heating to cure it. The pressure at the time of pressure molding is 0.05 to 15 kg / cm 2 G, preferably 3
~ 12 kg / cm 2 G. When the molded product is cured under heating, a temperature condition of 30 ° C. or higher, preferably 80 ° C. or lower is adopted, and the curing time is usually at a relative temperature of 40 to 40 ° C.
It is 1 to 3 hours under the condition of 80%. The heat-cured product of the molded product can be used as a product as it is, but in order to further advance the curing reaction and improve the mechanical strength, it is a constant temperature selected at or near room temperature and at a relative temperature of 40 to 100%. 14 to 90 days under conditions, preferably 30 to 60
It is preferable to keep it for about a day before use.

【0014】前記のようにして得られた無機軽量化粧板
20の構造説明図を図4に示す。図4(a)はその平面
図、図4(b)はその断面図を示す。図4において、4
は表面板、5は接着剤層、21は空隙部、22は無機質
軽量板を示す。本発明の無機軽量化粧板20において
は、隣接する表面板4の間には溝状の空隙部21が存在
する。この空隙部21における深さtは、図1に示した
仕切部材2,3の高さt′に対応し、空隙部21の幅w
は、図1に示した仕切部材2,3の幅w′に対応するも
のである。従って、この無機軽量化粧板20における空
隙部の深さtと、表面板5の厚みTとの間には、次の関
係が成立する。 O<t/T≦0.8 (1) また、表面板の厚みTと幅wとの間には、次の関係が成
立する。 1.5≦T/w≦10 (2) 本発明の無機軽量化粧板20において、その全体の厚み
は10〜100mm、好ましくは10〜40mm程度で
あり、接着剤層5の厚みは0.05〜2mm程度であ
り、表面板の厚みは、その全体の厚みの10〜50%、
通常、3〜20mmの範囲に規定するのがよい。
FIG. 4 is a structural explanatory view of the inorganic lightweight decorative board 20 obtained as described above. FIG. 4A shows a plan view thereof, and FIG. 4B shows a sectional view thereof. In FIG. 4, 4
Is a surface plate, 5 is an adhesive layer, 21 is a void, and 22 is an inorganic lightweight plate. In the inorganic lightweight decorative board 20 of the present invention, a groove-shaped void portion 21 exists between the adjacent surface plates 4. The depth t in the void portion 21 corresponds to the height t ′ of the partition members 2 and 3 shown in FIG. 1, and the width w of the void portion 21.
Corresponds to the width w'of the partition members 2 and 3 shown in FIG. Therefore, the following relationship is established between the depth t of the void in the inorganic lightweight decorative board 20 and the thickness T of the surface board 5. O <t / T ≦ 0.8 (1) Further, the following relationship is established between the thickness T and the width w of the surface plate. 1.5 ≦ T / w ≦ 10 (2) In the inorganic lightweight decorative board 20 of the present invention, the total thickness thereof is 10 to 100 mm, preferably 10 to 40 mm, and the thickness of the adhesive layer 5 is 0.05. Is about 2 mm, the thickness of the surface plate is 10 to 50% of the total thickness,
Usually, it is preferable to set it in the range of 3 to 20 mm.

【0015】図5は本発明で用いる成形用型枠の他の実
施例についての構造説明図で、図5(a)は平面図、図
5(b)は、図5(a)におけるA−A′断面図を示
す。図5の型枠は、その縦と横の2つの側縁部にそれぞ
れ仕切部材25及び26を配設したもので、その他の点
では図1に示したものと同じ構造である。図5に示した
成形用型枠を用いる場合の無機軽量化粧板の製造も、前
記図1に示した型枠を用いる場合と同様にして行うこと
ができる。図6に、図5で示した型枠を用いて得られた
無機軽量化粧板の構造説明図を示す。図6(a)はその
平面図、図6(b)はその断面図を示す。図6におい
て、4は表面板、5は接着剤層、21は隣接する表面板
の間に形成された空隙部、22は無機質軽量板を示す。
また、27は化粧板の縦と横の側縁部に形成された空隙
部を示す。図6に示したこの無機軽量化粧板は、その縦
と横の側縁部に空隙部27が形成されていることから、
その複数個を平面に並べて施工するに際し、空隙部27
を有する側端面と、空隙部27を有しない側端面を空き
合せるだけで一枚の平面板状に容易に仕上げることがで
きる。図7に、このようにして並列配置した化粧板の構
造説明図を示す。図7(a)はその平面図、図7(b)
はその断面図を示す。
FIG. 5 is a structural explanatory view of another embodiment of the molding form used in the present invention. FIG. 5 (a) is a plan view and FIG. 5 (b) is A- in FIG. 5 (a). The A'sectional view is shown. The formwork shown in FIG. 5 has partition members 25 and 26 respectively arranged on its two vertical and horizontal side edges, and otherwise has the same structure as that shown in FIG. The inorganic lightweight decorative board in the case of using the molding frame shown in FIG. 5 can be manufactured in the same manner as in the case of using the frame shown in FIG. FIG. 6 is a structural explanatory view of an inorganic lightweight decorative board obtained by using the mold shown in FIG. FIG. 6A shows a plan view thereof, and FIG. 6B shows a sectional view thereof. In FIG. 6, 4 is a surface plate, 5 is an adhesive layer, 21 is a void formed between adjacent surface plates, and 22 is an inorganic lightweight plate.
Further, reference numeral 27 denotes a void portion formed on the vertical and horizontal side edges of the decorative plate. Since this inorganic lightweight decorative board shown in FIG. 6 has voids 27 formed in the vertical and horizontal side edges thereof,
When arranging a plurality of them in a plane, the void 27
It is possible to easily finish it into a single flat plate-like shape only by vacantly matching the side end surface having the gap and the side end surface having no void 27. FIG. 7 shows a structure explanatory view of the decorative plates arranged in parallel in this way. FIG. 7A is a plan view thereof, and FIG.
Shows the sectional view.

【0016】前記のようにして無機軽量化粧板を製造す
る方法においては、無機軽量板の製造と、その無機軽量
板に対する表面板の積層接着を同時に行うことができる
利点がある上、得られる無機軽量化粧板は、表面板と無
機軽量板との間の接着強度が大きく、界面剥離を生じに
くいという利点がある。さらに、前記の方法では、化粧
板の厚みのバラツキによる製品厚みの影響がなく、均一
な製品が得られ、かつ複数個の表面板含む化粧板を一度
のプレス成形により得ることができるので生産性が高い
という大きな利点がある。さらに、製品の表面には溝状
の空隙部が形成されているので、仕上げ施工(目地剤塗
布)が簡素化され、更には、プレス圧縮残留応力の緩和
が助長され、反りの防止にも有効である。
In the method for producing the inorganic lightweight decorative board as described above, there is an advantage that the production of the inorganic lightweight board and the laminating and adhesion of the surface board to the inorganic lightweight board can be carried out at the same time, and the resulting inorganic board is obtained. The lightweight decorative board has an advantage that the adhesive strength between the surface board and the inorganic lightweight board is large and interface peeling hardly occurs. Further, in the above method, there is no influence of the product thickness due to the variation in the thickness of the decorative plate, a uniform product can be obtained, and a decorative plate including a plurality of surface plates can be obtained by one press molding, so that productivity is improved. There is a big advantage that is high. In addition, since groove-like voids are formed on the surface of the product, finishing work (joint application) is simplified, and further relaxation of press compression residual stress is promoted, which is also effective in preventing warpage. Is.

【0017】本発明の無機軽量化粧板は、あらかじめ形
成した無機質軽量板上に、接着剤層を介して表面板を積
層接着させることによっても製造することができる。こ
の場合、無機質軽量板として、複数の表面板を所定の空
隙部を介して積層接着し得るように、その、表面が表面
板の形状に対応するように、幅w′、高さt′の凸部に
より複数に区画されたものを用いる。そして、この無機
質軽量板上に形成された各区画に対して下面に接着剤を
塗布した表面板を積層接着させる。また、このような表
面に凸部を有する無機質軽量板は、図1及び図5に示し
た型枠において、その底板の表面上の仕切部材に対応す
る部分に凹部を形成したものを型枠として用い、これに
成形材料を充填し、加圧成形することにより得ることが
できる。
The inorganic lightweight decorative board of the present invention can also be manufactured by laminating and adhering a surface board to an inorganic lightweight board which has been formed in advance through an adhesive layer. In this case, as the inorganic lightweight plate, a plurality of surface plates can be laminated and adhered through a predetermined gap portion, and the surfaces thereof have a width w ′ and a height t ′ so that the surface corresponds to the shape of the surface plate. The one that is divided into a plurality by the convex portion is used. Then, a surface plate having an adhesive applied to the lower surface is laminated and adhered to each of the sections formed on the inorganic lightweight plate. Further, such an inorganic lightweight plate having a convex portion on the surface is a mold frame shown in FIGS. 1 and 5 in which a concave portion is formed in a portion corresponding to the partition member on the surface of the bottom plate. It can be obtained by using it, filling it with a molding material, and press-molding.

【0018】[0018]

【発明の効果】本発明の無機軽量化粧板は、無機物を主
成分として構成されているにもかかわらず、軽量であ
り、さらにその表面が天然石様に形成されているため美
感においてもすぐれているという特徴を有する。本発明
の無機軽量化粧板は、複数個の表面板からなり、隣接す
る表面板間には空隙部を存在させていることから、隣接
する表面板間の目地剤塗布が容易になり、かつ反りの発
生の防止されたものである。さらに、本発明の無機軽量
化粧板は、複数の表面板からなる大型のものであること
と、化粧板の厚みを均一にできることから、その壁や床
等の固体表面に対する貼付け作業は容易かつ効率的なも
のになり、格別の熟練は必要とされず、石工職人以外の
者でも容易にその貼付け作業を行うことができる。本発
明の無機軽量化粧板の製造方法は、焼成工程の工程を含
まないため、簡単な設備でかつ低コストで実施すること
ができる。しかも、本発明では、複数個の表面板を含む
製品を一度に生産できることから、化粧板の生産性にお
いてもすぐれている。
INDUSTRIAL APPLICABILITY The inorganic lightweight decorative board of the present invention is light in spite of being composed mainly of an inorganic substance, and is excellent in aesthetic appearance because its surface is formed like a natural stone. It has the feature. The inorganic lightweight decorative board of the present invention is composed of a plurality of surface boards, and since the voids are present between the adjacent surface boards, the application of the jointing agent between the adjacent surface boards is facilitated and the warp is prevented. The occurrence of is prevented. Furthermore, since the inorganic lightweight decorative board of the present invention is a large-sized one composed of a plurality of surface boards and the thickness of the decorative board can be made uniform, it is easy and efficient to apply it to a solid surface such as a wall or floor. Since it does not require special skill, even a person other than a mason can easily perform the pasting work. Since the method for manufacturing an inorganic lightweight decorative board of the present invention does not include a firing step, it can be carried out with simple equipment and at low cost. Moreover, according to the present invention, since a product including a plurality of surface plates can be produced at one time, the productivity of the decorative plate is also excellent.

【0019】[0019]

【実施例】次に本発明を実施例によりさらに詳細に説明
する。なお、以下において示す部及び%はいずれも重量
基準である。
EXAMPLES Next, the present invention will be described in more detail by way of examples. In addition, all parts and% shown below are based on weight.

【0020】実施例1〜16 JIS 3号水ガラス100部に対し、硬化剤(縮合リ
ン酸アルミニウム)15部を配合し、さらに無機粉体と
して、シラス原石粉12部、マイカ8部及びカオリン1
0部を配合し、均一に混合して水ガラス系接着剤Aを調
製した。また、JIS 3号水ガラス128部に、硬化
剤(縮合リン酸アルミニウム)18部、シラス原石粉
8.4部、マイカ5.6部、カオリン5.6部及び補強
繊維(ビニロン繊維)1.5部、ラテックス4.5部を
配合し、均一に混合して水ガラス系接着剤Bを調製し
た。また、シラスバルーンとしては、粒径180〜42
0μmの成分100部と粒径38μm以下の成分50部
とからなるものを用いた。成形用型枠としては、図5に
示す構造のものを用いた。この場合、型枠1の寸法は、
縦:(600+4w′)mm、横:(600+4w′)
mm、高さ:100mmであり、仕切部材2、3及び2
6の各幅w′及び高さt′は表1に示した通りであっ
た。次に、厚みT=10mmの大理石板の片側全面に水
ガラス系接着剤Aを約0.5mm厚で塗布し、塗布面を
上に向けて型枠の各区画10、11、12、13に載置
する。次いでシラスバルーン150部と水ガラス系接着
剤B177.6部との混合物Aを型枠内に充填し、その
上に押圧板を載置し、圧力10kg/cm2Gで25m
m厚まで加圧した後、その成形物(化粧板)を型枠から
取出し、これを40℃のオーブン中で3時間加熱硬化さ
せ、得られた化粧板をさらに室温約25℃で7日間放置
した。このようにして図6に示す構造の無機軽量化粧板
を得た。このものについて、その厚み、及び嵩密度等を
測定した。これらの結果を併せて表1に示した。本発明
の無機軽量化粧板は、界面剥離のない良好な外観を示し
た。なお、実施例4〜6は、接着剤Aのかわりにアルミ
ナ系無機接着剤(昭和高分子株式会社製:ハイパーラン
ダム(R) C−989)を使用した。接着剤A及びアルミ
ナ系無機接着剤はいずれも問題なく使用することができ
たが、接着剤Bに比べて、接着剤Aが多少接着強度に劣
る傾向を示した。
Examples 1 to 16 15 parts of a hardening agent (condensed aluminum phosphate) was mixed with 100 parts of JIS No. 3 water glass, and further 12 parts of rough shirasu powder, 8 parts of mica and 1 kaolin were used as inorganic powder.
0 parts were compounded and uniformly mixed to prepare a water glass adhesive A. Further, in 128 parts of JIS No. 3 water glass, 18 parts of a curing agent (condensed aluminum phosphate), 8.4 parts of rough shirasu powder, 5.6 parts of mica, 5.6 parts of kaolin and reinforcing fiber (vinylon fiber) 1. 5 parts of latex and 4.5 parts of latex were mixed and uniformly mixed to prepare a water glass adhesive B. Further, as the shirasu balloon, the particle size is 180 to 42.
A mixture of 100 parts of 0 μm and 50 parts of a particle size of 38 μm or less was used. The molding frame used had the structure shown in FIG. In this case, the size of the mold 1 is
Vertical: (600 + 4w ') mm, Horizontal: (600 + 4w')
mm, height: 100 mm, partition members 2, 3 and 2
Each width w'and height t'of 6 are as shown in Table 1. Next, a water glass adhesive A is applied to the entire surface of one side of a marble plate having a thickness T = 10 mm to a thickness of about 0.5 mm, and the applied surface is faced up to each section 10, 11, 12, 13 of the formwork. Place it. Then, a mixture A of 150 parts of shirasu balloon and 177.6 parts of water glass adhesive B was filled in a mold, and a pressing plate was placed on the mold A, and the pressure was 10 kg / cm 2 G for 25 m.
After pressurizing to m thickness, the molded product (decorative board) is taken out from the mold, heat-cured for 3 hours in an oven at 40 ° C, and the resulting decorative board is left at room temperature of about 25 ° C for 7 days. did. Thus, an inorganic lightweight decorative board having the structure shown in FIG. 6 was obtained. About this thing, the thickness, the bulk density, etc. were measured. The results are also shown in Table 1. The inorganic lightweight decorative board of the present invention showed a good appearance without interfacial peeling. In Examples 4 to 6, an alumina-based inorganic adhesive (manufactured by Showa Polymer Co., Ltd .: Hyper Random (R) C-989) was used instead of the adhesive A. Both the adhesive A and the alumina-based inorganic adhesive could be used without any problem, but the adhesive A showed a tendency to be somewhat inferior in adhesive strength to the adhesive B.

【0021】[0021]

【表1】 [Table 1]

【図面の簡単な説明】[Brief description of drawings]

【図1】成形用型枠の1つの実施例についての構造説明
図である。 図1(a):平面図 図1(b):図1(a)のA−A′断面図
FIG. 1 is a structural explanatory view of one embodiment of a molding form. FIG. 1A: Plan view FIG. 1B: AA ′ cross-sectional view of FIG.

【図2】図1の成形用型枠の分割区画内に、上面に接着
剤を塗布した表面板を載置した状態図である。
FIG. 2 is a view showing a state in which a surface plate having an upper surface coated with an adhesive is placed in the divided sections of the molding frame of FIG.

【図3】図1の成形用型枠内に無機骨材と水ガラスと水
ガラス硬化剤の混合物からなる成形材料を充填した状態
図である。
3 is a state diagram in which a molding material made of a mixture of an inorganic aggregate, water glass and a water glass curing agent is filled in the molding frame of FIG.

【図4】図1の成形用型枠を用いて製造された本発明の
無機軽量化粧板の構造説明図である。 図4(a):平面図 図4(b):断面図
FIG. 4 is a structural explanatory view of an inorganic lightweight decorative board of the present invention manufactured by using the molding frame of FIG. 1. Figure 4 (a): Plan view Figure 4 (b): Sectional view

【図5】成形用型枠の他の実施例についての構造説明図
である。 図5(a):平面図 図5(b):図5(a)のA−A′断面図
FIG. 5 is a structural explanatory view of another embodiment of the molding frame. FIG. 5A: Plan view FIG. 5B: AA ′ cross-sectional view of FIG.

【図6】図5の成形用型枠を用いて製造された本発明の
無機軽量化粧板の構造説明図である。 図6(a):平面図 図6(b):断面図
6 is a structural explanatory view of an inorganic lightweight decorative board of the present invention manufactured using the molding frame of FIG. 5. FIG. FIG. 6A: Plan view FIG. 6B: Cross sectional view

【図7】図6の無機軽量化粧板を並列配置した場合の説
明図である。 図7(a):平面図 図7(b):断面図
7 is an explanatory diagram of a case where the inorganic lightweight decorative boards of FIG. 6 are arranged in parallel. FIG. 7A: Plan view FIG. 7B: Cross-sectional view

【符号の説明】[Explanation of symbols]

1 成形用型枠 2,3,26 仕切部材 4 表面板 5 接着剤層 6 成形材料 10〜13 分割区画 20 無機軽量化粧板 21,27 空隙部 22 無機質軽量板 1 Molding Form 2, 3, 26 Partitioning Member 4 Surface Plate 5 Adhesive Layer 6 Molding Material 10-13 Divided Section 20 Inorganic Lightweight Decorative Board 21, 27 Void 22 Inorganic Lightweight Board

Claims (3)

【特許請求の範囲】[Claims] 【請求項1】 シラスバルーンを主成分とする無機骨材
と水ガラスと水ガラス硬化剤との混合物から形成された
一個の厚み7〜90mmの無機質軽量板と、その上に積
層接着された複数個の厚み3〜20mmの天然石板又は
天然石様板とからなり、該隣接する天然石板又天然石様
板の間には、下記式(1)及び(2)を満足する空隙部
が介在することを特徴とする無機軽量化粧板。 O<t/T≦0.8 (1) 1.5≦T/w≦10 (2) (但し、Tは天然石板又は天然石様板の厚みを示し、t
は空隙部の深さを示し、wは空隙部の幅を示す)
1. An inorganic lightweight plate having a thickness of 7 to 90 mm formed from a mixture of an inorganic aggregate containing shirasu balloon as a main component, water glass and a water glass curing agent, and a plurality of laminated and adhered layers thereon. And a natural stone plate or a natural stone-like plate having a thickness of 3 to 20 mm. Between the adjacent natural stone plates or natural stone-like plates, voids satisfying the following formulas (1) and (2) are interposed. Inorganic lightweight decorative board. O <t / T ≦ 0.8 (1) 1.5 ≦ T / w ≦ 10 (2) (where T is the thickness of the natural stone plate or the natural stone-like plate, t
Indicates the depth of the void, and w indicates the width of the void.)
【請求項2】 該無機質軽量板と該天然石板又は天然石
様板との間にアルミナ系無機接着剤からなる接着剤層が
介在する請求項1の無機軽量化粧板。
2. The inorganic lightweight decorative board according to claim 1, wherein an adhesive layer made of an alumina-based inorganic adhesive is interposed between the inorganic lightweight board and the natural stone board or the natural stone-like board.
【請求項3】 下記式(1)及び(2)を満足する仕切
部材により内部が複数の区画に分割された型枠のその各
区画内に、該区画の平面形状に対応する平面形状の天然
石板又は天然石様板をその上面に接着剤を塗布して載置
するとともに、その接着剤塗布面上に硬化剤を含む水ガ
ラスで表面被覆したシラスバルーンを主成分とする無機
骨材を層状に積層し、常温又は加熱下において加圧し、
前記硬化剤と水ガラスを反応させることを特徴とする無
機軽量化粧板の製造方法。 O<t′/T≦0.8 (1) 1.5≦T/w′≦10 (2) (但し、Tは天然石様又は天然石様板の厚みを示し、
t′は仕切部材の高さを示し、w′は仕切部材の幅を示
す)
3. A natural stone having a planar shape corresponding to the planar shape of the compartments in each compartment of a formwork whose interior is divided into a plurality of compartments by a partition member satisfying the following formulas (1) and (2). A plate or a natural stone-like plate is placed by applying an adhesive on its upper surface, and the inorganic aggregate mainly composed of shirasu balloon whose surface is coated with water glass containing a curing agent is layered on the adhesive-coated surface. Laminate, pressurize at room temperature or under heat,
A method for producing an inorganic lightweight decorative board, which comprises reacting the curing agent with water glass. O <t '/ T≤0.8 (1) 1.5≤T / w'≤10 (2) (where T represents the thickness of natural stone or natural stone-like plate,
(t 'indicates the height of the partition member, and w'indicates the width of the partition member)
JP5895192A 1992-02-10 1992-02-10 Inorganic lightweight decorative laminated sheet and its production Pending JPH05221746A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP5895192A JPH05221746A (en) 1992-02-10 1992-02-10 Inorganic lightweight decorative laminated sheet and its production

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP5895192A JPH05221746A (en) 1992-02-10 1992-02-10 Inorganic lightweight decorative laminated sheet and its production

Publications (1)

Publication Number Publication Date
JPH05221746A true JPH05221746A (en) 1993-08-31

Family

ID=13099141

Family Applications (1)

Application Number Title Priority Date Filing Date
JP5895192A Pending JPH05221746A (en) 1992-02-10 1992-02-10 Inorganic lightweight decorative laminated sheet and its production

Country Status (1)

Country Link
JP (1) JPH05221746A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2012102509A (en) * 2010-11-09 2012-05-31 Torio Ceramics Kk Sheet building material
EP2129518B1 (en) 2007-03-23 2019-05-08 Imerys Filtration Minerals, Inc. Metal compound coated particulate mineral materials, methods of making them, and uses thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2129518B1 (en) 2007-03-23 2019-05-08 Imerys Filtration Minerals, Inc. Metal compound coated particulate mineral materials, methods of making them, and uses thereof
JP2012102509A (en) * 2010-11-09 2012-05-31 Torio Ceramics Kk Sheet building material

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