JPH05165171A - Silver halide color photographic sensitive material - Google Patents

Abstract

PURPOSE:To enhance sensitivity and color development density and to prevent occurrence of color turbidity and color fog by incorporating a specified acyl group having a specified coupler and a specified compound. CONSTITUTION:The silver halide color photographic sensitive material contains the acyl group having the acylacetamido type yellow dye-forming cupler represented by formula I and at least one of the noncolor-developing and diffusion-resistant compounds represented by formulae II-VIII. In formulae I-VIII, R1 is a monovalent group; Q stands for a specified nonmetallic atomic group together with the adjacent C atom; R<21> is H or an aliphatic or heterocyclic group; each of R<31> and R<41> is H or an aliphatic group or the like; each of R<12>, R<22>, R<32>, and R<71> is is H, alkyl, or the like; R<42> is cyano or the like; each of G<31>, G<51>, and G<71> is -SO2- or the like; each of R<13>, R<23>, R<33>, R<43>, R<53>, R<73>, R<14>, R<24>, R<34>, R<44>, R<54>, and R<74> is H or a group removable under alkaline conditions; R<73> is alkyl; R<11> is a group substitutable on the benzene ring; Y<61> is a divalent group; and each of L<61> and L<62> is a divalent bonding group.

Description

Detailed Description of the Invention

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a silver halide color photographic light-sensitive material, and more specifically, it contains a specific yellow dye-forming coupler (referred to as yellow coupler) and a hydrazine compound and is excellent in color developability, color turbidity, and color turbidity. The present invention relates to a silver halide color photographic light-sensitive material in which generation of fog is suppressed, graininess and sharpness are improved, and storage stability is improved.

[0002]

It is well known in the prior art that silver halide color light-sensitive materials cause undesirable color contamination between different color-sensitive layers. As a means to prevent these,
For example, US Patent Nos. 2336327 and 4277553.
A method using a hydroquinone compound has been proposed. Certainly, these compounds have some effect in preventing color contamination, but the effect is small, and after the anti-effect effect is expressed, a colored product is formed, and photographic performance changes during the production of sensitive materials and storage. There was a problem.

On the other hand, a compound and a coupler which release a compound similar to the compound of the present invention by reaction with an oxidized product of a color developing agent have been proposed in US Pat. No. 4,390,618 and the like. However, these compounds are different from the compound of the present invention in that they have a coupler color-forming unit and a redox unit, and their effects and the mechanism for expressing them are also different from the present invention. In addition, JP-A-62-27
No. 731 proposes to use a compound similar to the compound of the present invention, but the above-mentioned patent requires that the compound has diffusibility and interacts with a silver halide emulsion. In the invention, it is necessary to be diffusion resistant, it is not preferable to interact with the emulsion, and the effect is completely different.

A silver halide color photographic light-sensitive material containing a diffusion-resistant hydrazine compound as a scavenger for a further oxidized developing agent is disclosed in JP-A-1-147455.
No. 2, No. 2-12239, No. 3-150560, No. 3
-150561, 3-150562, 3-15
It is disclosed in No. 4051 and No. 3-164735.

On the other hand, European Patent Application Publication (EP) 447
The yellow coupler described in No. 969A is an acylacetamide type yellow coupler having a specific cyclic structure in an acyl group, and has excellent color forming performance (high coupling reactivity and high color density) and a spectral absorption spectrum of a sharp color image. It is characterized by giving a vector.

However, when the coupler was introduced into a silver halide color photographic light-sensitive material having a multilayer structure, the color turbidity was unexpectedly increased. Further, the graininess and sharpness were inferior to those of the conventional yellow coupler.

As a measure against this problem, it is common to add a hydroquinone compound to the photosensitive silver halide emulsion layer and / or the non-photosensitive layer. However, although this method has a certain effect, it is still insufficient,
Rather, in terms of storability, it resulted in deterioration of performance such as increased fog.

[0008]

SUMMARY OF THE INVENTION Therefore, the first object of the present invention is to provide a silver halide color photographic light-sensitive material having high sensitivity, high color density, color turbidity and suppressed color fog. is there. The second object of the present invention is to provide a silver halide color photographic light-sensitive material having improved graininess and sharpness. Thirdly, an object of the present invention is to provide a silver halide color photographic light-sensitive material which has little change in photographic performance during storage and is excellent in storability.

[0009]

These objects of the present invention have been achieved by the silver halide color photographic light-sensitive materials shown in the following (1) and (2). (1) At least one red-sensitive silver halide emulsion layer, at least one green-sensitive silver halide emulsion layer on a support,
In a silver halide color photographic light-sensitive material having at least one blue-sensitive silver halide emulsion layer and at least one non-photosensitive layer, at least an acylacetamide type yellow dye-forming coupler having an acyl group represented by the following general formula (1): One and the following general formulas (2), (3),
(4), (5), (6), (7) or (8) A non-color-forming and diffusion-resistant compound represented by at least one selected from the group of silver halide color characterized by containing Photographic material. General formula (1)

[0010]

[Chemical 9]

[In the formula, R ₁ represents a monovalent group. Q is C
Together with a 3- to 5-membered hydrocarbon ring or N, O, S, P
Represents a nonmetallic atom group necessary for forming a 3- to 5-membered heterocycle having at least one heteroatom selected from However, R ₁ is not a hydrogen atom,
It does not combine with Q to form a ring. ] General formula (2)

[0012]

[Chemical 10]

General formula (3)

[0014]

[Chemical 11]

General formula (4)

[0016]

[Chemical 12]

General formula (5)

[0018]

[Chemical 13]

General formula (6)

[0020]

[Chemical 14]

General formula (7)

[0022]

[Chemical 15]

General formula (8)

[0024]

[Chemical 16]

[In the formula, R ²¹ is a hydrogen atom, an aliphatic group or a heterocyclic group, R ³¹ and R ⁴¹ are a hydrogen atom, an aliphatic group, an aromatic group or a heterocyclic group, and R ¹² , R ²² , R ³² , R
⁷¹ is a hydrogen atom, an alkyl group, an aralkyl group, an aryl group, a heterocyclic group, an alkoxy group, an aryloxy group, an amino group, an alkenyl group, an alkynyl group or a hydrazino group, and R ⁴² is a cyano group, a nitro group or a peroxy group. Is a fluoroalkyl group or a thioacyl group, G ³¹ is —SO
_{2 -, - SO -, -} PO (R 35) -, a iminomethylene or -COCO-, R ³⁵ is an alkyl group or an aryl group, those G ^51, G ⁷¹ is described in G ^31, - CO-
And R ¹³ , R ²³ , R ³³ , R ⁴³ , R ⁵³ ,
R ⁷³ , R ¹⁴ , R ²⁴ , R ³⁴ , R ⁴⁴ , R ⁵⁴ , and R ⁷⁴ are a hydrogen atom or a group that is removed under alkaline conditions, R ⁷³ may be an alkyl group, and R ¹¹ may be a benzene ring. Is a substituent,
Z ⁵¹ is a group necessary for forming a ring, Y ⁶¹ is a divalent group having a hydrazine or hydroxylamine structure, L ⁶¹ and L ⁶² are divalent linking groups, and n, m and q Is 0, 1 or 2, and j and k are 0 or 1. The groups described above may have a substituent. ]

(2) The non-photosensitive layer has the general formula (2),
(3), (4), (5), (6), (7) or at least one selected from the group of compounds represented by (8) is contained in the above item (1). Silver halide color photographic light-sensitive material.

The acylacetamide-type yellow dye-forming coupler (hereinafter referred to as the yellow coupler of the present invention) and the general formula (2) to which the acyl group used in the present invention is represented by the general formula (1). The compound represented by (8) will be described in detail. The acylacetamide type yellow coupler of the present invention is preferably represented by the following general formula [Y]. Formula [Y]

[0028]

[Chemical 17]

In the formula [Y], R ₁ is a monovalent substituent except a hydrogen atom, and Q is selected from C and a 3- to 5-membered hydrocarbon ring or at least one N, S, O, P. R ₂ is a hydrogen atom or a halogen atom (F, Cl, Br, I. The following formula [Y] represents a non-metal atom group necessary for forming a 3- to 5-membered heterocyclic ring containing a hetero atom in the ring. The same in the description), an alkoxy group, an aryloxy group, an alkyl group or an amino group, and R ₃ is a group capable of substituting on the benzene ring,
X represents a hydrogen atom or a group capable of leaving by a coupling reaction with an oxidation product of an aromatic primary amine developing agent (hereinafter referred to as leaving group), and n represents an integer of 0 to 4. However, when 1 is plural, plural R ₃ may be the same or different.

Examples of R ₃ are halogen atom, alkyl group, aryl group, alkoxy group, aryloxy group, alkoxycarbonyl group, aryloxycarbonyl group, carbonamide group, sulfonamide group, carbamoyl group, sulfamoyl group, Alkylsulfonyl group, ureido group, sulfamoylamino group, alkoxycarbonylamino group, aryloxysulfonyl group, acyloxy group, nitro group, heterocyclic group, cyano group, acyl group, acyloxy group, alkylsulfonyloxy group, arylsulfonyloxy group Examples of the leaving group include a heterocyclic group bonded to the coupling active position with a nitrogen atom, an aryloxy group, an arylthio group, an acyloxy group, an alkylsulfonyloxy group, an arylsulfonyloxy group, a heterocyclic oxy group, and a halo group. There is a down atom.

The substituents preferably used in formula [Y] will be described below. In the formula [Y], R ₁ is preferably a halogen atom, a cyano group, or the total number of carbon atoms (hereinafter abbreviated as C number) 1 to 30 which may be substituted.
A monovalent group (eg, an alkyl group, an alkoxy group, an alkylthio group) or a monovalent group having a C number of 6 to 30 (eg, an aryl group, an aryloxy group, an arylthio group), and the substituent thereof is, for example, halogen. There are atoms, alkyl groups, alkoxy groups, nitro groups, amino groups, carbonamide groups, sulfonamide groups, and acyl groups.

In the formula [Y], Q is preferably a C number of 3 to 3 which may be substituted with C in any of 3 to 5 members.
It represents a group of non-metal atoms necessary for forming a hydrocarbon ring of 0 or a heterocycle having a C number of 2 to 30 containing at least one hetero atom selected from N, S, O and P in the ring. Also,
The ring formed by Q together with C may contain an unsaturated bond in the ring. Examples of the ring formed by Q together with C include a cyclopropane ring, a cyclobutane ring, a cyclopentane ring, a cyclopropene ring, a cyclobutene ring, a cyclopentene ring, an oxetane ring, an oxolane ring, a 1,3-dioxolane ring, a thietane ring, There are thiolane ring and pyrrolidine ring. Examples of the substituent include a halogen atom, a hydroxyl group, an alkyl group, an aryl group, an acyl group, an alkoxy group, an aryloxy group, a cyano group, an alkoxycarbonyl group, an alkylthio group and an arylthio group.

In the formula [Y], R ₂ is preferably a halogen atom, which may be substituted, and has a C number of 1 to 30.
Alkoxy group, aryloxy group having 6 to 30 C, C
It represents an alkyl group having 1 to 30 or an amino group having 0 to 30 carbon atoms, and examples of the substituent include a halogen atom, an alkyl group, an alkoxy group, and an aryloxy group.

In the formula [Y], R ₃ is preferably a halogen atom, any of which may be substituted, an alkyl group having 1 to 30 C atoms, an aryl group having 6 to 30 C atoms, or 1 to 30 C atoms.
Alkoxy group, C2-30 alkoxycarbonyl group, C7-30 aryloxycarbonyl group, C1-30 carbonamido group, C1-30 sulfonamide group, C1-30 Carbamoyl group, C number 0-3
0 sulfamoyl group, C 1-30 alkylsulfonyl group, C 6-30 arylsulfonyl group, C 1
To 30 ureido group, C number 0 to 30 sulfamoylamino group, C number 2 to 30 alkoxycarbonylamino group, C number 1 to 30 heterocyclic group, C number 1 to 30 acyl group, C number It represents an alkylsulfonyloxy group having 1 to 30 or an arylsulfonyloxy group having 6 to 30 carbon atoms, and examples of the substituent thereof include a halogen atom, an alkyl group, an aryl group, a heterocyclic group, an alkoxy group, an aryloxy group and a hetero group. Ring oxy group, alkylthio group, arylthio group, heterocyclic thio group, alkylsulfonyl group, arylsulfonyl group, acyl group, carbonamido group, sulfonamide group, carbamoyl group, sulfamoyl group, alkoxycarbonylamino group, sulfamoylamino group , Ureido group, cyano group, nitro group, acyloxy group, alkoxycarbonyl group, aryl Oxycarbonyl group, an alkylsulfonyloxy group, an arylsulfonyloxy group.

In the formula [Y], n preferably represents an integer of 1 or 2, and the substitution position of R ₃ is preferably meta or para with respect to the acylacetamide group.

In the formula [Y], X preferably represents a heterocyclic group or an aryloxy group bonded to the coupling active position by a nitrogen atom.

When X represents a heterocyclic group, X is preferably a 5- to 7-membered monocyclic or condensed-ring heterocyclic group which may be substituted, and examples thereof include succinimide, maleinimide and phthalimide. , Diglycolimide, pyrrole, pyrazole, imidazole, 1,2,4-triazole, tetrazole, indole, indazole,
Benzimidazole, benzotriazole, imidazolidine-2,4-dione, oxazolidine-2,4-dione, thiazolidine-2,4-dione, imidazolidine-
2-one, oxazolidin-2-one, thiazolidine-
2-one, benzimidazolin-2-one, benzoxazolin-2-one, benzothiazolin-2-one, 2
-Pyrrolin-5-one, 2-imidazolin-5-one,
Indoline-2,3-dione, 2,6-dioxypurine, parabanic acid, 1,2,4-triazolidine-3,5
-Dione, 2-pyridone, 4-pyridone, 2-pyrimidone, 6-pyridazone-2-pyrazone, 2-amino-1,
3,4-thiazolidine, 2-imino-1,3,4-thiazolidin-4-one and the like, and these heterocycles may be substituted.

Examples of the substituents on these heterocycles include halogen atom, hydroxyl group, nitro group, cyano group, carboxyl group, sulfo group, alkyl group, aryl group, alkoxy group, aryloxy group, alkylthio group and arylthio group. Group, alkylsulfonyl group, arylsulfonyl group, alkoxycarbonyl group, aryloxycarbonyl group, acyl group, acyloxy group, amino group, carbonamido group, sulfonamide group, carbamoyl group, sulfamoyl group, ureido group, alkoxycarbonylamino group, There is a sulfamoylamino group.

When X represents an aryloxy group, X preferably represents an aryloxy group having a C number of 6 to 30,
It may be substituted with a group selected from the substituent group mentioned when X is a heterocycle.

Examples of the substituent of the aryloxy group include a halogen atom, a cyano group, a nitro group, a carboxyl group, a trifluoromethyl group, an alkoxycarbonyl group, a carbonamido group, a sulfonamide group, a carbamoyl group, a sulfamoyl group and an alkylsulfonyl group. , An arylsulfonyl group, or a cyano group is preferable.

Substituents particularly preferably used in formula [Y] will be described below.

R ₁ is particularly preferably an alkyl group having a C number of 1 to 30 (eg methyl, ethyl, n-propyl, n-).
(Butyl, isobutyl, n-octyl, n-dodecyl, phenoxymethyl, phenylthiomethyl, p-toluenesulfonylmethyl, benzyl, cyclohexylmethyl, methoxyethyl), most preferably an alkyl group having 1 to 4 C atoms. .

Q is particularly preferably a ring formed with C is 3
It is a group of non-metal atoms forming a 5- to 5-membered hydrocarbon ring, and examples thereof include an ethylene group, a trimethylene group, or a tetramethylene group, all of which may be substituted. Here, as the substituent, an alkyl group, an alkoxy group, an aryl group,
There are halogen atoms.

Q is most preferably a substituted or unsubstituted ethylene group.

R ₂ is particularly preferably a chlorine atom, a fluorine atom, an alkyl group having 1 to 6 C atoms (eg, methyl, trifluoromethyl, ethyl, isopropyl, t-butyl), an alkoxy group having 1 to 8 C atoms. (Eg methoxy, ethoxy, methoxyethoxy, butoxy), or C number 6
~ 24 aryloxy groups (eg phenoxy group, p-
Trilyloxy, p-methoxyphenoxy), most preferably chlorine atom, methoxy group or trifluoromethyl group.

R ₃ is particularly preferably a halogen atom,
A cyano group, a trifluoromethyl group, an alkoxy group, an alkoxycarbonyl group, an aryloxycarbonyl group, a carbonamido group, a sulfonamide group, a carbamoyl group or a flufamoyl group, most preferably a chlorine atom,
It is an alkoxy group, an alkoxycarbonyl group, a sulfamoyl group, a carbonamide group or a sulfonamide group.

X is particularly preferably the following formula [Y-1],
It is a group represented by [Y-2] or [Y-3]. Formula [Y-1]

[0048]

[Chemical 18]

In the formula [Y-1], Z is --O--C (R ₄ ).
_{(R 5) -, - S} -C (R 4) (R 5) -, - N (R 6) -C
_{(R 4) (R 5)} -, - N (R 6) -N (R 7) -, - N (R 6)
-CO -, - represent or _{-C (R 10) = C (} R 11) - C (R 4) (R 5) -C (R 8) (R 9). Where R ₄ ,
R ₅ , R ₈ and R ₉ represent a hydrogen atom, an alkyl group, an aryl group, an alkoxy group, an aryloxy group, an alkylthio group, an arylthio group, an alkylsulfonyl group, an arylsulfonyl group or an amino group, and R ₆ and R
₇ represents a hydrogen atom, an alkyl group, an aryl group, an alkylsulfonyl group, an arylsulfonyl group or an alkoxycarbonyl group, and R ₁₀ and R ₁₁ represent a hydrogen atom, an alkyl group or an aryl group. R ₁₀ and R ₁₁ may combine with each other to form a benzene ring. R ₄ and R ₅ , R ₅
And R _6, R ₆ and R ₇ or R ₄ and R ₈ are bonded with each other to form a ring (e.g. cyclobutane, cyclohexane, cycloheptane, cyclohexene, pyrrolidine, piperidine) may be formed.

Among the heterocyclic groups represented by the formula [Y-1], particularly preferable ones are those in which Z is -O- in the formula [Y-1].
_{C (R 4) (R 5} ) -, - N (R 6) -C (R 4) (R 5) - or _{-N (R 6) -N (R} 7) - is a heterocyclic group which is. The C number of the heterocyclic group represented by the formula [Y-1] is 2 to 30, preferably 4 to 20, and more preferably 5 to 16.

Formula [Y-2]

[0052]

[Chemical 19]

In the formula [Y-2], at least one of R ₁₂ and R ₁₃ is a halogen atom, a cyano group, a nitro group,
A group selected from a trifluoromethyl group, a carboxyl group, an alkoxycarbonyl group, a carbonamido group, a sulfonamide group, a carbamoyl group, a sulfamoyl group, an alkylsulfonyl group, an arylsulfonyl group or an acyl group, and the other is a hydrogen atom, It may be an alkyl group or an alkoxy group. R ₁₄ represents a group having the same meaning as R ₁₂ or R ₁₃ and m represents an integer of 0-2. Formula [Y-
The C number of the aryloxy group represented by 2] is 6 to 30, preferably 6 to 24, and more preferably 6 to 15.

Formula [Y-3]

[0055]

[Chemical 20]

In the formula [Y-3], W is N together with a pyrrole ring, a pyrazole ring, an imidazole ring, 1, 2, 3
-Represents a non-metal atom group necessary for forming a triazole ring, a 1,2,4-triazole ring or a tetrazole ring. The heterocyclic group represented by the formula [Y-3] may be substituted, and examples of preferable substituents include a halogen atom, a nitro group, a cyano group, an alkoxycarbonyl group, an alkyl group, an aryl group, an amino group, There are alkoxy groups, aryloxy groups or carbamoyl groups. Formula [Y-
The C number of the heterocyclic group represented by 3] is 2 to 30, preferably 2 to 24, more preferably 2 to 16.

X is most preferably a group represented by the formula [Y-1].

The coupler represented by the formula [Y] is a dimer or more of the substituents R ₁ , R ₂ , R ₃ , Q or X which are bonded to each other via a bond or a divalent or higher valent group. You may form the multimer of. In this case, the number of carbon atoms shown in each of the above substituents may be out of the specified range.

Specific examples of the yellow coupler represented by the formula [Y] are shown below.

[0060]

[Chemical 21]

[0061]

[Chemical formula 22]

[0062]

[Chemical formula 23]

[0063]

[Chemical formula 24]

[0064]

[Chemical 25]

[0065]

[Chemical formula 26]

[0066]

[Chemical 27]

[0067]

[Chemical 28]

[0068]

[Chemical 29]

[0069]

[Chemical 30]

[0070]

[Chemical 31]

[0071]

[Chemical 32]

The yellow coupler represented by the formula [Y] can be synthesized by a conventionally known synthesis method, for example, European Patent Application (EP) No. 4
It can be synthesized by the method described in No. 47969A.

The coupler represented by the formula [Y] can be used in any layer in the light-sensitive material. That is,
Any of a light-sensitive layer (blue-sensitive emulsion layer, green-sensitive emulsion layer, red-sensitive emulsion layer) and non-light-sensitive layer (for example, protective layer, yellow filter layer, intermediate layer, antihalation layer) can be used. It is preferably used in the blue-sensitive emulsion layer or a non-light-sensitive layer adjacent thereto.

The amount of the coupler represented by the formula [Y] is preferably 0.05 to 5.0 mmol / m ² , more preferably 0.2 to 2.0 mmol / m ² .

When the coupler represented by the formula [Y] is used in the light-sensitive layer, the molar ratio of the coupler to the silver halide is in the range of 1: 0.1 to 1: 200, more preferably 1 : 2-1: 200. When used in the non-photosensitive layer, the amount is preferably 2.0 to 0.01 mol with respect to the silver halide in the adjacent silver halide emulsion layer.

The coupler represented by the formula [Y] may be used alone or in combination with another yellow coupler (for example, a benzoylacetanilide type yellow coupler or a pivaloylacetanilide type yellow coupler).

Next, the compounds represented by the general formulas (2) to (8) will be described in more detail. R ²¹ , R ³¹ ,
The aliphatic group represented by R ⁴¹ is a linear, branched or cyclic alkyl group having 1 to 30 carbon atoms, an aralkyl group, an alkenyl group or an alkynyl group, and examples thereof include those described for R ¹² . Examples of the aromatic group for R ³¹ and R ⁴¹ include phenyl and naphthyl, with phenyl being preferred. R ²¹ ,
The heterocyclic group for R ³¹ and R ⁴¹ is saturated or unsaturated,
It may be a monocyclic ring or a condensed ring, and examples thereof include pyridyl, imidazolyl, thiazolyl, quinolyl, morpholino and thienyl. R ¹¹ is, for example, an alkyl group, an acylamino group,
Sulfonylamino group, ureido group, urethane group, alkoxy group, aryloxy group, hydroxy group, carboxyl group, aryl group, carbamoyl group, sulfamoyl group, alkylthio group, arylthio group, sulfonyl group,
Sulfinyl group, acyl group, halogen atom, cyano group,
It is a heterocyclic group or a sulfo group, more preferably an acylamino group, a sulfonylamino group, a ureido group, a urethane group or an alkoxy group.

The alkyl groups of R ¹² , R ²² , R ³² and R ⁷¹ are
A straight chain, branched chain or cyclic group having 1 to 30 carbon atoms, such as methyl, cyclohexyl, 2-octyl or octadecyl. The aralkyl group has a carbon number of 7 to 30, and examples thereof include benzyl, phenethyl and trityl.
The aryl group has 6 to 30 carbon atoms, and examples thereof include phenyl and naphthyl. The heterocyclic group is as described for R ²¹ . The alkoxy group has 1 to 3 carbon atoms.
0, for example, methoxy, octyloxy, 2-pentyloxy, benzyloxy, cyclohexyloxy. The aryloxy group has 6 to 30 carbon atoms, and examples thereof include phenoxy and naphthyloxy. The amino group is a substituted or unsubstituted group, and the substituent is an alkyl, aryl or heterocycle having 1 to 30 carbon atoms.
The alkenyl group has 2 to 30 carbon atoms, and examples thereof include vinyl and 1-dodecenyl. The alkynyl group has 2 to 30 carbon atoms and is, for example, ethynyl, 1-octynyl or 2-phenylethynyl.

As the hydrazino group, R ^{31 of the} general formula (4) is used.
^{-N (R 33) N (R} 34) - and the like. The perfluoroalkyl of R ⁴² has a carbon number of 1 to 30, and examples thereof include trifluoromethyl and perfluorooctyl. Thioacyl has 2 to 30 carbon atoms, and examples thereof include thioacetyl and thiobenzoyl. R ^{13 to} R ⁷³ , R ¹⁴
As the groups to be removed under alkaline conditions of R ⁷⁴ to R ⁷⁴ , those having 20 or less carbon atoms, and examples thereof include an alkylsulfonyl group, an arylsulfonyl group, an acyl group, a dialkylaminomethyl group and a hydroxymethyl group. R ¹³ ~
A hydrogen atom is preferable as R ⁷³ and R ^{14 to} R ⁷⁴ . Z ^{51 in the} general formula (6) is methylene, ethylene, trimethylene, —CO—, 1,2-phenylene, —O—, —S.
It is a divalent linking group consisting of-, -NH-, -NHNH-, and combinations thereof, and the ring is preferably a 5- to 8-membered ring.
Of the general formula (7), more preferred is the general formula [7-1]
Is represented by.

[0080]

[Chemical 33]

In the formula, R ⁸¹ is a hydrogen atom, a halogen atom or an alkyl group, and L ⁸¹ is —CO—, —SO ₂ —, —N.
H-, -O-, -S-, phenylene, alkylene, and a divalent linking group consisting of a combination thereof, L ⁸² is a divalent group obtained by removing a hydrogen atom from R ^{31 in the} general formula (4). And G ⁸¹ and R ⁸³ have the same ^meanings as G ³¹ and R ^{33 in} the general formula (4). X is a group derived from an amino group or hydroxy group, respectively -N general formula ^{(4) (R 34) -} (G 31) m
It is synonymous with -R < ³² > and -OR- ⁷⁴ of General formula (8).
r, t, and u are 0 or 1. The above groups may be substituted with the groups described for R ¹¹ . In addition, general formula (2)-
The molecular weight of (6) and (8) is preferably 300 to 150.
0, more preferably 450 to 1000, and further preferably 500 to 800. Two or more of these may be combined to form an oligomer (bis form, tris form, etc.).
It is preferable that R ^{11 to} R ⁷¹ and R ^{12 to} R ⁴² have incorporated therein a ballast group commonly used in a non-moving photographic material such as a coupler. In that case, it is more preferable to have a polar group as a substituent. The polar group is a group having a π value smaller than −1.0 in combination, and examples thereof include hydroxy, sulfonamide, amino, carboxy, carbamoyl, sulfamoyl, ureido and heterocyclic groups.
The compounds represented by the general formulas (2) to (8) may have a group (for example, thiourea, a mercaptoheterocycle or an azole) as a substituent which enhances adsorption on the surface of silver halide.
As the diffusion resistant group, a ballast group is more preferable than an adsorption group on silver halide. Of the general formulas (2) to (8), (2), (3), (4) and (7) are preferable. Specific examples of the compounds represented by the general formulas (2) to (8) of the present invention are shown below, but the invention is not limited thereto.

[0082]

[Chemical 34]

[0083]

[Chemical 35]

[0084]

[Chemical 36]

[0085]

[Chemical 37]

[0086]

[Chemical 38]

[0087]

[Chemical Formula 39]

[0088]

[Chemical 40]

[0089]

[Chemical 41]

[0090]

[Chemical 42]

[0091]

[Chemical 43]

[0092]

[Chemical 44]

[0093]

[Chemical 45]

[0094]

[Chemical 46]

[0095]

[Chemical 47]

[0096]

[Chemical 48]

[0097]

[Chemical 49]

[0098]

[Chemical 50]

[0099]

[Chemical 51]

[0100]

[Chemical 52]

[0101]

[Chemical 53]

[0102]

[Chemical 54]

[0103]

[Chemical 55]

[0104]

[Chemical 56]

The synthesis of these compounds is described in, for example, Japanese Patent Laid-Open No.
-164,735, 3-154,051, 3-15
0,560, 3-150,562, 1-315,7
It can be easily carried out according to the method of the patent described or cited in No. 31.

The compounds represented by the general formulas (2) to (8) can be used in any layer in the light-sensitive material.
That is, a photosensitive layer (blue-sensitive silver halide emulsion layer, green-sensitive silver halide emulsion layer, red-sensitive silver halide emulsion layer),
It can be used in any of the non-photosensitive layers (eg, protective layer, non-photosensitive fine grain silver halide emulsion layer, intermediate layer, filter layer, subbing layer, antihalation layer), but the intermediate layer, particularly the photosensitive emulsion layer. It is preferable to use it for the intermediate layer between (the same color-sensitive layer or different color-sensitive layers).

To add these compounds to these layers, they are dissolved in the coating solution as they are or in an organic solvent having a low boiling point such as alcohol (eg methyl alcohol) which does not affect the silver halide color photographic light-sensitive material. It can also be added. Further, it can be dispersed and impregnated in a polymer such as latex, or can be dissolved in a high boiling point organic solvent and emulsified and dispersed in an aqueous solution.

The total amount added to the light-sensitive material of the present invention is usually 0.
001 to 0.8 g / m ² , preferably 0.005 to
0.5 g / m ² , more preferably 0.01 to 0.3 g / m ²
Is.

The light-sensitive material of the present invention may have at least one layer of a blue-sensitive layer, a green-sensitive layer and a red-sensitive silver halide emulsion layer provided on a support, and a halogen There is no particular limitation on the number and order of layers of the silver halide emulsion layer and the non-photosensitive layer. As a typical example, a silver halide photographic light-sensitive material having at least one light-sensitive layer composed of a plurality of silver halide emulsion layers having substantially the same color sensitivity but different sensitivities on a support. And the photosensitive layer is blue light, green light,
And a unit light-sensitive layer having color sensitivity to red light, and in a multilayer silver halide color photographic light-sensitive material, the unit light-sensitive layers are generally arranged in order from the support side to the red-color-sensitive layer and green. The color sensitive layer and the blue color sensitive layer are installed in this order. However, the order of installation may be reversed depending on the purpose, or the order of installation may be such that different photosensitive layers are sandwiched between the same color-sensitive layers. A non-photosensitive layer such as various intermediate layers may be provided between the above-described silver halide photosensitive layers and as the uppermost layer and the lowermost layer. The intermediate layer includes JP-A Nos. 61-43748 and 59-113.
No. 438, No. 59-113440, No. 61-20037, No. 61-20038 may contain a coupler, a DIR compound, and the like, and a color mixing inhibitor may be used as is usually used. May be included. The plural silver halide emulsion layers constituting each unit light-sensitive layer preferably use a two-layer constitution of a high-sensitivity emulsion layer and a low-sensitivity emulsion layer as described in West German Patent No. 1,121,470 or British Patent No. 923,045. be able to. In general, it is preferable that the layers are arranged so that the photosensitivity is gradually lowered toward the support, and a non-photosensitive layer may be provided between each halogen emulsion layer. In addition,
57-112751, 62-200350, 62-206541, 62-2
As described in No. 06543, a low-sensitivity emulsion layer may be provided on the side farther from the support, and a high-sensitivity emulsion layer may be provided on the side closer to the support. As a specific example, from the side farthest from the support,
Low sensitivity blue photosensitive layer (BL) / High sensitivity blue photosensitive layer (BH) / High sensitivity green photosensitive layer (GH) / Low sensitivity green photosensitive layer (GL) / High sensitivity red photosensitive layer (RH) / Low sensitivity red photosensitive layer (RL) order, or BH / BL / GL / GH / RH / RL order, or BH / BL / GH /
It can be installed in the order of GL / RL / RH. In addition,
As described in JP-A-55-34932, the blue-sensitive layer / GH / RH / GL / RL may be arranged in this order from the side farthest from the support. Also, JP-A-56-25738 and 62-63936
It is also possible to arrange the layers in the order of blue-sensitive layer / GL / RL / GH / RH from the side farthest from the support, as described in the specification. Further, as described in JP-B-49-15495, the upper layer is a silver halide emulsion layer having the highest sensitivity, the middle layer is a silver halide emulsion layer having a lower sensitivity, and the lower layer is more sensitive than the middle layer. An example is an arrangement in which a silver halide emulsion layer having a low degree of sensitivity is arranged, and the layer is composed of three layers having different sensitivities in which the sensitivities are gradually lowered toward the support. Even when it is composed of three layers having different sensitivities, as described in JP-A-59-202464, a medium-sensitivity emulsion from the side distant from the support in the same color-sensitive layer. The layers may be arranged in the order of high-speed emulsion layer / low-speed emulsion layer. In addition, they may be arranged in the order of high-speed emulsion layer / low-speed emulsion layer / medium-speed emulsion layer, or low-speed emulsion layer / medium-speed emulsion layer / high-speed emulsion layer. Also, in the case of four layers or more, the arrangement may be changed as described above. In order to improve color reproducibility, U.S. Pat.Nos. 4,663,271 and 4,70
5,744, 4,707,436, JP-A-62-160448, 6
3- It is preferable to dispose the donor layer (CL) having a multi-layer effect having a spectral sensitivity distribution different from that of the main photosensitive layer such as BL, GL and RL described in the specification of 89850 adjacent to or in proximity to the main photosensitive layer. . As described above, various layer configurations and arrangements can be selected according to the purpose of each light-sensitive material.

The preferred silver halide contained in the photographic emulsion layer of the photographic light-sensitive material used in the present invention contains silver iodobromide, silver iodochloride, or iodochlorobromide containing about 30 mol% or less of silver iodide. It is silver. Particularly preferred is silver iodobromide or silver iodochlorobromide containing from about 2 mol% to about 10 mol% silver iodide. Silver halide grains in photographic emulsions have regular crystals such as cubes, octahedra and tetradecahedrons, grains having irregular crystal forms such as spheres and plates, twin planes, etc. It may have a crystal defect of, or a composite form thereof. The grain size of silver halide is about
It may be fine particles of 0.2 μm or less or large-sized grains having a projected area diameter of up to about 10 μm, and may be a polydisperse emulsion or a monodisperse emulsion. The silver halide photographic emulsion which can be used in the present invention is, for example, Research Disclosure (RD) N.
o.17643 (December 1978), pp. 22-23, "I. Emulsion production (Emu
lsion preparation and types) ”, and the same No.18716
(Nov. 1979), p. 648, ibid. No. 307105 (Nov. 1989), 863.
-886, and Graphide, Physics and Chemistry of Photography, published by Paul Montel (P.Glafkides, Chemie etPh.
isique Photographique, PaulMontel, 1967), "Photographic Emulsion Chemistry" by Duffin, published by Focal Press (GF Duf
fin, Photographic Emulsion Chemistry (FocalPress, 1
966)), "Production and coating of photographic emulsions" by Zelikman et al., Published by Focal Press (VL Zelikman et al., Making a
nd Coating Photographic Emulsion, Focal Press, 196
It can be prepared using the method described in 4).

Monodisperse emulsions described in US Pat. Nos. 3,574,628 and 3,655,394 and British Patent 1,413,748 are also preferable. Further, tabular grains having an aspect ratio of about 3 or more can be used in the present invention. Tabular grains are described by Gatov, Photographic Science and Engineering (Gutoff, PhotographicScience
and Engineering), Vol. 14, pp. 248-257 (1970);
U.S. Pat.Nos. 4,434,226, 4,414,310, 4,433,0
It can be easily prepared by the methods described in 48, 4,439,520 and British Patent 2,112,157. The crystal structure may be uniform, may have a different halogen composition between the inside and the outside, may have a layered structure, and may have a different composition by epitaxial bonding. Alternatively, it may be bonded to a compound other than silver halide such as silver rhodanide and lead oxide. Also, a mixture of particles having various crystal forms may be used. The above emulsion may be either a surface latent image type which forms a latent image mainly on the surface, an internal latent image type which forms a latent image inside the grain or a type which has a latent image both on the surface and inside, but a negative type emulsion. It is necessary to be. Among the internal latent image type emulsions, core / shell type internal latent image type emulsions described in JP-A-63-264740 may be used. The method for preparing this core / shell type internal latent image type emulsion is described in JP-A-59-133542. The thickness of the shell of this emulsion varies depending on the development process and the like, but is preferably 3 to 40 nm, particularly preferably 5 to 20 nm.

The silver halide emulsion is usually one which has been physically ripened, chemically ripened and spectrally sensitized. Additives used in such a process are described in Research Disclosure No. 17643, No. 18716 and No. 307105, and the corresponding portions are summarized in the table below. The light-sensitive material of the present invention comprises two or more kinds of emulsions having different characteristics of at least one of the grain size, grain size distribution, halogen composition, grain shape and sensitivity of the light-sensitive silver halide emulsion.
It can be mixed and used in the same layer. US Patent No.
No. 4,082,553, the surface of which is covered with a silver halide grain, U.S. Pat. No. 4,626,498, JP-A-59-214852, the inside of which is covered with a silver halide grain, and a colloidal silver is a photosensitive halogenated photosensitive grain. It can be preferably used for a silver emulsion layer and / or a substantially light-insensitive hydrophilic colloid layer. The fogged silver halide grain inside or on the surface means a silver halide grain that enables uniform (non-imagewise) development regardless of the unexposed area and exposed area of the light-sensitive material. .. A method for preparing a silver halide grain whose inside or surface is fogged is described in U.S. Pat.
It is described in No. 9-214852. The silver halide forming the inner nucleus of a core / shell type silver halide grain having a fogged inside may have the same halogen composition or different halogen compositions. As the silver halide having the inside or surface of the grain fogged, any of silver chloride, silver chlorobromide, silver iodobromide and silver chloroiodobromide can be used. There is no particular limitation on the grain size of these fogged silver halide grains, but as the average grain size,
0.01 to 0.75 μm, particularly 0.05 to 0.6 μm is preferable. Also,
The grain shape is not particularly limited and may be regular grains or polydisperse emulsion, but monodisperse (at least 95% of the weight or number of silver halide grains is within ± 40% of the average grain size) It is preferable that the particles have a particle size of

In the present invention, it is preferable to use a non-photosensitive fine grain silver halide. The non-photosensitive fine grain silver halide is a fine grain of silver halide which is not exposed to light during imagewise exposure for obtaining a dye image and is not substantially developed in the developing treatment, and it is preferable that the fog is not fogged in advance. .. The fine grain silver halide has a silver bromide content of 0 to 100 mol%, and may optionally contain silver chloride and / or silver iodide. Preferred is one containing 0.5 to 10 mol% of silver iodide. Fine grain silver halide has an average grain size (average diameter of circles in the projected area)
Is preferably 0.01 to 0.5 μm, more preferably 0.02 to 0.2 μm. The fine grain silver halide can be prepared in the same manner as in the case of ordinary photosensitive silver halide. In this case, the surface of the silver halide grain does not need to be optically sensitized nor spectral sensitization. However, prior to adding this to the coating liquid, it is preferable to add a known stabilizer such as a triazole-based, azaindene-based, benzothiazolium-based, mercapto-based compound or zinc compound in advance. Colloidal silver can be preferably contained in the layer containing the fine grain silver halide grains. Coated silver amount of the light-sensitive material of the present invention is preferably 6.0 g / m ² or less, 4.5 g / m ² or less is most preferred.

Known photographic additives that can be used in the present invention are also described in the above three Research Disclosures, and the relevant portions are shown in the following table. Types of additives RD17643 RD18716 RD307105 1. Chemical sensitizer, page 23, page 648, right column, page 866 2. Sensitivity enhancer, page 648, right column 3. Spectral sensitizer, page 23 to 24, page 648, right column 866 to 868 Color sensitizer: page 649, right column 4. Whitening agent: page 24, page 647, right column 868, page 5, fogging prevention, page 24-25, page 649, right column, page 868-870, stabilizer, light absorber, 25- Page 26 Page 649 Right column Page 873 Filter ~ Page 650 Left column Dye, UV absorber 7. Stain 25 Page Right column 650 Page Left column 872 Inhibitor ~ Right column 8. Dye image Page 25 650 Page Left column 872 Stabilizer 9. Hardener 26 pages 651 left column 874 to 875 pages 10. Binder page 26 651 pages left column 873 to 874 pages 11. Plasticizer, page 27 650 pages right column 876 lubricants 12. Coating aids , Pages 26 to 27, page 650, right column, pages 875 to 876, surfactant 13. static, page 27, page 650, right column, pages 876 to 877, inhibitors 14. matting agents, pages 878 to 879

Further, in order to prevent deterioration of photographic performance due to formaldehyde gas, it is preferable to add to the light-sensitive material a compound capable of reacting with formaldehyde described in US Pat. Nos. 4,411,987 and 4,435,503. .. In the light-sensitive material of the present invention, US Pat.
No. 4,788,132, JP-A-62-18539, JP-A 1-28
It is preferable to contain the mercapto compound described in No. 3551. A compound which, in the light-sensitive material of the present invention, releases a fog agent, a development accelerator, a silver halide solvent or a precursor thereof as described in JP-A 1-106052, irrespective of the amount of developed silver produced by development processing. Is preferably contained. In the light-sensitive material of the present invention, a dye dispersed by the method described in International Publication WO88 / 04794 or JP-A-1-502912 or
EP317,308A, U.S. Pat.No. 4,420,555, JP 1-25935
It is preferable to include the dye described in No. 8. Various color couplers can be used in the present invention, and specific examples thereof include Research Disclosure No. 1764 mentioned above.
3, VII-CG, and No. 307105, VII-CG
Are described in the patents listed in. Examples of yellow couplers other than those represented by the general formula (1) of the present invention include, for example, U.S. Pat. Nos. 3,933,501 and 4,022,620.
Nos. 4,326,024, 4,401,752, 4,24
No. 8,961, Japanese Patent Publication No. 58-10739, British Patent No. 1,425,020
No. 1,476,760, U.S. Patent No. 3,973,968, No.
4,314,023, 4,511,649, European Patent 249,473
Those described in No. A, etc. are preferable.

As the magenta coupler, 5-pyrazolone compounds and pyrazoloazole compounds are preferable, and US Pat. Nos. 4,310,619, 4,351,897, and European Patent 73,63 are preferred.
6, U.S. Pat.Nos. 3,061,432, 3,725,067,
Research Disclosure No. 24220 (June 1984
Mon), JP-A-60-33552, Research Disclosure No. 24230 (June 1984), JP-A-60-43659, 61-71.
No. 2238, No. 60-35730, No. 55-118034, No. 60-185951
U.S. Pat.Nos. 4,500,630, 4,540,654, and
Those described in 4,556,630 and WO88 / 04795 are particularly preferable. Examples of cyan couplers include phenol-based and naphthol-based couplers, and US Pat.
52,212, 4,146,396, 4,228,233, and
4,296,200, 2,369,929, 2,801,171,
No. 2,772,162, No. 2,895,826, No. 3,772,002
No. 3, No. 3,758,308, No. 4,334,011, No. 4,32
7,173, West German Patent Publication No. 3,329,729, European Patent No. 12
1,365A, 249,453A, U.S. Pat.No. 3,446,622
No. 4,333,999, 4,775,616, 4,45
No. 1,559, No. 4,427,767, No. 4,690,889, No.
Those described in 4,254,212, 4,296,199, JP-A-61-42658 and the like are preferable. Furthermore, JP-A-64-553,
Pyrazoloazole couplers described in JP-A Nos. 64-554, 64-555 and 64-556 and imidazole couplers described in US Pat. No. 4,818,672 can also be used. Typical examples of polymerized dye-forming couplers are described in US Pat.
3,451,820, 4,080,211 and 4,367,282,
No. 4,409,320, No. 4,576,910, British patent 2,1
No. 02,137, European Patent No. 341,188A and the like.

Examples of couplers in which the color forming dye has an appropriate diffusibility include US Pat. No. 4,366,237 and British Patent 2,12.
5,570, European Patent 96,570, West German Patent (Publication)
Those described in 3,234,533 are preferable. Colored couplers for correcting unwanted absorption of color forming dyes are described in Research Disclosure No. 17643, Item VII-G, No. 307.
105 VII-G, U.S. Pat. No. 4,163,670, Japanese Examined Patent Publication No. 57
-39413, U.S. Pat.Nos. 4,004,929, 4,138,258
And those described in British Patent No. 1,146,368 are preferred.
Further, a coupler for correcting unnecessary absorption of a coloring dye by a fluorescent dye released at the time of coupling described in U.S. Pat.No. 4,774,181, and a dye capable of reacting with a developing agent described in U.S. Pat.No. 4,777,120 to form a dye. It is also preferable to use a coupler having a precursor group as a leaving group.
Compounds that release a photographically useful residue upon coupling are also preferably used in the present invention. DIR couplers that release development inhibitors are described in RD 17643, VII-F above.
And the patents described in No. 307105 and VII-F, JP-A-57-151944, 57-154234, and 60-184248,
63-37346, 63-37350, U.S. Patent 4,248,962,
Those described in No. 4,782,012 are preferable. RD No.1
The bleaching accelerator releasing couplers described in 1449, 24241 and JP-A-61-2201247 are effective for shortening the processing time having a bleaching ability, and particularly, the tabular silver halide grains described above. The effect is great when it is added to the photosensitive material using. Examples of couplers that release a nucleating agent or a development accelerator imagewise during development include British Patent 2,097,1
No. 40, No. 2,131,188, JP-A Nos. 59-157638 and 59-1.
Those described in No. 70840 are preferable. In addition, JP-A-60-10
7029, 60-252340, JP-A-1-44940, 1-456
Compounds which release a fogging agent, a development accelerator, a silver halide solvent and the like by an oxidation-reduction reaction with an oxidized product of a developing agent described in No. 87 are also preferable.

Other compounds that can be used in the light-sensitive material of the present invention include competitive couplers described in US Pat. No. 4,130,427 and US Pat. Nos. 4,283,472 and 4,3.
38,393, 4,310,618 and the like, multi-equivalent couplers, DIR redox compound releasing couplers, DIR coupler releasing couplers, DIR coupler releasing redox compounds described in JP-A-60-185950 and JP-A-62-24252. Alternatively, DIR redox-releasing redox compounds, couplers releasing dyes that undergo color restoration after withdrawal described in European Patents 173,302A and 313,308A, ligand-releasing couplers described in U.S. Pat. -75747 couplers releasing leuco dyes, U.S. Pat.
Examples thereof include couplers that release the fluorescent dye described in No. 181.

The coupler used in the present invention can be introduced into the photographic material by various known dispersion methods. Examples of the high boiling point solvent used in the oil-in-water dispersion method are described in US Pat. No. 2,322,027. Specific examples of the high-boiling organic solvent having a boiling point of 175 ° C. or higher at atmospheric pressure used in the oil-in-water dispersion method include phthalic acid esters (dibutyl phthalate, dicyclohexyl phthalate, di-2-ethylhexyl phthalate, decyl phthalate, bisyl phthalate). (2,4-di-t-amylphenyl) phthalate, bis (2,4-di-t-amylphenyl)
Isophthalate, bis (1,1-diethylpropyl) phthalate, etc., phosphoric acid or phosphonic acid esters (triphenyl phosphate, tricresyl phosphate,
2-ethylhexyl diphenyl phosphate, tricyclohexyl phosphate, tri-2-ethylhexyl phosphate, tridodecyl phosphate, tributoxyethyl phosphate, trichloropropyl phosphate, di
-2-Ethylhexylphenylphosphonate, etc., Benzoic acid esters (2-ethylhexylbenzoate, dodecylbenzoate, 2-ethylhexyl-p-hydroxybenzoate, etc.), Amides (N, N-diethyldodecaneamide, N, N-diethyllauryl) Amides, N-tetradecylpyrrolidone, etc.), alcohols or phenols (isostearyl alcohol, 2,4-di-tert-amylphenol, etc.), aliphatic carboxylic acid esters (bis (2-ethylhexyl) sebacate, dioctyl azetase Rate, glycerol tributyrate, isostearyl lactate,
Trioctyl citrate, etc., aniline derivatives (N, N-
Dibutyl-2-butoxy-5-tert-octylaniline) and hydrocarbons (paraffin, dodecylbenzene, diisopropylnaphthalene, etc.) and the like. The auxiliary solvent has a boiling point of about 30 ° C or higher, preferably 50 ° C.
Organic solvents with temperatures above 160 ° C can be used. Typical examples are ethyl acetate, butyl acetate, ethyl propionate,
Examples thereof include methyl ethyl ketone, cyclohexanone, 2-ethoxyethyl acetate, dimethylformamide and the like. The steps and effects of the latex dispersion method and specific examples of the latex for impregnation are described in US Pat. No. 4,199,363, West German Patent Application (OLS) Nos. 2,541,274 and 2,541,230.

In the color light-sensitive material of the present invention, phenethyl alcohol, JP-A-63-257747 and JP-A-62-272248,
And 1,2-benzisothiazolin-3-one described in JP-A-1-80941, n-butyl p-hydroxybenzoate,
It is preferable to add various preservatives or antifungal agents such as phenol, 4-chloro-3,5-dimethylphenol, 2-phenoxyethanol, and 2- (4-thiazolyl) benzimidazole. The present invention can be applied to various color light-sensitive materials. Typical examples include color negative films for general use or movies, color reversal films for slides or televisions, color papers, color positive films and color reversal papers.
Suitable supports that can be used in the present invention are, for example, the above-mentioned R
D. No.17643, page 28, No.18716, page 647 From right column 648
It is described on the left column of the page and on page 879 of the same No. 307105. In the light-sensitive material of the present invention, the total thickness of all hydrophilic colloid layers on the emulsion layer side is preferably 28 μm or less, more preferably 23 μm or less, further preferably 18 μm or less, particularly preferably 16 μm or less. Also, the film swelling speed T
_1/2 is preferably 30 seconds or less, more preferably 20 seconds or less.
The film thickness means a film thickness measured under a humidity condition of 25 ° C. and a relative humidity of 55% (2 days), and the film swelling rate T _1/2 can be measured according to a method known in the art. For example, Photographic Science and Engineering (Photog
r.Sci.Eng.), No. 2, No. 2, pages 124 to 129 can be measured using a swellometer (swelling meter), and T _1/2 is 30 ° C. in a color developer. , 90% of the maximum swollen film thickness reached after 3 minutes and 15 seconds of treatment is defined as the saturated film thickness, and is defined as the time required to reach 1/2 of the saturated film thickness. Membrane swelling speed T
_1/2 can be adjusted by adding a hardening agent to gelatin as a binder or changing the aging condition after coating. The swelling rate is preferably 150 to 400%. The swelling ratio can be calculated from the maximum swollen film thickness under the conditions described above according to the formula: (maximum swollen film thickness-film thickness) / film thickness. The light-sensitive material of the present invention is preferably provided with a hydrophilic colloid layer (referred to as a back layer) having a total dry film thickness of 2 μm to 20 μm on the side opposite to the side having the emulsion layer.
In this back layer, the above-mentioned light absorber, filter dye,
It is preferable to contain an ultraviolet absorber, an antistatic agent, a hardener, a binder, a plasticizer, a lubricant, a coating aid, a surface active agent and the like. The swelling ratio of this back layer is 150-500
% Is preferred.

The color photographic light-sensitive material according to the present invention has the RD. No.17643, pages 28 to 29, No. 18716, 651 left column to right column, and No. 307105, pages 880 to 881 can be developed by a usual method. The color developing solution used in the development processing of the light-sensitive material of the present invention is preferably an alkaline aqueous solution containing an aromatic primary amine type color developing agent as a main component. As this color developing agent,
Aminophenol compounds are also useful, but p-phenylenediamine compounds are preferably used, and typical examples thereof include 3-methyl-4-amino-N, N diethylaniline and 3-methyl-4-amino-N-. Ethyl-N-β-hydroxyethylaniline, 3-methyl-4-amino-N-ethyl-N-β-methanesulfonamidoethylaniline, 3-methyl-4-amino-N
-Ethyl-β-methoxyethylaniline and their sulfates, hydrochlorides or p-toluenesulfonates. Among these, especially 3-methyl-4-amino-N
-Ethyl-N-β-hydroxyethylaniline sulfate is preferred. Two or more kinds of these compounds can be used in combination depending on the purpose. The color developer is an alkali metal carbonate,
It contains a pH buffer such as borate or phosphate, a chloride salt, a bromide salt, an iodide salt, a development inhibitor such as a benzimidazole, a benzothiazole or a mercapto compound, or an antifoggant. It is common. If necessary, hydroxylamine, diethylhydroxylamine, sulfite, hydrazines such as N, N-biscarboxymethylhydrazine, phenylsemicarbazides, triethanolamine, various preservatives such as catecholsulfonic acids, ethylene glycol, Organic solvent such as diethylene glycol, benzyl alcohol,
Development accelerators such as polyethylene glycol, quaternary ammonium salts, amines, dye-forming couplers, competing couplers, auxiliary developing agents such as 1-phenyl-3-pyrazolidone, tackifiers, aminopolycarboxylic acids, aminopolyphosphones. Acid, alkylphosphonic acid, various chelating agents represented by phosphonocarboxylic acid, for example, ethylenediaminetetraacetic acid, nitrilotriacetic acid, diethylenetriaminepentaacetic acid, cyclohexanediaminetetraacetic acid, hydroxyethyliminodiacetic acid, 1-hydroxyethylidene- 1,1-diphosphonic acid, nitrilo-N, N, N-trimethylenephosphonic acid,
Representative examples include ethylenediamine-N, N, N, N-tetramethylenephosphonic acid, ethylenediamine-di (o-hydroxyphenylacetic acid) and salts thereof.

When the reversal process is carried out, black and white development is usually carried out and then color development is carried out. In this black-and-white developer, known black-and-white developing agents such as dihydroxybenzenes such as hydroquinone, 3-pyrazolidones such as 1-phenyl-3-pyrazolidone or aminophenols such as N-methyl-p-aminophenol are used alone. Alternatively, they can be used in combination. The pH of these color developing solution and black-and-white developing solution is generally 9-12. The replenishing amount of these developing solutions depends on the color photographic light-sensitive material to be processed, but is generally 3 liters or less per square meter of the light-sensitive material, and is reduced to 500 ml or less by reducing the bromide ion concentration in the replenishing solution. You can also When the replenishment amount is reduced, it is preferable to prevent the liquid evaporation and air oxidation by reducing the contact area with the air in the processing tank. The contact area between the photographic processing liquid and air in the processing tank can be represented by the aperture ratio defined below. That is, aperture ratio = [contact area between treatment liquid and air (cm ² )] ÷ [volume of treatment liquid (cm ³ )] The above aperture ratio is preferably 0.1 or less, and more preferably 0.001 to 0.05. Is. As a method for reducing the aperture ratio in this way, in addition to providing a cover such as a floating lid on the photographic processing liquid surface of the processing tank, a method using a movable lid described in JP-A-1-82033 is disclosed. The slit development processing method described in 63-216050 can be mentioned. Reducing the aperture ratio is not limited to both the color development and black and white development steps, but also the subsequent steps such as bleaching, bleach-fixing,
It is preferably applied in all steps such as fixing, washing with water, and stabilization. Further, the amount of replenishment can be reduced by using a means for suppressing the accumulation of bromide ions in the developing solution. The color development processing time is usually set to 2 to 5 minutes, but the processing time can be further shortened by setting the temperature and high pH and using the color developing agent at a high concentration.

The photographic emulsion layer after color development is usually bleached. The bleaching process may be performed at the same time as the fixing process (bleach-fixing process) or separately. Further, in order to speed up the processing, a processing method of bleach-fixing processing after bleaching processing may be used. Further, treatment with two continuous bleach-fixing baths, fixing treatment before the bleach-fixing treatment, or bleaching treatment after the bleach-fixing treatment can be optionally carried out. As the bleaching agent, compounds of polyvalent metals such as iron (III), peracids, quinones, nitro compounds and the like are used. Typical bleaching agents include organic complex salts of iron (III), such as ethylenediaminetetraacetic acid, diethylenetriaminepentaacetic acid, cyclohexanediaminetetraacetic acid, methyliminodiacetic acid, 1,3-diaminopropanetetraacetic acid and glycol etherdiaminetetraacetic acid. Polycarboxylic acids or complex salts of citric acid, tartaric acid, malic acid and the like can be used. Of these, aminopolycarboxylic acid iron (III) complex salts including ethylenediaminetetraacetic acid iron (III) complex salts and 1,3-diaminopropanetetraacetic acid iron (III) complex salts are preferable from the viewpoint of rapid treatment and prevention of environmental pollution. . Further, the aminopolycarboxylic acid iron (III) complex salt is particularly useful in both the bleaching solution and the bleach-fixing solution. The pH of a bleaching solution or a bleach-fixing solution using these aminopolycarboxylic acid iron (III) complex salts is usually 4.0 to 8, but a lower pH can be used for speeding up the processing.

If necessary, a bleaching accelerator can be used in the bleaching solution, the bleach-fixing solution and their pre-bath.
Specific examples of useful bleach accelerators are described in the following specifications: US Pat. No. 3,893,858, West German Patent 1,290,812.
No. 2,059,988, JP-A No. 53-32736, No. 53-57831
No. 53, No. 53-37418, No. 53-72623, No. 53-95630, No. 53
-95631, 53-104232, 53-124424, 53-141
623, 53-28426, Research Disclosure
No. 17129 (July 1978), etc., a compound having a mercapto group or a disulfide group; JP-A-50-140129
Thiazolidine derivatives described in JP-B-45-8506, JP-A-52-20832, JP-A-53-32735, and US Pat. No. 3,706,561.
Thiourea derivative described in Japanese Patent No. 1,127,715,
Iodide salt described in JP-A-58-16,235; West German Patent No. 966,
Polyoxyethylene compounds described in JP-A Nos. 410 and 2,748,430; polyamine compounds described in JP-B-45-8836; Other JP-A-49-40,943, 49-59,644, 53-94,92
No. 7, No. 54-35,727, No. 55-26,506, No. 58-163,940
Compounds described in No. 1; bromide ions and the like can be used. Among them, a compound having a mercapto group or a disulfide group is preferable from the viewpoint of having a large accelerating effect, and in particular, US Pat.
3,858, West German Patent 1,290,812, JP-A-53-95,630
Compounds described in US Pat. Further, U.S. Pat.
The compounds described in No. 834 are also preferable. These bleaching accelerators may be added to the light-sensitive material. These bleaching accelerators are particularly effective when bleach-fixing a color light-sensitive material for photographing. In addition to the above compounds, the bleaching solution and the bleach-fixing solution preferably contain an organic acid for the purpose of preventing bleach stain. Particularly preferred organic acid has an acid dissociation constant (pKa) of 2
A compound of -5, specifically acetic acid, propionic acid,
Hydroxyacetic acid and the like are preferred. Examples of the fixing agent used in the fixing solution and the bleach-fixing solution include thiosulfates, thiocyanates, thioether compounds, thioureas, and a large amount of iodide salts, but thiosulfates are generally used. In particular, ammonium thiosulfate can be used most widely. Further, the combined use of thiosulfate and thiocyanate, thioether compounds, thiourea and the like is also preferable. Preservatives for fixers and bleach-fixers include sulfites, bisulfites, carbonyl bisulfite adducts or European Patent No. 294
The sulfinic acid compounds described in No. 769A are preferable. Furthermore,
It is preferable to add various aminopolycarboxylic acids and organic phosphonic acids to the fixing solution and the bleach-fixing solution for the purpose of stabilizing the solution. In the present invention, the fixing solution or the bleach-fixing solution has a pH of
For adjustment, a compound having a pKa of 6.0 to 9.0, preferably an imidazole such as imidazole, 1-methylimidazole, 1-ethylimidazole, and 2-methylimidazole.
It is preferable to add 1 to 10 mol / l.

The total time of the desilvering process is preferably as short as possible so long as no desilvering failure occurs. Preferred time is 1 to 3 minutes
Minutes, more preferably 1 minute to 2 minutes. The treatment temperature is 25 ° C to 50 ° C, preferably 35 ° C to 45 ° C. In the preferable temperature range, the desilvering rate is improved and the stain generation after the processing is effectively prevented. In the desilvering process, it is preferable that the stirring is strengthened as much as possible.
As a specific method for strengthening stirring, a method of impinging a jet of a processing solution on the emulsion surface of the light-sensitive material described in JP-A-62-183460, or stirring using a rotating means of JP-A-62-183461 is used. Method of improving the effect, further moving the photosensitive material while the emulsion surface is in contact with the wiper blade provided in the solution to make the emulsion surface turbulent to further improve the stirring effect, circulation of the entire processing solution There is a method of increasing the flow rate. Such a stirring improving means is effective for any of the bleaching solution, the bleach-fixing solution and the fixing solution. It is considered that the improvement of the stirring speeds up the supply of the bleaching agent and the fixing agent into the emulsion film and, as a result, increases the desilvering rate. Further, the above-mentioned stirring improving means is more effective when a bleaching accelerator is used, and it is possible to remarkably increase the accelerating effect and eliminate the fixing inhibiting effect of the bleaching accelerator. The automatic processor used for the light-sensitive material of the present invention is disclosed in JP-A-60-191257.
No. 60-191258 and No. 60-191259. The above-mentioned JP-A-6
As described in No. 0-191257, such a conveying means can significantly reduce the carry-in of the treatment liquid from the front bath to the rear bath, and is highly effective in preventing the performance deterioration of the treatment liquid. Such effects are particularly effective in shortening the processing time in each step and reducing the amount of processing liquid replenishment.

The silver halide color photographic light-sensitive material of the present invention is generally washed with water and / or stabilized after the desilvering treatment. The amount of rinsing water in the rinsing process depends on the characteristics of the photosensitive material (for example, depending on the materials used such as couplers), application, and further, the rinsing water temperature, the number of rinsing tanks (number of stages), replenishment system such as countercurrent, forward flow, and other various conditions. It can be set in a wide range.
Of these, the relationship between the number of washing tanks and the amount of water in the multi-stage countercurrent system is as follows.
nd Tele-vision Engineers Volume 64, P. 248 ~ 253 (195
May, May issue). According to the multi-stage counter-current method described in the above literature, the amount of washing water can be significantly reduced, but due to the increase in the residence time of water in the tank, bacteria propagate, and the suspended matter produced adheres to the photosensitive material, etc. Problems arise. In the processing of the color light-sensitive material of the present invention, as a solution to this problem, the method of reducing calcium and magnesium ions described in JP-A-62-288,838 can be used very effectively. Further, isothiazolone compounds and siabendazoles described in JP-A-57-8,542, chlorine-based bactericides such as chlorinated sodium isocyanurate, and other benzotriazoles, etc., Hiroshi Horiguchi, "Chemistry of Antibacterial and Antifungal Agents" (1986)
Sankyo Publishing, Sanitary Technology Society, "Microbial sterilization, sterilization, antifungal technology" (1982) Industrial Technology Association, Japan Antibacterial and Antifungal Society edited by "The Antibacterial and Antifungal Encyclopedia" (1986) Can also be used. PH of washing water in the processing of the light-sensitive material of the present invention
Is 4-9, preferably 5-8. The washing water temperature and washing time can also be set variously depending on the characteristics of the light-sensitive material, application, etc., but generally 15 to 45 ° C. for 20 seconds to 10 minutes, preferably
A range of 30 seconds to 5 minutes at 25-40 ° C is selected. Further, the light-sensitive material of the present invention can be directly processed with a stabilizing solution instead of the above washing with water. In such stabilization treatment, all known methods described in JP-A-57-8543, JP-A-58-14834 and JP-A-60-220345 can be used. Further, there is a case where further stabilization treatment is carried out after the water washing treatment, and an example thereof is a stabilizing bath containing a dye stabilizer and a surfactant, which is used as a final bath of a color light-sensitive material for photographing. be able to. As a dye stabilizer,
Aldehydes such as formalin and glutaraldehyde,
Examples thereof include N-methylol compounds, hexamethylenetetramine, and aldehyde sulfite adducts.
Various chelating agents and antifungal agents can also be added to this stabilizing bath.

The overflow solution resulting from the above washing with water and / or supplementation of the stabilizing solution can be reused in other steps such as the desilvering step. In the processing using an automatic processor, etc., when the above processing solutions are concentrated by evaporation,
It is preferable to correct the concentration by adding water. The silver halide color light-sensitive material of the present invention may contain a color developing agent for the purpose of simplifying and accelerating the processing. For incorporation, it is preferable to use various precursors of color developing agents. For example, indoaniline-based compounds described in U.S. Pat. Metal salt complexes described, JP-A-53-135
Urethane compounds described in No. 628 can be mentioned.
The silver halide color light-sensitive material of the present invention contains various types of 1-phenyl-3-methyl-3-phenyl-3-(-3-phenyl) -3-phenyl-3- (phenyl-3-phenyl) -3- (phenyl) -3-phenyl-3-(-3-phenyl) -3- (phenyl) -3- (phenyl) -3- (phenyl) -3-phenyl-3-(-3-phenyl) -3- (phenyl) -3-phenyl-3-(-3-phenyl-3-phenyl-3-phenyl-3- (phenyl-3-phenyl-3-phenyl-3-phenyl-3-phenyl-3-phenyl-3-phenyl-3-phenyl-3-phenyl-3-phenyl-3-phenyl-3-fluoro-3-bromo-3-chloro-3-bromo-3-bromo-3-amino-3-bromo-3-amino-3-bromo-3-amino-3-bromo-3-amino-3-phenyl-3-phenyl-3-bromo-3-octyl-3-bromo-3-bromo-3-bromo-3-octyl-3-bromo-3-bromo-3-octyl-3-bromo-3-bromo-3-bromo-3-octyl-3-phenyl-3-bromo-3-bromo-3-bromo-3-bromo-3-octyl-3-phenyl-3-chloro-3-bromo-3-bromo-3-bromo-3-bromo-3-bromo-3-bromo-3-bromo-3-bromo-3-bromo-3-bromo-3-bromo-3-bromo-3-bromo-3-bromo-3-bromo-3-bromo-3-bromo-3-bromo-3-bromo-3-bromo-3-bromo-3-bromo-3-bromo-3-bromo-3-bromo-3-bromo-3-bromo-3-bromo-3-bromo-3-bromo-3-bromo-3-bromo-3-bromo-3-bromo-3-bromo-3-bromo-3-bromo-3-bromo-3-bromo-3-bromo-3-bromo-3-bromo-3-bromo 3-bromo-3-bromo-3-bromo-3-bromo-3-bromo-3-bromo-3-bromo-3-bromo-3-bromo-3-bromo-3-bromo-3-bromo-3-bromo-3-bromo-3-bromo-3- did lead;
You may incorporate pyrazolidones. Typical compounds are described in JP-A-56-64339, JP-A-57-144547, and JP-A-58-115438. Various treatment liquids in the present invention are 10 ℃
Used at ~ 50 ° C. Normally, a temperature of 33 ° C to 38 ° C is standard, but a higher temperature accelerates the processing to shorten the processing time, and a lower temperature lowers the image quality to improve the stability of the processing liquid. be able to. Further, the silver halide light-sensitive material of the present invention includes U.S. Pat. No. 4,500,626, JP-A-60-133449, JP-A-59-218443, and JP-A-61-238056.
It can also be applied to the photothermographic material described in European Patent No. 210,660A2.

[0128]

EXAMPLES The present invention will be described in more detail with reference to examples below, but the present invention is not limited thereto. Example 1 On a subbed cellulose triacetate film support,
Each layer having the composition shown below was applied in multiple layers to prepare Sample 101, which is a multilayer color light-sensitive material. (Photosensitive layer composition) The materials used for each layer are classified as follows: ExC: Cyan coupler HBS: High boiling point organic solvent ExM: Magenta coupler ExO: Color mixture inhibitor ExY: Yellow coupler W: Surfactant ExS: Sensitizing dye H: Gelatin hardening agent ExU: Ultraviolet absorber B: Polymer S: Formalin scavenger or antifoggant F: Additive (stabilizer, antifoggant, etc.) The number corresponding to each component is g / m ² unit The coating amount represented by is shown, and for silver halide, the coating amount in terms of silver is shown. However, with respect to the sensitizing dye, the coating amount is shown in mol unit per mol of silver halide in the same layer.

(Sample 101) First layer (antihalation layer) Black colloidal silver Silver 0.090 Dispersion of organic solid disperse dye A 10.0 Dispersion of organic solid disperse dye B 5.0 Gelatin 1.4

Second layer (intermediate layer) 2,5-di-t-pentadecylhydroquinone 0.18 ExM-1 0.070 ExC-1 0.020 ExS-1 0.0020 ExU-1 0.060 ExU-2 0.080 ExU-3 0.10 HBS-1 0.10 HBS-2 0.020 Gelatin 1.0

Third Layer (Low Sensitivity Red Sensitive Emulsion Layer) Emulsion A Silver 0.25 Emulsion B Silver 0.25 ExS-3 1.5 × 10 ^-4 ExS-4 1.8 × 10 ^-5 ExS-5 2.5 × 10 ^-4 ExC-2 0.005 ExC-3 0.17 ExC-4 0.17 ExC-5 0.020 ExC-9 0.005 ExM-3 0.020 ExU-1 0.070 ExU-2 0.050 ExU-3 0.070 HBS-1 0.060 Gelatin 0.87

Fourth Layer (Medium Sensitivity Red Sensitive Emulsion Layer) Emulsion D Silver 0.53 ExS-3 1.0 × 10 ^-4 ExS-4 1.4 × 10 ^-5 ExS-5 2.0 × 10 ^-4 ExC-1 0.010 ExC-2 0.005 ExC-3 0.050 ExC-4 0.050 ExC-6 0.080 ExC-9 0.020 Gelatin 0.70

Fifth layer (high-sensitivity red-sensitive emulsion layer) Emulsion G Silver 1.0 ExS-3 1.0 × 10 ^-4 ExS-4 1.4 × 10 ^-5 ExS-5 2.0 × 10 ^-4 ExC-1 0.050 ExC-2 0.005 ExC-3 0.20 ExC-4 0.20 ExC-7 0.20 ExC-8 0.020 ExC-9 0.015 ExU-1 0.070 ExU-2 0.050 ExU-3 0.070 HBS-1 0.22 HBS-2 0.10 Gelatin 1.6

Sixth layer (intermediate layer) ExO-1 0.060 ExM-4 0.050 HBS-1 0.020 Gelatin 0.80

Seventh Layer (Low Sensitivity Green Sensitive Emulsion Layer) Emulsion A Silver 0.15 Emulsion B Silver 0.15 Emulsion C Silver 0.10 ExS-2 5.0 × 10 ^-5 ExS-6 3.0 × 10 ^-5 ExS-7 1.0 × 10 ^-4 ExS-8 3.8 × 10 ^-4 ExM-1 0.021 ExM-3 0.030 ExM-5 0.20 ExY-4 0.0050 ExM-7 0.10 HBS-1 0.10 HBS-3 0.010 Gelatin 0.63

Eighth layer (intermediate layer) ExM-4 0.018 ExC-8 0.040 HBS-1 0.16 HBS-3 0.0080 Gelatin 0.50

9th layer (high-sensitivity green-sensitive emulsion layer) Emulsion E Silver 1.2 ExS-2 0.50 × 10 ^-5 ExS-6 3.5 × 10 ^-5 ExS-7 8.0 × 10 ^-5 ExS-8 3.0 × 10 ^-4 ExM-3 0.025 ExM-8 0.015 ExM-9 0.50 ExY-1 0.020 HBS-1 0.25 HBS-2 0.10 Gelatin 1.5

10th layer (intermediate layer) ExO-1 0.040 HBS-1 0.020 Gelatin 0.80

Eleventh layer (donor layer having a multilayer effect on the red-sensitive layer) Emulsion J Silver 1.2 Emulsion K Silver 2.0 ExS-2 4.0 × 10 ^-4 ExC-2 0.10 ExM-2 0.13 HBS-1 0.10 HBS-2 0.10 Gelatin 0.80

12th layer (yellow filter layer) Yellow colloidal silver Silver 0.050 Dispersion of organic solid disperse dye B 15.0 ExO-1 0.080 HBS-1 0.030 Gelatin 0.95

13th Layer (Low Sensitivity Blue Sensitive Emulsion Layer) Emulsion A Silver 0.080 Emulsion B Silver 0.070 Emulsion F Silver 0.070 Emulsion G Silver 0.450 ExS-9 5.6 × 10 ^-4 ExC-3 0.042 ExY-2 0.87 ExY-3 0.010 ExY-4 0.020 ExC-2 0.0070 HBS-1 0.28 Gelatin 2.4

14th layer (middle sensitive layer) ExO-1 0.03 HBS-2 0.050 Gelatin 0.78

Fifteenth layer (high-sensitivity blue-sensitive emulsion layer) Emulsion H Silver 0.77 ExS-9 2.2 × 10 ^-4 ExY-1 0.010 ExY-2 0.60 ExY-3 0.010 HBS-1 0.070 Gelatin 0.69

Sixteenth Layer (Protective Layer) Emulsion I Silver 0.20 ExU-4 0.11 ExU-5 0.17 HBS-1 0.050 Dispersion of organic solid disperse dye A 0.50 Dispersion of organic solid disperse dye B 0.50 W-1 0.020 H- 1 0.40 B-1 (diameter about 1.5 μm) 0.10 B-2 (diameter about 1.5 μm) 0.10 B-3 0.020 S-1 0.20 Gelatin 1.8

In addition to the above, the samples thus prepared were
1,2-benzisothiazolin-3-one (200 ppm average for gelatin), n-butyl-p-hydroxybenzoate (about 1,000 ppm) and 2-phenoxyethanol (about 10,000 ppm) were added. Furthermore W
-2, W-3, B-4 to B-6, F-1 to F-
17, containing iron salt, lead salt, gold salt, platinum salt, iridium salt and rhodium salt.

Preparation of Dispersion A of Organic Solid Disperse Dye ExF-1 shown below was dispersed by the following method. That is, water 21.7
3 ml of P-octylphenoxyethoxyethoxyethoxyethane sulfonate of 5% aqueous solution and 0.5 g of P-octylphenoxypolyoxyethylene ether (polymerization degree of 10) of 5% aqueous solution were placed in a 700 ml pot mill, and dye ExF- 1 to 5.0g
And 500 ml of zirconium oxide beads (diameter 1 mm) were added and the contents were dispersed for 2 hours. A BO type vibration ball mill manufactured by Chuo Koki was used for this dispersion. After dispersing, take out the contents and add to 8 g of 12.5% gelatin aqueous solution,
The beads were filtered off to obtain gelatin dispersion A of the dye.

Preparation of Dispersion B of Organic Solid Disperse Dye ExF-2 below was replaced with ExF-1 of Dispersion A above. The following was prepared in the same manner as Dispersion A.

[0148]

[Table 1]

In Table 1, (1) Emulsions A to K were prepared according to the examples of JP-A-2-91938.
It was reduction sensitized during grain preparation using thiourea dioxide and thiosulfonic acid. (2) Emulsions A to K were prepared according to the examples of Japanese Patent Application No. 2-34090.
Gold sensitization, sulfur sensitization and selenium sensitization are performed in the presence of the spectral sensitizing dye described in each photosensitive layer and sodium thiocyanate. (3) For the preparation of tabular grains, low molecular weight gelatin is used according to the examples of JP-A 1-158426. (4) Dislocation lines as described in Japanese Patent Application No. 2-34090 have been observed in tabular grains and normal crystal grains having a grain structure by using a high voltage electron microscope.

[0150]

[Chemical 57]

[0151]

[Chemical 58]

[0152]

[Chemical 59]

[0153]

[Chemical 60]

[0154]

[Chemical formula 61]

[0155]

[Chemical formula 62]

[0156]

[Chemical 63]

[0157]

[Chemical 64]

[0158]

[Chemical 65]

[0159]

[Chemical 66]

[0160]

[Chemical 67]

[0161]

[Chemical 68]

[0162]

[Chemical 69]

[0163]

[Chemical 70]

[0164]

[Chemical 71]

[0165]

[Chemical 72]

[0166]

[Chemical formula 73]

(Samples 102 to 134) First of Sample 101
Samples 102 to 134 were prepared by replacing ExO-1 of the 0th and 12th layers and ExY-2 of the 13th and 15th layers with equimolar amounts of the compounds shown in Table 2. These samples were exposed to sensitometric exposure with green light and subjected to the following color development processing. The density of the processed sample was measured, and values obtained by subtracting the yellow fog density from the yellow color density at the exposure point where the magenta density gives fog +2.0 are shown in Tables 2 and 3.

Immediately after the white exposure for sensitometry (condition A) and after standing for 7 days in the dark at 50 ° C. and 80% relative humidity (condition B), the following development processing was carried out. Sensitivity of green-sensitive layer under condition B to condition A (relative sensitivity at fog of magenta density + 0.25 point)
Table 2 and Table 3 show the changes in fog and the changes in sensitivity and fog under the forced deterioration condition. Here, the relative sensitivity is the relative value of the logarithm of the exposure amount that gives a density of fog + 0.25. The relative sensitivity of the blue sensitive layer under the condition A is also shown.

Further, after uniformly exposing with a green light, it is exposed with a blue light with an MTF measuring pattern to obtain an MT of a yellow image.
The F value was calculated.

[0170]

[Table 2]

[0171]

[Table 3]

The structures of the comparative compounds shown in Tables 2 and 3 are as follows.

[0173]

[Chemical 74]

Color development processing was carried out at 38 ° C. according to the following processing steps. (Processing method) Process processing time Processing temperature Color development 3 minutes 15 seconds 38 ° C Bleaching 3 minutes 00 seconds 38 ° C Water washing 30 seconds 24 ° C Settling 3 minutes 00 seconds 38 ° C Water washing (1) 30 seconds 24 ° C Water washing ( 2) 30 seconds 24 ℃ Stability 30 seconds 38 ℃ Dry 4 minutes 20 seconds 55 ℃

Next, the composition of the treatment liquid will be described. (Color developer) (Unit: g) Diethylenetriaminepentaacetic acid 1.0 1-Hydroxyethylidene-1,1-diphosphonic acid 3.0 Sodium sulfite 4.0 Potassium carbonate 30.0 Potassium bromide 1.4 Potassium iodide 1.5 mg Hydroxylamine sulfate 2.4 4- [N- Ethyl-N-β-hydroxyethylamino] -2-methylaniline sulfate 4.5 Water was added to 1.0 liter pH 10.05

(Bleaching Solution) (Unit: g) Ethylenediaminetetraacetic acid sodium ferric trihydrate 100.0 Ethylenediaminetetraacetic acid disodium salt 10.0 3-Mercapto-1,2,4-triazole 0.08 Ammonium bromide 140.0 Ammonium nitrate 30.0 Ammonia water ( 27%) 6.5 ml Add water 1.0 liter pH 6.0

(Fixer) (Unit: g) Ethylenediaminetetraacetic acid disodium salt 0.5 Ammonium sulfite 20.0 Ammonium thiosulfate aqueous solution (700 g / liter) 290.0 ml Water was added to 1.0 liter pH 6.7

(Stabilizing Solution) (Unit: g) Sodium p-toluenesulfinate 0.03 Polyoxyethylene-p-monononylphenyl ether (average degree of polymerization 10) 0.2 Ethylenediaminetetraacetic acid disodium salt 0.05 1,2,4-triazole 1.3 1,4-bis (1,2,4-triazol-1-ylmethyl) piperazine 0.75 Water was added to 1.0 liter pH 8.5

From Tables 2 and 3, the compounds of the present invention [compounds represented by the above-mentioned general formulas (2) to (8)] and the yellow coupler of the present invention containing the samples of the present invention show small color turbidity and high sensitivity. It can be seen that the sharpness is excellent and the change in photographic performance (change in sensitivity, increase in fog) under the condition of forced deterioration is small.

Example 2 ExO-1 of the 14th layer and the 13th layer of the sample 101, the first layer
Samples 201 to 206 were prepared by substituting the compounds shown in Table 4 with equimolar amounts of ExY-2 in 5 layers.

White light exposure for sensitometry was applied to these samples, and the following color development processing was performed to evaluate photographic performance. Also, expose through the RMS measurement wedge,
After the same development processing, the RMS of the yellow image was measured using an aperture having a diameter of 48 μm.

(Processing process) Process Processing time Processing temperature Replenishment amount ^* Tank capacity Color development 3 minutes 5 seconds 38.0 ° C 600 ml 17 liters Bleach 50 seconds 38.0 ° C 140 ml 5 liters Bleach fixing 50 seconds 38.0 ° C-5 liters 50 seconds 38.0 ° C 420 ml 5 liters Water wash 30 seconds 38.0 ° C 980 ml 3 liters Stable (1) 20 seconds 38.0 ° C −3 liters Stable (2) 20 seconds 38.0 ° C 560 ml 3 liters Dry 1 minute 60 ° C * Replenishment The amount is per 1 m ² of the light-sensitive material. The stabilizing solution is a countercurrent system from (2) to (1), and the overflow solution of washing water is all introduced into the fixing bath. When replenishing the bleach-fixing bath, a cutout is provided at the top of the bleaching tank of the automatic developing machine and at the top of the fixing tank so that all of the overflow solution generated by supplying the replenishing solution to the bleaching tank and the fixing tank is added to the bleach-fixing bath. I was allowed to flow in. The amount of developing solution brought into the bleaching process, the amount of bleaching solution brought into the bleach-fixing process, the amount of bleach-fixing solution brought into the fixing process, and the amount of fixing solution brought into the rinsing process were each 1 m ² of the light-sensitive material. It was 65 ml, 50 ml, and 50 ml. The crossover time is 6 seconds in all cases, and this time is included in the processing time of the previous step. Also,
Each replenisher was replenished with the same solution as the respective tank solution.

The composition of the processing liquid is shown below. (Color developer) (Unit: g) Diethylenetriaminepentaacetic acid 2.0 1-Hydroxyethylidene-1,1-diphosphonic acid 3.3 Sodium sulfite 3.9 Potassium carbonate 37.5 Potassium bromide 1.4 Potassium iodide 1.3 mg Hydroxylamine sulfate 2.4 2-Methyl-4 -[N-Ethyl-N- (β-hydroxyethyl) amino] aniline sulfate 4.5 Water was added to 1.0 liter pH 10.05

(Bleaching Solution) (Unit: g) 1,3-Diaminopropanetetraacetic acid Ammonium ferric acid monohydrate 130 Ammonium bromide 80 Ammonium nitrate 15 Hydroxyacetic acid 50 Acetic acid 40 Water is added to 1.0 liter pH [prepared with aqueous ammonia] ] 4.4

(Bleaching Fixing Solution) A 15:85 (volume ratio) mixture of the above bleaching solution and the following fixing solution. (PH 7.0)

(Fixer) (Unit: g) Ammonium sulfite 19 Ammonium thiosulfate aqueous solution (700 g / liter) 280 ml imidazole 15 Ethylenediaminetetraacetic acid 15 Water was added to 1.0 liter pH [Prepared with ammonia water and acetic acid] 7.4

(Washing Water) Tap water was used as an H-type strongly acidic cation exchange resin (Amberlite IR-produced by Rohm and Haas).
120B) and OH-type strongly basic anion exchange resin (Amberlite IR-400) were passed through a mixed bed column to adjust the concentration of calcium and magnesium ions to 3 mg.
/ Liter or less, followed by sodium diisocyanurate dichloride 20 mg / liter and sodium sulfate 150
mg / l was added. The pH of this solution is 6.5 to 7.
It was in the range of 5.

(Stabilizing Solution) (Unit: g) Sodium p-toluenesulfinate 0.03 Polyoxyethylene-p-monononylphenyl ether (average degree of polymerization 10) 0.2 Ethylenediaminetetraacetic acid disodium salt 0.05 1,2,4-triazole 1.3 1,4-bis (1,2,4-triazol-1-ylmethyl) piperazine 0.75 Water was added to 1.0 liter pH 8.5

The results are shown in Table 4. It can be seen that the sample of the present invention has no lowering in sensitivity as compared with the comparative sample and is excellent in graininess.

[0190]

[Table 4]

Even if the compound (2) -1 of the present invention was added in an amount of 0.020 g / m ² to the fifteenth layer of Sample 101, the same graininess improving effect was obtained. Further, instead of the compound (2) -1, (2) -3, (2) -8, (4) -2, (4) -3,
Even if (7) -1 and (8) -1 were added in equimolar amounts, the effect of improving the graininess was recognized.

Example 3 Similar effects were obtained with samples in which the emulsions of Examples 1 and 2 were replaced with emulsions LP as described below.

[0193]

[Table 5]

[0194]

[Table 6]

Example 4 A surface of a paper support laminated on both sides with polyethylene was subjected to a corona discharge treatment, followed by providing a gelatin subbing layer containing sodium dodecylbenzenesulfonate, and further coating various photographic constituent layers to prepare A multilayer color photographic paper (401) having the layer structure shown was produced. The coating liquid was prepared as follows.

Preparation of First Layer Coating Solution Yellow coupler (ExY) 130.0 g, color image stabilizer (Cpd-1) 15.0 g, color image stabilizer (Cpd-2)
7.5 g, color image stabilizer (Cpd-3) 16.0 g, solvent (Solv-1) 25 g, solvent (Solv-2) 25
g and 180 cc of ethyl acetate and dissolved in 10%
An emulsified dispersion A was prepared by emulsifying and dispersing in 1000 g of a 10% gelatin aqueous solution containing 60 cc of sodium dodecylbenzenesulfonate and 10 g of citric acid. On the other hand, a silver chlorobromide emulsion A (a cube, a 3: 7 mixture of a large size emulsion A having an average grain size of 0.88 μm and a small size emulsion A having a grain size of 0.70 μm (silver molar ratio). The variation coefficient of the grain size distribution is , 0.08 and 0.10 respectively, and silver bromide 0.
3 mol% localized on a part of the particle surface) was prepared.
In this emulsion, blue-sensitive sensitizing dyes A and B shown below were added to the large-sized emulsion A per mol of silver at 2.0 ×, respectively.
10 ⁻⁴ , and for small size emulsion A, 2.
5 × 10 ⁻⁴ mol is added. The chemical ripening of this emulsion was performed by adding a sulfur sensitizer and a gold sensitizer. The above emulsified dispersion A and this silver chlorobromide emulsion A are mixed and dissolved,
The first layer coating solution was prepared so as to have the composition shown below.

Coating solutions for the second to seventh layers were prepared in the same manner as the coating solution for the first layer. As a gelatin hardening agent for each layer, 1-oxy-3,5-dichloro-s-triazine sodium salt was used. Also, Cpd-14 and C are added to each layer.
The total amount of pd-15 is 25.0 mg / m ² and 50 mg / m ² , respectively.
It was added so as to be m ² . The following spectral sensitizing dyes were used in the silver chlorobromide emulsion of each photosensitive emulsion layer.

[0198]

[Table 7]

[0199]

[Table 8]

[0200]

[Table 9]

1- (5-methylureidophenyl) is added to the blue-sensitive emulsion layer, the green-sensitive emulsion layer and the red-sensitive emulsion layer.
-5-Mercaptotetrazole was added in an amount of 8.5 x 10 ^-5 mol, 7.7 x 10 ^-4 mol and 2.5 x 10 ^-4 mol per mol of silver halide, respectively. Further, 4-hydroxy-6-methyl- was added to the blue-sensitive emulsion layer and the green-sensitive emulsion layer.
1,3,3a, 7-Tetrazaindene was added in an amount of 1 × 10 ⁻⁴ mol and 2 × 10 ⁻⁴ mol per mol of silver halide, respectively. To prevent irradiation, the following dyes (the amount in parentheses represents the coating amount) were added to the emulsion layer.

[0202]

[Chemical 75]

[0203]

[Table 10]

[0204]

[Table 11]

[0205]

[Table 12]

[0206]

[Table 13]

[0207]

[Chemical 76]

[0208]

[Chemical 77]

[0209]

[Chemical 78]

[0210]

[Chemical 79]

[0211]

[Chemical 80]

[0212]

[Chemical 81]

[0213]

[Chemical formula 82]

[0214]

[Chemical 83]

Samples (402) to (408) were prepared by substituting Cpd-4 of the second layer of the sample (401) and ExY of the first layer with equimolar amounts of the compounds shown in Table 14. The above samples were exposed to white light for sensitometry and then subjected to the following color development processing.

Processing Steps Temperature Time Color Development 35 ° C. 45 seconds Bleaching Fixing 35 ° C. 45 seconds Rinse (1) 35 ° C. 30 seconds Rinse (2) 35 ° C. 30 seconds Rinse (3) 35 ° C. 30 seconds Dry 80 ° C. 60 Seconds (Rinse was a three-tank countercurrent system from (3) to (1).)

The composition of each processing liquid is as follows. [Color developer] Water 800 ml Ethylenediaminetetraacetic acid 3.0 g 4,5-Dihydroxybenzene-1,3-disulfonic acid disodium salt 0.5 g Triethanolamine 12.0 g Potassium chloride 2.5 g Potassium bromide 0.01 g Potassium carbonate 27.0 g Fluorescent Whitening agent (WHITEX 4 manufactured by Sumitomo Chemical Co., Ltd.) 1.0 g Sodium sulfite 0.1 g Disodium-N, N-bis (sulfonate ethyl) hydroxylamine 5.0 g N-Ethyl-N- (β-methanesulfonamidoethyl) -3- Methyl-4-aminoaniline / 3/2 sulfuric acid monohydrate 5.0 g Water was added to 1000 ml pH (25 ° C / in potassium hydroxide and sulfuric acid) 10.05

[Bleach-fixing solution] Water 600 ml Ammonium thiosulfate (700 g / liter) 100 ml Ammonium sulfite 40 g Ethylenediaminetetraacetic acid iron (III) ammonium 55 g Ethylenediaminetetraacetic acid 5 g Ammonium bromide 40 g Nitric acid (67%) 30 g Water was added. 1,000 ml pH (25 ° C / acetic acid and ammonia water) 5.8

[Rinse Solution] Sodium chlorinated isocyanurate 0.02 g Deionized water (conductivity 5 μs / cm or less) 1000 ml pH 6.5

The difference between the magenta density at the exposure point giving the maximum yellow color density and the magenta density at the exposure area giving the minimum yellow color density of the obtained color-developed sample was determined to obtain the magenta color turbidity in the yellow color development.
Shown in FIG. From the table, it is understood that the combination of the compound of the present invention and the yellow coupler of the present invention can sufficiently prevent color turbidity while giving high yellow maximum color density.

[0221]

[Table 14]

Example 5 Preparation of Sample 501 A sample 501 was prepared by preparing a multilayer color light-sensitive material having the following compositions on a cellulose triacetate film support having a thickness of 127 μ and having an undercoat. The numbers represent the amount added per m ² . The effect of the added compound is not limited to the described use.

First layer: antihalation layer Black colloidal silver 0.20 g Gelatin 1.9 g UV absorber U-1 0.1 g UV absorber U-3 0.04 g UV absorber U-4 0.1 g High boiling organic solvent Oil-1 0.1 Microcrystalline solid dispersion of Dye E-1 0.1 g

Second layer: intermediate layer Gelatin 0.40 g Compound Cpd-C 5 mg Compound Cpd-J 5 mg Compound Cpd-K 3 mg High boiling point organic solvent Oil-3 0.1 g Dye D-4 0.4 mg

Third Layer: Intermediate Layer Finely grained silver iodobromide emulsion with a fogged surface and inside (average grain size 0.06 μm, coefficient of variation 18%, AgI content 1 mol%) silver amount 0.05 g gelatin 0.4 g

Fourth layer: low-sensitivity red-sensitive emulsion layer Emulsion A Silver amount 0.1 g Emulsion B Silver amount 0.4 g Gelatin 0.8 g Coupler C-1 0.15 g Coupler C-2 0.05 g Coupler C-3 0.05 g Coupler C-9 0.05 g Compound Cpd-C 10 mg High boiling point organic solvent Oil-2 0.1 g Additive P-1 0.1 g

Fifth layer: Medium-sensitive red-sensitive emulsion layer Emulsion B Silver amount 0.2 g Emulsion C Silver amount 0.3 g Gelatin 0.8 g Coupler C-1 0.2 g Coupler C-2 0.05 g Coupler C-3 0.2 g High boiling point organic solvent Oil-2 0.1 g Additive P-1 0.1 g

Sixth layer: High-sensitivity red-sensitive emulsion layer Emulsion D Silver amount 0.4 g Gelatin 1.1 g Coupler C-1 0.3 g Coupler C-2 0.1 g Coupler C-3 0.7 g Additive P-1 0.1 g

Seventh layer: intermediate layer Gelatin 0.6 g Additive M-1 0.3 g Color mixture inhibitor Cpd-I 2.6 mg UV absorber U-1 0.01 g UV absorber U-2 0.002 g UV absorber U-5 0.01 g Dye D-1 0.02 g Compound Cpd-C 5 mg Compound Cpd-J 5 mg Compound Cpd-K 5 mg High boiling point organic solvent Oil-1 0.02 g

Eighth layer: intermediate layer Silver iodobromide emulsion with fogged surface and inside (average grain size 0.06 μm, variation coefficient 16%, AgI content 0.3 mol%) silver amount 0.02 g gelatin 1.0 g additive P- 10.2 g Color mixing inhibitor Cpd-A 0.1 g

Ninth layer: low-sensitivity green-sensitive emulsion layer Emulsion E Silver amount 0.1 g Emulsion F Silver amount 0.2 g Emulsion G Silver amount 0.2 g Gelatin 0.5 g Coupler C-4 0.1 g Coupler C-7 0.05 g Coupler C-8 0.20 g Compound Cpd-B 0.03 g Compound Cpd-C 10 mg Compound Cpd-D 0.02 g Compound Cpd-E 0.02 g Compound Cpd-F 0.02 g Compound Cpd-G 0.02 g High boiling point organic solvent Oil-1 0.1 g High boiling point organic Solvent Oil-2 0.1 g

Layer 10: Medium-speed green-sensitive emulsion layer Emulsion G Silver amount 0.3 g Emulsion H Silver amount 0.1 g Gelatin 0.6 g Coupler C-4 0.1 g Coupler C-7 0.2 g Coupler C-8 0.1 g Compound Cpd-B 0.03g Compound Cpd-D 0.02g Compound Cpd-E 0.02g Compound Cpd-F 0.05g Compound Cpd-G 0.05g High boiling organic solvent Oil-2 0.01g

Eleventh layer: High-sensitivity green-sensitive emulsion layer Emulsion I Silver amount 0.5 g Gelatin 1.0 g Coupler C-4 0.3 g Coupler C-7 0.1 g Coupler C-8 0.1 g Compound Cpd-B 0.08 g Compound Cpd-C 5 mg Compound Cpd-D 0.02 g Compound Cpd-E 0.02 g Compound Cpd-F 0.02 g Compound Cpd-G 0.02 g Compound Cpd-J 5 mg Compound Cpd-K 5 mg High boiling point organic solvent Oil-1 0.02 g High boiling point organic Solvent Oil-2 0.02g

Twelfth layer: intermediate layer Gelatin 0.6 g

Thirteenth layer: Yellow filter layer Yellow colloidal silver Silver amount 0.07 g Gelatin 1.1 g Color mixing inhibitor Cpd-A 0.01 g High boiling point organic solvent Oil-1 0.01 g Dye E-2 microcrystalline solid dispersion 0.05 g

Fourteenth layer: Intermediate layer 0.6 g of gelatin

Fifteenth layer: low-sensitivity blue-sensitive emulsion layer Emulsion J Silver amount 0.2 g Emulsion K Silver amount 0.3 g Emulsion L Silver amount 0.1 g Gelatin 0.8 g Coupler C-5 0.2 g Coupler C-6 0.1 g Coupler C-10 0.4 g

Sixteenth layer: Medium sensitivity blue-sensitive emulsion layer Emulsion L Silver amount 0.1 g Emulsion M Silver amount 0.4 g Gelatin 0.9 g Coupler C-5 0.3 g Coupler C-6 0.1 g Coupler C-10 0.1 g

Seventeenth layer: High-sensitivity blue-sensitive emulsion layer Emulsion N Silver amount 0.4 g Gelatin 1.2 g Coupler C-5 0.3 g Coupler C-6 0.6 g Coupler C-10 0.1 g

[0240]

19th layer: Second protective layer Colloidal silver Silver amount 0.1 mg Fine grain silver iodobromide emulsion (average particle size 0.06 μm, AgI content 1 mol%) Silver amount 0.1 g Gelatin 0.4 g

20th layer: Third protective layer Gelatin 0.4 g Polymethylmethacrylate (average particle size 1.5 μ) 0.1 g Copolymer of methylmethacrylate and acrylic acid 4: 6 (average particle size 1.5 μ) 0.1 g Silicone oil 0.03g Surfactant W-1 3.0mg Surfactant W-2 0.03g

In addition to the above composition, additives F-1 to F-8 were added to all emulsion layers. In addition to the above composition, gelatin hardener H-1 and coating and emulsifying surfactants W-3, W-4, W-5 and W-6 were added to each layer. Furthermore, phenol, 1,2-benzisothiazolin-3-one, 2-phenoxyethanol, phenethyl alcohol, and p-benzoic acid butyl ester were added as antiseptic and antifungal agents.

[0244]

[Table 15]

[0245]

[Table 16]

[0246]

[Table 17]

[0247]

[Chemical 84]

[0248]

[Chemical 85]

[0249]

[Chemical formula 86]

[0250]

[Chemical 87]

[0251]

[Chemical 88]

[0252]

[Chemical 89]

[0253]

[Chemical 90]

[0254]

[Chemical Formula 91]

[0255]

[Chemical Formula 92]

[0256]

[Chemical formula 93]

[0257]

[Chemical 94]

[0258]

[Chemical 95]

[0259]

[Chemical 96]

[0260]

[Chemical 97]

The silver halide color photographic light-sensitive material prepared as described above was exposed and then processed according to the following steps. Treatment process Time Temperature First development 6 minutes 38 ° C Water wash 2 minutes 38 ° C Inversion 2 minutes 38 ° C Color development 6 minutes 38 ° C adjustment 2 minutes 38 ° C Bleach 6 minutes 38 ° C Settling 4 minutes 38 ° C Water wash 4 minutes 38 ° C stable 1 minute 25 ° C

The composition of each processing liquid was as follows. [First developer] Nitrilo-N, N, N-trimethylenephosphonic acid / 5 sodium salt 1.5 g Diethylenetriamine pentaacetic acid / 5 sodium salt 2.0 g Sodium sulfite 30 g Hydroquinone / potassium monosulfonate 20 g Potassium carbonate 15 g Sodium bicarbonate 12 g 1-Phenyl-4-methyl-4-hydroxymethyl-3-pyrazolidone 1.5 g Potassium bromide 2.5 g Potassium thiocyanate 1.2 g Potassium iodide 2.0 mg Diethylene glycol 13 g Water added 1000 ml pH 9.60 pH is hydrochloric acid or potassium hydroxide I adjusted it with.

[Reversal Liquid] Nitrilo-N, N, N-trimethylenephosphonic acid-5 sodium salt 3.0 g stannous chloride dihydrate 1.0 g p-aminophenol 0.1 g sodium hydroxide 8 g glacial acetic acid 15 ml water 1000 ml pH 6.00 The pH was adjusted with hydrochloric acid or sodium hydroxide.

[Color developer] Nitrilo-N, N, N-trimethylenephosphonic acid / 5 sodium salt 2.0 g sodium sulfite 7.0 g trisodium phosphate dodecahydrate 36 g potassium bromide 1.0 g potassium iodide 90 mg hydroxide Sodium 3.0g Citrazic acid 1.5g N-ethyl-N- (β-methanesulfonamidoethyl) -3-methyl-4-aminoaniline / 3/2 sulfuric acid monohydrate 11g 3,6-dithiaoctane-1,8- Diol 1.0 g Water was added to 1000 ml pH 11.80 The pH was adjusted with hydrochloric acid or potassium hydroxide.

[Preparation liquid] Ethylenediamine tetraacetic acid / disodium salt / dihydrate 8.0 g Sodium sulfite 12 g 1-Thioglycerol 0.4 g Sodium formaldehyde bisulfite adduct 30 g Water is added to 1000 ml pH 6.20 pH is hydrochloric acid or hydroxylation Adjusted with sodium.

[Bleach] Ethylenediaminetetraacetic acid ・ disodium salt ・ dihydrate 2.0 g Ethylenediaminetetraacetic acid ・ Fe (III) ・ ammonium ・ dihydrate 120 g Potassium bromide 100 g Ammonium nitrate 10 g Water added 1000 ml pH 5.70 pH Was adjusted with hydrochloric acid or sodium hydroxide.

[Fixer] Ammonium thiosulfate 80 g Sodium sulfite 5.0 g Sodium bisulfite 5.0 g Water was added to 1000 ml pH 6.60 The pH was adjusted with hydrochloric acid or aqueous ammonia.

[Stabilizer] Benzisothiazolin-3-one 0.02 g Polyoxyethylene-p-monononylphenyl ether (average degree of polymerization 10) 0.3 g Water was added to 1000 ml pH 7.0

Cpd- of the eighth and thirteenth layers of Sample 501
A is the compound (2) -1, (2) -3, (2)-of the present invention.
8, (3) -1, (4) -2, (4) -3, (4)-
5, samples (7) -1 and (8) -1 were replaced with equimolar amounts, and subjected to the same exposure and color development processing as Sample 501. As a result, compared to Sample 501, the colors of magenta and yellow were increased. Improvement of turbidity was observed. The yellow coupler C- of the 15th, 16th and 17th layers of Sample 501
Experiment in which 10 (coupler Y-18 of the present invention) was replaced with couplers Y-12, Y-19 and Y-20 of the present invention in equimolar amounts, and Cpd-A of the eighth layer and the thirteenth layer were similarly replaced. However, the same effect was obtained.

Claims (2)

[Claims] 1. A red-sensitive silver halide emulsion layer on a support,
In a silver halide color photographic light-sensitive material having a green-sensitive silver halide emulsion layer, a blue-sensitive silver halide emulsion layer and a non-photosensitive layer, an acylacetamide type yellow dye-forming coupler having an acyl group represented by the following general formula (1) And the following general formulas (2), (3), (4), (5), (6),
A silver halide color photographic light-sensitive material comprising at least one selected from the group of non-color forming and diffusion resistant compounds represented by (7) or (8). General formula (1) [In the formula, R ₁ represents a monovalent group. Q is 3 with C
Represents a non-metallic atomic group necessary for forming a 5- to 5-membered hydrocarbon ring or a 3- to 5-membered heterocycle having at least one hetero atom selected from N, O, S, and P in the ring. However, R ₁ is not a hydrogen atom and does not combine with Q to form a ring. ] General formula (2) General formula (3) General formula (4) General formula (5) General formula (6) General formula (7) General formula (8) [In the formula, R ²¹ is a hydrogen atom, an aliphatic group or a heterocyclic group, R ³¹ and R ⁴¹ are a hydrogen atom, an aliphatic group, an aromatic group or a heterocyclic group, and R ¹² , R ²² , R ³² and R ⁷¹ are a hydrogen atom, an alkyl group, an aralkyl group, an aryl group, a heterocyclic group, an alkoxy group, an aryloxy group, an amino group, an alkenyl group, an alkynyl group or a hydrazino group, and R ⁴²
Is a cyano group, a nitro group, a perfluoroalkyl group or a thioacyl group, G ³¹ is —SO ₂ —, —SO—, —PO (R ³⁵ ) —, iminomethylene or —COCO—, and R ³⁵ Is an alkyl group or an aryl group, G ⁵¹ and G ⁷¹ are the same as those described for G ³¹ , with addition of —CO—, and R ¹³ , R ²³ ,
R ³³ , R ⁴³ , R ⁵³ , R ⁷³ , R ¹⁴ , R ²⁴ , R ³⁴ , R ⁴⁴ , R
⁵⁴ and R ⁷⁴ are a hydrogen atom or a group removed under alkaline conditions, R ⁷³ may be an alkyl group, R ¹¹ is a substituent for the benzene ring, and Z ⁵¹ is a group necessary for forming a ring. Y ⁶¹ is a divalent group having a hydrazine or hydroxylamine structure, L ⁶¹ and L ⁶² are divalent linking groups, n, m and q are 0, 1 or 2, and j, k is 0 or 1. The groups described above may have a substituent. ] 2. The non-photosensitive layer has the general formulas (2), (3),
(4), (5), (6), (7) or at least one selected from the group of compounds represented by (8) is contained, the halogen according to claim (1). Silver halide color photographic light-sensitive material.