JPH05126822A - Total organism carbon measuring apparatus - Google Patents

Abstract

PURPOSE:To achieve a recording of a TC value, an IC value and a TOC value with a single pen recorder and an identification of the TOC value from other out values. CONSTITUTION:A TC memory 4 stores a TC measured value detected with a CO2 detecting section 2 and an IC memory 6 stores an IC measured value detected with the CO2 detecting section 2. A TOC calculating section 8 determines a difference between both the measured values to calculate the concentration of TOC. An analog output section 10 outputs the TC measured value, the IC measured value and the TOC calculated value by one analog signal sequentially while it controls an output operation to differentiate the output time of the TOC calculated value rom the output time of the TC measured value and IC measured value.

Description

Detailed Description of the Invention

[0001]

The present invention comprises a carrier gas supply unit, a sample injection unit, a combustion oxidation reaction unit and a CO ₂ detection unit, and measures total carbon (TC) and inorganic carbon (IC) in a sample separately. The present invention relates to a total organic carbon (TOC) meter, and more particularly to a TOC meter characterized by an output system of its measured value.

[0002]

2. Description of the Related Art In a TOC meter, in order to obtain a TOC value, T
A method of measuring C and IC separately and obtaining TOC = TC-IC is mainly used. Such TOC
As for the output, only the TOC value is output as an analog signal, or all of the TC value, the IC value and the TOC value are output as analog signals to, for example, a 3-pen recorder for recording.

[0003]

Problem to be Solved by the Invention TC value, IC value and T value
In order to record the three outputs of the OC value on the recorder, the conventional method requires a three-pen recorder. But 3
Pen recorders are significantly more expensive than one-pen recorders. Therefore, the present invention outputs a TC value, an IC value and a TOC value on one analog signal using a one-pen recorder,
In addition, the purpose is to make it possible to distinguish the TOC value from other output values.

[0004]

FIG. 1 shows the present invention. T
The C memory 4 stores the TC measurement value detected by the CO ₂ detection unit 2, and the IC memory 6 stores the I measurement value detected by the CO ₂ detection unit 2.
Store C measurements. The TOC calculator 8 calculates the TOC concentration by taking the difference between the two measured values. The analog output unit 10 is T
The C measurement value, the IC measurement value, and the TOC calculation value are sequentially output as one analog signal, and the output operation is controlled so that the output time of the TOC calculation value is different from the output time of the TC measurement value and the IC measurement value.

[0005]

1 shows an example of a TOC meter to which the present invention is applied. The sample flows into the flow-through type sample container 12 from the lower inlet, and the sample is discharged from the upper outlet. A fixed amount of the sample in the sample container 12 is collected by the sample injection unit 14, and the TC reaction unit 1
6 or the IC reaction part 18 is switched to be guided. The TC reaction section 16 is provided with a TC combustion tube filled with an oxidation catalyst, and a heating furnace is provided outside the TC combustion tube to heat the TC combustion tube. To the TC reaction section 16, pure oxygen gas or high-purity air from which CO ₂ and hydrocarbons have been removed is supplied from the carrier gas supply section 20 as a carrier gas at a controlled gas flow rate. In the TC reaction section 16, all the carbon components in the supplied sample are converted into CO ₂ gas and guided to the measurement cell of the non-dispersion type infrared gas analyzer (NDIR) 22 of the CO ₂ detection section to be detected. Inorganic carbon is generated as CO ₂ gas in the IC reaction section 18, and NDI is generated together with the carrier gas.
It is guided to the measuring cell of R22 and detected. Sample injection part 1
In the case of No. 4, the standard solution 23 can also be injected to prepare a calibration curve for TC or IC.

In order to process the detected value of the NDIR 22,
A signal processing unit 24 is provided, and the signal processing unit 24 operates at T
TOC is calculated from C and IC, and TC, IC and TOC are calculated.
The analog output unit 10 is connected to the signal processing unit 24 in order to output to the recorder. Reference numeral 26 is a measurement value display / printing unit for displaying and printing the measurement values. Comparing FIG. 1 and FIG. 2, the TC memory 4, the IC memory 6, and the TOC calculation unit 8 correspond to the signal processing unit 24.

In the operation of one embodiment, the TC value and the IC value of the sample are measured at a certain measurement cycle (for example, 10-minute cycle),
Calculate the TOC value by calculating the difference (TC-IC)
It is displayed on the screen such as T or printed on the printer.
An analog signal (DC0 to 1VDC) that outputs those measured values
Or DC4 ~ 20mA) TC value, IC value and TOC
The signals corresponding to the values are sequentially output. In order to distinguish the TOC value from the IC value or the TC value, the TC value and the IC value are each 1
The TOC value is output only for 0 seconds, and the TOC value is output for the rest of the time (9 minutes and 40 seconds in the case of measurement of 10-minute cycle).

According to FIG. 3 and FIG. 4, TC value, IC value and TO
A procedure for outputting the C value will be described. TC value → I as an example
It is assumed that the C value is measured in order and then the TOC value is calculated. When the measurement of TC value is completed (step 1),
The TC value is stored in the memory (step S2 → S
3). Next, when the measurement of the IC value is completed, the IC value is stored in the memory (steps S2 → S4), and the TOC value is calculated as TOC = TC-IC (step S5).
After that, the TC value is analog-outputted for 10 seconds (step S
6) Then, the IC value is analog-outputted for 10 seconds (step S7), and then the TOC value is analog-outputted (step S8). The analog signal is configured to be held unless the output value is changed. Therefore, the TOC value of the previous measurement continues to be output until the next TC measurement and IC measurement are completed and the TOC value is calculated. The output is as shown in FIG.

In the description of FIGS. 3 and 4, it is assumed that the TC value is measured first and the IC value is set later, but conversely, the IC value is measured first and the TC value is measured. May be set to be measured later. Analog output time is T
The C value, the IC value, and the TOC value may be set differently.

Some TOC meters do not measure TC and IC values, but POC (volatile organic carbon) and NP.
Measure OC (non-volatile organic carbon), TOC = POC
There is also one that calculates the TOC value as + NPOC. In that case, the POC value and the NPOC value may be sequentially output for one fixed time, for example, 10 seconds on one analog signal, and then the TOC value may be output on the analog signal. As for the operation, the present invention can be similarly applied by replacing TC in FIG. 3 and FIG. 4 with POC and replacing IC with NPOC.

[0011]

According to the present invention, the TC value, the IC value and the TOC value are sequentially output as one analog signal.
Since the OC value is output at an output time different from the TC value and the IC value, it is possible to record three values with one pen recorder and easily distinguish the TOC value from other values. Will be able to. Even if two measured values other than the TOC value are output for the same time, the TC value is always larger than the IC value in the case of TC value and IC value (TO
When C value is 0, TC value and IC value are the same),
These two values can be distinguished even at the same time output.

[Brief description of drawings]

FIG. 1 is a block diagram showing the present invention.

FIG. 2 is a schematic configuration diagram showing a TOC meter to which the present invention is applied.

FIG. 3 is a flowchart showing the operation of one embodiment.

FIG. 4 is a waveform diagram showing three values output by the operation of FIG.

[Explanation of symbols]

2 CO ₂ detection unit 4 TC memory 6 IC memory 8 TOC calculation unit 10 analog output unit 24 signal processing unit

 ─────────────────────────────────────────────────── ─── Continuation of the front page (72) Inventor Hiroaki Matsuhisa 1 Nishinokyo Kuwabara-cho, Nakagyo-ku, Kyoto City, Kyoto Prefecture Shimazu Corporation Sanjo Factory

Claims (1)

[Claims] 1. A total organic carbon measuring device comprising a carrier gas supply part, a sample injecting part, a combustion oxidation reaction part and a CO ₂ detecting part for separately measuring total carbon and inorganic carbon in a sample. TC memory for storing the measured value, IC memory for storing the inorganic carbon measured value, TOC calculation unit for calculating the total organic carbon concentration by taking the difference between the both measured values, total carbon measured value, inorganic carbon measured value And an analog output section in which the calculated total organic carbon values are sequentially output as one analog signal, and the output time of the calculated total organic carbon values is different from the output time of the measured total carbon values and the measured inorganic carbon values. An all-organic carbon measuring device characterized by being provided.