JPH05119449A - Silver halide color photographic sensitive material - Google Patents

Abstract

PURPOSE:To improve treatment stability an preservable property by incorporating a specified emulsion having high silver chloride content, a specified epoxy compd. which is hardly soluble in water, and a specified compd. into an yellow color developing layer. CONSTITUTION:The yellow color developing layer contains an emulsion with high silver chloride content containing >=90mol% silver chloride, one kind of epoxy compd. having one group expressed by formula I which is hardly soluble in water, and one kind of compd. expressed by formula II. In formula I, R1-R5 are same or different hydrogen atoms, alkyl groups or aryl groups. R is a substituent and(n)is an integer 0-4. -Y- is a bivalent connecting group and -X- is -O-, -S-, or -N(R')-. R' is a hydrogen atom, acyl group, alkylsulfonyl group, aryl group, heterocyclic group, or -C(R6)(R7)(R8), wherein R6, R7, and R8 may be same or different alkyl groups or specified groups. Or R6 and R7 are hydrogen atoms. In formula II, R1-R4 are independently hydrogen atoms, etc.

Description

Detailed Description of the Invention

[0001]

FIELD OF THE INVENTION The present invention relates to a multilayer silver halide color photographic light-sensitive material suitable for rapid processing. More particularly, it relates to a multilayer silver halide color photographic light-sensitive material which is excellent in processing stability of a yellow colored portion and is excellent in storability of a yellow image after processing.

[0002]

2. Description of the Related Art In recent years, in order to meet the demand for rapid processing, a high silver chloride emulsion is used in a light-sensitive material and is used in combination with a processing solution containing neither sulfite nor benzyl alcohol contained in conventional color developing solutions. Various systems are being developed and introduced to the market. Generally, a silver halide color photographic light-sensitive material has three colors of yellow, magenta and cyan.
A color photographic coupler is contained in a light-sensitive emulsion layer, and an exposed light-sensitive material is subjected to color development processing with a so-called color developing agent to perform color reproduction by a subtractive method. When the photographic performance of the three colors changes due to changes in various factors in the process from exposure to post-processing drying, including differences between the production lots of the photosensitive material, the color reproduction balance achieved by the combination changes and the image Quality is degraded. In fact, when the exposed photosensitive material is continuously processed in the photo lab, various compounds are eluted from the photosensitive material into the processing solution, the processing solution is taken out by the photosensitive material, contamination between processing steps, and evaporation of moisture. The liquid composition gradually changes due to the concentration of the liquid due to. Therefore, it is an important issue in quality control to suppress the change in photographic performance against the change in the liquid composition. Although various attempts have been made to solve this problem, the attempts from the side of the light-sensitive material include the control of the developability of the silver halide emulsion, the improvement of the film physical properties of the light-sensitive material, the improvement of the coupler, and the high boiling solvent. Has been improved, and materials that have little effect on photographic performance during elution have been used. However, these methods that have been proposed hitherto are not sufficient, and further improved techniques have been demanded.

On the other hand, in light of the purpose of recording and storing the light-sensitive material, naturally, it is necessary to maintain the image immediately after processing without deterioration even after long-term storage. At present, there is a problem that the yellow color image has a weak dark storage property and that the color tends to become turbid when stored for a long time. In order to solve such problems, it is disclosed in JP-A-64-50048, 64-50049 and 61-4041 that a cyclic ether compound or an epoxy group-containing compound is used. The effect was not yet at a sufficient level, and the effect was small especially when the so-called rapid processing was performed with a developer containing no benzyl alcohol. Further, there is almost no effect on the color turbidity of the yellow color image, and a new technique has been demanded.

[0004]

SUMMARY OF THE INVENTION It is an object of the present invention to provide a multilayer silver halide color photographic light-sensitive material which has excellent processing stability of a yellow color forming layer and excellent storage stability of a yellow dye image after processing.

[0005]

The objects of the present invention have been achieved by the following techniques. In a silver halide color photographic light-sensitive material containing a yellow color forming silver halide emulsion layer, a magenta color forming silver halide emulsion layer, and a cyan color forming silver halide emulsion layer on a support, the yellow color forming layer contains silver chloride. A high silver chloride emulsion having a content of 90 mol% or more, at least one of water-insoluble epoxy compounds having at least one group represented by the general formula (AO), and at least a compound represented by the general formula (IV). A silver halide color photographic light-sensitive material containing one kind.

[0006]

[Chemical 4]

In the general formula (AO), R ₁ , R ₂ , R ₃ and R
₄ and R _{5, which} may be the same or different, each represents a hydrogen atom, an alkyl group or an aryl group. R represents a substituent, n represents the integer of 0-4. -Y- represents a divalent linking group. -X- is -O-, -S- or -N (R ')
Represents-. R ′ represents a hydrogen atom, an acyl group, an alkylsulfonyl group, an arylsulfonyl group, an aryl group, a heterocyclic group or —C (R ₆ ) (R ₇ ) (R ₈ ). Here, R ₆ , R ₇ and R ₈ may be the same or different and each represents an alkyl group or a group represented by general formula (AO-1) shown below. R ₆ and R ₇ further represent a hydrogen atom.

[0008]

[Chemical 5]

When n is 2 to 4, a plurality of R's may be the same or different. Also, any one of R ₁ to R ₅
, R ′ and R, or two Rs may combine with each other to form a 5- to 7-membered ring. However, when X is -S-, the total number of carbon atoms of the compound is 15 or more. When X is —O— and —Y— is —SO ₂ — or phenylene, n is an integer of 1 to 4, or at least one of R _{1 to} R ₅ is an alkyl group or aryl. It is a base. When X is —O— and Y is —O—CO ₂ —, R ₁
The total carbon number of R ₄ and R is 10 or more.

[0010]

[Chemical 6]

In the general formula (IV), R ₁ , R ₂ , R ₃ and R ₄ are each independently a hydrogen atom, an aliphatic group, an aromatic group,
It represents an aliphatic oxycarbonyl group, an aromatic oxycarbonyl group or a carbamoyl group. However, R ₁ , R ₂ , R ₃
Not all of R ₄ and R ₄ are hydrogen atoms at the same time, and the total number of carbon atoms thereof is 8 to 60. In addition, R ₁ and R ₂ , and R ₃ and R ₄ may form a 5-membered to 7-membered ring, respectively.

The present invention will be described in more detail below. First, the water-insoluble epoxy compound having a group represented by formula (AO) of the present invention will be described in detail. The poorly water-soluble epoxy compound is an epoxy compound having a solubility in water of 10% or less at 25 ° C. and a total carbon number of 9 or more, preferably 18 or more, more preferably 30 or more.

The alkyl group represented by the general formula (AO) is a linear, branched or cyclic alkyl group (for example, methyl, ethyl, n-propyl, i-propyl, n-butyl, t-butyl, cyclohexyl, n-octyl). , T-octyl,
n-decyl, sec-dodecyl, n-hexadecyl, n
-Octadecyl) and may further have a substituent. The aryl group in formula (AO) is an aromatic hydrocarbon group (for example, phenyl or naphthyl) and may have a substituent.

The heterocyclic group represented by the general formula (AO) is a 5- to 7-membered cyclic group in which at least one ring-constituting atom is an atom selected from an oxygen atom, a nitrogen atom and a sulfur atom. It doesn't matter. Further, it may have a substituent. Examples of the heterocyclic group include thienyl, furyl, imidazolyl, pyrazolyl, pyrrolyl,
Indolyl, pyridyl, chromanil, pyrazolidinyl,
Examples thereof include piperazinyl, 4-morpholinyl, triazinyl and the like. The substituent in formula (AO) means an alkyl group, an alkenyl group, an alkynyl group, an aryl group, a heterocyclic group, an alkoxy group, an aryloxy group, an alkylthio group, an arylthio group, a hydroxy group, a halogen atom, a cyano group, and a nitro group. Group, acyl group, acyloxy group, silyloxy group, sulfonyl group, sulfonyloxy group, alkoxycarbonyl group, aryloxycarbonyl group, amide group, imide group, carbamoyl group, sulfamoyl group,
Examples thereof include ureido group, urethane group, aminosulfamoyl group, amino group, alkylamino group, arylamino group and heterocyclic amino group.

R ₁ , R ₂ , R ₃ , R ₄ and R ₅ may be the same or different and each represents a hydrogen atom, an alkyl group,
Alternatively, it represents an aryl group. R represents a substituent, n is 0 to
Represents an integer of 4. When n is 2 to 4, plural Rs may be the same or different. -Y- is a divalent linking group (for example, a single bond, -O -, - S -, - SO 2 -, - S- substituted which may imino group, -O-CO ₂ -, the substituents And an phenylene group which may have a substituent, a phenylene group which may have a substituent, a naphthylene group and a divalent heterocyclic group).

X is --O--, --S-- or --N (R ')-.
Represent R'is a hydrogen atom, an acyl group (eg acetyl, acroyl, benzoyl), an alkylsulfonyl group (eg methanesulfonyl, ethanesulfonyl, dotecansulfonyl), an arylsulfonyl group (eg benzenesulfonyl, toluenesulfonyl), an aryl group, a heterocycle group, a _{-C (R 6) (R 7} ) (R 8). Here, R ₆ , R ₇ and R ₈ may be the same or different and each represents an alkyl group or a group represented by general formula (AO-1) shown below. R ₆ and R ₇ further represent a hydrogen atom.

[0017]

[Chemical 7]

R ₁ , R ₂ and R ₃ in the general formula (AO-1) represent the groups defined in the general formula (AO). Further, any two of R _{1 to} R ₅ , R ′ and R or two R
May combine with each other to form a 5- to 7-membered ring. However, when X is -S-, the total number of carbon atoms of the compound is 15 or more. The X is -O-, and and -Y- is -SO ₂
-Or phenylene, n is an integer of 1 to 4, or at least one of R _{1 to} R ₅ is an alkyl group or an aryl group. X is -O- and Y is -O
When it is —CO ₂ —, the total carbon number of R _{1 to} R ₄ and R is 10 or more.

The group represented by the general formula (AO) may have a partner atom bonded to any of a hydrogen atom, a carbon atom, a nitrogen atom, a sulfur atom and an oxygen atom. Among the epoxy compounds having a group represented by the general formula (AO),
From the viewpoint of the effect of the present invention, it is a compound having 3 or more, more preferably 4 or more, and still more preferably 5 or more groups represented by the general formula (AO). On the other hand, the epoxy compound having a group represented by the general formula (AO) preferably has a total sum of benzene rings of 2 or more, more preferably 3 or more, and further preferably 4 or more.
That is all.

Of the epoxy compounds having a group represented by the general formula (AO) of the present invention, the following general formula (A) is preferable.
E-1), (AE-2), (AE-3) and (AE-
4).

[0021]

[Chemical 8]

In the general formulas (AE-1) to (AE-4), E represents the following general formula (AO-2).

[0023]

[Chemical 9]

R _{1 to} R ₅ and X in the general formula (AO-2) represent the groups defined in the general formula (AO). In formulas (AE-1) to (AE-4), R represents a group defined by formula (AO). L ₁ , L ₂ , and L
₃ may be the same or different and each represents a divalent linking group. As L ₁ , L ₂ and L ₃ , an alkylene group which may have a substituent is preferable, and examples thereof include the following structures.

[0025]

[Chemical 10]

N ₁ is 3 to 6, m ₁ is 0 to 3, and n ₂ is 1 to
5, n ₃ is 1 to 4, n ₄ is 1 to 5, m ₂ is 0 to 4, m ₃
Is 0 to 3, m ₄ is 0 to 4, n ₅ is 1 to 5, m ₅ is 0.
4, m ₆ ~m ₉ represents an integer of 0-4. p ₁ and x represent a real number of 0 to 20. p ₂ represents an integer of 3 to 4, A
Represents a trivalent to tetravalent organic group. Examples of A include the following structures.

[0027]

[Chemical 11]

When a plurality of E's and R's are present, the plurality of E's may be the same or different, and the plurality of R's may be the same or different. The compounds represented by the general formulas (AE-2) and (AE-3) may be a mixture of compounds having different numbers of p ₁ and p ₂ .

Among the compounds represented by the general formulas (AE-1) to (AE-4), the general formulas (AE-1) to (AE-3)
Those represented by
Those represented by E-2) to (AE-3), and those represented by the general formula (AE-2) are most preferable. Among those represented by the general formula (AE-2), the general formula (AO-
It is preferable that -X- in 2) is represented by -O-, and p ₁ is 1 to 20, more preferably 2 to 2.
0, more preferably 3 to 20, most preferably 4 to 20
And n _{2 to} n ₄ are preferably 1 to ₂ , m _{2 to} m ₄ are preferably 0 to 3, and most preferably 1 to 2, and R is an alkyl group, a halogen atom or an alkoxy group. preferable.

Specific examples of the compound of the present invention are shown below.
The present invention is not limited to this.

[0031]

[Chemical 12]

[0032]

[Chemical 13]

[0033]

[Chemical 14]

[0034]

[Chemical 15]

[0035]

[Chemical 16]

[0036]

[Chemical 17]

[0037]

[Chemical 18]

[0038]

[Chemical 19]

[0039]

[Chemical 20]

[0040]

[Chemical 21]

[0041]

[Chemical formula 22]

[0042]

[Chemical formula 23]

The variables x and y in the structural formula are real numbers and may be in the range of 0 to 20. The reason why x is not necessarily an integer is that epoxy compounds having several kinds of integer values are mixed in a certain ratio and show the average value thereof. These epoxy compounds may be used alone or in combination of two or more.

The epoxy compound of the present invention is used by emulsifying and dispersing it in a hydrophilic binder such as an aqueous gelatin solution together with a coupler or separately using a surfactant. The epoxy compound of the present invention itself may be used as the high boiling organic solvent, but a high boiling organic solvent having a boiling point of 160 ° C. or higher other than the epoxy compound of the present invention, which is hardly soluble in water, a low boiling auxiliary organic solvent or / and water. You may use together with an insoluble polymer soluble in an organic solvent. As examples of the high boiling point organic solvent and the polymer, those disclosed in JP-A-64-537 are preferable. Further, the coupler and the sparingly water-soluble epoxy compound can be added to different layers, but it is preferable to add them in the same layer, particularly in the same oil droplet.

The epoxy resin used in the present invention is
For example, it can be obtained by reacting bisphenol A and epichlorohydrin in the presence of caustic soda (see Naoshishiro Oishi et al., "Plastic Materials Course (5) Epoxy Resin", Nikkan Kogyo Shimbun). The use amount of the epoxy compound of the present invention is preferably 3% to 100%, and more preferably 5% to 30% by weight with respect to the yellow coupler.

Next, the compound represented by formula (IV) of the present invention will be explained. In the general formula (IV), R ₁ ,
R ₂ , R ₃ and R ₄ are each a hydrogen atom, an aliphatic group, an aromatic group, an aliphatic oxycarbonyl group (dodecyloxycarbonyl, allyloxycarbonyl etc.), an aromatic oxycarbonyl group (phenoxycarbonyl etc.) or Represents a carbamoyl group (tetradecylcarbamoyl, phenyl-methylcarbamoyl, etc.), wherein R ₁ ,
R ₂ , R ₃ , and R ₄ are not all hydrogen atoms at the same time, and the total number of carbon atoms is 8 to 60.

The term "aliphatic group" as used herein means a linear, branched or cyclic aliphatic hydrocarbon group and is meant to include saturated and unsaturated groups such as alkyl, alkenyl and alkynyl groups. Typical examples are methyl, ethyl, butyl, dodecyl, octadecyl, eicosenyl,
iso-propyl, tert-butyl, tert-octyl, tert-
Dodecyl, cyclohexyl, cyclopentyl, allyl,
Examples include vinyl, 2-hexadecenyl, propargyl, and the like.
Here, the aromatic group preferably represents a substituted or unsubstituted phenyl group or naphthyl group having 6 to 42 carbon atoms.

These aliphatic groups and aromatic groups further include an alkyl group, an aryl group, a heterocyclic group, an alkoxy group (eg, methoxy, 2-methoxyethoxy), an aryloxy group (eg, 2,4-di-tert-group). -Amylphenoxy, 2-chlorophenoxy, 4-cyanophenoxy),
Alkenyloxy group (for example, 2-propenyloxy), acyl group (for example, acetyl, benzoyl), ester group (for example, butoxycarbonyl, phenoxycarbonyl, acetoxy, benzoyloxy, butoxysulfonyl, toluenesulfonyloxy), amide group (for example, , Acetylamino, ethylcarbamoyl, dimethylcarbamoyl, methanesulfonamide, butylsulfamoyl), sulfamide groups (eg succinimide,
Hydantoinyl), a ureido group (eg, phenylureido, dimethylureido), an aliphatic or aromatic sulfonyl group (eg, methanesulfonyl, phenylsulfonyl), an aliphatic or aromatic thio group (eg, ethylthio, phenylthio), a hydroxy group, It may be substituted with a group selected from a cyano group, a carboxy group, a nitro group, a sulfo group, a halogen atom and the like. Below is the general formula (IV)
Specific examples of the compound represented by are shown below, but the present invention is not limited thereto.

[0049]

[Chemical formula 24]

[0050]

[Chemical 25]

[0051]

[Chemical formula 26]

[0052]

[Chemical 27]

[0053]

[Chemical 28]

For the method for synthesizing the compound of the general formula (IV) of the present invention, for example, (IV-9), the method described in Example 1 of column 11 of US Pat. No. 4,540,657 can be used. Other compounds can also be synthesized according to this method. The compound of the general formula (IV) of the present invention has the general formula (AO)
An epoxy compound having a group represented by and a yellow coupler are used separately or separately, and emulsified and dispersed in a hydrophilic binder such as an aqueous gelatin solution using a surfactant. The amount of the compound of the general formula (IV) of the present invention used is preferably 10% to 1000% by weight, more preferably 100% to 600% by weight based on the epoxy compound having a group represented by the general formula (AO) of the present invention. %.

The yellow coupler preferably used in the present invention is represented by formula (I).

[0056]

[Chemical 29]

In the general formula (I), R ₁ is a substituent, R ₂ is a halogen atom, an alkyl group, an aryl group, an alkoxy group, an aryloxy group, a dialkylamino group, an alkylthio group or an arylthio group, and R _{3 is} Is a substitutable group on the benzene ring, X ₁ is a hydrogen atom or a group capable of splitting off upon coupling reaction with an oxidation product of an aromatic primary amine type developing agent, and p is an integer of 0 to 4, respectively. Represent However, when p is plural, plural R ₃ may be the same or different.

In the general formula (I), R ₁ is an aryl group,
A tertiary alkyl group or a group represented by formula (D) is preferable. Among the tertiary alkyl groups, the t-butyl group is the most preferable.

[0059]

[Chemical 30]

In the general formula (D), R ₃₁ is a monovalent substituent except a hydrogen atom, and Q is selected from C and a 3- to 5-membered hydrocarbon ring or at least one of N, S, O and P. It represents a group of non-metal atoms necessary for forming a 3- to 5-membered heterocycle containing a hetero atom in the ring. The ring formed by Q together with C may contain an unsaturated bond in the ring. Examples of the ring formed by Q together with C include a cyclopropane ring, a cyclobutane ring, a cyclopentane ring, a cyclopropene ring, a cyclobutene ring and a cyclopentene ring. R ₃₁ is preferably a halogen atom, a cyano group, a monovalent group having 1 to 30 carbon atoms (for example, an alkyl group or an alkoxy group), or a monovalent group having 6 to 30 carbon atoms (for example, an aryl group or an aryloxy group). ) Is mentioned. R ₂ represents a halogen atom, an alkyl group, an aryl group, an alkoxy group, an aryloxy group, a dialkylamino group, an alkylthio group, or an arylthio group. Particularly preferred are chlorine atom, methyl group,
An ethyl group and a methoxy group. R ₃ represents a substitutable group on the benzene ring, and particularly preferably an alkoxy group, a carbonamido group or a sulfonamide group. X ₁ represents a hydrogen atom or a group capable of splitting off by a coupling reaction with an oxidized product of an aromatic primary amine type developing agent, and particularly preferably a heterocyclic group or aryloxy group bonded to the coupling active position with a nitrogen atom. It is a base. p represents an integer of 0 to 4, respectively. However, when p is plural, plural R ₃ may be the same or different.

Further, the coupler represented by the general formula (I) may form a dimer or a multimer which is bonded to each other through a divalent or divalent group. The yellow coupler of the general formula (I) is usually 0.1 to 1.0 mol, preferably 0.1 to 0.5 mol, per mol of silver halide.
Molar content. Specific examples of X ₁ and R ₃ and specific examples of the yellow coupler represented by formula (I) are shown below, but the invention is not limited thereto.

[0062]

[Chemical 31]

[0063]

[Chemical 32]

[0064]

[Chemical 33]

[0065]

[Chemical 34]

[0066]

[Chemical 35]

[0067]

[Table 1]

[0068]

[Table 2]

[0069]

[Table 3]

The term "photosensitive" or "non-photosensitive" used in the present invention is meant to include not only visible light but also sensitivity to electromagnetic waves in the infrared wavelength region. The color photographic light-sensitive material of the present invention is constituted by coating at least one yellow color-forming silver halide emulsion layer, magenta color-forming silver halide emulsion layer and cyan color-forming silver halide emulsion layer on a support. .. Generally, a yellow color forming silver halide emulsion layer, a magenta color forming silver halide emulsion layer and a cyan color forming silver halide emulsion layer are coated in this order from the support side. When an emulsion having sensitivity to visible light is used, a silver halide emulsion having sensitivity in each wavelength range, and a dye having a complementary color relationship with the light to be exposed-namely, yellow for blue, magenta for green and red. Incorporation of a so-called color coupler which forms cyan with respect to the above enables color reproduction by the subtractive method. However, the photosensitive layer and the coloring hue of the coupler may not have the above correspondence.

The silver halide emulsion used in the present invention has a silver chloride content of 90 mol% or more, further 95 mol% or more, and particularly 98 mol% or more, which is substantially free of silver iodide for the purpose of rapid processing. It is preferable to use silver chloride or silver chlorobromide. The halogen composition of the emulsion may be different or the same between the grains, but it is preferable to use an emulsion having the same halogen composition between the grains because the photographic performance of each grain can be easily made uniform. Regarding the halogen composition distribution inside the silver halide emulsion grains, the so-called uniform structure grains having the same composition in any portion of the silver halide grains, or the core inside the silver halide grains and the shell surrounding them. (Shell) [a single layer or a plurality of layers] particles having a so-called laminated structure having a different halogen composition or a structure having a portion having a different halogen composition inside or on the surface of the particle (edge of the particle when present on the particle surface, It is possible to appropriately select and use particles having a structure in which parts having different compositions are bonded to a corner or a surface. In order to obtain high sensitivity, it is advantageous to use either of the latter two particles rather than the particles having a uniform structure, and it is also preferable from the viewpoint of pressure resistance. When the silver halide grain has the above structure,
The boundary between the different portions in the halogen composition may be a clear boundary or an unclear boundary by forming a mixed crystal due to the difference in composition, and positively imparting a continuous structural change. It may be one. In such a high silver chloride emulsion, a structure having a silver bromide-rich phase localized in the inside and / or the surface of the silver halide grain in the form of layer or non-layer as described above is preferable. The halogen composition of the localized phase preferably has a silver bromide content of at least 10 mol%, more preferably more than 20 mol%. And these localized phases can be inside the grain, on the edges, corners or faces of the grain surface,
Those existing at the corners of the particles are particularly preferable. On the other hand, it is also preferable to use grains having a uniform structure in which the distribution of the halogen composition in the grains is small, for the purpose of suppressing the sensitivity decrease when the photographic material receives pressure.

The average grain size of the silver halide grains contained in the silver halide emulsion used in the present invention (the grain size is determined by the diameter of a circle equivalent to the projected area of the grain and the number average thereof is taken) is 0.1 μm. ˜2 μm is preferred. Also,
Their particle size distribution is a so-called simple coefficient of variation (standard deviation of particle size distribution divided by average particle size) of 20% or less, preferably 15% or less, more preferably 10% or less, most preferably 7% or less. It is preferably dispersed. At this time, it is also preferable to use the above monodisperse emulsion by blending it in the same layer for the purpose of obtaining a wide latitude, or to perform multi-layer coating. The shape of silver halide grains contained in a photographic emulsion is one having a regular crystal form such as a cube, a tetradecahedron or an octahedron, an irregular shape such as a sphere or a plate. ) Those having a crystalline form or those having a composite form thereof can be used. It may also be a mixture of those having various crystal forms. In the present invention, it is preferable that 50% or more, preferably 70% or more, and more preferably 90% or more of particles having the above-mentioned regular crystal form are contained in the present invention. In addition to these, an emulsion having tabular grains having an average aspect ratio (diameter in terms of circle / thickness) of 5 or more, preferably 8 or more as a projected area exceeding 50% of all grains can be preferably used.

The emulsion used in the present invention is described by P. Glafkides C
himie et Phisique Photographique (published by Paul Montel,
1967), GF Duffin Photographic Emulsion Chem
istry (Focal Press, 1966), VL Zelikman
et al by Making and Coating Photographic Emulsion
(Focal Press, Inc., 1964) and the like. That is, any of an acidic method, a neutral method, an ammonia method and the like may be used, and as a method for reacting a soluble silver salt and a soluble halogen salt, any method such as a one-sided mixing method, a simultaneous mixing method, and a combination thereof may be used. You may use. It is also possible to use a method of forming particles in an atmosphere in which silver ions are excessive (so-called reverse mixing method). As one form of the simultaneous mixing method, a method of keeping pAg in a liquid phase where silver halide is formed constant, that is, a so-called controlled double jet method can be used. According to this method, a silver halide emulsion having a regular crystal form and a substantially uniform grain size can be obtained.

The silver halide emulsion used in the present invention has various properties for the purpose of improving sensitivity, reciprocity property, temperature / humidity dependency during exposure, latent image storability, etc. in the process of emulsion grain formation or physical ripening. Polyvalent metal ion impurities can be introduced. Examples of compounds used include salts of cadmium, zinc, lead, copper, thallium, etc., or salts or complex salts of Group VIII elements iron, ruthenium, rhodium, palladium, osmium, iridium, platinum and the like. it can. Particularly, the above Group VIII elements can be preferably used. The addition amount of these compounds can be varied over a wide range depending on the purpose, but it is 10 relative to silver halide.
^-9 to 10 ^-2 mol is preferred. The silver halide emulsion used in the present invention is chemically and spectrally sensitized. Chemical sensitization includes sulfur sensitization represented by the addition of unstable sulfur compounds, selenium sensitization, and precious metal sensitization represented by gold sensitization.
Alternatively, reduction sensitization can be used alone or in combination. Spectral sensitization is carried out for the purpose of imparting spectral sensitivity in a desired light wavelength region to the emulsion of each layer in the light-sensitive material of the present invention. In the present invention, it is preferable to add a dye that absorbs light in a wavelength range corresponding to the desired spectral sensitivity-a spectral sensitizing dye. The spectral sensitizing dye used at this time is, for example, Heter by FM Harmer.
ocyclic compounds-Cyanine dyes and related compoun
ds (John Wiley & Sons New York, London, 1964
Year). Examples of specific compounds and the spectral sensitization method are described in JP-A-62-2152.
Those described on page 22, right upper column to page 38 of JP-A-72 are preferably used.

The silver halide emulsion used in the present invention contains various compounds or precursors thereof for the purpose of preventing fog during the production process of the light-sensitive material, storage or photographic processing, or stabilizing photographic performance. Can be added. Specific examples of these compounds are described in JP-A-62-2152.
Those described on pages 39 to 72 of Japanese Patent Publication No. 72 are preferably used. The emulsion used in the present invention may be any type of so-called surface latent image type emulsion in which a latent image is mainly formed on the grain surface, or so-called internal latent image type emulsion in which a latent image is mainly formed inside the grain. Is also good. The gelatin used in the present invention is preferably gelatin that has been subjected to deionization treatment. Gelatin usually contains a large amount of calcium ions and is often contained at 5000 ppm or more. The deionized gelatin used in the present invention has a calcium ion content of 500.
It is preferable to use one having a content of ppm or less. Deionized gelatin is preferably used in an amount of 10% by weight or more, more preferably 20% or more, based on the total gelatin.
% Or more is particularly preferable. Such gelatin may be used in any layer.

The light-sensitive material according to the present invention comprises a hydrophilic colloid layer for the purpose of improving the sharpness of an image, a dye which can be decolorized by a treatment described in European Patent EP 0,337,490A2, pages 27 to 76. Among them, an oxonol dye) is added so that the optical reflection density at 680 nm of the light-sensitive material is 0.70 or more, or a dihydric or tetrahydric alcohol (for example, tricarboxylic acid) is added to the water resistant resin layer of the support. It is preferable to contain 12% by weight or more (more preferably 14% by weight or more) of titanium oxide surface-treated with (methylolethane) or the like.

Photographic additives such as cyan, magenta and yellow couplers which can be used in the present invention are preferably dissolved in a high-boiling organic solvent, and the high-boiling organic solvent has a melting point of 100 ° C. or lower and a boiling point of 140 ° C. The above-mentioned water-immiscible compound can be used as long as it is a good solvent for the coupler. The melting point of the high boiling point organic solvent is preferably 80 ° C. or lower. The boiling point of the high boiling point organic solvent is preferably 160 ° C. or higher,
More preferably, it is 170 ° C. or higher. For details of these high-boiling point organic solvents, see JP-A-62-215272.
It is described in the lower right column on page 137 to the upper right column on page 144. Also,
The cyan, magenta or yellow coupler is dissolved in a loadable latex polymer (e.g., U.S. Pat. No. 4,203,716) in the presence or absence of the high boiling organic solvent or dissolved with a water insoluble and organic solvent soluble polymer. It can be emulsified and dispersed in a hydrophilic colloid aqueous solution. The homopolymers or copolymers described in columns 7 to 15 of US Pat. No. 4,857,449 and pages 12 to 30 of WO88 / 00723 are preferably used, and more preferably a methacrylate-based or acrylamide-based polymer. In particular, use of an acrylamide polymer is preferable in terms of color image stabilization.

In the light-sensitive material according to the present invention, it is preferable to use a color image storability-improving compound as described in European Patent EP 0,277,589A2 together with a coupler. In particular, it is preferably used in combination with a pyrazoloazole coupler. That is, the compound (F) that chemically bonds with the aromatic amine-based developing agent remaining after the color development processing to form a chemically inactive and substantially colorless compound and / or the fragrance remaining after the color development processing. The use of the compound (G), which forms a chemically inactive and substantially colorless compound by chemically bonding with an oxidant of a group amine color developing agent, simultaneously or solely, for example, in storage after processing. It is preferable in order to prevent stains and other side effects due to the formation of a coloring dye due to the reaction of the coupler with the color developing agent remaining in the film or its oxidant.

In order to prevent various molds and bacteria which propagate in the hydrophilic colloid layer and deteriorate the image, the light-sensitive material according to the present invention has an anti-mold property as described in JP-A-63-271247. It is preferable to add an agent.

As the support used in the light-sensitive material of the present invention, a white polyester support or a layer containing a white pigment for a display is provided on the support having a silver halide emulsion layer. A support may be used. Further, in order to further improve the sharpness, it is preferable to apply an antihalation layer on the silver halide emulsion layer coated side or the back side of the support. In particular, the transmission density of the support is 0.3 so that the display can be viewed with both reflected and transmitted light.
It is preferably set in the range of 5 to 0.8.

The light-sensitive material according to the present invention may be exposed to visible light or infrared light. The exposure method may be low-illuminance exposure or high-illuminance short-time exposure, and in the latter case, a laser scanning exposure method in which the exposure time per pixel is shorter than 10 ⁻⁴ seconds is preferable.

In the exposure, US Pat. No. 4,880,72
It is preferable to use the band stop filter described in No. 6. As a result, the light color mixture is removed, and the color reproducibility is significantly improved.

The color photographic light-sensitive material of the present invention is preferably subjected to color development after exposure, bleach-fixing, and washing treatment (or stabilizing treatment). Bleaching and fixing may be performed separately instead of the one bath as described above. When the color photographic light-sensitive material of the present invention is used, color development to water washing (or stabilization) can be performed within 4 minutes. More preferably 3
Within minutes.

Silver halide emulsions and other materials (additives and the like) and photographic constituent layers (layer arrangement and the like) applied to the light-sensitive material according to the present invention, and processing methods applied to process the light-sensitive material. The following patent publications, particularly European Patent EP 0,355,660A2 (Japanese Patent Laid-Open No. 2-1395
Those described in No. 44) are preferably used.

[0085]

[Table 4]

[0086]

[Table 5]

[0087]

[Table 6]

[0088]

[Table 7]

As cyan couplers, the above-mentioned cyan couplers and the diphenylimidazole type cyan couplers described in JP-A-2-33144, European Patent EP 0,333,185A2.
3-Hydroxypyridine cyan couplers (especially couplers (42) listed as specific examples, which have been converted into 2-equivalent by attaching a chlorine leaving group to couplers (6) and (9)) Is particularly preferable) and the cyclic active methylene cyan couplers described in JP-A No. 64-32260 (coupler examples 3, 8, and 34 listed as specific examples are particularly preferable) may be used in combination.

A method for processing a silver halide color light-sensitive material using a high silver chloride emulsion having a silver chloride content of 90 mol% or more is disclosed in JP-A-2-207250, page 27, upper left column to page 34, upper right column. The method described in 1. is preferably applied.

[0091]

EXAMPLES The present invention will be specifically described below with reference to examples, but the present invention is not limited thereto. Example 1 A multi-layer color photographic paper having the following layer constitution was prepared on a paper support laminated on both sides with polyethylene. The coating liquid was prepared as follows. 15.0 g of a yellow coupler (exemplified compound Y-31), 2.0 g of a color image stabilizer (A-35), 5.0 g of the exemplified compound (IV-1) of the general formula (IV), a color image stabilizer (Cpd
-2) 0.4 g, color image stabilizer (Cpd-1) 2.0 g, sodium dodecylbenzenesulfonate 2.0 g, ethyl acetate 25 cc
Dissolve by adding, and this solution is homogenized with a homogenizer.
0% lime-treated ossein gelatin aqueous solution 150 cc (citric acid
(Including 1.5 g). On the other hand, silver chlorobromide emulsion (cubic, large size emulsion B1 with average grain size 0.85 μm)
: 0.65 μm and small size emulsion B2 of 5: 5 mixture (molar ratio of silver), variation coefficient of grain size is 0.07 and 0.09 respectively, 0.2 mol% of silver bromide is localized on a part of grain surface in each emulsion. The content of the blue-sensitive sensitizing dyes A and B shown below is 2.2 × for each large-sized emulsion per mol of silver halide.
10 ⁻⁴ mol was added, and 2.7 × 10 ⁻⁴ mol was added to the small size emulsion. The chemical ripening of this emulsion was performed by adding a sulfur sensitizer and a gold sensitizer. The above emulsified dispersion and this emulsion were mixed and dissolved to prepare a coating solution for the first layer having the composition shown below. The coating solutions for the second to seventh layers were prepared in the same manner as the coating solution for the first layer. 1-Oxy-3,5-dichloro-s-triazine sodium was used as a hardening agent for gelatin in each layer. In addition, the total amount of Cpd-10 and Cpd-11 was 25.0 mg / m ² in each layer.
It was added so as to be 50.0 mg / m ² . The following spectral sensitizing dyes were used in the silver chlorobromide emulsion of each photosensitive emulsion layer.

[0092]

[Table 8]

[0093]

[Table 9]

[0094]

[Table 10]

For the blue-sensitive emulsion layer, the green-sensitive emulsion layer and the red-sensitive emulsion layer, 1- (5-methylureidophenyl)-
5-mercaptotetrazole with silver halide 1
3.4 × 10 ^-4 mol, 9.7 × 10 ^-4 mol, 5.5 × 10 per mol
^-4 mol was added. Further, 4-hydroxy-6-methyl-1,3,3a, 7 is added to the blue-sensitive emulsion layer and the green-sensitive emulsion layer.
Tetrazaindene was added in an amount of 1 × 10 ^-4 mol and 2 × 10 ^-4 mol per mol of silver halide, respectively. Further, the following dyes (the amount in parentheses represents the coating amount) were added to the emulsion layer to prevent irradiation.

[0096]

[Chemical 36]

(Layer Structure) The composition of each layer is shown below. The numbers represent the coating amount (g / m ² ). The silver halide emulsion represents the coating amount in terms of silver.

Support: Polyethylene laminated paper (polyethylene on the first layer side contains a white pigment (TiO ₂ ) and a bluish dye (ultraviolet))

First Layer (Yellow-Coloring Emulsion Layer) The Silver Chlorobromide Emulsion 0.27 Gelatin 1.10 Yellow-Coupler (Exemplified Compound Y-31) 0.75 Epoxy Compound of the Present Invention (Exemplified Compound A-35) 0.02 Color Image Stabilizer (Cpd-2) 0.02 Color image stabilizer (Cpd-1) 0.20 Solvent (Solv-1) 0.25 Second layer (color mixing prevention layer) Gelatin 0.99 Color mixing inhibitor (Cpd-4) 0.08 Solvent (Solv-7) 0.02 Solvent (Solv-2) 0.25 Solvent (Solv-3) 0.25

Third layer (magenta color forming emulsion layer) Silver chlorobromide emulsion (cubic, large size emulsion G1 having an average grain size of 0.52 μm and a small size emulsion G2 having a grain size of 0.42 μm in a ratio of 6: 4 (Ag mol) Coefficients of variation of grain size distribution are 0.10 and 0.08, respectively. AgBr 0.8 mol% was locally contained in a part of grain surface in each size emulsion) 0.13 Gelatin 1.45 Magenta coupler (ExM) 0.16 Color image stabilizer (Cpd-6) 0.15 Color image stabilizer (Cpd-2) 0.03 Color image stabilizer (Cpd-7) 0.01 Color image stabilizer (Cpd-8) 0.01 Color image stabilizer (Cpd-9) 0.08 Solvent (Solv- 3) 0.50 Solvent (Solv-4) 0.15 Solvent (Solv-5) 0.15 Fourth layer (color mixing prevention layer) Gelatin 0.70 Color mixing inhibitor (Cpd-4) 0.06 Solvent (Solv-7) 0.02 Solvent (Solv-2) 0.20 Solvent (Solv-3) 0.20

Fifth layer (cyan color-forming emulsion layer) Silver chlorobromide emulsion (cubic, 7: 3 mixture of a large size emulsion R1 having an average grain size of 0.58 μm and a small size emulsion R2 having a grain size of 0.45 μm (Ag mole) The coefficient of variation of the grain size distribution is 0.09 and 0.11, and AgBr 0.6 mol% was locally contained in a part of the grain surface in each size emulsion.) 0.20 Gelatin 0.85 Cyan coupler (ExC) 0.33 UV absorber (UV -2) 0.18 Color image stabilizer (Cpd-10) 0.15 Color image stabilizer (Cpd-11) 0.15 Color image stabilizer (Cpd-12) 0.01 Color image stabilizer (Cpd-9) 0.01 Color image stabilizer (Cpd -7) 0.01 Solvent (Solv-6) 0.22 Solvent (Solv-1) 0.01 Sixth layer (UV absorption layer) Gelatin 0.55 UV absorber (UV-1) 0.42 Color image stabilizer (Cpd-13) 0.15 Color image stabilization Agent (Cpd-6) 0.02

Seventh Layer (Protective Layer) Gelatin 1.13 Polyvinyl alcohol acrylic modified copolymer (modification degree 17%) 0.15 Liquid paraffin 0.03 Color image stabilizer (Cpd-14) 0.01 The compounds used here are shown below.

[0103]

[Chemical 37]

[0104]

[Chemical 38]

[0105]

[Chemical Formula 39]

[0106]

[Chemical 40]

[0107]

[Chemical 41]

[0108]

[Chemical 42]

[0109]

[Chemical 43]

[0110]

[Chemical 44]

The sample thus obtained was used as sample 101.
And Next, as shown in Table 2, the compositions of the first layer were changed to prepare Samples 102 to 109.

First, a sensitometer (FWH type, manufactured by Fuji Photo Film Co., Ltd., color temperature of light source: 3200 ° K) manufactured by Fuji Photo Film Co., Ltd. was used as sample 101, and a gray exposure was performed so that about 30% of the coated silver amount was developed. Gave. The exposed sample was subjected to continuous processing by using a paper processor with the following processing steps and a solution having a processing solution composition to prepare a developing processing state in a running equilibrium state.

Treatment process Temperature Time Replenisher * Tank capacity Color development 35 ° C 45 seconds 161 ml 17 liter Bleach fixing 30-35 ° C 45 seconds 215 ml 17 liter Rinse 30 ° C 90 seconds 350 ml 10 liter Dry 70-80 ° C 60 seconds * Replenishment amount per 1 m ² of light-sensitive material

The composition of each processing solution is as follows. Color developer Tank solution Replenisher Water 800 ml 800 ml Ethylenediamine-N, N, N ', N'-tetramethylenephosphonic acid 1.5 g 2.0 g Potassium bromide 0.015 g --- Triethanolamine 8.0 g 12.0 g Sodium chloride 1.4 g --- potassium carbonate 25 g 25 g N-ethyl-N- (β-methanesulfonamidoethyl) -3-methyl-4-aminoaniline sulfate 5.0 g 7.0 g N, N-bis (carboxymethyl) hydrazine 4.0 g 5.0 g N, N-di (sulfoethyl) hydroxylamine / 1Na 4.0 g 5.0 g Optical brightener (WHITEX 4B, Sumitomo Chemical Co., Ltd.) 1.0 g 2.0 g Water added 1000 ml 1000 ml pH (25 ° C) 10.05 10.45

Bleach-fixing solution (tank solution and replenisher are the same) Water 400 ml Ammonium thiosulfate (700 g / l) 100 ml Sodium sulfite 17 g Ethylenediaminetetraacetic acid iron (III) ammonium 55 g Ethylenediaminetetraacetate disodium 5 g Bromide Ammonium 40 g Water added 1000 ml pH (25 ℃) 6.0 Rinse solution (same as tank solution and replenisher) Ion-exchanged water (calcium and magnesium are 3 ppm or less each)

The following evaluations were performed on each sample. (A) Gradation fluctuation of yellow color development part Sensitometry for each of Samples 101 to 109 using a sensitometer (FWH type manufactured by Fuji Photo Film Co., Ltd.)
A three-color separation filter was used for gradation exposure, and the treatment with the liquid composition before the continuous treatment in the above treatment step and the treatment in the running equilibrium state were performed. In both treatments, the change (Δgamma) in the slope (gamma) of the density curve 0.8 to 1.8 of the characteristic curve of the yellow color development part was determined. The closer this Δgamma is to zero, the smaller the process variation and the better. (B) Preservation property of yellow dye image The sample treated in running equilibrium state in the evaluation (a) was stored at 80 ° C and 60% relative humidity for 40 days. The ratio (D / D ₀ (%)) of the density D after storage to the initial yellow density (D ₀ ) 2.0 was calculated. The closer the value is to 100, the higher the fastness of the yellow image, which is preferable. Also, the increase in magenta density (ΔD magenta) and the increase in cyan density (ΔD cyan) before and after storage at the point of initial yellow density 2.0 were measured. The smaller the values of ΔD magenta and ΔD cyan, the smaller the increase in yellow color turbidity, which is preferable. Table 2 shows the results of the above evaluations performed on Samples 101 to 109.

[0117]

[Table 11]

According to Table 2, the gray scales before and after running were observed only in samples 101 and 102 in which both the epoxy compound containing the group represented by the general formula (AO) and the compound represented by the general formula (IV) were used in combination. It can be seen that the change (Δgamma) is small and the image storability in the yellow colored portion is excellent.

Example 2 In sample 101 of Example 1, the yellow coupler was changed to Y.
Sample 201 to which the same weight mixture of −31 and Y-2 was substituted (equimolar substitution with Y-31 in Sample 101) and the kind and amount of the compound in the first layer were changed as shown in Table 3.
211 was produced. Table 3 shows the results of evaluation performed by performing the same processing as in Example 1.

[0120]

[Table 12]

According to Table 3, as in Example 1, only in Samples 201 to 208 in which both the epoxy compound containing a group represented by the general formula (AO) and the compound represented by the general formula (IV) were used in combination. , Gradation change before and after running (△ gamma)
It can be seen that there is little and the image storability in the yellow colored portion is excellent.

Example 3 Sample 101 of Example 1 in which the yellow-coupler species was changed to Y-2, Y-6, Y-12, Y-20, and Y-34 (equal moles as Y-31). Substituent) was prepared and evaluated in the same manner as in Example 1. As a result, a sample in which both the epoxy compound containing a group represented by the general formula (AO) and the compound of the general formula (IV) were used before and after running. It was reproduced that the gradation change (Δgamma) was small and the image storability in the yellow colored portion was excellent.

[0123]

According to the present invention, it is possible to obtain a silver halide color photographic light-sensitive material which has little gradation variation in the yellow color-developed portion even after running processing and has excellent dye image storability after processing.

─────────────────────────────────────────────────── ───

[Procedure amendment]

[Submission date] November 5, 1991

[Procedure Amendment 1]

[Document name to be amended] Statement

[Name of item to be corrected] Claim 1

[Correction method] Change

[Correction content]

[Chemical 1] In the general formula (AO), R ₁ , R ₂ , R ₃ , R ₄ and R ₅
May be the same or different and each represents a hydrogen atom, an alkyl group or an aryl group. R represents a substituent, n represents the integer of 0-4. -Y- represents a divalent linking group. −
X- represents -O-, -S- or -N (R ')-.
R'is a hydrogen atom, an acyl group, an alkylsulfonyl group, an arylsulfonyl group, an aryl group, a heterocyclic group or-
It represents C (R ₆ ) (R ₇ ) (R ₈ ). Where R ₆ and R ₇
And R ₈ may be the same or different and each represents an alkyl group or a group represented by general formula (AO-1) shown below.
R ₆ and R ₇ further represent a hydrogen atom.

[Chemical 2] When n is 2 to 4, a plurality of Rs may be the same or different. Further, any two of R ₁ to R ₅ , R ′ and R or two Rs may be bonded to each other to form a 5- to 7-membered ring. However, when X is -S-, the total number of carbon atoms of the compound is 15 or more. X is -O- and -Y-
Is —SO ₂ — or phenylene, n is an integer of 1 to 4, or at least one of R _{1 to} R ₅ is an alkyl group or an aryl group. When X is —O— and Y is —O—CO ₂ —, the total carbon number of R _{1 to} R ₅ and R is 10 or more.

[Chemical 3] In formula (IV), R ₁ , R ₂ , R ₃ and R ₄ each independently represent a hydrogen atom, an aliphatic group, an aromatic group, an aliphatic oxycarbonyl group, an aromatic oxycarbonyl group or a carbamoyl group. However, all of R ₁ , R ₂ , R ₃ and R ₄ are not hydrogen atoms at the same time, and the total number of carbon atoms thereof is 8 to 60. In addition, R ₁ and R ₂ , R ₃ and R
Each of ₄ and ₄ may form a 5-membered to 7-membered ring.

[Procedure Amendment 2]

[Document name to be amended] Statement

[Correction target item name] 0009

[Correction method] Change

[Correction content]

When n is 2 to 4, a plurality of R's may be the same or different. Also, any one of R ₁ to R ₅
, R ′ and R, or two Rs may combine with each other to form a 5- to 7-membered ring. However, when X is -S-, the total number of carbon atoms of the compound is 15 or more. When X is —O— and —Y— is —SO ₂ — or phenylene, n is an integer of 1 to 4, or at least one of R _{1 to} R ₅ is an alkyl group or aryl. It is a base. When X is —O— and Y is —O—CO ₂ —, R ₁
The total number of carbon atoms of R ₅ and R ₅ is 10 or more.

[Procedure 3]

[Document name to be amended] Statement

[Correction target item name] 0018

[Correction method] Change

[Correction content]

R ₁ , R ₂ and R ₃ in the general formula (AO-1) represent the groups defined in the general formula (AO). Further, any two of R _{1 to} R ₅ , R ′ and R or two R
May combine with each other to form a 5- to 7-membered ring. However, when X is -S-, the total number of carbon atoms of the compound is 15 or more. The X is -O-, and and -Y- is -SO ₂
-Or phenylene, n is an integer of 1 to 4, or at least one of R _{1 to} R ₅ is an alkyl group or an aryl group. X is -O- and Y is -O
When it is —CO ₂ —, the total carbon number of R _{1 to} R ₅ and R is 10 or more.

[Procedure amendment 4]

[Document name to be amended] Statement

[Correction target item name] 0101

[Correction method] Change

[Correction content]

Fifth layer (cyan color-forming emulsion layer) Silver chlorobromide emulsion (cubic, 7: 3 mixture of a large size emulsion R1 having an average grain size of 0.58 μm and a small size emulsion R2 having a grain size of 0.45 μm (Ag mole) The coefficient of variation of the grain size distribution is 0.09 and 0.11, and AgBr 0.6 mol% was locally contained in a part of the grain surface in each size emulsion.) 0.20 Gelatin 0.85 Cyan coupler (ExC) 0.33 UV absorber (UV -2) 0.18 color image stabilizer (Cpd-1) 0.33 color image stabilizer (Cpd-10) 0.15 color image stabilizer (Cpd-11) 0.15 color image stabilizer (Cpd-12) 0.01 color image stabilizer (Cpd -9) 0.01 Color image stabilizer (Cpd-7) 0.01 Solvent (Solv-6) 0.22 Solvent (Solv-1) 0.01 Sixth layer (UV absorbing layer) Gelatin 0.55 UV absorber (UV-1) 0.42 Color image stabilizing Agent (Cpd-13) 0.15 Color image stabilizer (Cpd-6) 0.02

[Procedure Amendment 5]

[Document name to be amended] Statement

[Correction target item name] 0108

[Correction method] Change

[Correction content]

[0108]

[Chemical 42]

Claims (1)

[Claims] 1. A silver halide color photographic light-sensitive material containing a yellow color-forming silver halide emulsion layer, a magenta color-forming silver halide emulsion layer, and a cyan color-forming silver halide emulsion layer on a support. High-silver chloride emulsion having a silver chloride content of 90 mol% or more, a general formula (AO)
A silver halide color photographic light-sensitive material comprising at least one water-insoluble epoxy compound having at least one group represented by and at least one compound represented by the general formula (IV). [Chemical 1] In the general formula (AO), R ₁ , R ₂ , R ₃ , R ₄ and R ₅
May be the same or different and each represents a hydrogen atom, an alkyl group or an aryl group. R represents a substituent, n represents the integer of 0-4. -Y- represents a divalent linking group. −
X- represents -O-, -S- or -N (R ')-.
R'is a hydrogen atom, an acyl group, an alkylsulfonyl group, an arylsulfonyl group, an aryl group, a heterocyclic group or-
It represents C (R ₆ ) (R ₇ ) (R ₈ ). Where R ₆ and R ₇
And R ₈ may be the same or different and each represents an alkyl group or a group represented by general formula (AO-1) shown below.
R ₆ and R ₇ further represent a hydrogen atom. [Chemical 2] When n is 2 to 4, a plurality of Rs may be the same or different. Further, any two of R ₁ to R ₅ , R ′ and R or two Rs may be bonded to each other to form a 5- to 7-membered ring. However, when X is -S-, the total number of carbon atoms of the compound is 15 or more. X is -O- and -Y-
Is —SO ₂ — or phenylene, n is an integer of 1 to 4, or at least one of R _{1 to} R ₅ is an alkyl group or an aryl group. When X is —O— and Y is —O—CO ₂ —, the total carbon number of R _{1 to} R ₄ and R is 10 or more. [Chemical 3] In formula (IV), R ₁ , R ₂ , R ₃ and R ₄ each independently represent a hydrogen atom, an aliphatic group, an aromatic group, an aliphatic oxycarbonyl group, an aromatic oxycarbonyl group or a carbamoyl group. However, R ₁ , R ₂ , R ₃ and R ₄ are not all hydrogen atoms at the same time, and the total number of carbon atoms thereof is 8 to 60. In addition, R ₁ and R ₂ , R ₃ and R
Each of ₄ and ₄ may form a 5-membered to 7-membered ring.