JPH05120668A - Magnetic recording medium - Google Patents
Magnetic recording mediumInfo
- Publication number
- JPH05120668A JPH05120668A JP3305599A JP30559991A JPH05120668A JP H05120668 A JPH05120668 A JP H05120668A JP 3305599 A JP3305599 A JP 3305599A JP 30559991 A JP30559991 A JP 30559991A JP H05120668 A JPH05120668 A JP H05120668A
- Authority
- JP
- Japan
- Prior art keywords
- magnetic
- weight
- powder
- parts
- resin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 230000005291 magnetic effect Effects 0.000 title claims abstract description 87
- 239000000843 powder Substances 0.000 claims abstract description 69
- 238000000576 coating method Methods 0.000 claims abstract description 34
- 239000011248 coating agent Substances 0.000 claims abstract description 33
- 230000005294 ferromagnetic effect Effects 0.000 claims abstract description 29
- 239000006247 magnetic powder Substances 0.000 claims abstract description 26
- 239000011230 binding agent Substances 0.000 claims abstract description 23
- 229920005989 resin Polymers 0.000 claims description 32
- 239000011347 resin Substances 0.000 claims description 32
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 13
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 10
- 229910052751 metal Inorganic materials 0.000 claims description 10
- 239000002184 metal Substances 0.000 claims description 10
- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 claims description 10
- AJCDFVKYMIUXCR-UHFFFAOYSA-N oxobarium;oxo(oxoferriooxy)iron Chemical compound [Ba]=O.O=[Fe]O[Fe]=O.O=[Fe]O[Fe]=O.O=[Fe]O[Fe]=O.O=[Fe]O[Fe]=O.O=[Fe]O[Fe]=O.O=[Fe]O[Fe]=O AJCDFVKYMIUXCR-UHFFFAOYSA-N 0.000 claims description 5
- PSBDWGZCVUAZQS-UHFFFAOYSA-N (dimethylsulfonio)acetate Chemical group C[S+](C)CC([O-])=O PSBDWGZCVUAZQS-UHFFFAOYSA-N 0.000 claims description 4
- 239000006249 magnetic particle Substances 0.000 claims description 2
- 239000000463 material Substances 0.000 abstract description 23
- 239000006185 dispersion Substances 0.000 abstract description 15
- -1 polyethylene terephthalate Polymers 0.000 description 25
- 239000003973 paint Substances 0.000 description 18
- 229920001577 copolymer Polymers 0.000 description 16
- 238000000034 method Methods 0.000 description 15
- 229920002635 polyurethane Polymers 0.000 description 12
- 239000012948 isocyanate Substances 0.000 description 11
- 229910000859 α-Fe Inorganic materials 0.000 description 11
- 125000004432 carbon atom Chemical group C* 0.000 description 10
- 230000000052 comparative effect Effects 0.000 description 10
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 10
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 9
- 239000000203 mixture Substances 0.000 description 9
- 150000002513 isocyanates Chemical class 0.000 description 8
- 239000002245 particle Substances 0.000 description 8
- 239000004814 polyurethane Substances 0.000 description 8
- 239000006229 carbon black Substances 0.000 description 6
- 235000014113 dietary fatty acids Nutrition 0.000 description 6
- 229930195729 fatty acid Natural products 0.000 description 6
- 239000000194 fatty acid Substances 0.000 description 6
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 5
- 125000000217 alkyl group Chemical group 0.000 description 5
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 5
- 238000001035 drying Methods 0.000 description 5
- 239000000696 magnetic material Substances 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 229920001296 polysiloxane Polymers 0.000 description 5
- 239000004576 sand Substances 0.000 description 5
- RTTZISZSHSCFRH-UHFFFAOYSA-N 1,3-bis(isocyanatomethyl)benzene Chemical compound O=C=NCC1=CC=CC(CN=C=O)=C1 RTTZISZSHSCFRH-UHFFFAOYSA-N 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Natural products C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
- 238000004220 aggregation Methods 0.000 description 4
- 239000002270 dispersing agent Substances 0.000 description 4
- 150000004665 fatty acids Chemical class 0.000 description 4
- 230000005415 magnetization Effects 0.000 description 4
- BARWIPMJPCRCTP-UHFFFAOYSA-N oleic acid oleyl ester Natural products CCCCCCCCC=CCCCCCCCCOC(=O)CCCCCCCC=CCCCCCCCC BARWIPMJPCRCTP-UHFFFAOYSA-N 0.000 description 4
- BARWIPMJPCRCTP-CLFAGFIQSA-N oleyl oleate Chemical compound CCCCCCCC\C=C/CCCCCCCCOC(=O)CCCCCCC\C=C/CCCCCCCC BARWIPMJPCRCTP-CLFAGFIQSA-N 0.000 description 4
- 229920001225 polyester resin Polymers 0.000 description 4
- 239000004645 polyester resin Substances 0.000 description 4
- 229920000139 polyethylene terephthalate Polymers 0.000 description 4
- 239000005020 polyethylene terephthalate Substances 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 229910052593 corundum Inorganic materials 0.000 description 3
- 239000010431 corundum Substances 0.000 description 3
- 239000011888 foil Substances 0.000 description 3
- 229910052742 iron Inorganic materials 0.000 description 3
- 238000004898 kneading Methods 0.000 description 3
- 239000000314 lubricant Substances 0.000 description 3
- 125000005397 methacrylic acid ester group Chemical group 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- 229920006122 polyamide resin Polymers 0.000 description 3
- 229920005749 polyurethane resin Polymers 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- 229920005992 thermoplastic resin Polymers 0.000 description 3
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- 229910000531 Co alloy Inorganic materials 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 229920000877 Melamine resin Polymers 0.000 description 2
- 239000004640 Melamine resin Substances 0.000 description 2
- QORUGOXNWQUALA-UHFFFAOYSA-N N=C=O.N=C=O.N=C=O.C1=CC=C(C(C2=CC=CC=C2)C2=CC=CC=C2)C=C1 Chemical compound N=C=O.N=C=O.N=C=O.C1=CC=C(C(C2=CC=CC=C2)C2=CC=CC=C2)C=C1 QORUGOXNWQUALA-UHFFFAOYSA-N 0.000 description 2
- 229920000459 Nitrile rubber Polymers 0.000 description 2
- 239000000020 Nitrocellulose Substances 0.000 description 2
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- 229910004298 SiO 2 Inorganic materials 0.000 description 2
- 229920002334 Spandex Polymers 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- 229920001807 Urea-formaldehyde Polymers 0.000 description 2
- 239000003082 abrasive agent Substances 0.000 description 2
- 125000005396 acrylic acid ester group Chemical group 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 125000003545 alkoxy group Chemical group 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- 239000002216 antistatic agent Substances 0.000 description 2
- 229910052788 barium Inorganic materials 0.000 description 2
- NTXGQCSETZTARF-UHFFFAOYSA-N buta-1,3-diene;prop-2-enenitrile Chemical compound C=CC=C.C=CC#N NTXGQCSETZTARF-UHFFFAOYSA-N 0.000 description 2
- 238000003490 calendering Methods 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 2
- 239000008199 coating composition Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000009833 condensation Methods 0.000 description 2
- 230000005494 condensation Effects 0.000 description 2
- 239000007822 coupling agent Substances 0.000 description 2
- GHVNFZFCNZKVNT-UHFFFAOYSA-N decanoic acid Chemical compound CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 description 2
- 229910003460 diamond Inorganic materials 0.000 description 2
- 239000010432 diamond Substances 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- ZQPPMHVWECSIRJ-MDZDMXLPSA-N elaidic acid Chemical compound CCCCCCCC\C=C\CCCCCCCC(O)=O ZQPPMHVWECSIRJ-MDZDMXLPSA-N 0.000 description 2
- LZCLXQDLBQLTDK-UHFFFAOYSA-N ethyl 2-hydroxypropanoate Chemical compound CCOC(=O)C(C)O LZCLXQDLBQLTDK-UHFFFAOYSA-N 0.000 description 2
- 238000000855 fermentation Methods 0.000 description 2
- 230000004151 fermentation Effects 0.000 description 2
- 238000011049 filling Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 2
- HJOVHMDZYOCNQW-UHFFFAOYSA-N isophorone Chemical compound CC1=CC(=O)CC(C)(C)C1 HJOVHMDZYOCNQW-UHFFFAOYSA-N 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 229920001220 nitrocellulos Polymers 0.000 description 2
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 235000021317 phosphate Nutrition 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 239000005056 polyisocyanate Substances 0.000 description 2
- 229920001228 polyisocyanate Polymers 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 2
- 229920002050 silicone resin Polymers 0.000 description 2
- 239000004759 spandex Substances 0.000 description 2
- RGTIBVZDHOMOKC-UHFFFAOYSA-N stearolic acid Chemical compound CCCCCCCCC#CCCCCCCCC(O)=O RGTIBVZDHOMOKC-UHFFFAOYSA-N 0.000 description 2
- 229920003048 styrene butadiene rubber Polymers 0.000 description 2
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
- 229920001187 thermosetting polymer Polymers 0.000 description 2
- 230000000007 visual effect Effects 0.000 description 2
- OYHQOLUKZRVURQ-NTGFUMLPSA-N (9Z,12Z)-9,10,12,13-tetratritiooctadeca-9,12-dienoic acid Chemical compound C(CCCCCCC\C(=C(/C\C(=C(/CCCCC)\[3H])\[3H])\[3H])\[3H])(=O)O OYHQOLUKZRVURQ-NTGFUMLPSA-N 0.000 description 1
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 description 1
- FKTHNVSLHLHISI-UHFFFAOYSA-N 1,2-bis(isocyanatomethyl)benzene Chemical compound O=C=NCC1=CC=CC=C1CN=C=O FKTHNVSLHLHISI-UHFFFAOYSA-N 0.000 description 1
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
- OCJBOOLMMGQPQU-UHFFFAOYSA-N 1,4-dichlorobenzene Chemical compound ClC1=CC=C(Cl)C=C1 OCJBOOLMMGQPQU-UHFFFAOYSA-N 0.000 description 1
- CVMYEWFFFUKQEF-UHFFFAOYSA-N 1-chloro-2-(2-chloroethenoxy)ethene Chemical compound ClC=COC=CCl CVMYEWFFFUKQEF-UHFFFAOYSA-N 0.000 description 1
- IIZPXYDJLKNOIY-JXPKJXOSSA-N 1-palmitoyl-2-arachidonoyl-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCC\C=C/C\C=C/C\C=C/C\C=C/CCCCC IIZPXYDJLKNOIY-JXPKJXOSSA-N 0.000 description 1
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
- SZIFAVKTNFCBPC-UHFFFAOYSA-N 2-chloroethanol Chemical compound OCCCl SZIFAVKTNFCBPC-UHFFFAOYSA-N 0.000 description 1
- QTWJRLJHJPIABL-UHFFFAOYSA-N 2-methylphenol;3-methylphenol;4-methylphenol Chemical compound CC1=CC=C(O)C=C1.CC1=CC=CC(O)=C1.CC1=CC=CC=C1O QTWJRLJHJPIABL-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229910000838 Al alloy Inorganic materials 0.000 description 1
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 1
- FERIUCNNQQJTOY-UHFFFAOYSA-M Butyrate Chemical compound CCCC([O-])=O FERIUCNNQQJTOY-UHFFFAOYSA-M 0.000 description 1
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Natural products CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 description 1
- 239000005632 Capric acid (CAS 334-48-5) Substances 0.000 description 1
- 239000005635 Caprylic acid (CAS 124-07-2) Substances 0.000 description 1
- 229920001747 Cellulose diacetate Polymers 0.000 description 1
- DQEFEBPAPFSJLV-UHFFFAOYSA-N Cellulose propionate Chemical compound CCC(=O)OCC1OC(OC(=O)CC)C(OC(=O)CC)C(OC(=O)CC)C1OC1C(OC(=O)CC)C(OC(=O)CC)C(OC(=O)CC)C(COC(=O)CC)O1 DQEFEBPAPFSJLV-UHFFFAOYSA-N 0.000 description 1
- 229920002284 Cellulose triacetate Polymers 0.000 description 1
- XTHFKEDIFFGKHM-UHFFFAOYSA-N Dimethoxyethane Chemical compound COCCOC XTHFKEDIFFGKHM-UHFFFAOYSA-N 0.000 description 1
- 102000009123 Fibrin Human genes 0.000 description 1
- 108010073385 Fibrin Proteins 0.000 description 1
- BWGVNKXGVNDBDI-UHFFFAOYSA-N Fibrin monomer Chemical compound CNC(=O)CNC(=O)CN BWGVNKXGVNDBDI-UHFFFAOYSA-N 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- CTKINSOISVBQLD-UHFFFAOYSA-N Glycidol Chemical compound OCC1CO1 CTKINSOISVBQLD-UHFFFAOYSA-N 0.000 description 1
- 239000005057 Hexamethylene diisocyanate Substances 0.000 description 1
- 229910001030 Iron–nickel alloy Inorganic materials 0.000 description 1
- 239000005058 Isophorone diisocyanate Substances 0.000 description 1
- 239000005639 Lauric acid Substances 0.000 description 1
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 1
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 1
- KWIUHFFTVRNATP-UHFFFAOYSA-O N,N,N-trimethylglycinium Chemical compound C[N+](C)(C)CC(O)=O KWIUHFFTVRNATP-UHFFFAOYSA-O 0.000 description 1
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 1
- JMHQPTAFBUVYBA-UHFFFAOYSA-N N=C=O.N=C=O.CC1=CC=CC=C1N Chemical compound N=C=O.N=C=O.CC1=CC=CC=C1N JMHQPTAFBUVYBA-UHFFFAOYSA-N 0.000 description 1
- 229910000990 Ni alloy Inorganic materials 0.000 description 1
- 229910018605 Ni—Zn Inorganic materials 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- 235000021314 Palmitic acid Nutrition 0.000 description 1
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical group OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004962 Polyamide-imide Substances 0.000 description 1
- 239000004695 Polyether sulfone Substances 0.000 description 1
- 239000004642 Polyimide Substances 0.000 description 1
- 229920002396 Polyurea Polymers 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 1
- 229910000676 Si alloy Inorganic materials 0.000 description 1
- 239000006087 Silane Coupling Agent Substances 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- 239000002174 Styrene-butadiene Substances 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 229920006311 Urethane elastomer Polymers 0.000 description 1
- 229920002433 Vinyl chloride-vinyl acetate copolymer Polymers 0.000 description 1
- NNLVGZFZQQXQNW-ADJNRHBOSA-N [(2r,3r,4s,5r,6s)-4,5-diacetyloxy-3-[(2s,3r,4s,5r,6r)-3,4,5-triacetyloxy-6-(acetyloxymethyl)oxan-2-yl]oxy-6-[(2r,3r,4s,5r,6s)-4,5,6-triacetyloxy-2-(acetyloxymethyl)oxan-3-yl]oxyoxan-2-yl]methyl acetate Chemical compound O([C@@H]1O[C@@H]([C@H]([C@H](OC(C)=O)[C@H]1OC(C)=O)O[C@H]1[C@@H]([C@@H](OC(C)=O)[C@H](OC(C)=O)[C@@H](COC(C)=O)O1)OC(C)=O)COC(=O)C)[C@@H]1[C@@H](COC(C)=O)O[C@@H](OC(C)=O)[C@H](OC(C)=O)[C@H]1OC(C)=O NNLVGZFZQQXQNW-ADJNRHBOSA-N 0.000 description 1
- FJWGYAHXMCUOOM-QHOUIDNNSA-N [(2s,3r,4s,5r,6r)-2-[(2r,3r,4s,5r,6s)-4,5-dinitrooxy-2-(nitrooxymethyl)-6-[(2r,3r,4s,5r,6s)-4,5,6-trinitrooxy-2-(nitrooxymethyl)oxan-3-yl]oxyoxan-3-yl]oxy-3,5-dinitrooxy-6-(nitrooxymethyl)oxan-4-yl] nitrate Chemical compound O([C@@H]1O[C@@H]([C@H]([C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O)O[C@H]1[C@@H]([C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@@H](CO[N+]([O-])=O)O1)O[N+]([O-])=O)CO[N+](=O)[O-])[C@@H]1[C@@H](CO[N+]([O-])=O)O[C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O FJWGYAHXMCUOOM-QHOUIDNNSA-N 0.000 description 1
- QXZUUHYBWMWJHK-UHFFFAOYSA-N [Co].[Ni] Chemical compound [Co].[Ni] QXZUUHYBWMWJHK-UHFFFAOYSA-N 0.000 description 1
- QVYYOKWPCQYKEY-UHFFFAOYSA-N [Fe].[Co] Chemical compound [Fe].[Co] QVYYOKWPCQYKEY-UHFFFAOYSA-N 0.000 description 1
- KGWWEXORQXHJJQ-UHFFFAOYSA-N [Fe].[Co].[Ni] Chemical compound [Fe].[Co].[Ni] KGWWEXORQXHJJQ-UHFFFAOYSA-N 0.000 description 1
- KXKVLQRXCPHEJC-UHFFFAOYSA-N acetic acid trimethyl ester Natural products COC(C)=O KXKVLQRXCPHEJC-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- GZCGUPFRVQAUEE-SLPGGIOYSA-N aldehydo-D-glucose Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C=O GZCGUPFRVQAUEE-SLPGGIOYSA-N 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 125000003342 alkenyl group Chemical group 0.000 description 1
- 229920000180 alkyd Polymers 0.000 description 1
- 150000003973 alkyl amines Chemical class 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- DTOSIQBPPRVQHS-PDBXOOCHSA-N alpha-linolenic acid Chemical compound CC\C=C/C\C=C/C\C=C/CCCCCCCC(O)=O DTOSIQBPPRVQHS-PDBXOOCHSA-N 0.000 description 1
- 235000020661 alpha-linolenic acid Nutrition 0.000 description 1
- KCZFLPPCFOHPNI-UHFFFAOYSA-N alumane;iron Chemical compound [AlH3].[Fe] KCZFLPPCFOHPNI-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 150000001414 amino alcohols Chemical class 0.000 description 1
- 229920003180 amino resin Polymers 0.000 description 1
- 229910000808 amorphous metal alloy Inorganic materials 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- 229960003237 betaine Drugs 0.000 description 1
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 150000007942 carboxylates Chemical group 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002301 cellulose acetate Polymers 0.000 description 1
- 229920006218 cellulose propionate Polymers 0.000 description 1
- 238000006757 chemical reactions by type Methods 0.000 description 1
- 150000008280 chlorinated hydrocarbons Chemical class 0.000 description 1
- 238000004581 coalescence Methods 0.000 description 1
- 239000011162 core material Substances 0.000 description 1
- 229930003836 cresol Natural products 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 229940117389 dichlorobenzene Drugs 0.000 description 1
- QDOXWKRWXJOMAK-UHFFFAOYSA-N dichromium trioxide Chemical compound O=[Cr]O[Cr]=O QDOXWKRWXJOMAK-UHFFFAOYSA-N 0.000 description 1
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 1
- 125000005442 diisocyanate group Chemical group 0.000 description 1
- 150000002009 diols Chemical class 0.000 description 1
- 229910001651 emery Inorganic materials 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 239000003759 ester based solvent Substances 0.000 description 1
- 239000004210 ether based solvent Substances 0.000 description 1
- 229940116333 ethyl lactate Drugs 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000003302 ferromagnetic material Substances 0.000 description 1
- 229950003499 fibrin Drugs 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 125000003709 fluoroalkyl group Chemical group 0.000 description 1
- 239000002223 garnet Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 229920000578 graft copolymer Polymers 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 238000009499 grossing Methods 0.000 description 1
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 1
- XWHPIFXRKKHEKR-UHFFFAOYSA-N iron silicon Chemical compound [Si].[Fe] XWHPIFXRKKHEKR-UHFFFAOYSA-N 0.000 description 1
- SZVJSHCCFOBDDC-UHFFFAOYSA-N iron(II,III) oxide Inorganic materials O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 description 1
- GJRQTCIYDGXPES-UHFFFAOYSA-N iso-butyl acetate Natural products CC(C)COC(C)=O GJRQTCIYDGXPES-UHFFFAOYSA-N 0.000 description 1
- FGKJLKRYENPLQH-UHFFFAOYSA-M isocaproate Chemical compound CC(C)CCC([O-])=O FGKJLKRYENPLQH-UHFFFAOYSA-M 0.000 description 1
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 description 1
- JMMWKPVZQRWMSS-UHFFFAOYSA-N isopropanol acetate Natural products CC(C)OC(C)=O JMMWKPVZQRWMSS-UHFFFAOYSA-N 0.000 description 1
- 229940011051 isopropyl acetate Drugs 0.000 description 1
- GWYFCOCPABKNJV-UHFFFAOYSA-N isovaleric acid Chemical compound CC(C)CC(O)=O GWYFCOCPABKNJV-UHFFFAOYSA-N 0.000 description 1
- OQAGVSWESNCJJT-UHFFFAOYSA-N isovaleric acid methyl ester Natural products COC(=O)CC(C)C OQAGVSWESNCJJT-UHFFFAOYSA-N 0.000 description 1
- 239000005453 ketone based solvent Substances 0.000 description 1
- 239000000787 lecithin Substances 0.000 description 1
- 235000010445 lecithin Nutrition 0.000 description 1
- 229940067606 lecithin Drugs 0.000 description 1
- 229960004488 linolenic acid Drugs 0.000 description 1
- KQQKGWQCNNTQJW-UHFFFAOYSA-N linolenic acid Natural products CC=CCCC=CCC=CCCCCCCCC(O)=O KQQKGWQCNNTQJW-UHFFFAOYSA-N 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- CWQXQMHSOZUFJS-UHFFFAOYSA-N molybdenum disulfide Chemical compound S=[Mo]=S CWQXQMHSOZUFJS-UHFFFAOYSA-N 0.000 description 1
- 229910052982 molybdenum disulfide Inorganic materials 0.000 description 1
- 125000000896 monocarboxylic acid group Chemical group 0.000 description 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 229960002446 octanoic acid Drugs 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 235000021313 oleic acid Nutrition 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 125000005496 phosphonium group Chemical group 0.000 description 1
- 125000002270 phosphoric acid ester group Chemical group 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 229920000233 poly(alkylene oxides) Polymers 0.000 description 1
- 229920002492 poly(sulfone) Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920002312 polyamide-imide Polymers 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920005906 polyester polyol Polymers 0.000 description 1
- 229920006393 polyether sulfone Polymers 0.000 description 1
- 229920001721 polyimide Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920002959 polymer blend Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- 229920003226 polyurethane urea Polymers 0.000 description 1
- 229920002620 polyvinyl fluoride Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 239000001397 quillaja saponaria molina bark Substances 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 239000012744 reinforcing agent Substances 0.000 description 1
- 229930182490 saponin Natural products 0.000 description 1
- 150000007949 saponins Chemical class 0.000 description 1
- 229910000702 sendust Inorganic materials 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 1
- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 239000011115 styrene butadiene Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- IIACRCGMVDHOTQ-UHFFFAOYSA-N sulfamic acid Chemical class NS(O)(=O)=O IIACRCGMVDHOTQ-UHFFFAOYSA-N 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 125000000542 sulfonic acid group Chemical group 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-O sulfonium group Chemical group [SH3+] RWSOTUBLDIXVET-UHFFFAOYSA-O 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 239000005061 synthetic rubber Substances 0.000 description 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 1
- ITRNXVSDJBHYNJ-UHFFFAOYSA-N tungsten disulfide Chemical compound S=[W]=S ITRNXVSDJBHYNJ-UHFFFAOYSA-N 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Landscapes
- Magnetic Record Carriers (AREA)
- Paints Or Removers (AREA)
Abstract
Description
【0001】[0001]
【産業上の利用分野】本発明は塗布型磁気記録媒体に関
し、さらに詳しくは、非磁性支持体上に少なくとも強磁
性粉末を含有する磁性塗膜を設けてなる磁気記録媒体に
関し、特に六方晶バリウムフェライト、Co―被着γ酸
化鉄、金属粉末等の強磁性粉を用いた記録密度の高い高
密度記録媒体に好適なものである。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a coating type magnetic recording medium, and more particularly to a magnetic recording medium comprising a non-magnetic support and a magnetic coating film containing at least a ferromagnetic powder, and more particularly hexagonal barium. It is suitable for a high-density recording medium having a high recording density using a ferromagnetic powder such as ferrite, Co-coated γ-iron oxide, and metal powder.
【0002】[0002]
【従来の技術】近年、磁気記録媒体の高密度化が検討さ
れ、強磁性粉として、微小粒径のCo―被着γ酸化鉄、
微小粒径でかつ高保持力の金属磁性粉、六角板状でかつ
微小粒径の六方晶フェライト粉等が注目されている。2. Description of the Related Art In recent years, high density magnetic recording media have been studied, and as a ferromagnetic powder, Co-deposited γ-iron oxide having a small particle size,
Attention has been focused on metal magnetic powder having a small particle size and high coercive force, and hexagonal ferrite powder having a hexagonal plate shape and a minute particle size.
【0003】しかし、これら強磁性粉の塗料化において
は、分散の良否が常に問題となり、未だ十分な解決にい
たっていない。However, when these ferromagnetic powders are used as paints, the quality of the dispersion has always been a problem, and a sufficient solution has not yet been reached.
【0004】例えば六方晶フェライト粉は板面に鉛直な
方向に磁化容易軸を有するため、塗料において粉同士が
その板状の面と面で密着し、極めて強い凝集体を形成す
る。また金属磁性粉は酸化物系磁性粉に比べて大きな、
磁性モーメントを有するため、塗料中においても粉同士
が強力に引き合って極めて強い凝集体を形成する。For example, since hexagonal ferrite powder has an axis of easy magnetization in the direction perpendicular to the plate surface, the powder particles are closely adhered to each other in the paint and form extremely strong agglomerates. In addition, metal magnetic powder is larger than oxide-based magnetic powder,
Since they have a magnetic moment, the powders strongly attract each other even in the paint to form extremely strong aggregates.
【0005】また磁性粉のバインダーとして、塩化ビニ
ル―酢酸ビニル系共重合体、繊維素系樹脂、ポリウレタ
ン系樹脂、ポリエステル系樹脂、ポリエステル―ポリウ
レタン系樹脂、ポリカーボネート―ポリウレタン系樹
脂、ポリビニルブチラール系樹脂など種々のものが分散
性改良のために検討されてきた。しかしながら、十分良
好な結果が得られているとは言えない。As a binder for the magnetic powder, vinyl chloride-vinyl acetate copolymer, fibrin resin, polyurethane resin, polyester resin, polyester-polyurethane resin, polycarbonate-polyurethane resin, polyvinyl butyral resin, etc. Various have been investigated to improve dispersibility. However, it cannot be said that sufficiently good results have been obtained.
【0006】そこで近年特に、磁性粉の分散性、及び充
填性の観点から極性基、例えばスルホン酸塩基、硫酸エ
ステル塩基、リン酸エステル塩基、ホスホン酸塩基、カ
ルボン酸塩基等を、上記結合剤の骨格、または側鎖に付
加した樹脂が広く使用されるようになっている。Accordingly, in recent years, in particular, from the viewpoints of dispersibility and packing of magnetic powder, polar groups such as sulfonate group, sulfate ester group, phosphate ester group, phosphonate group, and carboxylate group are used as binders. Resins added to the skeleton or side chains have been widely used.
【0007】しかし前記の金属磁性粉や六方晶フェライ
ト粉の凝集力は極めて強く、該バインダーを使用しても
凝集体を微分散化することが難しく、不十分な分散性の
塗料しか得られず、満足すべき磁気記録媒体を得ること
は難しい。However, the above-mentioned metal magnetic powder and hexagonal ferrite powder have a very strong cohesive force, and it is difficult to finely disperse the agglomerates even if the binder is used, and only a paint having insufficient dispersibility can be obtained. However, it is difficult to obtain a satisfactory magnetic recording medium.
【0008】[0008]
【発明が解決しようとする課題】本発明の目的は、磁性
塗料における強磁性粉の分散性、分散安定性を改善し
て、磁性塗膜のより一層の表面平滑性と高密度化をはか
り、優れた磁気記録特性、特に高密度磁気記録特性を付
与した磁気記録媒体を提供することにある。SUMMARY OF THE INVENTION The object of the present invention is to improve the dispersibility and dispersion stability of ferromagnetic powder in a magnetic coating material so as to achieve further surface smoothness and high density of a magnetic coating film. It is an object of the present invention to provide a magnetic recording medium having excellent magnetic recording characteristics, particularly high density magnetic recording characteristics.
【0009】[0009]
【課題を解決するための手段】本発明者らは上記目的を
達成すべく、鋭意研究を重ねた結果、磁性塗料中に強磁
性粉とともに平均粒径0.1μm以下の軟磁性磁性粉を
共存せしめることにより、磁性粉の分散処理において強
磁性粉の凝集がほぐれた隙間に前記軟磁性磁性粉が入り
こみ一層磁性粉の分散を促進するとともに、更にほぐれ
た磁性粉が塗料中で再凝集することが防止され(例えば
塗料を長時間放置した後塗膜化した場合でも、再凝集に
よる“ぶつ”がほとんど発生せず)、このため磁性層
(磁性塗膜)の表面平滑性を著しく向上できることを見
い出し本発明に到達した。Means for Solving the Problems The inventors of the present invention have conducted intensive studies to achieve the above object, and as a result, co-existed with a ferromagnetic powder a soft magnetic magnetic powder having an average particle diameter of 0.1 μm or less in a magnetic coating material. When the magnetic powder is dispersed, the soft magnetic powder enters the gap where the aggregation of the ferromagnetic powder is loosened to promote the dispersion of the magnetic powder, and the loosened magnetic powder is re-aggregated in the paint. Is prevented (for example, even if the coating is left for a long time and then formed into a coating film, "bumping" due to re-aggregation hardly occurs), and therefore the surface smoothness of the magnetic layer (magnetic coating film) can be significantly improved. The present invention has been found.
【0010】すなわち、本発明は非磁性支持体上に強磁
性粉を含有する磁性塗料の塗膜を設けてなる磁気記録媒
体であって、該磁性塗料中に平均粒径0.1μm以下の
軟磁性磁性粉を前記強磁性粉100重量部に対して0.
01〜20重量部含有することを特徴とする磁気記録媒
体である。That is, the present invention is a magnetic recording medium comprising a non-magnetic support and a coating film of a magnetic coating material containing a ferromagnetic powder, the magnetic coating material having an average particle diameter of 0.1 μm or less. The magnetic magnetic powder was added in an amount of 0.
The magnetic recording medium is characterized by containing 01 to 20 parts by weight.
【0011】本発明において使用する軟磁性磁性粉(以
下「A粉」と呼ぶ)は、平均粒径0.1μm以下の微小
粉であり、近角聡信著(裳華房発行)「強磁性体の物理
(下)磁気特性と応用」368〜376頁に記述されて
いる軟磁性材料、すなわち磁化率が高く抗磁力の小さ
な、金属または酸化物の微小粉が好ましく使用される。
これら軟磁性材料の内でも強電機器の磁心材料に使用さ
れるものより、磁気ヘッド材料用に使用される材料の方
がより好ましく使用できる。The soft magnetic magnetic powder (hereinafter referred to as “A powder”) used in the present invention is a fine powder having an average particle size of 0.1 μm or less, and is written by Satoshi Konnozumi (published by Sokabo) in “ferromagnetic material”. Physical (lower) magnetic properties and applications "368 to 376, that is, a soft magnetic material, that is, a fine powder of metal or oxide having a high magnetic susceptibility and a low coercive force is preferably used.
Among these soft magnetic materials, the material used for the magnetic head material can be more preferably used than the material used for the magnetic core material of the high-voltage equipment.
【0012】かかる軟磁性材料としては以下のものが挙
げられる。合金系材料としては鉄ケイ素合金、鉄―アル
ミニウム合金、鉄―ニッケル合金、鉄―コバルト合金、
鉄―コバルト―ニッケル合金、ニッケル―コバルト合金
等が、非晶質合金材料としてはセンダスト等が、酸化物
系材料としてはMn―Zn系フェライト、Ni―Zn系
フェライト、Mg―Zn系フェライト、Mg―Mn系フ
ェライト等が挙げられる。Examples of such soft magnetic materials include the following. Alloy-based materials include iron silicon alloy, iron-aluminum alloy, iron-nickel alloy, iron-cobalt alloy,
Iron-cobalt-nickel alloys, nickel-cobalt alloys, etc., sendust, etc. as amorphous alloy materials, and Mn-Zn ferrites, Ni-Zn ferrites, Mg-Zn ferrites, Mg as oxide materials. —Mn-based ferrite and the like can be mentioned.
【0013】これらの軟磁性体よりA粉を製造する方法
は、粉砕法その他公知の方法、特に磁性粒体を作るため
に提案されている種々の方法により製造することができ
る。The powder A can be produced from these soft magnetic materials by a pulverization method or other known methods, in particular, various methods proposed for producing magnetic particles.
【0014】かかる方法で作成したA粉は、その使用目
的から強磁性粉の分散処理工程以前の段階で強磁性粉と
共存せしめるのが好ましいが、分散処理工程以降の段階
でも加えることができる。The powder A produced by such a method is preferably made to coexist with the ferromagnetic powder before the dispersion treatment step of the ferromagnetic powder for the purpose of use, but it can be added at the stage after the dispersion treatment step.
【0015】A粉は、前もって分散液の状態で加えるこ
ともできるし、また粉の状態で加えてもよい。The powder A may be added in the form of a dispersion liquid in advance, or may be added in the form of powder.
【0016】A粉の使用量は強磁性粉100重量部当り
0.01〜20重量部添加することができる。特に分散
性向上のためには0.1〜20重量%添加するのが好ま
しく、さらに磁性粉の塗膜中での充填性を考えると0.
2〜15重量部の範囲が好ましく選択される。The powder A may be used in an amount of 0.01 to 20 parts by weight per 100 parts by weight of the ferromagnetic powder. In particular, in order to improve the dispersibility, it is preferable to add 0.1 to 20% by weight. Considering the filling property of the magnetic powder in the coating film,
A range of 2 to 15 parts by weight is preferably selected.
【0017】本発明において非磁性支持体は特に制限が
なく、通常使用されているものを用いることができる。
非磁性支持体を形成する素材の例としては、ポリエチレ
ンテレフタレート、ポリエチレン―2,6―ナフタレー
ト、ポリエチレン、ポリプロピレン、ポリカーボネー
ト、ポリアミド、ポリアミドイミド、ポリイミド、ポリ
サルホン、ポリエーテルサルホンなどの各種の合成樹脂
のフイルム、およびアルミニウム箔、ステンレス箔など
の金属箔を上げることができる。In the present invention, the non-magnetic support is not particularly limited, and those commonly used can be used.
Examples of materials forming the non-magnetic support include various synthetic resins such as polyethylene terephthalate, polyethylene-2,6-naphthalate, polyethylene, polypropylene, polycarbonate, polyamide, polyamideimide, polyimide, polysulfone and polyethersulfone. Films and metal foils such as aluminum foil, stainless steel foil can be raised.
【0018】本発明において強磁性粉は制限がなく、通
常使用されているものを用いることができるが、特にC
o―被着γ酸化鉄粉、Feを主体とする金属粉、六方晶
バリウムフェライト粉等が好ましい。更にCo―被着γ
酸化鉄粉としては、飽和磁化が70emu/gより大き
く、比表面積が20〜60m2 /g、針状比(軸比)が
5〜15、抗磁力が400〜1000 Oe(エルステ
ッド)のものが好ましい。またFeを主体とする金属粉
としては、飽和磁化が100emu/gより大きく、比
表面積が30〜70m2 /g、針状比が5〜15、抗磁
力が500〜3000 Oeの範囲にあるものが好まし
い。また六方晶バリウムフェライト粉としては、飽和磁
化が50emu/gより大きく、比表面積が25〜60
m2 /g、板状比が2〜10、抗磁力が200〜200
0 Oeの範囲にあるものが好ましい。In the present invention, there is no limitation on the ferromagnetic powder, and those commonly used can be used, but especially C
O-coated γ-iron oxide powder, Fe-based metal powder, hexagonal barium ferrite powder and the like are preferable. Co-deposition γ
As the iron oxide powder, one having a saturation magnetization of more than 70 emu / g, a specific surface area of 20 to 60 m 2 / g, an acicular ratio (axial ratio) of 5 to 15, and a coercive force of 400 to 1000 Oe (Oersted) is used. preferable. Further, as the metal powder mainly composed of Fe, one having a saturation magnetization of more than 100 emu / g, a specific surface area of 30 to 70 m 2 / g, an acicular ratio of 5 to 15, and a coercive force of 500 to 3000 Oe. Is preferred. The hexagonal barium ferrite powder has a saturation magnetization of more than 50 emu / g and a specific surface area of 25 to 60.
m 2 / g, plate ratio 2 to 10, coercive force 200 to 200
Those in the range of 0 Oe are preferable.
【0019】本発明において磁性塗料は、このような強
磁性粉およびA粉、具体的には軟磁性磁性粉を結合剤と
混合、分散させて調製するが、この分散プロセスとして
は公知の方法あるいは当業界に蓄積された方法を用いる
ことができる。In the present invention, the magnetic paint is prepared by mixing and dispersing such a ferromagnetic powder and A powder, specifically a soft magnetic magnetic powder, with a binder, and this dispersion process is a known method or Methods accumulated in the art can be used.
【0020】なお、本発明においては、結合剤は特に制
限されないが、スルホン酸塩基、スルホベタイン基の少
なくとも1種を含有するものが好ましく適用される。In the present invention, the binder is not particularly limited, but those containing at least one of a sulfonate group and a sulfobetaine group are preferably applied.
【0021】スルホン酸塩基、スルホベタイン基の少な
くとも1種を有する樹脂としては、分子中にスルホン酸
塩基、スルホベタイン基の少なくとも1種を有する樹脂
であれば如何なるものでもよく、そのような樹脂として
は、例えばウレタン樹脂、ポリエステル樹脂、塩化ビニ
ル系共重合体、塩化ビニリデン系共重合体、アクリル系
樹脂、ブタジエン―アクリロニトリル系重合体、スチレ
ン―ブタジエン系共重合体などが挙げられる。The resin having at least one of sulfonate group and sulfobetaine group may be any resin having at least one of sulfonate group and sulfobetaine group in the molecule. Examples include urethane resins, polyester resins, vinyl chloride-based copolymers, vinylidene chloride-based copolymers, acrylic resins, butadiene-acrylonitrile-based polymers, and styrene-butadiene-based copolymers.
【0022】かかる極性基導入結合剤は、市販のものを
利用してもよく、所望により公知文献の手法に従ってあ
るいは一部修正して、製造することができる。これらの
ものの若干例を引用すると、ポリエステル系結合剤の製
造:特開昭54―143117号、同54―15141
7号、同54―157603号、同56―74827
号、同59―132418号、同59―172118
号、同60―55514号、特開平1―95126号の
各公報、ポリウレタン系結合剤の製造:特開昭57―9
2423号、同58―41436号、同61―2023
27号、同62―28927号、同62―66420
号、特開平1―115920号の各公報、ポリウレタ
ン、ポリウレア系結合剤の製造:特開昭62―2892
0号公報、ビニル重合系結合剤の製造:特開昭58―1
08032号、同60―121514号、同61―32
216号、同61―39927号、同62―20841
9号の各公報、ベタイン系(その他)結合剤の製造:特
開昭60―177427号公報等々が挙げられる。As the polar group-introduced binder, a commercially available binder may be used, and it can be produced according to the method of a known document or partially modified if desired. To give some examples of these, the production of polyester binders: JP-A-54-143117 and JP-A-54-15141.
No. 7, No. 54-157603, No. 56-74827
No. 59-132418, No. 59-172118
No. 60-55514, JP-A-1-95126, and the production of polyurethane binders: JP-A-57-9
No. 2423, No. 58-41436, No. 61-2023
No. 27, No. 62-28927, No. 62-66420
No. 1, JP-A 1-115920, Production of polyurethane and polyurea binders: JP-A-62-2892
No. 0, Production of vinyl polymerization binder: JP-A-58-1
08032, 60-121514, 61-32
No. 216, No. 61-39927, No. 62-20841
No. 9, the preparation of betaine (other) binders: JP-A-60-177427 and the like.
【0023】上記極性基の樹脂中含量は、少なくとも1
×10-6当量/g(樹脂)以上であることが好ましく、
更に磁性粉の分散および再凝集防止の点から、より好ま
しくは1×10-6〜1×10-2当量/g(樹脂)、特に
好ましくは1×10-5〜1×10-2当量/g(樹脂)の
範囲である。The content of the polar group in the resin is at least 1.
It is preferably × 10 −6 equivalent / g (resin) or more,
Further, from the viewpoint of dispersion of magnetic powder and prevention of re-aggregation, more preferably 1 × 10 −6 to 1 × 10 −2 equivalent / g (resin), particularly preferably 1 × 10 −5 to 1 × 10 −2 equivalent / It is in the range of g (resin).
【0024】かかる極性基含有樹脂の使用量は、強磁性
粉100重量部当り0.1〜50重量部、更に0.5〜
40重量部、特に1〜30重量部であることが好まし
い。極性基含有樹脂は、単に重量割合だけでなく樹脂中
の極性基量も考え、強磁性粉100g当りの極性基の量
を1×10-6〜1×10-2当量/100g磁性粉、更に
2×10-6〜1×10-2当量/100g磁性粉、特に5
×10-6〜5×10-3当量/100g磁性粉とするのが
好ましい。The amount of the polar group-containing resin used is 0.1 to 50 parts by weight, and further 0.5 to 100 parts by weight of the ferromagnetic powder.
It is preferably 40 parts by weight, particularly preferably 1 to 30 parts by weight. Regarding the polar group-containing resin, considering not only the weight ratio but also the amount of polar groups in the resin, the amount of polar groups per 100 g of ferromagnetic powder is 1 × 10 −6 to 1 × 10 −2 equivalent / 100 g of magnetic powder, 2 × 10 −6 to 1 × 10 −2 equivalent / 100 g magnetic powder, especially 5
It is preferable to use x10 -6 to 5x10 -3 equivalent / 100 g of magnetic powder.
【0025】本発明における磁性塗料には、前述した強
磁性粉、A粉、スルホン酸塩含有樹脂の他に、従来から
知られ、あるいは用いられている成分を含有させること
ができる。例えば、熱可塑性樹脂、熱硬化性樹脂、反応
型樹脂等の如き結合剤、研磨剤、帯電防止剤、強化剤、
分散剤、潤滑剤などを単独あるいは組合せて含有させる
ことができる。In addition to the above-mentioned ferromagnetic powder, A powder, and sulfonate-containing resin, the magnetic coating material of the present invention may contain components that have been known or used in the past. For example, a binder such as a thermoplastic resin, a thermosetting resin, or a reactive resin, an abrasive, an antistatic agent, a reinforcing agent,
Dispersants, lubricants and the like can be contained alone or in combination.
【0026】この熱可塑性樹脂としては軟化温度が15
0℃以下、平均分子量が10,000〜300,00
0、重合度が約50〜2,000程度のもので、例えば
塩化ビニル・酢酸ビニル共重合体、塩化ビニル・塩化ビ
ニリデン共重合体、塩化ビニル・アクリロニトリル共重
合体、アクリル酸エステル・アクリロニトリル共重合
体、アクリル酸エステル・塩化ビニリデン共重合体、ア
クリル酸エステル・スチレン共重合体、メタクリル酸エ
ステル・アクリロニトリル共重合体、メタクリル酸エス
テル・塩化ビニリデン共重合体、メタクリル酸エステル
・スチレン共重合体、ウレタンエラストマー、ナイロン
―シリコン系樹脂、ニトロセルロース―ポリアミド樹
脂、ポリフッ化ビニル、塩化ビニリデン・アクリロニト
リル共重合体、ブタジエン・アクリロニトリル共重合
体、ポリアミド樹脂、ポリビニルブチラール、セルロー
ス誘導体(セルロースアセテートブチレート、セルロー
スダイアセテート、セルローストリアセテート、セルロ
ースプロピオネート、ニトロセルロース等)、スチレン
・ブタジエン共重合体、ポリエステル樹脂、クロロビニ
ルエーテル・アクリル酸エステル共重合体、アミノ樹
脂、各種の合成ゴム系の熱可塑性樹脂およびこれらの混
合物等が使用される。This thermoplastic resin has a softening temperature of 15
0 ° C. or less, average molecular weight 10,000 to 300,000
0, having a degree of polymerization of about 50 to 2,000, for example, vinyl chloride / vinyl acetate copolymer, vinyl chloride / vinylidene chloride copolymer, vinyl chloride / acrylonitrile copolymer, acrylic ester / acrylonitrile copolymer Coalescence, acrylic acid ester / vinylidene chloride copolymer, acrylic acid ester / styrene copolymer, methacrylic acid ester / acrylonitrile copolymer, methacrylic acid ester / vinylidene chloride copolymer, methacrylic acid ester / styrene copolymer, urethane Elastomer, nylon-silicone resin, nitrocellulose-polyamide resin, polyvinyl fluoride, vinylidene chloride-acrylonitrile copolymer, butadiene-acrylonitrile copolymer, polyamide resin, polyvinyl butyral, cellulose derivative (cellulose acetate Tate butyrate, cellulose diacetate, cellulose triacetate, cellulose propionate, nitrocellulose, etc.), styrene / butadiene copolymer, polyester resin, chlorovinyl ether / acrylic acid ester copolymer, amino resin, various synthetic rubber Thermoplastic resins and mixtures thereof are used.
【0027】熱硬化性樹脂または反応型樹脂としては塗
布液の状態では200,000以下の分子量であり、塗
布、乾燥後に加熱することにより、縮合、付加等の反応
により分子量は無限大のものになる。また、これらの樹
脂のなかで、樹脂が熱分解するまでの間に軟化または溶
融しないものが好ましい。具体的には例えばフェノール
樹脂、エポキシ樹脂、ポリウレタン硬化型樹脂、尿素樹
脂、メラミン樹脂、アルキッド樹脂、シリコン樹脂、ア
クリル系反応樹脂、エポキシ―ポリアミド樹脂、ニトロ
セルロースメラミン樹脂、高分子量ポリエステル樹脂と
イソシアネートプレポリマーの混合物、メタクリル酸塩
共重合体とジイソシアネートプレポリマーの混合物、ポ
リエステルポリオールとポリイソシアネートとの混合
物、尿素ホルムアルデヒド樹脂、低分子量グリコール/
高分子量ジオール/トリフェニルメタントリイソシアネ
ートの混合物、ポリアミン樹脂およびこれらの混合物等
を上げることができる。The thermosetting resin or the reaction type resin has a molecular weight of 200,000 or less in the state of a coating solution, and by heating after coating and drying, the molecular weight becomes infinite due to reactions such as condensation and addition. Become. Further, among these resins, those which are not softened or melted before the resin is thermally decomposed are preferable. Specifically, for example, phenol resin, epoxy resin, polyurethane curable resin, urea resin, melamine resin, alkyd resin, silicone resin, acrylic reaction resin, epoxy-polyamide resin, nitrocellulose melamine resin, high molecular weight polyester resin and isocyanate prepolymer. Polymer mixture, methacrylate copolymer and diisocyanate prepolymer mixture, polyester polyol and polyisocyanate mixture, urea formaldehyde resin, low molecular weight glycol /
A mixture of a high molecular weight diol / triphenylmethane triisocyanate, a polyamine resin, a mixture thereof and the like can be used.
【0028】これらの結合剤の単独または組合されたも
のが使われる。磁性層の強磁性微粉末と結合剤との混合
割合は重量比で、強磁性微粉末100重量部に対して、
結合剤5〜300重量部の範囲で使用される。These binders may be used alone or in combination. The mixing ratio of the ferromagnetic fine powder and the binder in the magnetic layer is a weight ratio, and is based on 100 parts by weight of the ferromagnetic fine powder.
The binder is used in the range of 5 to 300 parts by weight.
【0029】研磨剤としては、一般に使用される材料で
溶融アルミナ、炭化ケイ素、酸化クロム(Cr
2 O3 )、コランダム、人造コランダム、ダイアモン
ド、人造ダイアモンド、ザクロ石、エメリー(主成分:
コランダムと磁鉄鉱)等が使用される。これらの研磨剤
はモース硬度が5以上であり、平均粒子径が0.05〜
5μmの大きさのものが効果があり、好ましくは0.4
〜1.5μmである。これらの研磨剤は結合剤100重
量部に対して7〜15重量部の範囲で添加される。この
量が7重量部より少ないと十分な耐久性が得られず、ま
た15重量部より多すぎると充填度が減少し、十分な出
力が得られない。As the polishing agent, generally used materials are fused alumina, silicon carbide and chromium oxide (Cr
2 O 3 ), corundum, artificial corundum, diamond, artificial diamond, garnet, emery (main component:
Corundum and magnetite) are used. These abrasives have a Mohs hardness of 5 or more and an average particle size of 0.05 to
Those having a size of 5 μm are effective, and preferably 0.4
Is about 1.5 μm. These abrasives are added in the range of 7 to 15 parts by weight based on 100 parts by weight of the binder. When the amount is less than 7 parts by weight, sufficient durability cannot be obtained, and when the amount is more than 15 parts by weight, the filling degree is reduced and sufficient output cannot be obtained.
【0030】帯電防止剤としては、カーボンブラック、
カーボンブラックグラフトポリマーなどの導電性微粉
末;サポニンなどの天然界面活性剤;アルキレンオキサ
イド系、グリセリン系、グリシドール系などのノニオン
界面活性剤;高級アルキルアミン類、第4級アンモニウ
ム塩類、ピリジンその他の複素環類、ホスホニウムまた
はスルホニウム類などのカチオン界面活性剤;カルボン
酸、スルホン酸、燐酸、硫酸エステル基、燐酸エステル
基等の酸性基を含むアニオン界面活性剤;アミノ酸類、
アミノスルホン酸類、アミノアルコールの硫酸または燐
酸エステル類等の両性活性剤などが使用される。As the antistatic agent, carbon black,
Conductive fine powder such as carbon black graft polymer; natural surfactant such as saponin; nonionic surfactant such as alkylene oxide type, glycerin type, glycidol type; higher alkylamines, quaternary ammonium salts, pyridine and other complex Cationic surfactants such as rings, phosphoniums or sulfoniums; anionic surfactants containing an acidic group such as carboxylic acid, sulfonic acid, phosphoric acid, sulfuric acid ester group, phosphoric acid ester group; amino acids,
Amphoteric activators such as amino sulfonic acids, sulfuric acid or phosphoric acid esters of amino alcohols, etc. are used.
【0031】上記の導電性微粉末は結合剤100重量部
に対して0.2〜20重量部が、界面活性剤は0.1〜
10重量部の範囲で添加される。The conductive fine powder is 0.2 to 20 parts by weight with respect to 100 parts by weight of the binder, and the surfactant is 0.1 to 20 parts by weight.
It is added in the range of 10 parts by weight.
【0032】これらの界面活性剤は単独または混合して
用いられるものであるが、時としてその他の目的、例え
ば分散、磁気特性の改良、潤滑性の改良、塗布助剤とし
て適用される場合もある。These surfactants are used alone or as a mixture, but sometimes they are used for other purposes such as dispersion, improvement of magnetic properties, improvement of lubricity and coating aid. ..
【0033】分散剤(顔料湿潤剤)としては、カプリル
酸、カプリン酸、ラウリン酸、ミリスチン酸、パルミチ
ン酸、ステアリン酸、オレイン酸、エライジン酸、リノ
ール酸、リノレン酸、ステアロール酸等の炭素数12〜
22の脂肪酸(R1 COOH、R1 は炭素数11〜22
のアルキルまたはアルケニル基);前記の脂肪酸のアル
カリ金属(Li、Na、K等)またはアルカリ土類金属
(Mg、Ca、Ba)からなる金属石鹸;前記の脂肪酸
エステルの弗素を含有した化合物;前記の脂肪酸のアミ
ド;ポリアルキレンオキサイドアルキルリン酸エステ
ル;レシチン;トリアルキルポリオレフィンオキシ第4
級アンモニウム塩(アルキルは炭素数1〜5、オレフィ
ンはエチレン、プロピレンなど);その他カップリング
剤(例えばシランカップリング剤、チタンカップリング
剤等)等が使用される。この他に炭素数12以上の高級
アルコール、およびこれらの他に硫酸エステル等も使用
可能である。これらの分散剤は、結合剤100重量部に
対して、0.5〜20重量部の範囲で添加される。As the dispersant (pigment wetting agent), the carbon number of caprylic acid, capric acid, lauric acid, myristic acid, palmitic acid, stearic acid, oleic acid, elaidic acid, linoleic acid, linolenic acid, stearolic acid, etc. 12-
22 fatty acids (R 1 COOH, R 1 has 11 to 22 carbon atoms
An alkyl or alkenyl group); a metal soap comprising an alkali metal (Li, Na, K, etc.) or alkaline earth metal (Mg, Ca, Ba) of the above fatty acid; a fluorine-containing compound of the above fatty acid ester; Amides of fatty acids; polyalkylene oxide alkyl phosphates; lecithin; trialkyl polyolefinoxy fourth
Quaternary ammonium salt (alkyl has 1 to 5 carbon atoms, olefin has ethylene, propylene, etc.); other coupling agents (for example, silane coupling agent, titanium coupling agent, etc.) and the like are used. In addition to these, higher alcohols having 12 or more carbon atoms, and other than these, sulfuric acid ester and the like can be used. These dispersants are added in the range of 0.5 to 20 parts by weight with respect to 100 parts by weight of the binder.
【0034】潤滑剤としては、ジアルキルポリシロキサ
ン(アルキルは炭素数1〜5)、ジアルコキシポリシロ
キサン(アルコキシは炭素数1〜4)、モノアルキルモ
ノアルコキシポリシロキサン(アルキルは炭素数1〜
5、アルコキシは炭素数1〜4)、フェニルポリシロキ
サン、フロロアルキルポリシロキサン(アルキルは炭素
数1〜5)などのシリコンオイル;グラファイトなどの
導電性微粉末;二硫化モリブデン、二硫化タングステン
などの無機微粉末;ポリエチレン、ポリプロピレン、ポ
リエチレン・塩化ビニル共重合体、ポリテトラフルオロ
エチレンなどのプラスチック微粉末;α―オレフィン重
合物;常温で液状の不飽和脂肪族炭化水素(n―オレフ
ィン二重結合が末端の炭素に結合した化合物、炭素数約
20);炭素数12〜20の一塩基性脂肪酸と炭素数3
〜12の一価のアルコールからなる脂肪酸エステル類、
フルオロカーボン類などが例示される。これらの潤滑剤
は、結合剤100重量部に対して、0.2〜20重量部
の範囲で添加される。As the lubricant, dialkyl polysiloxane (alkyl has 1 to 5 carbon atoms), dialkoxy polysiloxane (alkoxy has 1 to 4 carbon atoms), monoalkyl monoalkoxy polysiloxane (alkyl has 1 to 5 carbon atoms).
5. Alkoxy has 1 to 4 carbon atoms, silicon oil such as phenyl polysiloxane, fluoroalkyl polysiloxane (alkyl has 1 to 5 carbon atoms), conductive fine powder such as graphite, molybdenum disulfide, tungsten disulfide, etc. Inorganic fine powder; polyethylene, polypropylene, polyethylene-vinyl chloride copolymer, polytetrafluoroethylene, and other plastic fine powder; α-olefin polymer; unsaturated aliphatic hydrocarbons that are liquid at room temperature (n-olefin double bond Compound bound to terminal carbon, carbon number about 20); monobasic fatty acid having 12 to 20 carbon atoms and 3 carbon atoms
Fatty acid esters consisting of ~ 12 monohydric alcohols,
Examples are fluorocarbons. These lubricants are added in the range of 0.2 to 20 parts by weight with respect to 100 parts by weight of the binder.
【0035】硬化剤としては低分子量イソシアネート化
合物が好ましく用いられる。この低分子量イソシアネー
ト化合物としては、トリレンジイソシアネート、4,
4′―ジフェニルメタンジイソシアネート、ヘキサメチ
レンジイソシアネート、キシリレンジイソシアネート、
ナフチレン―1,5―ジイソシアネート、o―トルイジ
ンジイソシアネート、イソホロンジイソシアネート、ト
リフェニルメタントリイソシアネート等のイソシアネー
ト類、また当該イソシアネート類とポリアルコールとの
生成物、またイソシアネート類の縮合によって生成した
ポリイソシアネート類を例示することができる。これら
低分子量イソシアネート化合物の市販されている商品名
としては、コロネートL、コロネートHL、コロネート
2030、コロネート2031、ミリオネートMR、ミ
リオネートMTL(日本ポリウレタン(株)製)、タケ
ネートD―102、タケネートD―110N、タケネー
トD―200、タケネートD―202(武田薬品(株)
製)、デスモジュールL、デスモジュール1L、デスモ
ジュールN、デスモジュールHL(住友バイエル(株)
製)等を例示することができる。これらは単独もしくは
硬化反応性の差を利用して二つもしくはそれ以上の組合
せによって使用することができる。A low molecular weight isocyanate compound is preferably used as the curing agent. As the low molecular weight isocyanate compound, tolylene diisocyanate, 4,
4'-diphenylmethane diisocyanate, hexamethylene diisocyanate, xylylene diisocyanate,
Isocyanates such as naphthylene-1,5-diisocyanate, o-toluidine diisocyanate, isophorone diisocyanate, and triphenylmethane triisocyanate, products of the isocyanates and polyalcohols, and polyisocyanates formed by condensation of the isocyanates It can be illustrated. Commercially available trade names of these low molecular weight isocyanate compounds are Coronate L, Coronate HL, Coronate 2030, Coronate 2031, Millionate MR, Millionate MTL (manufactured by Nippon Polyurethane Co., Ltd.), Takenate D-102, Takenate D-110N. , Takenate D-200, Takenate D-202 (Takeda Pharmaceutical Co., Ltd.)
Made), Death Module L, Death Module 1L, Death Module N, Death Module HL (Sumitomo Bayer Ltd.)
Manufactured) and the like. These can be used alone or in combination of two or more by utilizing the difference in curing reactivity.
【0036】本発明における磁性塗料は、従来公知の方
法で製造できる。The magnetic coating material of the present invention can be manufactured by a conventionally known method.
【0037】磁性塗料の調製に使用する溶媒としては有
機溶媒が好ましい。この有機溶媒としては、例えば任意
の比率で、アセトン、メチルエチルケトン、メチルイソ
ブチルケトン、シクロヘキサノン、イソホロン、テトラ
ヒドロフラン等のケトン系溶媒;酢酸メチル、酢酸エチ
ル、酢酸ブチル、酢酸イソブチル、酢酸イソプロピル、
乳酸エチル、酢酸グリコール、モノエチルエーテル等の
エステル系溶媒;エーテル、グリコールジメチルエーテ
ル、ジオキサンなどのグリコールエーテル系溶媒;ベン
ゼン、トルエン、キシレン、クレゾール、クロルベンゼ
ン、スチレンなどのタール系溶媒(芳香族炭化水素);
メチレンクロライド、エチレンクロライド、四塩化炭
素、クロロホルム、エチレンクロルヒドリン、ジクロル
ベンゼン等の塩素化炭化水素、N,N―ジメチルホルム
アルデヒド、ヘキサン等が使用できる。An organic solvent is preferable as the solvent used for preparing the magnetic coating material. Examples of the organic solvent include ketone solvents such as acetone, methyl ethyl ketone, methyl isobutyl ketone, cyclohexanone, isophorone, and tetrahydrofuran in any ratio; methyl acetate, ethyl acetate, butyl acetate, isobutyl acetate, isopropyl acetate,
Ester-based solvents such as ethyl lactate, glycol acetate and monoethyl ether; glycol ether-based solvents such as ether, glycol dimethyl ether and dioxane; tar-based solvents such as benzene, toluene, xylene, cresol, chlorobenzene and styrene (aromatic hydrocarbons) );
Chlorinated hydrocarbons such as methylene chloride, ethylene chloride, carbon tetrachloride, chloroform, ethylene chlorohydrin and dichlorobenzene, N, N-dimethylformaldehyde and hexane can be used.
【0038】強磁性粉および上述の各成分の混練分散に
あたっては、強磁性粉および各成分を全て同時に、ある
いは個々に順次に分散機に投入する。例えば、分散剤等
を含む溶剤中に磁性粉を加え、所定の時間分散をつづけ
て磁性塗料とする方法などがある。その際、磁性粉はA
粉と予め接触共存させることが好ましく、この共存状態
で他の成分と混合するのが好ましい。これによってA粉
の作用がより効果的となる。In kneading and dispersing the ferromagnetic powder and the above-mentioned respective components, the ferromagnetic powder and the respective components are all charged into the disperser at the same time or individually. For example, there is a method in which magnetic powder is added to a solvent containing a dispersant and the dispersion is continued for a predetermined time to obtain a magnetic coating material. At that time, the magnetic powder is A
It is preferable to make the powder coexist with the powder in advance, and it is preferable to mix with other components in this coexisting state. This makes the action of the A powder more effective.
【0039】磁性塗料の混練分散にあたっては各種の分
散機が使用できる。例えば二本ロールミル、三本ロール
ミル、ボールミル、ペブルミル、トロンミル、サンドグ
ライダー、ゼグバリ(Szegvari)アトライター、高速イ
ンペラー分散機、高速ストーンミル、高速度衝撃ミル、
ディスパー、ニーダー、高速ミキサー、ホミジナイザ
ー、超音波分散機などを用いることができる。Various dispersers can be used for kneading and dispersing the magnetic paint. For example, two roll mill, three roll mill, ball mill, pebble mill, tron mill, sand glider, Szegvari attritor, high speed impeller disperser, high speed stone mill, high speed impact mill,
A disper, a kneader, a high speed mixer, a homogenizer, an ultrasonic disperser or the like can be used.
【0040】また、混練分散に関する技術として、ディ
ー・シー・パットン著“塗料の流動と顔料分散”(19
75年)に記載されている技術を用いることができる。As a technique for kneading and dispersing, see D.C. Patton, "Paint Flow and Pigment Dispersion" (19
1975) can be used.
【0041】かくして得られる磁性塗料を非磁性支持体
上に塗布する方法は従来公知の方法を用いることができ
る。例えば多層同時塗布法によって同時に2層以上の磁
性層を設けてもよい。As a method of applying the magnetic coating material thus obtained onto a non-magnetic support, a conventionally known method can be used. For example, two or more magnetic layers may be simultaneously provided by a multi-layer simultaneous coating method.
【0042】かかる方法により、支持体上に塗布された
磁性層は必要により前記のように層中の磁性体を無配向
させる処理を施したのち、形成した磁性層を乾燥する。
また必要により表面平滑化加工を施したり、所望の形状
に打ち抜いたりして磁気ディスクとする。According to such a method, the magnetic layer coated on the support is optionally subjected to the treatment for non-orienting the magnetic material in the layer as described above, and then the formed magnetic layer is dried.
If necessary, the surface is smoothed or punched into a desired shape to obtain a magnetic disk.
【0043】磁性層の厚みは乾燥厚みで約0.2〜12
μm、好ましくは0.3〜4μmの範囲となるように塗
布する。重層の場合は合計で上記の範囲とされる。ま
た、この乾燥厚みは磁気記録媒体の用途、形状、規格な
どにより決めるとよい。The magnetic layer has a dry thickness of about 0.2 to 12
It is applied so that it is in the range of μm, preferably 0.3 to 4 μm. In the case of multiple layers, the total is within the above range. The dry thickness may be determined depending on the use, shape, standard, etc. of the magnetic recording medium.
【0044】この磁性層は強磁性粉の分散不良や再凝集
に起因する表面欠陥が極めて少なく、表面平滑性に極め
て優れ、例えば中心線平均粗さ(Ra)で0.020μ
m以下と極めて平滑であり、ノイズが少なくS/N比が
良好であり、さらに短波長における記録特性が著しく向
上した磁性層である。This magnetic layer has very few surface defects due to poor dispersion of ferromagnetic powder and re-aggregation, and has extremely excellent surface smoothness. For example, the center line average roughness (Ra) is 0.020 μm.
It is a magnetic layer which is extremely smooth as m or less, has little noise, has a good S / N ratio, and has remarkably improved recording characteristics at short wavelengths.
【0045】[0045]
【実施例】以下、フレキシブル磁気ディスクの実施例を
掲げて本発明をさらに説明する。なお、例中の特性は次
の方法で求めた。EXAMPLES The present invention will be further described with reference to examples of flexible magnetic disks. The properties in the examples were obtained by the following methods.
【0046】1.塗料分散度 磁性塗料を厚み75μmのポリエチレンテレフタレート
フイルムの表面に乾燥後厚みが3.0±1.0μmとな
るように塗布し、乾燥、平滑化処理をする。得られた塗
膜を微分位相差顕微鏡(倍率:100倍)で観察し、任
意の1視野で視野内の径20μm以上の凹凸の数をカウ
ントし、その数をもって塗料分散度とする。1. Dispersion degree of coating material A magnetic coating material is applied on the surface of a polyethylene terephthalate film having a thickness of 75 μm so that the thickness after drying becomes 3.0 ± 1.0 μm, followed by drying and smoothing treatment. The obtained coating film is observed with a differential phase contrast microscope (magnification: 100 times), the number of irregularities having a diameter of 20 μm or more in the visual field is counted in one arbitrary visual field, and the number is defined as the paint dispersity.
【0047】2.短波長記録特性 キャップ長0.3μm、リング型Mn―Znフェライト
ヘッドを有する3.5インチフロッピーディスクドライ
ブを用いて、最適記録電流にて記録波長0.7、1.5
μmにおける出力を測定する。この出力を基準ディスク
の出力を0 dBとして示す。2. Short wavelength recording characteristics Using a 3.5 inch floppy disk drive having a cap length of 0.3 μm and a ring type Mn—Zn ferrite head, recording wavelengths of 0.7 and 1.5 at optimum recording currents.
Measure the output in μm. This output is shown as the output of the reference disk being 0 dB.
【0048】3.S/N(信号/雑音)比 ディスクの記録領域の最インナーで記録波長0.7μm
において測定した。3. S / N (signal / noise) ratio Recording wavelength 0.7 μm at the innermost part of the recording area of the disc
Was measured at.
【0049】[0049]
【実施例1〜8、比較例1,2】実施例1〜5の磁性塗
料を以下のようにして調製した。すなわち、以下の 六方晶バリウムフェライト 80重量部 (比表面積:50m2 /g、抗磁力:800 Oe 板状比:7 ) A粉(表1参照) 表1参照 ポリウレタン 6重量部 (協和醗酵工業(株);エステン5701 F1 ) 塩ビ・酢ビ樹脂 6重量部 (日信化学(株)TA-5C ) α―アルミナ 5重量部 (住友化学(株)AKP-20) オレイン酸オレイルエステル 5重量部 カーボンブラック 5重量部 (三菱化成(株)#3950 ) ガーファック RE610 3重量部 (東邦化学(株)) シクロヘキサノン 400重量部 よりなる組成物をサンドグラインダーで混合分散した
後、 コロネートL 10重量部 (日本ポリウレタン(株):低分子量イソシアナ-ト ) を添加し、さらに高速ディスパー中で混合し、磁性塗料
を調製した。Examples 1 to 8 and Comparative Examples 1 and 2 The magnetic coating materials of Examples 1 to 5 were prepared as follows. That is, the following hexagonal barium ferrite 80 parts by weight (specific surface area: 50 m 2 / g, coercive force: 800 Oe plate ratio: 7) A powder (see Table 1) See Table 1 Polyurethane 6 parts by weight (Kyowa Fermentation Industry ( Ltd .; Esten 5701 F1) Vinyl chloride / vinyl acetate resin 6 parts by weight (Nisshin Chemical Co., Ltd. TA-5C) α-alumina 5 parts by weight (Sumitomo Chemical Co., Ltd. AKP-20) Oleic acid oleyl ester 5 parts by weight Carbon Black 5 parts by weight (Mitsubishi Kasei Co., Ltd. # 3950) Garfac RE610 3 parts by weight (Toho Chemical Co., Ltd.) Cyclohexanone 400 parts by weight A composition consisting of 400 parts by weight was mixed and dispersed in a sand grinder, and then Coronate L 10 parts by weight (Japan Polyurethane Co., Ltd .: low molecular weight isocyanate) was added and further mixed in a high speed disperser to prepare a magnetic paint.
【0050】また、比較例1,2の磁性塗料として、実
施例1においてA粉に替えて表1記載のα―Fe2 O3
(比較例1)、SiO2 (比較例2)とした以外は全く
同じ組成の磁性塗料を全く同じように調整した。As the magnetic paints of Comparative Examples 1 and 2, α-Fe 2 O 3 shown in Table 1 was used instead of the powder A in Example 1.
Magnetic paints having the same composition except that (Comparative Example 1) and SiO 2 (Comparative Example 2) were prepared in exactly the same manner.
【0051】また実施例6〜8の磁性塗料を実施例1〜
5と同様にして調整した。すなわち、以下の 六方晶バリウムフェライト 80重量部 (比表面積:50m2 /g、抗磁力:800 Oe 板状比:7 ) A粉(表1参照) 表1参照 ポリウレタン 4重量部 (協和醗酵工業(株);エステン5701 F1 ) スルホン酸塩基等含有樹脂 2重量部 MR110 (実施例6)、TP-249(実施例7,8) 塩ビ・酢ビ樹脂 4重量部 (日信化学(株)TA-5C ) α―アルミナ 5重量部 (住友化学(株)AKP-20) オレイン酸オレイルエステル 5重量部 カーボンブラック 5重量部 (三菱化成(株)#3950 ) ガーファック RE610 3重量部 (東邦化学(株)) シクロヘキサノン 400重量部 よりなる組成物をサンドグラインダーで混合分散した
後、 コロネートL 10重量部 (日本ポリウレタン(株):低分子量イソシアナ-ト ) を添加し、さらに高速ディスパー中で混合し、磁性塗料
を調製した。Further, the magnetic paints of Examples 6 to 8 were applied to Examples 1 to 1.
It adjusted like 5th. That is, the following hexagonal barium ferrite 80 parts by weight (specific surface area: 50 m 2 / g, coercive force: 800 Oe plate ratio: 7) A powder (see Table 1) See Table 1 Polyurethane 4 parts by weight (Kyowa Fermentation Industry ( Ltd .; Esten 5701 F1) 2 parts by weight of resin containing sulfonate group MR110 (Example 6), TP-249 (Examples 7 and 8) 4 parts by weight of vinyl chloride / vinyl acetate resin (Nisshin Chemical Co., Ltd. TA- 5C) α-alumina 5 parts by weight (Sumitomo Chemical Co., Ltd. AKP-20) Oleic acid oleyl ester 5 parts by weight Carbon black 5 parts by weight (Mitsubishi Kasei Corporation # 3950) Garfac RE610 3 parts by weight (Toho Chemical Co., Ltd. )) Cyclohexanone (400 parts by weight) was mixed and dispersed in a sand grinder, and then 10 parts by weight of Coronate L (Nippon Polyurethane Co., Ltd .: low molecular weight isocyanate) was added and mixed in a high-speed disper. , To prepare a magnetic paint.
【0052】なお、ここでMR110は日本ゼオン
(株)のスルホン酸塩基含有塩ビ・酢ビであり、TP―
249は日本合成(株)のスルホン酸塩基含有ポリエス
テルポリウレタンである。Here, MR110 is a vinyl chloride / vinyl acetate containing sulfonate group of Nippon Zeon Co., Ltd., and TP-
249 is a sulfonate group-containing polyester polyurethane manufactured by Nippon Gosei Co., Ltd.
【0053】得られた磁性塗料は15℃で24時間熟成
させた後、厚さ75μmのポリエチレンテレフタレート
の片面上に乾燥後の厚みが2.5μmとなるように塗布
し、無配向化処理後乾燥し、次いで磁性層にカレンダー
加工を施した。さらに裏面にも同様の処理を実施した。
60℃、100時間熱処理後、円板状に打ち抜き磁気デ
ィスクを作成した。この磁気ディスクの特性を表1に示
す。The obtained magnetic coating composition was aged at 15 ° C. for 24 hours, applied on one surface of polyethylene terephthalate having a thickness of 75 μm so that the thickness after drying was 2.5 μm, and after non-orientation treatment, dried. Then, the magnetic layer was calendered. Further, the same treatment was performed on the back surface.
After heat treatment at 60 ° C. for 100 hours, a disk-shaped magnetic disk was punched out. The characteristics of this magnetic disk are shown in Table 1.
【0054】A粉を使用することにより、表1に示す如
く、塗料の分散性、特に分散安定性の向上が著しい。さ
らに工業的製品においては作り始めと作り終りの製品に
品質のバラツキが出ることは好ましくないが、A粉の使
用により塗料が安定化しているため品質のバラツキもま
た最小限(短波長記録特性評価)におさえられている。
さらにS/N比が大巾に向上している。By using the powder A, as shown in Table 1, the dispersibility of the coating material, particularly the dispersion stability, is remarkably improved. Furthermore, in industrial products, it is not desirable that the quality of the products at the beginning and the end of the production will vary, but the variation in quality is also minimal because the coating is stabilized by the use of powder A (short wavelength recording characteristics evaluation ).
Furthermore, the S / N ratio is greatly improved.
【0055】なお、表1のS/N比および短波長記録特
性は比較例1を基準ディスクとしたもので表示した。The S / N ratio and short wavelength recording characteristics in Table 1 are shown by using Comparative Example 1 as a reference disk.
【0056】[0056]
【表1】 [Table 1]
【0057】[0057]
【実施例9〜14、比較例3,4】実施例9〜11の磁
性塗料をCo―被着γ酸化鉄を用いて以下のように調整
した。すなわち、下記の Co―被着γ酸化鉄 70重量部 (比表面積50m2 /g、抗磁力750 Oe 針状比 10) A粉(表2参照) 3重量部 スルホン酸塩基等含有樹脂(表2参照)6重量部 ガーファック RE610(東邦化学(株))3重量部 ポリウレタン 6重量部 (大日本インキ化学(株):スハ゜ンテ゛ックス T-5250) 塩ビ・酢ビ樹脂 8重量部 (日信化学(株)TA-5C ) α―アルミナ 4重量部 (住友化学(株)AKP-20) カーボンブラック 6重量部 (三菱化成(株)#3950 ) オレイン酸オレイル 6重量部 シクロヘキサノン 400重量部 よりなる組成物をサンドグラインダーで混合分散した
後、 コロネートL 10重量部 (日本ポリウレタン(株):低分子量イソシアナ-ト ) を添加し、さらに高速ディスパー中で混合し、磁性塗料
を調製した。Examples 9 to 14 and Comparative Examples 3 and 4 The magnetic paints of Examples 9 to 11 were prepared as follows using Co-adhered gamma iron oxide. That is, the following Co-adhered γ iron oxide 70 parts by weight (specific surface area 50 m 2 / g, coercive force 750 Oe, acicular ratio 10) A powder (see Table 2) 3 parts by weight Resin containing sulfonate group (Table 2 6 parts by weight Garfac RE610 (Toho Chemical Co., Ltd.) 3 parts by weight Polyurethane 6 parts by weight (Dainippon Ink and Chemicals, Inc .: Spandex T-5250) 8 parts by weight vinyl chloride / vinyl acetate resin (Nisshin Chemical Co., Ltd.) ) TA-5C) α-alumina 4 parts by weight (Sumitomo Chemical Co., Ltd. AKP-20) Carbon black 6 parts by weight (Mitsubishi Kasei Co. # 3950) Oleyl oleate 6 parts by weight Cyclohexanone 400 parts by weight After mixing and dispersing with a sand grinder, 10 parts by weight of Coronate L (Nippon Polyurethane Co., Ltd .: low molecular weight isocyanate) was added, and further mixed in a high speed disperser to prepare a magnetic paint.
【0058】また比較例3として、実施例9においてA
粉に替えてα―Fe2 O3 を用いた以外は全く同様にし
て調整した磁性塗料を用意した。As Comparative Example 3, A in Example 9 was used.
A magnetic paint prepared in exactly the same manner was prepared except that α-Fe 2 O 3 was used instead of the powder.
【0059】更に実施例12〜14の磁性塗料として金
属鉄磁性粉を用いて以下のように調整した。すなわち、
下記の 金属鉄磁性粉 70重量部 (比表面積50m2 /g、抗磁力1500 Oe 針状比 10) A粉(表2参照) 3重量部 スルホン酸塩基等含有樹脂(表2参照)6重量部 ガーファック RE610(東邦化学(株))3重量部 ポリウレタン 6重量部 (大日本インキ化学(株):スハ゜ンテ゛ックス T-5250) 塩ビ・酢ビ樹脂 8重量部 (日信化学(株)TA-5C ) α―アルミナ 4重量部 (住友化学(株)AKP-20) カーボンブラック 6重量部 (三菱化成(株)#3950 ) オレイン酸オレイル 6重量部 シクロヘキサノン 400重量部 よりなる組成物をサンドグラインダーで混合分散した
後、 コロネートL 10重量部 (日本ポリウレタン(株):低分子量イソシアナ-ト ) を添加し、さらに高速ディスパー中で混合し、磁性塗料
を調製した。Further, magnetic iron magnetic powder was used as the magnetic coating material of Examples 12 to 14 to make the following adjustments. That is,
70 parts by weight of the following metallic iron magnetic powder (specific surface area 50 m 2 / g, coercive force 1500 Oe needle ratio 10) A powder (see Table 2) 3 parts by weight Resin containing sulfonate group, etc. (see Table 2) 6 parts by weight Garfac RE610 (Toho Chemical Co., Ltd.) 3 parts by weight Polyurethane 6 parts by weight (Dainippon Ink and Chemicals Co., Ltd .: Spandex T-5250) 8 parts by weight vinyl chloride / vinyl acetate resin (Nisshin Chemical Co., Ltd. TA-5C) α-alumina 4 parts by weight (Sumitomo Chemical Co., Ltd. AKP-20) Carbon black 6 parts by weight (Mitsubishi Kasei Co. # 3950) Oleyl oleate 6 parts by weight Cyclohexanone 400 parts by weight A composition is mixed and dispersed by a sand grinder. After that, 10 parts by weight of Coronate L (Nippon Polyurethane Co., Ltd .: low molecular weight isocyanate) was added and further mixed in a high-speed disperser to prepare a magnetic paint.
【0060】また比較例4として、実施例12において
A粉に替えてSiO2 を用いた以外は実施例12と全く
同様にして調整した磁性塗料を用意した。As Comparative Example 4, a magnetic coating material prepared in exactly the same manner as in Example 12 except that SiO 2 was used instead of the powder A in Example 12 was prepared.
【0061】得られた磁性塗料は、15℃で24時間熟
成させた後、厚さ75μmのポリエチレンテレフタレー
トフイルム上に乾燥後の厚さがCo―被着γ酸化鉄の場
合には1.0μm、金属鉄系強磁性粉の場合には2.7
μmとなるように塗布し、無配向処理後乾燥し、次いで
磁性層にカレンダー加工を施した。以下、実施例1〜8
と同様にして磁気ディスクを作成した。The obtained magnetic coating composition was aged at 15 ° C. for 24 hours, and then dried on a polyethylene terephthalate film having a thickness of 75 μm, and the thickness after drying was 1.0 μm in the case of Co-adhered γ iron oxide. 2.7 for metallic iron-based ferromagnetic powder
It was coated so as to have a thickness of .mu.m, non-oriented and dried, and then the magnetic layer was calendered. Hereinafter, Examples 1 to 8
A magnetic disk was created in the same manner as in.
【0062】この磁気ディスクの特性を表2に示す。な
お、表2においてS/N比、短波長記録特性は、実施例
9〜11においては比較例3を、実施例12〜14にお
いては比較例4を基準ディスクとしたもので表示した。
また同表のスルホン酸基等含有樹脂の欄のMR110,
TP―249は、前記実施例6〜8と同じである。Table 2 shows the characteristics of this magnetic disk. In Table 2, the S / N ratio and the short wavelength recording characteristics are shown by using Comparative Example 3 as a reference disk in Examples 9 to 11 and Comparative Example 4 in Examples 12 to 14.
MR110 in the column of resin containing sulfonic acid group, etc. in the table,
TP-249 is the same as in Examples 6 to 8 above.
【0063】[0063]
【表2】 [Table 2]
Claims (4)
結合剤を含有する磁性塗膜を設けてなる磁気記録媒体に
おいて、該磁性磁性塗膜中に平均粒径0.1μm以下の
軟磁性磁性粉を前記強磁性粉100重量部に対して0.
01〜20重量部含有することを特徴とする磁気記録媒
体。1. A magnetic recording medium comprising a non-magnetic support and a magnetic coating film containing at least a ferromagnetic powder and a binder, wherein the magnetic coating film has a soft magnetic particle size of 0.1 μm or less. Magnetic powder was added to 100 parts by weight of the ferromagnetic powder.
A magnetic recording medium containing 0.1 to 20 parts by weight.
粉100重量部に対して0.2〜15重量部である請求
項1記載の磁気記録媒体。2. The magnetic recording medium according to claim 1, wherein the content of the soft magnetic magnetic powder is 0.2 to 15 parts by weight with respect to 100 parts by weight of the ferromagnetic powder.
ベタイン基の少なくとも1種を1×10-6当量/g(樹
脂)以上含有する極性基含有樹脂を前記強磁性粉100
重量部に対して0.1〜50重量部含有する請求項1ま
たは2記載の磁気記録媒体。3. The ferromagnetic powder 100, wherein the binder contains a polar group-containing resin containing at least one of a sulfonate group and a sulfobetaine group at 1 × 10 −6 equivalent / g (resin) or more.
The magnetic recording medium according to claim 1 or 2, which is contained in an amount of 0.1 to 50 parts by weight with respect to parts by weight.
イト、Co―被着γ酸化鉄、または金属粉末である請求
項1〜3記載のいずれかの磁気記録媒体。4. The magnetic recording medium according to claim 1, wherein the ferromagnetic powder is hexagonal barium ferrite, Co-coated γ iron oxide, or metal powder.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP3305599A JPH05120668A (en) | 1991-10-25 | 1991-10-25 | Magnetic recording medium |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP3305599A JPH05120668A (en) | 1991-10-25 | 1991-10-25 | Magnetic recording medium |
Publications (1)
Publication Number | Publication Date |
---|---|
JPH05120668A true JPH05120668A (en) | 1993-05-18 |
Family
ID=17947087
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP3305599A Pending JPH05120668A (en) | 1991-10-25 | 1991-10-25 | Magnetic recording medium |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH05120668A (en) |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6194226A (en) * | 1984-10-16 | 1986-05-13 | Victor Co Of Japan Ltd | Magnetic recording medium |
JPS61133012A (en) * | 1984-11-30 | 1986-06-20 | Hitachi Maxell Ltd | Magnetic recording medium |
JPS62204430A (en) * | 1986-03-03 | 1987-09-09 | Nippon Telegr & Teleph Corp <Ntt> | Magnetic card |
JPH02134724A (en) * | 1988-11-15 | 1990-05-23 | Konica Corp | Magnetic recording medium |
JPH02218013A (en) * | 1989-02-20 | 1990-08-30 | Toppan Printing Co Ltd | Magnetic recoding medium |
JPH03134822A (en) * | 1989-10-20 | 1991-06-07 | Berumateitsuku:Kk | Method of coating of magnetic recording layer in magnetic recording medium |
JPH0410215A (en) * | 1990-04-27 | 1992-01-14 | Tokyo Jiki Insatsu Kk | Magnetic recording medium |
-
1991
- 1991-10-25 JP JP3305599A patent/JPH05120668A/en active Pending
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6194226A (en) * | 1984-10-16 | 1986-05-13 | Victor Co Of Japan Ltd | Magnetic recording medium |
JPS61133012A (en) * | 1984-11-30 | 1986-06-20 | Hitachi Maxell Ltd | Magnetic recording medium |
JPS62204430A (en) * | 1986-03-03 | 1987-09-09 | Nippon Telegr & Teleph Corp <Ntt> | Magnetic card |
JPH02134724A (en) * | 1988-11-15 | 1990-05-23 | Konica Corp | Magnetic recording medium |
JPH02218013A (en) * | 1989-02-20 | 1990-08-30 | Toppan Printing Co Ltd | Magnetic recoding medium |
JPH03134822A (en) * | 1989-10-20 | 1991-06-07 | Berumateitsuku:Kk | Method of coating of magnetic recording layer in magnetic recording medium |
JPH0410215A (en) * | 1990-04-27 | 1992-01-14 | Tokyo Jiki Insatsu Kk | Magnetic recording medium |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US4513054A (en) | Magnetic recording medium | |
EP0107984B1 (en) | Magnetic recording medium | |
US4844977A (en) | Magnetic recording medium | |
US4666770A (en) | Magnetic recording medium | |
EP0107985B1 (en) | Magnetic recording medium | |
JPS60124023A (en) | Magnetic recording medium | |
US4911997A (en) | Magnetic recording medium | |
JPS60201527A (en) | Magnetic recording medium | |
JP3071549B2 (en) | Magnetic recording media | |
JPH05120668A (en) | Magnetic recording medium | |
JP2809909B2 (en) | Magnetic recording media | |
CA2060364A1 (en) | Process for preparing magnetic coating composition | |
JPH05120673A (en) | Magnetic recording medium | |
JPH05242459A (en) | Magnetic recording medium | |
JPH05242460A (en) | Magnetic recording medium | |
JPH0682458B2 (en) | Magnetic recording medium | |
JP2614103B2 (en) | Magnetic recording media | |
JP3537454B2 (en) | Manufacturing method of magnetic paint | |
JP2871978B2 (en) | Ferromagnetic metal powder and magnetic recording medium using the same | |
JPH05120672A (en) | Magnetic recording medium | |
JPH0363926A (en) | Magnetic recording medium and its production | |
JPH1166544A (en) | Magnetic recording medium | |
JPS60131633A (en) | Manufacture of magnetic recording medium | |
JPS60175213A (en) | Magnetic recording medium | |
JPH04286716A (en) | Flexible magnetic disk |