JPH05171570A - Spray-type sizing agent composition - Google Patents
Spray-type sizing agent compositionInfo
- Publication number
- JPH05171570A JPH05171570A JP3338535A JP33853591A JPH05171570A JP H05171570 A JPH05171570 A JP H05171570A JP 3338535 A JP3338535 A JP 3338535A JP 33853591 A JP33853591 A JP 33853591A JP H05171570 A JPH05171570 A JP H05171570A
- Authority
- JP
- Japan
- Prior art keywords
- sizing agent
- spray
- composition
- polymer
- agent composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
Description
【０００１】[0001]
【産業上の利用分野】本発明はスプレー型糊剤組成物に
関する。更に詳しくは、付着した汚れを容易に除去する
ことができるスプレー型糊剤組成物に関する。FIELD OF THE INVENTION The present invention relates to a spray type paste composition. More specifically, it relates to a spray type sizing agent composition capable of easily removing attached dirt.
【０００２】[0002]
【従来の技術及びその課題】スプレー型の糊剤は手軽に
使用することができるので便利である。スプレー型糊剤
は部分的な糊付け、特に襟、袖部分の糊付けに好適であ
る。この襟、袖部分は人体に密着し摩擦等を受けるため
汚れが付着すると通常の洗濯においてはなかなか汚れが
脱落し難く、ブラシ等で部分洗いをしているのが通例で
ある。一般に市販されているスプレー型糊剤の主成分は
低粘度化した化工澱粉が使用されている。このような糊
剤は一般的に汚れの脱落性を容易にする性質をもってい
るが、帯電防止効果に関しては不充分であり、特に化学
繊維や混紡の衣料では静電気による汚れの付着や黒ずみ
の問題が残っている。2. Description of the Related Art A spray type sizing agent is convenient because it can be used easily. The spray type sizing agent is suitable for partial sizing, particularly sizing for the collar and sleeves. Since these collars and sleeves are in close contact with the human body and are subject to friction and the like, if dirt is attached, it is difficult for the dirt to come off during normal washing, and it is customary to carry out partial washing with a brush or the like. Generally, the main component of the commercially available spray type sizing agent is a modified starch having a low viscosity. Although such a sizing agent generally has the property of facilitating the removal of stains, it is insufficient in terms of the antistatic effect, and especially in the case of chemical fibers and clothing made of blended fabrics, there is a problem of stain attachment and darkening due to static electricity. Remaining.
【０００３】[0003]
【課題を解決するための手段】本発明者らは上記課題を
解決すべく鋭意研究を重ねた結果、下記の一般式(1)[Means for Solving the Problems] As a result of intensive studies conducted by the present inventors to solve the above problems, the following general formula (1)
【０００４】[0004]
【化２】 [Chemical 2]
【０００５】〔式中、R1，R2は炭素数１〜18のアルキル
基、ヒドロキシアルキル基、X はハロゲン、-CH3SO4 又
は-C2H5SO4を示す。n は分子量が1000〜600 万となる数
である。〕で表される構造を有するジアリルジアルキル
アンモニウム塩を重合して得られる重合物が、糊剤とし
ての造膜性と帯電防止性の両機能を兼ね備えており、従
来の糊剤と同程度の張り性を持ち、且つ従来の糊剤より
帯電防止効果が著しく高まることを見出し、本発明を完
成するに至った。[In the formula, R 1 and R 2 represent an alkyl group having 1 to 18 carbon atoms, a hydroxyalkyl group, X represents halogen, —CH 3 SO 4 or —C 2 H 5 SO 4 ). n is a number with a molecular weight of 10 to 6 million. ] A polymer obtained by polymerizing a diallyldialkylammonium salt having a structure represented by the following has both the function of forming a film as a sizing agent and the function of antistatic property, and has the same degree of tension as a conventional sizing agent. It has been found that the anti-static effect is significantly higher than that of the conventional sizing agent and that the present invention is completed.
【０００６】すなわち本発明は、下記の一般式(1) で表
される構造を有する重合物を主成分とすることを特徴と
するスプレー型糊剤組成物を提供するものである。[0006] That is, the present invention provides a spray type paste composition comprising a polymer having a structure represented by the following general formula (1) as a main component.
【０００７】[0007]
【化３】 [Chemical 3]
【０００８】〔式中、R1，R2は炭素数１〜18のアルキル
基、ヒドロキシアルキル基、X はハロゲン、-CH3SO4 又
は-C2H5SO4を示す。n は分子量が1000〜600 万となる数
である。〕。[In the formula, R 1 and R 2 represent an alkyl group having 1 to 18 carbon atoms, a hydroxyalkyl group, X represents halogen, —CH 3 SO 4 or —C 2 H 5 SO 4 ]. n is a number with a molecular weight of 10 to 6 million. ].
【０００９】本発明の糊剤の主成分であるジアリルジア
ルキルアンモニウム塩を重合して得られる重合物の分子
量は、1000〜600 万が好ましく、更に好ましくは5000〜
100万、特に好ましくは１万〜50万の範囲である。分子
量が1000よりも小さい場合には十分な張り性能と汚れ落
とし効果が得られないし、また600 万よりも大きい場合
にはスプレー性が良好でなくなるために好ましくない。The molecular weight of the polymer obtained by polymerizing the diallyldialkylammonium salt which is the main component of the sizing agent of the present invention is preferably from 10 to 6 million, more preferably from 5000 to
The range is 1,000,000, particularly preferably 10,000 to 500,000. When the molecular weight is less than 1000, sufficient tensioning performance and stain removal effect cannot be obtained, and when it is more than 6 million, the sprayability is not good, which is not preferable.
【００１０】上記の一般式(1) で表される構造を有する
重合物は、例えば式中のR1及びR2がメチル基でX がClの
場合は、ジアリルジメチルアンモニウムクロライドを重
合開始触媒により重合して得ることができる。重合開始
触媒の種類により−OC6H5 、−OC4H9 等の異なる末端が
生成する。また、重合時の溶媒の種類によっては水素引
抜き反応により末端がH になる場合もある。また、本発
明の重合体としては、DADMAC・POLYMER （東洋ケミカル
ズ株式会社製）の商品名で市販されているものが使用で
きる。本発明の糊剤の主成分である前記一般式(1) で表
される構造を有する重合物は何れもその塩を用いること
ができる。また、この重合物は組成物中に 0.2〜10重量
％、好ましくは 0.5〜５重量％配合される。The polymer having the structure represented by the above general formula (1) can be prepared, for example, by using diallyldimethylammonium chloride as a polymerization initiation catalyst when R 1 and R 2 are methyl groups and X is Cl. It can be obtained by polymerization. -OC 6 H 5 according to the type of the polymerization initiator catalyst, different ends of such -OC 4 H 9 is produced. In addition, depending on the type of solvent used during polymerization, the terminal may become H 2 due to the hydrogen abstraction reaction. Further, as the polymer of the present invention, those commercially available under the trade name of DADMAC POLYMER (manufactured by Toyo Chemicals Co., Ltd.) can be used. As the main component of the sizing agent of the present invention, a salt thereof can be used for any of the polymers having the structure represented by the general formula (1). Further, this polymer is blended in the composition in an amount of 0.2 to 10% by weight, preferably 0.5 to 5% by weight.
【００１１】本発明のスプレー型糊剤組成物には更に、
ポリビニルアルコール、化工澱粉、カルボキシメチルセ
ルロース、ヒドロキシアルキルセルロース等の水溶性高
分子を張り向上のために添加したり、クエン酸、リンゴ
酸、安息香酸、酒石酸等の有機酸、ポリエチレングリコ
ール、グリセリン、ポリプロピレングリコールの如きア
イロン付着防止剤、シリコーンの如きアイロンすべり
剤、エチルアルコール、プロピルアルコール等の如き低
級アルコール、ポリオキシエチレンアルキルエーテルの
如き浸透剤、その他の蛍光染料、殺菌剤、香料、更にエ
アゾールとして使用する場合には罐腐食防止剤の如き添
加剤が加えられる。The spray-type paste composition of the present invention further comprises
Add water-soluble polymers such as polyvinyl alcohol, modified starch, carboxymethyl cellulose, hydroxyalkyl cellulose, etc. to improve adhesion, and organic acids such as citric acid, malic acid, benzoic acid, tartaric acid, polyethylene glycol, glycerin, polypropylene glycol. Such as iron anti-sticking agent, ironing agent such as silicone, lower alcohol such as ethyl alcohol and propyl alcohol, penetrant such as polyoxyethylene alkyl ether, other fluorescent dye, germicide, fragrance, and aerosol In some cases additives such as corrosion inhibitors are added.
【００１２】本発明のスプレー型糊剤組成物はポンプ式
或いはトリガー式のスプレー容器に充填し使用しても良
いが、エアゾール用の耐圧罐に噴射剤と共に充填し使用
することもできる。この時の噴射剤としては液化プロパ
ン、液化ブタン、及びそれらの混合物、或いはジメチル
エーテルを使用するのが良い。噴射剤と本発明の組成物
との重量比率は噴射剤：本発明組成物＝３：97〜40：60
が好ましく、更に好ましくは５：95〜30：70である。The spray-type paste composition of the present invention may be used by filling it in a pump-type or trigger-type spray container, but it can also be used by filling it with a propellant in a pressure can for an aerosol. At this time, liquefied propane, liquefied butane, a mixture thereof, or dimethyl ether is preferably used as the propellant. The weight ratio of the propellant to the composition of the present invention is as follows: propellant: composition of the present invention = 3: 97 to 40:60.
Is preferred, and more preferably 5:95 to 30:70.
【００１３】本発明に係わるスプレー型糊剤組成物で
襟、袖等を処理した衣類は着用により汚れが付着して
も、普通の洗濯により汚れが脱落し、もみ洗い、ブラシ
洗い等の部分洗いの必要がない。また、本発明のスプレ
ー型糊剤組成物は帯電防止性能に優れているため、静電
気による衣料への汚れの付着を防ぐことができる。Clothes whose collars, sleeves, etc. have been treated with the spray type adhesive composition according to the present invention can be removed by ordinary washing even if stains adhere to the clothes, and partial washing such as chaffing and brush washing. No need for Further, since the spray type sizing agent composition of the present invention has excellent antistatic performance, it is possible to prevent dirt from adhering to clothing due to static electricity.
【００１４】[0014]
【実施例】以下、更に具体的に本発明を説明するために
実施例を示すが、本発明はこれらの実施例に限定される
ものではない。EXAMPLES Examples will be shown below to more specifically describe the present invention, but the present invention is not limited to these examples.
【００１５】実施例１ 以下に示す構造を有するポリマーを２重量％と0.5 ％シ
リコーンエマルジョン（5000cs；有効分35％）を水に溶
解し、試験液とした。この試験液をトリガー式容器に充
填し、カンチレバー法（JIS L 1096）により張り性能を
評価し、また、帯電防止性能の測定を行った。Example 1 2% by weight of a polymer having the structure shown below and 0.5% silicone emulsion (5000cs; effective content 35%) were dissolved in water to prepare a test solution. This test solution was filled in a trigger type container, the tension performance was evaluated by the cantilever method (JIS L 1096), and the antistatic performance was measured.
【００１６】[0016]
【化４】 [Chemical 4]
【００１７】[0017]
【化５】 [Chemical 5]
【００１８】＜張り性能の評価＞上記の試験液を、ポリ
エステル／綿＝65／35ブロード60番に100 ％ o.w.f (of
weight fabric)になるように均一にスプレーし、アイロ
ンの温度目盛りを綿にしてアイロンがけして乾燥させ
た。20℃、65％で調湿した後、カンチレバー法で張り性
能の評価を行った。 ＜帯電防止性能の評価＞上記で用いた、アイロンがけさ
れ調湿した後の布の表面抵抗値を測定し、帯電防止性能
の評価を行なった。これらの結果を表１に示す。<Evaluation of Tensile Performance> The above test solution was applied to polyester / cotton = 65/35 broad No. 60 at 100% owf (of
sprayed evenly to give a weight fabric), ironed on an iron temperature scale and ironed to dry. After conditioning the humidity at 20 ° C and 65%, the tension performance was evaluated by the cantilever method. <Evaluation of Antistatic Performance> The antistatic performance was evaluated by measuring the surface resistance value of the cloth used above after being ironed and subjected to humidity control. The results are shown in Table 1.
【００１９】[0019]
【表１】 [Table 1]
【００２０】実施例２ 実施例１で用いた本発明ポリマー(c) ，(d) 及び比較ポ
リマー(e) を各２重量％と0.5 ％シリコーンエマルジョ
ン（5000cs；有効分35％）を水に溶解し、試験液とし
た。この試験液と液化プロパンガス（内圧3.1 kg／cm2,
20℃）とを試験液：液化プロパンガス80：20の重量比率
でエアゾール缶に充填し、充分に震盪した後、実施例１
と同様に張り性能及び表面抵抗値の測定を行った。その
結果を表２に示す。Example 2 2% by weight of each of the polymers (c) and (d) of the present invention used in Example 1 and the comparative polymer (e) and a 0.5% silicone emulsion (5000 cs; effective content 35%) were dissolved in water. Was used as a test solution. This test liquid and liquefied propane gas (internal pressure 3.1 kg / cm 2 ,
(20 ° C) and a test solution: liquefied propane gas in a weight ratio of 80:20 were filled in an aerosol can and shaken sufficiently, and then, in Example 1.
The tension performance and the surface resistance value were measured in the same manner as in. The results are shown in Table 2.
【００２１】[0021]
【表２】 [Table 2]
Claims (1)
る重合物を主成分とすることを特徴とするスプレー型糊
剤組成物。 【化１】 〔式中、R1，R2は炭素数１〜18のアルキル基、ヒドロキ
シアルキル基、X はハロゲン、-CH3SO4 又は-C2H5SO4を
示す。n は分子量が1000〜600 万となる数である。〕1. A spray type paste composition comprising a polymer having a structure represented by the following general formula (1) as a main component. [Chemical 1] [Wherein, R 1, R 2 is an alkyl group having 1 to 18 carbon atoms, hydroxyalkyl group, X is a halogen, a -CH 3 SO 4 or -C 2 H 5 SO 4. n is a number with a molecular weight of 10 to 6 million. ]
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3338535A JP2986600B2 (en) | 1991-12-20 | 1991-12-20 | Spray type paste composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3338535A JP2986600B2 (en) | 1991-12-20 | 1991-12-20 | Spray type paste composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH05171570A true JPH05171570A (en) | 1993-07-09 |
| JP2986600B2 JP2986600B2 (en) | 1999-12-06 |
Family
ID=18319085
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP3338535A Expired - Fee Related JP2986600B2 (en) | 1991-12-20 | 1991-12-20 | Spray type paste composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2986600B2 (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AT501416A1 (en) * | 2005-02-15 | 2006-08-15 | Leopold Franzens Uni Innsbruck | METHOD AND SUBSTANCE MIXTURE FOR INCREASING THE SURFACE ACCURACY OF HYDROPHOBIC POLYMERS |
| CN102959011A (en) * | 2010-04-23 | 2013-03-06 | 拜耳知识产权有限责任公司 | Polymeric anti-static agent |
-
1991
- 1991-12-20 JP JP3338535A patent/JP2986600B2/en not_active Expired - Fee Related
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AT501416A1 (en) * | 2005-02-15 | 2006-08-15 | Leopold Franzens Uni Innsbruck | METHOD AND SUBSTANCE MIXTURE FOR INCREASING THE SURFACE ACCURACY OF HYDROPHOBIC POLYMERS |
| AT501416B1 (en) * | 2005-02-15 | 2007-11-15 | Leopold Franzens Uni Innsbruck | METHOD AND SUBSTANCE MIXTURE FOR INCREASING THE SURFACE ACCURACY OF HYDROPHOBIC POLYMERS |
| CN102959011A (en) * | 2010-04-23 | 2013-03-06 | 拜耳知识产权有限责任公司 | Polymeric anti-static agent |
| US20130109809A1 (en) * | 2010-04-23 | 2013-05-02 | Bayer Intellectual Property Gmbh | Polymeric anti-static agent |
| US9290590B2 (en) * | 2010-04-23 | 2016-03-22 | Bayer Intellectual Property Gmbh | Polymeric anti-static agent |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2986600B2 (en) | 1999-12-06 |
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