JPH049965A - Transfer type electrostatic thermal recording method - Google Patents
Transfer type electrostatic thermal recording methodInfo
- Publication number
- JPH049965A JPH049965A JP11350990A JP11350990A JPH049965A JP H049965 A JPH049965 A JP H049965A JP 11350990 A JP11350990 A JP 11350990A JP 11350990 A JP11350990 A JP 11350990A JP H049965 A JPH049965 A JP H049965A
- Authority
- JP
- Japan
- Prior art keywords
- medium
- recording
- image
- toner
- recording medium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000012546 transfer Methods 0.000 title claims abstract description 12
- 238000000034 method Methods 0.000 title claims description 17
- 238000010438 heat treatment Methods 0.000 claims description 7
- 210000000078 claw Anatomy 0.000 claims description 6
- 238000004140 cleaning Methods 0.000 abstract description 2
- 238000011161 development Methods 0.000 description 5
- -1 polyethylene Polymers 0.000 description 5
- 239000007788 liquid Substances 0.000 description 4
- 239000004743 Polypropylene Substances 0.000 description 3
- 229920001155 polypropylene Polymers 0.000 description 3
- 239000004698 Polyethylene Substances 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 229920000915 polyvinyl chloride Polymers 0.000 description 2
- 239000004800 polyvinyl chloride Substances 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- 229930182556 Polyacetal Natural products 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 229920002433 Vinyl chloride-vinyl acetate copolymer Polymers 0.000 description 1
- 229920006243 acrylic copolymer Polymers 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 229920002301 cellulose acetate Polymers 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000013013 elastic material Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 230000001678 irradiating effect Effects 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920006324 polyoxymethylene Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 229920001909 styrene-acrylic polymer Polymers 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- 239000005061 synthetic rubber Substances 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 230000037303 wrinkles Effects 0.000 description 1
Landscapes
- Electrophotography Using Other Than Carlson'S Method (AREA)
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は転写型静電熱記録方法に関し、詳しくは、特定
の記録媒体に静電荷像を形成せしめ、これを反転現像し
、得られたトナー像を普通紙等の記録紙に転写させ、再
び記録を行なう際には新たな前記特定の記録媒体を供給
するようにした転写型静電熱記録方法に関する。[Detailed Description of the Invention] [Industrial Application Field] The present invention relates to a transfer type electrostatic thermal recording method, and more specifically, an electrostatic charge image is formed on a specific recording medium, and the resulting toner is developed by reversing the image. The present invention relates to a transfer type electrostatic thermal recording method in which an image is transferred to recording paper such as plain paper, and when recording is performed again, a new specific recording medium is supplied.
記録方法は種々の手段が提案されており、そのもののう
ちには、(1)電気伝導性基体上に、加熱によって電気
抵抗を減じる樹脂層を設け、この層を静電的に荷電し、
原画にしたがった熱線の照射をして画像の静電潜像を形
成する方法(特公昭35−14722号公報)、あるい
は(2)熱線を十分に透過するエレクトロサーモグラフ
ィー材料を複写すべき原画に載せ、静電荷を与えた後、
熱線を作用させて静電潜像をつくり、乾式トナーによる
反転現像、次いで定着する複写法(特公昭38−143
47号公報)などが知られている。だが、これらの方法
は原稿と密着させた状態で赤外線照射をするので画像の
解像性が悪く、かつ、必要な記録エネルギーも大きいと
いった未解決な問題が残されている。Various recording methods have been proposed, including (1) providing a resin layer that reduces electrical resistance by heating on an electrically conductive substrate, and electrostatically charging this layer;
A method of forming an electrostatic latent image of an image by irradiating heat rays according to the original image (Japanese Patent Publication No. 35-14722), or (2) placing an electrothermographic material that sufficiently transmits heat rays on the original image to be copied. , after giving an electrostatic charge,
A copying method in which an electrostatic latent image is created by the action of heat rays, reversely developed with dry toner, and then fixed (Japanese Patent Publication No. 38-143)
Publication No. 47), etc. are known. However, these methods still have unresolved problems, such as poor image resolution and high recording energy requirements because infrared rays are irradiated while the document is in close contact with the document.
本発明は上記のごとき未解決な問題を解消し、また、従
来の技術より工程が簡単で、かつ、デジタル情報を普通
紙に記録できるようにした転写型静電熱記録方法を提供
するものである。The present invention solves the above-mentioned unresolved problems, and also provides a transfer electrostatic thermal recording method that has a simpler process than conventional techniques and is capable of recording digital information on plain paper. .
本発明の転写型静電熱記録方法は、常温で帯電性を有し
加熱下では非帯電性或いは弱帯電性となる静電熱記録層
を有するシート状記録媒体の一端をクランプ爪で咬えて
回転ドラムに巻きつけ、その状態で該記録媒体に均一帯
電を施こし、画像信号に対応した熱信号を与えて潜電潜
像を形成し、その帯電潜像を該均一帯電極性と同一極性
のトナーで反転現像して該記録媒体上に画像を形成し、
続いて、その画像を記録紙へ転写する工程を1サイクル
として行なった後、この1サイクル使用した該記録媒体
は排紙とし、Iサイクルの記録ごとに新たな該シート状
記録媒体を供給し前記工程を繰り返すことを特徴として
いる。In the transfer type electrostatic thermal recording method of the present invention, one end of a sheet-like recording medium having an electrostatic thermal recording layer that is chargeable at room temperature and becomes non-chargeable or weakly chargeable under heating is gripped with a clamp claw, and a rotating drum is moved. In this state, the recording medium is uniformly charged, a thermal signal corresponding to the image signal is applied to form a latent latent image, and the charged latent image is charged with toner having the same polarity as the uniformly charged polarity. forming an image on the recording medium by reverse development;
Subsequently, after performing the process of transferring the image onto recording paper as one cycle, the recording medium used in this one cycle is discharged, and a new sheet-like recording medium is supplied for each I-cycle recording. It is characterized by repeating the process.
本発明者らは、これまで種々の記録媒体について研究検
討を進めてきたが、常温で帯電性を有し加熱下では非帯
電性或いは弱帯電性となる性質をもつ記録媒体(静電熱
記録媒体)の使用によれば、面倒な操作を行なうことな
く良質の画像が得られることを確めた。本発明はこれに
よりなされたものである。The present inventors have so far carried out research and examination on various recording media, and found that recording media (electrothermal recording media) that are chargeable at room temperature and become non-chargeable or weakly chargeable under heating. ), it was confirmed that high quality images could be obtained without any troublesome operations. The present invention has been achieved thereby.
以下に、本発明を添加の図面に従がいながらさらに詳細
に説明する。In the following, the invention will be explained in more detail with reference to the additional drawings.
先ず、本発明で用いられる静電熱記録媒体は、第1図に
示したように、ベース層14の表面に静電熱記録層15
が形成され、ベース層14の裏面に導電層16が形成さ
れたものである。但し、導電層16はベース層14の裏
面が導電性ドラムなどに接しているような場合には敢え
て形成されていなくてもかまわない。例えば、後に説明
を加える第3図に示した装置にみられるように、プラテ
ンドラム7が導電性であってアースされたものであれば
、静電熱記録媒体1には導電層16が敢えて設けられて
いなくてもかまわない。First, the electrostatic thermal recording medium used in the present invention has an electrostatic thermal recording layer 15 on the surface of the base layer 14, as shown in FIG.
is formed, and a conductive layer 16 is formed on the back surface of the base layer 14. However, the conductive layer 16 may not be formed if the back surface of the base layer 14 is in contact with a conductive drum or the like. For example, as seen in the apparatus shown in FIG. 3, which will be explained later, if the platen drum 7 is conductive and grounded, the electrostatic thermal recording medium 1 is intentionally provided with the conductive layer 16. It doesn't matter if you don't.
ベース層14は静電熱記録層15の支持体であり。The base layer 14 is a support for the electrostatic thermal recording layer 15.
例えばポリエステル、ポリ塩化ビニル、ポリエチレン、
ポリプロピレンなどのフィルム(厚さは1〜50R好ま
しくは1〜30IJrn程度)からなっている。このベ
ース層14は静電熱記録層15の必要条件と一致するの
であれば、ベースM14を静電熱記録層と兼ねさせるこ
とができる。For example, polyester, polyvinyl chloride, polyethylene,
It is made of a film such as polypropylene (thickness is about 1 to 50R, preferably about 1 to 30IJrn). If this base layer 14 meets the requirements for the electrostatic thermal recording layer 15, the base M14 can also serve as the electrostatic thermal recording layer.
静電熱記録層15は軟化点が30〜200°C好ましく
は60〜15℃の熱可塑性プラスチック層(厚さは1〜
50閾好ましくは約1〜30声程度)であり、常温では
電気抵抗が101111Ωcm以上であり、加熱信号を
受けた状態では109Ωcm以下になる材料が適当であ
る。具体的には、ポリ塩化ビニル、セルロースアセテー
ト、ポリアセタール、塩ビー酢ビ共重合体、エチレン−
酢ビ共重合体、アクリル系ポリマー、スチレン系ポリマ
ー、ポリエステル、ポリアミド、ポリエチレン、ポリプ
ロピレン、フッ素化アクリル−アクリル共重合体、スチ
レン−アクリル共重合体等がある。The electrostatic thermal recording layer 15 is a thermoplastic layer having a softening point of 30 to 200°C, preferably 60 to 15°C (thickness of 1 to 15°C).
50 threshold (preferably about 1 to 30 tones), and has an electrical resistance of 101111 Ωcm or more at room temperature and 109 Ωcm or less when receiving a heating signal. Specifically, polyvinyl chloride, cellulose acetate, polyacetal, vinyl chloride-vinyl acetate copolymer, ethylene-
Examples include vinyl acetate copolymers, acrylic polymers, styrene polymers, polyesters, polyamides, polyethylene, polypropylene, fluorinated acrylic-acrylic copolymers, and styrene-acrylic copolymers.
導電層16の材料としてはAQ蒸着層(100人〜20
00人の厚さ)や各種導電処理剤が用いられるが、第3
図に示したドラム7に導電性(体積抵抗109Ωcm以
下好ましくは106Ωe1m以下)のものを用いれば、
ベース層を兼ねることができる。なお、導電層16を有
する記録媒体を用いたときは、第3図に示したように、
クランプ爪71の裏側にアースがされていることが望ま
しい。The material for the conductive layer 16 is an AQ vapor deposited layer (100 to 20
00 thickness) and various conductive treatment agents are used, but the third
If the drum 7 shown in the figure is conductive (volume resistance 109Ωcm or less, preferably 106Ωe1m or less),
It can also serve as a base layer. Note that when a recording medium having a conductive layer 16 is used, as shown in FIG.
It is desirable that the back side of the clamp claw 71 be grounded.
かかる静電熱記録媒体1を用いて記録が行なわれる様子
を第2図によって説明すれば次のとおりである。The manner in which recording is performed using such electrostatic thermal recording medium 1 will be explained below with reference to FIG.
まず、(a)静電記録媒体1の静電熱記録層上に均一コ
ロナ帯電を施す。(b)画像信号に対応したデジタル信
号をサーマルヘッド3に与える。サーマルヘッド3は8
〜16dot/mn+の高解像度を有するシリアヘッド
やラインヘッドに用いられるものが好ましい。この加熱
により、加熱されたところの静電熱記録層の抵抗値は減
少し電荷は消失する。(C)均一コロナ帯電時の極性と
同極性のトナー4で反転現像すると静電熱記録媒体1上
には画像が形成される。現像には一成分系又は二成分系
乾式現像剤、液体現像剤のいずれが用いられてもがまわ
ない。次いで、(d)普通紙等の記録紙5にトナー像を
転写する。転写後は、乾式トナーが用いられた場合には
加熱定着され、湿式トナーが用いられた場合には記録紙
上に残存する液体(担体液)を乾燥する。First, (a) uniform corona charging is applied to the electrostatic thermal recording layer of the electrostatic recording medium 1. (b) Give a digital signal corresponding to the image signal to the thermal head 3. Thermal head 3 is 8
It is preferable to use a serial head or a line head having a high resolution of ~16 dots/mn+. By this heating, the resistance value of the heated electrostatic thermal recording layer decreases and the charge disappears. (C) An image is formed on the electrostatic thermal recording medium 1 by reversal development with toner 4 having the same polarity as that during uniform corona charging. It does not matter whether a one-component dry developer, a two-component dry developer, or a liquid developer is used for development. Next, (d) the toner image is transferred onto recording paper 5 such as plain paper. After the transfer, if a dry toner is used, the toner is heated and fixed, and if a wet toner is used, the liquid (carrier liquid) remaining on the recording paper is dried.
なお、帯電の操作は、前記のように、コロナ放電による
方法が最も均一な帯電となる手段であるが、金属ローラ
ーによるローラー帯電装置や導電性ブラシを用いて帯電
させる装置を用いてもよい。As for the charging operation, as described above, the method using corona discharge provides the most uniform charging, but a roller charging device using a metal roller or a charging device using a conductive brush may also be used.
なお、金属ローラーによる帯電を行なう場合、良好な接
触性を得るために均一な帯電を与える目的で、一方のロ
ーラーを導電性を有する弾性体即ちシリコーン系、フッ
素系、ウレタン系等の合成ゴムにカーボン等の低抵抗粒
子を分散した弾性体ローラーを有した帯電装置の使用が
望ましい。When charging with a metal roller, one of the rollers should be made of a conductive elastic material, such as synthetic rubber such as silicone, fluorine, or urethane, in order to provide uniform charging to obtain good contact. It is desirable to use a charging device having an elastic roller in which low resistance particles such as carbon are dispersed.
第3図は本発明方法の実施に有用な装置の一例の概略を
示したものである。枚葉の記録媒体1は供給ローラー6
1でトレイから取り出され、プラテンドラム7のクラン
プ爪71に咬えられる。記録媒体1の静電熱記録層表面
にコロナ帯電器21で均一帯電が施された後、サーマル
ヘッド3によって画像信号に対応した熱信号が与えられ
静電潜像が形成される。この静電潜像は現像ローラー4
1からのトナーで反転現像される。一方、記録紙5が供
給ローラー62によって記録媒体1のトナー像を有する
面に搬送され、転写用コロナ帯電器22の働きによって
記録媒体1上のトナーは記録紙5へと転写される。FIG. 3 schematically depicts an example of equipment useful in carrying out the method of the present invention. The sheet recording medium 1 is fed by a supply roller 6
1, it is taken out from the tray and caught by the clamp claw 71 of the platen drum 7. After the surface of the electrostatic thermal recording layer of the recording medium 1 is uniformly charged by the corona charger 21, a thermal signal corresponding to the image signal is applied by the thermal head 3 to form an electrostatic latent image. This electrostatic latent image is formed by the developing roller 4.
Reversal development is performed using toner from 1. On the other hand, the recording paper 5 is conveyed by the supply roller 62 to the surface of the recording medium 1 having the toner image, and the toner on the recording medium 1 is transferred to the recording paper 5 by the action of the transfer corona charger 22.
この転写後、記録媒体1とトナー像を担持した記録紙5
とは分離される。なお、図示されていないが、記録紙5
上のトナー像は、先に触れたとおり、乾式トナーからな
るものであれば例えば熱定着され、湿式トナーからなる
ものであれば乾燥される。記録媒体1はクランプ爪71
から外され排紙される。After this transfer, the recording medium 1 and the recording paper 5 carrying the toner image are
It is separated from Although not shown, the recording paper 5
As mentioned above, the upper toner image is, for example, heat-fixed if it is made of dry toner, or dried if it is made of wet toner. The recording medium 1 is a clamp claw 71
The paper is removed from the paper and ejected.
この一連の工程を1サイクルとした場合、】サイクルに
より、−枚の記録媒体1の使用に対して一枚の記録紙5
の上に画像形成がなされる。従って、多数枚の複写物を
得るには、その枚数に応じて前記サイクルが繰り返され
ることになる。If this series of steps is considered as one cycle, the ] cycle results in one recording paper 5 for each - number of recording media 1 used.
An image is formed thereon. Therefore, in order to obtain a large number of copies, the cycle described above is repeated according to the number of copies.
なお、第3図において、31はヘッドドライバー63は
排紙ローラー、64は静電熱記録媒体排紙ローラーを表
わしている。In FIG. 3, numeral 31 represents a head driver 63 and a paper ejecting roller, and 64 represents an electrostatic thermal recording medium ejecting roller.
次に実施例を示すが、本発明はこれに限られるわけでは
ない。Examples will be shown next, but the present invention is not limited thereto.
実施例1
第3図に示したような複写装置を用意した。厚さ約40
−のポリプロピレンシートに厚さ約1000人のAQ蒸
着層を設けた静電熱記録媒体をプラテンローラーのクラ
ンプ爪に挟みプラテンドラムに巻きつけた後、表面電位
−500vの帯電を行ない、8dot/I1mのサーマ
ルヘッドで0.6+sJ/datの記録エネルギーで文
字信号を印加し、市販の現像剤(リフ−社製湿式複写機
用液体現像剤)を用いて反転現像し、転写部で逆バイア
スを与え、普通紙上に転写画像を得た。使用後の記録媒
体は排紙した。記録後の静電熱記録媒体シートは、書込
み部の加熱加圧とにより、若干印字部が傷んでいたが、
排紙されてしまうので何等問題となることはなかった。Example 1 A copying machine as shown in FIG. 3 was prepared. Thickness about 40
An electrostatic thermal recording medium consisting of a polypropylene sheet with an AQ vapor deposited layer of about 1000 people thick is sandwiched between the clamp claws of a platen roller and wound around a platen drum, and then charged to a surface potential of -500V, with a surface potential of 8dot/I1m. A character signal is applied with a recording energy of 0.6+sJ/dat using a thermal head, reverse development is performed using a commercially available developer (liquid developer for wet-type copying machines manufactured by Lif Co., Ltd.), and a reverse bias is applied at the transfer section. A transferred image was obtained on plain paper. The recording medium was discharged after use. After recording, the printed area of the electrostatic thermal recording medium sheet was slightly damaged due to the heating and pressure applied to the writing area.
Since the paper was ejected, there was no problem.
本発明によれば、(1)シート状静電熱記録媒体を1回
のみの記録に用いるようにしているのでトナーのクリー
ニング、除電等が省略でき、また(2)静電熱記録媒体
の使い捨てにより、シワ等の発生による劣化がなく、信
頼性が高く良質の画像が容易に得られる。更にまた、装
置の複数さの問題も生じない。According to the present invention, (1) since the sheet-shaped electrostatic thermal recording medium is used for only one recording, toner cleaning, static neutralization, etc. can be omitted; and (2) because the electrostatic thermal recording medium is disposable, There is no deterioration due to the occurrence of wrinkles, etc., and high reliability and high quality images can be easily obtained. Furthermore, the problem of device plurality does not arise.
第1図は本発明に係る静電熱記録媒体の一例の断面図で
ある。
第2図は本発明の方法により画像が得られることの説明
図である。
第3図は本発明の方法の実施に有用な装置の一例の概略
図である。
1・・・静電熱記録媒体
(14・・・ベース層、15・・・静電熱記録層、16
・・導電層)
3・・・サーマルヘッド
4・・・トナー
5・・記録紙FIG. 1 is a sectional view of an example of an electrostatic thermal recording medium according to the present invention. FIG. 2 is an explanatory diagram of an image obtained by the method of the present invention. FIG. 3 is a schematic diagram of an example of an apparatus useful in carrying out the method of the present invention. 1... Electrostatic thermal recording medium (14... Base layer, 15... Electrostatic thermal recording layer, 16
...Conductive layer) 3...Thermal head 4...Toner 5...Recording paper
Claims (1)
帯電性となる静電熱記録層を有するシート状記録媒体の
一端をクランプ爪で咬えて回転ドラムに巻きつけ、その
状態で該記録媒体に均一帯電を施し、画像信号に対応し
た熱信号を与えて電潜像を形成し、その静電潜像を該均
一帯電極性と同一極性のトナーで反転現像して該記録媒
体上に画像を形成し、続いて、その画像を記録紙へ転写
する工程を1サイクルとして行なった後、この1サイク
ル使用した該記録媒体は排紙とし、1サイクルの記録ご
とに新たな該シート状記録媒体を供給し前記工程を繰り
返すことを特徴とする転写型静電熱記録方法。(1) One end of a sheet-like recording medium having an electrostatic thermal recording layer that is chargeable at room temperature and becomes non-chargeable or weakly chargeable under heating is held with a clamp claw and wound around a rotating drum. A recording medium is uniformly charged, a thermal signal corresponding to an image signal is applied to form an electrostatic latent image, and the electrostatic latent image is reversely developed with a toner having the same polarity as the uniformly charged polarity to form an electrostatic latent image on the recording medium. After forming an image and then transferring the image to recording paper as one cycle, the recording medium used for this one cycle is ejected, and a new sheet-like recording is made for each cycle of recording. A transfer type electrostatic thermal recording method characterized by supplying a medium and repeating the above steps.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP11350990A JPH049965A (en) | 1990-04-27 | 1990-04-27 | Transfer type electrostatic thermal recording method |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP11350990A JPH049965A (en) | 1990-04-27 | 1990-04-27 | Transfer type electrostatic thermal recording method |
Publications (1)
Publication Number | Publication Date |
---|---|
JPH049965A true JPH049965A (en) | 1992-01-14 |
Family
ID=14614138
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP11350990A Pending JPH049965A (en) | 1990-04-27 | 1990-04-27 | Transfer type electrostatic thermal recording method |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH049965A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1145696A4 (en) * | 1999-11-13 | 2004-11-24 | Nippon Clean Engine Res Inst C | Walking assisting wheel |
-
1990
- 1990-04-27 JP JP11350990A patent/JPH049965A/en active Pending
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1145696A4 (en) * | 1999-11-13 | 2004-11-24 | Nippon Clean Engine Res Inst C | Walking assisting wheel |
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