JPH05159757A - Thin type battery - Google Patents

Thin type battery

Info

Publication number
JPH05159757A
JPH05159757A JP3349531A JP34953191A JPH05159757A JP H05159757 A JPH05159757 A JP H05159757A JP 3349531 A JP3349531 A JP 3349531A JP 34953191 A JP34953191 A JP 34953191A JP H05159757 A JPH05159757 A JP H05159757A
Authority
JP
Japan
Prior art keywords
current collector
battery
active material
positive electrode
negative electrode
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP3349531A
Other languages
Japanese (ja)
Inventor
Hiroshi Kagawa
博 香川
Shiro Kato
史朗 加藤
Kazuo Murata
和雄 村田
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Yuasa Corp
Original Assignee
Yuasa Corp
Yuasa Battery Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Yuasa Corp, Yuasa Battery Corp filed Critical Yuasa Corp
Priority to JP3349531A priority Critical patent/JPH05159757A/en
Priority to PCT/JP1992/001577 priority patent/WO1993011572A1/en
Priority to DE69218587T priority patent/DE69218587T2/en
Priority to US08/087,682 priority patent/US5401595A/en
Priority to CA002100678A priority patent/CA2100678A1/en
Priority to EP92924870A priority patent/EP0570590B1/en
Publication of JPH05159757A publication Critical patent/JPH05159757A/en
Pending legal-status Critical Current

Links

Classifications

    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

Landscapes

  • Sealing Battery Cases Or Jackets (AREA)
  • Secondary Cells (AREA)

Abstract

PURPOSE:To provide a thin type battery wherein a battery internal temperature is not increased, even when power consumption is increased at the time of using the battery, to improve heat radiating efficiency by providing a fuse function for preventing fire and bursting. CONSTITUTION:In a thin type battery consisting of a generating element of laminating a positive pole active material 4, electrolytic layer 9 and a negative pole active material 8, a band-shaped positive pole current collecting terminal 2 is provided in the upper end part and a radiating fin 3 is provided in the side end part, of a positive pole current collector 1 of holding the positive pole active material. A band-shaped negative pole current collecting terminal 10 is provided in the upper end part and a radiating fin is provided in the side end part, of a negative pole current collector 7 of holding a negative pole having a carbon material or a negative pole consisting of lithium. Further, a sealing agent 6 is arranged in a peripheral edge part of the current collector except a part of the radiating fin and current collecting terminal, and the mutual sealing agent is bonded to close the inside of the battery in a pressure reducing condition by arranging each of the pole current collector opposed to each other.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は、エレクトロニクス機
器、電気自動車などの分野に使われる薄形電池の電池構
造に関するものである。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a battery structure of a thin battery used in fields such as electronic equipment and electric vehicles.

【0002】[0002]

【従来の技術】従来この種の薄形電池は、図5に示すよ
うな構造であって、正極活物質層、電解質層及び負極活
物質層を層状に重ねた発電要素の上下に正極集電体兼電
槽及び負極集電体兼電槽を配置し、接着性樹脂と集電体
兼電槽を一体化したものであり、更にこれを図6の如く
積層して用いていた。このような従来の構成では、消費
電力を大きくすると電池内部温度が上昇し、最悪の場合
には電池が発火又は破裂することがあった。
2. Description of the Related Art Conventionally, a thin battery of this type has a structure as shown in FIG. 5, in which a positive electrode current collector is provided above and below a power generating element in which a positive electrode active material layer, an electrolyte layer and a negative electrode active material layer are layered. A body-cum-battery and a negative electrode current-collector-cell were arranged, and the adhesive resin and the current-collector-cell were integrated, and these were laminated and used as shown in FIG. In such a conventional configuration, when the power consumption is increased, the internal temperature of the battery rises, and in the worst case, the battery may ignite or burst.

【0003】[0003]

【発明が解決しようとする課題】本発明は、上記の問題
点に鑑みなされたもので、電池使用時に消費電力が大き
くなっても電池内部温度が上昇せず、また発火、破裂を
防止するヒュ−ズ機能を有し、放熱効率を高めた薄形電
池を提供することを目的とするものである。
SUMMARY OF THE INVENTION The present invention has been made in view of the above problems, and does not cause the internal temperature of the battery to rise even if the power consumption increases when the battery is used, and prevents the ignition and the explosion. The purpose of the present invention is to provide a thin battery having a negative opening function and improved heat dissipation efficiency.

【0004】[0004]

【課題を解決するための手段】本発明は上記目的を達成
するべく、正極活物質を保持した正極集電体上端部に帯
状の正極集電端子と側端部に放熱フィンを設けること、
負極活物質を保持した負極集電体上端部に帯状の負極集
電端子と側端部に放熱フィンを設けること、該放熱フィ
ン及び集電端子部を除く集電体の周縁部に封口剤を配置
すること、該各極集電体を向き合わせて配置し互いの封
口剤を接着し電池内を減圧状態で密閉すること、各極集
電端子の帯部の一部に欠損部を設けたこと、各集電端子
が互いに横にずれて配置されていること、負極放熱フィ
ンと正極放熱フィンが互いに反対側に設けられているこ
となどを特徴とするものである。
In order to achieve the above object, the present invention provides a strip-shaped positive electrode current collector terminal at the upper end of the positive electrode current collector holding a positive electrode active material and a radiation fin at the side end.
A strip-shaped negative electrode current collector terminal is provided at the upper end of the negative electrode current collector that holds the negative electrode active material, and heat radiation fins are provided at the side ends, and a sealing agent is provided at the periphery of the current collector excluding the heat radiation fin and the current collector terminal portion. Arranging, arranging the current collectors facing each other, adhering a sealing agent to each other, and sealing the inside of the battery in a depressurized state, providing a defect in a part of the band of each current collector terminal. That is, the current collecting terminals are arranged laterally offset from each other, and the negative electrode heat radiation fins and the positive electrode heat radiation fins are provided on opposite sides.

【0005】[0005]

【作用】本発明において、集電板の上側端部に帯状の集
電端子(一部に欠損部を設ける)及び側端部に放熱フィ
ンを設けたものの中央部に活物質を保持し、さらにその
周縁部に封口剤を配置した正極集電板及び負極集電体を
互いに重ね合わせ封口する。このような電池では放熱フ
ィンが互いに独立して配置されているため、電池温度が
上がっても電気的に短絡することなく放熱でき、また集
電端子の一部欠損部により不良電池が該欠損部で切り離
され異常な温度上昇を防止する。またこれらの加工が連
続で行われるため、生産性が高く製造することができ
る。
In the present invention, the current collector is provided with a band-shaped collector terminal (a part of which is provided with a cutout) at the upper end of the collector plate and a radiation fin at the side end of the collector to retain the active material in the center. A positive electrode current collector plate and a negative electrode current collector, each having a sealing agent arranged on the peripheral portion thereof, are stacked and sealed. In such a battery, since the heat radiation fins are arranged independently of each other, heat can be radiated without electrical short-circuiting even when the battery temperature rises, and a defective battery can cause a defective battery to be partially damaged. It is separated by and prevents abnormal temperature rise. Further, since these processes are continuously performed, it is possible to manufacture with high productivity.

【0006】[0006]

【実施例】以下、本発明の詳細について、一実施例によ
り説明する。図1に示すように縦が約54mm、横が約
86mmの正極集電体1(ステンレス製集電体)の上側
端部に一部欠損部2’を設けた正極端子2を設け、且つ
側端部に放熱フィン3(幅約6mm)を設けた。次に中
央部表面に二酸化マンガンを主成分とする正極活物質4
をスクリ−ン印刷(縦が約50mm、横が約76mm)
し、さらに該正極活物質の表面を覆うようにポリエチレ
ンオキシドに過塩素酸リチウムを加えた高分子固体電解
質5を同じくスクリ−ン印刷した。次にポリプロピレン
系熱接着性樹脂などからなる封口剤6を周縁に接着し
た。また図2に示すように正極集電体1とほぼ同様な形
状の負極集電体7(ステンレス製集電体)の表面にリチ
ウムから成る負極活物質8をスクリ−ン印刷し、さらに
該負極活物質の表面を覆うようにポリエチレンオキシド
に過塩素酸リチウムを加えた高分子固体電解質9を同じ
くスクリ−ン印刷した。次に前記と同様に封口剤6を周
縁に接着した。このように加工した正極集電体と負極集
電体が対向するように重ね合わせて厚み0.2〜1.0
mmの発電要素を作成し、減圧下で添加物を含有したポ
リプロピレン系熱接着性樹脂などからなる封口剤6を互
いに熱融着し、集電体の内部を減圧密閉した。
EXAMPLES Details of the present invention will be described below with reference to examples. As shown in FIG. 1, a positive electrode current collector 1 (stainless steel current collector) having a vertical length of about 54 mm and a horizontal length of about 86 mm is provided with a positive electrode terminal 2 having a partially defective portion 2 ', and Radiating fins 3 (width of about 6 mm) were provided at the ends. Next, a positive electrode active material 4 containing manganese dioxide as a main component was formed on the central surface.
Screen printing (vertical length is about 50 mm, horizontal length is about 76 mm)
Then, the polymer solid electrolyte 5 obtained by adding lithium perchlorate to polyethylene oxide was screen printed in the same manner so as to cover the surface of the positive electrode active material. Next, a sealing agent 6 made of polypropylene-based heat-adhesive resin or the like was adhered to the periphery. Further, as shown in FIG. 2, a negative electrode active material 8 made of lithium is screen-printed on the surface of a negative electrode current collector 7 (stainless steel current collector) having substantially the same shape as the positive electrode current collector 1, and the negative electrode current collector 8 is further printed. The polymer solid electrolyte 9 in which lithium perchlorate was added to polyethylene oxide was screen printed in the same manner so as to cover the surface of the active material. Then, the sealing agent 6 was adhered to the periphery in the same manner as described above. The positive electrode current collector and the negative electrode current collector processed in this manner are laminated so as to face each other and have a thickness of 0.2 to 1.0.
A mm power generation element was prepared, and a sealing agent 6 made of a polypropylene-based heat-adhesive resin containing an additive and the like was heat-sealed to each other under reduced pressure, and the inside of the current collector was hermetically sealed under reduced pressure.

【0007】このようにして得られた電池の正面図を図
3に示す。正極側の端子2と負極側の端子10及び放熱
フィン3と放熱フィン11は互いに離れている。また図
4に図3のA−A’部の拡大断面図を示す。
A front view of the battery thus obtained is shown in FIG. The positive electrode side terminal 2, the negative electrode side terminal 10, the heat radiation fin 3 and the heat radiation fin 11 are separated from each other. Further, FIG. 4 shows an enlarged cross-sectional view of the AA ′ portion of FIG.

【0008】本発明の実施例による電池と従来の構造の
電池の各5セルについて、高率放電時での電池温度上昇
変化を表1に示した。
Table 1 shows changes in the battery temperature at the time of high rate discharge for each of the 5 cells of the battery according to the embodiment of the present invention and the battery of the conventional structure.

【0009】 [0009]

【0010】また、これらの電池を複数個積層させた場
合の電気的な安全性について、不良電池が電気的回路か
ら切り離されるかを調査した。従来は不良電池にも常に
電流が流れ、全体の電池特性を悪くしていたが、本発明
による電池を積層した場合は不良電池が端子の欠損部か
ら切り離されていた。
Further, regarding the electrical safety when a plurality of these batteries are laminated, it was investigated whether or not the defective battery is disconnected from the electrical circuit. Conventionally, current always flows through a defective battery to deteriorate the overall battery characteristics, but when the batteries according to the present invention are stacked, the defective battery is separated from the defective portion of the terminal.

【0011】[0011]

【発明の効果】上述したごとく、本発明は電池の安全性
を高め人が常時携帯するIDカ−ド、携帯用電話、メモ
リ−カ−ド、ポケットベルなど及び電気自動車に装着で
き、従来に比べて信頼性が高く工業的価値は極めて大で
ある。
As described above, the present invention enhances the safety of the battery and can be installed in an ID card, a mobile phone, a memory card, a pager, etc., and an electric vehicle that a person always carries. In comparison, it is highly reliable and its industrial value is extremely high.

【図面の簡単な説明】[Brief description of drawings]

【図1】本発明の薄形電池の正極集電体の斜視図であ
る。
FIG. 1 is a perspective view of a positive electrode current collector of a thin battery of the present invention.

【図2】本発明の薄形電池の負極集電体の斜視図であ
る。
FIG. 2 is a perspective view of a negative electrode current collector of the thin battery of the present invention.

【図3】本発明の薄形電池の正面図である。FIG. 3 is a front view of the thin battery of the present invention.

【図4】本発明の薄形電池の拡大断面図である。FIG. 4 is an enlarged cross-sectional view of the thin battery of the present invention.

【図5】従来の薄形電池の斜視図である。FIG. 5 is a perspective view of a conventional thin battery.

【図6】従来の薄形電池を積層した状態の斜視図であ
る。
FIG. 6 is a perspective view showing a state in which conventional thin batteries are stacked.

【符号の説明】[Explanation of symbols]

1 正極集電体 2 正極端子 2’ 欠損部 3、11 放熱フィン 6 封口剤 7 負極集電体 10 負極端子 10’ 欠損部 12 端子 DESCRIPTION OF SYMBOLS 1 Positive electrode collector 2 Positive electrode terminal 2'missing part 3 and 11 Radiating fin 6 Sealing agent 7 Negative electrode current collector 10 Negative electrode terminal 10 'Missing part 12 terminal

Claims (4)

【特許請求の範囲】[Claims] 【請求項1】 正極活物質、電解質層及び負極活物質を
層状に重ねた発電要素からなる薄形電池において、正極
活物質を保持した正極集電体上端部に帯状の正極集電端
子と側端部に放熱フィンを設けること、炭素質材料を有
する負極又はリチウムからなる負極を保持した負極集電
体上端部に帯状の負極集電端子と側端部に放熱フィンを
設けること、該放熱フィン及び集電端子部を除く集電体
の周縁部に封口剤を配置すること、該各極集電体を向き
合わせて配置し互いの封口剤を接着し電池内を減圧状態
で密閉したことを特徴とする薄形電池。
1. A thin battery comprising a positive electrode active material, an electrolyte layer, and a power generation element in which a negative electrode active material is laminated in layers, wherein a strip-shaped positive electrode current collector terminal and a side are provided on an upper end portion of a positive electrode current collector holding the positive electrode active material. Providing a radiation fin at the end, providing a strip-shaped negative current collector terminal at the upper end of the negative electrode current collector holding a negative electrode having a carbonaceous material or a negative electrode made of lithium, and providing a radiation fin at the side end, And disposing a sealing agent on the peripheral portion of the current collector excluding the current collecting terminal portion, arranging the respective electrode current collectors facing each other and adhering the sealing agent to each other, and sealing the inside of the battery under reduced pressure. Characteristic thin battery.
【請求項2】 各極集電端子の帯部の一部に欠損部を設
けたことを特徴とする請求項1記載の薄形電池。
2. The thin battery according to claim 1, wherein a defective portion is provided in a part of a band portion of each of the current collector terminals.
【請求項3】 各集電端子が互いに横にずれて配置され
ていることを特徴とする請求項1又は2記載の薄形電
池。
3. The thin battery according to claim 1, wherein the current collecting terminals are arranged laterally offset from each other.
【請求項4】 負極放熱フィンと正極放熱フィンが互い
に反対側に設けられていることを特徴とする請求項1、
2又は3記載の薄形電池。
4. The negative electrode heat radiation fin and the positive electrode heat radiation fin are provided on opposite sides of each other.
The thin battery according to 2 or 3.
JP3349531A 1991-12-06 1991-12-06 Thin type battery Pending JPH05159757A (en)

Priority Applications (6)

Application Number Priority Date Filing Date Title
JP3349531A JPH05159757A (en) 1991-12-06 1991-12-06 Thin type battery
PCT/JP1992/001577 WO1993011572A1 (en) 1991-12-06 1992-12-02 Thin battery and monolithic thin battery
DE69218587T DE69218587T2 (en) 1991-12-06 1992-12-02 THIN BATTERY AND MONOLITICAL THIN BATTERY
US08/087,682 US5401595A (en) 1991-12-06 1992-12-02 Film type battery and layer-built film type battery
CA002100678A CA2100678A1 (en) 1991-12-06 1992-12-02 Film type battery and layer-built film type battery
EP92924870A EP0570590B1 (en) 1991-12-06 1992-12-02 Thin battery and monolithic thin battery

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP3349531A JPH05159757A (en) 1991-12-06 1991-12-06 Thin type battery

Publications (1)

Publication Number Publication Date
JPH05159757A true JPH05159757A (en) 1993-06-25

Family

ID=18404356

Family Applications (1)

Application Number Title Priority Date Filing Date
JP3349531A Pending JPH05159757A (en) 1991-12-06 1991-12-06 Thin type battery

Country Status (1)

Country Link
JP (1) JPH05159757A (en)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6902847B1 (en) 1998-05-20 2005-06-07 Osaka Gas Company Limited Non-aqueous secondary cell and method for controlling the same
JP2005203192A (en) * 2004-01-14 2005-07-28 Toyota Motor Corp Laminated secondary battery
JP2009110936A (en) * 2007-10-10 2009-05-21 Panasonic Corp Lithium ion secondary battery
JP2010080325A (en) * 2008-09-26 2010-04-08 Asahi Kasei Corp Nonaqueous lithium type storage element and method of manufacturing the same
JP2011510433A (en) * 2007-12-25 2011-03-31 ビーワイディー カンパニー リミテッド Battery system for a vehicle having a separable connection
US8318347B2 (en) 2007-10-10 2012-11-27 Panasonic Corporation Lithium ion secondary battery
US10147930B2 (en) 2007-12-25 2018-12-04 Shenzhen Byd Auto R&D Company Limited Construction of electrochemical storage cell with conductive block

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6951699B2 (en) 1998-05-20 2005-10-04 Osaka Gas Company Limited Non-aqueous secondary battery and its control method
US6902847B1 (en) 1998-05-20 2005-06-07 Osaka Gas Company Limited Non-aqueous secondary cell and method for controlling the same
US7642001B2 (en) 1998-05-20 2010-01-05 Osaka Gas Company Limited Non-aqueous secondary battery and its control method
US8110303B2 (en) 1998-05-20 2012-02-07 Kri Inc. Non-aqueous secondary battery and its control method
JP4590869B2 (en) * 2004-01-14 2010-12-01 トヨタ自動車株式会社 Laminated secondary battery
JP2005203192A (en) * 2004-01-14 2005-07-28 Toyota Motor Corp Laminated secondary battery
JP2009110936A (en) * 2007-10-10 2009-05-21 Panasonic Corp Lithium ion secondary battery
JP2011040407A (en) * 2007-10-10 2011-02-24 Panasonic Corp Lithium ion secondary battery
JP4695170B2 (en) * 2007-10-10 2011-06-08 パナソニック株式会社 Lithium ion secondary battery
US8318347B2 (en) 2007-10-10 2012-11-27 Panasonic Corporation Lithium ion secondary battery
JP2011510433A (en) * 2007-12-25 2011-03-31 ビーワイディー カンパニー リミテッド Battery system for a vehicle having a separable connection
US10147930B2 (en) 2007-12-25 2018-12-04 Shenzhen Byd Auto R&D Company Limited Construction of electrochemical storage cell with conductive block
US10381632B2 (en) 2007-12-25 2019-08-13 Shenzhen Byd Auto R&D Company Limited Construction of electrochemical storage cell with conductive bridge
JP2010080325A (en) * 2008-09-26 2010-04-08 Asahi Kasei Corp Nonaqueous lithium type storage element and method of manufacturing the same

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