JPH0472394A - Composition for treating waste oil - Google Patents
Composition for treating waste oilInfo
- Publication number
- JPH0472394A JPH0472394A JP29888789A JP29888789A JPH0472394A JP H0472394 A JPH0472394 A JP H0472394A JP 29888789 A JP29888789 A JP 29888789A JP 29888789 A JP29888789 A JP 29888789A JP H0472394 A JPH0472394 A JP H0472394A
- Authority
- JP
- Japan
- Prior art keywords
- waste oil
- composition
- surfactant
- compound
- hydrophilic polymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000002699 waste material Substances 0.000 title claims abstract description 24
- 239000000203 mixture Substances 0.000 title claims abstract description 16
- 150000001875 compounds Chemical class 0.000 claims abstract description 18
- 239000004094 surface-active agent Substances 0.000 claims abstract description 15
- 229920001477 hydrophilic polymer Polymers 0.000 claims abstract description 8
- 229920002472 Starch Polymers 0.000 claims abstract description 6
- 239000008107 starch Substances 0.000 claims abstract description 6
- 235000019698 starch Nutrition 0.000 claims abstract description 6
- 229920001282 polysaccharide Polymers 0.000 claims abstract description 4
- 239000005017 polysaccharide Substances 0.000 claims abstract description 4
- 239000001913 cellulose Substances 0.000 claims abstract description 3
- 229920002678 cellulose Polymers 0.000 claims abstract description 3
- 150000004676 glycans Chemical class 0.000 claims abstract 2
- 229920005615 natural polymer Polymers 0.000 claims abstract 2
- 150000001413 amino acids Chemical class 0.000 claims description 2
- -1 polyoxyethylene Polymers 0.000 abstract description 24
- 229920003171 Poly (ethylene oxide) Polymers 0.000 abstract description 11
- 239000000344 soap Substances 0.000 abstract description 7
- 239000010813 municipal solid waste Substances 0.000 abstract description 6
- 238000003756 stirring Methods 0.000 abstract description 5
- 239000002202 Polyethylene glycol Substances 0.000 abstract description 3
- 229920001223 polyethylene glycol Polymers 0.000 abstract description 3
- 238000002156 mixing Methods 0.000 abstract description 2
- 235000011837 pasties Nutrition 0.000 abstract 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 abstract 1
- 239000003921 oil Substances 0.000 description 23
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 14
- 235000014113 dietary fatty acids Nutrition 0.000 description 10
- 239000000194 fatty acid Substances 0.000 description 10
- 229930195729 fatty acid Natural products 0.000 description 10
- 238000000034 method Methods 0.000 description 9
- 125000000217 alkyl group Chemical group 0.000 description 7
- 239000000126 substance Substances 0.000 description 7
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- 235000010443 alginic acid Nutrition 0.000 description 4
- 229920000615 alginic acid Polymers 0.000 description 4
- 229920000642 polymer Polymers 0.000 description 4
- FHVDTGUDJYJELY-UHFFFAOYSA-N 6-{[2-carboxy-4,5-dihydroxy-6-(phosphanyloxy)oxan-3-yl]oxy}-4,5-dihydroxy-3-phosphanyloxane-2-carboxylic acid Chemical compound O1C(C(O)=O)C(P)C(O)C(O)C1OC1C(C(O)=O)OC(OP)C(O)C1O FHVDTGUDJYJELY-UHFFFAOYSA-N 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 229940072056 alginate Drugs 0.000 description 3
- 150000005215 alkyl ethers Chemical class 0.000 description 3
- 150000004665 fatty acids Chemical class 0.000 description 3
- 229920000591 gum Polymers 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical compound OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- 229920001214 Polysorbate 60 Polymers 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 235000015278 beef Nutrition 0.000 description 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000000499 gel Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000013021 overheating Methods 0.000 description 2
- 229920000223 polyglycerol Polymers 0.000 description 2
- 150000004804 polysaccharides Chemical class 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000003755 preservative agent Substances 0.000 description 2
- 238000004064 recycling Methods 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 235000011121 sodium hydroxide Nutrition 0.000 description 2
- 239000003760 tallow Substances 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- 239000002351 wastewater Substances 0.000 description 2
- 229920001285 xanthan gum Polymers 0.000 description 2
- 235000010493 xanthan gum Nutrition 0.000 description 2
- 239000000230 xanthan gum Substances 0.000 description 2
- 229940082509 xanthan gum Drugs 0.000 description 2
- 244000215068 Acacia senegal Species 0.000 description 1
- 102000009027 Albumins Human genes 0.000 description 1
- 108010088751 Albumins Proteins 0.000 description 1
- 241000416162 Astragalus gummifer Species 0.000 description 1
- 239000005711 Benzoic acid Substances 0.000 description 1
- 229910021532 Calcite Inorganic materials 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 102000011632 Caseins Human genes 0.000 description 1
- 108010076119 Caseins Proteins 0.000 description 1
- GHXZTYHSJHQHIJ-UHFFFAOYSA-N Chlorhexidine Chemical compound C=1C=C(Cl)C=CC=1NC(N)=NC(N)=NCCCCCCN=C(N)N=C(N)NC1=CC=C(Cl)C=C1 GHXZTYHSJHQHIJ-UHFFFAOYSA-N 0.000 description 1
- 244000060011 Cocos nucifera Species 0.000 description 1
- 235000013162 Cocos nucifera Nutrition 0.000 description 1
- 102000008186 Collagen Human genes 0.000 description 1
- 108010035532 Collagen Proteins 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- 229920001353 Dextrin Polymers 0.000 description 1
- 239000004375 Dextrin Substances 0.000 description 1
- 241000467686 Eschscholzia lobbii Species 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 239000001856 Ethyl cellulose Substances 0.000 description 1
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 description 1
- 108010010803 Gelatin Proteins 0.000 description 1
- 229920002907 Guar gum Polymers 0.000 description 1
- 229920000084 Gum arabic Polymers 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- 229920002153 Hydroxypropyl cellulose Polymers 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 1
- MTCFGRXMJLQNBG-UHFFFAOYSA-N Serine Natural products OCC(N)C(O)=O MTCFGRXMJLQNBG-UHFFFAOYSA-N 0.000 description 1
- 241000854711 Shinkai Species 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- 229930006000 Sucrose Natural products 0.000 description 1
- 229920001615 Tragacanth Polymers 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 235000010489 acacia gum Nutrition 0.000 description 1
- 239000000205 acacia gum Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000000783 alginic acid Substances 0.000 description 1
- 229960001126 alginic acid Drugs 0.000 description 1
- 150000004781 alginic acids Chemical class 0.000 description 1
- 125000003282 alkyl amino group Chemical group 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 235000010233 benzoic acid Nutrition 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- JRXXLCKWQFKACW-UHFFFAOYSA-N biphenylacetylene Chemical compound C1=CC=CC=C1C#CC1=CC=CC=C1 JRXXLCKWQFKACW-UHFFFAOYSA-N 0.000 description 1
- 229910021538 borax Inorganic materials 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 125000002057 carboxymethyl group Chemical group [H]OC(=O)C([H])([H])[*] 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 239000005018 casein Substances 0.000 description 1
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 1
- 235000021240 caseins Nutrition 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- YCIMNLLNPGFGHC-UHFFFAOYSA-N catechol Chemical compound OC1=CC=CC=C1O YCIMNLLNPGFGHC-UHFFFAOYSA-N 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229960003260 chlorhexidine Drugs 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 229920001436 collagen Polymers 0.000 description 1
- 235000019425 dextrin Nutrition 0.000 description 1
- GSPKZYJPUDYKPI-UHFFFAOYSA-N diethoxy sulfate Chemical compound CCOOS(=O)(=O)OOCC GSPKZYJPUDYKPI-UHFFFAOYSA-N 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 238000010494 dissociation reaction Methods 0.000 description 1
- 230000005593 dissociations Effects 0.000 description 1
- 239000008157 edible vegetable oil Substances 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 description 1
- 235000019325 ethyl cellulose Nutrition 0.000 description 1
- 229920001249 ethyl cellulose Polymers 0.000 description 1
- 238000000855 fermentation Methods 0.000 description 1
- 230000004151 fermentation Effects 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 244000144992 flock Species 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- 239000003349 gelling agent Substances 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 235000010417 guar gum Nutrition 0.000 description 1
- 239000000665 guar gum Substances 0.000 description 1
- 229960002154 guar gum Drugs 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 239000001863 hydroxypropyl cellulose Substances 0.000 description 1
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 description 1
- 230000002779 inactivation Effects 0.000 description 1
- 150000002484 inorganic compounds Chemical class 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000012263 liquid product Substances 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 229930014626 natural product Natural products 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 235000019645 odor Nutrition 0.000 description 1
- 229940049964 oleate Drugs 0.000 description 1
- AICOOMRHRUFYCM-ZRRPKQBOSA-N oxazine, 1 Chemical compound C([C@@H]1[C@H](C(C[C@]2(C)[C@@H]([C@H](C)N(C)C)[C@H](O)C[C@]21C)=O)CC1=CC2)C[C@H]1[C@@]1(C)[C@H]2N=C(C(C)C)OC1 AICOOMRHRUFYCM-ZRRPKQBOSA-N 0.000 description 1
- 239000010893 paper waste Substances 0.000 description 1
- 239000001814 pectin Substances 0.000 description 1
- 235000010987 pectin Nutrition 0.000 description 1
- 229920001277 pectin Polymers 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 description 1
- 229920002432 poly(vinyl methyl ether) polymer Polymers 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 235000010408 potassium alginate Nutrition 0.000 description 1
- 239000000737 potassium alginate Substances 0.000 description 1
- MZYRDLHIWXQJCQ-YZOKENDUSA-L potassium alginate Chemical compound [K+].[K+].O1[C@@H](C([O-])=O)[C@@H](OC)[C@H](O)[C@H](O)[C@@H]1O[C@@H]1[C@@H](C([O-])=O)O[C@@H](O)[C@@H](O)[C@H]1O MZYRDLHIWXQJCQ-YZOKENDUSA-L 0.000 description 1
- 235000011118 potassium hydroxide Nutrition 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000001172 regenerating effect Effects 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 description 1
- 239000004328 sodium tetraborate Substances 0.000 description 1
- 235000010339 sodium tetraborate Nutrition 0.000 description 1
- MZSDGDXXBZSFTG-UHFFFAOYSA-M sodium;benzenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C1=CC=CC=C1 MZSDGDXXBZSFTG-UHFFFAOYSA-M 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- 239000002341 toxic gas Substances 0.000 description 1
- 239000003021 water soluble solvent Substances 0.000 description 1
Landscapes
- Colloid Chemistry (AREA)
- Fats And Perfumes (AREA)
Abstract
Description
【発明の詳細な説明】
(産業上の利用分野)
本発明は天ぷら、フライなどの食用油の廃油を処理する
ための処理組成物に関する。DETAILED DESCRIPTION OF THE INVENTION (Industrial Application Field) The present invention relates to a treatment composition for treating waste oil from edible oil for tempura, frying, etc.
より詳しくは使用済みの廃油を高分子化合物及び可燃性
の水溶性界面活性剤を水と共にゲル化せしめてそのまま
生ゴミとして廃棄するか石けんなどに再生することを特
徴とするものでゴミとして取扱い上の安易さゴミを二次
処理するとき悪臭、有害ガス、その他の公害を出さない
ことを狙いとUまたものである。More specifically, it is characterized by gelling used waste oil with a polymer compound and a flammable water-soluble surfactant together with water and disposing of it as raw garbage or recycling it into soap, etc., and it is difficult to handle as garbage. The aim is to avoid emitting bad odors, harmful gases, and other pollution when secondary processing of garbage is carried out.
従来から食用廃油を処理する方法としては特定の脂肪酸
で固める方法(特開昭55−106298)あるいは石
けん化する方法(特開昭6l−116000)物理的に
天然白土に吸着ろ過再生する方法(特開昭59−813
98)なとのり(にパルプ、不織布、その他繊維状、ス
ポンジ状物質的に吸着せしめて廃棄するなどの方法ある
いはアルカリ物質や界面活性剤と八に水に希釈して乳化
してそのまま排水に供するなど更には苛性ソーダ、苛性
カリなどの強アルカリ物質で石けんとして再生する所謂
廃油石けん化運動の一環としての化学的再利用法など種
々のものが開示され実用化されている。Conventional methods for treating edible waste oil include hardening it with specific fatty acids (Japanese Patent Laid-Open No. 55-106298), turning it into soap (Japanese Patent Laid-Open No. 61-116000), and physically regenerating it by adsorption and filtration on natural white clay (Japanese Patent Laid-Open No. 1983-116000). Kaisho 59-813
98) Dispose of it by adsorbing it with pulp, nonwoven fabric, or other fibrous or spongy materials, or dilute it with an alkaline substance or surfactant and water, emulsify it, and use it as wastewater. In addition, various methods have been disclosed and put into practical use, including chemical recycling methods as part of the so-called waste oil soap movement, in which soap is recycled using strong alkaline substances such as caustic soda and caustic potash.
(本発明が解決しようとする問題点)
本発明は廃油処理の煩雑さを解消し安心してしかも安全
に廃油処理を極めて簡便な方法で処理する方法を提供す
るものである。(Problems to be Solved by the Present Invention) The present invention provides a method for eliminating the complexity of waste oil treatment and processing waste oil in a safe and secure manner using an extremely simple method.
従来のいくつかの方法就中廃油を特定の脂肪酸でゲル化
する方法が極めて注目されているが温度が80° C以
上にならないとゲル化剤が使用できないため過熱による
油火災や取扱いが高温であるため火傷などを起し易く安
心且つ安全に重大なる問題を惹起しつつある。外、バル
ブ、スポンジ状物に吸収して廃棄する方法も油の吸収量
が限度がありいきおい必要以上の容量を余儀なくされた
為に高コスト及び流通過程でのスペース肥大化が進み効
率的ではなかった。Among several conventional methods, the method of gelling waste oil with a specific fatty acid has attracted much attention, but since the gelling agent cannot be used unless the temperature reaches 80°C or higher, oil fires due to overheating and handling at high temperatures are possible. Because of this, it is easy to cause burns and other problems, which is causing serious problems regarding safety and security. The method of disposing of oil by absorbing it into a valve or sponge-like material also has a limit on the amount of oil that can be absorbed, which necessitates a larger capacity than necessary, resulting in high costs and increased space in the distribution process, making it inefficient. Ta.
更に石けん化する方法も苛性ソーダを使用したり火を使
用したりして安全性について、今1つ懸念される問題を
残したままになっている。Furthermore, the method of making soap involves the use of caustic soda or fire, which still leaves concerns about safety.
加えて界面活性剤を利用してそのまま排水処理するに至
ってはそのまま未処理の油を分域に排水するに等しく二
次公害を惹起させる。In addition, treating wastewater directly using surfactants causes secondary pollution, which is equivalent to discharging untreated oil into the watershed.
本発明は、簡易に安全にしかも安心できる天然の原料の
みを利用した組成物を水と一緒に廃油と攪拌する(混合
する)だけでペースト及至ゲル状となしその体性ゴミと
共に廃棄するあるいは石けん化への二次利用を図らんと
するものである。The present invention is a simple, safe and reliable composition that uses only natural raw materials, which can be made into a paste or gel by simply stirring (mixing) it with water and waste oil, and can be disposed of with the body waste or used as soap. The aim is to achieve secondary use in the field of technology.
当該ペースト及至ゲル状物は水分が40〜60%含有す
るも焼却処理可能なもので燃焼しても有害物を発注する
ことなく自然分解する安全なものである。Although the paste or gel-like material contains 40 to 60% water, it can be incinerated and is safe because it naturally decomposes without producing harmful substances even if it is burned.
(fJ]題を解決するための手段)
本発明は親水性高分子化合物及びHLBが7以上の界面
活性剤からなる組成物を使用して廃油を廃油の40〜3
oo%位の水と混合してペースト化となし廃棄処理する
。(fJ) Means for Solving the Problem) The present invention uses a composition consisting of a hydrophilic polymer compound and a surfactant with an HLB of 7 or more to remove waste oil from 40 to 3
It is mixed with about 0% water to make a paste and disposed of.
水の代りに熱湯(60″ C以上)を用いるとよりペー
スト化が促され確実に処理できることとなる。If hot water (60''C or higher) is used instead of water, the paste will be more easily formed and the process can be carried out more reliably.
親水性高分子化合物としては次のものが挙げられる就中
天然系のものが安全性処理能力の上から好ましい。Examples of the hydrophilic polymer compound include the following, among which natural compounds are preferred from the standpoint of safety and processing ability.
(多糖系)キサンタンガム、デキストリンスターチサク
シノグルカン、力〜トラン、ペクチン、マンナンジアル
デヒドスターチグアーガム、カルボキシメチルスターチ
メチルスターチ、ロー力ストービンガム力うギナン、ア
ラビアガム、トラガントガム、その他機生物醗酵により
生成された多糖ガム類
(アミノ酸系)ゼラチン、カゼイン、コラーゲン、アル
ブミン
(セルロース系)メチルセルロース、ニノーロセルロー
ス、エチルセルロース、ヒドロキシプロピルセルロース
、ヒドロキシエチルセルロース、メチルヒドロキシツブ
ロビルセルロース、カルボキシメチルセルロース
(°アルギン酸系)アルギン酸ソータ、アルギン酸カリ
、アルギン酸アニモン、アルギン酸ブ11ピレングリコ
ール
(合成系)ポリビニルアルコーン、ポリヒニルピロリド
ン、ポリビニルメチルエーテル、カルホキンビニルボリ
マー ポリアクリル酸ソーダ、ポリ酢酸ビニル、ボッア
クリルアミド、ボッエチレンオキサイド、ポリエチレン
グリコール、/iQ化ユヂ1.ノン、プロピンコポリマ
ー、ボッビニルアルクール(その4IJ!、)う715
ナーfト、セオライト、モンモリヲーイト、ベン1ナイ
ト、コlコイタルアルミナ、などマグネシウム、アルミ
ニウムシリカ系の無機化合物等。(Polysaccharides) xanthan gum, dextrin starch, succinoglucan, tolan, pectin, mannandialdehyde starch, guar gum, carboxymethyl starch, methyl starch, low strength stoving gum, low strength stubbing gum, gum arabic, gum tragacanth, and other products produced by biological fermentation. polysaccharide gums (amino acid-based) gelatin, casein, collagen, albumin (cellulose-based) methylcellulose, ninocellulose, ethylcellulose, hydroxypropylcellulose, hydroxyethylcellulose, methylhydroxytubulobilcellulose, carboxymethylcellulose (alginic acid-based) alginate sorter , Potassium alginate, Animony alginate, But-11-pyrene glycol alginate (synthetic type), Polyvinyl alkone, Polyhinylpyrrolidone, Polyvinyl methyl ether, Calfoquin vinyl polymer, Sodium polyacrylate, Polyvinyl acetate, Botacrylamide, Botethylene oxide, Polyethylene glycol, /iQ compound 1. Non, propyne copolymer, bobbinyl alcohol (4IJ!) U715
Magnesium, aluminum-silica-based inorganic compounds such as nerf, theolite, montmorite, benite, colicotal alumina, etc.
一方II L )37以上の界面活性剤とし、では例え
ば
(陰イオン系)
LAS、ΔO3,SAS、7 /L/キル硫酸エステル
ソータ゛ 脂肪酸塩、アルキルフェノール、エトキシ硫
酸化物、アルキルスルホザクシネート、アルキル燐酸エ
ステルソーダ、アルキルアミノ酸塩
(非イオン系)
ポリオキシエチレンアルキルエーテル、ポリオキシエチ
レンアルキルフェノールエーテル、ポリオキシエチレン
モノアルキレートポリオキシエチレンジアルキレート、
ソルビタンモノアルキレート、ソルビタンポリアルキレ
ート、ポリオキシエチレンソルビタンモノアルキレート
、オキシエチレンオキシプロピレンフロックポリマー
アルキル脂肪酸アルキロールアミド、グリセロールモノ
アルキレート、ポリグリセロールアルキル脂肪酸エステ
ルなど
(いずれもアルキル基はC8〜CI[lが好ましい)
その地雨性系、陽イオン系のものもあるがとりわけ陰イ
オン、非イオン系で発泡性のすぐれたものがよく形状は
、組成物が粉(固)体の場合液体の場合でいずれてもよ
い両者の比率は任意に混合してもよいがペースト強度を
維持する上で高分子化合物が界面活性剤より多い方大体
前者か50〜・1)5%後者その残りが通常の割合であ
る。On the other hand, II L) is a surfactant of 37 or more, such as (anionic) LAS, ΔO3, SAS, 7 /L/Kyl sulfate ester sorter Fatty acid salt, alkylphenol, ethoxy sulfate, alkyl sulfosuccinate, alkyl phosphoric acid Ester soda, alkyl amino acid salt (nonionic) polyoxyethylene alkyl ether, polyoxyethylene alkylphenol ether, polyoxyethylene monoalkylate polyoxyethylene dialkylate,
Sorbitan monoalkylate, sorbitan polyalkylate, polyoxyethylene sorbitan monoalkylate, oxyethylene oxypropylene flock polymer
Alkyl fatty acid alkylolamides, glycerol monoalkylates, polyglycerol alkyl fatty acid esters, etc. (In all cases, the alkyl group is C8 to CI [preferably l).Although there are alkyl fatty acid alkylolamides, glycerol monoalkylates, polyglycerol alkyl fatty acid esters, etc. An ionic type with excellent foaming properties is preferred.The composition may be either powder (solid) or liquid.The ratio of the two may be mixed arbitrarily, but it is important to maintain the strength of the paste. If the polymer compound is more than the surfactant, the former is approximately 50 to 1) 5%, and the remainder is the normal proportion.
之らは2種以上併用しても構わないし予め水又は水溶性
溶剤例えばエチレングリコ1ル、プロピレングリコール
、1−3フヂレングリコール、低級アルキルセロソルフ
4M 級アルキルカルピトートル、低級アル:1−ル、
ソルビト−ルなどに予め分散又は溶解しても可である。Two or more of these may be used in combination, and water or a water-soluble solvent such as ethylene glycol, propylene glycol, 1-3 phenylene glycol, lower alkyl cellosol, 4 M-grade alkyl carpitotol, lower alkyl: - Le,
It is also possible to disperse or dissolve it in advance in sorbitol or the like.
(作用)
本発明は親水性高分子化合物及びf(L B 7以上の
界面活性剤の必須成分を組成物として廃油つまり疎水性
物質が水を介して一種のエマルジョンケルを形成する。(Function) The present invention uses a hydrophilic polymer compound and an essential component of a surfactant with an L B of 7 or more as a composition, and waste oil, that is, a hydrophobic substance, forms a kind of emulsion gel through water.
従って廃油は食用のものでも鉱物系の炭化水素、溶剤、
その他、水不溶性の物質を含むものも固化することがで
きるのが特徴である。Therefore, even if waste oil is edible, it may contain mineral hydrocarbons, solvents,
Another feature is that it can also solidify substances containing water-insoluble substances.
親水性高分子化合物の内多I!類がとりわ+:lずぐれ
ている。Uchida I of hydrophilic polymer compound! The kind is outstanding +: l is out of line.
例え(、t′キサンタンガム、ファーカム、ローカスト
ヒーンガム、アラビアカム、カラクタンカムが好ましい
。For example, t'xanthan gum, farcum, locust hean gum, arabicum, and calactancum are preferred.
界面活性剤では乳化力、親水性を考慮すればポリメキソ
エチレンアルキルフゴ、ノルエーテル、ポリオキシエチ
レンアルキルエーテル、硬化ヒマシ油EO何加物([E
O15モル以上)硬化牛脂EO付加物(EO15モル以
上 ポリオキシエチレン脂肪酸アルカノールアミF1ポ
リオキシエチレンソルヒタン脂肪酸エステル、ポリエチ
レングリコールアルキレート、エチレンプロピレンブロ
ノク共重合エーテル、ポリオキシエチレンショ糖脂肪酸
エステル、ポリクリセリンステアリン酸エステルなどが
々了ましく之らは粉状、フレーク状、ニードル状あるい
は、液状で存在する。HL B V B上としたのは親
水性を良好にして洗浄機能をもたらす目安であるためで
ある。Among surfactants, considering emulsifying power and hydrophilicity, polymexoethylene alkyl fugo, norether, polyoxyethylene alkyl ether, hydrogenated castor oil EO additives ([E
O 15 mol or more) Hardened beef tallow EO adduct (EO 15 mol or more Polyoxyethylene fatty acid alkanolamine F1 polyoxyethylene sorbitan fatty acid ester, polyethylene glycol alkylate, ethylene propylene bronoch copolymer ether, polyoxyethylene sucrose fatty acid ester, polycrystalline Serine stearate esters, etc., exist in the form of powder, flakes, needles, or liquid.The reason for setting it above HL B V B is to improve hydrophilicity and provide a cleaning function. It's for a reason.
この他に商品形成」−防腐剤を使用することを可とする
。In addition, it is allowed to use preservatives in product formation.
パラベン系、安息香酸系、陽イオン系、クロルヘキシジ
ン系、フェノール系などが代表である。Typical examples include parabens, benzoic acid, cations, chlorhexidine, and phenol.
この場合界面活性剤との不活性化11用を吟味して欲し
い。〔「江用清等衛生化学V021 No 42281
975年」参照〕本発明組成物は廃油に対して(100
重量部)1〜10重量部加える。In this case, please consider using inactivation 11 with a surfactant. [“Eyo Kiyoshi Sanitary Chemistry V021 No 42281
975]] The composition of the present invention is effective against waste oil (100
Parts by weight) Add 1 to 10 parts by weight.
又水の量はペースト強度によるが廃油に対して40〜3
00W%が一般的なるも厳しく規制できるものではない
。使用水はより好ましくは60° C以上の熱湯が分散
性乳化性を改良する。Also, the amount of water depends on the strength of the paste, but it is 40 to 3
Although 00W% is common, it cannot be strictly regulated. The water used is preferably hot water of 60° C. or higher to improve dispersibility and emulsification.
攪拌は、均一になればよく一律でない。Stirring should be done uniformly, but not uniformly.
本発明は特定の界面活性剤を使用するために使用容器(
例えば鍋、フライパン、廃油、貯蔵器をそのまま水洗い
するたりて食器洗いを利用する必要もない。The present invention provides a container for use with a specific surfactant (
For example, there is no need to wash pots, frying pans, waste oil, and storage containers with water or use a dishwasher.
この他にも増量剤、乳化促進剤、油吸収剤(パルプ、ス
ポンジ、フィブリル)など例えば硫酸塩、炭酸塩、鱗酸
塩、珪酸塩、硝酸塩尿素、シリカ、アルミナ、カルサイ
ト、セリサイト、キレート剤、アミン化合物、硼砂、ソ
ーダ化合物などを添加してもよい。In addition, fillers, emulsifiers, oil absorbents (pulp, sponge, fibrils), etc. such as sulfates, carbonates, scales, silicates, nitrates, urea, silica, alumina, calcite, sericite, chelates Agents, amine compounds, borax, soda compounds, etc. may be added.
(実施例−■) 次の廃油処理組成物を試作してみた。(Example-■) I tried making the following waste oil treatment composition.
■ポリオキシエチレン(Eo、10モル)ヤシアルキル
エーテル
■ポリオキシエチレン(Eo、25モル)硬化牛脂
■ステアリン酸ジェタノールアミド(Eo。■Polyoxyethylene (Eo, 10 mol) Coconut alkyl ether ■Polyoxyethylene (Eo, 25 mol) Hardened beef tallow ■Stearic acid jetanolamide (Eo.
15モル)
L IM ?; ノ 界 凹 茫 1王 ガ水道水
を加え全体をペーストになるまで攪拌する。(所用時M
20〜30秒)
試作物はそのまま古紙、ラップフィルムなどに包んで生
ゴミと同様に廃棄できる。15 moles) L IM? Add tap water and stir until the mixture becomes a paste. (When required M
(20-30 seconds) The prototype can be wrapped in waste paper, cling film, etc. and disposed of like garbage.
因みに本品を1ケ月放置した処理及び水の解離はなく又
ペースト強度も低下しなかった。Incidentally, when this product was left for one month, there was no dissociation of water and no decrease in paste strength.
(但し防腐剤を配合しないと腐敗する兆しがある。)
尚Fはペーストにならない液状品であった(実施例−2
)
界面活性剤
イ ポリオキシエチレン(EO25モル)ノニルフェノ
ールニーチル
ロ 直鎖アルキル(C,2)ベンゼンスルホン酸ツーダ
ハ オレイン酸ソーダ
実施例−1の使用例と同様に処理したが廃油処理時間、
使用容器の洗浄能、試作物のペースト強度などいずれも
本発明に比して大差がある。(However, there are signs of spoilage if no preservative is added.) F was a liquid product that did not become a paste (Example 2)
) Surfactant A Polyoxyethylene (25 mol of EO) Nonylphenol Nichirulo Straight chain alkyl (C,2) benzenesulfonic acid Sodium oleate Processed in the same manner as in Example 1, but the waste oil treatment time was
There are large differences in both the cleaning ability of the container used and the paste strength of the prototype compared to the present invention.
又高分子化合物のみを大量に使用するも可なるが価格的
に高くなり実用的でない。It would also be possible to use a large amount of only a polymer compound, but this would be expensive and impractical.
(効果)
かくして本発明の廃油処理組成物は従来品に比し次の格
別の効果を奉する。(Effects) Thus, the waste oil treatment composition of the present invention provides the following special effects compared to conventional products.
■過熱を要することなく廃油を処理できるので火事、火
傷などの心配がない。■ Waste oil can be processed without overheating, so there is no need to worry about fires or burns.
■ペースト試作物はそのまま新開紙などに包んで廃棄で
き生ゴミ同様に扱える。■Paste prototypes can be disposed of by wrapping them in paper, such as Shinkai paper, and can be treated like garbage.
■高分子化合物そのものは高価であり大量に使うとペー
スト状になりえるが不経済であり廃棄用品としてはなじ
まないばかりかベスト化するまで時間がかかる。■High molecular compounds themselves are expensive, and if used in large quantities they can become paste-like, which is uneconomical and not only not suitable for disposal, but also takes a long time to develop into the best quality.
■廃棄物は有害、有毒なガスを発生したり一次汚染を来
すことは全くない。■Waste does not generate harmful or toxic gases or cause primary pollution.
■処理組成物は少量で(廃油1ρ処理するのに約40g
程度であり流通過程に商品化し易い。■A small amount of treatment composition is required (approximately 40g to treat 1ρ of waste oil.
It is easy to commercialize the product in the distribution process.
■特別の技術を要することなく又殆んど1分以内に攪拌
するだけでペースト化して誰にでも簡易に処理できる。■It does not require any special skills and can be easily processed by anyone by turning it into a paste within about 1 minute by stirring.
以 −トBelow
Claims (2)
処理組成物(1) Waste oil treatment composition consisting of a hydrophilic polymer compound and a surfactant
物、セルロース化合物、でんぷん類化合物からなる天然
高分子及びHLBが7以上であって界面活性剤 から本質的になることを特徴とする廃油処理用組成物(2) Waste oil characterized in that the hydrophilic polymer compound consists essentially of a natural polymer consisting of polysaccharides, amino acids, compounds, cellulose compounds, and starch compounds, and a surfactant with an HLB of 7 or more. Treatment composition
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP29888789A JPH0472394A (en) | 1989-11-17 | 1989-11-17 | Composition for treating waste oil |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP29888789A JPH0472394A (en) | 1989-11-17 | 1989-11-17 | Composition for treating waste oil |
Publications (1)
Publication Number | Publication Date |
---|---|
JPH0472394A true JPH0472394A (en) | 1992-03-06 |
Family
ID=17865454
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP29888789A Pending JPH0472394A (en) | 1989-11-17 | 1989-11-17 | Composition for treating waste oil |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH0472394A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPWO2013172075A1 (en) * | 2012-05-18 | 2016-01-12 | 株式会社J−オイルミルズ | Crystallization accelerator |
-
1989
- 1989-11-17 JP JP29888789A patent/JPH0472394A/en active Pending
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPWO2013172075A1 (en) * | 2012-05-18 | 2016-01-12 | 株式会社J−オイルミルズ | Crystallization accelerator |
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